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By C. Han, S. J. Zhou, Y. B. Shen, D. Z. Wei, P. Fang

"Collecting property of two hydroxamic acid collectors have different type of nonpolar structure to hemimorphite has been comparatively studied via monomineral flotation test, and the reason causes different collecting performance has been discussed from the view of relationship between molecular structure and collecting property. The flotation tests results show that C5-9 hydroxamic acid has an unbranched linear alkyl nonpolar group shows better collecting property to hemimorphite than cyclohexyl hydroxamic acid which has a naphthenic nonpolar group. FTIR detecting results show that the adsorption type of collector adsorbed on hemimorphite surface is chemical adsorption. Calculation results of polar group’s geometric structure parameters, polar group’s electron density distribution, octanol-water partition coefficient (logP) and molecular frontier orbital energy show that the key factor caused different collecting property of two collectors to hemimorphite is the logP; unbranched linear alkyl nonpolar group is more conducive than naphthenic nonpolar group to make hemimorphite particle more hydrophobic.INTRODUCTIONZinc-bearing mineral recovered from lead-zinc ores is the main source that people can obtain zinc resource from nature. However, natural sulfide ores are currently getting depleted steadily for the primary zinc source. In order to satisfy the future demand of zinc resource, there is an obvious recognition that the recovery of zinc oxidized minerals from the ores is a crucial alternative (Hosseini & Forssberg, 2007; Navidi Kashani & Rashchi, 2008).But the fact that can’t be ignored is the flotation of zinc oxidized minerals is much more difficult than that of zinc sulfide minerals, which is mainly due to the flotation characteristics of these zinc oxidized minerals such as lower selectivity and higher reagent consumption, as well as complex and variety of lead-zinc ores. Presently, there have been many various beneficiation technologies used for recovering zinc oxidized minerals and dealing with ores for recovering metallic zinc such as flotation and hydrometallurgy (Abkhoshk, Jorjani, Al-Harahsheh, Rashchi, & Naazeri, 2014; Önal et al., 2005). But from an overall perspective, flotation is the most common method used for the beneficiation of zinc oxidized minerals, and there have been extensive investigations conducted on the flotation of zinc oxide ores (Ejtemaei, Gharabaghi, & Irannajad, 2014). Until now, the most well-known method used commercially for the flotation of zinc oxidized minerals is sulfidization with sodium sulfide and flotation with a cationic collector of amines containing from 8 to 18 carbon atoms. However, a major problem for this method is the large amount of fines and slime results in the increase of reagent consumption and promotes the phenomenon of slime-coating. For preclude this negative effect, the de-sliming and processing optimization is indispensible (Peres, Borges, & Galery, 1994; Salum, de Araujo, & Peres, 1992)."

Jan 1, 2016

"Liberation is a key requirement for efficient separation in mineral processing. As a consequence of this an understanding of the inherent textural features of an ore is no longer possible since during the process of liberation, texture is destroyed. Knowledge of key textural features, such as mineral grain size and distribution, prior to breakage processes provides the opportunity to understand the textural drivers for ore hardness. Modern characterisation methods, including automated SEM-based techniques, provide the possibility of measuring mineral characteristics at a range of scales. This paper discusses how textural features of two different ore types in a porphyry copper deposit can be measured and interpreted at a number of scales. Standard breakage tests conducted on the ores indicate that one of the ores can be characterised as hard and the other as soft. The impact of mineral grain size and the presence and scale of vein type structures in the two ores have been used to determine the extent to which these features influence ore hardness.INTRODUCTIONIn order to effectively convert ore into metal, knowledge of both the processing stages and the characteristics of the ore are essential. Prior to the advent of technologies that enabled the fundamental understanding of the sub-process at each stage of processing and the measurement of appropriate ore properties the most effective way to understand how an ore would respond to a process was to put it through that process, for example the way to determine how an ore would break was to first break it. Existing comminution models seek to predict the size distribution of rock fragments as the result of applied energy based on knowledge of the rock strength. It is common for these models to consider the rock as homogeneous and despite providing important data for the design and optimisation of industrial comminution circuits these models are only applicable within a narrow range of operation. In order for reliable predictive models to be developed that account for the inherent ore characteristics, a step change is required in the type of measurements that are carried out to characterise an ore and the type of data that is extracted and used as model inputs."

