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By B. Mishra

Several reactive metal purification processes using molten salts generate effluent from which significant quantities of metal can be recovered prior to discardinglrecycling the salt. A Salt-scrub [SS] process has been applied where the reactive metals are recovered as a metal-gallium alloy by calciothermic reduction of the metal compounds. The SS alloy compositions were produced by mixing, pressing and sintering the metal-powders. Measurement of metal recovery has been studied for cerium, silver, tin and lead. The process has been optimized for variables such as the metal quantity per kg of effluent salt, amount of excess calcium over stoichiometry, stirring rate and time and holding time at reduction temperature. Over ninety-seven percent metal recovery has been obtained under optimized conditions. The development of an alloy for efficient Salt Scrub processing reduces a major contaminated waste disposal problem as well as recovering the valuable reactive metal. Surrogate metals have been used in this work to study the behavior of plutonium.

Jan 1, 1994

By S. J. Liu

The conventional collector for bauxite mineral is oleic acid, which is highly insoluble and must be used in high dosage in bauxite flotation operations, that is the great drawback of oleic acid in use. A series of hydroxamic acid were synthesized, and their collecting ability to certain minerals in bauxite: diaspore, kaolinite were studied. The collecting power of various reagents to diaspore in an incremental sequence were shown as follows: benzyl hydroxamic acid<amylic hydroxamic ac-id<heptylic hydroxamic acid<oleic acid<octylic hydroxamic acid; while the incremental sequence of the collecting power to kaolinite was like this: benzyl hydroxamic acid<amylic hydroxamic ac-id<heptylic hydroxamic acid<octylic hydroxamic acid<oleic acid. It could be seen that octylic hydroxamic acid had the capability of high collectivity and good selectivity, and octylic hydroxamic acid was chosen to use in the following experiments. Reduced zeta potential showed the adsorption of the anionic collector on the mineral. By the adsorptive capability and IR tests, the adsorption of octylic hydroxamic acid on diaspore was determined to be chemical absorption, which was greater than that of oleic acid, as it was physical absorption. Results of floatation experiments on manually mixed minerals indicated that the collectivity and selectivity of octylic hydroxamic acid were better than oleic acid.

Jan 1, 2014

By T. Clinton Taylor

QUALITATIVELY, galena (native lead sulfide) reacts with aqueous solutions of the xanthates,1 and has its surface sufficiently altered so that there is a tendency for air bubbles to attach themselves to the mineral crystals where there was no such effect before the treatment. This property is utilized in froth flotation operations where the mineral sulfide particles are raised into the froth and the gangue whose surface is not altered remains behind. The results of a study of this reaction were reported" recently and certain tentative suggestions about the interaction of galena and the alkali xanthates were offered. In this paper, there is set down the results of a detailed quantitative investigation of the ions involved in this inter-action with a view to finding out more about the condition existing imme-diately at the surface of a crystal like a heavy metal sulfide after treatment with an organic reagent. Past experimental experience showed that finely ground galena shaken with aqueous potassium xanthate abstracts xanthate ion and at the same time sulfate ion, reducing ions of the type (SmOn)= where the ratio of m to n is less than 4:1 (as in sulfate), sometimes hydroxyl ion are thrown into solution.,

