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By Q. Fu, Q. Wang, L. G. Wen, M. X. Jia, J. J. Zhao, J. W. Zhou

The BGRIMM process mineralogy analyser (BPMA) is a new automated mineralogy software platform developed in China. This system consists of the BPMA software platform, controlling a combination of commercially available scanning electron microscopy (SEM) and energy dispersive Xray spectrometry (EDS). The BPMA software controls SEM and EDS through their application programming interfaces, to form an auto-SEM and EDS system that automatically acquires BSE images and X-ray spectra, respectively, and classifies minerals by spectrum-matching. After automated measurement and mineral identification, various quantitative process mineralogical data (e.g., mineral composition, mineral abundance, mineral liberation and intergrowth relationships, mineral associations, particle and grain sizes, particle density distributions, calculated assay, elemental deportments, mineral grade recovery and elemental grade recovery, etc.) would be calculated quickly, accurately and automatically. The BPMA could be used for ore characterisation as a new advanced automated mineralogy technology. Keywords: BSE image; X-ray spectrum; automated mineral identification; quantitative mineralogical investigation; automated mineralogy

Jan 1, 2020

By Lawrence Melis

Fission Uranium Corp.’s Triple R Uranium Deposit at its Patterson Lake South Project is located in northwest Saskatchewan in Canada’s Athabasca Basin. As part of pre-feasibility studies for the project a detailed metallurgical test program was completed to provide process design criteria. The testwork program encompassed preparation and analysis of test composites, comminution testing, uranium acid leaching, liquid-solid separation, solvent extraction of uranium, precipitation of uranium yellowcake products, tailings and effluent treatment, tailings physical and chemical characterization, and environmental testing of prepared tailings, as well as investigations of gold and silver recovery from the mineralization. The paper provides mineralogical information, testwork methodologies and test results which were used to arrive at process design criteria and the selection of the process flowsheet for the project.

Jan 1, 2020

By J. Warner, K. A. Hughes, P. E. R. Blanchard, J. Esslifie-Dughan, J. W. Reid

Tailings management plays an important role in reducing the environmental impact of Orano Canada’s uranium mining operations in Northern Saskatchewan. Uranium ores mined from Northern Saskatchewan are often associated with large amounts (10-20 wt%) of other harmful elements, such as arsenic and nickel. The JEB Tailings Management Facility (TMF) located at McClean Lake, Saskatchewan is designed to prevent potentially harmful water-soluble elements, particularly arsenic, from contaminating the surrounding environment by promoting the formation of water-insoluble minerals. It is therefore important to determine which arsenic-containing mineral species are present in the TMF and how they evolve over time. Researchers at the Canadian Light Source (Saskatoon, Saskatchewan) were successful in identifying the arsenic mineral species present in tailings samples collected from the TMF in 2013 using X-ray absorption near-edge structure (XANES) spectroscopy. XANES analysis verified that the majority of arsenic species in the TMF existed as amorphous and crystalline ferric arsenates with minor amounts of arsenite and arsenide species. Herein, XANES is again used to analyze a new set of tailings samples collected from the TMF in 2018, specifically focusing on the difference in the distribution of arsenic species in old and new tailings.

Jan 1, 2020

By L. Shasko, M. Hurlbert

As climate change is increasingly perceived as a problem, and fossil fuel based power production options are increasingly limited through regulatory restrictions and public distaste, future options become constricted. Reflexivity and social learning elicited through qualitative and mixed research methods offer important insight into what future power production pathways might be. Given factors of cost, baseload requirements, and energy density, options such as nuclear may be increasingly accepted. This paper explores this literature and possible methods of pursuing the reluctant acceptance of nuclear energy.

