Search Documents

By Robert W. Metcalf

Since the spread of the European war virtually cut off imports from Denmark, Belgium, and France, the Bureau of Mines has had numerous inquiries as to domestic sources of grinding pebbles and silex or other types of ball mill liners. USES Flint pebbles and tube-rill liners are used by grinders of certain ceramic materials to prevent contamination of the finished product by iron abraded from steal baler and liners. The feldspar industry is one of the largest users of flint grinding mediums; they are employed also by curtain grinders of talc and soapstone, ground sand and sandstone, quartz, and chalk. Some paint materials, such as lithopone, have been ground in pebble Flint pebbles have been used more or less in the past, especially by cement manufacturers, and, for fine grinding of gold, copper, or other ores in which iron contamination is not especially deleterious.

Jan 1, 1940

By S. B. Robertson, D. R. Dolinar, G. E. Hinshaw, G. M. Molinda, D. M. Pappas

Rock falls in coal mines cause many injuries each year. Most of these injuries are not caused by major roof collapses, but from falls of smaller rocks from the immediate top or roof skin. Even though safety professionals and mine operators strive to reduce these types of injuries, there has not been a substantial decrease in the rock fall injury rate over the past decade. Various surface controls are used in mines to control the roof skin. One control that has proven to be very effective is roof screening. Roof screen effectively controls roof skin and provides a high roof surface coverage. Although many mines are reluctant to use screen for primary skin control because of the additional costs of time and materials, others are having great success at controlling both the costs and surface rock. In this study, injury data are presented that show a dramatic reduction in roof skin injuries when screening is used. Much of this success is due to the protection from falling rock that the operators receive from roof screen. Five case studies in which roof screen was used are presented along with the associated costs of materials, impact on bolting advance rates, and potential ergonomic risks. The effects of roof screening on skin control and safety are also included. Finally, this paper provides information about best practices and features of roof bolting machines that affect production and safety.

By B. L. Razzaboni, P. Bolsaitis

"The formation of reactive oxygen species resulting from the interaction of silica dust particles with red blood cell membranes was investigated; particularly, the effect of surface hydroxyl (silanol) group concentration on the rate of formation of such reactive oxygen species was investigated. The rate of formation was measured indirectly through the effect of catalase, a hemoprotein peroxidase, on silica-induced hemolysis. It was found that the addition of exogenous catalase to erythrocytes markedly reduces the hemolysis caused by silica particles. Furthermore, the amount of catalase required for deactivation of silica per unit area of particle surface is lower for fumed silica particles and calcined crystalline particles than for uncalcined, crystalline silica, suggesting a correlation between the concentration of OH groups at the silica particle surface and its potential for generation of H2O 2• The addition of albumin, a copper chelator, also decreases hemolysis. These results suggest that the hemolysis caused by silica particles is at least partly related to the formation of H2O2 at the particle surface and its subsequent reaction with Cu+ ions. The relationship between the concentration of surface silanol groups on the silica surface and the amount of catalase required to decrease hemolysis may also provide a method for testing potential fibrogenicity of respirable dusts. IntroductionReactive hydroxyl groups on silica surfaces are known to be cytotoxic and are believed to play a major role in silicosis (1-9). It has been proposed that this cytotoxicity results from hydrogen bonding to cell membranes and a resulting increase in membrane fluidity and permeability (4). Surface hydroxyl groups on silica surfaces have also been shown to interact with carbonyl oxygens in cell membranes (1,5). An extensive study by Nolan et al. (6) of the relationship between the negative surface charge resulting from ionized silanol groups and the hemolytic activity of crystalline a-quartz (Min-U-Sil) has shown a positive correlation between hemolytic activity and the surface concentration of silanol groups. These authors demonstrated that the hydrogen bonding of polyvinyl-N-oxide (PVPNO) with silanol groups, as well as the bonding of metal cations to the ionized sm- groups, results in significant decreases in hemolytic activity. Furthermore, it has been found that the complete removal of surface hydroxyl groups from the surface of respirable silica particles nearly eliminates the hemolytic potential of silica (7), suggesting that hydroxyl groups might be involved in other cytotoxic processes associated with silica-induced lung injury. Reactive oxygen species have been .implicated in cellular damage caused by respirable silica particles. Evidence for the presence .of oxygen radical species (02, OH°, H2O2) generated by silica, especially on freshly formed surfaces, has been produced by various investigators. Kalbanev et al. (8) detected H2O 2 in aqueous suspensions of quartz. Electron spin resonance and spin trapping by Shi et al. (9) confirmed the presence of OH"" radicals in aqueous suspensions of quartz, and Gulumian and van Wyk (10) suggested that both glass and quartz produce hydroxyl radicals in the presence of H2O 2 • Gabor et al. (11) detected the presence of malondialdehydereactive lipid peroxides (i.e., lipid-0°) in cultures of macrophages and respirable silica particles using the thiobarbituric acid (TBA) reaction test. Will (12), however, reported that iron enhances the TBA value of peroxidized lipids, and Scheulen and Kappus (19) found that catalase augmented malondialdehyde formation, thereby increasing the TBA values."

