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By Carsten Rühlemann, David Friedmann, Bernd Friedrich, Thomas Kuhn

"This paper explores the option of direct reduction smelting of the nodules from the German license area in the equatorial NE Pacific in a submerged arc furnace (SAF). An optimized slag design is proposed to separate the larger Mn-bearing stream from the valuable metals (i.e. Ni, Cu, Co, Mo). The slag optimization allows a maximum of Mn to be retained in the manganese-silicate slag on the one hand and a maximized metal recovery in a FeNiCuCo alloy on the other. This way, the goal is to make use of the complete nodules (“zero-waste”) instead of extracting only the metals Ni, Cu, and Co, which make up about 3 wt%. The process closely relates to the “Inco Process” by the Ocean Management Inc. (OMI) of the late 1970s, which was a consortium of INCO (International Nickel Company, CAN; today Vale Canada), Preussag AG & Metallgesellschaft AG (GER), DOMCO (JPN), and Sedco (USA). However, the manganese containing slag is investigated in more detail to recover FeMn, FeMnSi and/or SiMn. To optimize the process modern tools such as thermo-chemical modeling in FactSage™ have been used. [1,2]Polymetallic deep-sea manganese nodules may offer a decreased dependency of raw material imports for Germany and the EU. Currently, four European countries (United Kingdom, Belgium, Germany, and France and an Eastern European consortium (InterOcean Metal)) hold exploration licences for these nodules in international waters in the equatorial NE-Pacific. The license areas each cover 75 000 km2 of the seafloor and are located in the Clarion Clipperton Fracture Zone (CCZ) south east off Hawaii at water-depths between 4000 and 6000 m. The nodules may be used as a resource for industrially important metals such as Cu, Ni, Mn as well as for technology metals like Co, Mo, V and Zn. The average chemical composition of nodules from the German license area is presented in Table 1. [3,4]"

Jan 1, 2017

By R. Agius, A. Nacu

"Adoption of the International Cyanide Management Code, regulatory requirements and community concerns have increased the need to implement suitable cyanide destruction processes at gold operations to meet ever more stringent discharge limits. As standards set for the allowable concentrations of cyanide, cyanide compounds and other contaminants may vary from country to country, jurisdiction to jurisdiction, and even from site to site, there is no “one size fits all” technological solution. Currently the most common cyanide destruction processes used in industry are sulfur dioxide/oxygen, hydrogen peroxide and Caro’s acid. Regardless of the process used, cyanide destruction plants must be reliable and achieve permit guidelines at all times. The selection of the most appropriate cyanide destruction process for an operation depends on several factors, including permit discharge requirements, tailings chemistry, location, site-specific climatic conditions and size of the operation. Only after considering all these factors together can the most effective approach be selected to achieve the permit guidelines economically and technically feasible. Finally performing the correct test work program is the most important step to ensure that the correct process design criteria can be determined to accurately calculate capital and operating costs.IntroductionThe adoption of the International Cyanide Management Code in 2005, stricter regulatory requirements and community concerns prompted by environmental incidents involving cyanide have increased the need to implement cyanide destruction processes at gold and silver operations.Process solutions associated with the extraction of gold and silver contain several forms of cyanide. The most toxic form of cyanide is free cyanide, which can be present as a dissociated cyanide anion (CN-) or gaseous or aqueous HCN. Weak or moderately stable cyanide complexes such as those of zinc, copper and nickel are classified as weak acid dissociable (CNWAD). Although less toxic than free cyanide, weak acid dissociable cyanide complexes are considered “ecologically sensitive” forms of cyanide and are regulated in most jurisdictions. In practice, reported WAD cyanide values are comprised of both free cyanide and weak acid dissociable cyanide complexes. Cyanide complexes with gold, mercury, cobalt and iron are referred to as strong acid dissociable complexes (CNSAD) and are much more stable even under mildly acidic conditions. Another term commonly used in cyanide chemistry is total cyanide, which represents all cyanide compounds present in solution, with the exception of cobalt complexes. Total cyanide levels in solutions are in most cases higher than WAD cyanide values and the difference between the two usually indicates the presence of iron-cyanide compounds. Typically, in Canada CNTOTAL levels cannot exceed 1 mg/L in solutions."

Jan 1, 2017

By Federico Pagliacci

"Many existing dams are subject to underwater seepage due to subsoil conditions, like deep alluvial deposits or pervious rocks or karst. Remedial works are necessary in order to install new cut-off walls to stop the water flow. In some cases the cut-off walls have to be executed at depths never reached so far, and difficult to reach with traditional foundation techniques. In many cases the Hydromill technology proved to be the best system to overpass rocky layers and ensure the required verticality. The maximum depth reached by the industry was in the range of 120-150 meters. This article describes the test performed to excavate and cast in place a 3.2x1.5 m panel to a depth of 250 m. The article will also describe the stratigraphy of the site down to 250 meters, as well as the technique adopted to achieve the said depth with deviations from verticality of 30 cm along the longitudinal axis (0.12%) and 20 cm along the transverse axis (0.10%), measured at the bottom of the excavation. The concreting of the panel, for about 1,100 m³, with plastic concrete in the lower portion and conventional concrete in the upper portion will be illustrated. Finally, the tests performed during the excavation and after concrete casting will be also described, with special attention to the continuous directional core drilling that was performed along the whole length of the panel to verify the results of the deviation from verticality, through the onboard instruments, and to control the quality of concrete at a depth never reached before. IntroductionMany existing dams are subject to underwater seepage due to subsoil conditions, like deep alluvial deposits or caves and cavities or acid solutions in the bedrock formations.Conventional remedial works generally consist in the construction of an additional cut-off wall throughout the dam body and the subsoil, in most cases being deeper than the original one. Today, many examples of successful remedial cut-off walls allow the engineers to design the most suitable solution according to the dam and subsoil characteristics and nature.The real difficulty stems from the depth at which the new cut-off wall has to be socketed in competent rock or soil, so as to eliminate underwater seepage. The maximum depth ever achieved with a cut-off wall is 122.5 m for the remedial work of Mud Mountain Dam, Washington, USA, in 1988-1990. This 0.85-1.0 m thick cut-off wall was realized by means of a Hydromill, by excavating single 2.8 m-wide secant panels."

