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By A. Pomianowski

A spectrophotometric study of xanthate solutions alone and their mixtures with equimolar amounts of alkyl trimethyl ammonium bromide (CnTAB) has established the additivity of ultraviolet spectra (190 - 400 my) for potassium ethyl xanthate (KEtX) and C12TAB. No obvious effect of C12TAB addition on the decomposition rate of KEtX was observed. The kinetics of collector abstraction by copper, nickel and sphalerite powders were studied in 10-5 - 10-3M solutions of KEtX alone and in equimolar mixtures of KEtX and C12TAB. Presence of C12TAB caused a 2 - 3 fold increase in the amounts of xanthate (equivalent to many monolayers) abstracted by copper and, nickel powders but had no effect on the abstraction of xanthate by unactivated sphalerite. The adsorption of C12TAB itself from the mixed solutions was very low, at most ore monolayer only, and was not influenced by the nature of the solid powder used. The results are interpreted in terms of molecular associations and synergistic action of xanthates and quaternary amines.

Jan 1, 1963

The influence of strongly chemisorbed solutes such as oxygen and sulphur on the rates of reactions at the gas-liquid iron interface is briefly reviewed. Deductions from recent studies of the rates of decarbur- ization of carbon-saturated liquid iron indicate ideal adsorption behaviour for sulphur over a wide temperature and composition range. This is in fair accord with available infor- mation on surface tensions in the Fe-C-S system. Previously unpublished results for the kinetics of the 14C02-CO exchange reaction are in accord with ideal absorption of oxygen on liquid iron. The derived value for the ideal adsorption coefficient of oxygen at 1550¦C is in quantitative agreement with measurements of the depression of surface tension in the Fe-0 system. Consideration is given to the applicability of such results to the violently agitated systems of steelmaking.

Jan 1, 1980

By Y. Posedko Eugene, S. S. Gudkov, Yu. E. Emelyanov, A. V. Bogorodsky, A. V. Boldyrev, S. V. Balikov

"The article presents the results of precious metals leaching using halogen solvents and their precipitation on a sorbent in the process of pressure oxidation. A technology of pressure oxidation – carbon-in-leach treatment (POX-CIL) of refractory sulphide gold-bearing flotation concentrates with the addition of a halogen solvent and a sorbent was developed based on the laboratory studies and pilot plant tests. The technology involves the following steps: oxidation of a flotation concentrate; precious metals dissolution and recovery on a sorbent; precious metals elution; electrolysis of eluates; smelting of cathode precipitates with producing Dore beads. This approach ensures oxidation at least 98% of sulphides and gold of more than 95%. The POX-CIL process have the following patents: a patent of the Eurasian Patent Organization No.017438 “A method of processing materials containing precious metals and sulphides” and a patent of the Russian Federation No.2625146 “A method of precious metals recovery from refractory sulphide gold-bearing materials”.INTRODUCTION Gold-bearing ores are classified as readily amenable to cyanidation, or non-refractory, and not readily amenable to cyanidation, or refractory [1]. Special attention should be given to the three most common technological types of gold-bearing ore materials, according to the Irgiredmet’s classification: pyrite-arsenopyrite ores with finely disseminated gold locked in sulphides (physical depression of gold in cyanidation process); cupriferous gold-bearing ores, when cyanidation comes along with chemical depression of gold by mineral compounds (cyanisides); carbonaceous ores showing higher sorption activity to precious metals dissolved in cyanide. Direct cyanidation of refractory sulphide gold-bearing materials does not provide high recovery of precious metals. There are the following methods of refractory gold-bearing ores and concentrates preparation to subsequent gold recovery: roasting, fine grinding, bacterial and pressure oxidation (POX) [2]. Existing POX-cyanidation flowsheets involve high costs due to a large amount of process operations and using expensive and environmentally hazardous sodium cyanide."

