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By Robert C. Johnson

Water-swelling fluormicas and fluormontmorillonoids were synthesized and described. They were found predominantly in the system Mg0 - MgF2 - Si02, with varying amounts of Li+ or Na+, Some water-swelling synthetic minerals were prepared with only strontium or lead in the twelvefold position, Water- swelling compounds containing either K+ or Ba+ were not found. The synthesized water-swelling products were shown by electron microscopy, X-ray diffraction, and chemical analysis to be typically two-silica-layer, platy compounds, Except for the complete substitution of fluoride for hydroxyl, the compounds were similar to the natural micas or montmorillonites. The stability and properties of the compounds were further established by electrodialysis, by differential thermal analysis, and by anion and cation exchange methods. Fluoride in the interlayer positions was nonexchangeable except through decomposition of the product. Exchanging the sodium or the lithium of the synthetic fluormicas or fluormontmorillonoids with potassium ion, particularly those derived from KOH provided a product from which a completely inorganic paper of extraordinary flexibility was fabricated. This paper had excellent mechanical and electrical properties except for water adsorption and a high power factor. Neither of these problems was solved during this investigation. However, papers with dielectric strength from 1,500 to 5,000 volts per mil were readily fabricated, particularly from the lithium containing fluormicas or fluormontmorill onoids.

Jan 1, 1963

By C. Q. Cupps

n view of increased interest in secondary recovery of oil in the Cut Bank field, Montana, a review has been made of unpublished data obtained during a 1943-44 study of reservoir oil characteristics in this field. Considerable uncertainty was attached to interpretations of subsurface oil sample analyses from six Cut Bank zone wells, one Lander sand well, and one Moulton sand well, because of adverse sampling conditions and wide range in the data. Much of this uncertainty has been removed by this review which has shown two of the Cut Bank zone samples and the Moulton sand sample to be representative of the reservoir oils. Estimates of original reservoir oil characteristics derived from differential-liberation analyses of these samples show that the oil in the Cut Bank zone was initially saturated at the gas-oil contact pres-sure, 750 psia, and the oil in the Moulton sand was undersaturated with a saturation pressure of only 380 psia. The rest of the samples were indicated to be nonrepresentative of the reservoir oils because of a disproportional vaporization of heavier components of the solution gas. The vaporization of these components is believed to be a cumulative effect of contact of the oil with bypassing, light-gravity gas which had been liberated at higher pressures from solution in oil farther back in the formation, or which had come from the gas cap, rather than from the singular effect of gas evolution caused by excessively low bottom-hole pressures. Change of oil composition caused by the latter was found to conform closely to that occurring during a differential liberation of gas in the laboratory.

Jan 1, 1967

By Terry J. Close

In 1985, at the request of the U.S. Bureau of Land Management, the U. S. Bureau of Mines studied part of the 56,623-acre South McCullough Mountains Wilderness Study Area (NV-050-435) in order to evaluate its identified mineral resources. The area studied is located in Clark County, NV, about 30 miles southwest of Boulder City. No mineral resources were identified. The study area contains the eastern part of the unorganized McCullough Mountain (McClanahan) mining district which has had no recorded production. Between 1911 and 1982, 23 lode claims were located in the part of the mining district that is in the study area; four of these claims are currently held by assessment (1986). A total of 11 mineral sites were found and examined during the U.S. Bureau of Mines investigations; 26 mine workings were examined. Of the 11 sites, four are within the study area, and seven are nearby. Of the seven nearby sites, six are adjacent to the west boundary and consist of precious-and base-metals bearing vein occurrences in metamorphic rocks. The seventh site is near the east study area boundary, and consists of a tungsten-bearing vein occurrence that is also in metamorphic rocks. The four sites within the study area consist of vein occurrences in metamorphic rocks that contain silver, gold, arsenic, lead, zinc, and copper. The veins at these four sites are too small and low grade to be classified resources; however, there are indications that three of the sites may have silver and gold resources at depth. Detailed delineation of the veins, and determinations of tonnages and grades are needed. This would entail additional mapping and sampling, trenching and drilling, and opening inaccessible workings.

Jan 1, 1987

By A. J. Kraemer

This paper on the physical and chemical properties of crude oils from California fields is one of a series of reports on the on the districts of the United States. The paper includes a short discussion of results, tabular data, and individual analyses of eight. California crudes. Analyses of other crude oils from California have been published it Reports of Investigations 2595, 2608, and 2846. The samples were obtained by members of the San Francisco office of the Bureau of Mines. The collecting 65 samples was facilitated by the courtesy of representatives of oil companies in California. The methods used in testing and analyzing the samples are described in detail in Bureau of Mines Bulletin 207. A discussion of the interpretation of crude-oil analyses, as made by the Bureau of Mines, is given in Bureau of Mines Report of Investigations 2806.