Jan 1, 2017

By Hongwei Wang, Hao Zhang, Panshi Xie, Xicai Gao, Youfu Zeng, Yongping Wu, Juan Dou

"The reserves and production of steep coal seams account for approximately 15–20% of the total coal reserves in China and 5–10% of the total annual coal production. More than 50% of the coal is high-quality coking coal and anthracite, based on reviews of steeply dipping seam mining at home and abroad. Fully mechanized mining is considered to be the only safe and efficient way to mine steeply dipping seams. To achieve fully mechanized longwall mining, four issues must be addressed: ground control, equipment stability control, development of complete sets of equipment, and safety. Engineers must focus on many factors of steeply dipping seams, such as the following: stope, roof asymmetrical structure, stability control, “roof-support-floor” system dynamics control, multi-region big-range ground control technology, adjustment false-inclined method, nonlinear layout method, control technology, safety, and development of complete sets of equipment. Engineering practices in China introduce these concepts systematically: fully mechanized mining of medium-thickness seams, fully mechanized high mining of thick seams, fully mechanized caving of extremely thick coal seams, fully mechanized mining of coal seams, roadway support, and so on. A steeply dipping seam is one with a dipping angle in the range of 35°–55°. This accounts for about 15%–20% of the total coal reserves in China. Because of the environment, more than 50% of the coal is high-quality coking coal and anthracite. Mining steeply dipping coal seams is known to be difficult in the mining industry. After the study conducted by Germany, Poland, and the former Soviet Union in the1970s–1980s, the fully mechanized mining basic theory, core technology, and key equipment research have not been a breakthrough. Being fully mechanized is a technological “restricted area” at home and abroad. A lot of steeply dipping seams are excavated by non-mechanized mining, leading to harsh job environments, labor-intensive work, low productivity, frequent accidents, and significant security hazards. The death rate per million tons of coal reaches above 4.0 and is far higher than slow inclined coal seam mining. Making steeply dipping seam mining safe and efficient is a global problem that urgently needs to be solved. Fully mechanized mining is the only way to overcome these problems (Wu, 2003; Wu, Yun, and Zhou, 2000). The realization of fully mechanized coal seam mining must solve four problems. (1) Examine the disaster mechanisms induced by overburden “key strata” mutation under steeply dipping seams as a basis for ground control methods and technical problems. (2) Work to solve the dynamic stability control technical problems of thousands of tons of complete sets of equipment under the steeply dipping seams. (3) Complete sets of equipment must be developed to adapt to the conditions of steeply dipping seams. (4) Overcome the steeply dipping face safety protection technical problems. In the last two decades, a number of universities, research institutes, and enterprises have realized the importance of safety and efficiency of steeply dipping seams in China. This is especially true of Professor Wu Yongping’s “hard coal layer safe and efficient mining” team at Xi’an University of Science and Technology. After several generations’ research and technical work, the team puts forward China’s longwall mechanized coal mining of steeply dipping seams strata control basic theory. This paper puts forth a series of key technologies of fully mechanized mining, develops and manufactures complete sets of equipment by independent innovation, and establishes a perfect face security system, forming a theory and technology system for fully mechanized longwall mining of steeply dipping seams."

Jan 1, 2017

By Gihan E. Abdelraham, Youssef G. Youssef, Mohamed M. Kamel

"Previous studies defined Narrow Mechanically Stabilized Earth, NMSE, walls as a retaining wall with aspect ratio (wall width to its height, L/H) less than 0.70 as in traditional walls. Some studies investigated its behavior and its failure planes compared to those of traditional walls. In this paper, parametric study using finite element analysis PLAXIS, 8.2 has been introduced to discuss global factor of safety, FS, maximum horizontal displacement, Ds, maximum tension force of reinforcement element, Tmax, and active earth pressure coefficient, ka, as a function of different aspect ratio of NMSE wall, L/H, reinforcing elements spacing, S, elastic axial stiffness of reinforcement element, EA, wall batter, 1/m, soil friction angle, f, and wall height, H. The results indicated that increasing aspect ratio increases the factor of safety, maximum horizontal displacement, maximum tensile force and active earth pressure. Increasing elastic axial stiffness increases factor of safety, maximum tension force of reinforcement element while decreasing the maximum horizontal displacement.IntroductionReinforced earth is a composite geoconstruction material, which embodies two basic components; namely engineering fill and reinforcing elements. The latter one is responsible for improving the tensile and shear resistance of the soil. The soil-reinforcement technique has been in use for many geotechnical applications especially MSE walls.A narrow wall system is referred to as a MSE wall with an aspect ratio, L/H, below 0.70 that is placed in front of a stabilized wall. An example of a narrow wall system with its dimensions is illustrated in Fig. 1."

