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By L. Rao, P. Carabin

"Advances in thermal plasma torches have resulted in this technology becoming a commercially viable solution for chemical and metallurgical processes. The main advantages of plasma are its ability to control process chemistry and to build small footprint reactors due to its high energy density and reactivity of the free radicals that are produced. This paper focuses on thermal plasmas produced by DC torches and their applications for waste treatment, production of high purity metals, and nanomaterials. Both transferred and non-transferred torches have been used as either a source of heat or as a reagent in various industrial processes. INTRODUCTIONPlasma technology has become an ideal solution for many industrial chemical, metallurgical and mechanical processes (Venkataramani, 2002). Thermal plasma powered systems are typical used for their unique characteristics such as high energy densities, high temperatures, small installation sizes, rapid startup and shutdown features, controlled process chemistry and use of electrical energy as a heating source resulting in decoupling the heat source from the oxygen flow rate (Heberlein et al., 2007). Depending on the nature of the main plasma forming gas used, thermal plasma systems offer a high temperature heating source coupled with a highly reactive plasma plume rich in free radicals and ions which promote otherwise hard to drive chemical reactions, as well as high heat transfer rates.Industrial plasmas can be broadly classified as thermal plasmas and non thermal plasmas. Thermal plasmas are atmospheric pressure plasmas characterized by local thermodynamic equilibrium (Boulos et al., 1994). Thermal plasmas are typically established between any two current conducting electrodes separated by an insulator. A plasma forming gas is blown between the two conducting electrodes resulting in a high temperature plasma plume. A plasma torch generates and maintains an electrically conducting gas column between the two electrodes; a cathode (negative electrode) and an anode (positive electrode) (Camacho, 1988). If both electrodes are housed in a single housing, resulting in an arc enclosed inside the plasma torch, then such plasma generating torches are termed as non-transferred (NT) plasma torches, whereas, if the second electrode is external to the torch, creating an arc transferred between the cathode and the working piece, then such plasma torches are termed as transferred (T) plasma torches. Depending on the source of the electricity which can be either direct current (DC), alternating current (AC) at main network frequency or at radio frequency (RF), the plasma torches are classified as DC, AC or RF plasma torches (Venkataramani, 2002)."

Jan 1, 2012

By Brian W. Mackenkzie, Jozef Lajzerowicz

This paper is intended to familiarize planners in the noncommunist world with the district planning approach used in eastern Europe for mining development. It deals generally with the basic nature of the district planning problem, the planning process for mining development and the state organization for the planning of mining districts. A number of applications of district planning techniques to both established and new eastern European mining districts are described.

Jan 1, 1971

"In response to mine head grades declining and orebodies becoming more complex, Glencore Technology has developed an alternative method for recovering economic minerals once leached into solution, rather than relying on conventional flowsheet options. The method involves the precipitation and separation of base metals from solution with limestone or lime. The final grade of these precipitate is not usually high enough to attract favourable terms of sale due to dilution from gypsum and sulphate salts. A set of operating conditions have been developed to allow the separation of the base metal precipitate from gypsum by exploiting the difference in particle size. A high-grade oxide product can be easily separated from the gypsum stream at very low cost. This process was originally developed by Glencore for zinc and copper systems. This paper reports on the successful application to nickel and cobalt, and this process has significant advantages over the incumbent precipitation process utilising magnesia.INTRODUCTION During evaluation of transitional and oxide zinc ore deposits during the 1990’s, Noranda Inc. (now Glencore) developed a sulphate based ore leach process to extract zinc into solution. For flowsheet development, conventional schemes dictated that once the zinc was dissolved in an acidified solution it was recovered by means of purification or solvent extraction followed by electrowinning and casting to produce zinc ingots. The deposits Noranda evaluated were high grade but had a relatively short mine life (10 years) and economic analysis showed that the projects couldn’t sustain the investment of a full zinc refinery. Compounding this problem was the lack of power supply infrastructure and the high power cost in the region. Noranda then evaluated alternative means of recovering zinc from solution. Laboratory testwork showed that a high-grade zinc precipitate (+50 wt% Zn) could be produced as an oxide, carbonate or sulphide by contacting acidified zinc sulphate solution with a number of reagents including soda ash, sodium hydroxide, and sodium hydrogen sulphide. Economic evaluation showed that the cost of the reagents are prohibitive, especially when the final product is still a metal intermediate (ZnO, ZnCO3 or ZnS). Noranda then continued to focus on fine zinc oxide precipitation for supply into the automotive tyre industry as this product would attract favourable terms of sale as a premium on Special High Grade (SHG) zinc."

