Search Documents

By P. C. Holloway, A. Tshilombo, T. Xue, M. J. Collins, R. Lopetinsky, I. Mihaylov, I. M. Masters

The Voisey’s Bay deposit contains a trace amount of cadmium, which reports to solution during pressure leaching of the nickel concentrate at Vale’s Long Harbour Hydrometallurgy Plant, and must be removed to produce high quality nickel cathode. In 2006, Vale approached Sherritt Technologies to collaborate on the development of a process for removing cadmium to low levels (<1 mg/L) in the nickel raffinate. Following successful bench scale and pilot plant testing at Sherritt’s laboratories, the cadmium removal process was then moved through engineering and construction, culminating in the successful commissioning and startup of a cadmium removal circuit at the Long Harbour Hydrometallurgy Plant in 2017. This paper presents the results of this collaboration and the challenges that were encountered through each stage of development, as well as current results from operation of the commercial cadmium removal circuit. INTRODUCTION Vale’s Long Harbour Processing Plant, with a nameplate capacity of 50,000 t/y nickel, began operation in 2014. In addition to electrolytic nickel rounds, the plant also produces electrolytic cobalt rounds and copper cathode. The Long Harbour Processing Plant uses a unique hydrometallurgical process developed by Vale Base Metals Technology Centre, as shown in Figure 1, to treat a nickel sulphide concentrate produced at the Voisey’s Bay mine and mill located in northern Labrador (VBN concentrate) (Stevens et al., 2009).

Jan 1, 2019

By K. C. Sole, G. Robinson, M. S. Moats, W. G. Davenport, S. Sandoval

Global practice in hydrometallurgical production of copper cathode by electrowinning is reviewed, based on individual plant operating data for 2018. Data from 29 plants were collected, representing 38% of world cathode copper production. Similar surveys were carried out in 1997, 1999, 2003, 2007, and 2013. This survey includes analysis of historical and current data. Evolving trends in operating conditions and performance, as well as equipment design and process technology choices, are analysed and differences in operating practices with location are assessed. Examples of recent technology and operational choices to increase productivity, improve copper quality, and decrease electrical energy consumption are discussed. Significant project expansions, particularly in Africa, and the consolidation of numerous small Chinese operations are also presented. INTRODUCTION Global trends and operating practices in copper electrowinning (EW) in 2018 are reviewed and evaluated. Similar world and African surveys were carried out in 1997, 1999, 2001, 2002, 2003, 2007, and 2013 (Robinson, Davenport, & Jenkins, 1997; Jenkins, Davenport, Kennedy, & Robinson, 1999; Davenport, Jenkins, Robinson, & Karcas, 2001; Robinson, Garbutt, & Davenport, 2002; Robinson, Davenport, Jenkins, King, & Rasmussen, 2003; Robinson, Davenport, Moats, Karcas, & Demetrio, 2007; Robinson, Sole, Sandoval, Moats, Siegmund, & Davenport, 2013). Contributing operations included sites from the USA and Mexico (9), Chile and Peru (6), Laos (1), Kazakhstan (1), and Africa (9). Despite fewer contributions compared with past experience, this survey nevertheless represents 2018 copper EW cathode production of 1.76 Mt, or about 38% of world production of 4.64 Mt (International Copper Study Group, 2017). This drop in permission to contribute is attributed to the more competitive nature of the industry and unprecedented production pressures; furthermore, several operations in Australia have shut down, while large operations that are currently commissioning or ramping up to full production in Africa and Asia declined to participate. Of the Chinese operations, which represent an increasingly important proportion of global electrowon cathode copper, particularly in Africa, only Tenke Fungurume (Democratic Republic of Congo; DRC) participated in this survey.

Jan 1, 2019

By Francisco Sena Leite, Pedro Brito, Gean Frank, PhD Soeiro de Carvalho, Jose, Vinicius Miranda

The consequences of rock blasting with explosives are directly related to the accuracy of drilling and, because they have an effect on fragmentation and ground level, they should be controlled to ensure a problem free production, increase work safety and reduce environment impact. Safety control is one of the most important processes in detonation, since it can compromise the worker security on site and, eventually, neighboring communities. Due to the technology advancements, it is possible to build a hole deviation control device with “of the shelf” parts, and for that reason the authors decided to evaluate the possibility of measuring hole deviation by creating a portable prototype using an electronic sensor capable of measuring the acceleration on objects, that is, to measure the own acceleration of a system, known as "accelerometer" and a micro-controller to handle and treat data. The main idea behind this paper is to validate the power of the Euler method, given the stepping limitations of the sensor and micro controller in order to reproduce of the hole shape. A case study was carried out, comparing the measurements of borehole deviations made by a traditional equipment and the prototype. A mobile application was also created in order to recover and treat and display the data to the user. For validation of the prototype, several holes were measured using the two devices. A residue analysis was used to validate the data obtained. After analyzing and confirming the effectiveness of the new equipment, the normality tests prove a symmetric distribution with null expected residual mean and minimum variance. Consequently, the accuracy of the prototype is evidenced. Thus, the authors aspire to emphasize the potential of using these sensors allied to a traditional numerical method for analysis of hole deviation.

