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By A. P. I. Popoola, T. J. Olaniyi, A. A. Adeleke

"A laboratory froth flotation experiment was conducted on a low-grade carbonatite copper ore sample obtained from Phalaborwa in the Limpopo province of South Africa. The sample was a homogenous hydrocyclone overflow which serves as the feed to the flotation cells at Palabora Mining Company (PMC). The sample has an average copper assay of 0.59% with predominant copper-bearing minerals being chalcopyrite, bornite and cubanite. The carbonatite nature of the ore comes from the high content of calcium (28.85%) and magnesium (6.84%) minerals. Collectors used were sodium diethyl dithiocarbamate and potassium ethyl xanthate alongside Senfroth 38 supplied by Senmin. The results showed that at 200 g/t mixture of collectors (50:50), an optimum grade of 8.03% Cu in the rougher flotation concentrate was achieved at 74% recovery, while during the second flotation, 24.65% Cu was obtained at 74.4% recovery using a Senfroth 38 dosage of 6 L/t with 100 g/t mixed (50:50) collectors. The particle size and pH value of the pulp played a significant role in that the mixed collectors performed efficiently at pH above 8.3 and at room temperature while particle sizes greater than 53 µm were well concentrated when compared with those of less than 53 µm. INTRODUCTION The need for copper ore concentration research is on the rise as a result of the depletion of deposits and the advent of low-grade copper ores. Although most copper ore deposits have other valuable minerals that support their economic extraction, the increase in technological innovations as regards copper usage and applications has increased the demand for copper. Several factors influence concentration results in a froth flotation column, of which the reagent used is most influential."

Jan 1, 2015

By K. Heatwole, D. Shier, A. Davis, J. Kidder, S. Sunkavalli

"Acid rock drainage (ARD) is produced when sulfides are exposed to oxygen and water. Oxidation reactions typically result in a depression of pH and leaching of solutes and metals. Many oxidation models have been developed based on oxygen diffusion, but in environments with high permeability, other transport processes (i.e., convection and advection) can play an important role. Multiple sulfide mineral phases with differing oxidation rates should also be incorporated. WROC, a finite-difference model, was developed to account for these factors in predicting ARD. The program includes sulfide mineral oxidation using a shrinking core mechanism, heat transfer by conduction, heat of reaction and oxygen transport by diffusion and advection. The model was validated using data from the literature. After validation, the WROC model was used to simulate several different waste rock scenarios, including different forms of sulfide mineralization and the effect of implementing a waste rock cover. The results demonstrate that including specific sulfide mineral phases can have a significant effect on oxidation and that implementation of a cover can also aid in reducing waste rock oxidation.IntroductionAcid rock drainage (ARD) is a notable environmental concern in areas where rock or other material with acid generation potential is disturbed. ARD is defined as drainage that occurs as a result of sulfide oxidation in rock exposed to air and water. ARD is characterized by low pH, elevated metals concentration (especially aluminum, iron and manganese), sulfate and high total dissolved solids. The low-pH water that results from acid generation is capable of solubilizing heavy metals contained within the rock. The principal sulfide mineral in mine wastes is pyrite (FeS2). Pyrite oxidation is complex and can involve chemical and biological reactions. Oxidation of pyrite by atmospheric oxygen produces one mole of Fe2+, two moles of SO4 2- and two moles of H+ for every mole of pyrite oxidized, as described by Eq. (1)."

Jan 1, 2015

By L. F. Contreras

In open pit mine design, it is customary for geotechnical engineers to define the appropriate slope design angles within practical limits. The conventional approach to slope angle design is based on the comparison of calculated stability indicators, such as the factor of safety (FS) and the probability of failure (PF), with generic acceptability criteria not directly related to the impacts of failure. A major drawback of this type of approach is related to the difficulty of defining meaningful acceptability criteria. An alternative methodology of pit slope design is proposed, where the economic impacts of potential slope failures are calculated and used as the elements on which to apply the acceptability criteria for design. The methodology is based on the construction of a graph, referred to as a risk map, that relates the probability of exceeding the economic impact of slope failure to the magnitude of the impact measured in monetary terms. The process includes the analysis of a selected number of representative years of the mine plan and slope sections of the pit areas to define the required inputs for the construction of the risk map. The paper discusses the concepts used in interpreting the probability of slope failure, and describes the approach followed for the estimation of the economic impacts of slope failure and the construction of the risk map. Finally, the two main uses of the risk map are discussed, including the comparison with acceptability criteria for the evaluation of a specific open pit design and the comparative analysis of open pit design options in terms of value and risk to identify optimum pit layouts.