Jan 1, 2017

By K. A. Clark

A meeting between representatives of the Scientific and Industrial Research Council of Alberta and the Deputy Minister of Mines for Canada was held at Edmonton in May, 1929, for the purpose of formulating a co-operative plan for carrying forward studies in aid of the development of commercial methods for utilizing the bituminous sands of Alberta. It was agreed that to the Alberta Research Council should be allocated the general problem of investigation of the processes for the separating of bitumen from the sands, including studies of methods of emulsifying, dehydrating and otherwise preparing separated bitumen for industrial applications. It was further agreed that during the present year the work of the Alberta Research Council should be to continue its laboratory investigations of points of design of its separation plant; to further perfect its separation procedure; to recondition its existing separation plant at Dunvegan Yards, Edmonton, in the light of laboratory studies and to operate it for the purpose of demonstrating its efficiency; to carry on tests in emulsifying and dehydrating or otherwise preparing separated bitumen for industrial application; and on the basis of the experience gained in the operation of the preliminary plant at Dunvegan Yards to prepare and design and, as far as possible, to proceed with the erection of, a semi-commercial separation plant at a site to be chosen, probably at the bituminous sand deposits near McMurray, Alberta. This paper presents, in the main, a progress report of the carrying out of this programme.

Jan 1, 1929

By Ann Lamontagne

Le parc à résidus de l?ancienne mine Dunraine contient des résidus générateurs de drainage minier acide. Le concept proposé pour la restauration du site est d?utiliser le fort potentiel alcalin des boues rouges, résidus d?aluminerie, afin de neutraliser les résidus miniers. En appliquant une certaine quantité de boues rouges à la surface du parc, on provoquera une neutralisation de l?acidité. De plus, les alcalis contenus dans les boues rouges vont provoquer la précipitation de minéraux stables (sulfates tel la jarosite). La précipitation de ces minéraux provoquera la formation d?une couche indurée qui rendra difficile la circulation de l?oxygène et de l?eau. Bien que ce concept ait été vérifié en laboratoire, ce sont là des hypothèses qui restent à vérifier dans des conditions réelles d?exposition. Les principales questions soulevées par l?utilisation des boues rouges, mis à part le contexte géochimique, est le contexte technico-économique. En effet, le transport de quantité importante d?un matériel argileux humide présente un défi économique important. Outre le défi économique, la manipulation et l?épandage de ce produit sur des parcs à résidus constituent également un défi important. Cet article présente les conclusions d?une étude technique sur le transport, la manutention et l?épandage de boues rouges sur un parc à résidus situés en Abitibi : le site de Dunraine.

Nov 1, 2002

By P. D. S. St. Pierre

IN REGENT YEARS, blast furnace operators have found it necessary to improve their technology in order to handle increasingly low-grade feed and yet satisfy the demands for greater tonnages of metal. Studies have been made covering several aspects of the problem, and in this connection the slags produced in the iron-making process have been critically examined with a view to discovering the slag with the optimum properties for a given operation. A good slag should combine, as far as possible, the properties listed in Table I. Unfortunately, some of these desirable properties are incompatible. For example, the advantage of the small ?bulk of a low-flux slag is offset by its low desulphurization potential and high viscosity. Similarly, a very fluid slag increases refractory wear. It will be seen, then, that a balance must he struck between these conflicting requirements. In the .present paper only the melting relationships of blast furnace slag ?compositions will be considered in detail. In interpreting the data herein presented, the optimum property requirements listed in Table 1 must strictly be borne in mind. It should also be noted that the discussion presented here always relates to calcined fluxes, since this facilitates reference to the final slag composition. Thus, in making calculations pertaining to the ?burdening of the furnace, due allowance should ?be made for the fact that the fluxes are added as carbonates.