Jan 1, 2019

By Li Qihou, Liu Zhihong, Liu Zhiyong, Yao Wei

Black copper sludge, which mainly contains copper, arsenic and a little antimony, bismuth, selenium, tellurium, is an important recyclable secondary resource. In this paper, selective removal of arsenic from black copper sludge by alkaline oxidative pressure leaching was studied. The influences of alkali concentration, leaching time, leaching temperature, oxygen pressure, liquid-solid ratio and other variables on the leaching rate of arsenic, copper and tellurium were investigated. The results were as follows: when the leaching process was conducted at initial alkali concentration of 1mol/L, liquid-solid ratio of 10, stirring rate of 500r/min, leaching temperature of 140°C for 5 h and oxygen pressure of 2.5MPa, the leaching rates of arsenic and tellurium were 85.43% and 59.7% respectively, and copper, antimony, bismuth were not leached. Hence, arsenic has been removed effectively from black copper sludge, while the valuable metals such as copper, antimony and bismuth remained in the residue that can be further recovered easily. INTRODUCTION Black copper sludge is a byproduct in the purification process of copper electrolyte. Arsenic, antimony and bismuth are major harmful impurities in copper electrolytic refining system. The accumulation of these impurities will cause adverse effects, such as the increase of electrolyte resistance and power consumption and deterioration of cathode copper quality (Wang, Liu, & Zhang, 2001). Hence, electrolyte purification is an essential part of the electrolysis process (Liang, Chen, & Guo, 2009). Electrolyte purification methods include electrowinning (Davenport, King, Schlesinger, & Biswas, 2002), solvent extraction (Navarro, Simpson, & Alguacil, 1999), ion exchange (Arroyo et al., 2017), coprecipitation (Wang et al., 2003, 2018; Xiao et al., 2007; Xiao, Cao, Mao, Shen, & Ren, 2014), activated carbon adsorption (Navarro & Alguacil, 2002), electrodialysis (Cifuentes et al., 2015), redox process (Zhou, Peng, Zheng, Ma, & Cui, 2011; Peng, Zheng, Zhou, & Chen, 2012; Zheng, Peng, Ke, & Chen, 2013), among which the electrowinning method is simple in operation and effective in impurities removal, making it the main process for current electrolyte purification. Some copper ions can react with harmful impurities to form complex black copper sludge by controlling the operation conditions of electrowinning process. Based on the estimated data provide by Davenport et al. (2002), an annual output of 400,000 tons cathode copper could produce 432-2168 tons of black copper sludge by electrowinning method. Black copper sludge contains 30~50% copper, 15~30% arsenic and a small amount of rare elements such as selenium and tellurium. Thus, recovery of valuable metals can bring huge economic interests. Moreover, arsenic in these sludges could cause significant environmental pollution. Therefore, effective removal of arsenic from these sludges is urgent and significant.

Jan 1, 2019

By Kevin Andrews, Terry Hamric, Scott Nelson

"Mining conditions in underground coal mines are dictated by the environment in which the coal seams were geologically deposited. Depositional features can change rapidly, significantly affecting mining conditions. Mine geologists understand factors affecting mining conditions, predict future conditions, and provide guidance to mine management. A case study demonstrates how a mine in Appalachia merged an understanding of depositional environments with mining conditions and drilling data to make informed decisions as the mine encountered geologic anomalies. The assessment included drilling, mapping of geologic hazards and mine productivity, and creation of a conceptual depositional model. Metallurgical coal quality and clean tons per foot served as incentives for continued advance. Mining in the south was historically favorable, with good production and advance rates. As mining advanced north, changing geologic conditions caused the upper seam split to abruptly disappear. The mine ramped down into the lower seam split. Mining in the north area encountered unfavorable conditions, including transition roof, “horsebacks,” sandstone intrusions, roof rolls, and bony floor, resulting in low rates of mining advance. The mine geologist characterized the features and created a predictive model for future mining. Most of the adverse conditions were attributed to the coal in the north being part of an incised, transgressive valley fill environment, as compared to the favorable conditions in the south resulting from a floodplain depositional environment. Geologic conditions, low productivity, and unfavorable future predicted conditions in the north ultimately resulted in mine closure and reallocation of resources to a new mine with better forecasted conditions.INTRODUCTIONThe role of a geologist in assisting coal mining operations to understand and predict the impact of varying geological factors on mining productivity is a critical one, especially when management decisions must be made about the future prospects of a mine operating in difficult conditions. Chase, Newman, and Rusnak (2006) provide a very thorough discussion of the evolution of the role of the coal mine geologist and emphasizes the importance of understanding geology with regard to mine management decisions. Using actual mining performance data to determine which geologic factors are the most critical for mining is a powerful tool for making informed mine management decisions. For example, Nelson, Mullennex, and Miller (1988) provide a case study of analyzing the geologic factors impacting productivity of a Kentucky longwall mine to predict future mining conditions for the operation. In that case, the difficult geologic factors for longwall mining were prevalent across much of the remaining permit area and, in response, mine management converted the operation from a longwall operation to a continuous miner (CM) operation to better adapt to the geology. In another example, Keim and Miller (1999) evaluated geologic conditions impacting a West Virginia longwall mine. In both examples, significant geotechnical and geological information was available, including the opportunity to compare predicted mining conditions against actual conditions as mining progressed. Numerous examples of advanced Geologic Hazard Mapping (GHM) methodologies have come from government agencies and academia. For example, development of the Coal Mine Roof Rating (CMRR) system (Molinda and Mark, 1994) provided a standard means for geologists and engineers to communicate quantitatively with regard to mine roof conditions, and the introduction of the Stability Mapping System (SMS) provided an efficient means for analyzing numerous factors affecting coal mine stability (Wang and Heasley, 2005)."

