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By T. R. Ellis

"Editor’s Note: This is an expanded abstract. The full report is available on SME’s website at http://www.smenet.org/publications-resources/ resources/sme-valuation-standards-tutorials.The author has three goals for this review of mineral valuation standards internationally.1. To place the SME Standards and Guidelines for Valuation of Mineral Properties (SME Valuation Standards) and International Mineral Property Valuation Standards template (IMVAL Template) within the global context of existing mineral valuation standards.2. To review the current status of harmonization of each International Mineral Valuation Committee (IMVAL) member’s mineral valuation standards (or code) with the IMVAL template and suggest remedies for issues found.3. To suggest future enhancements for the IMVAL Template and SME Valuation Standards, and to suggest future roles for the IMVAL and SME committees. From the author’s review, Ellis draws the following conclusions.The SME Valuation Standards comprise a minimum set of principles-based standards and guidelines for developing and reporting valuations of mineral properties (including petroleum properties) for public and private use, subject to jurisdictional requirements. The standards are also designed to provide mineral valuation guidance that supplements application of the International Valuation Standards Council’s International Valuation Standards (IVS) and the U.S. government endorsed Uniform Standards of Professional Appraisal Practice (USPAP), published by the Appraisal Foundation.The SME Valuation Standards is the first set of valuation standards developed by a minerals institute adopting and modifying the IMVAL template. As a result, the SME standards are essentially totally harmonized and otherwise aligned with the IMVAL template. IMVAL was initially conceived in 2012 as a discussion body to aid harmonization of each member’s valuation standards, by modifying to function the same. IMVAL primarily developed the IMVAL template, published in July 2016, to produce an agreed reference framework of essential mineral valuation guidance content as the goal for harmonization of the Australasian Code for Public Reporting of Technical Assessments and Valuations of Mineral Assets (VALMIN Code), The South African Code for the Reporting of Mineral Asset Valuation (SAMVAL) and the Canadian Standards and Guidelines for Valuation of Mineral Properties (CIMVal standards and guidelines). The harmonization would result from each mineral valuation standards committee modifying its standards to operate similarly to the IMVAL template, producing valuation reports with similar content and value for the same mineral property. The template is also available for other bodies to adopt and modify for their regional setting’s needs, as SME did, or use as a convergence goal when updating an existing standard."

Jan 2, 2018

By E. Jong, E. Watkins

"The application of passive tracer gas sources in underground mines is particularly useful for long-term tracer studies as well as for studies conducted in permissible areas of underground coal mines. The use of passive perfluoromethylcyclohexane (PMCH) sources has been previously demonstrated in underground mines, but this new work details the testing of multiple, distinct tracer compounds compatible with passive sources. A description of their potential application in mine ventilation systems is also provided. Three tracer compounds are detailed: (1) PMCH, (2) perfluoroethylcyclohexane (PECH) and perfluoromethylcyclopentane (PMCP). The release rates of these tracers were examined over a 180-day period at multiple temperatures. The advantages and disadvantages of these sources are presented, along with potential applications in characterizing ventilation circuits, flow through gob and leakage. IntroductionThe use of tracer gases for ventilation applications is an established practice, with various past research projects conducted using sulfur hexafluoride (SF6). Tracer gas techniques have been applied to assess flow rates, dilutions rates and auxiliary ventilation system efficiencies with quick, reliable and accurate results (Suglo and Frimpong, 2002). Perfluorocarbon tracer (PFT) compounds are a new introduction to ventilation and air modeling applications in terms of ventilation flow characterization (Watson et al., 2007).PFTs are liquids that are characterized by low background presence in air, low reactivity, high detectability and low toxicity. A design was proposed, called a permeation plug release vessel (PPRV), to convert PFTs from a liquid to a gas and then release the gaseous tracer in a controlled manner. The initial concept was originally introduced by Brookhaven National Laboratory and refined later to become the PPRV. The PPRV functions by allowing the volatile PFT liquid to become a vapor in a controlled manner. The vapor diffuses through a permeable silicone stopper at a predictable rate proportional to temperature (Zhang and Cloud, 2006)."