Jan 1, 2015

By R. F. Favreau, Patrice Favreau

"A blast with explosives creates vibration waves in the zone around the blast.The prediction of the intensity of vibrations is important because people in the cinity demand that the vibrations do not disturb them, and society imposes limits on the vibrations. The U. S. Bureau of Mines (USBM) showed that the easurement of the particle velocity U predicts the risk of damage from vibrations. A currentapproach of blasters to monitor vibrations is to measure them with a seismograph at several distances S, and create a graph of U vs. S and the explosive charge “W” according to the equation U = K / (S / W)N where K and N are constants that depend on the blast method and the nature of the ground over the distance S. Though useful, this equation is empirical, and the results predicted from it are very variable, as shown by figure 1 which indicates that a prediction of U can deviate significantly from the actual value. Moreover, a minimum of two seismograph measurements at two values of S are required to establish the curve. However, here now exists another very convenient method to predict U; it is with the simulator Vibmas, which is based on the fundamental principles of how a blast reates vibrations. This simulator takes into account not only W but rather all the blast parameters, the type of explosive and the properties of the rock. Moreover, to establish the calculation of U as a function of S, only one seismograph measurement is required rather than two as for the USBM method. This last difference is important because it makes it easy to predict U not only as a function of S, but also as a function of the orientation of S. On the site this allows much safer control of the vibrations, and the use of larger explosive charges which reduce excavation costs. The article presents results from a field case at a hydroelectric project in Canada, where the deviation was very moderate. Use of this vibration simulator on the Web is very easy."

Jan 1, 2015

By J. A. Marts, R. C. Gilmore, Jr. Bogin, S. A. Saki, J. F. Brune, J. W. Grubb

"Colorado School of MinesResearchers at Colorado School of Mines (CSM) have developed computational fluid dynamic (CFD) models to study gas distributions and explosion and fire hazards in longwall gobs. In underground coal mines, methane continuously emitted from surrounding strata mixes with air from active mine workings and may form explosive gas zones (EGZs). Some western United States coal mines are also prone to spontaneous combustion (spon com). Insight into oxygen concentrations within the gob is crucial for assessing spon com hazards and mitigation strategies. Nitrogen injection used in conjunction with progressive gob sealing can reduce EGZs and spon com hazards by forming a dynamic seal that separates the methane in the gob from the air that ingresses from the face. This paper describes CFD modeling simulations studying the formation of such dynamic seals by optimizing the nitrogen injection locations. The impact of nitrogen on oxygen ingress and formation of EGZs is discussed. Optimum nitrogen injection quantities and injection locations were determined. Dynamic seal formation is most effective if the headgate nitrogen injection locations are split between the first crosscut inby the face and a second location about 300 m (1,000 ft) further inby. INTRODUCTION Underground longwall coal mine ventilation systems are designed to dilute hazardous gases and to provide breathable air to miners working in the area. Methane gas is liberated as the mining process extracts the coal and disturbs the surrounding strata. Methane mixes with the ventilation air and often produces explosive gas zones (EGZs) within longwall gobs (Brune 2013). Past CFD modeling research of underground coal mine ventilation systems has shown the effects of face air quantity on EGZs (Worrall 2012) and nitrogen injection to control spon com (Balusu et al. 2005; Ren et al. 2012; Ren et al. 2011; Smith and Yuan, 2008; Yuan and Smith, 2014). Other modeling approaches include network ventilation models of oxygen ingress (Dziurzynski and Wasilewski, 2012), and coupled Linear Network CFD algorithms (Wedding 2014). In a project sponsored by the National Institute for Occupational Safety and Health (NIOSH), CSM researchers are using Fluent®, a CFD software package by ANSYS, Inc., to model gas compositions and flows in underground longwall gobs. Figure 1 shows a progressively sealed gob with a U-type ventilation system in a three entry development. As the longwall advances, seals are constructed along the headgate in the crosscuts between the center entry and the gob. Additional gob isolation seals are built to block off the headgate entries inby the face. Nitrogen is injected through the seals in the first two crosscuts on the headgate side and at the first crosscut inby the face on the tailgate side, as shown in Figure 1."

