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By M. J. Ferrante

Laboratory-scale tests were undertaken to examine several electrolytes for possible use in separating nickel and cobalt from products being prepared at Nicaro, Cuba. The most extensive work was done with nickel sulfate-ammonium fluoride, ammonium fluoride, ammonium sulfate, and nickel sulfate-boric acid electrolytes. All four electrolytes exhibited some selectivity for dissolving nickel carbonate from Nicaro basic carbonate used for regeneration. The nickel sulfate-ammonium fluoride electrolyte exhibited less selectivity for dissolving nickel carbonate from Nicaro basic carbonate than it did from synthetic mixtures. Ammonium fluoride leaching experiments showed that a low concentration and high temperature gave a good nickel extraction with C. P. reagents; however, this was not confirmed in tests using Nicaro basic carbonate. Electrolytic tests employing ammonium fluoride leach liquors gave no further separation, since approximately 90 percent of the cobalt was deposited at the cathode with the nickel.

Jan 1, 1958

By Roger J. Morrell

Bureau of Mines laboratory experiments with reduced scale cutter and cutter forces were performed to (1) define the fundamental relationships governing disk cutter performance and (2) to develop a method of predicting disk cutter performance in soft, medium, and hard rocks. The rock cutting experiments were performed in four igneous and metamorphic rocks that ranged in compressive strength from 38,000 to 67,000 psi. A special testing machine called a linear cutter apparatus (LCA) was used to load and traverse a free rolling disk cutter across a smooth rock surface. Each pass of the disk produced a single crater, and runs were spaced to avoid breakage between craters. During each run the normal and tangential cutter forces were measured and recorded. The soft and medium rock data were obtained from previous Bureau experiments with disk cutters. Crater depth, tangential cutter force, crater volume, specific energy versus normal cutter force, and crater width versus depth are defined within this study. With the use of standard physical properties, performance prediction equations were developed using stepwise linear regression analysis techniques. A method of using these prediction equations to calculate the boring rate, the cutter spacing, and the torque and energy requirements of a full-scale boring machine was also developed.

Jan 1, 1974

By Lloyd A. Morley

The problems associated with the presence of organic materials and of water in explosion-proof enclosures used in high voltage, high capacity applications were examined through a literature search and theoretical reasoning. Information on volatilities is presented. The conclusion is reached that explosive pressures are significantly enhanced by inclusion of these materials.

Jan 1, 1976

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Jan 1, 1975

By R. T. DeWoody, J. W. Chester, W. C. Miller

The work was done to develop a relatively efficient muffler for quieting the exhaust of a rock drill . The exhaust of a pneumatic rock drill is the source of the major part of the noise generated by the drill . The exhaust noise can be reduced in a number of different ways , but this study involved only reactive mufflers . The reactive muffler can be simulated by an electrical circuit . Information obtained from analogous electrical circuits was used to design an efficient exhaust muffler for pneumatic rock drills . Electrical analogies proved to be a valuable tool in the design of mufflers .

Jan 1, 1964

By T. Bertke

This document assesses the environmental aspects of a preliminary design for processing kaolin clay as the domestic resource for recovery of alumina by a hydrochloric acid leach-HCl gas induced crystallization process. The report covers waste sources, control measures, and potential environmental and health effects applicable to the process technology.

Jan 1, 1980

By E. A. Mihok

A pilot plant for treating mine drainage by neutralization with limestone was designed, fabricated, and operated by the Bureau of Mines. The process consists of (1) producing a very fine (minus 400-mesh) limestone slurry, (2) mixing the slurry with the mine water, (3) aerating the resulting mixture to remove carbon dioxide and precipitate iron, and (4) separating the solids from the liquid by sedimentation. A mine discharge of pH 2.8, containing 1,700 ppm total acidity, 36 ppm ferrous iron, and 360 ppm total iron, was treated at rates from 300 to 400 gpm. The treated water ultimately reached a pH of 7.4 and contained no detectable iron. The resulting sludge compacted to approximately one-third the volume of sludge from mine water neutralized with lime. The advantages of the limestone process, compared with the conventional lime process are as follows: Widespread distribution and lower cost of run-of-mine, indigenous limestone; simplicity of plant design; reduced hazards and plant operating and maintenance costs accruing from the use of a less reactive chemical agent; higher solids concentration of the precipitated sludge; and no deleterious effect caused by accidental overtreatment. While total process costs could not be determined, it is conservatively estimated that the cost of treating mine water by the limestone process is one-third to one-half the cost of the lime process, depending on the characteristics of the water to be treated and the availability and quality of limestone used.