Jan 1, 2016

By Alessandro Boscaro, Daniele Martinelli, Cristina Gabriela Oñate Salazar, Daniele Peila, Carmine Todaro

"The wear phenomenon in TBM machines is not a simple issue, as many parameters are playing an important role on the consumption of the tools during a tunnel excavation. The action of the wear due to the contact with the soil can occur on the excavation tools, on the cutterhead, in the excavating chamber and on the screw conveyor. The test developed at the Laboratory “Tunnelling and Underground Space Center” of the Politecnico di Torino is aimed to reproduce the interaction between the tools and the excavated material, simulating the excavation conditions in terms of soil conditioning and water content. The test, which is not standardized, is studied to evaluate the wear in a global point of view. The present work starts by testing the influence of the use of chemical agents during the conditioning phase on the drop of the wear phenomenon, in terms of metal weight loss. 1. INTRODUCTION The wear phenomenon of the excavation tools used in TBM tunneling machines is playing recently a major role in the design stage of full-section tunnels in both soils and rocks. Concerning EPB excavation technology, the main issue regarding productivity is the wear of its components (Peila et al.,2012), which increases the so called dead time in the whole process. The friction generated between the components and the ground causes the consumption of the tools and other metallic components in contact with the ground, described as primary and secondary wear by Nielsen et al. (2006a). This leads to downtime, with risky and complicated maintenance operations (Peila and Schulkins, 2009), as occurred in recent tunneling works in Liguria (Italy). The study of this argument in granular soils is very delicate, as it encloses not only the properties of the excavation tools, but also the characteristics of the ground to be excavated (hardness, mineralogy composition, shape and dimension of the particles and moisture content). The penetration mechanism is based on the scraping of the ground, by mean of cutting tools, with its consequent consumption. Concerning the rocks, the excavation principle is characterized by crushing the rock mass matrix by applying high compressive stresses through cutting disks. In such a way, to avoid frequent downtimes and their consequent economic losses, it is very important to study this subject and therefore understand and forecast the durability of the components, in order to try to maximize the productivity of the machine by reducing the frequency of maintenance stoppings."

Jan 1, 2016

By Jose R. Hernandez-Aguilar

"This paper revisits data from previous studies (Hernandez-Aguilar, 2010, 2011) to better understand the link between metallurgical performance and bubble size (Db) in the collection (pulp) zone of full-scale flotation systems. To obtain conclusive evidence exclusively related to the collection zone, the experiments were designed in those studies to control both the bubble generation method and the influence of the froth zone on the overall metallurgical performance in industrial and pilot-scale flotation columns. The results showed that generating small (1 mm) bubbles had a significantly higher beneficial effect on the recovery of coarse (> 75 µm) particles compared to the effect on fine (< 16 µm) particles. It was observed that, under certain practical conditions, the recovery of liberated coarse particles was close to zero, but could be recovered almost completely by reducing bubble size. The evidence revealed an apparent inconsistency of the so-called “k–PSb” model: at constant froth recovery, increasing Sb did not always result in higher recovery, as the model predicts. Overall, the evidence showed that it was not the Sb but the bubble size that proved to be a more reliable link to metallurgical performance. Only under highly suboptimal bubble size conditions (Db = 3 mm) did the froth zone seem to play a role, possibly reflecting an effect of pulp-zone bubble size on froth stability. However, for the most part, both the bubble generation method and the froth zone played inconsequential roles. An empirical model that better describes the kinetics of particle collection is proposed.INTRODUCTIONStudies showing the link between metallurgical performance and the interactions of bubbles and particles in the collection (pulp) zone of industrial flotation systems are scarce. A common belief among a number of mineral processing practitioners considers that “small” bubbles are favourable to recover “small” particles and that, conversely, “larger” bubbles are more efficient at floating “coarse” particles. However, perceptions like this are often substantiated by anecdotal evidence rather than by rigorous data analysis. What is the optimum bubble size for a particular case, how operating conditions can be adjusted to control a target bubble size, and whether the bubble size needs to be changed in the first place to optimize the operation of a flotation plant are questions that usually remain without solid answers.The studies reported by Hernandez-Aguilar (2010, 2011) were, in part, performed to test the effect of bubble size on flotation response and, thus, help address some of the above questions. The focus of the studies was to optimize the metallurgical grade-recovery performance of the Cu-Mo separation plant at Teck’s Highland Valley Copper mine (HVC). The outcome was compelling and significantly valuable: consolidated production data showed that in 2008 – the year when the recommendations from the studies started to be implemented – the Mo plant recovery was 89%, and gradually increased to 92% and 94% in 2009 and 2010, respectively, along with an increase in Mo concentrate grade. (Note: these production figures were not included in the publications quoted above; however, they were shown during an oral presentation at the 43rd Annual Meeting of the Canadian Mineral Processors in 2011.)"