Jan 1, 2017

By Alireza Ayoubian, Douglas S. Roy, Gianni O. Chieruzzi

"A 400 MW, gas-fed power plant on floating piles and piled raft foundations was constructed in the Province of Moskovskaya, Russia in 2008. The subsurface is characterized by fill underlain by loose to medium dense alluvial deposits, with peat and clay interbeds, a stiff to hard, highly plastic, silty clay stratum of glacial origin, and a stratum of very dense, varved interbeds of sand and silt.More than 800, drilled concrete piles were constructed at the site. The pile length ranged from 15 to 23 meters below existing surface grade, and the pile diameter ranged from 0.9 to 1 meter.Initial analyses by others predicted total power plant settlements of 3 to 4 cm when subjected to the permanent loading conditions. Under a peer review process for the equipment supplier, subsurface investigation and testing were performed to verify the consolidation parameters used for foundation design of the power plant foundation. The parameters obtained in this investigation were used in the 3-D finite-element model ELPLA as inputs for the settlement analysis of the turbine building and power island. The ELPA analyses predicted settlements on the order of 7 cm over a period of 30 years. The actual settlements after two years of monitoring were compared against the model predictions. The rate of settlement and the recompression index were both underestimated in our model. The measured settlements have enabled us to calibrate both of these model parameters so that the model better matches the data.IntroductionA 400 MW, gas-fed power plant was constructed near Moscow in the Province of Moskovskaya in Russia.Figure 1 shows the general arrangement of the main structures, and the geometry of the piles supporting those structures."

Jan 1, 2017

By H. Saeedi Ali, A. J. Monhemius

"Anglo Asian Mining’s Gedabek mine is situated in the Lesser Caucasus mountains in Western Azerbaijan. The ore body is a complex copper-gold porphyry deposit, comprising intermixed oxidized, transition and sulphidic gold and copper-bearing ores. Gold in the sulphide ores is generally not refractory and is recoverable by cyanide leaching, but the secondary copper minerals, which are also cyanide soluble, lead to high cyanide consumptions. Ore processing at Gedabek is by agitation leaching for high grade ore (>1g Au/t) and heap leaching for lower grade ore. In order to cope with the high copper concentrations in the cyanide leach liquors, a unique combination of resin-in-pulp for selective gold extraction and SART processing for copper removal and cyanide recovery is used. In 2015, a flotation plant was added to treat the tailings from the agitation leach plant before the tails are sent to the tailings dam. This plant produces a copper sulphide flotation concentrate and also recovers some of the residual gold and silver in the tailings. Since February 2017, due to lower grades of gold and higher copper in the feed ore, the decision was taken to alter the flow sheet and to carry out flotation ahead of agitation leaching, to reduce the cyanide consumption during leaching by removing soluble copper minerals. The paper compares and contrasts the performance of the plant in the two configurations, namely, (i) leaching followed by flotation and (ii) flotation followed by leaching.INTRODUCTION In May 2009, Anglo Asian Mining started open pit mining for gold on its Gedabek property in the Lesser Caucasus Mountains in western Azerbaijan. Gedabek is situated on the highly mineralized Tethyan Belt that runs from the Himalayas to the Balkans. The ore body at Gedabek is a complex copper-gold porphyry deposit, comprising intermixed oxidized, transition and sulphidic gold-bearing ores. The sulphidic ores contain mainly pyrite and chalcopyrite, with some secondary copper sulphide minerals, such as bornite and chalcocite, and minor amounts of sphalerite, galena and tetrahedrite. Gold in the sulphide ores is generally not refractory and is recoverable by cyanide leaching, but the secondary copper minerals, which are also cyanide soluble, lead to high cyanide consumptions and passivation of free gold."

Jan 1, 2017

By R. Kumar, N. R. Mandre

"The beneficiation of iron ore slimes by selective flocculation was studied. Polyacrylamide (PAM) and guar gum were used as flocculant, along with sodium hexametaphosphate (SHMP) as a dispersant. The samples collected were initially subjected for chemical and mineralogical studies. The mineralogical studies indicated the presence of haematite and goethite as the principal iron-bearing minerals, with quartz and kaolinite as gangue minerals. The selective flocculation tests showed that the Fe grade can be enhanced from 58.24% to 64.60% Fe at a recovery of 66.33% using polyacrylamide as the flocculant. A Fe grade of 63.20% at a recovery of 68.04% was obtained using guar gum as flocculant. The efficacy of the studies was analysed using a separation index, which indicated that the higher separation index was obtained with the tests employing polyacrylamide as the flocculant. IntroductionIndia is endowed with huge reserves of highgrade iron ore and is one of the prominent producers in the world. As the high-grade iron ores have been exhaustively mined, it has become imperative to use low-grade iron ores, fines, and slimes to meet the growing demand. Also, generation of fines and slimes during mining and processing contributes to loss of minerals to the extent of 30% of the total value (Mandre and Panigrahi, 1997). These fines/slimes are often discarded as waste into tailing ponds, containing considerable amounts of iron. Therefore beneficiation of tailings/slimes has become necessary for optimal utilization of the resources.In recent years, interest in recovery of valuable minerals from low-grade ores, slimes, and tailings has increased worldwide. These activities are initiated not only to recover minerals but also to address various environmental issues associated with fine particle treatment. The literature reveals that several technologies have been employed in this regard, including flotation, advanced gravity separation, and high-intensity magnetic separation. However, these processes are found to be ineffective for fine particle treatment due to lower collision probability in flotation, decreased gravitational effect in gravity separation, and reduced drag force in magnetic separation, among other factors (Batisteli and Peres, 2008; Das et al., 2007; Dworzanowski, 2012; Rocha, Caneado, and Peres, 2010). Therefore, it is in this regard that selective flocculation has gained importance in treating slimes in recent years."