Jan 2, 2018

By M. Lundström, J. Aromaa, S. Seisko

"Gold dissolution was investigated in ferric chloride media, promoted as one of the most promising alternatives for cyanide-free gold leaching. The characteristics of gold open circuit potential (OCP) and its relation to gold dissolution rate was investigated. Furthermore, the reaction mechanism of gold dissolution in ferric chloride leaching was discussed. The effect of solution variables, [Fe3+] = 0.02–1.0 M, [Cl–] = 2–5 M, T = 25–95 °C and pH = 0–1.0, on OCP and dissolution rate were studied electrochemically using rotating disk electrode (RDE) and linear polarization resistance (LPR) method with ?cyc = 1000 RPM. The investigated gold OCPs in ferric chloride solutions were found to vary between 597 and 688 mV vs. saturated calomel electrode (SCE) and gold dissolution rates between 1.2·10–5–5.0·10–4 mol s–1 m–2. Increase in temperature (25–55 °C) and ferric concentration (0.02–1.0 M) changed OCP into more positive values, while increase in chloride concentration (2–5 M) decreased it. The logarithm of gold dissolution rate was shown to increase linearly with increasing OCP at the temperature range 25–95 °C, ferric concentration range 0.02–0.5 M and chloride concentration range 2–4 M. A notable increase in the gold dissolution reaction rate was evident at T > 55 °C. INTRODUCTION Currently cyanide leaching is the predominant method used in gold production from primary raw materials (Marsden and House, 2006). However, since the Baia Mare disaster in Romania in 2000, the use of cyanide has been the subject of international concern due to the toxic nature of the chemical posing a significant health threat if exposed to the ecological entities (Hilson and Monhenius, 2006; UNEP/OCHA, 2000). Therefore, several countries e.g., Costa Rica, Czech Republic, Germany, Hungary, Turkey, many states of the USA and provinces of Argentina, have started to ban or limit cyanidation via legislation (Laitos, 2012). Thus, alternative solutions, such as thiourea, thiosulphate, oil-coal agglomerates as well as halides have been investigated in order to replace cyanide as lixiviant (Adams, 2016; Aromaa et al., 2014; Aylmore, 2005; Hilson and Monhemius, 2006; Lampinen et al., 2015). Ferric and cupric chloride leaching have been reported to have advantage over cyanidation being capable to dissolve refractory gold minerals, without pre-treatment such as pressure oxidation or roasting (Angelidis et al., 1993; Lundström et al., 2014; Marsden and House, 2006; van Meersbergen et al., 1993). According to Aylmore (2005), 4% of publications for alternative lixiviants to cyanide in gold leaching were within category oxidative chloride processes including aqua regia and acid ferric chloride leaching. Further, some patents have been granted for ferric chloride leaching of gold (Abe and Hosaka, 2010; Lundström et al., 2016)"

Jan 1, 2018

By J. Fellowes, V. Landais, J. Robson, J. Carr

"Aerospace Al-Zn-Mg-Cu (7xxx) alloys are known to be susceptible to environmentally assisted cracking (EAC). This phenomenon has been studied intensively for many decades, leading to empirically adopted methods to mitigate this problem through overaging and composition design. In parallel, many theories have been developed to explain EAC in 7xxx, but none is yet universally accepted. Today, a number of emerging techniques offer potential to shed new light on EAC in 7xxx. The purpose of the present paper is to demonstrate how X-ray tomography (XCT) combined with electron microscopy can be used to identify the true crack path in 3-dimensions, and hence identify material for site specific electron microscopy analysis. Composition mapping over large areas to high accuracy has been performed using a modern electron microprobe analysis system. This has been combined with transmission electron microscopy to investigate local composition in matrix and precipitates at high resolution. This combination of techniques across length scales offers the potential to provide new insights into the links between local composition, microstructure, and EAC resistance.INTRODUCTION Environmentally-assisted cracking (EAC) is a phenomenon which dramatically decreases the performance of metals and can cause premature failure of large structures. Observed in situations where components were not subjected to critical loads and no widespread corrosion was involved, this type of brittle failure is extremely difficult to predict. The EAC designation covers a number of phenomena, e.g. stress corrosion cracking (SCC), hydrogen embrittlement (HE), corrosion fatigue (CF), etc. Initially identified in steels, EAC can also affect other metals such as high-performance aerospace aluminium alloys, and this phenomenon has been a concern for industries for decades. Extensive research has been conducted on the effects of various environments (moist air, saline water, dry hydrogen gas, etc.) on microstructures and crack propagation, however no consensus has been reached and the exact nature of the mechanisms that control EAC is still being debated (Birnbaum & Sofronis, 1994; Gangloff, 2007; Holroyd & Scamans, 2013; Lynch, 2012; Oriani, 1972; Scamans, Alani & Swann, 1976, Young & Scully, 2002)."

Jan 1, 2018

By Chenyang Zhang, Zhigang Yin, Wei Sun, Jingxiang Zou, Jianyong He, Yuehua Hu, Zhijie Xu

"In this work, a novel compound 4-Amino-5-mercapto-1,2,4-triazole was first synthesized and its selective adsorption mechanism on the surface of chalcopyrite was comprehensively investigated using UV-vis spectra, zeta potential, Fourier Transform Infrared Spectroscopy(FTIR), X-ray Photoelectron Spectrscpy Measurements(XPS), and Time of Flight Secondary Ion Mass Spectrometry (ToF-SIMS) and first principle calculations. The experimental and computational results consistently demonstrated that AMT would chemisorb onto the chalcopyrite surface by the formation of a five-membered chelate ring. The first principle periodic calculations further indicated that AMT would prefer to adsorb onto Cu rather than Fe due to the more negative adsorption energy of AMT on Cu on the chalcopyrite (001) surface, which was further confirmed by the coordination bonding energies of AMT-Cu and AMT-Fe based on the simplified cluster models at a higher accuracy level (UB3LYP/Def2TZVP). The bench scale results indicated that the selective index improved significantly when using AMT as a potential chalcopyrite depressant in Cu-Mo flotation separation.INTRODUCTIONFroth flotation is one of the most important processes to separate valuable minerals from gangue by taking advantage of differences in the physical chemistry of their surface properties(Laitinen et al., 2014), particularly in their surface hydrophobicity. Hydrophobicity differences between valuable and gangue minerals could be regulated by adding different chemical additives (surfactants)(Kor, Korczyk, Addai-Mensah, Krasowska, & Beattie, 2014), such as collector and depressant. It could be conducted economically to selectively separate and enrich the complicated and/or poor ores, by adopting appropriate surfactants. For example, the beneficiation of molybdenite usually relies on a two-stage process to realize flotation separation of molybdenite from other unwanted sulphide ores(Wie & Fuerstenau, 1974). In the first step, a bulk molybdenite concentrate is produced by utilizing kerosene/ diesel oil and pine oil/alcohols as collector and frother, respectively. Second, sodium hydrosulphide, sodium cyanide, ammonium sulphide, or Nokes reagent are adopted as depressants in the separation stage. However, these depressants are usually toxicant and cannot meet the requirements of environmental protection. A large number of efforts have been taken to develop alternative environmentally-friendly depressants (Ansari & Pawlik, 2007; J. H. Chen, Lan, & Liao, 2013; Li et al., 2015; Yin, Sun, Hu, Zhai, & Guan, 2017; Yin, Sun, Hu, Zhang, Guan, Liu, et al., 2017; Yin et al., 2016). Although some novel and environmental-friendly depressants have been reported to achieve good performance in Cu-Mo flotation separation at a laboratory scale, there are still some challenging problems, including toxicity, high price or poor performance in practice, which severely limit their practical applications in Cu-Mo flotation separation on a commercial scale."