Jan 1, 1956

By Xuanxue Mo, Kaihui Yang

"Abstract- The Laochang mine, located in the Sanjiang area of southwestern Yunnan Province of China, is a volcanogenic massive Pb-Zn-Cu sulfide deposit. It is hosted by a pyroclastic sequence of Barly Carboniferous age, namely the lower member of the Yiliu Group, which was intruded by syenite and rhyolite porphyry . The volcanic suite is basaltic or basaltic-andesitic in composition, has alkaline affinities, and is associated with the initial rifting along the margin of the Baoshan-Shanstate continental rnicroplate (Yang, 1989). The ores are typically Pb>Zn>Cu in composition, averaging 3.820Jo Pb, 3.51% Zn, from 0.01% to 1.85% Cu (0.107% av.), a high average content of Ag (113 g/t) and recoverable amounts of Au, Tl, Gd, Ga, Ge, In. A massive sulflde zone, in which lenticular and stratiform orebodies are localized in a sulflde-carbonate-silica shale unit or sulfldic tufflte horizon that usually overlies coarse-grained pyroclastic rocks, is underlain by a stringer sulflde zone developed in a subvolcanic intrusion or volcanic sequence. The sulfide mineral assemblages, from the top to the bottom of the deposit, are: realgar + orpiment - galena + sphalerite + pyrite- chalcopyrite + pyrite + pyrrhotite + arsenopyrite. Oxide and sulfate minerais occur rarely in the massive ores. The massive ores are generally fine-grained and banded, but coarse-grained ore, colloform and framboidal texture, and growth-zoned pyrite and sphalerite are common. Sedimentary features such as graded bedding, brecciated and deformed ore clasts, and chaotically emplaced blocks, are well preserved, indicating that the massive orebodies have undergone slumping and dis­ placement. Alteration is weak in the hanging-wall rocks, but strong in the stringer zone. Two dis­ tinctive alteration zones have been identified: the upper zone, characterized by an assemblage of quartz, carbonates, chlorite, albite, zeolite and sericite, and the lower zone containing diopside, trema­ lite, actinolite, gamet, clinozoisite, and epidote.The general features of the Laochang deposit are in accord with the descriptive mode! of VMS deposits (Lydon, 1984). However, it falls into neither the Zn-Cu group nor the Zn-Pb-Cu group chemically (Franklin et al., 1981). The depositional setting of the Laochang deposit is quite different from Cyprus or Besshi-type massive sulfide deposits. Laochang is hosted by alkaline lavas that were erupted in a submarine continental rift. Although some features of the Laochang deposit are similar to those of Kuroko-type deposits, there are remarkable differences in the alteration mineral assemblage, the proportion of ore-forming elements (lead enriched) and the amounts of oxides and sulfates. These suggest corresponding differences in ore fluid composition and the associated ore-forming environment. Thus, the authors suggest that the Laochang deposit may be a distinct type of VMS deposit."

Jan 1, 1993

By R. Edinger

Aerospace and space products depend, probably more than any other products in industry, on advanced materials. While there are many ways of producing aerospace parts, in many cases the process does not allow the design of the metallurgical properties according to the part or product requirements in accordance with its mechanical configuration. Key to the next level of innovative manufacturing is the capability to control the amount of energy applied to the process, as well as the addition of materials in form of vapor or solid particles such as powder in order to build up the metallurgical composition required. With the development of a high speed pulsed laser-electron beam source, the LASTRON(TM) technology, we deliver the basic requirement for a digital manufacturing process of aerospace and space products. This technology, combining Laser and electron beam, finds application in welding, drilling-machining, and is currently modified to allow digital coating (PEB-PVD) methods. In addition to the coating, a powder metallurgical process, called Rapid Manufacturing (RM), will allow the precision melting of parts based on CAD/CAM files. The RM process and the digital coating will allow the production of graded aerospace alloys in parts for jet engines and aero-structures.

