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By Md. Amanullah

A novel triple action load cell assembly (LCA) was developed to determine three index parameters reflecting compressive, tensile and shear characteristics of mudcakes. The results indicate that the tensile, compressive and torsional behaviour of mudcakes are strongly influenced by the physics and chemistry of the mud additives. Eine neuartige dreifach wirkende Druckkammer zur Bestimmung der drei Indexparameter Druck, Zug, und Scherung von Spülungskuchen wurde entwickelt. Die Ergebnisse weisen auf einen starken Einfluss der physikalischen und chemischen Spülungszusätze auf Druck, Zug, Scherung hin. Un assemblage d'une nouvelle cellule a triple action (LCA) a été développée pour déterminer trois paramètres caractérisant la compression, la contrainte en traction et la résistance á la fracture des cakes. Les résultats indiquent que les comportements tensile, compressif et de torsion des argiles sont fortement influencés par la chimie et la physique des additifs des boues.

Jan 1, 2003

By C. Ndou, T. Mothupi, H. Mandende

The technological advances in efficient, rapid, and non-destructive hyperspectral core logging systems for systematic mineral mapping have led to the discovery and exploitation of new mineral deposits Hyperspectral imaging in the long-wave infrared range has been recently used successfully to identify various phosphatebearing minerals (monazite, xenotime, and britholite), with limited work on apatite associated with mafic-ultramafic layered intrusions. In this study we investigate the effectiveness of a hyperspectral imaging (HSI) system with long-wave infrared (LWIR) bandwidthsto identify apatite in the Upper Zone of the Bushveld Complex. The accuracy of the HSI results was validated by mineralogical and geochemical data. The two apatite-enriched zones detected by HSI suggesting widespread development of apatite throughout the uppermost 600 m of the Upper Zone. The lower apatite-enriched zone is approximately 40 m thick, while the upper apatite-enriched zone is about 23 m thick, consistent with previous thickness determinations by traditional logging and analytical methods. Spectral mixing observed in the response of apatite is ascribed either to the common association of apatite and olivine in these rocks, or to differences between the spatial resolution of the hyperspectral image and the size of apatite grains. The VNIR-SWIR wavelength region did not show prominent spectral features of apatite. Nonetheless, HSI in the LWIR range is effective in mapping apatite and should therefore be considered as an exploration tool. This research advances our knowledge of the reflectance spectroscopy of REE-bearing minerals, which makes it easier to detect, identify, and quantify REE-bearing silicate minerals by HSI.

Feb 6, 2023

By H. Ramazi, A. Amini

"This article is devoted to the introduction of a new technique of electrical resistivity data processing called residual resistivity (RR). We define RR as measured resistivity minus background resistivity. To determine the background resistivity, the data acquired from electrical resistivity measurements along a given survey line is evaluated, and then an equation is fitted to the data corresponding to a chosen measurement station as a function of current electrode spacing (or array length). The RR technique was applied to several synthetic models to compare the conventional resistivity inversion of each model with its RR-based inversion. A case study was carried out in a karstic area in Zarrinabad, Lorestan Province, western Iran, to detect the location and geometry of probable cavities by conventional resistivity inversion and RR-based inversion. The results showed that the anomalous zones are better highlighted in the RR-based inversion images in comparison with the conventional inversion images. In some cases, anomalies detected by the RR-based images were hidden in the conventional method. IntroductionThe geoelectrical resistivity method has been widely used since the early 20th century, and plays an important role in several fields such as groundwater and subsurface mineral exploration, geotechnical and environmental investigations, and archeological studies (Bayrak and Senel, 2012; Candansayar and Basokur, 2001; Fehdi et al., 2011; Hee et al., 2010; Osella et al., 2003; Wilkinson et al., 2010). The goal of geoelectrical resistivity surveys is to determine the distribution of subsurface resistivity by measuring the current-potential difference on the ground surface (Aizebeokhai et al., 2010). In the electrical resistivity method, an electrical current is injected into the ground by two electrodes, called current electrodes (AB), and the potential difference is measured between another pair of electrodes, the potential electrodes (MN). Several methods of interpretation are available for application to electrical resistivity data, the simplest being the graphical interpretation of the apparent electrical resistivity pseudo-sections along each survey line. A second method, electrical resistivity inversion, has been developed to create relatively accurate two- and threedimensional computational resistivity models of subsurface sections (Loke and Barker, 1996; Niwas and Mehrotra, 1997; Nordiana et al., 2014; Oldenburg and Li, 1994; Papadopoulos et al., 2009; Yilmaz and Narman, 2014). In the inversion method, models of subsurface objectives are mathematically inverted to reach optimal solutions subject to prescribed objective functions, constrains, and convergence criteria. A common problem when using the electrical resistivity inversion method is that the inversion model of an electrical resistivity profile may be non-unique because different inhomogeneities in the investigation media can result in the same electrical response (Smith and Vozzof, 1984)."