Jan 1, 2019

By K. Parameswaran

This paper builds on presentations made at the Conference of Metallurgists (COM) 2015, COM 2017 and Extraction 2018 and associated papers published in the respective conference proceedings. Based on the classic Brundtland Commission definition of sustainable development as “development that meets the needs of the present without compromising the ability of future generations to meet their own needs,” the paper describes how metal mining can be compatible with sustainable development and how sustainability considerations have been applied in the primary copper industry, using several examples of sustainable mining practices from ASARCO LLC operations. Finally, the paper discusses how these considerations might be used in the future by discussing the need for developing a sustainable development strategy and how this strategy can be aligned with the United Nations Sustainable Development Goals. INTRODUCTION The primary copper industry comprises: mining (also referred to as “extraction”); mineral processing (also referred to as “beneficiation, “milling” or “concentration,”) which includes leaching, solvent extraction (SX), crushing, grinding, froth and flotation operations; and metallurgical processing which includes smelting and converting; refining, which includes fire-refining or anode refining and electro-refining; and electrowinning (EW). There are two routes for producing refined copper: hydrometallurgical and pyrometallurgical. The hydrometallurgical route comprises mining (open-pit and underground), mineral processing (crushing and grinding — for heap leaching only; leaching and SX) and metallurgical processing (EW). The pyrometallurgical route involves mining, mineral processing (crushing, grinding and froth flotation) and metallurgical processing (smelting, fire refining and electro- refining). The primary copper industry is capital, water, resource and energy intensive with the potential for significant environmental impacts, if the environmental aspects are not properly managed. ASARCO LLC (Asarco) was organized in 1899 as the American Smelting And Refining Company. Originally a consolidation of several lead-silver smelting companies, it evolved over the years into an integrated producer of primary non-ferrous metals, including copper, lead and zinc and associated co-products. Grupo México, S.A.B. de C.V (Grupo México) acquired Asarco in 1999. Today, Asarco is a vertically integrated producer of primary refined copper and associated co-products such as gold, silver, selenium and tellurium. Asarco operates three open-pit mines and mills, two leach, SX-EW plants, a copper smelter in Arizona and a copper electrolytic refinery in Texas.

Jan 1, 2019

By Alastair Torrance, Braden T. Lusk, MinGi Seo, Gary Cavanough

Velocity of Detonation (VOD) is the most commonly used method to determine explosive performance as VOD is a function of the confinement (ground conditions) density and composition of the explosive. Techniques used to measure VOD include resistance wire, time domain reflectometry, simple start stop and fibre optic methods. All these approaches require a cable of some sort to be inserted into each blast hole being monitored and the holes to be fired in a specific sequence. It is time consuming and fairly technical to position the cables correctly to gather the data from each hole. It slows down the hole loading process and increases the number of people on a bench at that time. The equipment and cable limits the measurements to a few holes, typically 5 or less, that are in close proximity. These measurements can generate useful information about the monitored holes but does not provide a full picture of how the explosive is performing across the whole blast and whether any change in performance is noted with changing ground conditions or confinement.

Jan 1, 2019

By Atsuki Sado, Akira Ueno, Kazuaki Takebayashi, Kunio Watanabe

The Saganoseki Refinery of Pan Pacific Copper Co., Ltd., Japan, introduced the ISA 2000® process in 2006 to improve product quality and productivity. After resolving various technical difficulties associated with the process, a current density of 325 A/m2 and electrolytic copper production of 234 000 tons per year were realized in 2018. In recent years, Saganoseki Smelter & Refinery has promoted treatment of recycled materials in addition to copper concentrates. Accordingly, the amount and type of impurities charged to the smelting process have tended to increase. In the electrorefining process, impurities such as nickel and antimony cause anodic passivation and formation of suspended solids, respectively. Although these undesirable phenomena can be avoided by controlling impurity concentrations in the anode and electrolyte to appropriate ranges, this also limits the choice of recycled materials that can be processed by the smelter. To achieve both stable operation of the electrorefining process and flexibility in treatment of recycled materials in the smelting process, Saganoseki Refinery improved the capacity of the impurity recovery processes during 2016 to 2018. This paper describes the expansion of the purification plant to remove and recover nickel and antimony. INTRODUCTION The Saganoseki Refinery of Pan Pacific Copper Co., Ltd., Japan, introduced the ISA 2000® (wax- less permanent cathode method) in 2006 to improve product quality and productivity. Since then, the refinery has gradually increased current density, and has been committed to establishing stable operation and high productivity via various improvements related to the electrolyte filtration and additive management systems. Figure 1 shows the trends of current density and current efficiency at the refinery. Although the current efficiency temporarily dropped when the current density was raised to 322 A/m2, it consistently exceeded 97% thereafter. At present, stable operation at 325 A/m2 has been achieved and continues.