Jan 1, 2006

By J. B. Mawdsley

From the view point of the mining engineer, the square-set method of stoping as practised at Butte, Montana, is one ?of the outstanding features of well conducted mining operations in that camp. The following information was obtained in the course of two months underground work in the Granite Mountain mine, during the summer of 1920, which is one of the properties of the North Butte Mining Company, situated on the well known Speculator vein. Most of the information was derived from personal observation and from discussions with various miners and with members of the staff. Geology The copper mining area of the Butte district is some two miles long by one and a half miles wide, a mineralized area in a great batholith of monzonite granite, locally known as the Boulder batholith. This extensive body of granite is traversed by several series of mineralized fault-fissures which differ in strike but generally dip steeply. Geologists agree that following the formation of the fissures, alkaline solutions ascended and decomposed the felspathic portions of the granite in the immediate vicinity of the fissure walls, and that these alkaline solutions were followed by cupiferous solutions which filled the fissures and replaced the granite next to the walls. A zone of oxidized ore, varying in thickness from 10 to 400 feet, overlies a sulphide zone containing chalcocite, enargite, bornite and chalcopyrite, with a small amount of quartz gangue. The veins are from 3 to 100 feet in width and contain, on the average, 3 per cent of copper, 2 ounces of silver, and 15 cents in gold per ton.

Jan 1, 1925

By Adam Moore, Ryan Gillespie, Jarrett Quinn, Audrey Walters, Peter Radziszewski

"Vale Long Harbour Processing Plant (LHPP) was designed to process Voisey’s Bay nickel concentrate into finished nickel and associated copper and cobalt products. The plant includes a secondary grinding circuit comprising two Stirred Media Detritors (SMDs) operating in parallel. The ultrafine grinding circuit was designed to process concentrate at a rate of 33 t/h and produce a ground product (P80) of 20 µm to feed the leach circuits. Start-up of the grinding circuit at LHPP was undertaken in December 2014.The objective of this paper will be to describe the design, commissioning, start-up and performance of the secondary grinding circuit with a focus on the two Metso SMD-355-C mills. Following a brief overview of Vale’s LHPP and the SMD technology, the paper will review the design of the SMD secondary grinding circuit from lab tests through to scale-up performance prediction. This will be followed by the results of circuit commissioning outlining some of the issues raised and addressed after which SMD performance will be outlined. Specifically, the SMD circuit grinding performance will be examined since start-up which will include the effect of media size and wear on grinding. Furthermore, impeller wear will be examined by determining initial “shear volume” and worn “shear volume” as well as its effect on mill power and the means to maintain it. The paper closes with a discussion on grinding performance."

Jan 1, 2016

By Kevin C. Milne

"The solution of problems associated with development of a sour gas reserve will be of increasing importance in tl1e next few years if gas export is approved •by the National Energy Board. The purpose of this paper is to review briefly the history of the Carstairs gas field, and tCI describe in a general manner the reservoir, and the producing and processing facilities.HISTORYThe Carstairs gas field was discovered in April 1958 when the discovery well, Home Carstairs 10-17, was successfully completed as a gas well in the Elkton member of the Turner Valley formation. Geo-graphic location of the field is shown in Figure No. 1. Note that the field is about five miles west of the town of Carstairs, Alberta, which in turn is about 40 miles north of Calgary. Drilling subsequent to the discovery well resulted in three addition-al producing wells and one dry hole during I.958; two producing wells during 1959; and one producing well and one dry hole during 1960. Thus, seven producing wells and two dry holes have been drilled in the Carstairs field to date.In November 1959 a 12-section block in the Carstairs field was unitized on a surface acre basis. Mean-while, in June 1959, operators in the field executed an ""Interim Plant Agreement"" that provided the money needed to start construction of a joint venture processing plant and gathering system. Construction of the plant and gathering system was completed in February 1960."