Jan 1, 2016

By W. V. Mutler

Present day capital costs are analyzed for a 2,000 metric tonne per day (MTPD) pyrite burning plant and compared with a sulphur burning plant of the same capacity. Power, raw material and steam production rates are then compared for the two facility types. A sensitivity analysis is conducted to highlight the impact changing sulphur, pyrite, capital and operating costs have on the relative economics of these feeds. Technological improvement effects on capital cost and energy recovery are also discussed. Besides the steam produced from the burning of pure sulphur or pyrite, plants using an advanced form of heat recovery can produce up to 10 bar steam using heat from acid formation. The quantity depends on the overall water balance which is influenced by such factors as gas strength and product acid concentration. Modern materials and innovative process design also improve the ability to increase the high pressure steam from the roaster boiler in pyrite plants above the traditional 1.25 kg of superheated steam per kg of acid produced.

Jan 1, 2009

By S. J. Thomas, P. A. Lilly, J. A. L. Napier

An industry research project has been established to examine the issue of rock mass failure in large open pit slopes. The approach began with numerically modelling failure at the laboratory scale with a displacement discontinuity program. The interim results from the program suggest the output failure mode is dependent upon the input parameter cohesion weakening. Es wurde ein Forschungsproject mit unterstützung von Bergbauindustrie bearbeitet. Die Zielsetzung der vorliegenden Arbeit war die Analysierung des Böschungsgefähr im größen Festgesteinstagebauen. Das Verfahren besteht aus der numerischer Modelierung mit Ansatz einen sonderen Rechnerprogram. Die erste Ergebnis zeigt, daß die Aufgabe am Angabendaten (cohesion) abhängig sein wird. Un project de recherche industriel fût conduit avec le but d’examiner les éboulements de roche dans les mines a ciel ouvert. La premiere étape a été de modelliser numériquement les éboulements dans un laboratoire en utilisant un programme de déplacement discontinu. Les resultants préliminaires du programme indiquent que la prédiction des ébouliements est directement reliée à la magnitude de la cohesion.

Jan 1, 2003

By F. Ntuli, T. V. Nyangadzayi

Chromium green is an essential metal with various applications in the paints, construction, electronics, and aerospace industries. The main source of chromium green is the carbo-thermic reduction of chromite ores, however, chromite ores are being heavily depleted on a global scale, hence the need to find alternative or secondary sources for the chromium. In order to meet the global demand for chromium there is a need to implement principles of the sustainable circular economy to keep chromium within the material loop. Ferrochrome slag and stainless steel slags are secondary resources that are potential sources of chromium. In this work, recovery of chromium from ferrochrome slag was investigated. The ferrochrome slag was alkaline leached using sodium hydroxide- sodium hypochlorite solution to reduce the use of potent reagents that have a potential negative environmental impact. The leachate produced by oxidative alkaline leaching of ferrochrome slag contained hexavalent chromium, which was used to recover the extracted chromium through a two-stage process involving reduction and precipitation. Reduction of hexavalent Cr to trivalent Cr was investigated using anhydrous FeSO4 at concentrations of 5 g/L, 10 g/L, and 15 g/L. Precipitation was conducted by dosing the reduced leach solution with 1 M sodium hydroxide at dosages of 5 ml/L, 10 ml/L, and 15 ml/L. The experiments were designed using the Taguchi (L9) orthogonal array and analysed according to the ANOVA, general linear model. The optimized conditions for the reduction step were ferrous sulfate dosage of 5 g/L with a pH of 12, and for the precipitation step, 1 M sodium hydroxide at a dosage of 15 ml/L with a setting time of 90 minutes and pH of 7. Physical changes were observed during the two-step chromium recovery, with solution changing from a yellowish colour to dark green colour indicating completion of the reaction. The chromium recovery was found to be 93.3%.