Jan 1, 2020

By Bertrand Quiniou, Pierre Amadieu

Ion exchange technologies and processes are proven and established technologies widely used in numerous industries including hydrometallurgy for metal separation and recovery from metal bearing solutions. They have evolved through innovation which includes the development of countercurrent multistage (or multivessel) ion-exchange contactor systems with the benefit, for industrial operations, of greatly reduced footprints and ion-exchange media inventories, as compared to more traditional fixed bed contactor systems. Information on procedures for design and sizing of countercurrent multistage ion-exchange contactor systems is not readily available since it is most often proprietary know-how. The purpose of the present work is to develop a simple and innovative approach for the sizing and modeling of industrial countercurrent multistage ion-exchange contactor systems. The suggested approach builds upon published results and upon the following observation: in an industrial setting, knowledge of how component concentration or load on a contactor output streams vary with time t within a cycle duration (0 < t < T) is generally of little interest, only knowledge of time average of such concentration or load over a cycle duration T is sought for. The presented approach will be tested against current or past performances of industrial countercurrent multistage contactors of Orano Mining operations such as SNK‑3M moving packed bed contactors in Kazakhstan and NIMCIX fluidized bed contactors in Namibia.

Jan 1, 2020

By L. Shasko

Deliberative mapping is a method of public engagement designed to bring citizens and specialists together to inform policy decisions in conflict-laden areas of science and technology (Stirling and Davies 2004a). Citizens and specialists participate in the process both separately and together. A deliberative mapping study was held in Regina, Saskatchewan in October and November of 2019. Participants in the study assessed options for reducing greenhouse gas emissions in small, remote or off-grid communities, including assessing the role of small modular nuclear reactors (SMRs) in climate change mitigation. Deliberative mapping is designed to facilitate direct, two-way conversations between citizens and specialists through both formal and informal discussions. The relationship building component of this process may increase trust. Public consultation processes that lack two-way dialogue or are seen as obligatory rather than meaningful can worsen public opposition or lead to negative public perceptions. Public education alone is not enough to change public opinion. Providing people with more information on topics they already hold opinions on can work to reaffirm previously held biases, but building relationships can provide new pathways to overcome divisions and turn close-mindedness into open-mindedness.

Jan 1, 2020

By Mark Liskowich

When is it the proper time to initiate engagement with various stakeholders, including Indigenous communities? This paper will demonstrate what stage of a project’s evolution is the appropriate time to initiate a stakeholder engagement plan. It will look at aspects to consider when identifying the communities to involve. It will describe the contents of a Stakeholder Engagement Management Plan as well and touch on how tried and true options analyses, such as a Multiple Accounts Analysis can be used to inform the results of the engagement, guide the development of your project and clearly document the engagement process. It will illustrate the benefits of initiating engagement at the appropriate point in your project’s schedule, and the limitations of doing so too early and at later stages of the project engineering. The benefits of this approach can be realized within any legislative Jurisdiction including the Canadian Environmental Assessment Act 2012 and Canada’s new Impact Assessment Act.

Jan 1, 2020

By John R. Hayes, Kebbi A. Hughes, John Rowson, Peter E. R. Blanchard, Jeremiah C. Beam, Andrew P. Grosvenor, Arthur Situm

Uranium ore bodies contain elements within mineral phases that need to be disposed of responsibly. Solid waste can be placed in a tailings management facility (TMF) to contain the waste elements and limit interactions with the environment. It is important to understand how the chemistry of the tailings evolves throughout the lifetime of the operations that feed the TMF and after the site has been decommissioned. The objective of our collaboration with Orano Canada was to study how the tailings from the TMF located at McClean Lake, Saskatchewan change over time. This manuscript discusses our use of X-ray absorption spectroscopy (XAS) and X-ray microprobe to study the fate of Mo and Ca in the tailings. Mo is considered an element of concern (EOC) and it is necessary to determine if a stable solid Mo-bearing species forms. Thermodynamic modeling suggested that aqueous Mo would precipitate over time as powellite (CaMoO4). Comparing Mo K-edge XAS spectra from the solid tailings to the aqueous Mo concentration in the pore water showed that powellite did form and that this did result in a decrease in the aqueous Mo concentration over time. Further, it has been proposed that Ca2+(aq) can react with bicarbonate ions in the pore water and precipitate as calcium carbonate (e.g., CaCO3). This reaction would limit the aqueous bicarbonate present in the tailings that could react with uranyl ions to form soluble uranyl-carbonate complexes. We have identified several trace Ca-bearing species, including carbonates, in the tailings using XAS and X-ray microprobe.