Jan 1, 2018

By Shawna Munn, Jakub Hudler

This paper outlines the use of tunneling headwall softeyes for transit construction projects in the Greater Toronto Area (GTA) over the past decade. Due to spatial constraints, tunnel boring machines were used to construct the underground tunnels requiring the design of launch and exit shafts with headwall softeyes to facilitate tunneling operations. Variable ground conditions and shaft geometries lead to the development of innovative headwall and tunnel softeye design applications using fiber reinforced polymer (FRP) elements (beams, reinforcing bars, and tiebacks). This paper outlines the challenges and benefits associated with designing and constructing shafts using various systems. Lessons learned throughout design and construction of more than 20 structures over the past 10 years are outlined. The constructability challenges with using FRP and design performance are also discussed. For over a decade, the City of Toronto has been expanding its metropolitan transit network with a variety of new transit construction projects. Two recent projects in the Greater Toronto Area (GTA) for underground infrastructure include the Toronto York Spadina Subway Extension and the Eglinton Crosstown Light Rail Transit project. These add a total of 31 new stations and 18.6 km (11.5 miles) of underground transit (TTC 2017) (EllisDon 2016). Due to ground conditions and spatial constraints of existing surface infrastructure, these projects utilized tunnel boring machines (TBMs) to construct the underground tunnels requiring the design of various types of shafts and headwalls to facilitate underground tunneling operations. To allow for tunneling through the headwalls, these shafts were designed with “softeyes” - a section of the wall without metal reinforcement that allows the TBMs to tunnel through.

Jan 1, 2018

By P. Coghill, P. Revell

"Geo-sensing is the ability to routinely measure or infer rock properties at a range of scales using non-destructive scanning devices. These devices can provide information and data flows to support integrated decision making across the minerals value chain. Geo-sensing has been used for many years in minerals exploration using technologies such as satellite imaging and airborne geophysics but to date the use of sensing technologies in between the mine and mill has been very limited. The aim of this research is to develop new mineral sensing technologies that can enable grade engineered ore streams through the rejection of low value gangue or deleterious elements either in the pit or during transfer to the mill. This paper focusses on the research and development being carried out by the Cooperative Research Centre for Optimising Resource Extraction (CRC ORE) and its associated members on new sensing technologies. At the start of their development these technologies were classified on the Technology Readiness Level scale at 3 (TRL3), equivalent to a proof of concept. Laboratory testing and design is aimed at progressing these sensing technologies to TRL5 which is ready for testing at an end users site. New data obtained during the laboratory testing and design phases are presented in the paper demonstrating performance specifications such as detection limits and measurement speed which can be used to infer the pod size of gangue that can be rejected at scale. Grade Engineering® and coarse gangue rejection are considered as key drivers for the mining industry to address the higher mining, processing and environmental costs associated with ore bodies with declining grades. This is an industry wide problem and the development of mineral sensors is seen as key enabling technologies for Grade Engineering® and coarse gangue rejection. The technologies presented in this paper enhance value through early decision making of ore quality and improve the overall resource value case through improved grade and throughput engineering."

Jan 1, 2018

By Chi Zhang, Junyi Wu

"With the increasing popularity of lithium cobalt oxide in lithium ion battery industry, which is driven by new energy vehicle and mobile device applications, the demand of cobalt is also growing rapidly in recent years. There is a significant trend of increasing investment on cobalt capacity in China, and the automation renovation is considered as an option of improving production efficiency. This study aimed at evaluating the practicability of stainless permanent cathode blank and automatic stripping process in cobalt electrowinning process. The purpose is to replace the old starter sheet process in cobalt electrowinning, which so far was used by most of cobalt refineries in China, but very labor intensive and exposed operators to serious aerosols that contained both cobalt and acid. In the old starter sheet process, the initial cobalt starter sheet is produced onto a plate made of titanium, while the titanium cathode blank and hanger bar fit the critical corrosive environment but is lack of mechanical strength for automatic production which has been mature in copper electrowinning process. To evaluate the proper materials instead of titanium, the coupon corrosion tests with different raw materials including 316L and other stainless steel grades were held for several months in production environment at a cobalt tank house in China. Following the comparison between titanium and other tested materials, a pilot production test in a cobalt tank house is also on-going.INTRODUCTION Cobalt has been known in early China and used in pottery glazes, and the ancient Greeks and Romans used its compounds to make colored glass since long time ago. The blue on the colored porcelain from the Tang Dynasty in China was also due to the presence of cobalt compounds. The word cobalt is known being derived from the German kobalt, from kobold meaning ""goblin"", because the cobalt-bearing blue ore, CoAsS, was called kobaltin in Europe in the Middle Ages, it may have been thought to be harmful to the health of the miners because of arsenic in the ores."