Jan 1, 2019

By Fulian He, Jianhang Chen, Dongdong Chen, Shoubao Zhang

"The Wangjialing Coal Mine is the main colliery of the China Coal Huajin Energy Limited Liability Company. The average thickness of the coal seam in District 201 is 6.21 m. Fully mechanized longwall mining was used in this district. The ventilation roadway of panel 20102 was influenced by the retreat mining of the adjacent panel 20104. Therefore, large deformation and severe roof falls occurred in this roadway, seriously influencing the safety production of this coal mine. To support the roadway, cable truss was proposed to strengthen the reinforcement of this ventilation roadway. First, numerical simulation was used to optimize the reinforcement parameters, including the cable installation angle, cable length, and eccentric distance. Based on numerical simulation results, in-situ tests were conducted in the ventilation roadway of panel 20102 with the cable truss technology. In-situ monitoring results showed that the roof-to-floor convergence and the convergence of roadway on two sides were within the safety range. Furthermore, no apparent separations occurred in the roof. These indicate that based on the designed parameters, the cable truss system can effectively maintain the roadway stability under the severe influence of the adjacent longwall mining.INTRODUCTIONCable bolts are flexible tendons composed of multi steel wires, which are wound into a strand (Chen, Hagan, and Saydam, 2018). They were initially introduced in the hard rock mining industry in the 1960s. Later, they found rapid application in coal mines to maintain the stability of excavations (Wang et al., 2015).The standard cable bolt is composed of seven steel wires with a diameter of 15.2 mm. Laboratory and in-situ tests showed that there is a low bonding capacity between the standard cable bolt and the grout (Craig and Holden, 2014; Chen, Hagan, and Saydam, 2018). Then, modified cable bolts are developed based on the standard cable bolts. They are improved by changing the surface geometry of standard cable bolts, such as birdcaged cable bolts (Hutchins et al., 1990) or nutcaged cable bolts (Hyett et al., 1993). Further tests proved that modified cable bolts have better mechanical interlock and friction between the cable bolt and grout, leading to larger load transfer capacity of cable bolts.Although cable bolts have been used for many years, failure of the cable bolting system still occurs. A common failure mode is the damage of surrounding confining medium while the cable bolt is still hanging in the roof, which is caused by the bond failure of the cable/grout interface (Hutchinson and Diederichs, 1996). To prevent the cable bolting system from failing, the cable truss system is more widely used in mining engineering."

Jan 1, 2019

By M. Hardy

"The structural design of mine headframes is challenging due to the significant differences in the geometry, rigidity, and behaviour of these structures compared to conventional buildings. The differences are related to the main purpose of these structures, which is not human occupancy, but rather the support of hoisting equipment. The main objective of this paper is to present the seismic elastic behaviour of headframe structures in comparison with conventional buildings, which is the base case for the definition of seismic loads. This paper highlights the impact of backlegs on the dynamic behaviour of mine headframes, more specifically the resulting torsional sensitivity. INTRODUCTION The design of industrial structures is often governed by industrial processes rather than by architectural constraints. In ground-mounted hoisting plants, the structural configuration of headframes must allow clearances around conveyances and ropes while resisting the lateral loads associated with the hoisting equipment. Typically, these structures use backlegs to withstand the lateral loads, which leads to highly irregular structures with unconventional dynamic behaviour. The codes and standards applicable to the structural design of mine headframes in Canada are often incomplete or not adapted to the reality of practising engineers. This situation creates confusion, and engineers must look at various guidelines and international standards to support the engineering calculations required for the design of these structures. The loads resulting from the support of hoisting equipment, such as ropes and conveyances, are usually simple to calculate and are determined based on the information from manufacturer and industry related guidelines. Moreover, the loads associated with snow accumulation and wind are calculated applying the same methodology used for conventional buildings, without any major issues. On the other hand, the seismic loads are often difficult to calculate based on the methodology from the National Building Code of Canada due to the significant differences in the dynamic behaviour of the structures. The resulting structures may be either over-designed or worse, under-designed. Hence, there is a lack of uniformity in engineers’ designs. The latest edition of CSA S16-14 “Design of steel structures” includes Annex M (Informative) “Seismic design of industrial steel structures” to help designers close the gap between the requirements of traditional regulations and actual engineering practice."