Jan 1, 1960

By Marcondes Lima Costa

Abstract-The Amazon region is characterized by the development of deep chemical weathering represented by widespread lateritic covers and soils. Two distinct periods of laterite formation can be distinguished: mature laterites from the Eocene-Oligocene (and locally from the end of the Cretaceous), and immature laterites from the Pleistocene. The older laterites occur on plateau landscapes, and the younger ones on widespread hilly to flat lowlands. Both types show complete or truncated profiles, generally covered by deep yellow to brown topsoils. The mature laterite profiles contain high concentrations of gibbsite and/or aluminum phosphate, whereas the immature ones are poor in these minerals. The Amazon region is rich in mineral deposits related to lateritic profiles. Some mineral deposits are of primary origin but were concentrated to economic grades by lateritic processes. The most important ore deposits are of iron, aluminum (bauxite), kaolin, manganese, gold, nickel, copper and phosphate. These are mainly related to mature profiles. The wide spectrum of ore deposits and mineralogical and geochemical complexity of the Amazon laterites has been promoted by: (1) the prevalence of ideal conditions for laterite formation throughout much of the Tertiary; (2) the presence of varied basement lithologies due to contrasting geological environments; and (3) a variety of epigenetic alteration types. The lateritic profiles show a well-developed ore zonation which is related to specific lateritic horizons. Iron and gold deposits occur in the ferruginous horizon, which is nearest the surface; the central aluminous horizon hosts bauxites, aluminum phosphate, strontium and gold; and the lower clayey horizon contains deposits of manganese, nickel, copper and kaolin. Resistate phases which residually accumulate throughout entire profiles include titanium (as ilmenite and anatase), chromium (as chromite), tin (as cassiterite), yttrium (as xenotime), and niobium (mainly as ilmenorutile). Epigenetic alteration, caused by swamp environments developed above truncated lateritic profiles, has led to the formation of high-grade kaolin and refractory bauxites. The laterites in the Amazon region contain most of all known kinds of ore mineralization related to laterite processes.

Jan 1, 1997

By Marcondes Lima Costa

The Amazon region is characterized by the development of deep chemical weathering represented by widespread lateritic covers and soils. Two distinct periods of laterite formation can be distinguished: mature laterites from the Eocene-Oligocene (and locally from the end of the Cretaceous), and immature laterites from the Pleistocene. The older laterites occur on plateau landscapes,and the younger ones on widespread hilly to ?at lowlands. Both types show complete or truncated pro?les, generally covered by deep yellow to brown topsoils. The mature laterite pro?les contain high concentrations of gibbsite and/or aluminum phosphate, whereas the immature ones are poor in these minerals. The Amazon region is rich in mineral deposits related to lateritic pro?les. Some mineral deposits are of primary origin but were concentrated to economic grades by lateritic processes. The most important ore deposits are of iron, aluminum (bauxite), kaolin, manganese, gold, nickel, copper and phosphate. These are mainly related to mature pro?les. The wide spectrum of ore deposits and mineralogical and geochemical complexity of the Amazon laterites has been promoted by: (1) the prevalence of ideal conditions for laterite formation throughout much of the Tertiary; (2) the presence of varied basement lithologies due to contrasting geological environments; and (3) a variety of epi-genetic alteration types. The lateritic pro?les show a well-developed ore zonation which is related to speci?c lateritic horizons. Iron and gold deposits occur in the ferruginous horizon, which is nearest the surface; the central aluminous horizon hosts bauxites, aluminum phosphate, strontium and gold;and the lower clayey horizon contains deposits of manganese, nickel, copper and kaolin. Resistate phases which residually accumulate throughout entire pro?les include titanium (as ilmenite andanatase), chromium (as chromite), tin (as cassiterite), yttrium (as xenotime), and niobium (mainly asilmenorutile). Epigenetic alteration, caused by swamp environments developed above truncated lateritic pro?les, has led to the formation of high-grade kaolin and refractory bauxites. The laterites inthe Amazon region contain most of all known kinds of ore mineralization related to laterite processes.

Jan 1, 1997

By H. Tsuruta, A. Fujibayashi, I. Sumi, A. Murao, R. Murai

Injection of biomass into blast furnace as alternative reducing agent is so effective for the purpose of mitigation of carbon dioxide emissions from steel industries, because biomass is considered to be carbon neutral raw materials. Certain amount of Palm Kernel Shell (PKS) is abandoned after Palm oil extraction process. To use as a reducing agent of blast furnace, PKS was carbonized and classified by 100 mesh sieve. To examine the gasification behavior of PKS carbide under the blast furnace conditions, several combustion experiments were conducted using hot model experimental furnace. The experimental results showed that the gasification efficiency of PKS carbide increased as the quantity of volatile matter increased. This tendency is the almost the same for the pulverized coal, so carbide of PKS can be used at blast furnace at appropriate amount of volatile matter that can be controlled by carbonization condition. In addition, the pressure drop of the furnace tends to decrease because the amount of ash in PKS carbide may be smaller than that of pulverized coal. PKS carbide is a suitable reducing agent in that respect.