Jan 1, 1968

By Henry C. Meeves

The Bureau of Mines, between 1956 and 1963, examined 18 major pegmatite districts in Arizona, Colorado, New Mexico, South Dakota, Utah, and Wyoming to evaluate their content of beryllium, a material in short domestic supply that has become increasingly important to modern industry. This examination report includes the salient statistics on the production of pegmatite minerals other than quartz and feldspar; and brief descriptions of 170 specific pegmatite deposits.

Jan 1, 1966

By John W. Mentz

Phase I study efforts addressed: 1) acid mine drainage formation theory; 2) effects of inundation in reducing acid mine drainage formation; 3) summary information on the types of acid abatement technology currently available and the problems inherent in each; 4) analysis of two potential means of partially inundating abandoned segments of active underground mines to reduce acid formation. This subsequent Phase II Draft Final Report addresses all of the above, but concentrates on and defines Item 4. Seal construction techniques were taken through five logical steps as follows: A) Location Analysis; B) Coal Barrier Pillar Analysis: C) Ground Water Analysis; D) Design Considerations: E) Economic Analysis. The design details of both low wall dams and section seals were discussed in a series of segments: a) Case Histories; b) Feasibility Analysis; and c) Design (including representative calculations). Study efforts showed that both concepts are feasible only in certain mines where the geologic-hydrologic physical makeup is suitable to contain a mine pool. Low wall dams in particular were found to have extremely limited applicability as a means of pollution reduction. Section seals, while clearly dependent upon site specific conditions, have a some what broader range of utility and are more effective in pollution reduction. The proven dramatic reduction in acid mine drainage attributable to inundation makes this a concept that must be considered.

Jan 1, 1981

By J. L. Kohler

This final report on Bureau of Mines Contract J0348005 presents the results of an investigation into the development of a Management Information System (MIS) for underground coal mines. The motivation for the research is the unrealized potential for increasing safety and productivity of the well developed mine monitoring system technology. The intent of this project was to examine the information issues, various design aspects of an integrated monitoring/MIS, and associated application concerns, such as the impact of this technology on safety. The work performed on this contract used mine ventilation as a prototypical example. The report is presented in five chapters and six appendices. In addition to the introduction and conclusions chapters, one chapter deals with ventilation MIS system requirements; another with the formulation of a knowledge-based expert system (KBES) structure to implement the integrated ventilation monitoring/MIS system, and one on the health and safety implications of the system. The appendices present details of the KBES system application with an example using a mine ventilation simulator (PSU/MVS). An important conclusion is that a KBES formulation of an integrated monitoring/ MIS for coal mine management is feasible and desirable.

Jan 1, 1986

By F. D. DeVaney

Metallurgists and coal-washing engineers have used heavy liquids for years in studying the characteristics of ores and coal. By such means true separations can be made between the various specific-gravity increments in the materials examined. To use of heavy liquids has permitted determination of the possible grades of tailings and concentrates by specific-gravity methods on any particular size, and therefore the size to which the ore must be crushed to free the valuable material. The simplicity of float-and-sink separation and the high degree of efficiency attained in the laboratory are factors that commend the method for commercial concentrations.

Jan 1, 1940

By Dale R. Ralston

This investigation was divided into two major phases. Phase I of the study was an examination of the occurrence and production of acid water within the Bunker Hill Mine in northern Idaho. The second phase of the project involved the study of water movement through an abandoned tailings pile. Mineralogy and hydrogeology were determined to be the two most important factors in the acid mine drainage problem. Low pH water was formed in the mine in areas of lead-zinc ore rich in pyrite. Water movement in the mine was important in the production of acid and the transportation of heavy metals. Areas of recharge to the mine were identified. A data collection network was installed to monitor water quality and quantity changes. The quantity of acid drainage from the mine was found to vary directly with surface runoff events. The study of the abandoned tailings pile was performed to determine the characteristics of water movement through the tailings material and the resultant impact on the hydrologic environment. The Page Tailings Pile, abandoned in 1969, was utilized as a study area. An extensive network of piezometers and meteorological data collection sites were installed in and near the pile. Data collected to date indicate the presence of a ground-water mound under the east half of the pile. Some transfer of ions from the tailings pile to the ground-water system has been detected.

Jan 1, 1973

By Kyle W. Charlton

The Bureau of Mines utilizes special testing methods for the analysis of underground mine atmospheres for use during or after mine disasters and fires. These methods depend upon drawing sample gas to the surface through multiple tube bundles with the subsequent analysis of grab samples or the automatic analysis by often remotely located instruments on a continuous, 24-hour basis. During cold weather, low ambient temperature causes condensation and freezing of condensable vapors in the sample which can result in delayed response times or complete blockage of the sample line. This report covers research and resulting development conducted by the Bureau of Mines to produce a reliable method to selectively remove condensable vapors and particulate in the sample gas stream under worst-case field conditions. The effort resulted in two prototype systems which have greater field utility than originally anticipated. The innovative project resulted in two patent applications submitted through the Bureau of Mines.

