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By Aidan Giblett

"It is important to make a clear distinction on the scope of work of the Global Mining Standards and Guidelines (GMSG) guideline for sampling grinding circuits. Many mineral processing practitioners are familiar with the sampling and surveying of comminution circuits, in particular grinding circuits, for performance diagnosis and the identification of optimization potential. These surveys often provide information for population balance modelling of individual comminution and classification unit processes, and consequently require a large amount of information to calibrate and validate the unit models. As a result, these surveys are labour intensive, somewhat expensive, depending on internal capabilities of the mine site or company and have a long time span from initial planning to final reporting. They also require a high level of expertise to process the survey data, simulate the circuit and make sensible recommendations on follow up actions.As a result of these factors, full grinding circuit surveys are not a common occurrence at a large number of processing facilities, and several years may pass before follow up surveys are conducted. In the ensuing gap between surveys, the efficiency of the grinding circuit must often be taken on faith, and this is considered an unacceptable lapse in an environment of strained natural resources and low commodity prices.To support the rapid and productive energy efficiency analysis being promoted by the ICE working group, a much simplified survey and analysis process is required. The process reflected in the GMSG guideline is indeed more conducive to frequent analysis, at a skill level that is well within the capabilities of the average plant metallurgist. As a result, it becomes feasible to conduct mini-surveys of plant performance, which can be used to quickly and precisely diagnose the high level impact of process changes. These methods can also be manipulated by an experienced practitioner to provide sufficient information for modelling of the circuit to estimate the impact of process changes, allowing an initial rate and rank exercise to focus plant optimization efforts."

Jan 1, 2015

By M. R. Henzinger, G. Lenz, A. Gaich, Pötsch, W. Schubert, P. Wagner

"The better the information on the rock mass and its fracture system, the better is the basis for any rock mechanical decision that is required during the excavation process. While in conventional tunnelling free view to the tunnel face is available, possibilities are limited for mechanised tunnelling using a tunnel boring machine (TBM). An approach, already formulated in 2005, is used that produces digital photographs through openings in the cutting wheel of a TBM and merges them into a circular three-dimensional image. The 3D image is then used for geometric rock mass characterisation purposes including geological mapping, for example to measure spatial orientations or determine joint spacing. In the paper the basic concept is described together with first results from a pilot test.INTRODUCTIONA three-dimensional image unites digital photographs with spatial information on the objects/surfaces it shows. Since they combine geometric and visual information they are a straightforward source for geometric rock mass analysis and geological mapping. Their obvious benefits among others are: (i) they allow spatial measurements even in inaccessible regions, (ii) they provide objective and reproducible records of the rock mass conditions, and (iii) they increase working safety (Gaich et al. 2004).Pre-requisite for the generation of 3D images is the acquisition of at least two photographs from the region of interest. From the photographs the imaged object surfaces are reconstructed by means of image analysis using methods from photogrammetry (Slama, 1980) and computer vision (Hartley & Zisserman, 2001). See also Figure 1."

Jan 1, 2015

By N. Andersen

During the preliminary design phases and feasibility study of a proposed vertical shaft, a vertical diamond drill-hole is normally drilled on the site. This paper outlines how rock mass characteristics, in-situ rock stress, rock strength, hydrological characteristics, and structural parameters can be determined using wireline logging of this borehole. In addition, a rock mass classification scheme is developed, based on published work, and in particular the Q-factor is adapted to assess the stability of raise-bored shafts. The ‘stick plot’ is introduced, which combines all geotechnical parameters applicable to the stability of a vertical shaft into a colourcoded format where cross-correlations can readily be made on a day-today basis during the shaft-sinking process.

