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By J Janus, J Krawczyk

Local accumulation of methane in workings of a longwall is one of the most common causes of mining accidents. This gas has many sources: it may leak from goaf through permeable sealings, or through gaps between roof support sections. This stream is then mixed with ventilation air. In the case of auxiliary ventilation ducts, or free jet fans, we have to consider the propagation of a clean air stream in areas with an air-methane mixture. Therefore, modelling the mixing process of methane with ventilation air is important for determining the hazardous areas and thus to ensure safety. Computational fluid dynamics (CFD), specifically the finite volume method, provides tools for such modelling. However, this method requires validation. For this purpose, we have compared measurements with simulations for selected test cases having sufficient similarity to the present problems. In typical methane explosion hazard areas, such as a longwall, it is difficult to make measurements sufficiently to confirm credibility of 3D CFD simulations. As a relevant alternative, an injector methane drainage station placed in an underground gallery has been selected. The stream of drained goaf methane is entrained by compressed air powered injectors and then mixed with ventilation air. Research in this area does not interfere with mining operations, it can be performed safely in a repeatable way. Flow within the site has many similarities to conditions in mine drifts of the longwall area. Comparative research of measuring the methane concentration distribution in the mine drift downstream injector station, with simulations of propagation of the methane stream, was carried out. For measuring the methane concentration distribution in the mine drift a multipoint measurement velocity system developed at the Strata Mechanics Research Institute was used. For the simulation a finite volume method for turbulent flow of gas mixtures was applied. Preliminary results of comparison are shown as graphs and tables.CITATION:Janus, J and Krawczyk, J, 2013. An analysis of the mixing of air and methane in the stream produced by the mine injector station - Presenting preliminary results of measurements and modelling, in Proceedings The Australian Mine Ventilation Conference , pp 49-56 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 1, 2013

By S Nkwanyana, I Govender

Batch experiments in a 0.6 m diameter mill have shown that improvements of about 13 per cent in the efficiency of energy utilisation can be realised in ball mills by replacing 25 per cent of the ball charge by an equivalent volume of cost-free critical size pebbles from AG/SAG mills. For a mill of a given size, speed and charge filling, the rate of size reduction of ore particles depends on (i) the frequency of grinding media collisions (ii) the probability of capture of ore particles between the colliding grinding media (iii) the probability of fracture of the captured particles. The probability of fracture depends on the magnitude of collision energy. The distribution of collision energy into shear and impact events determines the relative strengths of attrition breakage and impact breakage. The efficiency of energy utilisation depends on which of the two mechanisms of breakage is more desirable in a particular milling stage. In this paper collision data from a series of DEM simulations of a mill charged with steel media and a mixture of steel media and pebbles is presented in energy spectra and spatial distribution maps. The data provides the necessary detail to elucidate the improvements in the efficiency of energy utilisation in ball mills when using a mixture of pebbles and steel media.

Aug 24, 2022

By R L. Chaney, M Mahoney

Mine and ore beneficiation wastes and smelter contaminated soils often cause phytotoxicity and threaten adverse environmental effects if not remediated. Science has clarified both the risks from soil metals and methods to alleviate those risks that can be applied at low cost. Phytoremediation is a family of plant and agronomy based technologies to deal with environmental aspects of sites requiring remediation. If valid risk assessment indicates that metals comprise risk, phytostabilisation may be used to alleviate that risk for most contaminated sites. In particular, Zn-Pb, Cu and Ni mine and smelter sites are readily remediated by making the soil calcareous and fertile, with added organic and metal sorbent amendments that include soil microbes to ‘revitalise’ the soil. In each case, the soil fertility and causes of phytotoxicity should be clarified by agricultural soil extractions, and the combination of amendments required to improve fertility and reverse phytotoxicity identified and found locally. In contrast with phytostabilisation, phytoextraction/phytomining uses rare metal hyperaccumulator plants and agronomic management to maximise annual phytoextraction of soil elements into plant shoots for harvest, ashing and use as a metal ore. Plants that accumulate more than two per cent Ni in shoots, and yield 10–20 t ha-1 dry biomass yield 200–400 kg Ni ha-1, which has value greater than all common agricultural crops. Considering the value of elements, existence of hyperaccumulator plants and demonstrated agronomic management for Ni phytomining, it is clear that mine sites and Ni mineralised subore-grade serpentine soils can be phytomined economically as an agricultural mining technology. A team developed agronomic methods and improved cultivars of Alyssum, which can be profitably grown on temperate zone Ni mineralised or contaminated soils. Plant species for tropical ultramafic soil materials have been identified. Phytoextraction is also strongly needed to remove Cd from rice soils to prevent human disease from soil Cd.CITATION:Chaney, R?L?and?Mahoney, M, 2014. Phytostabilisation and phytomining – principles and successes, in Proceedings Life-of-Mine 2014 , pp 3–16 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 16, 2014