Jan 1, 2020

By W. McCombe, G. Remple, L. Nightingale-Mercer

The McClean Lake Mill is located approximately 850 kilometres north of Saskatoon, Saskatchewan, Canada, and is operated by Orano Canada Inc. (Orano). The mill was designed to process high grade uranium ores, and a multi-year expansion was completed in 2014 to increase its production capacity to 24 Mlbs U3O8 per annum. The mill also underwent various upgrades to allow it to safely transition from processing low grade ores to high grade ores from the nearby Cigar Lake Mine. During the metallurgical test work on the Cigar Lake ores, it was identified that some ore zones of the deposit have a propensity to generate hydrogen gas during acid leaching. Hydrogen is a volatile and explosive gas, which poses obvious safety concerns in the leaching circuit. Uranium processing is further complicated by the fact that an oxidant in the form of oxygen gas or hydrogen peroxide is required to regenerate iron in the leach, which further increases the risk posed by hydrogen gas. During 2013 Orano and its consultant Hatch designed and engineered several novel upgrades to the leaching circuit to mitigate the risk of hydrogen gas evolution in the process. Best in class technology was utilized in addition to control and operating strategy changes to ensure the leaching circuit could be safely operated with ores that evolve hydrogen gas. This paper reviews the design concepts and modifications implemented on this unique and challenging project, and also provides an update on the operational reality of hydrogen in the circuit gained through five years of operational experience with hydrogen evolving ores.

Jan 1, 2020

By John Rowson, Caitlin Brown, Kebbi Hughes, Joseph Esslifie-Dughan

The McClean Lake mill in northern Saskatchewan, Canada, is operated by Orano Canada Inc. and has been in production for the last 20 years. The tailings preparation process at the mill has been designed with decommissioning in mind, to produce tailings that are geochemically stable over the long-term within the site’s tailings management facility. Twenty years of study have contributed to a detailed understanding of geochemical and geotechnical properties of the McClean Lake tailings. Validation of the tailings properties has occurred through in-situ sampling campaigns conducted initially every year, and later every five years. Each sampling campaign has applied the same rigorous sampling procedure to provide data with useful correlations year over year. Each campaign result compares elements such as the inherent variability of the tailings, consolidation of the tailings and variations in the tailings placement methods. We will discuss lessons learned from seven sampling campaigns over 20 years and present data to show the reliable tracking of geochemical evolution of the in-situ tailings over time; providing opportunities for continuous improvements.

Jan 1, 2020

By Thom Mambe, Angelo Fernando

The objective of this work was to identify key parameters related to the reduction of the sulphur content in ammonium diuranate (ADU), and the identification of solid products being formed under various operating conditions. A laboratory-scale, continuous ADU precipitation circuit was assembled using a glass reactor vessel immersed in a temperature-controlled water bath. A pre-prepared uranium feed solution was fed continuously using a peristaltic pump. Anhydrous ammonia mixed with compressed air was metered and pumped using a double-headed peristaltic pump. An over-head mixer was used to keep the solids in suspension. The precipitated ADU slurry was removed from the reactor at the same flow rate as the feed solution. The slurry was sampled to generate ADU solids for chemical and physical analysis after four hours of continuous operation to ensure steady-state conditions. The following variables were studied to determine their influence on the sulphur content in the resulting ADU. (a) sulphate:uranium molar ratio in the reactor (1:1, 1:5, 1:10 and 1:20) (b) precipitation pH ( pH 6, 6.5, 6.9, 7.5 and 9) and (c) precipitation temperature (40C and 60C) A total of 18 tests covering the above parameters were conducted, and the results indicated that the sulphur content in the resulting solids was highly dependent on the reaction pH. Out of the pH levels tested, tests completed at pH 6.9 and 7.5 generated solids containing the lowest sulphur contents, between 0.5 to 1.5% S uranium basis (UB). The sulphur content in solids was found to vary linearly with the sulphate:uranium ratio in the feed solution, showing a statistically valid correlation. The impact of temperature was minor between 40°C and 60°C, with a slight advantage at higher temperatures. Tests at a sulphate:uranium ratio of 1:1 produced solids with the lowest sulphur contents. The influence of pH or temperature on sulphur content in solids was almost non-existent at this sulphate:uranium ratio. Precipitation pH is the major factor influencing ADU sulphur content, followed by the uranium to sulphate ratio.