Jan 1, 2018

"INTRODUCTION Twin Metals Minnesota (TMM) (operating as a joint venture between Duluth Metals and Antofagasta PLC) assumed control of the property in 2010. Amec became involved with the project in 2011 and in 2012 incorporated additional drilling in order to update historic resource estimates. The Maturi geological model and resource estimate was updated in 2014 to incorporate additional information obtained during 2013 and 2014 drill campaigns. In 2017, Amec was purchased by the Wood Group and is now known as Wood. Geology The Twin Metals Minnesota (TMM) Maturi, Maturi Southwest, Birch Lake, and Spruce Road properties are located in northeastern Minnesota (Figure 1). This talk discussed the Maturi deposit only, although all four deposits share similarities. The following geology is summarized from Peterson and Severson (2002).Maturi lies within the Superior Province of the Canadian Shield which is exposed in central and northeastern Minnesota and extends northward into Ontario. In eastern Minnesota, the Midcontinent Rift System developed during crustal scale extension in the Mesoproterozoic Era. The rift system is traceable, as exposures of mantle-derived tholeiitic to subalkaline mafic lava flows, intrusives, and rift-filling fluvial sedimentary rocks, and in the subsurface as a gravity anomaly (high), from the eastern end of Lake Superior, arcing west across the lake basin, and extending south-southwest to northeastern Kansas. Intrusion of the Duluth Complex, circa 1,108 - 1,099 Ma, was related to rifting and is co-genetic with the North Shore Volcanic Group mafic volcanic rocks that form the hanging wall of the Duluth Complex to the east. Cu-Ni-precious metals (PM) mineralization including Pt, Pd, Au and Ag within the Duluth Complex is hosted by mafic to ultramafic intrusive rocks that are part of the overall intrusive complex. The Duluth Complex is defined as a more or less continuous mass of mafic to felsic plutonic rocks that extends northeastward for more than 170 miles (275 km) in an arcuate fashion from Duluth nearly to Grand Portage in Minnesota. It is bounded by a footwall of Paleoproterozoic sedimentary rocks and Archean granite-greenstone terranes (Peterson and Severson, 2002), and a hanging wall largely of comagmatic anorthosite, rift related flood basalts, and hypabyssal intrusions of the Beaver Bay Complex. Mineralization is hosted in the basal mineralized zone (BMZ) of the South Kawishiwi Intrusion (SKI). The SKI magmas intruded sub-horizontally between hangingwall Anorthositic Series (AN) rocks and footwall granitic rocks of the Neoarchean Giants Range batholith (GRB). The Maturi local geology and the deposit footprint (shaded orange) is shown in Figure 2."

Jan 1, 2018

By Mary Ellen Bruce Large, Antonio Marinucci, Silas C. Nichols

Tip post-grouting of bored pile (drilled shaft) foundations refers to a method where cementitious grout is injected beneath the tip of a shaft to improve the overall performance of the constructed foundation. This technique, when performed satisfactorily and in the appropriate ground conditions, enhances axial load-displacement performance by improving the mobilization of pile’s resistance. Potential benefits associated with tip post-grouting include reduced settlement under loading, better alignment of load transfer curves, and improved ground beneath the base of the bored pile. However, to be able to realize the benefits attributed to this method, the design, construction, of both the bored pile and the post-grouting system must meet a minimum level for quality assurance. The various factors affecting the successful installation and performance of a bored pile (e.g., workmanship, base cleanliness, borehole integrity, and concrete placement) have been discussed by numerous practitioners and researchers in the available technical literature. For a conventional (i.e., ungrouted) bored pile, acceptance is based on a combination of visual inspection, material testing, and the results of integrity and/or performance testing of the constructed pile. A properly executed tip post-grouting program can be a relatively comprehensive and complex process, which is typically evaluated throughout the construction process based on the results of prior projects and/or on test pile(s) at the particular site. For tip post- grouting programs, verification procedures and acceptance criteria should be established during and incorporated into the design process to ensure design intent and objectives are achieved. Project specifications should be produced to ensure performance requirements are achieved. This paper will present and discuss factors affecting the successful execution of tip post-grouting, including grouting criteria, instrumentation, reliability and uncertainty with the method and outcome, and verification and acceptance. INTRODUCTION Constructing bored piles (drilled shafts) is increasingly more challenging given the lack of ideal site locations, tight project site confines, difficult or restricted access, greater demands on drilling equipment, and close proximity to adjacent structures. To evaluate the feasibility of bored piles as an appropriate foundation system, a myriad of factors is evaluated during design, including site conditions and constraints, budgeting and scheduling, reliability and risk exposure, presence of and depth to adequate load bearing soils/rock, and the magnitude of the imposed loading. Moreover, updated design codes increased load demand per element, and improved material strengths have led to more complex foundation designs, larger foundation elements, and significant increases in load magnitude. Monopile (monoshaft) foundations have been utilized where one large bored pile is used in lieu of a group of piles connected via a pile cap. In addition, to accommodate the design criteria, site conditions, and imposed loading, the geometry of the bored piles being designed and installed have been as large as 13 feet (4 m) or greater in diameter and to depths in excess of 260 feet (80 m).