Jan 1, 1990

By Gerald W. Elger

This report describes development of the fusion-leach crystallization precipitation process for producing a hafnium content feed material for hafnium-zirconium separation plants. Mixtures of zircon, potassium silicofluoride, and potassium carbonate (or potassium chloride) were fused to prepare soluble potassium zirconium hexafluoride-potassium hafnium hexafluoride salts. High extraction of these salts was obtained by countercurrent leaching the fused material in dilute hydrofluoric acid. About one-half of the hafnium was recovered in hafnium-enriched mother liquor by cooling clarified lead: liquor to crystallize most of the zirconium salt. Additional hafnium was recovered from the primary crystals in a multiple dissolution-recrystallization step. Hafnium-enriched oxides having a hafnium-zirconium ratio of more than three times that of zircon were precipitated from the combined mother liquors. The hafnium and zirconium recoveries in the precipitate were 83 and 24 percent, respectively. About 71 percent of the zirconium and the remainder of the hafnium were recovered in potassium zirconium hexafluoride crystals of low-hafnium content.

Jan 1, 1966

By H. C. Hamontre

[The Bureau of Mines well-bore caliper was designed to provide an instrument that could be operated through 2-inch tubing, which 'a used particularly in many input wells on water-flooding projects of eastern, Kansas and northeastern Oklahoma. It should find wide application elsewhere under many other conditions where it has not been possible previously to make caliper logs with the larger probes used on other instruments. The caliper has three additional advantages over other instruments of this type: (1) It measures 4 radii (up to 18 inches) 90° apart with an accuracy of ± 1/4 inch; (2) the measuring arms can be opened and closed at will by remote control; and (3) it is run and operated on a single-conductor, armored electric cable (Amergraph, type 1-H-0). The caliper probe is 1-3/4 inches in diameter and approximately 6 feet in length. The electrical control and measuring circuits are encased in a stainless-steel tubular case. Measuring arms, made of 5/16-inch aluminum tubing, are attached near the lower end of the instrument. Distances the arms are extended are indicated t the surface by a meter calibrated to read directly in inches. Depths at which the radii measurements are taken are indicated by a wireline depth indicator on the cable-reeling. The instrument is not affected by pressure or temperature, it can be run open hole or under pressure through a lubricator. This paper describes and illustrates the instrument and outlines the operating procedures. A bibliography at the end of the report gives references to articles and patents on the development and use of other well-bore calipers.]

Jan 1, 1954

By L. M. Demers, R. E. Edelson, M. P. Rose, D. T. Superdock

The pulmonary alveolar macrophage is a major defensive cell which counteracts the invasive properties of bacteria and particles when these substances invade the pulmonary environment. Pulmonary exposure to coal dust particles is believed to activate these macrophages to release a host of d1emical mediators which can neutralize or contribute to the harmful effects of these dust particles. Our efforts have been concerned with assessing a specific family of mediator substances produced by the alveolar macrophage from arachidonic acid when these cells are in contact with activating substances such as coal dust. Metabolites of arachidonic acid produce a vast array of effects which can impact significantly on pulmonary function both with normal pulmonary events and with pathologic processes of the lung. Our studies demonstrate that isolated alveolar macrophages obtained from rats or guinea pigs cultured in vitro release appreciable amounts of the cyclooxygenase products prostaglandin E2 and thromboxane A2 and release significant amounts of the lipoxygenase products .5-HETE and LTB4. In the presence of l x 104 -1x10·7 g/ml of a coal dust suspension, alveolar macrophages from the rats and guinea pigs alters their pattern of arachidonic acid metabolite release. In the rat, exposure of alveolar macrophages in vitro to the higher concentrations of coal dust causes a significant reduction in PGE2, TXB2 and LTB4 in a 4 hour time course study. In contrast, macrophages from the guinea pig in response to coal dust had little change in TXB2 release, only a slight inhibition in PGE2 production and an initial stimulation in LTB.t release over the 4 hour time course. Cells from guinea pigs released considerably more TXB2 than the rat under these conditions while rat cells formed considerably more LTB4 than guinea pig alveolar macrophages. These findings support the following conclusions.