Jan 1, 2020

By B. K. Ayres

Modern management of uranium mine or mill waste storage facilities (WSFs) often requires that they be remediated or decommissioned with a cover system. In addition to creating a self-sustaining landscape that supports the end land use, cover systems are intended to reduce long-term risks to human and ecological receptors from the stored waste to acceptable levels. The performance and longevity of a cover system will be strongly influenced by the features or shapes of the WSF final landform. Hence, cover systems and landforms must be thought of as an integrated design. Based on the author’s experience, the most important elements of the design process for maximizing the potential of WSF final landforms / cover systems being sustainable over the long term are noted in this manuscript. Several key items that must be considered and addressed during the planning phase of constructing a WSF final landform are also described. Various methods for monitoring performance of a WSF final landform are also reviewed. Key aspects associated with decommissioning a tailings WSF and waste rock pile at the former Cluff Lake uranium mine in northern Saskatchewan are included to illustrate many of the practical insights provided in this paper.

Jan 1, 2020

By Dale Verran, Jared Orynik, Chad Sorba, David Bronkhorst

Denison Mines Corp. (“Denison”) has a 90% interest in the Wheeler River Uranium Project (“Wheeler River”) located along the eastern edge of the Athabasca Basin in northern Saskatchewan between the Key Lake mill and the McArthur River uranium mine. The project is host to the high-grade Phoenix and Gryphon uranium deposits, discovered by Denison in 2008 and 2014 respectively, which include combined Indicated Mineral Resources of 132.1 million pounds U3O8 (1,809,000 tonnes at an average grade of 3.3% U3O8). The Pre-Feasibility Study (“PFS”), completed in accordance with NI 43-101 in September 2018, is highlighted by the selection of the In-Situ Recovery (“ISR”) mining method for the development of the Phoenix deposit, with an estimated average operating cost of $4.33 (US$3.33) per pound U3O8. Phoenix is the highest-grade undeveloped uranium deposit known globally, including Indicated Mineral Resources of 166,000 tonnes at 19.1% U3O8 for 70.2 million pounds U3O8. The paper aims to provide a summary of Wheeler River and an overview of the proposed development of the Phoenix and Gryphon deposits according to the PFS completed for the Project. Further details regarding the PFS, including additional scientific and technical information are described in greater detail in the NI 43-101 Technical Report titled "Pre-Feasibility Study for the Wheeler River Uranium Project, Saskatchewan, Canada" dated October 30, 2018 with an effective date of September 24, 2018. A copy of this report is available on Denison's website and under its profile on SEDAR at www.sedar.com and on EDGAR at www.sec.gov/edgar.shtml.

Jan 1, 2020

By David Sanscartier, Elizaveta Petelina, Alexey Klyashtorin

This paper provides an overview of the radiological risk mitigation approach applied by the Saskatchewan Research Council (SRC) for the remediation of 35 legacy uranium mine sites in northern Saskatchewan where uranium exploration and extraction took place in the 1950–60s. Mining activities resulted in an irregular increase of the gamma radiation dose rate (up to 18 μSv/h). The radiological objectives for the sites include a gamma dose rate at a spot (<2.5 μSv/h above local background), and the dose rate averaged over a hectare (<1 μSv/h above local background). These objectives are generally achievable at the impacted sites through the installation of shielding soil cover. This method may be impractical for site areas with rough terrain (e.g., steep slopes) and/or difficult access. A risk assessment approach is applied to determine if these areas can be safely left uncovered or if additional mitigation measures should be implemented. The risk assessment approach is based on two factors: (i) the ambient radiation dose rates collected through gamma surveys, and (ii) actual land use data collected through various surveys of activities of local community members at the sites. Exposure scenarios based on four land uses are applied to estimate a potential annual dose load for members of the public. The estimated doses are compared with the criterion of 0.3 mSv/a recommended by the Canadian Guidelines for the Management of Naturally Occurring Radioactive Materials (NORM). If the criteria are not satisfied, a mitigation plan is developed, and post-remediation gamma levels are modelled using GIS tools to evaluate the performance of the proposed mitigations. The proposed approach allows the team to optimize resources for the site remediation so that public exposure to NORM are as low as reasonably achievable after remediation.