Jan 1, 2016

By W. Newcomen, G. Dick

"Effective management and mitigation of pit slope instability in open pit mines begins with a comprehensive slope monitoring programme. The ability to differentiate between non-critical pit wall movements due to rebound or relaxation of the excavated slopes and movements that may be indicative of slope failure is important for maintaining a safe working environment and maximizing production. Slope failure prediction methods using velocity, acceleration, and strain criteria have been introduced and put into practice over the past few decades. Forty-eight slope failures with surface monitoring data are presented and assessed using the strain-based failure prediction approach, with consideration of the quality of the rock mass and the potential failure mechanism. The results indicate that the strain-based approach can be used to provide general guidance regarding strain thresholds for pit walls for a variety of failure modes in diverse geological environments. The advantages and potential drawbacks of the strain-based and other slope failure prediction methods are discussed. The importance of implementing a pit slope monitoring and performance evaluation system early in mine development is also emphasized. IntroductionThe successful prediction of the Manefay Slide pit slope failure at Bingham Canyon at 9:30 am on 10 April 2013 (Engineering and Mining Journal, 2014) highlighted the importance of having a comprehensive slope monitoring system that provides an accurate prediction of the time of failure of an open pit slope. Using most of the geotechnical monitoring tools available, the time of the failure was predicted within hours and equipment and personnel were evacuated from the pit well in advance of the failure. From a time to slope failure perspective, the monitoring system in place was a success.There are two general groups interested in monitoring pit walls, with slightly different objectives in mind when the monitoring system is being set up. There are those at the mine site that have to implement the pit slope design, monitoring protocols, and the action response plans, and there are those designing the slopes (often consultants) who regularly visit the mine but may not be responsible for the day-to-day activities. was a success.There are two general groups interested in monitoring pit walls, with slightly different objectives in mind when the monitoring system is being set up. There are those at the mine site that have to implement the pit slope design, monitoring protocols, and the action response plans, and there are those designing the slopes (often consultants) who regularly visit the mine but may not be responsible for the day-to-day activities."

Jan 1, 2016

By Z. Leng

"After detonation of the explosive, the final blast-induced damage area around the blast-hole falls into three categories, namely crushed zone, fractured zone, and elastic deformation zone. This paper presents a modified model to calculate the size of crushed zone around a blast-hole in drill-and-blast, with the hoop compressive stress and cavity expansion effect taken into account. The material in the crushed zone was assumed to be a granular medium without cohesion, but with internal friction. On this basis, the formula for crushing zone radius was derived. The proposed approach was verified with tests reported in the literature and the simulated results from SPH-FEM coupled models. A full statistical analysis was also carried out, and the predicted values were found to be in better agreement with the test results compared with other models. A sensitivity analysis of the modified model showed that the size of the blast-induced damage area is mainly affected by the following factors: rock mass properties, in situ stress, and borehole pressure. In particular, the roles of borehole pressure and in situ stress are discussed. Finally, suggestions are made on how the size of the crushing zones can be decreased. IntroductionOver the past decades, drill-and-blast has become the most commonly used technology in rock excavation. It is well known that in rock mass fragmentation with explosives, the annular rocks around the blast-hole are converted into fines. The formation of these fines consumes a significant part of the energy of the detonation, which in general is ignored in the determination of the efficiency of detonation (Glatolenkov and Ivanov, 1992; Furtney et al., 2012). Many studies show that only 20–30% of the total explosive energy is effectively used in fragmenting the rock, and up to 50% of the energy generated by conventional charges is wasted in overcrushing of the crushed zone and the inner part of the fractured zone (Ouchterlony et al., 2004; Sanchidrian et al., 2007). How to control the crushed zone to enhance the effective utilization of explosive energy, reducing the unit explosive consumption and the engineering cost, is therefore of great significance."

Jan 1, 2016

By Pedro C. Carneiro, Luiz G. I. Maciel

"This article presents data of advance and excavation rates in tunnelling works, and how theseactivities interact with the duration and cost of a contract. These key parameters, after analysis andsynthesis, will be used in coming works to ensure the evolution and adaptation of the method created by the Norwegian University of Science and Technology - the NTNU Method - to Brazilianconditions, which will be reflected in the duration and cost of underground drill and blast tunnellingworks."

Jan 1, 2016

By C. Clark, J. Seymour, D. Benton

"National Institute for Occupational Safety and Health NIOSH is conducting research on jackleg use and related accidents in underground metal mines. This paper provides an analysis and overview of jackleg drill usage, accidents, operational characteristics, and alternatives, based on information from injury reports, legacy research, stakeholder input, and published literature. Jackleg drills are involved in more ground fall accidents in underground metal mines than any other drill. Jackleg-related injuries are most prevalent at the face in the course of installing initial ground support. Alternatives to jacklegs for drilling and bolting under incomplete support in narrow underground openings are not yet available. Small mechanized bolting equipment needs to be developed to address jackleg-related accidents and improve safety at mines where jacklegs are being used. JACKLEG DRILL Description The term “jackleg drill” is a generic name for a class of handheld, rotary, percussion rock drills that are equipped with an attached reaction leg to provide stability and thrust for the drill (Figure 1). All of the drill and leg controls are located near the operator’s handle at the rear of the head portion of the drill. Jacklegs are classified according to the bore size of their pneumatic pistons which normally range from 6.03 to 8.26 cm (2.375 to 3.25 in) [Kurt, 1982; Clark, 2012]. Jacklegs typically weigh 460 N (103 lbs), but their weight can approach 535 N (120 lbs) after they are fitted for operation with drill steel and air and water hoses [McKibbin and Clark, 2001]. In underground mines, jackleg drills are commonly used to drill 3.8-cm (1.5-in) diameter holes 1.83 m (6 ft) deep in rock. Application The jackleg drill is primarily used in underground mines when the size of the ore body, the ground conditions, or the mining method do not permit large openings to be mined using mechanized equipment (e.g., narrow vein mining). Jacklegs are used to drill blast-holes for explosives and also holes for installing ground support. These versatile drills are used in nearly all phases of mining including exploration, development, production, and maintenance [Kurt, 1982; Williams et al., 2007; Chen and McKinnon, 2012]. The jackleg is used to drill holes in rock using drill bits attached to hollow steel bars called drill steels (rotary percussion drilling). After the hole is drilled, the jackleg can be used to install different types of ground support components, depending on the ground conditions and the specific ground support measures that are needed. For example, the jackleg can be used to install expansion-anchor rockbolts or resin-grouted rockbolts using the drill’s rotary-motion feature. On the other hand, the jackleg can also be used to install friction-type Split-Set™ rockbolts using the drill’s percussion (hammer-motion) feature. As shown in Figure 1, various washer-like bearing plates can be installed along with these bolts to provide additional ground support and to help secure surface control products, such as wire mesh and shotcrete that are in turn used to retain small, loose material between the bolts [Clark, 2012]."