Jan 1, 2015

By L. H. Chen, Y. C. Chen, Leo Benyamin, W. C. Chen

"To investigate the evolution of fluid-driven fracture of rock-like material subjected to borehole fluid pressure and its consequential damage with regard to post-peak stabilization, micro-seismic activities have been monitored using nondestructive technique of acoustic emission (AE) corresponding to the macro-scale complete history of loading curve by setting the hollow cylindrical external circumferential strain to be a closed-loop feedback signal during servo-fluid-driven tests. Development of a novel fluidinduced loading system injected from internal borehole as well as monitoring system were equipped such that the initiation and propagation of micro-cracks enable to analyze experimentally. By programming/controlling either injection rate or fluid pressure, synthetic sandstones with low-permeability made by cement mortar were conducted in this study. It found that both the growth of macro-crack initialized intensively as reaching the breakdown pressure and the micro-seismic activities represented by AE locations show nice agreement. The experimental results in this paper provide better understandings of fluid-driven fracture mechanism.INTRODUCTIONFluid-driven fracture is a process of generating cracks by injecting viscous fluid into solid material. Conventionally, fluid-driven fracture tests have been performed by mining industry to measure the in situ stress (Haimson & Fairhurst, 1969) and fluid-driven fracture has been employed by the petroleum industry to recover oil and gas. Additionally, the mechanism of crack growth or the extension of existing cracks is important to the evolution of volcanic dikes over distances of a few kilometers (Lister & Kerr, 1991; Rubin, 1995), crack propagation in dams (Bolzon & Cocchetti, 2003) and the disposal of radioactive waste (Sun, 1969)."

Jan 1, 2015

By Erkan Bayrak, Serkan Erkara, Ozkan Duzgun, Ekin Gungor

This paper presents part of the outcomes of the drill and blast optimization project carried out at Kisladag Gold Mine in Turkey. Kisladag Gold Mine is the largest gold mine in Turkey with a low-grade, bulk-tonnage, open pit operation that uses heap leaching for gold recovery. After blasting, the ore is fed to a three-stage crushing circuit which prepares crushed ore approximately -10 mm (0.39 in) for heap leaching. Crusher downtime analysis showed that blocky material and insufficient feed are causing significant downtimes with the primary crusher. This was supported by the fragmentation data collected to date. It was decided to initiate a fragmentation project to understand the variation in the run-of-mine (ROM) size with a view to provide a consistent feed to the crushing circuit. The study includes the analyses of the ore strength and structure, image analysis of the fragmentation pictures acquired from blasts, blast auditing and quality assurance and quality control (QA/QC) analyses. During this project, over 200 fragmentation pictures were acquired from 47 blasts to optimize ore and waste blasts. Ore strength varies between 30 and 120 MPa and rock quality designation (RQD) ranges between 30 and 100. A site-specific fragmentation model was used to calibrate the fragmentation for blast domains formed. In addition, alternative cases were simulated to achieve blasts designs with consistent ROM fragmentation size distribution. Alternative blast designs that include stemming length and powder factor changes were suggested. Long stemming length, drill cuttings use, free faced blasts, small shot sizes and poor stemming length control were some of the key issues causing coarse fragmentation.

Jan 1, 2015

By A. Noble

"In coal and mineral processing, several numeric parameters are used to quantify the separation performance of unit operations. For density-based separations, the partition curve is used as the starting point for many stages of diagnostic analyses. The curve is often quantified by its midpoint slope sharpness, and this single value is subsequently used for technical evaluation, benchmarking, and comparison. While this analytical approach does depict misplacement by relative density class, it inherently prioritizes middling separation and does not consider process economics or the micro-price value of individual classes. Alternatively, the organic efficiency parameter does consider process economics; however, it does not reveal information on the root cause of lost revenue or misplacement. In this paper, a new analytical approach is introduced which reconciles the technical misplacement data derived from the partition curve with the economic data derived from micro-pricing. The result is a new analytical procedure which reflects a better use of performance data. INTRODUCTION Partition curves are commonly used in the characterization, evaluation, and simulation of various physical separators. In mineral processing, partition curve analysis is routinely applied to hydrocyclones, screens, and density separators. Graphically, the partition curve depicts the recovery of particles as a function of a physical property on which the separation is based (e.g. particle density, size, magnetic susceptibility, etc.). Given the probabilistic nature of many real separators, the partition curve often exhibits a characteristic “S” shape (Fig. 1), similar to a cumulative normal distribution. Other geometric features of the curve are also depicted in Fig. 1, including the high and low closeout (or bypass) values, the midpoint slope, and the separation cut point (property value with 50% recovery). Partition curve analysis was originally proposed to evaluate coal washability (Tromp, 1937). Given the limited computational resources at the time, the analytical methods relied heavily on graphical construction and interpretation of the curve. Owing to the simplicity of the calculation and interpretation, many of these graphical approaches are still widely used for performance analysis today. The most common calculations are based on the slope of the partition curve at the midpoint. Increased slopes correspond to enhanced separation performance, since a perfect separation exhibits a stepwise transition from 0 to 1 at the desired cut point (i.e. an infinitely large slope). One common formulation of this slope, the Ecart Probable (Ep), is derived by evaluating the slope between the 25% and 75% recovery points:"