Jan 1, 1933

By W. H. Bassett

In considering the effects of reducing gases on hot solid copper the following conclusions have been reached. (1) Depth of deoxidation of copper heated in reducing gas is greater the smaller the amount of cuprous oxide originally present in the copper, the range studied being from 0.015 to 0.136 per cent. oxygen. It is suggested that the reason for this difference in depth of deoxidation is that, when the copper is low in cuprous oxide, the reducing gas is diluted less by the gas that is formed in the reaction than when the copper is high in cuprous oxide; and the greater the concentration of the reducing gas the deeper the deoxidation. (2) The rate of deoxidation is much mire rapid at the beginning of exposure than at the end, a condition especially noticeable at temperatures around 900° C.; that is, deoxidation is retarded as the depth penetrated by the reducing gas increases. (3) Within the accuracy of the experiments arsenic in copper up to 0.5 per cent. has no tendency to increase or decrease the action of a reducing gas on the cuprous oxide present in the copper. IN 1912 pieces of 0.365-in. hard copper rod 1/2 in. long were heated in a porcelain tube in an electric furnace, while illuminating gas was passed through. An approximate analysis of this gas is: FIG. 1.-EFFECT OF TIME AND TEMPERATURE ON DEOXIDATION RATE OF 0.365-IN. COPPER BY ILLUMINATING GAS; COPPER PLUS SILVER, 99.983 PER CENT. Hydrogen 38 per cent., carbon monoxide 30 per cent., illuminants 13 per cent., methane 10 per cent., ethane 3 per cent., carbon dioxide 3 per cent., nitrogen 2 per cent., oxygen 0.4 per cent. After heating for various lengths of time at various temperatures, samples were quenched

Jan 1, 1926

By C. G., Fink

The dissolution of gold by cyanide solutions was studied by determining the time required for the solvents to dissolve gold leaf. Minute traces, even 0.5 ppm, of sulphide ion retard the dissolution of gold, and this behavior cannot be accounted for by the presently accepted hypotheses involving oxygen-depletion or thiocyanate formation. On the other hand, traces of the salts of lead, bismuth, mercury, and thallium considerably accelerate the dissolution. The beneficial effect of lead is dependent upon the pH and cyanide ion concentration of the solution.

Jan 1, 1950

By Charles Hardy

ACTIVATED alumina is an aluminous material which may be 1 classified chemically as a partially dehydrated aluminum trihydrate having a high porosity and a perma¬nent physical structure. In general, it may be employed effectively and economically for the complete removal of water vapor from gases and vapors; for the selective adsorption of certain as especially those of the higher boiling points, and as a catalyst or catalyst carrier. Other forms of alumna are available and may be employed similarly but not so effectively nor can reactivation be accomplished with uniformity over many cycles without deterioration. The adsorption-reactivation cycle of activated alumina can be repeated many times without any apparent depreciation ill

Jan 1, 1934

An effective electrowinning process in hydrometallurgical industry requires fluoride levels in the base metal solution to be less than 10 mg/l. Selective removal of the fluoride ions from base solution is thus desired, if fluoride was added to control calcium and magnesium in the circuit. Consequently, adsorption of fluoride onto activated alumina was studied in a batch and a column set-up. The effects of base metal solution pH, temperature, initial concentration and flow rate on activated alumina performance were investigated in either a batch or column configuration. A two-level factorial experimental design was implemented in studying column dynamics. Results demonstrate that activated alumina is an effective adsorbent for selective removal of fluoride from base solution. In the batch operation, fluoride was removed to values below the maximum allowable concentration (10 mg/[l]) when pH was = 8. In the column adsorption step at 55°C and 600mg/[l] initial concentration, up to 16 bed volumes were processed before breakthrough level was reached. Desorption step using 1% sodium hydroxide solution achieved an elution of 8 bed volumes. The activated alumina (AA) had a capacity of 8.65 gF/[l]AA at the 10mgF/[l] fluoride breakthrough level during the column adsorption test. Keywords: Fluoride; activated alumina; adsorption; recovery; regeneration.

Jan 1, 2009

By Kent von Maubeuge, Charles R. Landis

The global bentonite industry is a dynamic market balancing a range of end uses with an ever growing number of bentonite producers. In addition, markets in developed countries are elevating the level of detail and transparency for materials reporting in programs, such as the Registration, Evaluation, Authorization and restrictions of Chemicals (REACH) program in the European Union. Bentonite is impacted by programs of this nature. The majority of the bentonite products sold around the world are sodium bentonites. These sodium bentonites consist either of natural sodium bentonites, or naturally occurring bentonite dominated by divalent interlayer cations (Ca+2 andMg+2) subsequently exchanged with sodium cation. The latter variety is often called “sodium-activated“, or “soda-ash treated” bentonite. Once exchanged with sodium, these bentonites are often difficult to distinguish from natural sodium bentonites using common commercial testing protocols. Due to their similar colloidal and bulk chemical properties; the lack of test procedures designed specifically to identify this product feature; and the failure to completely or effectively explain their differences, sodium-activated bentonite is often considered to be identical to natural sodium bentonite in the industry. This article defines both general types of sodium bentonite and presents a technique that could serve the industry as a tool to confirm the variety of sodium bentonite in question. Specifically, geochemical properties such as carbon (C13/C12) and oxygen (O18/O16) isotopic ratios can distinguish activated, even slightly activated bentonites, from bentonites not introduced to additional sodium during manufacture.