By J Hadjigeorgiou

Narrow vein mining, as most types of mining, faces important geotechnical challenges. The specificity of geotechnical challenges in narrow vein mines stems from the nature of the deposits, which are often inclined, discordant and found within fractured rock or faults or in shear zones within country rock. This complicates the construction of representative geomechanical models and limits the applicability of several engineering design tools. Furthermore, in certain cases, the severity of encountered geotechnical problems is considerably greater in narrow vein than in wider orebodies. This paper provides an overview of geotechnical and other challenges in narrow vein mines with a focus on how these are currently addressed. Of particular concern is the use of manual labour working close to the mining face where there is greater exposure to geomechanical hazards. This review concludes with a particular emphasis on understanding the limitations of commonly used engineering tools and techniques to address geotechnical problems in narrow vein mines.CITATION:Hadjigeorgiou, J, 2012. Geotechnical challenges in narrow vein mining, in Proceedings Narrow Vein Mining 2012 , pp 15-22 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 26, 2012

By A Sturgess, P McKenna, P D. Erskine, D Doley, V C. Glenn

For more than four decades, rehabilitated lands in the Bowen Basin have been planted with buffel grass (Cenchrus Ciliaris), which is often used to provide rapid, stabilising and erosion reducing cover to reshaped landforms (Erskine and Fletcher, 2013; Harwood, Hacker and Mott, 1999; Grigg, Shelton and Mullen, 2000; Naidu et al, 1997). Historically introduced to Central Queensland and encouraged by pastoralists in the early 1900s (Humphreys, 1967), the species has been extensively used by mine managers in seeding mixes (Coaldrake and Russell, 1970; Edye, 1975), and the invasive nature of the grass has led to the monodominance in rehabilitated areas of semi-arid Central Queensland. With 40 open cut coalmines in Central Queensland (Department of Natural Resources and Mines, 2015), a considerable amount of land is either disturbed mine footprint (156 200 ha) or rehabilitated (29 200 ha) (Dale, 2015), and the bulk of rehabilitation consists of relatively young (<30-year-old) developing ecosystems, with demonstrated biomass fuel loads up to 20 t/ha (Grigg, Shelton and Mullen, 2000).Uncontrolled fire poses a significant risk to rehabilitated landforms that are located in close proximity to mining infrastructure, neighbouring communities, open pits with exposed flammable coal seams and flammable stockpiled coal resource. Mine lease holders in Queensland have the added responsibility of managing and protecting any endangered regional ecosystem communities, and flora and fauna listed federally under the Environment Protection Biodiversity and Conservation Act 1999 or the State Vegetation Management Act 1999; as well as, any culturally significant sites such as scar trees or middens that are found on-site. Additionally, uncontrolled fire in rehabilitated landscapes poses a significant risk to mine site closure goals, with the potential to create altered states and stalled ecological trajectories (Grant, 2006). CITATION:McKenna, P, Glenn, V, Erskine, P D, Doley, D and Sturgess, A, 2016. Fire behaviour in buffel grass dominated mine site rehabilitation in Central Queensland, Australia, in Proceedings Life-of-Mine 2016 Conference , pp 158–162 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 28, 2016

By Riley S. J

The basic aim of mine planning is to design mine layouts and schedules that achieve optimisation of operations, minimum cost and maximum resource recovery. Successful accomplishment of this aim is facilitated by timely and comprehensive rehabilitation planning commencing at the pre-feasibility stage and continuing until the end of mining. Incorporation of a final landfomt design for waste rock dumps in a mine plan requires a prediction of surface stability, which may be achieved through erosion modelling. Erosion prediction models can be placed in two broad categories: soil loss prediction models eg USLE and CREAMS, and geomorphic models such as SIBERIA. A waste rock dump landform design based on selected slope form and grade and drainage systems should be developed as part of planning. A digital terrain model (DTM) of the landfonn should then be produced which can be modelled for long-term erosional stability using pre-determined parameter values. If acceptable standards of stability are not achieved, the landform should be redesigned and remodelled until the desired result is obtained. The planning process incorporating models requires knowledge of spoil or waste rock properties and model parameter values. This information is site specific and can be obtained from drill cores or costeans at the pre-mining stage and from spoil or waste rock during the mining stage. Realistic model parameter values are critical in post-mining landfonn design and can be obtained by several methods, including rainfall simulation, monitoring, geochemical analyses and grain size analysis.