Jan 1, 2020

By D. Kong, A. Klyashtorin, L. McGilp, I. Wilson

This work reports on applying iron oxide coated sands media in an experimental permeable reactive barrier to remove uranium species from uranium containing water. A field experiment was conducted at the legacy Gunnar uranium mine & mill site that was abandoned in the 1960s with limited to no decommissioning. The flooded Gunnar mine pit presently contains about 3.2 million m3 of water contaminated by dissolved U (1.2 mg/l), Ra-226 (0.4 Bq/l), and minor concentrations of other contaminants (As, Se, etc.). The water is seeping over the pit rim into Lake Athabasca posing environmental and health concerns. Iron oxide coated sands can be used to immobilize uranium species through an adsorption process. Methods for preparation of hydrous ferric oxide sorbents and their supported forms onto silica sands are described. Fourier transform infrared spectroscopy (FTIR), and powder X-ray diffraction (pXRD) were used to characterize the physical-chemical properties of the sorbent. The monolayer uranium uptake capacity (Qm) was estimated through the Langmuir adsorption isotherm. Adsorption kinetic experiments were performed in a lab environment before moving to a field trial. Based on these lab results and the input on field-scale appropriate geometries, a pilot permeable reactive barrier was fabricated and a field test conducted near the Gunnar pit in June 2019. This pilot test provided technical data and information needed for designing a full-scale permeable barrier based on the iron oxide coated sands, which may be applied for in-situ water treatment at Gunnar and other legacy uranium sites.

Jan 1, 2020

By Meifeng Zhi, Yuqing Niu, Xixin Chang, Fengqi Zhao, Weimin Qiu, Hao Wang, Zhenqian Wen, Zujun Shu

An applicable Eluex process was developed for acid in-situ leaching (ISL) uranium mine in Bayanwula. In this process, uranium was adsorbed with strong base anion resin from the pregnant solution, then the loaded resin was eluted by sulfuric acid. After D2EHPA extraction, the concentrated eluate was enriched, and the loaded organic phase was stripped by sodium carbonate. The yellow cake was obtained by sodium hydroxide precipitation at last. The uranium concentration in the loaded strip solution was 52.8 g/L. Parameters of the process were determined, and the impact of the Eluex process in underground leaching was also investigated. In industrial design, 95% of raffinate went back to elution and 5% back to in-situ leaching. No significant effect on uranium leaching or resin adsorption was found.

Jan 1, 2020

By B. Pewkliang, K. Ehrig, E. Macmillan, M. Smith, V. Liebezeit, Y. Li

The Olympic Dam iron-oxide copper-gold (IOCG) uranium-silver deposit is the largest publicly declared uranium, fifth largest copper and third largest gold resource. Currently, the operation consists of an underground mine and integrated processing plant. Uranium is produced from leaching of flotation tailings and is a co-product to copper cathode with by-product gold and silver bullion. The Olympic Dam geometallurgy team began studying ore from the Southern Mine Area (SMA) in 2006 and soon discovered uranium behaviour was far more variable than the behaviour in the Northern Mine Area, which had been mined from the start of the operation in 1988. The primary objective of Olympic Dam geometallurgy is to develop metallurgical performance predictors that reliably describe the process performance of different ore types and distribute these into the resource block model for use as a fundamental input into mine planning. The nature of the uranium mineralisation (compositionally and texturally complex and highly variable) meant that classic mineralogy techniques alone could not provide the resolution required for prediction of uranium extraction. However, the combination of quantitative mineralogy, results from laboratory-scale leach tests and modelling within the geometallurgy program has enabled prediction of both uranium flotation recovery (via association with sulphides) and uranium leach extraction, including at variable leach conditions. These stope-based predictions have supported trade-off decisions between operating costs and uranium revenue, and have predicted the changing recovery as the mining operations have moved into the Southern Mine Area in recent years.