Jan 1, 2017

By C. J. Konya, A. Konya

"Presplitting is a form of blasting that when executed properly will create a smooth wall that will minimize secondary conditioning. In recent years, presplitting has become a popular technique to be used in both the mining and construction industry, however, presplitting fails on many occasions because of ‘geologic conditions’. This is typically because of improper explosive loads consisting of overloading and underloading blastholes. In this paper the authors introduce new factors such as a presplit factor which varies for different rock types, selection criteria for the spacing of presplits, the optimization of explosive load, as well as prediction methods for the environmental affects for the technique of Precision Presplitting. BACKGROUND Methods of controlled blasting in which a smooth, stable wall could be blasted have been an important consideration since blasting in mining and construction has begun. How can one use an explosive, with its massive energy and power, to break a non-homogenous rock without causing backbreak, poor walls, or deviations in the wall over large distances? The blasting industry has known for a long time that blasting ‘high benches’ would result in better walls and less backbreak. However, this was not a sufficiently controlled technique for critical projects, such as the Niagara Power Plant. This was one of the main challenges Hercules Powder faced when they began the project. In order to achieve this, they used a new tool in the explosive engineer’s toolkit, presplitting. The presplitting done on the Niagara Power Project utilized 1 ½” x 8” (38mm x 203mm) 40% gelatin dynamite in 2 ½” (63.5) diameter boreholes. This was done on multiple levels with benches between 12 feet to 52 feet (3.6m to 15.8m) with a total powder factor of 0.75 pounds/cubic yard (0.45 kg/m3). The spacing on these holes ranged between 18 inches to 24 inches (0.46m to 0.61m), center to center (Langfors & Kihlstrom, 1973). The strange aspect of this project was that this “lightly loaded” closely spaced row was fired before the production blast, yet this project produced some of the best walls seen at that time directly from blasting. In today’s blasting industry, presplitting is a more common way to produce smooth, stable high-walls for both the construction and the mining industry. Today, explosive loads for traditional presplitting is generally measured in pounds per foot (kilograms per meter) and typically ranges from 0.30 lb. /ft. to 0.5 lb. /ft. (0.45 kg/m to 0.75 kg/m). MECHANICS OF PRESPLITTING When analyzing a blasting process like the Niagara Project, many wonder how did that work when normally confining a charge would cause cratering and increased backbreak. Since then, presplitting mechanics have been studied extensively. It has been shown in many models that presplitting is not achieve through the collision of shockwave, but by gas pressure in the boreholes. In addition to models and finite element simulations, this has been proven full scale using Pyrodex, a propellant, to create a presplit plane with no shock wave present (Konya, Dean Barrett, & Smith Jr, Presplitting Granite Using Pyrodex, A Propellant, 1986)."

Jan 1, 2017

By Barbara Rutter, Shonn Kevin McNeil

"This study discusses how a prototype was built to measure the sonic velocity in powdered explosives.The sonic velocity of an explosive is a benchmark to determine if the explosive deflagrates or detonates;however, little work has been done to determine this value for powdered explosives. This paperdiscusses the results of the initial prototyping tests where two known mediums, air and water, were used for validation. The prototype did record the sonic velocity within the known velocity ranges of air and water; however, a few depths did not fall into this range. This prototype could be used for testinggranular materials."

Jan 1, 2017

By Terrence M. Carroll, Chu E. Ho, Dimitrios Niarchos

"Construction of the new extension to Terminal 4 at John F Kennedy International Airport in Queens, New York involved the application of tapered piles for foundation support. Initial design based on past load testing experience had indicated that a pile depth of 65 feet was necessary to achieve a capacity of 394 tons. However, piles with a single length of 62 feet were ordered and installed, which led to marginal performance of the piles. This paper presents the technical considerations for mitigating the situation based on a systematic review of three preliminary pile load tests and dynamic capacity measurements on the shorter piles. Consideration was given to the long term gain in capacity of tapered piles due to set up in the Glacial Sand. The observational approach to the evaluation of piling performance adopted on this project resulted in salvaging many piles which failed to comply with the specified driving criteria. It was acknowledged that a more prudent course of action was for the Contractor to have ordered more appropriate pile lengths that allowed for potential variation in soil conditions across the site. The 4.6% saving in pile material did not warrant the effort that was required to mitigate the 39% of installed piles that did not meet the specified driving criterion.INTRODUCTIONAn expansion project at John F. Kennedy International Airport in Queens, New York involved the Phase 2 extension of Concourse B at Terminal 4. The site consists of 4 to 5 feet of pavement over about 10 feet of hydraulically placed sandy fill. Below this is a layer of marsh deposit, comprising of soft organic clay and peat, up to about 11 feet thick. Beneath the marsh deposits is a deep layer of glacial sand which extends to well over 100 feet below ground. Figure 1 shows the typical subsurface profile at the site. The new structures were supported on 223 steel tapered piles. The piles consisted of a straight steel pipe 18 inches in diameter and 0.375 inches thick, with a 25 feet long tapered bottom section (diameter varying from 18 inches down to 8 inches at the pile toe). The piles were first driven to the founding depth and subsequently in-filled with concrete. The concrete strength (fc) specified was 4,500 psi and the yield strength of the steel piles (fy) was 50 ksi. Initial pile design, based on earlier experience with static pile load testing for Phase 1 development at the same terminal, indicated that a pile length of 65 feet was necessary. However, piles with a single length of 62 feet were ordered and installed by the Contractor, leading to marginal performance of the piles. This paper presents the technical considerations for the adoption of alternative pile driving criteria, based on a systematic review of the preliminary static load test results for the present site and PDA measurements obtained during pile installation, in order to accommodate the capacity of the shorter piles."