Jan 1, 2015

By A. P. Yovanovic, P. Bonadia, M. N. Moraes, C. F. Matos

"The magnesite flotation operation of Magnesita Refractories, in Brumado – Brazil, has four parallel ball mills working in closed circuit with hydrocyclones to grind the ore for the reverse flotation of silicates in mechanical cells. The modification proposed here opens the circuit for three of the ball mills so that their products are collected together to feed a high frequency screen. The oversize of the screen feeds the fourth ball mill in closed circuit for secondary comminution. The product reports to dewatering and flotation. The undersize undergoes desliming and subsequent flotation operation. According to pilot tests performed, the modification on the magnesite flotation operation will promote a 20% increase in the productivity, 8.5% increase in mass recovery and a 26% reduction in water consumption. The gains are due to the fact that the silicates in the feed are concentrated in the smaller particles (<100µm) with over grinding in the existing closed comminution circuit, making it impossible to take advantage of this natural selectivity. The combination of open circuit, more selective milling, and the high frequency screen, ensures high efficiency particle size classification. This renders the process more effective, both to the screen undersize with its high contents of silicates and fines, and to the screen oversize, which is almost without fines and has a higher magnesite grade. This situation allows for the setting of specific parameters for the flotation of both the primary milling undersize and the secondary milling product.INTRODUCTIONMagnesita Refractories, with its operations site in Brumado, is the largest producer of high purity dead burned magnesia (DBM) in Latin America. The magnesite ore is extracted from an open pit mine, named Pomba, after which it is crushed and handpicked. Due to the presence of disseminated silicate the ore has to be ground and concentrated by means of reverse flotation, before feeding the high temperature kilns for sintering and conversion to DBM.The magnesite flotation unit has an impact crusher to reduce the size of the feeding ore, which is transported to the mills by conveyor belts. The milling operation is composed of four ball mills in closed circuit with hydrocyclones. The closed circuit generates a high circulating load with excess fines, which is detrimental to the selectivity of the desliming and flotation operations, reducing both mass andmetallurgical recovery.In the current scenario, the capacity of the flotation plant is insufficient to meet the demand of the DBM kilns, forcing the operation to work with high purity ores in order to attain the highest possible mass recovery in the concentration process. This is not an ideal situation as it requires the mining site to work with higher stripping ratios.The objective of this work was to improve the magnesite flotation unity to increase its productivity. After a detailed analysis, the milling was identified as the limiting process, which made the authors to focus on this operation."

Jan 1, 2016

By Robert B. Parsons

"A joint federal/provincial/industry subcommittee of the Intergovernmental Working Group on the Mineral Industry (IOWG) has published an informative and readable report on taxation matters concerning Canada&apos;s mining industry. The report, which was presented to the federal and provincial mines ministers in September 1986, identifies and discusses key tax issues relating to this industry. The report is mandatory reading for anybody with an interest in mineral exploration or production in Canada.IntroductionIn 1986, Canada&apos;s federal and provincial mines ministers were presented with an important report concerning the taxation of this country&apos;s mining industry. This document is important for a number of reasons, two of the reasons being: first, the report contains an objective analysis of the key mineral taxation issues of the day; and, second, the report is the product of a cooperative exercise involving representatives of various facets of the industry and government. The report should be regarded as compulsory reading for anybody who has an interest in fiscal matters affecting mineral exploration and production.The ""Report on Fiscal Proposals"" was prepared by a subcommittee of the Intergovernmental Working Group on the Mineral Industry (IOWO). IOWO is a group of senior federal, provincial, and territorial government officials concerned with the analysis of mineral policy issues in Canada."