Jan 1, 2018

By R. Batterham

"The history of mineral processing is indeed long and has always been tied to mining methods of the day. While many new processes and devices have been developed, the most significant trend in recent times has been the ever increasing scale of operations. There is serious doubt this ongoing trend is enough to match the global trend of falling grades and rising energy demands needed for mineral processing. As well we see that globally, the social licence to operate for mining (and hence mineral processing) is far from secure. Indeed, some argue that mining as we know it is dying and in the future, mining will be much more environmentally secure, even to the extent of insisting upon “in place” recovery and only bringing to the surface the valued product. In this paper we comment on the ramifications of broader uptake of more sustainable mining for mineral processing methods and address the specific question of whether recent progress in in place recovery will lead to a timely breakthrough. The answer proposed is that this is possible in the next 10 - 20 years but in the meantime, the focus is just as likely to be on removal of waste much earlier in circuits. Either way, mineral processing as we know it will change significantly. INTRODUCTION Mineral processing has a long history well covered in a recent publication (Habashi, 2006) who points out “the ancient Egyptians knew already that it would be easier to melt an earth rich in gold particles than another which is poor. As a result, all efforts were made to enrich the gold by washing away the light gangue minerals. Similarly, another ancient method for enriching gold particles from a river stream was by means of fleece, hence the Greek myth of the “golden fleece”. Since the middle ages, striving for improved economics has driven a string of innovative developments in milling and separation. The reader is again referred to the informative and illustrative text by Habashi."

Jan 1, 2018

By Satyajit Vaidya, Rudolph Frizzi, Luis Berroteran

This paper presents design and construction challenges associated with a high-capacity rock-socketed drilled pile foundation system for a 60-story building recently constructed in an urban environment. The site is in very close proximity to surrounding 1-to-6-story buildings and a commuter rail subway tunnel structure. High compression, uplift, and lateral loads imposed by the tall, slender tower constructed over a relatively small site footprint posed a significant design challenge due to the close proximity of the subway tunnel and other structures. Construction challenges included those associated with advancing the drilled pile casings through overburden materials using internal flush method mandated by the Transit Agency, advancing the casings through very dense glacial till materials encountered above top of rock, and drilling rock sockets in variable rock conditions. This paper provides a brief overview of the site and subsurface conditions, and discusses the resulting design and construction challenges for the drilled pile foundation system and how they were addressed. SITE AND SUBSURFACE CONDITIONS The 8,350-square-foot site is located in a busy neighborhood in downtown New York City (NYC). Buildings neighboring the site are supported on shallow foundations, and their basements extend about 15 feet below the sidewalk level. A NYC-Landmarked building is located within a NYC Department of Buildings (DOB)-designated 90-foot influence limit from the Project site. NYC Transit Authority (NYCTA) subway tunnel and station structures are located in close proximity to the Project site. The subway tunnel structure extends about 50 to 55 feet below the sidewalk level. Although the upper portion of the tunnel structure is about 13.5 feet away from the site property line, the lower portion is only about 1 foot away from the property line. A site location plan is presented as Fig. 1. Geotechnical borings revealed subsurface conditions generally consisting of successive strata of surficial fill, sandy and silty soils, and glacial till (predominantly consisting of cobbles and boulders) overlying mica schist bedrock. A generalized subsurface profile is presented in Fig. 2. The surficial fill stratum was about 10 to 23 feet thick, and generally consisted of loose to medium dense sandy soils with varying proportions of silt, gravel, and miscellaneous debris such as brick. The underlying sandy and silty soil stratum was about 60 to 79 feet thick and generally consisted of loose to medium dense inter-bedded layers of fine to coarse sand, silty fine sand, and silt. The underlying glacial till stratum was about 26 to 70 feet thick and generally consisted of cobbles and boulders embedded in a very dense soil matrix. Top of bedrock was encountered in the borings about 110 to 150 feet below sidewalk level. Groundwater level was measured at about 30 feet below sidewalk level.