Jan 1, 2015

By S. Peng, N. Vayenas, A. Farah

"While genetic algorithms have been widely adopted in ore grade estimation and optimization, mine design, and production scheduling in the mining engineering field, reliability and maintainability analysis of mining equipment using genetic algorithms has been a relatively new research area in recent years. This paper presents an application of genetic algorithms using case studies with seven underground scoop trams whose maintenance records have been collected over a period of 12 months from an underground mine in the Sudbury mining area. Based on the assumption that various factors that contribute to machine failures resemble the biological evolution process, the authors have developed an in-house PC software application called GenRel which adopts genetic algorithms in its programming. In this study, the authors feed the historical maintenance data into GenRel in order to predict future maintenance characteristics of mining equipment in a time period of three months. Then the predicted maintenance characteristics are compared to the actual maintenance records in the same time period. A statistical study is then used to examine the similarity between the predicted data and the recorded data.INTRODUCTION Today maintenance costs of sophisticated engineering systems are so high that maintainability draws great attention from scientific researchers to operations managers. For instance, a study by [1] shows that American manufacturers spend more than 300 billion U.S. dollars on plant maintenance and operations. Therefore it is understandable that the main objectives of applying maintainability principles to engineering systems are to reduce projected maintenance costs, to use maintainability data to estimate system or equipment availability/unavailability and to determine labor-hours and other related resources needed to perform the projected maintenance. A system with better maintainability would inherently provide the benefit of lower maintenance costs, less time to recover with lower breakdown frequency (design for simplicity), less complexity of maintenance tasks and relatively reduced man-hours [2]. Most maintainability functions use the Time To Repair (TTR) as the independent variable. It is common to use probabilistic or statistical concepts to define a maintainability function, for example, the probability density function. Let t denote the time. Assuming a repair starts at t=0 and completes at time T, the maintainability can be mathematically defined [3] as in Equation (1)."

Jan 1, 2015

By Erika Moonin, Jim Nickerson, Claudio Cimiotti, Roberto Bono

"In response to the severe drought on the Colorado River basin and in order to preserve existing water capacity to the Las Vegas Valley, the Southern Nevada Water Authority contracted a new deep-water intake (Intake No. 3) located in Lake Mead. The current project (Contract No. 070F-01-C1) includes 5 km (3 miles) of tunnel with very difficult geological conditions and a 200- m (650-ft) deep shaft and marine works. This paper will present the current status of the design-build contract being constructed by Vegas Tunnel Constructors and the challenges and problems faced and the innovative solutions developed to handle the difficult conditions encountered during tunneling with up to 15 bars of pressure.ProjectbackgroundThe Las Vegas Valley receives the majority of its water from Lake Mead, which is located approximately 30 km (20 miles) east of the Las Vegas, NV metropolitan area. Due to the severe drought that has hit the southwest region of the United States, the water level in Lake Mead has receded from its high water level of 372 m (1,221 ft) above mean sea level (amsl) to a low of 330 m (1,076 ft) amsl in June 2015. Should the lake level continue to fall, at elevation 320 m (1,050 ft) amsl, the current water intakes will not be able to draw enough water to meet the needs of the local area. The risk of losing water capacity has prompted the construction of a new deeper intake. Not only is the new Intake No. 3 situated at a lower elevation in the lake at 262 m (860 ft) amsl, the new Intake No. 3 is also located to draw better quality (Fig. 1).Project challengesThe project has had several difficult challenges to overcome:• The work consisted of a 1.2 kt (1,300 st) structure constructed on a barge and lowered 100 m (330 ft) into Lake Mead anchored with 9,200 m3 (12,200 cu yd) of tremie concrete.• The drill-and-blast starter tunnel was impacted by three inflow events, resulting in a one-year project delay.• One of the main challenges was selecting the tunnel boring machine (TBM) and excavating the tunnel with expected hydraulic head pressure of as much as 17 bar (16 bar was the highest pressure recorded during the drive), crossing faulted areas, low rock cover and the risk of tunnel instability due to direct connection with the lake.• Extensive pre-excavation grouting with a constant head pressure ranging from 12 bar to 15 bar.• Structural repair of the cutterhead in difficult hydrogeological conditions [water inflow of approx. 800 m3/hr (4,000 gpm)].• Complete repair of the cascade sealing system for the main bearing and two replacements of the pinion bearings.• The TBM approach to the intake structure."