Jan 1, 2015

By G. A. Bezuidenhout, J. P. T. Kapusta, D. K. Chibwe

"Peirce-Smith converters (PSCs) are extensively used in the copper, nickel, and platinum group metals industries. The typical converting operation involves lateral purging of air into molten matte through a bank of tuyeres. This blowing operation occurs at low pressure from the blowers, resulting in a bubbling regime that is considered inefficient from both a process and an energy utilization perspective. Inherent drawbacks also include recurrent tuyere blockage, tuyere punching, and low oxygen efficiency.Western Platinum embarked on a full-scale industrial evaluation of generating a jetting regime by using sonic injection. Prior to industrialscale tests, a numerical assessment to ascertain the feasibility of implementing sonic injection into a PSC was conducted. The work included flow characterization at high-pressure injection achieving sonic velocity at the tuyere exit. The 2D and 3D simulations of the three-phase system were carried out using the volume of fluid method together with the RKE turbulence model to account for the multiphase and turbulent nature of the flow.This paper discusses the key findings in understanding plume extension, velocity distribution, shear wall stress analysis, and phase distribution characteristics in the system. Plant trials are also discussed with reference to the commercial aspects of a full-scale implementation of sonic injection in the smelter."

Jan 1, 2015

By A. Cecala, J. Noll, J. Hummer

The National Institute for Occupational Safety and Health has observed that many control rooms and operator compartments in the U.S. mining industry do not have filtration systems capable of maintaining low dust concentrations in these areas. In this study at a mineral processing plant, to reduce respirable dust concentrations in a control room that had no cleaning system for intake air, a filtration and pressurization system originally designed for enclosed cabs was modified and installed. This system was composed of two filtering units: one to filter outside air and one to filter and recirculate the air inside the control room. Eighty-seven percent of submicrometer particles were reduced by the system under static conditions. This means that greater than 87 percent of respirable dust particles should be reduced as the particle-size distribution of respirable dust particles is greater than that of submicrometer particles, and filtration systems usually are more efficient in capturing the larger particles. A positive pressure near 0.02 inches of water gauge was produced, which is an important component of an effective system and minimizes the entry of particles, such as dust, into the room. The intake airflow was around 118 cfm, greater than the airflow suggested by the American Society of Heating, Refrigerating, and Air-Conditioning Engineers (ASHRAE) for acceptable indoor air quality. After one year, the loading of the filter caused the airflow to decrease to 80 cfm, which still produces acceptable indoor air quality. Due to the loading of the filters, the reduction efficiency for submicrometer particles under static conditions increased to 94 percent from 87 percent.

Jan 1, 2015

By Alastair Torrance, Mitchell Nipperess, Andrew Olsson, Italo Onederra, Gary Cavanough

Components of bulk explosive products include ammonium nitrate, water, fuel, stabilizers, and calcium nitrate. The physical attributes include prill/emulsion ratio, density, and viscosity and in the case of prilled ammonium nitrate, hardness, size distribution and fuel oil absorption. These components and attributes in conjunction with ground conditions determine all aspects of explosive performance including the risk of fume. This paper presents a fume risk assessment matrix of explosives components and physical attributes as a function of a simple description of ground conditions. Instrumentation to provide a measure of the quality of the explosive product are also described and these include both “on bench” physical measurements and laboratory analysis. “On bench” methods include “in hole “density, velocity of detonation (VOD), detonation pressure and detonation temperature. Part of the quality control process involves a mobile laboratory unit which at this stage can provide measurements of water content, ammonium nitrate content, calcium nitrate content, fuel content, prill characteristics and prill/emulsion ratio. This unit can be taken to sites to enable the testing of bulk and sensitized products at site rather than after transportation.

Jan 1, 2015

By P. L. Yorio, D. R. Willmer

"The current paper presents the results of a study designed to explore the types of practices that are fundamentally important to developing and maintaining comprehensive risk-based health and safety management systems (HSMS) in mining organizations. Eighteen practicing health and safety (H&S) executives, managers, and professionals from a variety of mining commodities were asked to assess the fundamental importance of 20 distinct elements and 133 different practices assembled from a review of several HSMS consensus standards. The research approach assumes that developing and maintaining a robust HSMS requires unwavering attention to activities designed to either: 1) directly contribute to a risk management system’s plan-do-check-act cycle; or 2) build an organization’s internal infrastructure without which the cycle cannot be sustained. The results of this study suggest that the following areas require consistent focus and attention: Leadership Development; Accountability; Knowledge, Skills, and Abilities Development; System Coordination; Culture Enhancement; Behavior Optimization; and Risk Management Studies. Each element and its corresponding top-ranked and top-rated practices are discussed.INTRODUCTION Since the time of the Industrial Revolution, occupational health and safety (H&S) management has been a topic of practitioner thought and academic inquiry (1). In the U.S., decades of regulation and research have resulted in a surplus of prescriptive information (techniques, tools, approaches, standards, programs, practices, policies, etc.). With an abundance of such information, a simple H&S solution to address a problem in the U.S. mining industry may seem straightforward. Counter to this assertion, however, some evidence suggests that the abundance of information may create complexity and cause confusion in the minds of organizational leaders and H&S managers, ultimately discouraging the voluntary pursuit of a sound approach (2). In line with this perspective, in 2006 the U.S. National Mining Association (NMA) formed an independent commission to examine H&S management issues within the mining industry. The findings of the commission called for the mining industry to adopt a risk-based management paradigm. In the presentation of its findings, the commission stated that “…every mine should employ a sound risk-analysis process, should conduct a risk analysis, and should develop a management plan to address significant hazards identified by the analysis” (3). Grounded in the well-known plan-do-check-act cycle, the recommended risk management system allows for mines to ground strategic management choices in their mine-specific hazards and risk profiles"