Jan 1, 2004

By McDonald K. J, Flann R. C

A liquid phase sintering (LPS) process for preparing basket anodes from nickel powder has been scaled-up and the innuence of compact green density and sulphur content, as well as sintering conditions (period and syngas now.rate) on the perfonnance of anodes has been evaluated. The product anodes have been tested in an industrial electroplating tank. It is concluded that if anode residues are to be minimised, then with a sintering temperature of 960&quot;C, compact green density needs to be as high as economically achievable (85 - 87 per cent density of solid nickel) and the sintering period approximately 40 minutes. With these constraints, if residual sulphur contents of anodes are to be kept as low as those of commercial anodes, then the sulphur content of the green compacts would need to be less than 1670 ppm. At the same time, it is also found that residual sulphur concentrations as high as 2000 ppm are beneficial to anode pcrfonnancc and not detrimental to the quality of the electroplate. The ability of the LPS process to produce marketable nickel anodes for the electroplating industry is clearly demonstrated.

Jan 1, 1993

By Ahmad Ghahremaninezhad, Rebecca Radzinski

Arsenic is a highly toxic compound that is naturally found in the environment and is released through the processing of sulphide minerals. Arsenate (As5+) is less toxic than arsenite (As3+) and is soluble in water but can form insoluble precipitates when metal ions are present. The arsenic removal processes used in industry assume that arsenic is in its pentavalent state. Hydrogen peroxide can be employed to oxidize arsenite; however, it is expensive. It has been shown that activated carbon can be used to catalyze the oxidation of arsenite with oxygen as the only consumed reagent at ambient conditions with an efficiency of 99% in less than 24 hours. The mechanism which oxidizes arsenite is not yet understood; however, this study shows that a strong oxidizing agent is formed in-situ. The species and amount of oxidant formed were determined via iodimetric titration and electrochemical methods. The production of oxidant was optimized by comparing the amount of oxidant formed in-situ to the relative amount of arsenite oxidized.

Jan 1, 2015

By D. A. Ainsworth

"The first known use of activated carbon dates back to the Ancient Egyptians who utilized its adsorbent properties for purifying oils and medicinal purposes. Centuries later, the early ocean going vessels stored drinking water in wooden barrels, the inside of which had been charred. (However, by modern definition the carbon used in these applications could not truly be described as activated.) By the early 19th century, both wood and bone charcoal was in large scale use for the decolorization and purification of cane sugar.However, it was not until the beginning of the First World War that the potential of activated carbon was really capitalized upon. The advent of gas warfare necessitated the development of suitable respiratory devices for personnel protection. Granular activated carbon was used to this end as, indeed, it still is today.By the late 1930's there was considerable industrial scale use of carbon for both gaseous and liquid phase application and new manufacturing processes had been developed to satisfy the needs of industry. During the 1939-1945 war, a further significant development took place - the production of more sophisticated chemically impregnated carbon for the removal of both war and nerve gases."