Jan 1, 2015

By Schmitz Stefan, Stephan Jee-Sun

"Due to the reunion of Western and Eastern Germany in the late 80’s, a multitude of infrastructure projects had to be executed. A good portion of these projects required improvement of the motorway system. In the southern region of Leipzig, in the eastern part of Germany, it was required to connect two existing motorways. Parts of the new motorway pass old strip mining areas. These strip mining areas consist of up to 70m thick backfill material. Especially the upper 20m are very inhomogeneous soil material with a very low bearing capacity. In order to increase the bearing capacity, to decrease the differential settlements and to homogenize the soil parameters, soil improvement using sand-gravel columns was required. Bauer Spezialtiefbau GmbH executed the installation of approx. 711,000 linear meters of columns with a length from 5 m to 25 m. For the project, 11 rigs with frame leads up to 40m were used to install the 43,000 columns with a diameter of 0.8m in 27 weeks.1. INTRODUCTION1.1 Site LocationThe construction site is located in the south-eastern part of Germany, in the south west of the city Leipzig.The area to be treated had a size of approx. 500,000 m² to allow the construction of dam/embankments and a highway bridge.1.2 Required WorkIn addition to the general earthworks and the installation of geogrids and fibre mats, a total amount of more than 710,000 linm of Gravel-Sand Columns with different lengths due to the given soil conditions had to be installed:•nos. 4,206 Columns length 5m ? 21,030 linm•nos. 4,581 Columns length 10m ? 45,810 linm•nos. 10,820 Columns length 15m ? 162,300 linm•nos. 19,634 Columns length 20m ? 392,680 linm•nos. 3,574 Columns length 25m ? 89,350 linmFor the installation of the columns Gravel-Sand with the grain size of 0/32mm was used. The total amount of Material was 580,000mt"

Jan 1, 2015

By Stefan Larsson, Jan Ekström, Jennie Kock-Larsen, Håkan Garin

"This paper describes the testing procedure (or protocols) for quality control of dry deep mixing columns in a major ground improvement project carried out in Sweden. Quality control was mainly based on column penetration tests performed at different stages in the project and on two occasions after installation. In the paper, the results from the tests are compared with tests on the unimproved clay. As expected, the results show that the correlation between undrained shear strength in the columns and in the unimproved soft soil depends mainly on the in-situ stress. However, the correlation probably depends on when the tests were performed after mixing. When the influence of the in-situ stress was excluded from the analysis, no significant correlation could be identified. This means that the undrained shear strength in the columns and in the unimproved soft can be considered to be uncorrelated when the strengths and the corresponding variability are evaluated with depth from groups of tests.INTRODUCTIONQuality control and quality assessment of deep mixing (QC/QA) constitute a key component in verification of the limit state design. Due to the complex mixing process and varying geological conditions, it is normally not possible to sufficiently assess the strength and deformation properties in advance. In Sweden, the most commonly used QC/QA method for verification of the limit state is the column penetration test (Axelsson and Larsson 2003; Bergman et al. 2013). The method works well but is time-consuming and requires many tests since property variability is normally high. The column penetration test can be used to assess the undrained shear strength Cu,col. However, it is not clear how the strength correlates to the undrained shear strength of the unimproved soil Cu,soil. There are common factors such as the in-situ stress state and the natural water content, which makes a positive correlation probable, i.e. as Cu,soil decreases, Cu,col also decreases and vice versa. The unimproved soil has a natural spatial variability, but it is not known if the improved soil follows the same variation. The mixing process has a substantial influence on the strength variability and may supersede the influence of other factors. However, if a sufficiently good correlation exists between Cu,col and Cu,soil, information from the geotechnical ground investigations can be used in the design and planning of QC/QA of deep mixing in a more stringent manner. Information about the correlation is also essential in reliability based design, where a strong positive correlation may have a negative influence on reliability. However, as discussed by Al-Naqshabandy and Larsson (2013), this correlation may be weak or insignificant for a representative failure domain where the mixing process may have a dominant influence on the strength variability. It is thus of interest to assess the correlation."