Jan 1, 1986

By B. McHenry, A. E. Wraith, P. J. Mackey

The Wallaroo smelter on the Yorke Peninsula, South Australia commenced smelting operations in 1861 treating ores from the nearby Moonta and Kadina mines. The plant expanded and modernized on several occasions and was a leader in the successful introduction of new technology to improve operations. It operated continuously until 1923 when local mines became exhausted; in the closing stages of the 19th century it was the largest copper smelter in the world outside of those in Swansea, Wales. In 1892 a small electrolytic refinery was established at Wallaroo, the first in Australia, based on principles developed by Elkington at Pembrey, Wales in 1869. The Wallaroo refinery was specifically built to recover gold and silver from copper produced by smelting gold-containing feed materials shipped from Western Australia. This first venture into electrolytic refining was replaced in 1903 by a somewhat larger refinery which, although modest in size for its time, with a capacity of about 1000 tonnes of cathode copper per year, was very productive in precious metals. Anode copper was produced by an updated version of the reverberatory-based Welsh process until 1910 when barrel-type pneumatic converters were introduced based on American practice; subsequently, anodes were cast by tapping the precious-metals rich "bottoms" portion of converter copper as produced at about one-fifth into the copper blow. The present paper describes the Wallaroo refinery, its anode supply and products, supported by initial observations on a sample of a Wallaroo cathode held in the collection of the South Australia Museum, Adelaide SA, Australia. INTRODUCTION Australia ranked 6th in the world for copper mine production in 2018, with an output of 918,000 tonnes of mined copper, after Chile, Peru, Congo, China and the USA; about 40% of Australian mined copper was smelted in the country. Interestingly, the world ranking of Australia in mined copper has, with a few variations, remained about the same for more than 100 years – of interest, it was also the 6th largest country for copper production at 21,089 tonnes in 1899. At that time, all or most of the copper was smelted in the country (Mackey, 2016). Copper was first discovered in Australia in 1842 in South Australia not far from Adelaide; additional copper discoveries in the region soon followed. At first, copper ore was shipped to Swansea, Wales for smelting (Bampton, 2003). However, in addition to the long, 150 day one-way sea passage, it seems Welsh smelters preferred higher grade of ores – these aspects and likely a mood in the new colony to be independent of Swansea (Evans, 2014) evidently encouraged local smelting at the mine sites using small, Welsh-type reverberatory furnaces fired with hardwood as fuel and operated by Welsh and Cornish migrants. The first large copper smelter in Australia commenced in 1848 at Bremer, near Callington some 60 km east of Adelaide. With larger discoveries on Yorke Peninsula, the Wallaroo copper smelter at Wallaroo Bay on the west coast of the peninsula commenced operations in 1861 (Bell & McCarthy, 2008). Thus began one of the most successful, and in its day, one of the most advanced and innovative plants in Australia if not the world. In the late 1860s, it was considered one of the largest copper smelters in the world (Bell & McCarthy, 2008)

Jan 1, 2019

By Ron Zevenhoven

In Finland one opportunity for large-scale CO2 capture, utilisation and storage (CCUS) is CO2 mineralisation, i.e. mineral carbonation. A process route under development towards industrial application involves production of magnesium hydroxide or sulphate from serpentinite rock (serpentine = 3MgO·2SiO2·2H2O), followed by conversion either in a pressurised fluidised bed (PFB) reactor, giving magnesium carbonate, or in an aqueous solution process giving magnesium hydro-magnesites. Iron present in the rock is typically obtained FeO(OH). Results obtained with these process routes and progress towards industrial demonstration is addressed, process heat integration and operation on flue gases (without CO2 pre-separation!) being key features for economic viability. A process route utilizing calcium-containing slag by-product from iron- and steelmaking under development towards large-scale application is the so-called slag2pcc concept. It converts an industrial by-product into valuable material, reduces use of natural material and streams to landfills while binding CO2 produced by the process generating the slag. Using ammonium salts, calcium is extracted from steel converter (BOF) slags and subsequently carbonated in a two-stage aqueous process (at ambient temperatures and pressures). Precipitated calcium carbonate (PCC) is produced while regenerating the ammonium salt. Process performance and scale-up while guaranteeing a certain PCC quality are presented.