Jan 1, 2018

By L. Gutierrez, M. Jeldres, R. J. Jeldres

"Clays are present in a large number of mineral deposits and are commonly found as gangue. Its complex chemical structure, characterised by anisotropic surfaces, makes its presence a permanent challenge for flotation operations, increasing the reagent consumption, decreasing the quality of the concentrate, and changing the rheological properties of the system. In this context, the main objective of this research is to improve the floatability of chalcopyrite minerals in the presence of clays by using guar gum, a low molecular weight organic polymer, which acts as a surface coating agent for clays. Clay Minerals Society provided the kaolinite sample and the chalcopyrite sample was purified from mineralized rock specimens obtained from Ward’s Natural Science Establishment. Micro flotation tests were carried out in a 150 cm3 Partridge-Smith cell, using compressed air as the gas phase at a flow rate of 80 cm3/min. Potassium amyl xanthate (PAX) and methyl isobutyl carbinol (MIBC) were used as a collector and a frother, respectively. The results showed that the use of guar gum improves the recovery of chalcopyrite in the presence of kaolinite because it induces the formation of clay aggregates that settle by gravitational effects, preventing the 'coating effect' and decreasing excessive collector consumption. pH played a key role in the guar gum performance, which was most effective at highly alkaline conditions (pH 11), where the copper recovery improved from 73% to 90%. The work has significant implications for the mineral flotation in the presence of clay minerals.INTRODUCTION The mining industry is continuously confronted with challenges that alert the sustainability of the sector. There is little availability of water, the grade of the deposits are getting smaller, and the gangue is becoming more complex. Usually, clays are part of the gangue in numerous systems, including copper ore, porphyry, nickel, platinum, etc. (Senior & Thomas, 2005). The structure is mainly composed of layers of tetrahedral silica (T) and octahedral alumina (O) that join in certain proportions: 1: 1 (T-O) and 2: 1 (T-O-T) (Theng, 2012). Also, they expose two crystallographically different surfaces: the faces, which tend to be negatively charged, and the edges, which carry a charge that changes from positive to negative depending on the pH (Van Olphen, 1977). One of the most common clays in copper deposits is kaolinite, whose structure is composed of an octahedral sheet of gibbsite bound to a tetrahedral silica sheet in the ratio 1:1"

Jan 1, 2018

By Eric R. Borys, Amaneh E. Kenarsari, Brett Gitskin

This case study discusses impacts of excessive Earth Retention System (ERS) lateral movement at a project in city of Chicago. The ERS (cantilevered sheeting) moved inward towards the excavation and caused lateral displacement and cracks in six drilled shafts located about 1 to 2 lateral feet (0.3 to 0.6 m) from the face of the sheet pile wall. Up to 9 inches (23 cm) of horizontal movement was observed on top of the supporting sheet-pile. Similarly, survey measurements showed the top of the drilled shafts moved laterally up to 8 inches (20.3 cm). To evaluate the cause of failure and determine a remediation solution, the soil, shaft and site conditions were investigated. Pile Integrity Tests (PIT) were conducted at the affected drilled shafts. The shafts with identified anomalies were cored and video-recorded. The cause of the failure was determined to be related to variable soil conditions across the site, deeper excavation (i.e., increased effective ERS wall height), and other differences between design and as-built conditions. Internal bracing, in the form of walers and rakers, was installed to limit further movement of the sheet pile as a short-term solution, with additional grade beams framed into the basement slab-on-grade as a long- term solution. Five of the six cracked shafts were spliced with reinforcing bars and high strength grout and one shaft was replaced. INTRODUCTION The subsoil in the Chicago Area mostly consists of glacial till clays underlain by water-bearing granular soil over bedrock. The glacial clays have very soft to medium consistencies for a typical thickness of 30 to 50 feet (9.1 to 15.2 m) below which hard clays (Hardpan, i.e., heavily over-consolidated clay soils) are encountered. The soft clays are often referred to as the “Chicago Blue Clay”. Beach Sands are also found above upper soft clays in several areas, especially within a three-mile strip near Lake Michigan (Peck and Reed 1954). Due to the existence of soft clay in Chicago area, supporting the mid to high rise buildings on drilled shafts extended to Hardpan is a common practice in modern building design. In the early 19th century it used to take about 3 weeks to excavate 1 shaft hole and about 1½ days to fill the shaft with concrete in Chicago (Manierre 1916). The early 19th century methodology of excavating a shaft consisted of hand digging the shaft, installing wood lagging as temporary shoring with spoils removed with a rope and pulley system from the surface. Today, the excavation of a typical drilled shaft in Chicago uses heavy drilling equipment and requires much less time for excavation and concrete placement. It is not uncommon for contractors to excavate shafts and place concrete at a rate of about 2 to 5 drilled shafts per day (with one drill rig).

Jan 1, 2018

By A. O. Gapchich, T. N. Matveeva, N. K. Gromova

"Tin sulfide ores and aged man-made products obtained after their processing are distinguished by a complex material composition and uneven impregnation of sulfide minerals (chalcopyrite, galena, arsenopyrite, etc.) and tin ore (cassiterite). Enrichment of such ores is performed through sophisticated multistage schemes using not only gravitational methods, but also gravity flotation, flotation, magnetic separation techniques. Tin ores also contain rare and precious metals (indium, scandium, silver), characterized by fine dispersity and microscale to nanoscale fineness of mineral formations. During flotation concentration these metals are extracted along with the main ore minerals into concentrates (tin, copper, tungsten, etc.), however, up to 10-20 % of them are lost with final tailings. The aim of the work is an experimental study of the modification of the surface of sulfide minerals and cassiterite by stable metal-collector complexes to increase extraction of fine tin, silver, copper and other metals from complex tin ores. Triamide cyanuric acid (TCA) was studied as a thin silver flotation modifier. Thermophilic polymer with a functional group of phenylphosphine TMPPh was used as a selective flocculant. For experimental studies of the physical and chemical effects of collecting agents on the surface of minerals the following analytical techniques were used - the analytical scanning electron emission ASEM (LEO 1420VP INCA OXFORD ENERGY 350) and laser (KEYENCE VK-9700) microscopy, measurements of electrode potentials of mineral anthills by potentiometric titration, monomineral and pulp flotation. New data on formation of the adsorbed layer of DBDTC on the surface of chalcopyrite, galena and arsenopyrite were obtained, and the dimensions of the reagent films and the strength of their adsorption. The indiscriminateness of cassiterite to DBDTC ensures its selective separation into a chamber product during the flotation of sulfides. It is shown, that modification of the sulfide surface by stable complexes Me-DBDTC and Ag-TCA-TMPPh will increase the recovery of non-ferrous metals and silver into a collective sulfide concentrate and will provide a high-quality tin concentrate for flotation of tin sulfide ores.The studies were perfomed with the aid of the Russian Science Foundation (Project No. 17-17-01292).INTRODUCTIONTin sulfide ores and aged man-made products obtained after their processing are distinguished by a complex material composition and uneven impregnation of sulfide minerals (chalcopyrite, galena, arsenopyrite, etc.) and tin ore (cassiterite). Enrichment of such ores is performed through sophisticated multistage schemes using not only gravitational methods, but also gravity flotation, flotation, magnetic separation techniques. Tin ores also contain rare and precious metals (indium, scandium, silver), characterized by fine dispersity and microscale to nanoscale fineness of mineral formations. During flotation concentration these metals are extracted along with the main ore minerals into concentrates (tin, copper, tungsten, etc.), however, up to 10-20 % of them are lost with final tailings. In this regard, it seems advisable to use new varieties of flotation reagents in order to increase extraction of finely dispersed tin, silver, copper and other non-ferrous and precious metals from multi-metal tin ores (Bocharov and Ignatkina, 2007; Khanchuk etal., 2012; Wu and Zhu, 2006; Yusupov etal., 2016)."