Jan 1, 2015

By J. García, B. Arango, F. Calderón, O. J. Restrepo-Baena, A. Carreno, L. Rojas-Mendoza, J. Pérez, E. Bedoya

"Tungsten extraction is a subject of global interest due to is properties. These properties, such as its high melting point, have contributed to the development of metallurgical extraction processes that can be adapted to the particular chemical composition and mineralogy of the ore. In Colombia there is a research deficit in tungsten related areas, and especially with regard to its extractive metallurgy. In this study the physical, chemical and mineralogical characterization of a sample were performed. Subsequently, crushing and grinding were employed to reduce the material to a more convenient size, making it suitable for further concentration and metallurgical processes. Through physical concentration techniques it was obtained a concentrated ranging between 60 -70 % of WO3 content.INTRODUCTION Tungsten is a metal of great economic importance due to its excellent properties such as high density and extraordinary melting point 3422°C), which is indeed the highest of all the elements. Tungsten is primarily used in metal alloys, manufacture of special steels, coatings and catalysts; products of interest to both international and national industry. However; given that the use and economic value is determined by the percentage of tungsten in the mineral, particle size and chemical associations, it becomes essential to properly characterize the mineral to further define possible metallurgical extraction routes. The metallurgical processes for minerals enriched in tungsten may vary depending on location and the genesis of the ore body, which means that for each ore a particular set of operating conditions must be determined. This is important since process standardization can lead to misuse of the mineral resource. However, in Colombia there is a research deficit as it relates to minerals enriched in tungsten and to its extractive metallurgy. Then, there is a need to conduct studies that can lead to a better understanding of the ore, and to develop extraction processes for the metal of interest. EXPERIMENTAL A state of the art review was made in order to gain insights of the tungsten metallurgical process. Comminution was necessary with the aim to reduce the sample size; therefore the sample was taken into crushing and grinding stages. Concentration techniques such as magnetic separation, gravity and / or electrostatic were also applied. Physical, chemical and mineralogical characterization were performed by using polished sections, grain size determination, X-Ray Fluorescence (XRF) and X-ray diffraction (XRD) techniques."

Jan 1, 2015

By Félix Lewandowsky

El presente texto describe las actividades para corregir los pasivos ambientales heredados y asumidos bajo responsabilidad de la Compañía Minera Colquirrumi S.A. Para ello, se elaboró un plan de cierre de los cuatro depósitos de los relaves de Hualgayoc donde se busca mostrar los criterios utilizados, los estudios de ingeniería y la forma cómo se ejecutaron las obras de cierre definitivas de los depósitos de relaves.

Jan 1, 2015

By Yi Yang, Mark Zoback

"We report laboratory studies of the time-dependent deformation of core samples from four different formations in the Williston Basin - the Lodgepole formation, the Middle and Lower Bakken formations and Three Forks formation. The laboratory tests reveal varying amounts of viscoplastic deformation in response to applied differential stress. The time-dependent deformation is generally greater in rocks with higher clay and organic content, and can be described by a power-law function. Because the magnitude of the creep strain is linearly proportional to the applied differential stress, we can utilize viscoelastic theory and geophysical logs to estimate the degree to which tectonic stress is affected by viscoplastic stress relaxation. We suggest that viscoplastic stress relaxation results in the Upper and Lower Bakken Formations act as frac barriers during hydraulic fracture stimulation in the Middle Bakken, but the Lodgepole and the Three Forks Formations are not frac barriers.INTRODUCTIONHorizontal drilling and multi-stage hydraulic fracturing in shale reservoirs are critical for successful exploitation of ultra-low permeability shale gas, tight gas and shale oil reservoirs. Characterization of the mechanical properties of the reservoir rocks is essential to understanding the behavior of rocks during drilling and completion. Previous laboratory studies have shown that the timedependent deformation in clay-rich shales can be characterized as linear/viscoelastic deformation (Chang et al., 1997; Hagin and Zoback, 2004a, b; Sone and Zoback, 2013b, 2013c). Sone and Zoback (2013c) showed that laboratory measurements of time-dependent deformation in various gas shale reservoir rocks, and demonstrated that the viscoplastic deformation of these rocks can be characterized by a power-law function. They interpreted the results in the framework of linear viscoelastic theory to quantitatively assess the geomechanical effect of viscous time-dependent deformation over engineering and geological time scales. (Sone and Zoback, 2014) further extended the theory and proposed a viscous relaxation model that can be applied to predict the continuous differential stress magnitude using the geophysical logs. They tested the validity of their model by comparing the stress prediction with the occurrence of drilling induced tensile fractures (DITFs) and the vertical hydraulic fracture penetration observed from microseismicity."