Jan 1, 2015

By S. M. Chentouf, M. Jahazi, N. Bombardier, T. Belhadj

The main limiting factor in the commercial expansion of superplastic forming (SPF) of thin sheet aluminum alloys is the extent of cavitation phenomenon that takes place during the processing. The severity of the cavitation process is mainly dependent on the uniformity of deformation (i.e. level of local thinning) during processing. In the present paper, correlations are made between thickness variations in several formed sheets and the characteristics of the cavities observed in the material. The 1.4 mm thick 5083 aluminum alloy sheets were hot pre-formed at around 450°C for 4 min and then air-cooled. Opto-digital and Scanning Electron Microscopy were used to examine the microstructure and analyse the cavities. Also, grain size measurements were carried out for different location in the SPF formed piece. The surface and volume fractions of the cavities were measured with the aid of metallography image processing (MIPTM) on as-polished samples prior to etching. The results are analyzed in terms of the influence of applied strain and microstructure conditions on the propensity to cavitation of the alloy.

Jan 1, 2015

By T. T. Wang, T. H. Huang, S. S. Zhan

"Fractures with diverse features dominate the hydraulic behavior of fractured rocks and are one of the major subjects for hydrogeological characterization of a site. This study investigates curve patterns obtained by packed tests, and as well the influence of fracture features based on 59 sets of in situ packer tests with different fracture combinations and fracture features. The result shows that, in the example of Heshe site, neat and tidy fractures usually provide stable channel for water flow during testing, and the hydraulic properties of fractures infilled with breccia and mud may change during testing because of leaching and/or washed out of infilling breccia and mud. Different combinations of fractures with diverse features in packed test sections lead to different curve patterns for in situ hydrogeological tests. For groundwater flowing predominately through neat and tidy fractures, the pressure-discharge curve of modified Lugeon tests are usually linear curve pattern, and the pressure decrease while the discharge increase in pressure-discharge-time curves of single-hole double packer tests, which benefit statistically determining the transmissivity of dominant fracture sets. INTRODUCTIONFractures interlaced in rock masses are major channels for groundwater flow and generally account for the anisotropic and heterogeneous characteristics of permeability for fracture rocks. To describe reasonably the permeability of a fracture rock, the Discrete Fracture Network (DFN) approach and others with similar ideals have been developed. Many methodologies and associate equipment, for instance, the televiewer and the in situ hydrogeological test, have been proposed to investigate the spatial distribution and the transmissivity for different fracture sets, which are two main parameters necessary for the DFN or similar model simulation (Pearson & Money, 1977; Barker & Black, 1983; Hsieh et al., 1985; Bernard et al., 2006; Quinn et al., 2012). However, diverse outlooks for the pressure-discharge curves and the temporal pressure and associate temporal discharge curves often confuse the investigation results by significant deviations on derived permeability (Houlsby, 1976; Zlotnik, 1994; Royle, 2009; Camilo, 2010).Aiming on technical development for in situ hydrogeological tests and fracture investigation, an experimental well site with 10 wells has been established in Heshe in central Taiwan since 2011 (Wang et al., 2011; Song, 2012; Zhan et al., 2013). Extensive geological survey and well-hole scanning by a televiewer provide spatial distributions and outlooks of fractures in detail. Additionally, a series of Lugeon tests, double packer injection tests and pumping tests have been performed to investigate the permeability of fracture rocks, and dominate fracture sets as well. Based on the results obtained from the Heshe site, this study classifies the curve patterns of hydraulic packer tests. The features of fractures involved in packed sections for packer tests are then inspected in detail. Relationship between the curve patterns of hydraulic packer tests and associated features of corresponding fractures in rock are discussed and addressed accordingly."

