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By J. M. Stuve

Low-temperature heat capacities and the enthalpy of formation were deter-mined calorimetrically by the Bureau of Mines for CuO?CuS04. The derived standard entropy (S°298.15) was 40.36±0.04 cal/deg-mole, and the enthalpy of formation (?H°f) was -219.l±0.3 kcal/g-mole. A large thermal anomaly was observed in the heat capacity of CuO?CuS04 at 20±0.1 K. Gibbs energy of formation data are tabulated up to 1,200 K. Construction details of a precision low-temperature adiabatic calorimeter capable of determining heat capacities of solids in the temperature range 5 to 320 K are given. A calibrated miniature germanium resistance thermometer was incorporated into the calorimeter to extend the range of accurate measurements below 15 K. High-resistance dc heater windings were used throughout the cryostat to reduce heat conduction of inner connecting wires.

Jan 1, 1975

Through a contract, the Bureau of Mines has funded the development of an Automated Breathing Metabolic Simulator (ABMS). The ABMS simulates man in all of the breathing and metabolic parameters for monitoring support and resuscitation equipment. For the first time, complete breathing and metabolic simulation are incorporated in the same device. Breathing rate, breathing depth, breath velocity contour, oxygen uptake, and carbon dioxide release are all variable over wide ranges, simulating conditions from sleep to hard work with respiratory exchange ratios covering the range of hypoventilation to hyperventilation. In addition, all of these parameters are remotely controlled to facilitate the use of the device in hostile test environments. The exhaled breath is also at body temperature and completely saturated. The simulation in faith¬ful to the extent of having a variable functional residual capacity and an anatomical dead space equivalent to that of humans. The ABMS will be used as a stand-in for humans in test and validation of respiratory equipment, permitting more extensive and safer evaluation in hazardous environments where human testing would have to be limited. In addition, it will greatly reduce the cost of prolonged testing in cases where simulation chambers with human subjects require three shifts of crews, including standby physicians. Perhaps most importantly, it will provide a calculated and reproducible test and validation facility. The ABMS is under complete computer control. Through a typewriter terminal the test sequence can be input into the computer which will then automatically adjust the ABMS to simulate any desired sequence of metabolic activities for time durations up to 15 hours. The computer also monitors the test procedures and provides test results printout.

Jan 1, 1973

By John W. Taber

"INTRODUCTION AND SUMMARYDiscovery of these unusual fluorite deposits was brought to the attention of the Bureau of Mines late in 1951, shortly after the first locations were made. A brief investigation of the deposits by the Bureau revealed seven principal outcrops of fluorite in two areas. The smallest outcrop continuously exposes massive fluorite over an area 25 by 55 feet; the largest outcrop is a similar exposure 180 by 240 feet. The deposits, appear to be sharp-walled, low-angle, tabular ore bodies in granite and are at least 10 feet thick.The Bureau investigation of the deposits included bulldozer strip-trenching, drilling and blasting rock cuts, and channel sampling across three of the largest outcrops. This sampling indicated an average grade of 97.2 percent CaFp and 1.44 percent SiO2.Preliminary metallurgical tests on the ore indicate that it can be concentrated to acid-grade specifications by simple gravity methods. One laboratory test recovered 78.4 percent of the fluorite in a product containing 98.7 percent CaF2, 0.25 percent SiO2, and 0.10 percent Fe2O3."

Oct 1, 1952

By N. A. Eilertsen, Rolf S. Paine

The Bureau of Mines studied the presplitting technique used for controlling overbreakage in the walls of a vertical shaft at the U.S. Army Corps of Engineers Littleville Dam project near Huntington, Mass. The periphery of the shaft, the dimensions of which were 16-1/2 feet wide by 21 feet long and 52 feet deep, was presplit (cracked) in the solid to a depth of 48 feet prior to full-depth sinking. Presplitting prevented overbreak in a fairly soft schist and provided sound self-supporting walls which required very little scaling.