Jan 1, 2018

By G. I. Voiloshnikov, V. E. Dementyev

"One of the most important advances in the world gold metallurgy is the introduction of adsorption technologies for processing of ores and concentrates. «Adsorbent-In-Pulp» process allows to eliminate pulp filtration that is especially important during processing of clay and slime bearing ores. “Adsorbent-In-Leach” process is one of the ways for processing of preg-robbing (carbonaceous) products. High efficiency, increased metals recovery, decrease in capital and operational costs, possibility of easy control and adjustment are the advantages of adsorption processes. Anion-exchange resins and activated carbons are used as adsorbents. This paper presents Irgiredmet experience on gold adsorption technology using both adsorbents (RIP, RIL, CIP, CIL processes). It includes results of long-term studies of different theoretical and practical issues of adsorption processes. Irgiredmet started development of ion exchange technology (RIP, RIL) in 1964. Laboratory and pilot plant tests were conducted to develop process design criteria for 15 RIP plants of the former USSR. During this test work a great number of newly synthesized resins including strong- and medium-base resins was studied, different types of adsorption feed (ores and concentrates) were tested; some theoretical regularities of adsorption process were investigated; the technology of two stage adsorption for silver gold ore, improved flowsheet for gold elution and resin regeneration, designs of technological equipment for adsorption, elution, electrowinning processes including pulsation columns, electrowinning cells etc. were developed. Irgiredmet took part in commissioning of practically all RIP plants in the former USSR. Due to its efforts RIP process became to be the standard technology. Last Irgiredmet RIP projects include the development of adsorption technology using medium-base resin for the three mines owned by GC Petropavlovsk (Amur region, Russia). The complex of the testworks on activated carbon gold adsorption technology including the search of prospective activated carbons; study on gold adsorption mechanism; development, testing and introduction of process flowsheets and the equipment for their realization was conducted. The original gold elution process was developed. The developed CIP technology was firstly introduced at Lebedinsky gold plant (Yakutia). Now carbon adsorption technology is widely used at Russian gold mines as CIP, CIL, CIC processes. The most relevant example of CIP introduction is Svetlinsky gold plant (Ural, Russia) with capacity 8 Mt of ore/ year."

Jan 1, 2018

By Saul J. Esdalera

The flotation response to amine collector and its adsorption on the mineral surface was studied as a function of pH and collector concentration. The flotation response increased in the order anorthite + intermediate plagih clases + albite, while adsorption of amine obeyed the Freundlich equation r = A.Cn. This adsorption is proposg to be due to a covalent bonding between the AlOH surface pups of the plagioclase altered outer layer and the amino group of the collector. Finally, the study showed thatmtial dissolution of the solid phase provides the necessary conditions for amine attachment on the mineral particles and consequent flotation.

Jan 1, 1980

By Martin E. Chenevert

The early work of Terzaghi1 showed that the true stress state of a rock can be expressed by the principle of effective stress. This principle states that effective stress is equal to total applied stress minus the pore pressure. Since the introduction of this principle, a great effort has been made to measure the pore pressure of rocks so that the true stress state can be determined. For clean, permeable sandstones, it is usually found that the effective stress principle can easily be applied. Direct measurement of the pore pressure is achieved with a hydraulic pressure device and the effective stress state thereby computed. However, for fine-grained rocks which contain large amounts of clay (referred to herein as shales), pore pressure measurements are usually quite difficult because of the adsorptive forces of the clay platelets, which produce negative internal pressures. No suitable device is known for measuring internal pressures of dry shales; the effective stress approach is therefore not feasible and data are usually presented in another form. As an example, data from compressive strength tests are presented as a function of rock wetness, rather than effective confining stress. The work of Belopoloskii2 and Colback and Wiid3 are examples of such data. It was pointed out by Lambe and Whitman4 that a better way must be found to express the effective stress of argillaceous rocks. The information presented herein is an attempt to fill that need. Various authors have been able to measure moderate negative pore pressures (0-240 psi) within rather wet, argillaceous rocks by means of various pore pressure devices. In 1961 Lambe5 resented information which shows that pore pressures in argillaceous rocks are indeed negative ; he presented values of suction pressure as low as - 14 psi. Likewise,

Jan 1, 1970

By Manju Gurung, Birendra Babu Adhikari, Keisuke Ohto, Hidetaka Kawakita, Katsutoshi Inoue, Shafiq Alam

Novel bio-adsorbent gel was prepared by immobilizing functional groups of glycidyltrimethyl ammonium chloride, a kind of quaternary ammonium chloride, onto polymer matrices of persimmon extract for the recovery of precious metals such as palladium(II) and platinum(IV) from chloride media. It was found that this adsorption gel exhibits high selectivity to gold(III), palladium(II) and platinum(IV) over base metals such as copper(II) and iron(III) while crude persimmon extract, the feed material, exhibits high selectivity only for gold(III). From the adsorption isotherms study, the maximum adsorption capacities for gold(III), palladium(II) and platinum(IV) were evaluated as 3.30, 1.67 and 1.00 mol/kg, respectively. Those for palladium(II) and platinum(IV) are higher than those of simple quaternary ammonium chloride type of chemically modified persimmon tannin gel and commercially available anion exchange resin.