Jan 1, 1994

By F D. I Hodgson

Twenty-seven observation test pits were excavated at four different spoils dumps at three collieries in the Witbank Coalfield. The holes were dug into the upper three metres of the spoils to ascertain if any weathering profiles, variation with age or influence of topsoil covering could be gauged. Samples from these holes were also subjected to laboratory testing (ABA, humidity cells and mineralogy on several selected samples). The test pits showed that there was a good correlation between in situ paste pH-values and ABA results for samples taken from the pits. At all the collieries, no correlation between age of spoils and in situ acidity could conclusively be drawn. The depth of soil cover also appears to be a minor consideration in determining the eventual acidity of the spoil. In the pits where acidity was found, the weathering was evident when contrasted to areas still buffered. It is unclear if the weathering leads to the acidity or vice versa, as the soil covering appeared to be similar. The spoils proved to be extremely variable with regard to particle size and material on a micro and macro scale. Evidence from most of the holes suggested that there was enough water contained in the fine material in the spoils to support the initiation of acid generation. Conclusions from this investigation are that the mineralogy of the spoils is the most important factor in determining the eventual occurrence of acidic hotspots, and that prior characterisation and selective handling will provide the best management practice for these spoils.

Jan 1, 2003

By P Holtham, J Meng, E Tabosa, W Xie

Turbulence and its distribution are of great importance in flotation, and have received considerable attention recently. However, there is no mature technique to measure turbulence in three-phase (liquid-solid-gas) industrial flotation cells due to the opaque, highly aggressive and abrasive nature of the slurry involved. Previous research has shown that the piezoelectric vibration sensor (PVS) is a promising tool for turbulence measurement in industrial flotation cells. The PVS is a robust device that converts mechanical vibration to electrical signal, from which turbulence information can be extracted. An improved calibration method has allowed development of a frequency model to calculate the force applied to the sensor. Experimental results and comparison with laser doppler anemometry (LDA) have shown that the PVS can measure fluid kinetic energy, which is related to turbulent kinetic energy, a parameter used in the literature to represent turbulence in flotation. Laboratory measurement in a two-phase (water and air) 60 L cell and with slurry in a 3.5 L cell gave good stable results and mostly consistent trends between the measured turbulence profile and cell operation. When applied in a 300 m3 industrial cell filled with water, the addition of air or slurry to the cell resulted in a shift in the turbulence profile. This is expected because a change in fluid density will change the force applied to the sensor. It is therefore concluded that the piezoelectric sensor is an easy-to-use and robust technique that is fully capable of measuring turbulence in industrial flotation environments.CITATION:Meng, J, Tabosa, E, Xie, W, Runge, K C and Holtham, P, 2014. Development and application of a piezoelectric sensor for turbulence measurement in industrial flotation cells, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 457–470 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By M F. L Gibson

The issue of flyrock is very important in the operation of all mineral extraction sites that use blasting. Unlike the other environmental effects of blasting, ground vibrations and air overpressure, flyrock is (or should be) a rare event, with severe consequences which may include damage to property, injury or fatalities. These physical consequences are often matched by a loss in public confidence in the management of the operation, mistrust and bad press. In this work a deterministic analysis of flyrock was carried out using the equations of a particle in motion with drag. The solutions to these equations were used to reproduce the curves of Lundborg et al (1975) for the relationship between flyrock boulder size and maximum ejection distance. A probabilistic approach based on Monte Carlo simulation was built up with the analytical model using published data together with local case study material. A typical quarry blast situation was modelled and estimates of safe standoff distances were determined using risk assessment techniques.