Jan 1, 2016

By T. A. Chepushtanova, I. U. Motovilov, V. A. Luganov, G. D. Guseynova

"Kazakhstan has significant reserves of oxidized nickel ore with low nickel content. Processing of such ores is effective via pyrometallurgical technologies such as smelting to ferronickel or matte with consecutive extraction of metals from melting products. There are also many options for direct hydrometallurgical processing. However, they do not provide high nickel recovery.We studied extraction of nickel and cobalt by using combined technology of low-grade ore processing from the Shevchenko Kazakhstan deposit, which includes smelting to poor matte followed by hydrometallurgical processing of the matte. The nickel content in the initial ore was 0.75–0.9%. Pyrite concentrate of Sokolov-Sarybai Kazakhstan deposit containing 0.17% cobalt and 0.06% nickel had been used as a sulphidizer at smelting.As a result of the study, we were able to extract up to 98% of the nickel and up to 80% of the available cobalt. Obtained matte contained 3.1% nickel, 0.29% cobalt, 71.6% iron and 24.3% sulfur. Matte leaching was carried out by hydrochloric acid. The iron content in the pregnant solution was 170–185 g/dm3. Nickel and cobalt precipitation from the pregnant solution was carried out by hydrogen sulfide. Initial matte or cast iron was used as neutralizers during the process. Practically complete precipitation of nickel was achieved at 3–5% excess of neutralizer at 333–343°K in 4 hours; up to 95% of cobalt precipitation was achieved in 50% excess of neutralizer at 363°K in 8 hours. The purified solution contained 200–600 mg/dm3 of nickel, 80-100 mg/dm3of cobalt and 175–185 g/dm3 of iron. The purified solution allows to obtain iron oxides by high-temperature hydrolysis, and to regenerate hydrochloric acid.As a result of non-ferrous metals precipitation we obtained sulfide concentrate with concentration of Ni up to 25% and concentration of Co up to 5.5%. The technology is recommended for semi-industrial testing."

Jan 1, 2016

By Liu Yulin, Zhao Yi, Tan Qi, Liu Lei

"Hydrotalcite is one kind of layered double hydroxides, and has special crystal chemical characteristics. Due to its good thermal stability, hydrotalcite used as the PVC heat stablier has attracted scientists’ attention. In this study, nano-hydrotalcite was synthesized by the method of mechanochemistry/crystallization, using brucite, Al(OH)3 and Na2CO3 as raw materials, and added into PVC to investigate the effect of hydrotalcite on thermal stability of composites. The synthesis mechanism was suggested by virtue of XRD, FE-SEM, FT-IR. It has been indicated that at the first of dry milling process, the parical sizes of brucite and Al(OH)3 decrease, while specific surface areas of them increase by the action of mechanical force, until produced amorphous particles. In the process of wet milling, metal ions in the amorphous body, which has high surface energy, can easily react with H2O, and produce the precursor of Mg6Al2(OH)18•4.5H2O, which has the same crystal structure as hydrotalcite. Under the hydrothermal condition, anions of OH- in the interlamination of precursor are exchanged by CO32- in the solution and nano-hydrotalcite is generated at last. The thermal stability was characterized by Congo red method. The results have revealed that hydrotalcite is one kind of long-term heat stabilizer, and residual stability time increase with the rise of added hydrotalcite amounts.INTRODUCTIONHydrotalcite, one kind of anionic clays, has been attracted a great interest for researchers because of their unexpected physical and chemical properties. The general formula is Mg6Al2(OH)16CO3·4H2O, where Mg2+ and Al3+ occupy octahedral positions in the brucite-like layers, and CO32- is an interlayer anion (Hoyo, 2007). Hydrotalcite is widely used in the fields of chemical engineering, materials engineering, environmental protection, medicine, and so forth, owing to its unique capability of adsorbability, ion exchange and thermal stability (Rozov, Berner, & Taviot-Gueho, 2010; Iwasaki, Yoshii, & Nakamura, 2012; Ay, Zümreoglu-Karan, & Temel, 2011; Cavani, Trifiro, & Vaccari, 1991; Li & Duan, 2005; Lin, Wang, & Evans, 2006). As a result, the study on synthesis and application of hydrotalcite has received considerable attentions."