Jan 1, 2016

By Jianguo Yin, Wenqiang Yang, Xiaoli Yuan, Juan An, Wentang Xia

Low grade iron ore with phosphorus (LGIOWP), a raw and wasted industrial solid material was used as an adsorbent to remove Pb(II) from wastewater. The effects of initial pH value, adsorptive time, initial Pb(II) concentration, adsorptive temperature and LGIOWP dosage on the Pb(II) removal efficiency were studied. The results show that the Pb(II) removal efficiencies exceed 99.4% and Pb(II) concentrations are less than 0.30 mg/L under the conditions of pH value 7.0, adsorptive temperature 50 oC, adsorptive time 30 min, initial Pb(II) concentration 100 mg/L, particle size <0.25 mm, adsorbent dosage 5 g/L and stirring speed 260 r/min. After Pb(II) removal reaction, the Pb(II) concentrations of wastewater completely accord with the requirement of national discharge standards of pollutants from lead and zinc industries (GB 25466-2010) (TPb= 0.5 mg/L) in China. Therefore, it can be concluded that LGIOWP is a new low-cost adsorbent which is suitable for the adsorption of Pb(II) from wastewater.

Jan 1, 2015

By Daniel Geraldo da Cruz

Medidas de adsorção, tensão superficial e potencial zeta (PZ) são as ferramentas mais usadas para entender os fenômenos interfaciais e, consequentemente, os aspectos químicos envolvidos nos processos de flotação. No presente trabalho avaliou-se a adsorção dos coletores oleato de sódio (OLS) e dodecilamina (DDA) em hematita e quartzo, respectivamente, a partir da medida indireta da adsorção dos reagentes baseada em determinações das tensões superficiais das soluções residuais dos coletores após adsorção. Mediu-se também o potencial zeta dos minerais estudados em função da concentração dos coletores. As medidas indicaram que ocorreu a adsorção. Em relação à hematita os resultados sugerem a ocorrência de adsorção química. Para os ensaios realizados variando-se o tempo de adsorção, observou-se o aumento na adsorção de OLS sobre a hematita em função do tempo. Para o sistema quartzo-dodecilamina os resultados não apresentaram tendência quanto à influência do tempo na adsorção. Esse comportamento sugere que a cinética de adsorção de dodecilamina sobre o quartzo é mais rápida, ocorrendo adsorção nos primeiros instantes de contato entre a solução e o mineral.

Aug 8, 2018

By Verônica Scarpini Candido

Foi notado que o rejeito originado a partir do beneficiamento do caulim é rico em silico-aluminatos, apresentando assim potencial em processo de adsorção. O presente trabalho consiste em avaliar o potencial adsortivo do rejeito do caulim quimicamente tratado. Foi utilizado o corante de azul de metileno (AM) em solução aquosa para se ter o conhecimento de adsorção do rejeito de caulim in natura e calcinado a 700ºC onde ambos foram submetidos a uma ativação química com H2SO4. Após o equilíbrio da amostra do rejeito do caulim junto ao azul de metileno, suas concentrações foram determinadas por espectrofotometria. Os resultados preliminares comprovam que o rejeito apresenta uma boa capacidade adsortiva para concentração de até 50,00 mg/L de AM, demostrando, potencial para ser utilizado na remoção de corantes em tratamento de afluentes.

Oct 30, 2017

By L. Shevenell, L. Stillings

The Acid Drainage Technology Initiative-Metal Mining Sector (ADTI-MMS) has established a Pit Lake Committee to enhance the science and understanding for the long-term management of pit lakes. Participation in this new committee is from members of federal and state agencies, industry, and academia, including numerous individuals representing 10 states. Work has begun on a pit lake literature search and review, database, classification, and sampling and monitoring procedures document. Coordination with the International Network for Acid Prevention (INAP) has been established. Future work will include preparing a prediction and assumption verification document, a report identifying variables upon which water quality is dependent, and an applied remediation technologies document, including an evaluation of the effects of backfilling.