Mar 1, 1989

By Oliver Bowles

"Properties and Uses.Iceland spar is a name given to a pure crystallized form of calcite (CaCo3) which is sufficiently transparent and free of defects to be used in the manufacture of optical instruments. While the actual requirements are small, the degree of purity and physical perfection demanded renders it somewhat difficult to obtain suitable material.The properties of value in Iceland spar are its transparency combined with double refraction. It is used in the manufacture of polarizing microscopes, saccharimeters, colorimeters and photometers. Its most important use is in the manufacture of Nicol prisms, which constitute an essential part of every polarizing microscope. The principle governing the construction of the Nicol prism is as follows:Ordinary light in passing through a crystal of calcite is resolved into two rays of plane polarized light vibrating in planes at right angles to each other and having different indices of refraction. Thus the two rays follow different paths through the crystal. The prism of Iceland spar is cut diagonally and cemented together again with a transparent cement having an index of refraction intermediate between the two rays passing through the prism. Canada balsam is employed for this purpose. The prism is cut at such an angle that the ray having the greatest index of refraction meets the surface of the balsam at an angle greater than the angle of total reflection, and it is thus deflected to the side of the prism, while the second ray passes through. Thus one of the rays is eliminated and polarized light vibrating in a single plane is obtained."

Apr 1, 1920

By W. C. McBee

A family of modified-sulfur cements has been developed by the Bureau of Mines for the preparation of construction materials with improved properties. Various types of sulfur cements were prepared by reacting sulfur with mixtures of dicyclopentadiene (DCPD) and oligomers of cyclopentadiene (CPD). Durable cements were prepared with structural characteristics ranging from rigid to flexible. These cements were used to prepare corrosion-resistant materials for use in a wide variety of industrial applications where resistance to acidic and salt conditions is needed. These materials were prepared as rigid concretes, flexible pavings, spray coatings, and grouts. Production of modified-sulfur cements in a commercial-size plant was demonstrated.

Jan 1, 1981

By A. H. Roberson, F. S. Wartman

For many years , it has been the common practice at most copper mines to recover copper in solution in effluent mine water by precipitating the copper with scrap iron.4/ The technique employed varies from simply throwing scrap iron or tin cans into the waste ditches to passing the water through elaborate launder systems containing detinned scrap and baled cans . In general , a considerable amount of low - cost copper has been recovered that otherwise would have been lost . Iron consumption usually varies from 1 to 1-1/2 pounds of iron for each pound of copper recovered . The grade of the precipitate may be as much as 90 percent copper.4/ ,5/ Where the consumption of iron is materially greater , its cost is likely to be the determining factor of profit . In times of emergency, when the demand for scrap iron for remelting increases the cost of the iron sharply, and the supply of tin cans is not large enough to meet requirements , recovery of the copper might not be economical . The three principal reactions that take place when an acid mine water containing iron and copper salts in solution is brought into contact with metallic iron are : (1 ) Copper is precipitated and an equivalent amount of iron is dissolved , CuSO4 + Fe Cu + FeSO4 ; ( 2) ferric salts are reduced to ferrous salts , Fe2 (SO4 ) 3 + Fe = 3FeSO4 ; and (3) the free acid in the solution reacts. with metallic iron to produce ferrous sulfate , H2SO4 + Fe = H2 + FeSO4 . = Because of the reported high.consumption of iron (5 to 6 pounds per pound of copper precipitated ), when copper in water from the Hornet mine of the Mountain Copper Co. ( California ) was precipitated upon scrap iron , a series of tests was made to determine . the . optimum treatment, time , and consumption of iron .

Feb 1, 1944

This report presents a Bureau of Mines study comparing the construction costs, leakage measurements, and predicted performance of different types of large stoppings built and tested in a room-and-pillar oil-shale mine. The six full-sized structures (30 ft high by 55 ft wide) included both permanent and temporary stoppings and were fabricated using materials ranging from structural steel to coated brattice cloth. Leakage across each stopping was measured at differential pressures ranging up to 1.0 in w.g., using both the brattice window method and sulfur hexa-fluoride (SF6) tracer gas. Blast air pressures resulting from a full-scale face blast of approximately 1,800 lb of ammonium nitrate-fuel oil (ANFO) explosives were measured across two of the stoppings and the pre-and post-leakage rates were compared for all the stoppings. Overall performance of the stoppings for production applications was evaluated using an operational model of a two-panel oil-shale mine. Different combinations of temporary and permanent stoppings were evaluated based upon ventilation performance and construction and operating costs.