Dec 11, 2024

By C. W. P. Finn

INFACON is of special significance to people in South Africa who are interested in ferro-alloys, because it was in South Africa that the idea of regular international congresses on ferro-alloys was conceived and developed. INFACON 74, the first-ever such congress, was held in Johannesburg from 22nd to 26th April, 1974, being organized by the South African Institute of Mining and Metallurgy, the National Institute for Metallurgy, and the Ferro Alloy Producers' Association of South Africa. Design Awards The Design Institute is inviting entries for the 1981 Shell Design Awards. Any product that falls into the three categories shown below, and that was designed in South Africa and is in production, is eligible for an award. Since their inception in 1970, the Shell Design Awards

Jan 1, 1981

By M. Z. Emad, M. U. Khan, A. ur Rehman

The use of stemming plugs in surface blasting is gaining popularity because of the environmental, technical, and economic advantages. Although previous studies have established the operational effectiveness of different types of stemming plugs, evaluations of the economic and ergonomic impacts are lacking, thereby hindering their application in many mining operations. Consequently, a significant proportion of mining operations end up performing less efficient blasts. We evaluated the effectiveness of three types of stemming plugs by conducting multiple full-scale production blasts. The results show that stemming plugs reduce the need for secondary blasting and increase blast performance. An economicanalysis showed that the incorporation of stemming plugs can reduce blasting costs significantly.

Jul 1, 2021

By A. J. Jager, D. P. Roberts

The stoping of platinum orebodies in the Bushveld has in the past been accomplished by using in-stope pillars to ensure stability of the workings. In the future, the use of continuous mining machines to mine the platinum orebodies is probable. It is not envisaged that such machines will cut in-stope pillars. This paper describes the alternative support systems that will replace the pillars and the stope geometries that will be required for this type of mining. The paper describes how the support resistance provided by in-stope pillars in current mining was determined and then evaluates support systems that can substitute for these pillars. Conceptual layouts based on existing breast mining layouts are presented. The layouts consist of panels of up to 100 m face length between rigid strike stabilizing pillars. A number of design charts are then proposed that allow for the design of appropriate support systems.

Jan 1, 2004

By M. -H. Fillion

"Geotechnical stability analysis and design in open pit mines requires access to representative geological, structural, hydrogeological, and rock mass models. The quality and quantity of collected geomechanical data used to build such models can have significant implications in the design of safe and economically viable slopes. Data collection is a continuous process throughout the life of a mine. The process starts from exploration to conceptual/preliminary feasibility, feasibility, design and construction, operations (early production/late production), and mine closure.As geomechanical data is often limited at an early stage of a project, the estimated variability of the geotechnical factors may be larger than the actual data variability. This can potentially result in a conservative selection of the pit slope angle. Collecting additional geomechanical data at later stages of the mine development may contribute to reducing the uncertainty associated with the geotechnical properties and a steeper slope angle may be used for the design. This can result in significant economic benefits.This paper investigates the impact of access to new data over time, following a series of geomechanical data collection campaigns, on design decisions. This is illustrated by comparing the resulting slope design, at three stages of the mine project, at a South African open pit mine. To demonstrate this, a series of slope stability analyses were performed using limit equilibrium tools. For each project stage, the slope angle design was modified until a similar probability of failure of 5% or less was obtained. The corresponding factor of safety distributions for each project stage were then compared to evaluate the impact of collecting additional data on the resulting slope design.The results showed that data variability can differ significantly from one project stage to another. Data variability may be greater at more advanced project stages (i.e. a wider distribution of the factor of safety). Furthermore, the results showed that, even for the cases with greater variability, steeper slope angles were possible at more advanced stages for the proposed design requirement (probability of failure < 5%). In this investigation, as more data became available, the uncertainty associated with data variability could be sufficiently reduced to allow the selection of less conservative slope angles. This can be used as a managerial tool in developing data collection strategies and allocating the necessary funds, and can lead to important economic benefits to the mining operation."