Jan 1, 1931

This paper on. the physical and chemical properties of crude oils from California fields is one of a series of reports on the oil-producing districts of the United States., The paper includes a short discussion of results, tabular data, and individual analyses of eight California crudes. Analyses of other crude oils from California have been published in Reports, of Investigations 2595,3/ 2608,4/ and 28465/. The samples were obtained by members of the San Francisco office of the Bureau of Mines. The collecting samples was facilitated by the courtesy of representatives of oil companies in California.

Jan 1, 1931

By Benjamin W. Haynes

Analytical procedures are described for the quantitative determination of 16 elements (As, Ba, Be, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb, Sb, Se, TI, and Zn) and 7 ionic species (NH4, C032-, CI-, F-, NO3-, P043-, SO42-), identification of major and minor mineral components, and measurement of physical properties associated with manganese nodules and nodule processing reject waste materials. Compound identification methods discussed include X-ray diffraction, infrared spectroscopy, scanning and transmission electron microscopy, selective area electron diffraction, and optical and reflected light microscopy. Methods for elemental analysis include atomic absorption spectrophotometry, inductively coupled plasma emission spectroscopy, neutron activation analysis, fluorescent X-ray spectrography, and ion chromatography. Thermal gravimetric analysis, ultraviolet-visible spectrophotometry, ion specific electrodes, and standard wet chemical procedures are briefly discussed. Physical properties determined in manganese nodule materials include grain size distribution, specific gravity, triaxial shear, permeability, maximum density, Atterberg limits, and slurry density. The results of a round-robin analysis of an ammonia process waste material and manganese nodule standards demonstrate the applicability of the discussed methods. Tests discussed for the evaluation of the waste materials for disposal options include the Environmental Protection Agency (EPA) EP toxicity test, the ASTM shake extraction test, and the U.S. Army Corps of Engineers EPA seawater elutriant test.

Jan 1, 1983

By C. C. Hustwit

The U.S. Bureau of Mines formulated a new mathematical model to characterize iron oxidation. The new model is intended to replace the currently used model, recommended by the Environmental Protection Agency (EPA), for most acid mine drainage (AMD) treatment applications. The new model was evaluated in a series of five synthetic AMD treatment tests. The initial ferrous iron concentrations ranged from 800 to 2,400 mg/L. In these tests, the Bureau model underpredicted the measured ferrous iron oxidation rates by a range of 3.24 to 8.03 pct. This was considered to be in close agreement after consideration of experimental error. The model proposed by the EPA was also evaluated using the same test data. The EPA model underpredicted the oxidation rates by a range of 77 to 100 pct in four tests and overpredicted by 19 pct in one test. The model formulated by the Bureau expresses that the rate of iron oxidation is a function of a treatment system's oxygen transfer efficiency and is independent of ferrous iron concentration when treated to near-neutral pH's. A new test method for evaluating oxygen transfer in flow-through reactors is also described.

Jan 1, 2010

By B. W. Gandrud

In the summer of 1950, Bureau of Mines engineers visited a number of coal-preparation plants in western Europe and Great Britain to obtain information on European and British coal-cleaning and froth-flotation practices. In view of the growing importance of froth flotation as a process for cleaning fine sizes of coal, it was felt that such data and information would be of value in this country, for, although froth flotation has been adopted for use in a few of our plants, it has not as yet been employed as extensively as in British and European preparation plants. Many of the important coal beds in western Europe, especially in the Ruhr Valley of Germany and in the Dutch coal-mining region of Limburg, Netherlands, are very friable, with the result that the run-of-mine product contains a large proportion of the sizes too fine to be treated successfully by any other method than froth flotation. Furthermore, the relatively high cost of producing coal from these beds has for many years made it economically feasible and desirable to treat the fines by froth flotation, especially in the coking-coal fields.

Jan 1, 1951

By Forrest T. Moyer

To keep the mineral and allied industries informed of trends in the causes of accidents, and to point out the need for corrective measures, the Bureau of Mines collects, analyzes, and periodically publishes health and safety statistics. This report includes data for 1963 on injury experience, with related employment statistics, at coal mines in the United States. These data are presented in tabular form under the following headings: General Injury Experience Tables 1 to 6: Current data on number of injuries, degree of injury, frequency and severity rates, average severity, and related employment and production data by work location.

Jan 1, 1966

By Forrest T. Moyer

To keep the mineral and allied industries informed of trends in the causes of accidents, and to point out the need for corrective measures, the Bureau of Mines collects, analyzes, and periodically publishes health and safety statistics. This report includes data for 1963 on injury experience, with related employment statistics, at coal mines in the United States. These data are presented in tabular form under the following headings: General Injury Experience Tables 1 to 6: Current data on number of injuries, degree of injury, frequency and severity rates, average severity, and related employment and production data by work location.