Jan 1, 2015

By J. S. Fox

"Besshi-type Cu-Zn (-Ag-A u ± Co) deposits are tabular, stratiform volcanogenic sulphide bodies which are usually associated with mafic volcanic rocks of oceanic or intra-plate geochemistry, but which can also be found locally with ultramafic volcanics or subvolcanic mafic intrusions. A thick sequence of continentally-derived clastic sediment usually encloses both the mafic volcanics and the ore. Besshi-type deposits form subaqueously, in epicratonic rifting environments, more-or-less proximally, and as a result of hydrothermal convection in their subjacent mafic volcanic - clastic sedimentary piles. They belong to a rift -related metallogenic spectrum that includes sediment-hosted and Cyprus-type base metal deposits, and may diller genetically from these mainly with respect to rate and degree of crustal extension. Modern analogues to these deposits are f ound in the submarine volcanogenic sinters of the Gulf of California rift system.The associated lithologies and tectonic selling of Besshi-type deposits clearly distinguish them from Kuroko-type ores. This difference also seems to be reflected in their lead isotopic character. For example, leads from Besshi-type deposits in the Sanbagawa belt of Japan and from the Blue Ridge belt of southeastern U.S.A. lie on extended anomalous lead lines and have lowslopes in 207Pb/204 Pb - 206Pb/ 204 Pbspace (Sato and Sasaki, 1980; Leriuray, 1982), wheras those from most Kurokotype mining districts exhibit only narrow isotopic ranges and lie near or on the orogene growth curve (e.g. , Franklin et a I., 1981). More over, where Besshi- and Kuroko-type deposits are found in the same orogene, the former often occur earlier in the tectonic cycle than the tatter (e.g., Japan, the Norwegian Caledonides, the southern Appalachians and south-central Finland).Besshi-type deposits are not confined to any particular part of the world, or to any geological epoch. Moreover, in many mineralized belts, Besshi-type deposits are the predominant volcanogenic ore type. On a world-wide scale, deposits of this type therefore constitute an important base metal resource."

Jan 1, 1984

By K. D. Watson

"THE Mindamar zinc-lead-copper mine, owned by Mindamar Metals Corporation Limited, is at Stirling in Richmond County, near the south-eastern shore of Cape Breton Island, Nova Scotia (Figure I). It is connected by several roads with the Canadian National railway at Sydney and St. Peters.The deposit is said to have been discovered around 1895 as an outcrop in the bed of Copper brook, but the details are obscure. Not until 1925, when it was optioned by American Cyanamid Company, was it developed underground. Between 1927 and 1938, the 1-nine was operated intermittently by The British Metal Corporation (Canada) Limited, and yielded approximately 200,000 tons of ore averaging about IO per cent zinc, 2 per cent lead, I per cent copper, and small quantities of silver and gold. In December 1950, Dome Exploration (Canada) Limited made an agreement with Mindamar Metaî Corporation Limited, which was exploring the old mine, to assume management and prepare the property for production. Production started in April 1952 with a new mill and a new four-compartment shaft, and between that time and the end of 1954 it has totalled 545,347 tons of ore averaging 5·89 per cent zinc, 1·35 per cent lead, 0·66 per cent copper, 0·032 oz. gold, and 2 151 oz. silver.The Mindamar orebodies are irregular lenses and large veins lying within a wide, almost vertical shear zone of remarkable persistency. The shear zone consists mainly of well-foliated sericite schist derived from siliceous siltstone, and it contains a vast amount of dolomite and magne-site of hydrothermal origin. Most of the ore is extremely fine-grained and some of the high-grade material has a conspicuous thinly layered structure. The metallic minerals, in order of decreasing abundance, are pyrite, sphalerite, chalcopyrite, galena, and tennantite; the gangue minerals, in the same order, are dolomite and magnesite, quartz, sericite, talc, chlorite, barite, albite, and alunite.The geological setting of the deposit is shown in Figure 2. Except along streams and lake shores, almost all of the bedrock is concealed by glacial drift. The group of rocks in which the deposit occurs consists principally of greywacke, siltstone, tuff, brecoia, and Javas, and has been correlated lithologically with the Bourinot group of Middle Cambrian age. A short distance west of the mine, these rocks are in contact along the Stirling fault with conglomerate, arkosic sandstone, and quartzite belonging to the Middle River group of Silurian or Devonian (?) age, which elsewhere in the area overlies the Bourinot group unconformably. The large bodies of granitic rocks in the region, and the large lenticular masses of diorite and quartz diorite associated with them, have been assigned by Weeks (5, pp. 68-69) to the Devonian."

Jan 1, 1949