Jan 1, 2018

By J. M. Ortiz, J. Haas, W. Kracht, G. Pamparana

This work explores the effect of ore hardness variability on the design of a solar photovoltaic system with battery storage and grid backup, to operate a semi-autogenous grinding mill (SAG). First, a case of two synthetic ore populations was studied, without any consideration of spatial distribution. The mean and variance of the ore hardness (measured in specific energy consumption, SEC) of both populations were subjected to a sensitivity analysis. The operation was evaluated with one and two stockpiles. The latter allows classifying according to ore hardness as a way to adapt the SAG energy consumption to the solar cycle. The results show that using two stockpiles allows achieving a larger autonomy (i.e. less energy imports) at lower total costs, especially when the difference of mean hardness between the two populations is large. The difference in variance (between the two populations) has a smaller impact on the design recommendations. Second, a case study was performed considering the spatial distribution of geometallurgical units. Two cases were considered: (a) brownfield, when there is historical information of the actual variability of the ore hardness; and (b) greenfield, when the system design relies mainly on geometallurgical modeling. Brownfield and greenfield planning result in similar sizing recommendations of the solar power plant, if precise drill cores are available. In this case, geometallurgical modeling is an effective tool for forecasting the energy demand necessary for designing the power plant.

Jan 1, 2018

By S. Onuki, T. Ando, M. Tejima, R. Enomoto, Y. Okada

"Al–Si–Cu–Mg die casting alloys are widely used in the automotive industry, and recent advancements in high pressure die casting technology enable heat treating products to achieve desirable properties. However, CO2emissions associated with die-casting production lines should be reduced to address the global warming issue. In this study, the relation between the microstructures and thermal stability of precipitates formed during isothermal aging at 423, 485, and 558 K of Al-11.0 mass%Si-1.8 mass%Cu-0.2 mass% Mg (JIS ADC12) was investigated using Vickers hardness tests and transmission electron microscopy (TEM). The hardness tests and TEM results showed that Si compounds and Al–Cu compounds enhanced the mechanical properties of the alloy and that the predominant compound affecting the mechanical properties differed between specimens treated at 423 K and those treated at 558 K. Moreover, additional aging at 423–458 K resulted in a material with a Vickers hardness higher than that of the isothermally single-aged material. Differential scanning calorimetry, differential elemental analysis, and selected-area diffraction analysis using TEM suggested that the combination of Al–Cu compounds precipitated at low aging temperatures and Si compounds precipitated during preliminary aging increased the mechanical strength, resulting in a maximum hardness of 130 HV.INTRODUCTIONAl–Si–Cu–Mg die casting alloys have well-balanced mechanical properties, machinability, and cast ability. These alloys are therefore widely used in the automotive industry because of their superior characteristics, accounting for>90% of the aluminum used in die casting production. As a substitute for iron-based materials, these alloys have contributed to the development of lightweight vehicles.Dong et al. (2014) reported that the heat treatment of die casting materials is effective for changing their dimensions under high temperatures as a result of the precipitation of solid-solution elements. Recent advancements in high pressure die casting technology have led to the application of heat treatments of Al–Si–Cu–Mg alloy products to reduce fuel consumption and satisfy customer needs. Although attempts to reduce CO2emissions have focused on fuel consumption in cars and fuel efficiency regulations have become increasingly strict in recent years, CO2discharged from production lines should also be reduced without adversely affecting the properties of the product. Heat treatments for artificial aging after solution treatment (T6 treatment) and after casting (T5 treatment) are CO2discharge sources, which together with a holding furnace account for >80 % of the CO2discharged during the casting process."