Jan 1, 2017

By Donald Bruce, Mark Harris, Wesley Schmutzler, James Sanders

"This paper evaluates the history, construction and most importantly the performance of two remedial seepage cutoff walls installed in two major dams in the United States. Beaver Dam, on the White River in northwest Arkansas, was completed in 1966 and seepage through the karstic limestone under the embankment was apparent almost immediately upon filling of the reservoir. Several attempts to stop the seepage by grouting were unsuccessful. In 1994 a cutoff wall consisting of secant piles drilled with 32"" diameter down-the-hole hammers to a maximum depth of 185'?was completed and the seepage was reduced to a negligible amount. It has been over 20 years since the completion of the cutoff wall, and all indications are that the cutoff wall is performing as expected. Walter F. George Lock and Dam on the Chattahoochee River near Fort Gaines, Georgia, was completed in 1963 and suffered the same problem as Beaver Dam due to the limestone on which the dam was founded. Cutoff walls were installed in both embankments (1980s) and solved the problem in these areas, but under-seepage at the concrete lock, dam and spillway structures increased to the point that remediation was essential. The cutoff wall had to be installed through 110'?of water and another 100'?into rock upstream of an active dam that continued to generate electricity during the construction of the cutoff wall. A secant pile wall, in combination with a diaphragm wall, was completed in front of these structures in 2004. It has been over 10 years since the completion this cutoff wall and, again, the cutoff wall is performing as expected. The paper describes the construction of these cutoffs, but focuses on the long-term performance in terms of controlling seepage and piezometric levels.BEAVER DAMBeaver Dam is located on the White River, 609 miles above its mouth, in Carroll County, Northwest Arkansas. The construction of the dam and Beaver Reservoir was authorized on September 1954 by the Congressional Flood Control Act for purposes of water supply, flood control and hydroelectric power generation. The dam site was selected in 1957: construction began in November 1960 and was completed in June 1966. (FIG. 1)"

Jan 1, 2017

By F. Mohamm

"Recent changes in regulations and scientific advances concerning selenium bioaccumulation have placed greater importance on non-biological treatment systems for selenium control. Mining wastewater contains hexavalent selenium (selenate) as the predominant aqueous species and possibly small amounts of tetravalent selenium (selenite). Non-biological removal of selenite is accomplished readily and cost effectively by ferric co-precipitation and adsorption using ferric oxyhydroxides sourced from ferric salts or iron anodes in electrocoagulation cells. Selenate on the other hand is difficult to remove. It is often incorrectly assumed that electrocoagulation is suitable for removing both selenite and selenate. Selenate removal efficiency by electrocoagulation is low and the amount of waste residue produced high. In contrast, BioteQ’s Selen-IX™ process removes selenate very efficiently and produces a much smaller amount of stable residue. The process combines selective ion exchange with electro-reduction of selenate in electrocells that physically resemble electrocoagulation cells but are designed and operated differently. This paper summarizes four years of pilot scale demonstration on a wide range of mine waters and discusses the key benefits and limitations of Selen-IX™. The pros and cons of combining ion exchange with electro-reduction in comparison to direct electro-reduction of selenate are also reviewed.INTRODUCTION Selenium in Mining and Mineral Processing Effluents Similar to sulphate and metals, selenium presence in mining and mineral processing wastewater originates from minerals contained in the mined deposits. Therefore, no organoselenium species are typically present in these kinds of waters and inorganic species including selenite (SeO32-), selenate (SeO42) and elemental selenium account for the majority, if not all, selenium present in these streams. Elemental selenium is not always present in mine water but is often contained in smelter wastewater. To comply with new environmental regulations, a successful water treatment plant must remove selenium from all these forms effectively and economically without generating by-products that are difficult to dispose of or manage. Elemental selenium can be dealt with using filtration or gravity separation in clarifiers often assisted by flocculants and/or coagulants. Mine impacted waters typically contain other forms of suspended solids which are removed from water in this way. Once the solids are removed, the selenium species that remain untreated are the dissolved forms. In mining waters this is mostly selenate with small fraction of selenite. In smelter wastewater, the majority could be selenite. It is well established that tetravalent selenium is readily removed from water by using ferric iron co-precipitation at pH > 4 (NAMC SWG, 2010). Ferric hydroxide/ferrihydrite solids act as the adsorbent for tetravalent selenium when it is in one of the ionic forms of biselenite or selenite. This treatment for tetravalent selenium is highly efficient. Therefore, tetravalent selenium removal is generally not an issue and is often easily incorporated into lime neutralization or unit operations such as electrocoagulation used for removing other metals present in mine impacted waters. Another option of dealing with tetravalent selenium is sulphide precipitation in acidic pH which produces SeS2 and can separate selenite from other metals and/or sludge produced at neutral to alkali pH."