Jan 1, 2002

By Dr. Anurag Agrawal, Fathur Rozaq, Nella Lubis, Relinda Sanistya, Herry Saputra, Rudolf Sitorus

In mining operations, basic drone applications such as pre- and post-blast photo comparisons, blast video recordings, and sample-based fragmentation analysis are often used to assess blast performance. However, these methods lack the depth needed for comprehensive evaluations, leading to suboptimal results. This study explores the innovative integration of drone mapping technology with artificial intelligence (AI) at the Martabe Gold Mine in North Sumatra Province, Indonesia, to address these limitations. High-resolution drones and ground control points (GCPs) are utilized to create detailed orthomosaic maps, and advanced AI algorithms are applied to enhance the accuracy of blast performance insights. Field experiments reveal substantial improvements in comprehensive blast performance evaluations through this integrated approach. Enhancements include improved pre- and post-blast evaluations, AI collar detection, fragmentation size measurements, heave muckpile profiles, cast material measurements, floor prediction models, and muck pile topography volume, which is vital for ore tonnage predictions. Notably, this method achieves an average volume accuracy of 1% compared to light detection and ranging (LiDAR) technology. While LiDAR is known for its precision, the drone-based method offers a highly accurate, cost-effective, and user-friendly alternative suitable for mining applications. Despite LiDAR's superior precision, our approach provides a practical solution due to its accessibility and ease of implementation. In conclusion, the integration of advanced drone mapping and AI technologies has the potential to revolutionize blasting operations. By addressing the limitations of previous methods, this approach meets the evolving needs of the mining industry and sets new standards for accuracy and effectiveness in blast performance assessment. The combination of high-spectral drone images and AI-based software analysis demonstrated nearly 99% accuracy in ore tonnage prediction models compared to LiDAR, showcasing its promising capabilities.

Jan 21, 2025

By R. Esteban, D. Runnels, J. Torrealba-Vargas, G. Couture

"Data handling is an important step in the development of a simulator of a mineral processing circuit. The model requires representative data of the scenario to be modeled. The model development involves protocols that must be followed very closely to complete a successful project.Data handling of large and diverse datasets (metallurgical test results, geological data, mining models, historical data, etc.) is a key element of the model. The information needs to be processed, reconciled, interpreted, modeled and presented to support the design or the optimization of a mineral processing plant.Best practice recommends that teams from different disciplines (such as mining, metallurgy, geology and environmental) interact to define the most important variables that could influence the simulator. For example by adopting a geometallurgical approach in the earlier stages of the project, it is possible to consolidate the number of main ore rock types in a testwork program (saving money and time) by involving geologists and metallurgists in the sample selection and data interpretation.Planning the development of a model involves an understanding of the software capabilities but also the limitations and the magnitude of the data required to calibrate the model in case of changes in the project.A successful model requires a deep understanding of the circuit to be modeled and thus plant personnel should be considered as members of the team.This paper describes the use of the "state of the art" tools for data analysis, simulation and optimization; and shows three practical examples of the use those tools in the design of mineral processing plants."