Jan 1, 1981

By Rudolf E. Greuer

This report contains the practical application of a computer program for the simulation of ventilation systems under the influence of mine fires and other emergencies on five hardrock mines. The introduction describes the need for such a program, its basic features, and the range of its applicability which is mainly a function of the available ventilation data. The second chapter discusses program modifications, whose necessity or desirability was, during the application, discovered. The following five chapters, which comprise the major portion of the report, give the detailed description of the program application on the five mines. For every one of the selected mines, the ventilation system, the source of the used ventilation data and their preparation for computer simulations are outlined. Based on data for the airflow distribution solely, fumes concentrations in the mines are calculated for several assumed fire locations. Based on data for airflow and pressure distributions, ventilation disturbances caused by fires as well as the resulting fumes concentrations and temperatures are determined. The consequences for escape routes and the possible means to keep them free of fumes are discussed. To investigate the capabilities of the program, other contaminant sources and other potentially dangerous ventilation factors, like fan failures and changed surface temperatures, are simulated also. The results of the calculations have been entered into ventilation plans which makes them easier to scrutinize. All significant computer printouts have been attached.

Jan 1, 1981

By H. F. Yancey

About 65 percent of the more than 400 million tons of coal produced annually in the United States is mechanically cleaned to remove the inorganic impurities before being sent to market. The impurities, principally shale and clay with some pyrite, average about 20 percent of the raw coal treated. Nearly 95 percent of the tonnage is treated by wet processes, in which water, suspensions of solids in water, or occasionally calcium chloride solutions are employed. Difference in density of coal and impurity is the basis of these processes. Of major importance in the separation is the competency of the impurities, that is, the resistance of the impurities to size disintegration in water. In general, the impurities are more resistant in geologically older coals or those in effect made older by metamorphism. If the impurities suffer reduction in particle size when immersed in water, the separation of organic from inorganic material becomes more difficult, Recently the Scientific Department of the National Goal Board (Great Britain) undertook fundamental research into the interaction of shale and water and also developed an empirical method of assessing shale breakdown or disintegration. 6

Jan 1, 1962

By H. S. Price

This report discusses the development of a mathematical model that describes the flow of methane only and methane and water in a coal bed during mining operations. Because of the complex geometry, boundary conditions and fluid properties, the model is based on a numerical solution to the equations describing flow. The goals for the development of this model and requirements to which it complies are for the most part expressly stated in Request for Proposal No. 50110752. In addition to the capabilities specified under the scope of work the model can handle an anisotropic porous medium and a source term has been added which will simulate, somewhat, the effects of desorption. This term will be pressure dependent. The effect of time on such a term is only taken care of in the change of pressure with time. This source term will have the dimensions of Mcf/day/Mcf pore volume. It will be a part of the input data to be supplied by the user and will be entered as a table of rates versus pressure. These models consider the fracture system as the main porosity. All computed results pertain to the fractures. The source term mentioned above represents the flow from the matrix porosity into the fracture. Such flow should be small compared with the flow between fractures since these models handle only one porosity structure system.

Jan 1, 2012

By Forrest T. Moyer

INJURY experience and related employment information are presented in the chapter for the coal-mining, coking, oil and gas, peat, and native asphalt industries in the United States for 1964. No attempt has been made to combine these data and present injury-frequency rates reflecting the mineral-fuel industries because the hazards of the separate industries are not comparable. All rates in the text are calculated separately on data before rounding, hence component rates may not add to the total rates shown in the tables. Tabulations showing the trend of injuries and employment for all mineral industries are presented in Volume III. COAL Injury experience of the coal mining industry was improved in 1964, as measured by the declines of 1 and 14 percent, respectively, in the frequency and severity rates. Although the total number of injuries increased in 1964, a slightly greater proportional increase in man-hours worked caused the frequency rate to drop to 44.65 per million man-hours. The injury-severity rate in 1964 was 7,832 days lost per million man-hours of exposure. Employment and injury data for 1964 are based on final data for anthracite mines and preliminary data for bituminous coal and lignite mines. Fatality experience improved significantly with a record low number of 240 deaths in 1964. This total was 44 less than in 1963. The Nation's coal mines during 1964 were free of major disasters (a single accident resulting in the death of five men or more) for the first time since 1956. The

Jan 1, 1965

By Fred P. Giese

Southeastern reserves of titanium ores are large, widespread, and ample for anticipated demand. The leading titanium industries are mining and beneficiating sand deposits, principally in Florida, and manufacturing titanium pigments. Most of the mineral output is consumed by the producers themselves. In 1962, 20 percent of the national pigment capacity was in the Southeast.