Jan 1, 2001

By Kasai H, Hibi T, Matsuishi S

Coal oil mixture (COM), a liquid fuel pro- duced by mixing together coal and heavy oil on the 50-50 basis, has been brought to a level of practical use in Japan, being actually employed by a oil fired system at Yokosuka Thermal Power Station of The Tokyo Electric Power Co., Inc. A COM Production Plant, built in Onahama which is located about 160 miles from Yokosuka, required COM to be transported by sea. Mitsubishi Heavy Industries, Ltd. therefore performed a series of studies to develop a spe- cialized COM carrier, the world's first of its kind. Long lasting high stability is of pri- mary importance to successful use of COM. Much have been done in the way of research on stability of COM in the static storage, and the mechanism of COM static: stability is almost completety known. On the other hand, the knowledge about the COM dynamic stability, such as the stability while being transported aboard the COM carrier at sea, is still limited at the moment. The motion of COM aboard the COM carrier and how COM would settle were studied by tests. A visualization test on the COM behavior under dynamic motion was also performed and the mechanism of COM dynamic stability was analysed. The tests showed that the ship rolling motion had @n effect of promoting the settling of coal content of COM in the cargo hold. And studies were also made to device a method for esti- mating the settling quantity of coal during sea Transportation.

Jan 1, 1987

By M Edgar, G Pattemore, M Auad, K Job, A Job, S Gale

In recent decades, significant advances have improved the modelling techniques for predicting slope failure. Predicting failures is vital in open pit mining due to the significant risk posed to personnel and equipment from unstable pit walls. Failures not only cause harm and damage to people and equipment but also cause delays to production and subsequently increase operational costs. Coupled with improvements in modelling techniques, utilisation of advanced scanning systems, such as high-definition imagery from UAVs has enabled faster and more precise mapping and modelling. However, one key element required for accurate slope stability modelling and monitoring is the ability for mine geotechnical engineers to have an accurate understanding of the mineralogy and moisture content of slopes, in real-time. To address this challenge, research has been undertaken to utilise hyperspectral imaging across a broad spectrum, combined with high-definition imagery, and LiDAR to scan slopes for minerals and moisture content. In addition to accurately mapping mineralogy and moisture, the data must be collected autonomously and remotely to ensure ongoing safety. The results show that there are many direct and indirect benefits from this new technology, including the ability to monitor slopes at a safe distance and in real-time, improved accuracy of modelling, detection of risks, and improving the automation workflow for geotechnical engineers. The paper presents recommendations for the implementation of the technology in open cut mining environments.

Jun 22, 2022

By D Adhikary, M Khanal, B Poulsen, H Guo

During longwall mining, the ability to reliably estimate the height of longwall mining-induced fractures is critically important in order to effectively manage mining-induced water inflows and aquifer interference. The extent of mining-induced subsurface deformation, fracture, surface subsidence and aquifer interference is largely controlled by local lithological conditions, mining methods and mine layouts. Therefore for the purpose of quantifying mining impacts it is imperative to incorporate the local geology and mine plan parameters in a mine scale model. Two different numerical models based on 3D continuum (Finite Element Method) and 2D discrete (Discrete element method) domains, respectively, are developed to incorporate the mine site parameters of a study site in Australia. Both the models are calibrated and validated with measured mine data. The continuum numerical modelling method is used to investigate the change in permeability of the overburden strata due to underground extraction considering the full 3D nature of geology and mine layout. The discrete element modelling method is used to simulate the initiation and propagation of fractures, allowing the caving of overburden strata to be represented in a realistic manner, and the permeability enhancement of the strata overlying the goaf to be calculated from first principles. Permeability enhancement in the discrete element model is a direct function of the fractures induced in the deformation/caving process; fracture location, extent, aperture and connectedness. From the numerical modelling under the simulated condition for the mine studied here, it is predicted that the permeability of the caving zone from the goaf to five times the mining height increases by almost six orders of magnitude. In the fracture zone to approximately ten times the mining height, the change in permeability is predicted to be around two to three orders of magnitude. At the height of more than ten times the mining height the magnitude of permeability increased is predicted to be one to two orders of magnitude. CITATION:Khanal, M, Poulsen, B, Adhikary, D and Guo, H, 2018. Modelling of height of connective fractures during longwall mining, in Proceedings The Fourth Australasian Ground Control in Mining Conference (AusRock), pp 254–265 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 30, 2018