Jan 1, 2015

By Darin Cotton, Tim Burgess, Tim Martin

"As the leading US supplier of roof control drills, J. H. Fletcher and Company® has encountered an extensive set of roof strata challenges and has overcome various drilling issues by varying machine parameters and working with customers and tool manufacturers to develop solutions. Every mine wants to drill and install roof bolts as fast as possible with maximum safety at the lowest possible installation cost for their conditions. In most circumstances, the intuitive method of higher speeds and pressures can actually have a detrimental effect on the roof drill safety and performance.This paper will outline recent tests carried out at several different coal mines in the Eastern United States. The tests focused on optimizing the drilling parameters of feed pressure, feed rate, rotation speed, and drill torque.The drill feed, rotation speed, and rotation torque, as well as the type of bit selected, have a definite impact on the performance of the roof drill including drilling speed, safety, and tool life. The drilling process can be improved while also improving operator safety and reducing bolt installation costs by maintaining the appropriate roof drill settings for the specific strata conditions.The advantages of improving the drilling process includes increased bit life, increased drill steel life, reduced hanging drill steels, reduced clogging of the vacuum system, decreased whipping drill steel potential, reduced noise generation, and increased cutting size which reduces fine dust generation and dust collection system servicing.INTRODUCTIONIn recent times, the economic pressures that coal producers are facing have created an increased emphasis on controlling operating costs. Several coal operators have pointed out their dissatisfaction with low bit life, and there is a renewed interest in improving tool life and machine performance as part of an overall cost control strategy. Operators are looking for ways to reduce tooling cost, maintenance costs, and drill downtime without decreasing drill performance. This renewed interest in reducing operating costs, along with the ongoing desire to improve safety, created a perfect environment to take a fresh look at the existing fleet of machines to see what could be accomplished. The goal was to take a practical approach to reviewing machine parameters to determine what changes could be made. The emphasis was on changes that would be feasible to roll out to an entire fleet of machines in a short period of time with minimal capital expenditure. The thought process was that significant improvements could be made by simply tuning up the machine parameters to provide a more efficient and safer bolting process."

Jan 1, 2015

By K. Sakai, M. Miyaue, T. Aoki, T. Tani, S. Tanaka, N. Kudo

In the planning stage of a tunnel, due to limited available technology in the geological survey and the financial restriction, tunnel supports are often designed from unsatisfactory information, and the tunnel construction is started. Therefore, "observational construction" is carried out in the construction stage, in which the design is rationally verified and modified by observations/measurements. Moreover, the ground conditions ahead of a tunnel face must be predicted for efficient and safe tunnel construction. The authors have examined effective prediction methods to the ground conditions ahead of a tunnel face under construction of a mountain tunnel (Aoki et al., 2010) in view of the established method (Schubert et al., 1995). Though the prediction method of Schubert et al. requires the displacement in the direction of tunnel axis, it is difficult to obtain its accurate data by the electro-optical distance meter. Then, we have proposed a method that uses tilt sensors installed at the tunnel crown near the face to obtain the slight tilting information. To measure inclination of the tunnel crown, this inclinometer was originally developed as a daily management measurement, such that the geological condition and its possible change behind the face could be detected early, and a steady advance and construction safety could be ensured. This paper describes the method of forward prediction mechanism and advantages of this proposed method. It then presents the typical results of a field demonstration test at a tunnel under construction. Lastly, the predictable range from the stratum boundary at which ground stiffness changes are discussed based on the results of three-dimensional numerical analysis.