Jan 1, 2016

By P. Linzer, L. M. Linzer

The gravity method is often applied in mining-related scenarios such as geological and mineral exploration, detecting subsurface cavities and voids (“receptacles”) that may become sinkholes, siting of surface structures, fault-mapping, and more. It is also widely applied in geotechnical engineering to map subsurface karst profiles and to detect subsurface cavities, such as can occur in open pit mines. While it is widely acknowledged that, compared with other available geophysical methods, this method is the most applicable to the karst profiling problem, survey geometries applied in the field are often far from optimal. The gravity surveying specifications prescribed in SANS 1936 omit some key requirements for optimal survey outcomes, and this paper is intended to fill those gaps. The authors have seen scopes of work that require only a few measurements over the footprint of a proposed structure, indicating a lack of understanding of the nature of the gravitational field. A single gravity measurement is subject to the camouflaging effects of several influences, many of which can be larger than the anomaly caused by the subsurface density variation itself. Papers in the body of literature show an awareness of the need to map the regional field so that it can be subtracted to unmask the residual gravity anomaly, but rarely do they examine how instrument sensitivity governs the size of detectable anomalies or discuss how a detailed terrain correction can be instrumental for isolating faint targets. This paper aims to explain how to apply the gravity method correctly to mining and geotechnical problems, specifically in the detection of subsurface cavities. It discusses various factors to assist with optimising the acquisition of gravity data and its processing so as to maximise the practical value of gravity surveys.

Sep 1, 2025

By W. Guiye, L. Chongjun, L. Huinan, Z. Yangge, H. Long

The current application of copper-molybdenum (Cu-Mo) separation inhibitors is often associated with large dosage, high toxicity, environmental pollution problems. In order to solve these problems, a light sensitive Cu-Mo separation inhibitor LS（light sensitive inhibitor，abbreviated to LS） was developed. In this paper, inhibitory performance, photodegradation rule, and acting mechanism of LS were studied. The subsequent test results showed that, compared with traditional inhibitors, LS has shown comparative advantages, with lower dosage and good inhibiting effect. A series of flotation tests with LS as inhibitor were conducted on a Cu-Mo concentrate. A locked-cycle test showed that a molybdenum concentrate containing Mo 49.88% and Cu 0.6%, with 93.23% molybdenum recovery and a copper concentrate containing Cu 29.92%, with 99.99% copper recovery can be obtained. The photodegradation performance of the reagent was investigated under 365 nm, 254 nm and sunlight irradiation. The degradation of the reagents could be completely achieved by irradiation of three wavelengths of light. However, with the different wavelength of irradiation light, the degradation rate is different, the time required to reach 50% degradation rate being 3 h (254nm), 4 h (solar light) and 6 h (365nm) respectively. The inhibition mechanism on chalcopyrite was studied. FTIR study showed that LS could be adsorbed on the surface of chalcopyrite by chemical adsorption, which could enhance the hydrophilicity of chalcopyrite. Ultraviolet adsorption tests indicated that the adsorption capacity of LS on chalcopyrite surface was greatly affected by pulp pH value, and the proper pH value was 5-9. Keywords: Copper-molybdenum separation, Inhibitor, Light-sensitive, Photodegradation, Mechanism.

Jan 1, 2020

By L. Tartibu, S. Assuli, P. Nkul, A. Kabimba, W. Elongo, N. Makhotla, D. F. Verwey, F. G. Ndiitwani, J. Bilali, T. Mukongo

The presence of colloidal silica negatively impacts various hydrometallurgy processes. This paper details the nature of colloidal silica, operational issues caused by colloidal silica, as well as various mitigation measures. MMG Kinsevere observed severe phase-continuity instability, increased crud formation, and reagent consumption, and reduced current efficiency in electrowinning with a deterioration in copper quality. Historical mitigation measures were initially implemented but failed to solve the problem. MMG Kinsevere successfully achieved efficient silica removal without adverse effect on the solvent extraction with the use of DEHSCOFIX® SC12 coagulant. A week into the coagulant trial, silica concentration had dropped from > 1500 mg/L to within 500 mg/L. The solventextraction plant recovered its stability and again operated at maximum capacity. Additionally, improvement was observed on current efficiency and copper cathodes quality with use of the coagulant.

Jan 1, 2023

Mr D. Twigg graduated in Metallurgy at the Sheffield Polytechnic, and later obtained a Master of Science degree at the University of Bradford. Mr I.D. Matthews matriculated at Roosevelt High School and joined the No. 1 Parachute Battalion in 1968. He worked in Zimbabwe for 31 years in geological prospecting, civil engineering, and open-pit mining.