Jan 1, 2019

By D. Collins, J. Winfield, V. Gangrade, B. Slaker, S. Braganza

"Researchers at the National Institute for Occupational Safety and Health (NIOSH) are investigating the unique pillar stability issues associated with room-and-pillar mining in dipping underground stone mines. The objective of this paper is to study the post-blast impact in and around a pillar, using microseismic monitoring. To accomplish this, a microseismic monitoring system has been installed at a dipping underground stone mine in central Pennsylvania. The microseismic system is comprised of 18 uniaxial accelerometers; 12 sensors are installed in a single pillar and 6 sensors are installed in the surrounding area. More than 4,400 microseismic events have been located near the study pillar following the blasts. The number of triggers increased significantly following the blast, and the trigger rate in the first five minutes was 60 triggers per minute and three triggers per minute over the next three hours. The processing of high-quality triggers indicated a large number of low magnitude microseismic events near the blasting face. The event locations were identified more accurately by using a 3D-velocity model, with an average 9 m expected location accuracy for this array calculated using the system data. Seismicity was absent from the core of the pillar, but significant numbers of events were found following cutter roof along a crosscut as it was developed as well as in the location of a rib failure event. Additionally, the events were located in the roof, showing high number of microseismic events within 0–10 m of the roof line compared to 10–30 m above the roof line.INTRODUCTIONGround control stability is essential to any mining operation for ensuring mineworker safety and health and preventing catastrophic failures of underground structures. The National Institute for Occupational Safety and Health (NIOSH) has conducted research in stone pillar design and has established fundamental pillar design guidelines for the underground stone industry, which resulted in the development of the S-Pillar program (Esterhuizen et al., 2011; Esterhuizen and Murphy, 2018). However, the data that makes up the S-Pillar database consists of shallow depth, flat-lying, single-level mining operations. Therefore, to expand this dataset and to develop guidelines for challenging conditions such as dipping and multi-level mines, NIOSH is currently conducting detailed pillar response investigations at mines with these characteristics. The study is being conducted using multiple research approaches, including seismic modeling and tomography, numerical modeling (Sears et al., 2019), stress monitoring, and LiDAR-based laser scanning (Slaker, Murphy, and Winfield, 2019). This paper discusses the findings from the microseismic monitoring system installed at the Pleasant Gap Mine, a steeply dipping underground limestone mine in central Pennsylvania."

Jan 1, 2019

By L. Vollert

In August 2018, the first full-scale HydroFloatTM cells for the recovery of coarse composited copper and gold were commissioned at Newcrest’s Cadia Valley operation in New South Wales, Australia. The primary objective of the installation is to recover coarse value-bearing composites that are lost to conventional flotation tailings, without the need for additional power input for particle size reduction to improve mineral liberation. This paper examines the application of Eriez HydroFloatTM technology for the recovery of coarse, poorly liberated copper sulphide particles drawing on recent experience from lab scale testwork through circuit design and commissioning of the full-scale installation at Cadia Valley. INTRODUCTION In the face of declining copper head grades and a tightening regulatory environment around the use of wet tailings dams, the processing of copper ores at coarser particle sizes has become a focal point for the industry. Sulphide flotation using the Eriez HydroFloatTM is one of the emergent technologies that sits under this umbrella of coarse pre-concentration. It has been demonstrated through numerous lab and pilot scale testwork programs carried out by Newcrest and others (Awatey, Kohmuench, Thanasekaran, Skinner & Zanin, 2013), to improve the flotation recovery of sulphide-rock composite particles with low surface liberation, relative to conventional flotation technology. The HydroFloatTM technology has been used widely for the recovery of coarse potash, phosphate, coal, vermiculite, spodumene and diamonds but has never been applied at full scale in either gold or sulphide flotation. In August 2018, the first full-scale 3.4 m diameter HydroFloatTM cells for the recovery of coarse composite copper and gold were commissioned at Newcrest’s Cadia Valley operation in New South Wales. The primary objective of the installation is to recover coarse value-bearing composite particles that are lost to conventional flotation tailings, without the need for additional upfront power input for particle size reduction to improve mineral liberation.

Jan 1, 2019

By A. Lewis, J. Zachwieja, M. Widell, P. Zhou, W. W. Geissler, M. Svensson, A. Movahedi, H. Nordberg

Flotation collectors for sulfide minerals has been traditionally based on xanthate, thiophosphate, thiophosphinate and thiocarbamate, all derived from sulfur chemistry. Tecflote™ is a new family of patented collectors based on nitrile chemistry which can supplement or replace thiol collectors, depending on the ore types. A steep grade-recovery curve typical of Tecflote™ collectors was observed when using Tecflote™ as the main collector for the rougher and cleaner steps allowing a better recovery compared to current thiol collectors while maintaining the desired grade. Additional recovery increase has also been observed by the addition of scavenger steps using Tecflote™ collector in combination with current thiol-based collector. The selectivity seen in the lab is transferred to full scale trial and is clearly seen in the rough flotation where the increase in the rough concentrate grade of 5% after pumping Tecflote S11 directly into the tank cell. The mechanisms for Tecflote’s selectivity towards sulfides are currently under investigation and will be discussed. Results of TOF-SIMS analysis will be presented, demonstrating the collector’s selective affinity to different mineral surfaces in flotation. INTRODUCTION The history of collectors used today started in 1882 when Zeise first made xanthates. It was first used in flotation in 1925 – Cornelius Keller’s first patent (Fuerstenau, Jameson, Yoon, 2007). Between 1928 and 1930 American Cyanamid filed 7 patents for dithiophosphate, including flotation and chemical synthesis of the reagent, the first of which was filed by Christmann in 1928 (Christmann, 1933). Synthesize of thionocarbamates for mineral flotation was filed in 1954, by Dow Chemical Company (Harris, 1954). Now that the head grades have been declining over the last decades the need to find more selective collectors to extract difficult and complex ores has pushed the industry to look at different chemistries. Thiol collectors standard to the industry rely on the sulfur in the collector molecule to bond to the mineral surface. The electronic property of this group is modified by the adjacent chemical groups, such as additional S, P or N have the effect of changing the selectivity of the collector (Wills & Finch, 2016). In the case of xanthate the length of the hydrophobic group also has an effect on the selectivity with some minerals such that the ethyl xanthate is more selective against pyrite and pyrrhotite than the long chain xanthates (Wills & Finch, 2016).