Jan 1, 2017

By R. J. Matetic, J. Noll, C. Zhou, J. DuCarme, M. Reyes, J. Srednicki

"In April 2016, MSHA began requiring the use of continuous personal dust monitors (cPDMs) to monitor and measure respirable mine dust exposures to underground coal miners. After the cPDM’s implementation, mine operators discovered that it interfered with proximity detection systems (PDSs), thus exposing miners to potential striking and pinning hazards from continuous mining machines. NIOSH was sought out by MSHA and mining industry stakeholders to determine how the cPDM and PDS interact with each other. Accordingly, NIOSH investigated existing standards, developed test protocols, designed experiments, and conducted lab evaluations. Some interferences were observed to be caused by electromagnetic interference (EMI) from the cPDM. Results showed that there was no significant interference when the cPDM and the miner-wearable component of the PDS were separated by distances of 6 inches or greater. In this study, the cPDM and PAD needed to be at least 6 inches apart in order for them to be used simultaneously and reduce interference potential. INTRODUCTION Underground coal miners are exposed to a variety of hazards on a daily basis such as coal dust exposure, high noise levels, roof and rib falls, the potential for fires and explosions, and operating and working with heavy machinery. One of the hazardous jobs is operating or working nearby a continuous mining machine (CMM). According to Mine Safety and Health Administration (MSHA) statistics, 40 miners have been fatally struck or pinned by a CMM since 1984. In an effort to prevent future striking and pinning fatalities from occurring, proximity detection systems have been developed and are required on all operating CMMs in underground coal mines, with the exception of full-face CMMs, by 2018 (1,2). Proximity detection systems (PDSs) are designed to alarm miners and stop machine motion in order to protect miners from being struck, pinned or crushed by CMMs(3). Currently, MSHA-approved PDSs, installed on CMMs, are based on the principle of magnetic flux density (B-field) (4,5). The system generates a magnetic field around a CMM and determines the relative distance a miner is from the CMM based on a detected magnetic flux density. A PDS typically consists of multiple magnetic field generators mounted at different places around the CMM, and personal alarm devices (PADs), which are worn by the miners to detect the magnetic flux density. When a miner, wearing a PAD, gets closer to the machine, the PAD detects a stronger magnetic field from the generators and detects a weaker magnetic field when a miner moves away from the machine. The magnetic field generators installed on CMMs typically produce modulated magnetic wave signals at frequencies between 10 kHz and 120 kHz. The magnetic fields are measured by three small magnetic coil antennas mounted on orthogonal axes inside of the PAD worn by the miner. According to Faraday’s Law, the changing magnetic field induces a voltage in each coil antenna, and the voltage values are transmitted from the PAD back to a controller on the CMM wirelessly, typically at a frequency between 400 MHz and 2.5 GHz. These values are then used to determine the distance between the miner and the generators of the machine. Typically this information is used to determine when a miner wearing a PAD is in a warning zone or stop zone which would trigger different alarms and actions such as slowing the machine down or stopping it."

Jan 1, 2017

By Daan Maijer, Wade Marquardt, Robert MacKay, Steven Cockcroft, Farzaneh Farhang Mehr

"To comply with the new Corporate Average Fuel Economy (CAFE) standards, the automotive industry is aiming to reduce weight and increase the power and efficiency of small displacement engines through the application of forced induction technologies. As an example, there are now several 2.0 litre turbocharged engines in production, producing in excess of 240 hp. To meet the need for improved fatigue properties in the engine blocks used in these high-output engines, a new water-cooled chill technology is under exploration at UBC in partnership with General Motors and Nemak. A series of experimental techniques were used to assess the capability of the new chill to extract heat from an A319 casting in the vicinity of the main bearing bulk head. The results show that this method has the potential to achieve a reduction in secondary dendrite arm spacing thus meeting the new microstructural specifications for these engines.INTRODUCTION The automotive industry is working to meet the stricter efficiency requirements laid out within the CAFE (Corporate Average Fuel Economy) regulations (Bastani, 2012; Cole, 1995; Mackay, 2011; Miller, 2000), while at the same time not sacrificing performance. One approach is to increase the use of lightweight materials, which leads to a decrease in the overall vehicle weight and fuel consumption (Cole, 1995; Mackay, 2011; Miller, 2000). Other approaches include smaller displacement engines and gas-electric hybrid drivetrains. However, one trend that is becoming clear, is a greater emphasis on force induction gasoline engines. This allows for weight reduction to be achieved with smaller displacement engines without sacrificing performance. One consequence of this approach is that the engine block materials are subject to higher in-service thermal and mechanical cyclic loads (Cole, 1995; Miller, 2011; Heysler, 2001) The fatigue properties of an alloy are strongly affected by a number of the, as-cast, microstructure features including, Secondary Dendrite Arm Spacing (SDAS), porosity and eutectic lamella spacing (including intermetallic ß-Al5FeSi platelets) (Mackay, 2010a; Mackay, 2010b; Viet-Duc, 2015; Casellas, 2005). It is generally accepted they can act as fatigue initiation sites and that a reduction in their size will result in an improvement in fatigue performance. For a given alloy chemistry, one of the key parameters affecting the length scale of all three is cooling rate (Mackay, 2000)."