Jan 1, 1985

By S. Lohmeier, D. Gallhofer, B. G. Lottermoser

Reprocessing of historic gold tailings is a common activity in South Africa, while base metal tailings offer similar reprocessing potential. The historic base metal tailings of the Namib Pb–Zn mine (Erongo Region, Namibia) still contain valuable resources of Pb and Zn in carbonate-rich matter. Micro-analysis of primary ore minerals identifies some galena as argentiferous and sphalerite as the principal host of Cd. This study demonstrates that knowledge of primary ore mineralogy helps to reveal the hosts of valuable commodities (Ag, Cd) and that field-portable X-ray fluorescence tools allow precise and accurate determinations of major and minor elements like Zn and Cd in such carbonate-rich material. Although there are limitations to directly determine the contents of certain element (i.e., As, Sb, In), linear correlations allow prediction of the likely abundance of these elements. Providing that the inter-mineral and inter-element relations are understood and there is consistency in sampling and analytical methodology, portable X-ray fluorescence analysis is an effective method to evaluate the chemical characteristics of base metal tailings for a range of major and trace elements.

Sep 9, 2024

By D. Weijie, S. Kai, Y. Hu, X. Ning, M. Shiyi, W. Junpeng, Z. Guihong, L. Xianjie

Flotation is one of the most important processes in the copper production industry. The copper grade in the concentrate is a pivotal indicator of the flotation process performance. However, it is difficult to achieve real-time measurement through hardware sensors. Based on the production data provided by an industrial operation, a novel soft sensor based on multi-layer perceptron (MLP) is proposed for effective monitoring of this pivotal indicator. The proposed soft sensor uses the nonnegative garrote (NNG) to perform global variable selection for MLP, while a local search (LS) approach is incorporated to improve the model presented by NNG. Simulation results show that the proposed algorithm has higher prediction accuracy and better model simplicity than other algorithms. Furthermore, the variables selected are consistent with the field experience, and the developed model can provide reference of feedback control for the optimisation of the process. Keywords: Flotation process of copper ore, nonnegative garrote, local search, soft sensor, multi-layer perceptron

Jan 1, 2020

By Xiang-nan Zhu, Hao Zhang, Lin Li, Jun Qiu, Yue-xian Yu, Chun-chen Nie, Xian-jun Lyua

Waste printed circuit boards (WPCBs) are excellent metal resources. Mineralogical characteristics of different components in WPCBs were analysed in this study. Organic-enriched particles, fibreglass-enriched particles, associated particles and metal-enriched particles were obtained by density gradient method. Subsequently, the elemental composition, morphology, dissociation characteristics, functional group composition and phase composition of different components were analysed by X-ray fluorescence spectrometer (XRF), scanning electron microscopy and energy dispersive spectrometer (SEM+EDS), infrared spectroscopy (FT-IR) and X-ray diffraction (XRD). Elemental analysis results show that Cu is mainly contained in metal-enriched particles. SEM+EDS analysis results demonstrate that ideal dissociation can be achieved when the WPCBs are broken to -1 mm. Organic matter particles are enriched with carbon and oxygen elements, while fibreglass particles and associated particles mainly contain Al and Si elements, verified by XRD analysis. FT-IR results show that hydrophilic and hydrophobic groups exist widely in all components, caused by widespread organic matter. This study reveals the important properties of different components in WPCBs, which is of great significance for the subsequent separation process. Key words: Waste printed circuit boards, mineralogical analysis, elemental composition, dissociation; phase analysis, functional group composition

Jan 1, 2020

By S. Lohmeier, D. Gallhofer, B. G. Lottermoser

In Southern Africa, historic mining and mineral processing of base metal deposits have almost exclusively focussed on the extraction of major metals, leading to the loss of remaining valuable raw materials into tailings dumps and waste rock piles. At the Namib Pb–Zn mine (Erongo Region, Namibia), historic base metal tailings deposits are present as unreclaimed exposed waste piles. The tailings comprise silt- (fraction A: d50 = 25 to 48 μm) to sand-sized (fraction B: d50 = 86 to 185 μm; fraction C: d50 = 210 to 230 μm) material and contain major concentrations of base metals (Pb av. 1.15 mass%, Zn av. 3.20 mass%), S (av. 9.95 mass%), as well as lower values of other metals (Cu av. 490 μg/g, Cd av. 133 μg/g, Ag av. 22 μg/g), and critical elements like Sb (av. 14.7 μg/g) and In (14.3 μg/g). Former mineral processing only targeted the extraction of galena and sphalerite. As a consequence, qualitative mineralogical composition of the tailings is similar to that of the primary ore. Ca–Fe–Mg(–Mn) carbonates, quartz, micas, chlorite, minor graphite, magnetite, and rare parisite relate to the former host rock and gangue matrix, whereas Fe-rich sphalerite, galena, magnetite, pyrite with minor pyrrhotite, rare arsenopyrite, marcasite, cassiterite, and accessory scheelite are original constituents of the primary ore. Reprocessing of such a material would be challenging, but a mixed Pb–Zn concentrate enriched in Cd and Ag might be obtained. In future, possible reprocessing of Namib tailings and associated disposal of wastes into an appropriately designed repository would not only generate valuable metal commodities, but such activities would also eliminate a major metal pollution source from the local environment.