Jan 1, 2015

By Gregory Beckstrom

"During a year of challenges in the mining industry, two groups collaborated Aug. 17- 20 for a joint conference on industrial minerals of the Upper Midwest. Hosted in Minneapolis, MN, the 4th Annual SME Twin Cities technical conference and the 51st Annual Forum on the Geology of Industrial Minerals (FGIM) drew attendees from throughout the United States and Canada.Highlights of the event included a one-day field trip on Aug. 17 to a crushed stone and gravel mining and processing operations near the Twin Cities, followed by a visit to a historic mine tunnel within the St. Peter sandstone formation. The latter was used as a speakeasy during America’s prohibition era. A two-day field trip on Aug. 19-20 made stops in central and northeastern Minnesota at a granite quarry and processing plant, a peat harvesting and packaging plant, an iron mine and taconite processing plant, and a silica sand storage and loading operation. In a nod to one of Minnesota’s celebrated luminaries, the group also stopped in Hibbing to visit the boyhood home of Robert Allen Zimmerman, better known to the rest of the world as Bob Dylan.A full-day technical program featuring talks on environmental impacts of silica sand mining, regulatory updates, mine land reclamation and methods for identifying construction material failures (alkali-silica reaction) was bookended by the two field trips.According to Minnesota state geologist Harvey Thorleifson, the keynote speaker of the technical program, “This joint SME and Forum on the Geology of Industrial Minerals conference is a reflection of the important role of the mining industry in society, of the important role that partnerships play, and of the prominence of industrial minerals on the Twin Cities region and iron ore on a national scale.” He added, “While this is a tough year for the mining industry in the region, we are confident in the strength of the profession and the industry in the medium term, as we anticipate a superb SME national conference in Minneapolis in 2018.”"

Jan 1, 2015

By T. Feldmann, G. P. Demopoulos

The adsorption of gold complexes on inorganic metal oxides has been mainly discussed in geochemical literature, but it is also of interest to the hydrometallurgical industry. This is so because it could be responsible for valuable metal losses or because it could potentially serve as alternative adsorbent material to activated carbon in certain cases such as from hot and acidic process slurries. This paper constitutes an early investigation into this subject by focusing on the effectiveness of FeOOH, Fe3O4 and Al2O3 as sorbent materials. All tests were done in a batch stirred-tank reactor under atmospheric conditions with synthetic gold(III)-chloride solutions at 23°C and 80°C, in the pH range of 1.6 to 9.0. Detailed kinetic tests were performed at different pH values (3 and 6) on FeOOH and Fe3O4 with solutions having gold concentrations from 5 mg/L to 130 mg/L. The adsorption of gold was found to be best both in terms of kinetics and loading characteristics at 80°C and pH=6. This was explained by a change in Au(III)-Cl speciation from a gold(III)-chloride complex to a gold(III)-chloride-hydroxy complex. By far, magnetite (reagent grade chemical) yielded the best gold adsorption characteristics making it an interesting sorbent material for further development considering that it can be advantageously recovered from slurry streams via magnetic separation. On the other hand, the tendency of gold(III)-chloro complexes to adsorb on metal (hydro) oxides needs to be taken into account to minimize undesirable metal losses in chloride-containing leaching media.

Jan 1, 2015

By A. David Miller, Douglas M. Barber

"The Rocky Mountain Arsenal was used by the military to produce chemical warfare agents and incendiary munitions for use during World War II and later by private companies for the production of industrial and agricultural chemicals. After an investigation performed in accordance with CERCLA confirmed significant levels of contamination due to the common industrial and waste disposal practices of the era and the discovery of over 300 species of wildlife inhabiting the land the Rocky Mountain Arsenal became a wildlife refuge and contamination cleanup efforts began. Three lime basins originally used to treat wastewater from the chemical production were decided to be contained in place, requiring a seepage barrier installed around the perimeter of the site to further prevent groundwater/contaminant migration. This case study will discuss the successful installation of a soil-bentonite cutoff wall around the area using deep soil mixing. Highlights of this case study will also include a discussion of the challenges faced due to construction activities performed with Level B Hazmat PPE requirements as well as added challenges brought on by the Winter season, after the project was delayed due to a positive air monitor detection for the chemical weapon Lewisite during construction of the work pad.INTRODUCTIONThe Rocky Mountain Arsenal (RMA), located just outside of Denver, Colorado, was established by the United States Army in 1942 to produce chemical warfare agents and incendiary munitions for use during World War II. Following the war, and as weapons production decreased, portions of the site were leased to private companies for the production of industrial and agricultural chemicals. The principal lessee, Shell Oil Company, manufactured mostly pesticides at RMA facilities from the early 1950s to the early 1980s.In 1984 an investigation began in accordance with the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) and confirmed significant levels of contamination due, in large part, to the common industrial and waste disposal practices of the era. It was also discovered that over 300 species of wildlife inhabited the land in the absence of regular human activity, including a group of bald eagles, leading to the passing of the Rocky Mountain Arsenal National Wildlife Refuge Act in 1992."