Jan 1, 2017

By L. Vollert

"The application of pneumatically-assisted fluidized bed flotation, specifically the ERIEZ HydroFloatTM technology, has found widespread use in non-sulphide processing (particularly phosphate, potash and coal) for the recovery of coarse particles. In gold processing, centrifugal gravity circuits and flash flotation cells are typically employed for the recovery of coarse and near-size liberated gold which tends to accumulate in recycled grinding streams due to bypass to the classifying cyclone underflow streams owing to the higher specific gravity of these gold particles. Early removal of this gold from the grinding circuits contributes toward the reduction of downstream processing losses as a result of overgrinding and particle shape deformation in the case of flotation processing, longer leach residence times in the case of extractive processing, and surface occlusions in the case of both flotation and extractive processing. Furthermore, recovery to bullion attracts higher payment terms by way of comparison to concentrate sales in the case of copper-gold concentrators. This paper assesses the application of pneumatically assisted fluidized bed flotation for the recovery of coarse liberated gold through the analysis of piloting data generated from the operation of a continuously operated 16 inch ERIEZ HydroFloatTM unit treating a sized coarse grinding circuit stream. The paper presents the stage recovery by size performance of the ERIEZ HydroFloatTM unit together with quantitative gold deportment analysis to demonstrate the efficiency with which gold was recovered during this pilot campaign and then compared to more conventional processing units – centrifugal gravity and conventional flotation.INTRODUCTION Newcrest Mining Limited (NML) has identified that an opportunity exists for improving the recovery of coarse composite particles at its current operations, both as a means for improving overall recovery and as an opportunity for early gangue rejection. As such, Newcrest Mining Limited has taken an interest in the application of pneumatically-assisted, fluidized-bed flotation i.e. ERIEZ HydroFloatTM technology. This interest dates back to 2011 with sighter testwork carried out on their Australian-held ore bodies (Kohmuench et al, 2013). Newcrest continues to assess ERIEZ HydroFloatTM potential for coarse composite recovery and, in the case of the topic of this paper, coarse gold recovery based on examples in the literature which demonstrate the efficiency of this technology in this regard (Carmona Franco et al., (2015); Miller et al., (2016); and Kohmuench et al, 2013)."

Jan 1, 2017

By B. F. Giyani, D. Rahal

"Stirred media mills have proved to be more energy-efficient than the conventional ball milling for fine grinding applications. The mill performance is governed by a number of operating variables including mill stirrer speed, feed particle size, solids content and slurry rheology. A study was conducted to assess effects of mill speed, media size and density, and slurry density on the Stress Intensity (SI) in a VXPmill and thereby the relationship to mill performance. For the mill speeds tested, it was found that the optimum tip speed is 7 m/s. If the speed is too high (12 m/s) energy losses result due to mechanical friction losses and heat generation. If the speed is too low (3 m/s), the kinetic energy is not sufficient to promote breakage. The size reduction ratio increases with the increase in mill speed and the decrease in solids content especially in the coarse fraction particle sizes. The effect of slurry rheology on mill performance was shown by assessing the effects of increasing solids concentration and decreasing particle size. Rheological effects seemed to interact with mill speed such that the mill was less energy-efficient at higher solids content and at higher mill speeds particularly for grinding to fine particle sizes. There is an opti"

Jan 1, 2017

By Gilbert R. Tallard

"Pouring deep foundations by the tremie pipe method is nowadays such a common process that it has becomes an unspecified practice. Means and methods are almost entirely at the contactor’s discretion. A variety of practices are permitted and seldom associated with the discovery of abnormalities and areas of random defects in concrete. This writer wishes to call the attention of stakeholders to the initiation details of the tremie pour operation.KEYWORDSINTRODUCTIONThe advent of slurry as a means of shoring an excavation of relatively small cross section but of possibly great depth has become part of state of the art in foundations construction, with the substitution of said slurry by concrete to provide the structural end product element through the use of tremie pipes. In appearance, there is nothing more simple than pouring concrete into a tremie pipe through a hopper after the basic work has been done i.e. the excavation or drilling, the cleaning of the slurry, the placement of the reinforcing cage, then the tremie concrete pour is almost a reward for a successful achievement. Force of habit has removed the awareness on the process fundamentals for initiating the pour; a variety of practices used call for a review and a reassessment as a means of reducing construction defects that may result from flawed practices, and and especially we are pouring deeper holes. This writer intends to address this issue focusing both on the drilled shaft and the diaphragm wall industries.TREMIE PIPES AND HOPPERSA tremie pipe diameter needs to be sufficiently large to allow the rapid descent of concrete with a minimum of friction loss and avoiding possible bridging in relation to aggregate size. Impervious joints between pipe sections are essential to prevent slurry “raining” over the concrete which can cause concrete segregation pockets and possibly plug the pipe with damaging consequences. That tremie pipes be long enough to reach the bottom may be self-evident but poorly written specifications can be erratic on that subject and seldom specific in terms of inches. A standard pipe of 10 inches is well accepted throughout the foundations industry; double O rings and spline joints are common and function well if properly maintained. However the practice to cover the joint with the ineffable duct tape indicates that all is not always well with this detail. Also, spline cables may shear in case of very long tremie pipes causing the separation of the tremie pipe requiring a restart in midstream with another probable source of inter mixing of concrete and slurry with subsequent defects."