Jan 1, 1965

By Charles F. Jackson

Waste filling has been employed for many years for supporting the walls of stopes and preventing failure and subsidence of the surrounding and overlying rock formations, and its effectiveness for this purpose has long been recognized. It is used for permanent support in ground where timbering (including square-setting) is inadequate for more than temporarily supporting the walls of the excavations. It should be rioted, however, that effective as a good, solid fill may be in resisting heavy side pressure and direct weight, its usefulness for supporting large areas of back and preventing breaking and movement of the overlying rocks is limited. Even the strongest and most uniform rocks will break if the unsupported span becomes too great; and since filling cannot be packed tightly against a horizontal back there is always a possibility of the back breaking and consequent subsidence if the maximum self-supporting span is exceeded. Planes of separation, such as bedding and fault planes, slips, and joints, are common in all rock masses; these may occur above the stoping area where their presence cannot be ascertained by observation. If too much reliance is placed upon filling for the support of a large horizontal area of back (as contrasted to support of vertical or steeply inclined walls) large masses of rock may break along a. plane of weakness, compress the fill, and leave an open space into which caving of the overlying rocks may continue until the space is filled. In this paper the term "waste filling" includes any filling material other than ore - waste mine rock, rock from surface quarries or opencuts, sand and gravel, mill sands, or slags from smelting operations.

Jan 1, 1935

By K. L. Rubow

"IntroductionAir sampling for airborne contaminants requires a system for moving air, a collection method, and a procedure to determine the quantity of contaminant collected. Because occupational exposure limits and air quality standards frequently are expressed in terms of concentrations, a method of determining the volume of air sampled is also needed. The four principal components in a sampling train are shown in Figure 12-1. The inlet admits the air sample into the train; the collector(s) separates the gas, vapor, or particles from the air; the flowmeter measures the rate or total quantity of air sampled; and the pump (air mover) provides the suction required to draw an air sample through the train. Inlet sampling considerations are discussed in Chapter 21. Various types of collectors are described in subsequent chapters. Flowmeters are discussed in Chapter 7.This chapter will describe the air mover portion of the sampling train and air sampling systems that contain three or four components in a convenient package. The chapter consists of two parts. The first part contains a brief description of the different types of air movers and air sampling systems. The second part consists of tables and figures showing detailed information on a wide variety of commercially available air movers and sampling systems. ient size is filled with a liquid in which the suspected contaminant is insoluble. When the liquid is allowed to escape from the vessel, it is replaced by air from the atmosphere to be sampled. Such an air sample is an integrated sample rather than an instantaneous sample because the mass of fluid requires a finite time to empty. In fact, by employing a large vessel with controlled drainage, this method can be used to move air at low flow rates through a sample collector for extended intervals. Additional discussion of this method can be found in Chapter 17."

Dec 1, 1996

By H. B. Salisbury

As a part of a research program designed to help minimize national requirements for new mineral commodities by maximizing recovery of metals from domestic secondary resources, the Bureau of Mines investigated the development of economic methods for recovering copper and associated metals from complex electronic scrap. Three types were selected for research: (1) multiple-pin plugs and connectors, (2) obsolete aircraft radio assemblies, and (3) the magnetic fraction of shredded electronic scrap furnished by the Bureau's Avondale Research Center. The plugs and connectors, after incineration to remove plastic components and melting, yielded a brittle ingot, as did the internal portion of the radio assemblies. The brittle ingots were ground to minus 35-mesh for processing, and the magnetic material was used in the as-received condition. A process using pretreated or raw scrap as a copper precipitant in various concentrations of acidulated copper sulfate solution was developed as a means of effecting an initial separation and upgrading in the form of high-grade cement copper containing all or most of the precious metals.