Jan 1, 1988

By W. F. M. GOSS

The locomotives in service on the railroads of this country consume more than one-fifth of the total coal production of the United States. The amount is so large that any small saving that can be made effective in locomotive practice at once becomes an important factor in conserving the fuel supply of the nation. For this reason the United States Geological Survey gave attEmtion to the special problems of combustion in locomotive boilers. It approached this task from several different directions. The facts presented herewith constitute one series of results. In the fall of 1906 the locomotive-testing laboratory of Purdue University, at Lafayette, Ind., entered on a series of tests, one purpose of which was to determine in precise terms the degree of efficiency with which a modern high-class American locomotive utilizes the heat energy of the fuel supplied to it. The general interest in the subject, the elaborate plans which had been formulated for conducting the work, and the substantial character of the support which had been pledged to maintain it justified the Geological Survey in aiding the investigation. a The cooperation of the Survey consisted in detailing experts to assist the regular staff of the laboratory in the chemical and calorific work of the tests. These experts, working under the general supervision of the director of the Purdue laboratory, became responsible for the sampling of smoke-box gases, of the fuel used, of the cinders caught in the front end, of the sparks discharged by the stack, and of the refuse caught in the ash pan. The gas analyses were made by them at the university laboratory. The analyses of all solid samples and the calorific tests of the fuels were made at the government fuel-testing plant at St. Louis. The representatives of the Survey were not concerned with other phases of the work.

Jan 1, 1911

By Gerald T. Homce

A system capable of monitoring mine electrical power systems and detecting impending component .failure could significantly improve power system safety and reduce unscheduled equipment downtime. Such monitoring would require a method of evaluating electrical parameters, calculated from terminal values, for indications of component deterioration. The U.S. Bureau of Mines has targeted electrical failure of squirrel cage induction motors and examined the use of mathematical models to aid in this evaluation. The initial stage of this work is complete, and has produced polynomial networks called adaptive learning networks (ALN's) that can detect and quantify winding insulation leakage simulated on laboratory motors. In this modeling process, empirical data from laboratory motors were used to select the electrical parameters most significant for assessing? motor conditions, and mathematical expressions relating these parameters to simulated deterioration were formed. ALN's developed thus far can process readily measured motor terminal information and quantify power and current levels of laboratory-simulated leakage to within 1% and 3% of full load values, respectively, for motors in the 10-to 150-hp size range. The next stage of this research is validation of these ALN's for actual motor failures; this stage is currently underway, using accelerated life testing of laboratory motors.

Jan 1, 2010

By A. Gene Collins

This report discusses some of the chemistry and geochemistry of cesium and rubidium. Knowledge of the cesium and rubidium content of oilfield waters aids in resolving the origin of waters and petroleum, exploring for petroleum and other valuable minerals, discovering water pollution sources, and augmenting the knowledge of geologic formations. The methods described in this report permit the detection of less than 0.01 mg/l of cesium and/or rubidium in a complex oilfield brine or water. Solvents possessing high-dielectric constants were evaluated for their ability to extract cesium and rubidium tetraphenylboron from oilfield waters and for their flame emission characteristics. Nitroethane was selected and used for the extraction and flame spectrophotometric determinations because it gave the highest sensitivity. Cesium 137 and rubidium 86 were used to determine the extraction efficiencies, which were about 87 percent and 58 percent respectively using a single 10 ml nitroethane extraction from a distilled water matrix. The standard deviation of the determination was 0.0008 mg for cesium and 0.0007 mg for rubidium in the 0.01 mg range.

Jan 1, 1965

Improve the dust-control effectiveness of the Rotoclone1 dry-dust collection systems used on surface coal mine drills.

Jan 1, 1994

Provide the technology to remotely reset circuit breakers on continuous mining machines used in extended cuts.