By C J. Moran

Given that the mining industry is committed to sustainable development principles and that Australia is experiencing changes to the regulatory environment that aim to modernise the water sector and encourage adoption of consistent approaches, there is a well defined need for the Australian minerals industry to develop a water accounting framework. This requires: key terms and definitions for water metrics for use in the Australian minerals industry that is consistent with the wider water sector, a suite of metrics representing key components of an operationÆs water balance, a calculation method for some of the metrics, and a reporting protocol. This paper presents the methodology that was used to derive these four components. Existing accounting frameworks were reviewed and key terms and definitions that were consistent with current requirements were proposed. A calculation methodology was developed to obtain some of the key indicators and variables that cannot be easily measured directly (water loss through evaporation is an example). The adopted terms and definitions dictated model development, with the conclusion that a systems approach was the most effective calculation process. To test the proposed definitions and calculation methodology, values for water metrics were derived for eight sites. The proposed framework and definitions could deal with the specific situations selected as case studies. The associated calculation methodology produced complete accounts at various levels. Some elements of the accounts could be directly checked against available data and simulations. The framework captured well variations in the reuse efficiencies; reuse efficiency could even vary for similar processes. It is concluded that this preliminary accounting framework provides a consistent language and metrics for quantifying and communicating water management, both at the intersection of the site with the surrounding landscape (through detailed reporting of site inputs and outputs) and within operational activities. Using this consistent framework for quantifying and documenting water use within an operation will provide a platform for compiling and comparing minerals industry water use with other sectors. This may support benchmarking activities within regions or companies and help demonstrate leadership amongst water users in water resource stewardship. The approach presented here is applicable to a wide variety of mining and processing activities, and biophysical environments, and can be adopted as the first step towards developing national water accounts for the Australian Minerals Industry.

Jan 1, 2009

By B G. Lottermoser

Field and laboratory data combined with computational modelling have been used to predict the pit water quality for the Highway Reward mine. Open pit mining of the Highway Reward copper-gold deposit has produced a final mining void with a diameter of 600 m and a depth of 280 m. This void will be left to fill with ground and surface water once pumping of pit water ceases. Several leaching tables were constructed to simulate weathering reactions and surface water run-off in the major pit wall units during a 200-day leaching experiment. To date, about three-quarters through the experiment, combined run-off from these cells has reached a pH

Jan 1, 2003

By E M. Wightman, C L. Evans

A recent survey of mineral processors undertaken as part of the International Mineral Processing Council (IMPC) Education Commission identified mineralogy as one of the key skills required for mineral processors (the other key areas being comminution, flotation, physical separation, sampling and extractive metallurgy). Past experience in a number of operations has shown what can be achieved when the data outputs from mineralogical tools are coupled with people with the right skills who can transform the data into actionable information. This paper reviews what has been done successfully in plant operations over a period of more than four decades and gives examples of a range of applications with both long and short-term objectives. The examples demonstrate the usefulness of mineralogical data – both basic and complex – in optimising mineral processing operations, whether the data are applied in a simple analysis or in more complex modelling. Similarly, the examples show the range of options available for operations to access the mineralogy information they need – through in-house experts and equipment based in centralised technology centres, through on-site equipment and experts or through external laboratories and consultants.The examples from industry highlight the huge potential benefit of including mineralogy as an integral part of operational best practice and raise the question of why more operations do not utilise what should be readily available data. Successful application of mineralogical data requires skilled people to generate relevant data of the required quality, together with skilled people to interpret the data (this may be the same person). And, as in any project, corporate recognition of the value of this approach to best practice is required to ensure continuing support. With fewer university courses providing courses in process mineralogy to undergraduate mineral processing engineers and chemical engineers, there is an increasing lack of knowledge about what mineralogical information is needed, how to get the required data and, equally importantly, how to turn the data into useful information.CITATION:Evans, C L and Wightman, E M, 2018. Understanding minerals in mineral processing – the basics and beyond, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 363–376 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