Jan 1, 2015

By Tamara Nestorovic, Luan T. Nguyen

"With the aim to mitigate excavation risks and reduce the costs caused by tunnel boring machine (TBM) stoppage when tunneling under uncertain soil conditions, prediction ahead of the tunnel face has become an increasing interest in the tunneling community. Our research topic is concerned with developing effective concepts for nondestructive identification of geological anomalies ahead of the tunnel face by waveform inversion of reflected tunnel seismic waves. The authors demonstrate that this new technique is promising in providing tunnel engineers with an accurate image of the geological situation that the TBM is going to encounter thanks to the waveforms’ rich information about the geological structure that affects propagation, reflection/refraction and mode conversion behavior of the elastic waves. By setting up a 2-dimensional numerical model for simulation of tunnel seismic wave propagation influenced by a dip layer change ahead of the tunnel face, the authors show that the waveform misfit to be minimized by the inversion process is highly multimodal and therefore propose a hybrid stochastic optimization method that can quickly and robustly converge to the global minimum. DEVELOPMENTS IN TUNNEL ADVANCE EXPLORATION Conventional site investigation by drilling boreholes helps to draw a general image of geological structures along the borehole axes but that image is likely to misrepresent the detailed geological structure due to limited sampled locations. Due to high costs and restricted boring space which deep tunneling and tunneling under urban areas encounter, many industrial and academic research groups have had great interest in developing nondestructive ahead of the tunnel face prediction systems. That means only excitation sources and receiving sensors, which are usually placed on the ground surface or on the side walls or on the cutter head of the TBM, are used for acquisition of the measurement data. The recorded signals in the form of seismic or electromagnetic/ electrical waves, which travel through the geological structure or are reflected back from it, hold the signature of the geological structure of concern, such as geological layer changes, fault zones, erratic rocks, boulders, construction remnants, etc., and therefore can be used to reconstruct the spatial and material properties of those hidden geological structures. Most common nondestructive ahead-of-tunnel investigation systems to date are based on interpretation of reflected elastic/ acoustic waves (seismic waves) and analysis of electromagnetic/ electrical resistivity signals (Mooney et al. 2012). However, due to insufficient penetration depth and spread of signals generated by radar and geoelectric sources, the use of seismic waves for ahead of the tunnel face prediction (tunnel reconnaissance) is more preferable (Kneib et al. 2000; Bohlen et al. 2007)."

Jan 1, 2016

By Trevor Ellis

The following is extracted from a report by the author to the International Valuation Standards Committee (IVSC), with minor modifications for the purpose of publication. The author represented the IVSC at the annual session of the Ad Hoc Group of Experts on Harmonization of Fossil Energy and Mineral Resources Terminology. This is a body organized by the United Nations Economic Commission for Europe (UNECE). This second session, held in Geneva, Switzerland, achieved an important agreement for advancement toward uniform global standards for the classification of minerals and petroleum reserves and resources. Attendees discussed the possibility of enhancing the United Nations Framework Classification for Energy and Mineral Resources (UNFC) for implementation globally as the classification standard for use in financial reports under the International Financial Reporting Standards (IFRS). Presently, there are between 100 and 200 mineral and petroleum resource classification (or definition) systems throughout the world — a similar number to what there are countries.

Jan 1, 2006

By Dan Ifrim

Soft ground tunneling poses major challenges to the underground industry. Most of soft ground tunnels are in highly urbanized areas, often include limited cover, and include a strong trend of increasing diameters. Therefore, soft ground tunneling works can sometimes cause inevitable ground movements and settlements that may lead to damages to adjacent buildings, roads, structures or utilities; many of these being “lifeline” infrastructure assets. Tunneling operations, Tunnel Boring Machine (TBM) advance rates, and face pressure control can significantly increase or decrease such risks, depending on how well the TBM and operational parameters are applied to the ground conditions. Additionally, the risks of impacting existing infrastructure are heightened in many parts of North America because of cobbles and boulders. To date there is no standardized guideline that determines appropriate tunneling rates nor operator’s guidelines, to ensure safe tunnelling in soft ground. The paper analyzes tunneling records from completed soft ground tunnels to determine a relation between ground conditions, tunnel cover, TBM cutters maintenance and TBM advance rates. The records are discussed to draw several mitigation measures to be adopted during tunnelling, to reduce risks of settlements, over excavation or sinkholes.

Jun 13, 2021

By R Stefansen

Stockyard operations are governed by the interaction between the different disciplines required to successfully schedule and control the supply chain of raw material through the stockyard in combination with the effectivity of the operation of the stockyard equipment. The system demonstrates a proven technology for implementing a centralised operation of full unmanned stockyard equipment, using a high precision absolute positioning system based on a Real-Time Kinematic (RTK) Global Navigation Satellite System (GNSS) receivers in combination with 3D rangefinders. The system implementation maps the surface profile of the stockyard inventory and allows in combination with proprietary algorithms for full operation of the stockyard machines without on-board operators. The operational impact of delayering the process by moving to a centralised operation is examined, together with the combined effect on the overall safety in the stockyard as a result of a change in reliance on operator skill dependencies. Average performance gains range from 10–20 per cent. The performance of the automation system is related to a consistency and reliability of uniform operation, which has an impact on the life expectancy and the effectiveness of the equipment. The effects of having instantaneous and correct information about the stockyard inventory volume measurement are investigated in relation towards spot price trading in current fast reacting markets.CITATION:Stefansen, R, 2017. Advanced automation for centralised stockyard operations, in Proceedings Iron Ore 2017, pp 105–110 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By Andreas Rohrhofer