Jan 1, 1964

By L. J. E. Hofer

THIS BULLETIN analyzes and summarizes research at the Bureau of Mines dealing with the preparation, properties, and reactions of iron carbides in the period 1948-60, part of which was sponsored by Wright Air Development Laboratories. The objective was to develop better catalysts for the synthesis of methane and higher hydrocarbons from hydrogen and carbon monoxide. The investigations resulted in the first adequate characterization of epsilon iron carbide, which later proved to be an important intermediate in the tempering of martensite in steel. At temperatures near 170° C, the carbon in carbon monoxide reacts nearly quantitatively with finely divided alpha iron to form an iron carbide in which the metal atoms occupy the positions of the close packed hexagonal arrangement with lattice parameters of ao=2.754 A and co=4.349 A. The carbide has a composition within 2 atomic percent of that required for the formula Fe2C, a Curie point of about 370° C, a specific magnetization of 160.4 ergs per gauss-gram Fe at 50° C, and a ferromagnetic moment of 1.70 Bohr magnetons. Epsilon iron carbide can be converted to chi iron carbide by thermal treatment at 343° C for about 70 hours. The chi iron carbide so formed has a Curie point of 247° C, a specific magnetization of 142.5 ergs per gauss-gram Fe at 50° C, a ferromagnetic moment of 1.72 Bohr magnetons per iron atom, and a paramagnetic moment of 5.5 Bohr rnagnetons per iron atom. Direct synthesis of this carbide from carbon monoxide at 240° C indicates a composition within 7 atomic percent of that required for Fe2C. Chi iron carbide can be converted to cementite at 550° C in about 315 minutes. The theta iron carbide so prepared has a Curie point of 210° C, a specific magnetization of 147.3 ergs per gauss gram Fe at 50° C, a ferromagnetic moment of 1.72 Bohr magnetons per iron atom, and a paramagnetic moment of 3.9 Bohr magnetons per iron atom. Pure chi iron carbide reacts to form theta iron carbide by the elimination of free carbon. In the presence of an excess of free iron in intimate contact with the carbide, chi iron carbide reacts with the free iron to form theta iron carbide. The second reaction proceeds at an appreciable rate at 320° C and can be used to snythesize finely divided theta iron carbide with no free-carbon impurity at low temperatures. The ease of the reaction in the presence of free iron suggests that chi iron carbide is an intermediate in the tempering of epsilon iron carbide to theta iron carbide as it proceeds in steels. Experiments on carbon steel show that the magnetic moment of the iron atoms in martensite is about 2.2 Bohr magnetons per atom, a value approximately the same as that of the iron atoms in alpha iron. The Curie points of epsilon iron carbide, chi iron carbide, and theta iron carbide were found -in various specimens of tempered steel to be 10° to 20° C lower than normal values. This shift is probably the result of manganese in solid solution. Preparations of various compositions of epsilon iron carbonitrides show many effects of extensive isomorphism between epsilon iron carbide and epsilon iron nitride. The action of carbon monoxide on finely divided alpha iron at 400° C results in free carbon deposits containing filaments about 0.1 micron in diameter and several times as long. The filaments are characterized by nuclei of dense material located midway from each end of the filament. Although carbiding to near completion at 240° C over periods of about 300 hours produces a preparation containing no appreciable percentage of epsilon iron carbide, very brief periods of carbiding of the order of a minute result in the formation of detectable epsilon iron carbide even at temperatures as high as 325° C. The data indicate that epsilon iron carbide is an intermediate in the formation of chi iron carbide during its formation from carbon monoxide in the gas phase. Attempts to convert cementite to chi iron carbide by cold work increased the Curie point but did not change the X-ray powder diffraction pattern.

Jan 1, 1966

By A. J. Farstad

Recent advances in microcomputer technology have opened the way for systems which can track the location of underground mining personnel from the surface. A computerized system has been designed which is capable of not only tracking the location of the miner but also of monitoring underground parameters, communicating between work stations and sounding alarms when underground conditions are judged to be unsafe. For the system described herein, the locations of the underground personnel are detected by a network of underground terminals which routinely emit RF pulses to interrogate miniature transponders worn by the miners. Each transponder is uniquely programmed to delay its response in such a way that the RF terminal can identify the individual transponders by the time slots in which the responding pulses are received. The underground terminals are then interrogated by the host computer on the surface which keeps a running account on underground mine conditions and personnel. The underground portion of the system is designed to operate even during mine emergencies, deriving its power from rechargeable battery supplies which are float charged during normal operation. Nine mines were visited on this program and the industry reaction to the system was generally favorable. By slanting the system design for daily use in the mine, the chance of its acceptance by the industry is enhanced. Furthermore its likelihood of being operational in the event of an emergency is significantly increased.

Jan 1, 1981