Jan 1, 1984

By Michael Drozd

"The operation of an activated charcoal system has five separate unit operations. These unit operations have common points for CIP, CIL and CIS system, which vary widely in application.The unit operations are:a. Absorptionb. Desorption (Stripping)c. Acid Washingd. Reactivatione. Carbon Handling (carbon transportation, sizing, dewatering, etc.)Cost optimization starts with the basic operating parameters (design philosophy) set down at the time of engineering design. These parameters undergo almost immediate change due to site specific ore requirements, throughput changes, operator requirements or reagent availability.Activated charcoal is sometimes viewed as simple, uncomplicated reagent that requires not optimization. To some extent, this statement is true, but under most circumstances, if the time necessary to optimize the use of activated charcoal is available, the effort is rewarded with significant savings. CPL-Carbon Link has embarked upon a program of supplying technical support with its activated charcoal. Several operations in the United States have undertaken to have CPL-Carbon Link do an operational survey to determine if potential savings are possible. CPL-Carbon Link has offered to do these surveys for projects that are clients or simply would like to have CPL-Carbon Link review their operation. The information accumulated by CPLCarbon Link is being used to attempt to fashion industry standards so that a common reference point can be established for activated charcoal usage."

Jan 1, 2008

By Jerzy A. Mielczarski

The separation of albites from quartz by flotation applying the conventional HF-methods is no longer acceptable from an environmental and health point of view. Therefore, the search for a new reagent scheme without using HF depressor for separation of albite from quartz is under consideration. The flotation behaviour of ore mineral components depends on the produced hydrophobic or hydrophilic surface coverage (chemical functionalization). Currently we have excellent possibility of monitoring surface composition and structure at molecular and atomic levels at surfaces of natural minerals contacted with aqueous solutions of collectors, activators, depressants which is vitally important for the understanding of the surface chemistry that govern selective and efficient flotation. Detailed surface characterization of minerals before and after their exposition to different solution conditions was performed by the most modern spectroscopic techniques such as developed by us the infrared external reflection technique combined with spectral simulation and X-ray photoelectron spectroscopy (XPS). It is possible to monitor surface reactions which facilitate the separation process and those which bring disadvantage to selective flotation. At first we found that a small amount of ?mineral impurity? presented in natural ore could play important role in selective hydrophobization process. It was found that the pH of solution (parameter possible to control) and natural mineral impurities present in mineral samples (parameter related to ore origin) play a very important role in the separation process. Another important parameter is interaction between minerals, quartz and albite, present in aqueous solution. The limitation of flotation separation resulting from chemistry will be discussed. Moreover, the most promising scheme for separation of albites from quartz will be examined.

Jan 1, 2014

By Rina Kim

The addition of lead to a gold leaching reactor can effectively accelerate or retard the gold cyanidation reaction. This study explored the effect of lead on the gold dissolution kinetics using cyclic voltammetry (CV) experiments. It was illustrated that the gold leaching kinetics in the cyanide solution enhanced with the addition of lead salt in the low overpotential region (–0.35 V vs. Ag/AgCl). The similar behavior was observed in the presence of ore containing 0.25% galena. In contrast, the gold oxidation kinetics retarded at –0.35 V (vs. Ag/AgCl) in the presence of silicate and lead-bearing mineral under certain conditions. Likewise, the lead addition was not functional for the high sulfur ore. This was attributed to the oxidation of the sulfides to the elemental sulfur, which subsequently formed a passivating layer on the gold surface. The results were evidently affirmed by the electrochemical tests and X-ray photoelectron spectroscopy (XPS) analysis.

By Nobuhiro Kuriyama

Electrochemical activation behavior of an AB2-Laves-phase type hydrogen storage alloy, Zr0,9Ti0.lNi1.lCo0.1Mn0.6V0.2 was studied to make clear activation process of pellet-type metal hydride electrodes. An alkaline treatment of the electrodes with heated alkaline solution gave alloy surface enriched with nickel, and the treated electrode was more easily activated. The treated electrode desorbed more hydrogen during the first charge-discharge cycle, and was activated without induction period. A cross sectional view of the activated electrode showed finer pulverization of alloy particles than the annealed alloy, and impedance spectroscopy indicated larger surface area of the electrode using the as-cast alloy. Since the as-cast alloy contains inhomogeneities, multi-phase microstructure and stress in the particle, the finer pulverization of alloy particles with hydrogenation are considered to increase surface area in an earlier cycle in the case of the as-cast alloy, which leads larger reaction area and faster activation of the as-cast alloy electrode.