Jan 1, 2016

By H. Huang, R. N. Gow

"EH-pH diagrams are useful tools in understanding how mineral surfaces react in solution and particularly how aqueous conditions can be changed to enhance mineral leaching processes. Successful application of these diagrams, however, requires that several considerations be kept in mind to prevent what had been termed as “gross errors” in their calculation and use. In this paper, the aqueous Cu-S system is used as the basis for explaining the mass-balanced method of calculating EH-pH diagrams with the STABCAL thermodynamic equilibrium software. A breakdown of the Gibbs’ Phase Rule and how it is used in STABCAL to modify the diagrams is included. The methodology was applied to the aqueous Cu-As-S system, and resulting diagrams were compared against examples of those generated using the predominant-ion method. The complexity of such diagrams increases with every additional component, and competition between species becomes more apparent, as can be seen by curvature in the resulting mass-balanced diagrams. The complete diagram for enargite (Cu3AsS4) is shown. It compares well with spectroelectrochemical measurements from Raman spectroscopy and cyclic voltammetry studies.IntroductionInnovation in the field of processing arsenicbearing copper ores has been of particular interest. Copper arsenic sulfosalt minerals such as enargite (Cu3AsS4) and tennanite (Cu12As4S13) are now frequently prevalent in ore bodies as the oxide and easily leachable sulfides become harder to find. These minerals, unless pretreated somehow, concentrate in copper sulfide flotation processes, in turn concentrating the arsenic levels. Increasing environmental restrictions on arsenic content for smelters makes the hydrometallurgical processing of these concentrates more favorable. While enargite is considered one of the more refractory copper sulfides, more so than chalcopyrite (CuFeS2), there are still several methods, both industrially proven and in development, that are capable of processing these ore types. Alkaline sulfide leaching can be used as a pretreatment method to solubilize arsenic selectively (Delfini et al., 2003; Anderson and Twidwell, 2008; Tongamp, Takasaki and Shibayama, 2010a, 2010b), or the entire metal content can be leached using acid-type leaches such as acidified ferric sulfate (Dutrizac, 1981; Hackl et al., 1995; Klauber, 2008), or the chloride assisted, CESL (McDonald and Muir, 2007) or nitrogen species catalyzed (Anderson, 2003) processes can be used.As development of these leaching technologies proceed, it is also important to develop an understanding of the mineral thermodynamics. To date, there are numerous studies on the Cu-Fe-S-H2O system, particularly as it relates to chalcopyrite leaching, yet few studies have done on the Cu-As-S-H2O system. Computer-generated EH-pH diagrams have been employed to illustrate the importance of thermodynamic calculations in providing insight into such a system."

Jan 1, 2016

By John A. Herbst, Gerald H. Luttrell, Jaisen N. Kohmuench, Aaron Noble, Michael J. Mankosa

The HydroFloat TM is an innovative fluidized-bed separator that can substantially increase the upper particle size that can be successfully treated by flotation. Recent studies conducted using laboratory, bench-scale and pilot-scale equipment indicate that this technology can be used to float coarse sulfide middlings that cannot be recovered by conventional flotation machines. Recent data collected from pilotscale tests conducted at a base metal concentrator indicate that this technology can float middlings particles as large as 850 microns in diameter containing as little as 1% exposed hydrophobic mineral. As such, the crossover of this technology into the base metals industry has the potential to substantially reduce grinding costs and increase concentrator recovery/capacity through the use of split-feed circuitry. The split-feed concept, which is often used for upgrading industrial minerals, involves segregation of the feed into more than one size class followed by subsequent upgrading using mills/separators/reagents specifically optimized for each size class. In this article, a split-feed circuit is described that utilizes two stages of classifying cyclones in conjunction with the HydroFloat_ separator. The circuit is designed to recover, recycle and regrind coarse middlings containing small amounts of valuable mineral while simultaneously rejecting coarse well-liberated siliceous gangue so that mill throughput can be increased. Simulation data conducted using well-known process models suggest that this approach can increase existing primary mill capacity by up to 25% with only modest investments in new classifying and flotation equipment.