Jan 1, 2015

By P. R. La Pointe, J. Clark

"Studies have shown that the roof in coal mines is nearly twice as likely to fail at intersections as at entries due to enlarged roof spans, stress redistribution and other factors. However, the relative stability of intersections in a mine varies, and an improved understanding of what factors impact roof instability can lead to efficient, proactive mining practices that both enhance stability and mining efficiency.A study was undertaken at an underground longwall coal mine to develop a model to predict the stability at the intersections of entries and cross-cuts. The statistical analyses relied upon observational and measured data regarding the development of tension cracks, seepage, intersection geometry, mining practices, geological attributes and geomechanical factors at 783 intersections. Each intersection was given a NIOSH roof. Common data mining techniques, such as multivariate linear regression, multinomial logistic regression, decision trees and probabilistic neural nets, were considered and evaluated to establish correlations and associations between stability and the other variables. Two of the more successful techniques were Decision Trees and Multinomial Logistic Regression. The analyses showed that a number of factors impacted stability:• Overburden thickness (impact on stress concentration magnitudes)• Initial opening area (impact on stress concentration magnitudes)• Sulfur content (depositional environment & impact of mechanical properties, leaching effects)• Intersection type (impact on stress concentrations)• Gob distance (impact on stress concentrations)• Presence or proximity of a particular sandstone (impact on mechanical properties)• Roof bolt type and diameter (impact on reinforcement)Some factors showed no statistically significant relation to stability. These included:• Total area• Supported areaSeepage was a more problematic variable in assess. Seepage is associated with instability, but it is not clear whether seepage occurs as a consequence of instability, for example, through the creation of tension cracks, or whether the intersection has been excavated where water already exists and has degraded the rock prior to excavation, leading to greater instability.Seepage appears related to the geology of the roof rock mudstones, not the sandstones. Tension cracks in the intersections occur preferentially where the Sulfur content is below 0.9%. The Sulfur may relate to mechanical differences in the roof rock, and where the Sulfur is low, the roof is less stable, there are more tension cracks, and seepage is greater. This suggests that the weaker mudstones may be more prone the development of tension cracks, not because these rocks are more brittle, but possibly weaker.2-way and 3-way intersections appear to have less seepage than 4-way, although very few intersections overall have any seepage. This is similar to the roof stability, in which the 2-way and 3-way are more stable. 2-way and 3-way intersections have fewer-than-expected tension cracks, while 4-way have more than expected. These results suggest that four-way intersections are weaker and more prone to tension crack development, also suggesting that increased seepage results from weaker roof conditions, rather than the converse. Thus seepage appears to be mostly a consequence of instability rather than a cause and is higher where there are 4-way intersections, mudstone geology and external loading factors like depth of cover and proximity to gob that promotes crack development. The study also indicated that a better understanding of the mudrock facies could reduce uncertainty."

Jan 1, 2015

By J. Mizera, J. Zdunek, K. J. Kurzydlowski, A. Dobkowska

This work concerns comparison of corrosion resistance of the aircraft aluminum alloy composed of Al - 2.3%Li - 0.1% Zr. The alloy was hot rolled (HR) from 13 mm to a thickness of 4 mm (e = 2.4) and 1 mm (e = 5.2). Corrosion resistance was investigated by Potentiodynamic Polarization Test. The investigation relied on exposure samples in two different corroding medium: 0.5 M NaCl solution and 0.01 M Na2SO4 solution with added 0.01% of Cl- at room temperature. Furthermore, the microstructure was analyzed using the optical microscope with polarized beam. The hardness was measured on lengthwise profile. It was stated that alloy after the largest deformation (equivalent total strain e = 5.2) is characterized by the best mechanical properties and the best corrosion resistance. The alloys in initial state and after deformation to 4 mm (e = 2.4) are characterized by worse corrosion resistance. It is associated with microstructure and density of dislocation in analyzing material.