Jan 1, 1966

By Rustu S. Kalyoncu

A major goal of the Bureau of Mines is to conserve the Nation's mineral resources by developing improved performance materials. In support of this mission, a survey of the state of the art of chemically bonded refractories has been made, covering the scientific literature, government reports, and patents. This review includes research and development results for phosphate, silicate, oxychloride, oxysulfate, and other bonding agents used in refractories manufacture. A significant finding of the review was that references on bonding mechanisms, bond formation kinetics, and other important process parameters and conditions were few and universally vague. As a result, recommendations are made to expand research efforts to investigate the kinetics and mechanisms of reactions in chemically bonded refractories.

Jan 1, 1982

By Gregory J. Chekan

The U.S. Bureau of Mines is investigating longwall panel and gate road layouts to increase coal recovery and reduce multiple-seam interactive problems. This report presents design practices for longwall mining multiple seams to provide mine planners and operators with practical guidelines for designing productive longwall mines. Key aspects of mine design that control longwall interactions are examined, including sequencing of seams, design of gate road pillars, and orientation of gate roads and longwall panels. Theories that describe stress transfer between multiple scams and the mechanics of interaction are addressed in relation to geology. Common longwall designs were further investigated using a boundary element model, MULSIM/NL. The model provided insight into relative stress transfer and distribution that occurs between longwall operations in multiple seams. Findings from the model show that (1) a longwall panel should be mined from the gob to the solid coal of an overlying mine, because the stress concentrations are lower; the approach angle should be kept under 30°; and (2) when mining in descending order, superpositioning gate roads usually produces the worst stress condition. To prevent this, the overlying isolated gate roads should be positioned from the centerline toward the headgate side of the underlying panel.

Jan 1, 1993

By James C. Duchon

The use of extended workdays (regular shift lengths of 10 or 12 h (hour), while still maintaining a 4O-h workweek) in mining operations is attracting growing interest in the United States. There is very little doubt that extended workdays is a very popular alternative among the work force because of the significant increase in days off, including weekends, especially when compared with traditional rotation schedules of working seven straight shifts or having only one weekend off every 4 to 6 weeks. However, there are some serious concerns by management, workers, unions, and various governmental policymakers that working 10-or 12-h days may create an added risk of accidents and health problems. The U.S. Bureau of Mines reviewed the literature studies related to the safety and performance issues of extended workdays. This report presents a summary of those findings. The studies examined in this review are divided into three sections: (1) laboratory, (2) field, and (3) accident and injury analysis. In general, results are inconclusive. Studies have shown both positive and negative effects. It is concluded, therefore, that in industries such as mining where accidents are a serious concern, special measures and evaluation in the use of extended workdays be considered.

Jan 1, 1994

By Merwin H. Howes

In constructing the NORAD Combat Operations Center, controlled blasting techniques were employed to achieve smooth walls and to avoid shattering the rock beyond excavation lines. Extraordinary measures were taken to stabilize the rock to permanently preserve the openings. Rock stabilization was accomplished by means of reinforced concrete and gunite linings, rock boltings, installation of chain-link fabric, and epoxy resin and cement grouting. A particular zone of weakness at a vital location was supported by exceptionally thick reinforced concrete lining, rock bolts, and cement grout.

Jan 1, 1966

By F. J. Perzak

The Bureau of Mines conducted a study to develop a standard fire test for 5-gal containers used for storing combustible fluids in underground coal mines. A standard test method was developed which evaluates the performance of the container in a 4-min tray fire. Bureau investigators used the standard test method to evaluate several types of closed 5-gal plastic and metal cans in outdoor tests. Each can tested contained 1 gal of nonfire-resistant (NFR) hydraulic oil. A container failed the test if it lost its contents in any of seven trials. Contents spilled either as a result of thermal rupture or melting. Fewer than 10 pct of the metal containers failed this criterion, but all the plastic containers failed. The metal container failures were usual-ly due to tipping over during pressure relief, which spilled the NFR oil. Replacing the NFR oil in the container with kerosene resulted in failure of more than 30 pct of the metal containers. The standard tests and preliminary tests showed that plastic containers are not equivalent to metal containers in their ability to contain combustibles such as lubricants and greases in a fire. For solvents and lubricants more volatile than NFR hydraulic oil, approved metal safety containers are recommended.