Jan 1, 2016

By V

"Recent regulations, as well as a general aversion to central dust collectors within the Powder River Basin Coal user’s community, have created a need for an alternate method for eliminating airborne dust. This paper addresses the capital expenditure as well as the cost of ownership of an integrated point source air cleaning system in comparison to a central collection system. This assessment was conducted by comparing the cost to purchase and operate a central dust collection system and integrated air cleaner system on a typical multiple transfer point application. The central dust collector consists of a negative pressure blower, a series of filter bags, a collection hopper, a screw conveyor to place collected material back into the material stream, and a series of ducts to pull air and dust from individual pickup points. The point specific integrated air cleaners consists of a negative pressure blower to pull dust and air from an application point through a bag-less filter media located at the application point. The agglomerated material is then redeposited into the material stream at point of use without the need for ducting or a central material hopper. The assessment yielded a 54% reduction in capital expenditure and a 26% reduction in operating costs for the same application when using individual dust filters as opposed to a central system. In addition to the lowered cost, there are reductions in risk associated with the elimination of ductwork and the central containment enclosure for collected explosive dust. By the conclusion of this paper, the reader will have a better understanding of the quantifiable differences between a central dust collection system and a set integrated air cleaner systems. BACKGROUND Spillage has always been a problem in the bulk solids handling industry. As long as there have been conveyors, there has been spillage. Spillage is material that falls off a conveyor belt and creates a hazard in the environment around a conveyor belt."

Jan 1, 2016

By L. Xia, B. Hart, G. Gingras, M. Furlotte

Plant and laboratory test work was performed in order to optimize a copper/zinc flotation separation circuit at Matagami concentrator, Canada. The testing identified a significant difference between the laboratory testing and the plant flotation, particularly for the sphalerite recovery in the rougher copper concentrate. Tests indicate that sphalerite recovery of the flotation concentrate in the laboratory testing was significantly higher than in the plant. The ToF-SIMS surface analysis identifies surface species responsible for the discrepancy in Zn recovery. It shows that sphalerite flotation is in response to the collector attachment and a significant enrichment of Cu on the surface of sphalerite grains. A comparative surface chemical analysis was performed on both sphalerite and chalcopyrite grains from the plant flotation and laboratory testing in order to identify surface species variability between the two testing. Two significant observations were revealed. First, there is considerably more hydrophilic iron oxyhydroxide on sphalerite surface from the plant flotation sample relative to those from the lab testing. The secondary coating likely completely or partially passivates sphalerite surfaces, reducing Cu enrichment and hence sphalerite floatability. Secondly, comparing the surface chemistry on sphalerite and chalcopyrite, the hydrophilic iron oxyhydroxide species have preference for the sphalerite grains relative to chalcopyrite. Despite numerous studies on the effect of galvanic coupling during grinding, there is limited documented evidence on the effect of the milling environment on the flotation and plant operations. This observation suggests that interaction between sulphide minerals and grinding media have a significant influence on subsequent flotation. This paper discusses the results of a detailed surface chemical evaluation of sphalerite grains from both the plant and laboratory testing in the context of grinding environments and pulp chemistry.

Jan 1, 2016

By M. Saghaeian, R. Hejazi, Sheikhzadeh. V., A. Abazarpoor

"The morphology of iron ore concentrate particles is known to influence several properties of iron ore pellets, including drop number, compression strength, and reduction properties. This study aimed to determine why grinding methods and particle morphology influence green pellet properties. Particle morphology can be directly related to the grinding method: ball mill (BM) or high pressure grinding roll (HPGR). In this research, two iron ore concentrates, namely Gol-e-gohar and Ardakan, were ground by a BM and HPGR to produce a suitable Blaine value for pelletizing (nearly 1,900 cm2/g). Morphological features of particles were subsequently investigated by sieving and cyclone sizing for particle size distribution, the Brunauer-Emmett-Teller (BET) and Blaine methods for specific surface area (SSA) and scanning electron microscopy (SEM) for the evaluation of shape descriptors. It was concluded that HPGR resulted in generating a greater proportion of fine particles compared to ball milling. The BET results showed that the SSA of HPGR pellet feed was higher than that from the BM due to a greater proportion of cracks, indents and bulges and the creation of new fracture surfaces. SEM images processed by ImageJ software indicated that particles ground by the BM tended to be more rounded and less elongated than HPGR particles because of the breakage model of each method. To show the effect of morphology on the green pellet quality, green pelletizing was performed in a pilot pelletizing disc. The HPGR pellet feed had a higher drop number in comparison to the BM pellet feed, due to the angular and rough shape of the particles.INTRODUCTIONThe demand for fine or ultra-fine particles as feed material for ceramics, composite materials, and mineral processing is on the rise (Kotake, Kuboki, Kiya, & Kanda, 2011). The final concentrate of iron ore processing plants (filter cake) has a size range roughly between 0 and 300 µm, depending on the liberation of Fe containing particles (Meyer, 1980). In general, to produce a suitable pellet feed of appropriate quality, Blaine numbers of 1800–2000 cm2/g should be achieved (Van der meer, 2015)."