Jan 1, 2015

By Randy Settgast, Daniel Moos, Hyunil Jo, Ghazal Izadi, Christine Baba

"Analyses of production logs of multiply fractured horizontal wells in unconventional plays show that only a small percent (~30%) of perforation clusters contribute to production. We present in this paper one possible approach to mitigating this problem, based on use of a fully 3-D numerical model of fracture propagation through a heterogeneous medium, by studying the influence both of spacing and of perforation friction on the initiation and propagation of simultaneous hydraulic fractures from a horizontal wellbore. The results indicate that while limited-entry perforating can help to equalize the lengths of fractures simultaneously growing from multiple clusters, it cannot equalize their widths. Both fracture width and fracture length can be equilibrated by combining non-even cluster spacing with limited-entry perforating. This has obvious benefits as it allows equalized placement of proppant across the entire series of perforation clusters, resulting in similar fracture widths and conductivities which enhances the likelihood that all clusters will contribute equally to production.INTRODUCTIONThere is substantial evidence from production logs and other information that during the hydraulic stimulation of horizontal wells, not all perforation clusters within a given stage will produce. One possible cause is the interaction between the hydraulic fractures emanating from each perforation cluster. Typically fractures created at the outer perforation clusters create “stress shadows”, i.e. increases in compressive stress in the minimum principal stress direction, which limit the growth of fractures growing from interior clusters; this is confirmed by modelling [1, 2, 3]. An example of this can be seen in Figure 1 which shows the final configuration of simultaneously propagating fractures from multiple, evenly spaced clusters when there is no perforation friction. The inner fractures are substantially shorter, reproducing the results by Bunger and Peirce [3]. The inner fractures also have substantially smaller widths.One approach to equalize the growth of simultaneously propagating fractures from a horizontal wellbore is by using limited-entry perforating as a method to equilibrate the flow rates into each of the different perforation clusters. Perforation friction is caused by the finite diameter of the entry points into the formation, and leads to a pressure drop across each perforation which is proportional to the flow rate squared. Fractures that take more fluid have a higher fluid velocity through the perforations than fractures receiving less fluid. This causes a larger pressure drop between the wellbore and more rapidly growing fractures, compared to the same pressure drop between the wellbore and the fractures that grow more slowly. Because pressure within the wellbore is approximately the same at each entry point, the larger pressure drop leads to less pressure being delivered to rapidly growing fractures, thereby decreasing their ability to propagate and reducing the amount of fluid they are able to receive. Because the mass rate of injection into the wellbore is constant, this forces more fluid into the fractures that were propagating more slowly, increasing their growth rate. It also increases the pressure required to drive fluid injection. The balance of these effects makes the system largely self-regulating and delivers more balanced fracture growth. While this effect is well known, it is often neglected in current numerical models."

Jan 1, 2015

By M. J. Makhula, R. M. S. Falcon, S. O. Bada, L. M. Falcon

"SynopsisThe combustion and co-combustion behaviour of macadamia nut shell, high-ash coal, and anthracite, along with their blends was studied using thermogravimetry. The reactivities of all samples were analysed in air, oxygen, and CO2 atmospheres and at different heating rates from 10 to 40°C/min. Macadamia shell was found to have a lower ash content, 0.36%, than coal with 27.49% ash. The calorific values were similar, 19.64 MJ/kg and 19.44 MJ/kg respectively. The differential thermogravimetric results indicate that as the heating rates increase the ignition, peak, and burnout temperatures increase significantly, leading to high combustion rates. The interaction between the fuels was evaluated using the weighted average model, and the results indicated that there is more synergetic interaction between 20% macadamia plus 80% coal under oxygen than in air and CO2 atmospheres. The results of the investigation provide the combustion and co-combustion characteristics of various samples and their blends and indicate their combustion compatibilities. IntroductionThe global macadamia nut industry is developing at a very rapid rate. South Africa is currently the world’s third largest producer, with a production of about 35 000 t as of 2012 (Department of Agriculture, Forestry and Fisheries, 2013), compared to 840 t produced in 1996. The greatest numbers of the macadamia nut farms in South Africa can be found in Mpumalanga, Limpopo, and KwaZulu-Natal provinces, with Mpumalanga as the largest producing area. There are many factors influencing the increased demand for macadamia nuts, the most important factor perhaps being their nutritional value (California Dried Fruit and Nuts, 2011; MPC, 2014) and their suitability as a feedstock for manufacturing cosmetics, bakery products, nut paste, chocolates, sauces, and ice-cream. As a fuel, macadamia shell has a high heating value ‘as-fired’ of about 20.71 MJ/kg (Vhathvarothai et al., 2013), which could in turn be used in drying the nust, and the shell could also be milled and applied as a fertilizer."