Jan 1, 2015

By A. S. Ibrado, D. W. Fuerstenau

"Gold, silver and copper form various complexes with cyanide, of which only the singly charged dicyano form adsorbs appreciably on activated carbon. The adsorption of the dicyano complexes appears to be controlled predominantly by chemical reaction at the surface of a shrinking unreacted core. Metal uptake over time is non-linear, which eliminates control by boundary layer diffusion. The rate of adsorption is not enhanced by a reaction interruption, which suggests the absence of concentration gradients in the pores. Finally, the rate of adsorption increases with decreasing activated carbon size in a manner consistent with the shrinking core model. The results of this investigation accentuate the importance of efficient acid washing of carbon and removing carbon fines from the barren carbon stream. INTRODUCTION With the dwindling reserves of high-grade ores, most of the world’s gold is produced from low-grade ores by cyanide leaching. In the past, leaching was followed by the Merrill-Crowe process, in which gold is precipitated from clarified pregnant solutions by zinc cementation. This process is still being used for high-silver ores, where the cost of carbon stripping becomes prohibitive. For deposits with silver-to-gold ratios of about 4 or less, adsorption on activated carbon would be the usual solution purification step taken. The process simplifies solid-liquid separation and offers a viable solution to preg-robbing organic carbon in some ores. The modern industrial application of carbon adsorption started with the carbon-in-pulp (CIP) process, where carbon adsorption was used mainly as a solution purification step. In 1973, Homestake Mining Company commissioned the first large-scale CIP plant in the U.S.A.1 Later, carbon was added earlier in the circuit to control preg-robbing by adsorbing gold cyanide onto activated carbon as soon as it is dissolved. The scheme is successful because activated carbon is a stronger adsorber than the organic carbon found in preg-robbing ores. This process came to be known as the carbon-in-leach (CIL) process. Numerous research investigations have been performed on the chemistry involved in the CIP process, which at the time of its introduction was not clearly understood. Of these, research on the kinetics of adsorption probably bears the most immediate impact on industrial practice,2,3 where adsorption systems rarely reach equilibrium, if at all, and slight slowdowns in the adsorption rate can translate into significant decreases in revenue. To illustrate this, organic compounds, like flotation reagents, have been known to impair CIP circuits. However, laboratory tests showed that the organic compounds do not significantly affect the adsorption capacity of activated carbon. Rather, the harmful effect may be attributed to a lowered adsorption rate.4,5 Also well known is the faster rate at which fine activated carbon powders reach equilibrium compared to coarse activated carbon, even though the final (equilibrium) amount of material adsorbed per unit weight is the same."

Jan 1, 2015

By H. Huang, Y. Takasaki, R. N. Gow

"The presence of enargite (Cu3AsS4) is problematic in gold processing not only because it is environmentally hazardous due to its arsenic content but also because it is refractory, causing both cyanide and oxygen consumption to increase. Selective leaching and treatment of the arsenic would prove advantageous prior to applying conventional gold leaching methods. The reactivity of enargite samples from Butte in Montana and Quiruvilca in Peru were spectroelectrochemically studied under alkaline conditions – pH range of 8-13 – using Raman spectroscopy and cyclic voltammetry. Raman spectra of the surface were collected during and after potentially cycled voltammograms in order to determine and compare surface species against theoretical EH-pH diagrams constructed from mass-balanced thermodynamic calculations using STABCAL software. Under slightly oxidizing conditions, covellite (CuS) peaks were found in a short matter of time, above ~100mV vs. SHE for pH 9-13, suggesting arsenic leaching specifically occurred. At longer conditioning times, elemental sulfur was observed and tended to passivate the surface. The presence of elemental sulfur suggests that copper was eventually leached from the surface. By operating above pH 12, under slightly reducing conditions near -300mV vs. SHE, arsenic can be selectively leached as thioarsenate (AsS4 3-) or thiosulfate (AsO4 3-) without sulfur formation.IntroductionEnvironmental limitations on the pyrometallurgical processing of ores and concentrates bearing arsenic and other hazardous elements often outweigh those in hydrometallurgical processing, particularly when minerals like enargite (Cu3AsS4) are present. The hydrometallurgical processing of enargite-bearing materials can be broken down into two categories: the co-dissolution of arsenic and copper under acidic conditions, and the selective leaching of arsenic under alkaline conditions. The selective leaching of arsenic would preferably leave behind copperrich sulfide phases, typically chalcocite (Cu2S) and covellite (CuS), which then become more amenable to conventional copper (and gold) processing. Furthermore, selective leaching often employs sulfide (S2-), bisulfide (HS-) or polysulfides (Sx 2-) to first extract the arsenic as AsS4 3- and AsS3 3- (Delfini et al., 2003; Anderson and Twidwell, 2008; Tongamp et al., 2010a,b). However, hypochlorite leaching (Viñals et al., 2003; Curreli et al., 2005; Mihajlovic et al., 2007), ammoniacal leaching (Gajam and Raghavan, 1983), and finegrinding to mechanically activate the enargite surface (Balaz and Achimovicova, 2006) have been investigated to increase the normally slow reaction kinetics. Because gold ores are becoming more refractory due to increasing arsenic contents as a result of enargite, these methods are being examined more closely by the gold-mining industry."