Jan 1, 2018

By J. Awmack, M. A. Tomlinson, P. J. Lind

"Peñasquito is a complex polymetallic deposit containing gold, silver, lead, zinc, and copper and is one of the largest producers of gold in Mexico. Mining activity is currently transitioning to a second open pit, Chile Colorado, which will be mined concurrently with the existing open pit, Peñasco. The ore bodies are located within diatreme pipes and into the surrounding sediment formation. In the coming years, mining will be carried out in more sedimentary zones, which are significantly higher in organic carbon content. Organic carbon in the feed influences both flotation and leaching operations. Several changes are being implemented to the Peñasquito flowsheet to mitigate the effects of increased organic carbon in the plant feed. These include the use of alternate reagent schemes, construction of a carbon pre-flotation circuit, implementation of a pre-leach flotation circuit ahead of pyrite leach, and evaluation of a tertiary process for separation of carbon and precious metal minerals.INTRODUCTION Goldcorp’s Peñasquito operation is located in the Mexican state of Zacatecas, approximately 200 km from the city of Zacatecas in the Mazapil municipality (Figure 1). Peñasquito has been in operation since 2009, with mining carried out by open-pit methods. Oxide ore has been processed in a heap leach facility and sulfide ore is treated in the sulfide processing plant. The processing capacity of the sulfide plant is 130,000 tonnes of ore per day and in 2016 production amounted to 465,000 ounces of gold, 17.6 million ounces of silver, 109 million lb of contained lead in lead concentrate, and 263 million lb of contained zinc in zinc concentrate (Goldcorp Inc., 2017). To recover more of the contained gold and silver and to mitigate the impact of increasing organic carbon content in the ore, a number of significant changes are being made to the operation."

Jan 1, 2018

By E. G. Ozhogina, O. B. Kotova

"The ores of black, non-ferrous, rare, noble metals are mostly distinguished by a variety of mineral types and complexity of their material composition. This article is devoted to the promotion of the concept of mineral processing in modern realities of the deficit of high–grade ores and increase in their demand. Normative and methodical documentation for specific types analysis with the definition of the field of application are presented in this paper. . For example, the pyrochlore-monazite-goethite ores from one of the deposits from Eastern Siberia - Chuktukonskoe ore field were tested. The development of mineralogical methods and testing of specific raw materials are shown. The method of small-angle X-ray (and also synchrotron) scattering, which was developed for solving problems associated with structural high-resolution diagnostics, was tested for bauxites of Vezhay-Vorykvinskoye field.INTRODUCTION A highly intense production of many types of mineral deposits results in gradual depletion and of mining-geological and mining-technical conditions of various ore reserves ?. Relatively easily accessible and rich deposits are getting depleted in the first place, and it is necessary to involve low grade and refractory ores into production and processing. Traditional technologies can hardly be applied (Chanturia, 2017; Bazin et al., 2014; Ponaryadov, 2017). The urgency of development of the concept of technological mineralogy focuses on the confirmation of new methods and approaches to the development of mineral deposits, creation of scientific and methodological pre-requisites for solving the problem of rational development of mineral deposits, maximum extraction and integrated application of all minerals (both principal and associated), expansion and strengthening of mineral and ores.The article is aimed at updating tasks that should be addressed within the applied mineralogical research: – forecast of quality of ore at early stages of exploration and technological indicators for the redistribution of properties ore, – interactive monitoring of these indicators by mineralogical and analytical methods;"

Jan 1, 2018

By Juan J. Monsalve, Nino Ripepi, Richard Bishop, Jon Baggett

"Terrestrial laser scanning (TLS) is a useful technology for rock mass characterization. A laser scanner produces a massive point cloud of a scanned area, such as an exposed rock surface in an underground tunnel, with millimeter precision. The density of the point cloud depends on several parameters from both the TLS operational conditions and the specifications of the project, such as the resolution and the quality of the laser scan, the section of the tunnel, the distance between scanning stations, and the purpose of the scans. One purpose of the scan can be to characterize the rock mass and statistically analyze the discontinuities that compose it for further discontinuous modeling. In these instances, additional data processing and a detailed analysis should be performed on the point cloud to extract the parameters to define a discrete fracture network (DFN) for each discontinuity set. I-Site Studio is a point cloud processing software that allows users to edit and process laser scans. This software contains a set of geotechnical analysis tools that assist engineers during the structural mapping process, allowing for greater and more representative data regarding the structural information of the rock mass, which may be used for generating DFNs. This paper presents the procedures used during a laser scan for characterizing discontinuities in an underground limestone mine and the results of the scan as applied to the generation of DFNs for further discontinuous modeling.INTRODUCTIONAccording to the Mine Health and Safety Administration (MSHA), between 2006 and 2016, the underground stone mining industry had the highest fatality rate in 4 out of 10 years, compared to any other kind of mining (MSHA, 2016). Additionally, during that same time, 40% of the fatalities were due to ground control issues, such as roof and rib collapses and pillar bursts. The National Institute for Occupational Safety and Health (NIOSH) developed guidelines for designing underground stone mines (Esterhuizen, Dolinar, Ellenberger, and Prosser, 2011). However, these guidelines do not apply to all underground stone mines.Monsalve, Baggett, Bishop, and Ripepi (2018) present a case study of an underground limestone mine experiencing a structurally controlled mode of failure. The authors analyze different methods to study that type of instability. They conclude that the integration of terrestrial laser scanning (TLS) with discrete element modelling (DEM) can be used to prevent rock falls in underground excavations to enhance worker safety. However, an adequate rock mass characterization and structural mapping must be performed in order to generate reliable models that allow the engineer to have a better understanding of the rock mass behavior."

Jan 1, 2018