Jan 1, 2016

By Rodrigo Serna, Nora Schreithofer, Zoltan Javor, Kari Heiskanen

"Mineral floatability is a function of mineral properties such as size, liberation, shape, surface composition, reagent coverage on the surface, level of oxidation on the surface, etc.; pulp chemistry: Eh, pH, temperature, DO, reagent type, etc. and hydrodynamic conditions: turbulence, gas dispersion, D32, etc. The biggest challenge with predicting the floatability of an ore is finding a measurement method that would take into account the effect of all of the variables on the floatability of the minerals. The particle-bubble attachment time measurement is considered as an alternative way to predict the floatability of minerals instead of using expensive and time consuming flotation tests because it takes into considerations both surface chemistry and hydrodynamic parameters present in the froth flotation. The existing particle-bubble attachment time method is suitable for studying some significant flotation variables such as pH, temperature, particle size, reagent type and concentration. Nevertheless, measuring the attachment time as a function of collector coverage or surface oxidation is much more challenging. This paper introduces a new induction timer designed to measure the effect of galvanic interaction on the attachment time of particles. The new setup employs an array of needles to create 6 bubbles with the average size of 2.1 mm. Imaging system is used to set the initial distance between the particle bed and the array of bubbles. The attached particles are collected and sent for further analysis. One of the main benefits of the new experimental setup is that the attached particles can be physically separated from the unattached particles therefore many of the particle properties can be analysed and evaluated.INTRODUCTIONSchumann (1942), and Tomlinson and Fleming (1963) proposed that the flotation rate constant is dependent on four probabilities: particle-bubble collision (PC), particle-bubble attachment (PA), particlebubble aggregate stability in turbulent environment (PE), and particle-bubble aggregate stability in froth phase (PF). Any change in any of these probabilities will affect the overall flotation rate constant. All of the above-introduced probabilities are influenced by stream- variables and mechanical variables but their extent of influence vary. The stream variables are particle properties that have been shown to affect flotation rate constant such as size, shape, liberation, mineralogical composition, reagent surface coverage, surface oxidation, etc. The mechanical variables are the direct and indirect properties of the flotation unit affecting flotation rate constant such as cell and impeller geometry, air rate, impeller speed, air holdup, bubble size, residence time, hydrodynamics, froth depth, etc. For instance, the probability of collision is affected by many mechanical variables (bubble size, hydrodynamics, bubbles holdup etc.) but only one stream variable (particle size) has a major effect on it. On the other hand the probability of attachment is affected by much more stream variables: particle size, shape, liberation, surface composition, particle surface oxidation and collector coverage, Eh, pH, etc."

Jan 1, 2016

By Helge B. Wurst, Michael P. Cipold, Jan F. Bachmann, Claus C. Bachmann

"In washability, the objective is to establish the set of maximum possible separation performance criteria for a given mineral feed. The method of choice for this has been the conventional sink-float analysis. Time, cost and safety aspects of the sink-float method have prompted the search for a new approach for establishing separation performance criteria, especially as performance levels of separator plants can be maximized if reliable information based on an analysis of washability in conjunction with particle size distribution, elemental constituency becomes readily available. The new method to establish washability and associated performance information utilizes at least two measurement technologies concurrently: single energy x-ray transmission and image processing. For porous or very inhomogeneous materials the results can be refined further by using dual energy x-ray transmission and image processing. The value of the collected data increases considerably if the washability data were additionally available in time to be considered in the control of the process plant. The incorporation of an automated washability monitor gives near real-time data that would impinge positively on the profitability of the plant operation. The method was extensively tested with a range of sample with different densities, varying from 1 g/cm³ (coal) to 5 g/cm³ (iron ore).INTRODUCTIONWashability of minerals like coal and iron ore is expressed by a curve or graph showing the results of a series of float-and-sink tests. Several of these curves are drawn to illustrate different conditions or variables, usually on the same axes, thus presenting the information on one sheet of paper. Washability curves are essential not only for the design but also for the operation of preparation plants.In determining the washability analysis, particle density is the underlying feature of all washability curves. Conventionally, the particles are separated into density fractions by immersing them in fluids of a predetermined density followed by skimming of those particles that stay afloat. The particles remaining afloat thus have a density lower than that of the fluid they were subjected to. The particles that remained at the bottom of the fluid container thus had a higher density higher than that of the fluid. By progressively increasing, for example, the density of the fluid and immersing the remaining particles so as to be able to skim the next density fraction, the particles would be fractionated into density groups. The liquids used range from aqueous solutions to organic liquids to suspensions. Unfortunately the liquids used for this separation process are often toxic and expensive. It stands to reason that a new method of determining washability is sought."