Sep 9, 2024

By Marek Dworzanowski

Dense medium separation (DMS) is critical to the operation of coal and diamond beneficiation plants. It is also utilised in iron ore, manganese, chromite and andalusite beneficiation as well as pre-concentration for platinum-bearing UG2 ore. Gravity concentration plays an important role in the processing of diamonds, coal, gold, platinum, titanium minerals, zircon, chromite, iron ore and manganese. The DMS and Gravity Concentration operations and technology in South Africa conference will focus on the operation of DMS and Gravity Concentration circuits in the South African Mining Industry. The current status of the technologies and equipment employed will be presented as well as future developments. The conference was set up to showcase South African DMS and Gravity Concentration operations and provide a forum where operators, technology and equipment suppliers can engage in knowledge sharing. The papers cover a wide spectrum of topics, including descriptions of operations, optimisation projects, new capital projects, equipment applications, process monitoring and process selection. Most commodities and unit processes associated with DMS and Gravity Concentration are covered. The conference venue was selected to be the CSIR Convention Centre in Pretoria. The CSIR has contributed to DMS research in South Africa and it is located not far from many coal, diamond, gold, platinum and chrome mines that extensively utilise DMS and Gravity Concentration in their beneficiation plants. I believe that the papers and presentations submitted for this conference will provide a valuable future reference for DMS and Gravity Concentration, thus making the work of all the contributors to this conference highly rewarding and worthwhile.

Jan 1, 2006

By X. Xiang, W. Xia, J. Yin

"TiCl4 slurry containing valuable metals is an unavoidable by-product of the titanium ore chlorination process. The recovery of these valuable metals, which include titanium, niobium, tantalum, and aluminum, is an urgent issue to tackle in the titanium industry. The results of this investigation show that the valuable metallic elements can be recovered from the slurry by evaporation in a sealed container and leaching with dilute hydrochloric acid. After evaporation at 200°C for 60 minutes, nearly 99% of the titanium was recovered in the form of TiCl4, which was formed by the reaction of the TiO2 in the slurry with AlCl3. After evaporation, metals like niobium, aluminum, and tantalum remained in the residue. By leaching with 2.1 mol/L HCl at a L/S ratio of 6:1 mL/g at 80°C for 60 minutes, the soluble metals, such as aluminum, iron, and copper were all removed from the residue, and the niobium and tantalum were further enriched in the leach residue. A concentrate containing 53.40 wt% Nb and 5.57 wt% Ta was obtained by washing the leach residue with dilute aqueous ammonia under stirring. A potential waste water purifying agent containing 263.75 g/L AlCl3 was produced by purifying the leaching solution with Al(OH)3 and modified polyacrylamide. IntrodutionTitanium tetrachloride (TiCl4) is an important intermediate in titanium metallurgy that is widely used in the production of titania and titanium sponge (Akhtar, Xiong, and Pratsinis, 1991). In conventional titanium metallurgical processes, high-titanium materials such as synthetic rutile and high-titanium slag are reacted with chlorine to produce TiCl4 in a fluidized-bed furnace. Accompanying elements, such as Al, Nb, and Fe also react with chlorine to form chlorides, which are mixed with gaseous TiCl4 (Anderson, 1917). In the condensation process, gaseous TiCl4 is refrigerated and high-boiling-point chlorides are precipitated in the liquid TiCl4 to form a slurry containing 50~60 wt% TiCl4 (Wang, Xiang, and Wang, 2012).Various methods have been proposed to recover TiCl4 from the slurry, including microwave heating and spray drying (Wang, Xiang, and Wang, 2012, Wang et al., 2010a). To date, the only way to recover the TiCl4 is to return the slurry to the fluidized-bed furnace. However, this causes fluctuations in the temperature in the furnace, resulting in incomplete reaction between titanium-rich materials and chlorine. Therefore, the slurry is often rinsed with water and neutralized by adding lime, which caused serious environmental pollution and wastes a valuable resource (Roy, Bhatt, and Rajagopal, 2003)."

May 1, 2019