Jan 1, 1981

By James Paone

The Bureau of Mines made drillability studies with impregnated diamond bits in the laboratory on 7 rock types and in the field on 21 different rock types. Results indicate that drill parameters of rotational speed, thrust, and torque must produce sufficient applied forces to induce stress levels that cause continuous failure in rock to achieve efficient penetration rates. Higher rotational speeds appear to be more effective in drilling relatively harder rocks, although the increased speed causes more bit wear; increases in thrust result in higher drilling rates but not linearly; and up to a critical value a linear relation exists between torque and penetration rate for a specific rock type. Penetration rates with impregnated bits show a trend similar to that obtained with surface-set bits for rock under 25,000 psi compressive strength.

Jan 1, 1966

By D. B. Dow

This paper on the physical chemistry of oil-field emulsions is the last of a series of three prepared as a result of a study of oil-field emulsions. The first paper3 deals with the factors responsible for the formation of emulsions, find the second4 with methods now utilized for dehydrating oil-field emulsions. A more complete report of the whole investigation is in preparation. The laws governing the formation and resolution of oil-field emulsions fall in that branch of physical chemistry doling with colloids. Much work has been done by the physical chemist on colloids And emulsions, and, although most of this work was on commercial and pharmaceutical emulsions, yet the principles developed apply in a general gray to oil-field emulsions.

Jan 1, 1925

By N. E. Hanna

To be approved for use in underground coal mines in the United States, explosives and blasting devices must pass certain safety tests prescribed by the Federal Bureau of Mines. These tests are described in Schedule 1-G4/ (explosives) and Schedule 26A5/ (blasting devices). An explosive or blasting device that passes the appropriate tests is placed on the active permissible list. As this list is subject to continuous revision, it has been the practice of the Bureau of Mines to publish periodically the names of explosives and blasting devices that have been added to the active list, as well as those that have been transferred to the inactive list; changes in brand names also are reported. The present circular gives all explosives and blasting devices on the active permissible list as of December 31, 1957, and shows all changes, additions, and transfers in that list between December 31, 1951,6/ and December 31, 1957.

Jan 1, 1958

By Kenneth M. Earl

This report describes the results of a field study conducted by the Bureau of Mines during 1956 and 1957 on manganese-and iron-bearing mineral deposits in the southern district of Aroostook County, Maine. The work was undertaken to determine the extent of deposits largely concealed under glacial drift and to obtain subsurface samples for manganese mineral identification and research in ore dressing and extractive metallurgy. The investigation was confined to the Westford Hill-Daggett Hill area in Hodgdon Township and to the Stewart prospects and vicinity in Linneus Township. Over 50 magnetic anomalies were mapped by magnetometric surveys in the Westford Hill-Daggett Hill area, Hodgdon Township. The largest anomaly, as outlined by the 1,000-gamma contour, indicates a deposit 3,200 feet long with a maximum width of 350 feet. The smallest anomaly measures about 10 feet wide by 25 feet long.

Jan 1, 1962

By Kenneth E. Hjelmstad

In situ leach mining operations often encounter difficulty maintaining adequate leach solution flow into the are formation. Swelling and dis-persion of clay particles in the formation are often responsible for this permeability loss. Permeability and leaching tests were done in the laboratory on clayey ores to evaluate a clay-stabilizing polymer's effectiveness in preventing these problems. Test results indicate that treating the ores with the stabilizer could maintain permeabilities two to five times greater than the long-term permeabilities present in untreated ores. Both alkaline (pH 8.5) and acidic (pH 2.0) leaches were used in the permeability-leaching tests. Since in situ leaching throughput rate is directly related to permeability, these results also indicate a potentially beneficial effect on operating parameters such as capacity and injection pressure. To determine the reasons for the success of the clay stabilizers, an investigation was conducted to cieter-mine the effect of the stabilizer on clay swelling and dispersion. Clay-swelling tests indicated that the clay stabilizer reduced clay swelling. Zeta potential measurements made on fine clay particles treated with the stabilizer were compared to measurements made on untreated particles and indicated that the stabilizer was electropositive and, therefore, could reduce the degree of negative charge on the particles and their tendency to disperse or migrate.