Jan 1, 2016

By Filip Rochette, Yvan De Busscher

Extraction of minerals can be achieved by a variety of technologies; one of them is ion exchange. There are several ion exchange configurations and mechanical set-ups available, but only one technology will provide more process performance and flexibility compared to the other. The multiple column Continuous Countercurrent Ion Exchange (CCIX) technology provides the highest form of process flexibility with also the highest mineral recovery feasible through ion exchange. In comparison with a fixed bed system, the PuriTech CCIX system offers the benefits of continuous counter-current contact mode. This way the resin capacity is fully exploited leading to reduction in resin inventory and, at the same time, in chemicals and water consumption, and product dilution. For any set of operating conditions the mass transfer zone has a characteristic length (MTZL). The MTZL can be expressed in duration, column length, or volume, but is the measure of the quantity of resin in the system that is doing "work" at any given moment in the process. The objective of continuous ion exchange processing is to eliminate all resin volume from the process equipment that is not within a mass transfer zone. In most commercial ion exchange processes for the recovery of metals, CCIX engineering can eliminate as much as 20 - 80 % of the ion exchange resin inventory. Consumptions of water and chemicals are typically brought down around 40% or more. For each type of resin the selectivity/affinity towards a particular metal depends on the basic process conditions such as pH, concentrations of other competing metals in solution. By changing the pH in the ion exchange process phase, the selectivity of the resin can be changed. By doing this, a split elution, or extraction of metals separately can be achieved and the effect of other competing metals (cross-contamination) can be reduced. For example the DOW resin XUS43578 is commonly used for the recovery of copper or nickel/cobalt separation.

Jan 1, 2016

By Yoshinori Shimada, Oleg Kotiaev, Hiroaki Sakamoto, Toshihiro Asakura, Naotoshi Yasuda, Norikazu Misaki, Masahiro Shinoda

"To ensure that trains run safely, the performance of railway civil engineering structures is checked by periodic inspections. General inspection method has merits and demerits, but none of them offers the combination of high accuracy and quick inspection. In an effort to resolve this problem, West Japan Railway Company, the Institute for Laser Technology and the Railway Technical Research Institute jointly developed a remote laser sensing system as an alternative to the impact acoustics method for detecting defective concrete elements in tunnel linings. The proposed remote laser sensing system has two lasers, one to apply an impact to the concrete surface and the other to measure the vibration of the concrete generated by the impact laser. The impact laser is a high-energy pulse laser that induces vibration in the concrete. The detection laser has a signal beam and a reference beam. The signal beam reflects on the concrete surface and goes into the dynamic hologram crystal. The reference beam diffracts in the dynamic hologram and enters the detection sensor with the signal beam. The vibration of the concrete surface can be measured to detect the movement of an interference pattern. A prototype of the remote laser sensing system was developed as shown in Figure1. A vibration and acoustic insulators are equipped to remove a noise generated from a maintenance car or electric generator in this system. The proposed laser remote sensing system and the detection algorithm were verified with the help of field test conducted in a tunnel on the Shinkansen. An impact test using hammering was applied to obtain the accurate response acceleration on the surface of the concrete before application of the proposed method. In this test, the result obtained from the proposed method has good agreement with that obtained from the impact test by hammering. Consequently, it is verified that the proposed method can be used as an alternative to the standard impact acoustics method."

Jan 1, 2016

By Sandeep Upadhya, Marc Morgan, Baljinder Bassi, James Fletcher, Mike Deevy, Nishant Nayan

"In order to protect public safety in the event of a deliberate fire attack, underground rail authorities are increasingly considering the need to design for arson-initiated fire scenarios. Where typical design fires for modern rolling stock mean a peak fire size is reached after 12 minutes, an arson-initiated fire reaches its peak within 2-3 minutes. We present the innovations required to successfully incorporate this requirement on a recent design-build project. In stations 3D modelling is used to optimise smoke reservoir designs, smoke chimneys, station boxes and tunnel geometry to allow coordination with structural requirements. In tunnels, novel coupling of one dimensional network modelling and 3D Computational Fluid Dynamics (CFD) is used to improve assessment of complex fire scenarios. Finally, the impact on tunnel structures is assessed through comparison with standard time-temperature curves and risk of explosive spalling. INTRODUCTION An increasing regulatory environment and the appreciable influence that terrorist incidents have had on public safety policy have motivated the need to protect against large arson fires, especially in civil structures and public transport systems. With a greater reliance of a growing urban population on underground subway systems, design of such infrastructure is continually being reassessed and developed worldwide. Underground rail authorities are paying increased consideration to the design of fires - with properties beyond the upper regions of growth and intensity - amongst arson fire studies. Use of fire hardened materials on modern rolling stock means fires caused accidentally can be expected to develop relative slowly. However, recent experiments involving large initiating fires (as would result from an arson attack) have shown rapid fire growth rates and flashover leading to greater maximum heat release rates, Hadjisophocleous (2012), White (2010), and Lönnermark, et al. (2015). This paper describes the challenges and innovations required to complete a detailed design to control smoke from such aggressive super-fast growing fires. Computational modelling is used to demonstrate the required smoke control design by configuring the mechanical exhaust system combined with careful coordination with the architectural and structural design. The design objectives are to provide tenable egress paths in accordance with NFPA 130 (2014) and fire-fighting access. Finally, analysis of the design fire is used to inform the tunnel lining design, reducing the risk of explosive spalling, protecting the asset in the event of a severe fire."

Jan 1, 2016