Jan 1, 2015

By Justin Cardwell, Alyson Cartwright

"Grade estimation is the cornerstone of longrange mine planning. Pit designs, metal recovery, mining costs, reserves calculations and reporting are all dependent upon a reliable grade model. If the geology is poorly understood or the interpolation methods and parameters have been haphazardly constructed, then massive financial losses will be the inevitable outcome. Therefore, a properly trained geologist must use all of the appropriate tools available including deposit knowledge and advances in modeling technology to construct the most geostatistically and practically sound long-range block model.Certain deposits, such as the sedimenthosted deposits at Tenke-Fungurume, require an interpolation method that best suits the style of mineralization. In 2014, Hexagon Mining developed a tool in MineSight called dynamic unfolding (MSDU) that has the potential to improve upon previous Euclidean-based interpolation methods. MSDU utilizes the nonstationarity of a folded grade trend to more accurately construct variograms and improve interpolation results based upon a modeled three-dimensional surface.Geology overview. The sediment-hosted Tenke-Fungurume mining district is located in the southeastern part of the Democratic Republic of the Congo (Fig. 1). The rocks within the district are primarily dolomites and shales from the lower half of the Roan Supergroup that were mineralized by ascending pregnant copper and cobalt rich brines within a massive sedimentary basin (Cailteux et al., 2005) (Fig. 2). These oxidized brines likely found a fluid channel in the porous RSC unit. The surrounding rock units provided a redox boundary for copper and cobalt precipitation along organic rich beds, forming a massive stratabound deposit that was later broken up by several subsequent tectonic events (Dewaele et al., 2006)."

Jan 1, 2015

By Manjeet Chowdhry, Qingxia Liu, Phillip Choi, Zhenghe Xu

Computational chemistry methods, such as density functional theory (DFT), are powerful tools to quantify reagent-mineral interactions encountered in sulphide mineral flotation. A quantitative relationship between theoretically calculated parameters based on chemical structure of collectors and their reactivity with different metals/minerals can provide valuable insights for design and development of more powerful and tailor-made reagents offering enhanced metal/mineral selectivity. DFT calculations at B3LYP/6-311++G(3df,3pd) level were employed to elucidate the reactivity of neutral sulphide collector reagents, including thionocarbamates (TC), thioureas (TU), xanthogen-formates (XF), dialkyldithiocarbamates (DTC) and dialkyltrithiocarbonates (TTC) with different heavy metal ions (Cu2+, Zn2+ and Pb2+) in solution. The extent of delocalization of lone pair electrons of heteroatoms (attached directly to C in C=S) over C=S group was found to be the dominant factor in determining the collector’s reactivity. Order of reactivity was established as: TU > TC > XF > DTC > TTC. All the collectors showed superior affinity towards copper followed by lead. Unidentate binding was observed through sulphur atom except for xanthogen-formate for which bidentate binding mode was observed. Effect of nature of substituent groups at N and/or O atom on reactivity of thionocarbamate and thiourea was also investigated. The results obtained through DFT calculations are consistent with the experimental data reported in literature.

Jan 1, 2015

By N. Behnood

"This paper describes how material selection, quality assurance, and failure investigation play important roles in the efficiency and safety of mining and metallurgical operations.INTRODUCTION Material selection, quality assurance, and failure investigation are all complementary elements of materials engineering in the application of materials technology for failure prevention. Based on commodity price increase of 300% between 2002 to 2013 [1] and increased cost ofcapital projects and operation, equipment failure, which in some cases causes complete shutdown of the operation, becomes a vital importance in mining and metallurgical plants. The following sections present a number of examples from many failure cases experienced by the author during his three decades of work as a materials engineer in the mining industry."

Jan 1, 2015