Jan 1, 1984

By J. A. Taylor, H. F. Yancey

"INTRODUCTION Froth flotation as applied to coal is a process for separating desirable carbonaceous material from undesirable inorganic matter. In general, the feed must be finer than one eighth inch in size. The principal use of the process in the preparation of coal appears to be in the treatment of the fine sizes produced by breakage during mining and preparation.The Bureau of Vines in Information Circular 6714 has published general information on coal flotation, summarized investigative studies of the process, and described operating plants throughout the world with their tonnage, reagent consumption and operating costs.4ACKNOWLEDGMENTSThe present study of means for depressing pyrite and reducing ash ty froth flotation was conducted at the Northwest Experiment Station of the United States Bureau of Wines in cooperation with the College of vines. University of Washington, under the general direction of A. C. Fieldner, chief engineer, Experiment Stations Division, Bureau of Wines. Grateful acknowledgment is made for suggestions and criticisms received from W. H. Coghill, supervising engineer, U.S. Bureau of Mines Mississippi Valley Experiment Station, Rolla, Mo.; J. B. Morrow, and R. E. Zimmerman, of the Pittsburgh Coal Co.; and Dean Milnor Roberts and Prof. Joseph Daniels, of the College of Mines, University of Washington.FLOTATION AND DEPRESSIONA substance will tend to float if its surface attracts a gas film more strongly than it does a liquid film when both air and liquid are competing for this attraction. On the other hand, a substance will not float if its surface attracts a liquid film more strongly than it does a gas film. All theories of depression depend upon this fact. A wetted particle of floatable size most likely will be found in the tailings after the flotation process has been completed.The crux of flotation is the selective wetting of the undesirable material that tends to float. Two general methods 5, 6, 7 of depression are in use: One combines a chemical substance with the surface to form a wettable compound, and the other employs some colloidal or ionic substance which the surface selectively adsorbs, thereby forming a wettable surface."

Jan 1, 1935

The purpose of this study is to develop designs to facilitate and accelerate auger rotation stoppage (and auger rotation start up so as to promote auger disengagement during auger miner repositioning) and to provide a time delay and warning signal prior to auger start up to permit any miner s near the augers to get away from the augers before they start rotating. In the underground coal mines in the U.S., there are four auger miners that are currently in use. They are the Jeffrey 100L (see Figure 1-1) and 100M (see Figure 1-2), and the Wilcox WCM and the MK20A (see Figure 1-3).

Jan 1, 1974

By Joseph S. Coffman

To determine the availability of manganese for metallurgical purposes from selected world resources, the Bureau of Mines evaluated the potential production of contained manganese in concentrates based on the demonstrated resources of 23 foreign and 8 domestic mines and deposits in 9 market economy countries. All but 2 of the 23 foreign deposits are operating mines; none of the domestic deposits are in operation. The demonstrated resources of the mines and deposits used in this study represent an in situ ore resource of approximately 2.2 billion tons," containing 780 million tons of manganese with a total recoverable production potential of 514 million tons of contained manganese in concentrates. The analyses of mines and deposits in this study indicate that about 213 million tons of the contained manganese (41 pct) is potentially available at a January 1981 constant dollar long-run total cost of up to $1.50 per long ton unit (22.4 lb, or 10.15 kg contained Mn), approximately 428 million tons (83 pet) is potentially available at a cost of about $1.75 or less, and 491 million tons (95 pet) is available at less than $3.30. The remaining 23 million tons, which is potentially available at much higher costs (about $8 to $35 per unit), represents the U.S. deposits. On an annual basis, with a cost range of up to $1.75 per long ton unit, the availability from currently operating mines would last at least 80 years based on 1980 world production data. Total manganese production costs are estimated to comprise mining-8 pet, beneficiation-3 pet, transportation-26 pet, and smelting-63 pet.