Jan 1, 2015

By V. S. Gischig, G. Preisig

Hydraulic stimulation of deep reservoirs is an essential procedure for developing engineered/enhanced geothermal systems (EGS), but also in other Geo-energy contexts. The goal is enhancing permeability to such a degree that fluid flow rates within the reservoir are sufficiently high for an economically productive reservoir. Two fracture stimulation mechanisms are distinguished that may occur concurrently during the hydraulic treatment: 1) During hydro-fracturing (HF) new tensile fractures are propagated from the borehole by means of a fluid pressure overcoming the minimal principle stress d3 plus the tensile strength T0 of intact rock. In case of a pre-existing fracture oriented normal to d 3 , the fracture can be opened by exceeding d 3 only. Fluid injection is performed via small packed intervals for creating a stack of hydraulic fractures. 2) During hydro-shearing (HS), over-pressure induces slip along pre-existing fractures that are favourably oriented in the stress field for reactivation in shear. Such stimulation is usually performed in a large packed interval or in an open borehole. Which mechanism occurs predominantly during stimulation depends on the rock mass structure and in-situ stress field, but also on the orientation of discontinuities intersecting the open-hole section and thus being pressurized. Both mechanisms also differ in how they affect fracture permeability. While permeability gained by HS is mostly irreversible due to rearrangement of asperity contacts accompanied with shear dilation, permeability enhanced during HF reduces nearly reversible after pressurization unless proppant is used to ensure permanent apertures. In this contribution, we critically discuss the pros and cons of both mechanisms regarding efficiency of enhancing permeability and the associated hazard of induced earthquakes based on literature review and numerical modelling. We review literature that reports on how much permeability required for productive EGS reservoirs and how much permanent permeability can be gained by stimulation. We also compile information regarding the degree of seismicity induced during HFor HS-dominated stimulation procedures, together with conceptual studies that reveal characteristics of seismicity associated with the two mechanisms. Many observations and models indicate that HF may have a higher tendency of being aseismic, while felt seismic events are usually associated with HS. Further, we present a hydro-mechanically coupled fracture flow model that investigates, if and to what degree the stimulation strategy can be designed such that one of the two mechanisms is evoked and dominates over the other. It shows that HS may dominate in presence of larger persistent fractures nearly optimallyoriented in the stress field, even if HF is attempted in short packed intervals. The model further demonstrates that stress transfer during HS promotes the development of permeability across an anisotropic layer of the stimulated rock instead of a large volume. Hence, the study sheds light onto the feasibility of creating productive EGS reservoirs in crystalline rock at several kilometres depths.

Jan 1, 2015

By Andrea Lisjak Bradley

Clay shales are currently being assessed as possible host rock formations for the deep geological disposal of radioactive waste. However, one main concern is that the favourable long-term isolation properties of the intact rock mass could be negatively affected by the formation of an excavation damaged zone (EDZ) around the underground openings. The goal of this thesis was to develop and validate a mechanically-based model of the deformation and failure process of a clay shale, namely Opalinus Clay (OPA), with particular focus on the influence of anisotropy on the short-term response of circular tunnels. To achieve this goal, a hybrid continuum-discontinuum numerical approach was developed in combination with new field measurements from the Mont Terri underground research laboratory. The response of OPA during the excavation of a full-scale emplacement (FE) test tunnel was characterized by geodetic monitoring of wall displacements, radial extensometers and longitudinal inclinometers. The deformation measurements indicated strong directionality induced by the combined effect of in-situ stress field and bedding planes striking parallel to the tunnel axis, with the most severe deformation occurring in the direction approximately perpendicular to the material layering. Computer simulations were conducted using a newly-extended combined finite-discrete element method (FEM/DEM), a numerical technique which allows the explicit simulation of brittle fracturing and associated seismicity. The numerical experimentation firstly focused on the laboratory-scale analysis of failure processes (e.g., acoustic activity) in brittle rocks, and on the role of strength and modulus anisotropy in the failure behaviour of OPA in tension and compression. The fracturing behaviour of unsupported circular excavations in laminated rock masses was then analyzed under different in-situ stress conditions. Lastly, the proposed modelling methodology was applied to the aforementioned FE tunnel to obtain unique insights into the EDZ formation process around emplacement tunnels for nuclear waste. The calibrated numerical model suggested delamination along bedding planes and subsequent extensional fracturing as key mechanisms of the damage process potentially leading to buckling and spalling phenomena. Overall, the research findings are already having a direct impact on the preliminary design process of an underground repository for nuclear waste in Switzerland.

Jan 1, 2015