Jan 1, 2002

By G. Gabra, M. Nagamori, J. J. Panneton

"RESUMELa calcination contrôlée de 10 serpentine permet de produire de 10 magnésie active. Le degré de I&apos;activation est mesure par 10 solubilité du magnésium dans les acides faibles tel que I&apos;acide acétique, La serpentine contenue dans les résidus d&apos;amiante du Québec peut donc être activée par calcination. Le teneur en magnésie active des rejets d&apos;amiante calcinés est fonction de divers paramètres: température, temps de calcination, granulométrie, etc. Les rejets d&apos;amiante de différentes provenances démontrent des comportements thermochimiques différents qui sont étudiés dans Ie présent travail au moyen d&apos;ATD, de TG, de la diffraction des rayons X et de la lixivation par l&apos;acide acétique. On constate qu&apos;un maximum d&apos;environ 80% de la magnésie totale peut être activé dans certains rejets d&apos;amiante du Québec et Ie degré d&apos;activation dépend de la provenance.vIntroductionOn sait depuis longtemps que la serpentine, Mg3Si2O5(OH)4, un silicate hydroxylé de magnésium, devient amorphe lorsqu&apos;elle perd de I&apos;eau d&apos;hydratation entre 600 et 700 °C. La serpentine ainsi calcinée est alors dissociée en magnésie et en silice. Cette magnésie, dite active, est soluble dans un acide faible ou même dans les solutions de sels d&apos;ammonium.Plusieurs precédés chimiques ont été proposés afin d&apos;extraire sous forme de composés magnésiens la magnésie de la serpentine. La plupart de ces procédés comportent une activation par calcination de la serpentine préalablement à une Iixiviation par un acide ou par une solution d&apos;un sel d&apos;ammonium.Malgré la contamination par Ie fer et par d&apos;autres éléments, les compositions chimiques des rejets de différentes mines d &apos;amiante du Québec, présentées au tableau 1, sont très proches de la serpentine typique. Puisque Ie degré d&apos;activation de la magnésie varie grandement d&apos;une serpentine à I&apos;autre lors de la calcination, la première étape de la recherche sur la transformation chimique des rejets d&apos;amiante du Québec se résume à une étude de leurs comportements thermochimiques."

Jan 1, 1982

By Qinbo Cao, Qianshan Peng, Heng Zou, Xingcai Yu

In this work, a new flotation strategy was proposed for the flotation of rutile. In this strategy, rutile was activated by Pb(NO3)2 and then floated with amyl xanthate (AX) as a collector at pH 8. Pb(OH)+ was the dominant lead species in the solution at pH 8 and is believed to be the major species reacting with the rutile surface. Time-of-flight secondary ion mass spectrometry (TOF-SIMS) study revealed that the lead activation products were well distributed on the rutile surface, and AX− could further bind with the Pb atom on the Pb-activated rutile surface. In this regard, the Pb-activated rutile could be floated by AX. Furthermore, X-ray photoelectron spectroscopy (XPS) analysis indicated that Pb(OH)2 was generated on the Pb-activated rutile surface. The electron transfer during the adsorption of the AX− on the Pb-activated rutile surface was also investigated by XPS analysis.

By Qinbo Cao, Qianshan Peng, Heng Zou, Xingcai Yu

In this work, a new flotation strategy was proposed for the flotation of rutile. In this strategy, rutile was activated by Pb(NO3)2 and then floated with amyl xanthate (AX) as a collector at pH 8. Pb(OH)+ was the dominant lead species in the solution at pH 8 and is believed to be the major species reacting with the rutile surface. Time-of-flight secondary ion mass spectrometry (TOF-SIMS) study revealed that the lead activation products were well distributed on the rutile surface, and AX− could further bind with the Pb atom on the Pb-activated rutile surface. In this regard, the Pb-activated rutile could be floated by AX. Furthermore, X-ray photoelectron spectroscopy (XPS) analysis indicated that Pb(OH)2 was generated on the Pb-activated rutile surface. The electron transfer during the adsorption of the AX− on the Pb-activated rutile surface was also investigated by XPS analysis.