Reliable high end automation and process optimization systems are main factors for excellent product quality, safe operation and maximized plant performance in the steel industry and its designated environmental plants. Primetals Technologies introduces new automation packages for consequent safe and cost efficient production. Many areas within the steelplant interested to be monitored and measured automatically are not implemented in the automation system due to limited access or technical reasons. A wireless, self-organizing network facilitates wide ranging data transmission in previously inaccessible areas and opens up a wide range of new opportunities. With Fluid Guard a system to detect leakages with highest accuracy and reacts properly for all kind of water cooled circuits is available, improving the safety in steelmaking process. Lance Guard can be utilized for all fully automatic and semi-automatic lance appliances, but is especially suitable for the products of Primetals Sublance Standard/2.0 and LiquiRob applications, since these systems make seamless integration particularly simple. Manual lance appliances may also be tested and diagnosed. Environmental plants have become a main part in steelmaking plants. Highest performance in combination with optimized energy consumption is the main target in Primetals Technologies’ innovations in automation optimization packages for dedusting systems. A new approach for preventive maintenance and operator assistance is introduced with the Acoustic Expert System. In combination with the new Ask cloud based system, Primetals enables a 24/7 monitoring and a whole lifetime observation of any equipment within a steelplant. Furthermore it is now enabled to check the condition of the plant at a fingertip at any time.

Aug 17, 2017

By Dan L'Heureux, Joe Haid, Stephen H. Chung

Most coal deposits in Western Canada involve steeply dipping multiple seams. An efficient way to recover coal seams would be to drill through the seams and blast both the overlying and underlying waste material in one shot without disrupting the coal seams while fragmenting the waste rock for easy removal. This requires special blasting techniques as reported by Chung and Jorgenson in 1985.

Jan 1, 1998

By Jorge Blázquez, Paulo Couceiro, Patricio Vergara, Luis Martínez, Juan Navarro

This study introduces the X-2Mill solution, a refined two-step methodology aimed at optimizing blast designs by aligning explosive energy with rock properties. The approach employs the X-4Traits Model, which uses drill-monitoring data from both autonomous and manual drilling modes to develop two critical indexes: the Drilling Rock Factor (DRF) and the Drilling SAG Power Index (DSPI). The DRF integrates the Size-Energy Fan Model with rock fragmentation results and blast design parameters, while the DSPI adjusts Specific SAG Energy (SESAG) based on Bond’s theory, incorporating ore X80 results, SAG mill capacity (TPH), and power draw to estimate milling difficulty. To enhance prediction accuracy, the X-2Mill solution incorporates, to a Principal Component Analysis of the normalized drilling data, a Meta Machine Learning model with a 3D spatial function, accounting for information from surrounding drill holes. This integration improves the precision of the DRF and DSPI estimates. The methodology unfolds in two main steps: Step 1: Bench-Scale Pattern Design, involves defining the target P80 size for ore based on the SESAG and the DSPI. It also establishes target X80 sizes for waste and oxide materials and iterates to determine the optimal Burden x Spacing (BxS) using the Size-Energy Fan Model and the DRF. Step 2: Blast-Scale Selective Explosive Density/Energy focuses on refining explosive density on a hole-by-hole basis to achieve the specified X80 values for ore, waste, and oxide materials. The X-2Mill Solution was developed at Minera Escondida Limitada (MEL) using data from 162,761 blastholes across 356 blasts conducted over three mine expansions. This solution addresses the challenges of blasting harder and more difficult rock, particularly in the lower levels of the mine. By adapting the blast pattern and explosive density to the specific rock properties and ore/waste designation, the X-2Mill Solution aims to achieve precise size distributions and improve overall blasting performance. The results demonstrate that the X-2Mill Solution balances ore fragmentation to meet SAG mill throughput requirements while optimizing powder factor costs for waste material and maintaining digging efficiency. By efficiently distributing explosive energy, the solution not only enhances throughput but also improves blasting efficiency while ensuring stable slopes and minimizing fault activation.

Jan 21, 2025