Jan 1, 2020

By W. L. Dam

Grand Junction, Colorado’s legacy with uranium mining and milling serves as a model attracting international interest. Access to water and central location to carnotite ore containing uranium and vanadium resulted in the World War II military creating a site in Grand Junction for developing extraction techniques; subsequently, several commercial mill sites were built in the area. Uranium mills produced ore into the 1970’s as well as tonnes of radioactive waste tailings. Tailings contain radium that emits radon gas. Despite the radiation hazard, sandy tailings were added to concrete and became incorporated into roads, schools, businesses and homes. Clean up of sites containing tailings and mill sites began in the 1970’s involving city, state, and federal officials. The Climax mill site had become an auto junk yard mixed with mill tailings. A new disposal site was built out of town and away from the river in the 1990’s. After Climax mill tailings were removed to the disposal site, the land sat vacant for two decades until citizens and city officials developed a masterplan for the riverfront property. The Las Colonias river park is being built in stages including an amphitheater, gardens, businesses and parks. One of the biggest obstacles to site remediation and reuse was overcoming public outrage, fear, and lack of trust which made funding sources scarce.

Jan 1, 2020

By Gwenaële Petit, Ulan Massimkhanov, Gilles Joubert

For its Zuuvch Ovoo uranium deposit in Mongolia, Badrakh Energy (partly owned by Orano Mining) is working on the prefeasibility study for exploitation by ISR (in situ recovery). As part of this project, Orano built a 2-cell (each cell is constituted of one producer well located in the center and surrounded by six injection wells in an hexagonal pattern) and a processing pilot plant that will be used to demonstrate the operability and economic viability of an ISR process. Another main objective of this pilot trial is to demonstrate the ability of Orano’s modeling tools to predict the ore behavior under given leaching conditions. To model uranium production by ISR, Orano uses HYTEC, a reactive transport computational software, which was adapted for its existing operation in Kazakhstan (Katco) to predict uranium recovery and reagent usage based on operating conditions. In order to perform similar simulations for this new deposit, Orano engaged in a comprehensive program including ore sampling, detailed characterization, and metallurgical testwork. The mineralogical conclusions were used to prepare a simplified geochemistry for the ore, in particular carbonate and reactive clay grades, uranium mineralization and penalizing elements such as pyrite. Then, bottle roll leach tests were used to characterize dissolution kinetics for smectite clays. Eventually, column leach test results such as pH, free acid, and uranium recovery were modeled on HYTEC to improve the fit of some of the dissolution kinetic parameters. Parameters fitted using metallurgical test work results will now be used as inputs for predictive model at the pilot scale, in order to anticipate operational results and help with operating decisions for production ramp up.

Jan 1, 2020

By S. Harvey

The McArthur River deposit is a structurally-controlled unconformity-related uranium deposit. The mineralization is situated at the intersection of a pronounced fault zone, referred to as the P2 fault zone, and the unconformity between Paleoproterozoic Wollaston Group metasedimentary rock and Paleoproterozoic to Mesoproterozoic Athabasca Group. Mineralization is variably hosted within the Athabasca Group fault wedge and the faulted basement, consisting of twelve zones covering a strike length of 2,700 m. The main P2 fault zone consists of several reactivated foliation-parallel faults containing narrow seams of graphitic clay gouge that are separated by highly cleaved, graphitic wall rock. The mine grid east-dipping P2 fault zone is characterized by reverse offset of the unconformity surface. It varies from a single discrete fault to splay offsets consisting of two to three individual splays. The combined vertical offset along the P2 fault zone is a maximum of about 80 m. The fault has emplaced a wedge-shaped sequence of Wollaston Group metasedimentary rocks into the Athabasca Group. Foliation-oblique faults occur throughout the McArthur deposit trend. Steep east-northeast trending faults generally exhibit apparent oblique dextral sense of shear. Less common, and possibly conjugate, are steep faults trending east-southeast with an apparent sinistral sense of shear. Offsets are generally less than 10 m on these structures. South-trending and shallow west-dipping brittle faults with offsets less than 1 m are also observed while rare steep, north-trending faults are also noted locally and played a critical role in development of the Zone 2 basement-hosted mineralization.

Jan 1, 2020