Jan 1, 2019

By D. Sancho, M. Weber

"At the start of a new shaft project, a specific number of ground investigations are performed. However, it is not uncommon that the ground conditions during shaft sinking may differ from the designed ones. Therefore, it is extremely important to use tools which minimize discrepancies and to include a monitoring system in the shaft design to collect sufficient data. The paper presents an overview of existing monitoring techniques and discusses future works required to improve, not only the construction during shaft sinking, but also the lining design methodology. INTRODUCTION In most cases, the investigations performed at the start of a new shaft are based on the analysis of rock and soil probes obtained from boreholes. In practice, such analysis performed on a single core often leads to different results when conducted by various experts. The discrepancy in core analysis influences further rock mass assessment and design assumptions. It is not uncommon that the ground conditions during shaft sinking may differ from the designed ones, which affects the estimated stress and strain state of the shaft lining. Therefore, it is extremely important to use tools which minimize such discrepancy and to include into the shaft design a monitoring system to collect sufficient data, which enables control of important phenomena, not only during shaft sinking but also during the life of the shaft. Furthermore, the information collected during shaft sinking, while it is important for proper shaft lining design and updates to the shaft lining due to the local mining and geological conditions, it is also important after shaft sinking. In the whole shaft lifetime, it is not uncommon that the shaft lining is damaged and the liner needs to be renewed (Figure 1) due to various reasons. For this purpose, detailed information collected during construction can be extremely important."

Jan 1, 2019

By N. A. Beier, R. Amos, Smith. L., C. Atherton, D. R. Barsi, D. Blowes, D. C. Sego

"Waste rock is one of the most abundant materials at mine sites and must be properly characterized and managed to limit acid rock drainage and other harmful byproducts. An experimental waste rock pile—part of the test piles research program—located at the Diavik diamond mine (Northwest Territories, Canada) was deconstructed and sampled to study the spatial variability of material properties. Bulk samples were classified based on the amount of material finer than 4.75 mm. Hydraulic properties of each sample were estimated and particle size distribution analysis was completed. These datasets and classification methods might be used to improve the understanding of hydraulic and geochemical behaviour of the material and to study waste rock at other sites. ¦ KEYWORDS Acid rock drainage (ARD), Material classification, Particle size distribution (PSD), Waste rock RÉSUMÉ Les stériles font partie des matériaux les plus abondants sur les sites miniers et, en tant que tels, doivent être correctement caractérisés et gérés afin de limiter le drainage rocheux acide (DRA) et la pré¬sence d’autres sous-produits nocifs. Dans le cadre du programme Test Piles Research Program, un amas de roches stériles expérimental situé à la mine de diamant Diavik (Territoires du Nord-Ouest, Canada) a été décomposé et mis à l’essai afin d’étudier la variabilité spatiale des propriétés des matériaux. Les échan¬tillons en vrac ont été classés en fonction de la quantité de matériaux plus fins que 4,75 mm. Les propriétés hydrauliques de chaque échantillon ont été estimées et l’analyse de la composition granulométrique effectuée. Ces ensembles de données et méthodes de classement serviront à mieux comprendre le com¬portement hydraulique et géochimique du matériau et à étudier les stériles sur d’autres sites. ¦ MOTS CLÉS classement des matériaux, composition granulométrique, drainage rocheux acide (DRA), stérilesINTRODUCTION Statement of problem The characterization of mine waste rock remains a challenge in active mining sites. The large volume of material and the large size of particles make it difficult to collect representative samples. Sampling techniques are often dis-ruptive to mining operations because they alter the structure of the waste rock pile or interfere with mine traffic. The convention at most mine sites to collect little to no information on waste rock material means that models and predictions of how waste material will behave and interact with the surrounding environment are based on general information that might not be site specific. This could lead to environmental damage or higher costs if environmental effects are underestimated during the construction of waste rock structures."