Jan 1, 1984

By Richard D. Mehring

A refined ad improved self-sealing brattice for use in coal mine rescue and recovery operations for directing the flow of air has been developed and tested by Goodyear Aerospace Corporation for the U.S. Bureau of Mines. The brattice is made from a lightweight, low cost material that meets MSHA flammability requirements. The units can be erected using pins, spade or lightweight extensible poles. Tests here conducted to determine leakage rate from minimal to a maximum of 1.5" H20. The ability to handle reverse flows was demonstrated and a non-flammable foam was used as an auxiliary sealing agent.

Jan 1, 1978

By David C. Oyler

Three long horizontal holes were drilled from a directionally drilled surface hole at the Emerald Mine near Waynesburg, Pa. The purpose was to adapt the technique of directional drilling for use in draining methane from coalbeds. A 504-m (1,652-ft) long, 76-mm (3-in) diameter, circular arc pilot hole was drilled, using a downhole mud motor, to enter the Pittsburgh coalbed at a vertical depth of 305 m (1,000 ft). The hole was reamed to 222 mm (8-3/4 in) and was cased to a measured depth of 486 m (1,595 ft). Three 76-mm (3-in) diameter horizontal drainage holes were then drilled, totaling 2,909 m (9,544 ft) of horizontal hole. Improvements in drilling methods increased the average drilling rate from 20.4 ill (67 ft) to 64.9 m (213 ft) per day. The cost of drilling the directional and horizontal holes (using a Government-owned drill rig) was $1,169,530, a figure inflated by inexperience and by delays caused by lost-circulation problems and fishing operations. An estimated total drilling cost of $960,000 (including rental of a drill rig) for an improved system, was determined by a detailed cost analysis. Initial gas and water production from November 1979 through May 1980 was low because of caving of the horizontal holes drilled in shale near the bottom of the casing.

Jan 1, 1982

By Robert Lee Stahl

Comprehensive field tests were made by the Federal Bureau of Hines at the Conda open pit mine near Soda Springs, Idaho, to determine whether surface geophysical techniques could be used to detect and delineate faults in phosphate deposits. The tests included seismic refraction, magnetometry, electrical resistivity, and airborne photography. Of the several geophysical techniques tested in the field, horizontal resistivity profiling was the most effective method for diagnosing faults. The method is quick, inexpensive, accurate, and can be easily used by mining company personnel to detect and delineate faults.

Jan 1, 1975

Reduce well construction and operation costs associated with in situ leach mining while increasing mineral recovery. Approach To accommodate the size of centrifugal pumps presently in use, in situ leaching production wells are typically drilled to 6 inches in diameter, while monitor wells are drilled to measure 4 inches in diameter. However, in order to reduce the cost of drilling these larger diameter wells and to increase recovery, the Bureau has developed jet pumps which have smaller diameters than centrifugal pumps of the same capacity. This allows both production and monitor wells to be drilled smaller. Bureau estimates indicate that the cost of drilling a 3-inch-diameter production well at in situ leaching operations would be about 35 percent less than the cost of a 6-inch well. Similarly, the cost of drilling a 2-inch-diameter monitor well would be about 26 percent less than the cost of a 4-inch well. Such significant savings in the cost of drilling these wells would effect a substantial reduction in total capital cost. Use of the new jet pumps can also increase the percentage of recovery because less costly wells allow closer well spacings, improving the distribution of the leach solution. How the System Works After the borehole is cased, the new small-diameter jet pump, along with piping and accessories, is installed and connected to a centrifugal pumping unit on the surface. High-pressure water from the surface pump is forced through a nozzle into the venturi of the jet type pump injector. This jet action lifts the leach and mineral-bearing solution to the surface.

Jan 1, 1984

By R. Wiebe

During a recent investigation the authors were interested in determining: (1) How many points were necessary to locate the deviation curve for copper-constantan thermocouples within an accuracy of about 0.05° C., used in connection with the, "standard" thermocouple of L. H. Adams (2) Whether copper-constantan thermocouples showing considerable deviations from the "standard" were consistent throughout their calibration. (3) How reliable the extrapolated portion is - that is, the interval between -183 and -220° C. of the "standard" thermocouple.

Jan 1, 1931