By M. Hao, S. Hu, X. Lyu, M. Lian, C. Anning, G. Yao, Z. Wang

The results revealed that the pozzolanic activity of the gold mine tailings and their main mineral phases improved by mechanical activation. Under the same activation conditions, the activated mica powders possessed the highest pozzolanic activity index, followed by the activated feldspar, and the activated quartz exhibited the lowest pozzolanic activity index. The addition of calcium oxide promoted the formation of amorphous C–(A)–S–H gel for all paste samples, and stratlingite and hydrotalcite were observed in calcium oxide activated mica paste. The addition of natural anhydrite promoted the formation of ettringite for the pastes of calcium oxide activated aluminosilicates materials (gold mine tailings, mica, and feldspar). Furthermore, the pozzolanic activity indexes of the mechanically activated gold mine tailings and their main mineral phases were tested to be qualified for use as supplementary cementitious material in cement. This paper provided an innovative approach for recycling gold mine tailings as supplementary cementitious materials in cement, which would be environmentally friendly and cost-effective. Keywords: Mechanical activation, gold mine tailings, supplementary cementitious material, hydration properties, pozzolanic activity

Jan 1, 2020

By T. Qiu

"The purpose of this study is to investigate the effect of the dosage of sodium hypochlorite as activator on the flotations of depressed marmatite and depressed chalcopyrite, with a focus on activation-flotation kinetics. Four flotation kinetic models were applied to test data using 1stOpt statistical analysis software to estimate the relationships between the maximum flotation recovery rates for the depressed marmatite and depressed chalcopyrite, the flotation rate constants and the sodium hypochlorite dosages. Within the range investigated, the highest flotation performances of depressed marmatite and depressed chalcopyrite were obtained at 2.5 mL/L sodium hypochlorite with zinc recovery rate of 93.8 percent and 3 mL/L sodium hypochlorite with copper recovery rate of 94.6 percent, respectively, after four minutes of flotation. A second-order model with rectangular distribution of flotabilities gave the best fit to test data collected at various sodium hypochlorite dosages. For the highest flotation performances of depressed marmatite and depressed chalcopyrite, the respective equations of their flotation models were derived and presented.IntroductionCyanidation tailings are the solid residues generated by gold plants that use cyanide to extract gold (Lv, Ding and Qian, 2015; Zhang, Li and Yu, 2013). Because of increasing demand for gold, the Chinese gold industry has developed rapidly, with production amounting to 451.799 tons in 2014, an increase of 5.5 percent from 2013. Chinese gold production has been the highest in the world for eight consecutive years. As a result, more than 2.45 million tons of cyanidation tailings are estimated to be discharged into tailings ponds every year (Li et al., 2010; Lv, Ding and Qian et al., 2015; Wang et al., 2015; Zhang, Li and Yu, 2013; Zhang, Li and Yu, 2012), and approximately 300 million tons of cyanide tailings are stockpiled in China, with the potential to cause serious environmental pollution as well as death to wildlife (Adams and Lloyd, 2008; Donato et al., 2007; Hewitt, Breuer and Jeffery, 2012; Velasquez-Lopez et al., 2011; Stephen et al., 2009; Zagury, Oudjehani and Deschenes, 2004). Concerns over cyanidation tailings are not exclusively environmental but also economic, as tailings occupy considerable land area, and tailings storage facilities increase the production costs of gold enterprises (Donato et al., 2007). Tailings often contain other valuable metals such as zinc, lead and copper. For example, the cyanidation tailings of Gaoyao Hetai Gold Plant in Guangdong Province contain 2.5 percent copper (Cu), 0.31 percent lead (Pb), 0.23 percent zinc (Zn) and 15.36 percent iron (Fe) (Shi, 2008), and the tailings of Tianshui Gold Plant in Gansu Province contain 1.94 percent Cu, 5.96 percent Pb, 0.27 percent Zn and 24.62 percent Fe. Cyanidation tailings have therefore been increasingly viewed as a secondary resource rather than waste."

Jan 1, 2016