Jan 1, 2019

By K. Mohamed, G. Rashed

A conventional mechanical anchor bolt consists of a smooth bar threaded at the anchor end, with a conical wedge, and a mechanical shell anchor. When the smooth bar is torqued, the conical wedge pushes the shell anchor against the borehole wall. Coal mines use mechanical bolts in addition to other types of bolts to control the deformation and stabilize the yielded coal ribs. Limited research has been conducted to understand how a mechanical anchor performs in a coal rib. Researchers from the National Institute for Occupational Safety and Health (NIOSH) conducted the study described in this paper to define the loading characteristics of mechanical bolts (stiffness and capacity) installed in coal ribs at five underground coal mines. Standard pull-out tests were performed in this study to define the loading characteristics of a mechanical rib bolt. Based on the strength of the coal seam and the conditions of the coal mines, the bolts were installed at different amounts of torque. A typical tri-linear load-deformation response was obtained from these tests. It was found that the anchorage capacity depends on the coal strength, and the anchorage stiffness depends on the installation torque. The outcome of this research provides essential data for rib support design. INTRODUCTION Rib falls are a serious hazard in underground coal mines. In the last 10 years, rib failures have resulted in 17 fatalities, representing 52% of the ground-fall fatalities in underground coal mines in the United States (MSHA, 2018). Although resin bolts has been used increasingly in the last few years to control coal ribs, mechanical bolting (mainly expansion-shell bolts) is still used in many underground coal mines. Recently, NIOSH researchers surveyed 90 sites in 14 underground coal mines in the Eastern United States and found that 79% of the mines determine their rib support requirement based on the depth, mining height, and the loading conditions, of which 35% use the conventional mechanical bolts. Conventional mechanical bolts are preferable for rib support because they do not require the miners to be too close to the rib during rib bolting. Hence, using the conventional mechanical rib bolts can reduce the risk of injuries and fatalities during the installation process. The mechanical bolt or the point-anchored bolt is the oldest type of rock bolt that is still in use today. The point-anchored bolt is a tensioned bolt anchored down the hole with a mechanical expansion shell or a grouted medium (Peng and Tang, 1984). Figure 1 shows the components of the mechanical anchor bolt. The mechanical anchor bolt consists of a plug, a shell anchor, a headed smooth bar with the top end threaded, a bearing plate, a hardened washer, and sometimes a friction-reducing washer. The shell anchor can be either standard or bail type. The shell of the standard type is held in place by a nut, while the bail anchor uses a strap to hold the shell in place (Peng, 2008). The diameter of the smooth bar is generally 5/8 in for the #5 bolt or 6/8 in for the #6 bolt. The diameter of the hole that the bolt is inserted into must be carefully controlled since an oversized hole can result in poor anchorage (Moss, 1971). The anchorage is obtained by applying torque to the bolt head, which in turn pulls the wedge down in the shell and expands the serrated leaves against the sides of the hole-wall. In the resin-grouted anchor, the resin replaces the mechanical expansion shell at the end of the hole. The anchorage is achieved by bonding between the resin, bolt, and the hole-wall.

Jan 1, 2019

By Zhiyang Long, Ruiling Xiao

"A mine shaft is one main development method of establishing access in an underground mine. The construction technology of the mine shaft sinking is complicated and large equipment setup on surface and in the mine shaft. The paper briefly reviews a single-line operation method, parallel operation method and mixed operation method as well as the features of the one operation method with the excavation, lining and installation. The special construction technology mainly would include ground freezing methods, full diameter shaft drilling methods, caisson methods, grouting technology and concrete curtain methods as well as other methods. The paper summarizes the shaft sinking numbers and effects by the special construction methods during different periods. The paper states the shaft sinking conditions and the each created record conditions in the coal, metallurgy, non-ferrous metal, hydropower, highway, railway, nonmetallic and other industries. The paper has a prediction on the shaft sinking requirements and development tendency in the future for China.INTRODUCTIONA mine shaft is one main development method of access in an underground mine. In recent years in China the new shaft mines represent 45% of the total number of new mines. With the development of new mining area under construction and the development of deeper mines, the ratio of the mine shaft as access for underground mines will increase. The construction technology of the mine shaft engineering will be complicated, the operation site footprint will be small and the working environment will be more difficult. The mine shaft sinking operation will often be varied by the geological conditions and affected by underground water inflows, seam gas outbursts, geothermal and other natural conditions. The safe construction of the mine shaft sinking will be challenged by all these conditions. Although the mine shaft engineering will only be about 5% of the total mine roadway engineering, the mine shaft construction period often will take over 40% of the total mine construction period. With the progress of modernized mine production technology and the construction of a high production and high efficient mine, the mine transportation roadways mostly would be set in the seam and the engineered amount of the mine rock roadways reduced year by year could cause more prominent long extensions of the mine shaft construction period. Therefore, in order to speed up the construction, to shorten the mine construction period and to realize the investment benefits as early as possible, the technical level of the mine shaft sinking should firstly be improved and the construction speed of the mine shaft engineering and sinking should be speeded up, which would have important significant benefits."