Jan 1, 1994

By Robert F. Holub

The U.S. Bureau of Mines (USBM) has tested a personal dosimeter for measuring radon decay products that is manufactured by Tom Scurry Associates. The tests were made to determine the accuracy of the dosimeter system for record keeping of radiation exposures to radon decay products encountered in mining. The radioactivity-detecting head is based on a design developed by the USBM, and the associated air pump was developed by the manufacturer. The dosimeter system was tested in the USBM radon chamber. The detecting head uses CaF:Dy thermoluminescent phosphors and is mounted on a self-regulating air pump. Batteries supply power sufficient for an 8-h shift. The dosimeter system is worn on the miner's belt. Dosimeter calibration tests were performed by the USBM. In addition, the pumps were tested and evaluated under continuous flow conditions. The results of these tests indicate that the Tom Scurry Associates Model DOSI600 dosimeter is suitable for general use in mines where record keeping for natural radiation exposure is required.

Jan 1, 1995

This Bureau of Mines investigation addressed two primary issues of air velocity measurement in mines: the determination and use of correction factors, and the development of guidelines for the selection of a suitable site at which the measurements should be taken. Other facets of the investigation included a comparison of measurement methods and devices, and aircourse cross-sectional area measurement. The study consisted of theoretical, laboratory, and in-mine investigations. The measurement devices included in the experimental phase were vane anemometer, vortex shedding anemometer, a prototype thermoan-emometer, smoke tube, and oil of wintergreen sprayer. The measurement methods included single-point centerline, timed-point traverse, continuous traverse for the anemometers, and various distances and cloud positions for the smoke tube and oil of wintergreen devices. The study resulted in guidelines for measurement site selection that are applicable to most inmine situations. It also showed that the use of correction factors is problematic. There are many potential pit-falls and there are cogent arguments against using certain correction factors. However, generalized correction factors were developed that can be successfully applied in routine ventilation work, provided that their use is properly understood.

Jan 1, 1985

By G. L. Neumann

"INTRODUCTION Mining in this area is inactive. The entire region is now comprised of small farms. Because approximately 1,500,000 tons of magnetite ore had been shipped from this area between 1855 and 1915, it was deemed probable that geophysical surveying and core drilling might indicate other ore bodies or sizable extensions of the previously mined ore bodies.ACKNOWLEDGEMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has, as its primary objective, the most effective utilization of our mineral resources, thus fortifying our national security and economy. It is the policy of the Bureau to publish the facts developed by each project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual investigative work and prepares the final report. The Metallurgical Branch, Oliver C. Ralston, chief, analyzes samples and performs beneficiatien tests.The chemical analyses and beneficiation tests included in this report were performed at the Eastern Experiment Station of the Bureau of Mines at College Park, Md., under the general supervision of J. B. Zadra, chief, College Park Division, Metallurgical Branch, and the immediate direction of Dr. Alton Gabriel, head of the laboratory service unit.The Mineral exploration Was under the general supervision successively of G. D. Jermain, district engineer, C. B. White, district engineer, and McHenry Mosier, chief, College Park Division, Mining Branch.The geophysical section of the exploration was performed by G. B. Botsford, engineer of the Bureau of Mines. Assistance was given by the Division of Geophysical Exploration of the Bureau of Mines, Dr. F. W. Leo, chief."

Dec 1, 1947

By A. Soderberg

This paper describing the mining practice at the Utah Copper Co., Bingham Canyon, Utah, is one of a series being prepared by the Bureau of Mines on mining practices, methods, and costs in the various mining districts of the United States. The Utah Copper Co. operates the low-grade open-out copper mine at Bingham Canyon, Utah, which is 30 miles in a southwesterly direction from Salt Lake City. In addition to the mine the company operates two flotation concentrators, the Magma plant and the Arthur plant, which have a combined capacity at maximum metallurgical efficiency of 60,000 tons daily. The concentrators are at Magna, about 18 miles from the mine. The company operates its own standard-gage railway, known as the Bingham and Garfield Railway, between the mine and the mills (fig. 1). Concentrates are smelted at the Garfield smelter of the American Smelting and Refining Co., situated 4 miles from the mills.

Jan 1, 1930

By T. E. Green, E. F. Spano, W. J. Campbell

A combined ion - exchange X- ray spectrographic method was developed and evaluated for determining trace amounts of cobalt and nickel in high - purity tungsten and tungsten trioxide . The sensitivity for both cobalt and nickel is in the range from 0.2 to 0.5 μg ( 0.04 to 0.1 ppm , based on 5 gram samples ) . Accuracy at the 5 to 20 μg level is ±10 percent of the amount present . Approximately 16 hours elapsed time is required for analysis

Jan 1, 1963