The Acid Drainage Technology Initiative (ADTI) was initiated in 1995 by federal agencies, the National Mining Association (NMA) and the Interstate Mining Compact Commission (IMCC) to identify, evaluate and develop cost-effective and practical acid drainage technologies. In 1999, ADTI was expanded through the addition of the metal mining sector, which is focused on drainage quality issues related to metal mines. ADTI addresses drainage quality issues from abandoned, active, and future coal and metal mines. The guiding principle of ADTI is to build consensus among industry, federal and state regulatory agencies on acid drainage technology development and technology transfer issues. ADTI is focusing its efforts on mine drainage prediction, sampling/monitoring, modelling and avoidance/remediation. ADTI is not a regulatory or policy development program. ADTI includes the Coal Mining Sector (CMS) and the Metal Mining Sector (MMS) under the overall guidance of the ADTI Operations Committee. The Operations Committee consists of representatives from industry, state and federal government and academia. The Coal Mining Sector includes two committees; a prediction committee and an avoidance and remediation committee. The Metal Mining Sector includes steering committee and work groups on prediction, sampling and monitoring, modelling, mitigation, and pit lakes. The Coal Mining Sector has produced two publications on the prediction and prevention of acid drainage. The Metal Mining Sector has workbooks under preparation covering the work group topics. This past winter, the Metal Mining Sector, working with the US Bureau of Land Management, presented a satellite training session on acid drainage. ADTI has evolved in response to changing needs and technologies as evidenced by the addition of the Metal Mining Sector in 1999. The Operations Committee and the members of the Coal and Metal Mining Sectors will guide future direction in response to identified issues.

Jan 1, 2003

By Giles D, Wegmann D

The Mt Todd Gold Project is located 42 km northwest of the township of Katherine within the Northern Territory of Australia. It is situated in the southeastern portion of the Pine Creek Geosyncline. The Batman gold deposit, the largest of several deposits at Mt Todd, hosts an identified mineral resource of 92.9 million tonnes (Mt) grading 1.4 grams/tonne (g/t) as at 31 December 1993. Host rocks at Batman are assigned to the Early Proterozoic Burrell Creek Formation, comprising greywacke and siltstone interbedded with shale. Gold mineralisation is associated with a very broad zone of sheeted and stockwork quartz-sulphide veins that occupy a corridor of intense brittle fracture and faulting. A conceptual model of formation involves the dilation of joints and micro-faults within overlying sediments during sinistral movement along a basement shear zone. Synchronous granite intrusion generated convective circulation of crustal fluids through the sedimentary pile resulting in the formation of auriferous quartz veins within favourable structures. The Batman zone of mineralisation is not directly related to fold structures which typify several other major gold deposits within the Pine Creek Geosyncline.

Jan 1, 1994

By S Garnes, W Austerberry, S Fraser

Despite significant investment in safety in the mining industry (mostly focused on processes and systems), many companies are unable to sustain and further improve their performance resulting in continued workplace incidents. The problem persists despite the best efforts of companies and allocation of resources to achieve Zero Harm. A DSS survey in 2019 found that two out of five companies that cannot manage risks and face disaster, leave the market within five years. All safety/risk management systems have the common steps of risk identification, prioritisation, design of controls consistent with risk tolerance, and verification of implementation/operability of controls. This is then complimented with improvement to one or more of the above elements through learnings obtained from incident investigations. In principle, the above process should work to reduce risks to, and keeping them at, a risk level consistent with risk tolerance in the organisation.

May 5, 2022

Knowledge of the crystal chemistry of carbonate apatites is very important for the development of the concept of biomineralisation and the creation of a scientific base for new biocompatible materials for medical purposes. The present work is devoted to research results on various synthetic and biological carbonate apatites obtained at Saint Petersburg University over many years. All-important problems will be considered such as the location of CO32- ions in the apatite structure, the ionic substitutions in various biological apatites and the development of synthesis methods for their analogues. Syntheses of apatites were realised by precipitation methods and under hydrothermal conditions (from solid compounds and by calcite treatment). Biological samples used in this study were physiogenic and pathogenic apatites formed in the human organism, eg in teeth and in renal and salivary stones and dental calculi as well as apatites from fossils of different taxonomic families (brachiopods, conodonts, fishes, reptiles, mammal) with different geological ages and burial conditions. The study of the crystal chemistry of carbonate apatites has been carried out by powder (including high-temperature measurements) and single-crystal X-ray diffraction methods, IR-spectroscopy, thermal analysis and various chemical analytical techniques.

Jan 1, 2008

This paper investigates the adequacy of current gas monitoring techniques to adequately detect spontaneous combustion in underground coalmines. Despite being in the 21st century spontaneous combustion continues to occur in underground coalmines sometimes being detected only at a very advanced stage. Control of the incident is often then very expensive and time consuming. The adequacy needs to be assessed not only from the point of view of the analysis technique be it tube bundle, gas chromatograph or real time sensor but also the number, location and sampling frequency of the monitoring locations. Recommendations are made to optimise monitoring processes and recognise limitations of current techniques.

Jan 1, 2005