Jan 1, 2019

By M. Narita, S. Nakayama, M. Fujihara

Hibi Kyodo Smelting Co., Ltd. was founded in 1968 and celebrated its 50th anniversary in 2018. In 1972, we started producing copper cathode with a production capacity of 84 KTPY. Since the company founding, we have undertaken seven expansion projects, and our current copper-cathode production capacity is 290 KTPY. To increase our production efficiency, two tank houses were converted from Conventional process to ISA process in 2006 and 2014. In another investment, we equipped a continuous glue dosing system, which allowed for strict additive-concentration control, yielded quality improvements and reduced the power-consumption rate. Along with an increase in the production of copper cathode, the amount of impurities eluted from the anode increases. To solve this problem, the chelate-resin purification process that was introduced in 1983 was renovated, and impurities could be recovered more efficiently. In this paper, we report various improvements that have been implemented at the refinery since 2000. INTRODUCTION Tamano Smelter and Refinery of Hibi Kyodo Smelting Co., Ltd., founded in 1968, celebrated the 50th anniversary of its founding in 2018. The Tamano Smelter opened its No. 1 tankhouse in 1972, and began operating No. 2 tankhouse in 1984. Thereafter, with continuous production increases and technical improvements, electrolytic copper production was increased from 84 KTPY to 290 KTPY as shown in Figure 1. Table 1 shows the major operating facilities and operation data in 2017.In this paper, details of equipment introduced to continuously dissolve and add glue, various improvements made to the chelate resin process, enhancements made to the crude Ni sulfate process, and another vibrating screen introduced to the copper slime processing flow in accordance with the expansion of copper production capacity since 2000 are reported.

Jan 1, 2019

By H. A. Khorami, T. Wong, B. Velapatino, E. Asselin, T. Donnelly, E. Bryce, R. Dixon

A copper–nickel concentration gradient alloy was designed and fabricated through a powder metallurgy (PM) process. Copper and nickel powders were mixed with different weight ratios from 0 to 100% copper in 10% increments. Each powder mixture was poured inside a cylindrical die and compacted between two punches using a hydraulic press machine at pressures up to 70 MPa, resulting in approximately 1 mm thick layers (discs) of pressed Cu–Ni powder. These 11 Cu–Ni compacted powder layers, i.e. 0–100% Cu with 10% increments, were then compressed together with pressures up to 420 MPa to form a green part. The green part was sintered in a vacuum furnace at 1000°C for 10 hours to form a solid mass (PM part) of Cu–Ni concentration gradient alloy. In the sintering process, Cu and Ni particles fused together and formed a single piece due to diffusion of the atoms across the boundaries of the particles. The diffusion of atoms also converted the stepwise concentration change into a uniform concentration gradient. INTRODUCTION Copper has numerous applications in different industrial sectors due to its superior physical, electrical, mechanical and chemical properties such as its excellent thermal and electrical conductivity, resistance to fatigue, high ductility, and resistance to corrosion. Moreover, copper and its alloys have natural antimicrobial properties. This has opened up new applications for copper–based self–disinfecting surfaces in healthcare in an effort to mitigate healthcare–associated infections (HAIs). HAIs affect millions of patients each year, leading to significant morbidity and mortality as well as financial losses to healthcare systems (World Health Organization, 2016). HAIs spread through three main routes: (a) iatrogenic in which HAIs are a direct consequence of medical encounters and/or treatment; (b) person to person where organisms are transferred between healthcare workers, patients, and visitors; and (c) environmental where transmission occurs via contaminated surfaces and equipment (e.g. doorknobs, railings, toilets/commodes, medical carts). The use of antimicrobial copper–based materials on high touch surfaces could diminish pathogen transmission via this latter rout. This has subsequently led to the development of a variety of copper–based materials for use in healthcare settings and promoted the investigation of the antimicrobial efficacy of copper–based materials.

Jan 1, 2019

By Euler De Souza

"The uninterrupted operation of a ventilation system is critical to ensure the mine meets its scheduled production and, as important, is vital to the health and safety of all personnel working underground. Those operating the mine ventilation system must have fundamental engineering training in the art of fluid dynamics and have a good comprehension and control of the mine ventilation network. Ventilation management by untrained and inexperienced personnel may result in serious consequences when the system becomes ineffective. This paper shares observations and experiences pertinent to the occurrence of upset conditions as a result of the improper design and operation of mine ventilation systems. A series of real life case studies are presented to describe disruptions to mine ventilation systems and the gradual deterioration of system operational efficiencies leading to eventual failure. Special focus is given to mistakes made and on the resulting serious consequences. The case studies also demonstrate how each upset condition was resolved, permitting the mines to safely resume production activities.INTRODUCTIONThe ventilation of operating mines is a continuously changing and evolving system; upset conditions will occasionally occur, but should be promptly resolved in order for the system to function properly, according to design, and in compliance.Those designing, managing or operating the mine ventilation system must have pertinent training and have a good understanding of fundamental ventilation concepts to be able to devise and implement engineering solutions to day-to-day challenges. Realistically, the operator must also have extensive practical experience and be able to effectively apply operating procedures, design criteria and ‘best practices’. They must be able to, on a daily basis, evaluate the mine ventilation system, determine and locate any problems, understand the causes of each problem, find a solution, and promptly and efficiently correct those problems.Ten case studies are presented to demonstrate how fundamental design or operational mistakes can lead to adverse conditions or to catastrophic consequences, how detailed on-site engineering assessments can be employed and how simple, low cost, engineering solutions can be implemented to successfully resolve the issues and return the ventilation system to compliance, permitting the mines to safely resume production activities."

Jan 1, 2019