Jan 1, 2017

By G. T. Lapidus, A. Garcés, O. J. Restrepo

"Colombian nickel laterites have historically been processed by pyrometallurgy. However, due to the depletion in ore grades, alternative processes are required. Hydrometallurgical processes, such as pressure acid leaching, have been proposed as alternatives to extract nickel from deposits with suitable characteristics. Such a leaching process requires high concentrations of acid to achieve acceptable extractions, and is not selective. In this study, an alternative aqueous alkaline glycine system has been employed to evaluate the leaching behaviour of a Colombian nickel laterite which contains 1.15% Ni, 0.12% Co and 41.1% Fe. Additionally, the effect of the addition of chloride ions, the use of a reducing agent and the application of a pre-treatment to improve the extraction of nickel were evaluated. Extractions of 4.63% Ni, 42.16% Co and 0.33% Fe were obtained using a 1M solution of glycine at pH 9. In addition, an increase in nickel extraction from 4.63% to 25.68% was achieved by applying a pre-treatment to the sample. The results show that even though nickel dissolution was much slower than in acid leaching, it was selective over other metals such as iron, proving the proposed method to have potential as a process for the extraction of nickel from Colombian laterites.INTRODUCTION Before 2010, most of the industrial operations used pyrometallurgical processes for the extraction of nickel, mainly in saprolitic regions of deposits, with greater contents of the metal. Nevertheless, due to the gradual depletion of such deposits, different hydrometallurgical processes have been studied as alternatives to process those nickel laterites with low grade and those which present problems of refractoriness due to the presence of acid consuming materials (McDonald & Whittington, 2008; Oxley & Barcza, 2013; Wang et al., 2012). However, such leaching processes require high concentrations of acid to achieve acceptable extractions and they are not selective. Facing lateritic nickel ore deposits containing high levels of acid consuming materials, an alkaline leaching medium becomes an advantageous alternative over acidic media, due to the increase in selectivity and decreased corrosiveness and reagent consumption (Tanda, Eksteen, & Oraby, 2017). Unlike conventional acidic reagents used for metal recovery, alkaline reagents can selectively dissolve the desired metal, leaving in the solid residue other elements such as iron, magnesium and aluminum, which are problematic in subsequent stages of metals separation and recovery. Furthermore, there are no serious corrosion problems associated with alkaline leaching, even at higher reagent concentrations, or at elevated temperature and pressure (Ntumba Malenga, Mulaba-Bafubiandi, & Nheta, 2015)."

Jan 1, 2017

By John Shirokoff, Ladan Khaksar

"Cyclic polarization technique and also potentiodynamic measurements were applied to study corrosion behavior of 13% chromium steels in chloride containing environment. Potentiodynamic measurements were performed at 25 and 75 °C with 0, 10 and 20 g/l NaCl in 0.01 M hydrochloric acid solution. At the same time, the significant pitting parameters such as corrosion potential (Ecorr), pitting potential (Epit), protection potential (Epro) and passive current (Ipass) of cyclic polarization curves with various NaCl concentration were analyzed and compared to describe the corrosion behavior of 13% chromium stainless steel. Surface measurement techniques such as SEM and EDS were used for morphology and analysis of corrosion products. The results showed that both temperature and Cl- concentration had significant effects on corrosion behavior of 13% chromium stainless steel in acidic solution.INTRODUCTION Of all the corrosion resistant alloys (CRA) used in oil and gas developments, martensitic stainless steels (MSS) are some of the most common ones these days. These steels not only have the advantages of normal steels: high strength, cost-effective, easy to manufacture, available in a wide variety of product forms, but they also have good CO2 corrosion resistance at higher temperatures as a result of their 11% minimum chromium content. One of the most common types of MSS used in the oil and gas industry is 13% chromium steel. NACE and API standards both reference several different varieties of 13% chromium steels for use in oil and gas projects(“Corrosion Resistant High Cr Steel for Oil and Gas Wells,” 2013). All types of 13% chromium steels have about 12 to 14% chromium and other minor alloying additions, and can be placed into two general groups: conventional and modified. Conventional 13% Cr steels (13Cr) are those most common in oil and gas, some of which are CA6NM (UNS J91150), AISI 410(UNS S41000), and AISI 420 (UNS S42000). These alloys have excellent corrosion resistance when compared to carbon steels up to about 300°F (150°C) and are used for a variety of wellhead, tubular, and downhole components however they have very limited resistance to cracking in H2S (Vallourec Group, 2015). Modified 13% Cr (M13Cr) steels came from the need for increased corrosion resistance at higher temperatures, increased H2S cracking resistance, and increased yield strength above 85 ksi (586 Mpa) primarily for tubular goods and other downhole equipment. These features were developed by taking a conventional 13Cr steel and adding nickel (Ni), molybdenum (Mo), copper (Cu), and other alloying elements. M13Cr provides better corrosion resistance than 13Cr up to about 350°F (177°C), yield strengths up to 110 ksi (758 Mpa), and also improved H2S cracking resistance(“Corrosion Resistant High Cr Steel for Oil and Gas Wells,” 2013)."

Jan 1, 2017