Jan 1, 1985

By Gary L. Hundley

The Bureau of Mines has devised and demonstrated a process for recovering Ni and Co from low-grade domestic laterites. The process consists of four major steps: (1) reduction roast, (2) ammoniacal leach, (3) solvent extraction, and (4) electrowinning. Several solid-liquid separation steps are required that affect the economics of the overall pro-cess. In this study, two techniques for solid-liquid separation, centrifugation and thickening, were investigated. This report presents the results of (1) laboratory and pilot plant studies to determine parameters for sizing centrifuges and thickeners and (2) an economic study of the two techniques, based on the requirements of a commercial-size (5,OOO-tpd) laterite processing plant. Sizing and other equipment-related recommendations, based on data from the Bureau's studies, were obtained from commercial manufacturers. The costs of thickening and centrifugation, including all the unit operations affected, were determined by the Bureau's process evaluation group. The total operating costs ~or separation using the two techniques (including depreciation on the capital cost of equipment) were found to be quite close: $17.26 per ton of laterite for centrifugation and $18.15 per ton of laterite for thickening. For centrifugal separation, the greatest cost was found to be the initial capital cost for the separation equipment; using thickeners, the greatest cost was for re-agent recovery.

Jan 1, 1984

By Michael E. Henderson

The U.S. Bureau of Mines (BOM) constructed the Hydraulic Transport Research Facility (HTRF) to investigate the hydraulic parameters relating to the transport of coarse coal. To achieve these goals in a timely and efficient manner, the Bureau contracted to Boeing Services International, Inc. (BSI) the responsibility of operating the HTRF and providing technical support. This data report is a summary of the testing and data results for the period from 6 September to 9 September 1983. The testing covered herein is for coarse 2-in by 0 (minus 50 mm) Pittsburgh Seam run-of-mine (ROM) coal in a 12-in (300 mm) pipeline, at velocities ranging from 8 to 16 ft/s (2.4 to 4.9 m/s) and at concentrations ranging from 15 to 50 pct.

Jan 1, 1985

By Edward W. Parsons

To determine in what part and to what extent creep or movement exists in an installed rock-bolt anchor and the effect of the creep or bleedoff on the tension load on a rock bolt, as well as the effect of normal mining activity on the rock-bolt load and anchor, the Bureau of Mines conducted tests in the laboratory and in two mines using four types of expansion-shell anchors, the wedge bolt, and in one mine, explosive-anchored rock bolts. Specially mounted heavy-duty springs, calibrated to obtain load readings from spring movement, were installed on the test bolts to prevent a drastic reduction in tension load caused by slipping or seating of the anchor. A dial gage, reading to 0.0001 inch, measured movement of the anchor shell against the rock and seating of the anchor wedge plug in the shell. While all bolts had electrical resistance strain gages for load reading, only readings from the laboratory tests were used because those from the field tests were erratic. The tests revealed that most load loss resulting from static loading is due to the slippage and seating of the serrations on the anchor shell into the drill-hole wall. Dynamic loading, primarily from sudden shocks from nearby blasting, and possibly from ground movement or mining activity, will cause the anchor wedge plug to seat in the anchor shell.

Jan 1, 1969

By Timothy A. Clancy

In support of research on forming ceramics from mining and processing wastes, the Bureau of Mines tested various commercial refractories to evaluate their resistance to melts of these wastes. Sixteen refractories of various types were exposed in slag erosion tests to two siliceous waste melts with Si02/CaO ratios of 4.0 and 2.2, The extent and nature of slag attack were then determined for each refractory. The nature of slag attack was investigated through scanning electron micrographs and microprobe elemental distributions. The refractories that performed best in resisting attack by the melts were high-alumina types, and of the refractories tested, the most resistant was a 90-pct-Al203, 10-pct-Cr203 refractory.

Jan 1, 1983

By R. A. Cattell

With the surrender of the Japanese Imperial Government as a climax to the capitulation of the German High Command , the main objective of the Petroleum and Natural Gas Division pivoted from war assignments to its main normal functions . One of these functions is to give wide public distribution to valuable technical facts which the Division has obtained through research on petroleum , natural gas , helium , and related subjects . During the war years many engineering data and scientific facts could be released only on a restricted basis as reports to war agencies and others immediately concerned . Moreover , many of the wartime reports contained masses of detailed data that were prepared under stress to meet emergency schedules . For peacetime publication and application , these data must be reviewed , correlated , and rearranged so as to present the essentials in proper form . To illustrate , a wartime report of 50 pages might be resolved into one curve in a composite graph for a peacetime publication . Another factor affecting the orientation of the work of the Division is the broader horizon of research revealed by its war activities . Fundamental research and careful engineering analyses are just as important in time of peace as in time of war; in fact , they should be more important to the forward view , because under peace conditions disrupting influences that distract from the orderly acquisition of knowledge are minimized . Therefore , the concerted effort has been not to " salvage " the results of the war activities , but to evaluate them on the basis of their relative importance in the future economy of the country . Where wartime investigations have pointed to peacetime accomplishments , the effort has been to give the corresponding type of work additional emphasis . This adjustment can not be made hurriedly , but many of the necessary preliminary steps on the new course have been taken ..

Jun 1, 1949