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By Milind Sabne, Pradip, P Kapur, Beena Rai

"The efficiency of an industrial flotation circuit depends on (a) the selectivity and the kinetics of the reagent combination selected for the separation (b) the hydrodynamic conditions prevailing in the flotation cell (essentially equipment design parameters) affecting both the pulp and froth phase (c) the operating parameters such as feed rate, pulp density, pH, temperature etc. including the mineralogy, particle size distribution and relative proportion of liberated and composite particles of constituent minerals in the feed to flotation circuit and (d) the circuit configuration itself. We have developed a molecular modelling based reagent design and selection framework to assist mineral engineers to arrive at the preferred reagent combination based on a rigorous, scientific and quantitative comparison of various options available for this purpose. Similarly we have also utilized a general circuit design methodology proposed by Kapur and Mehrotra in 1974. The advances thus made in modelling both the reagent chemistry as well as circuit design, along with the availability of sophisticated, automated tools for characterization of ores (liberation as well as mineralogical composition of the different flotation streams) provides a scientifically rigorous, quantitative, robust framework for design and optimization of complex flotation circuits. We illustrate in this paper the power and the utility of our rigorous optimization based approach to designing industrial flotation circuits for the beneficiation of a multi-component feed with the help of few case studies from our own work. With the proposed methodology, higher levels of process efficiencies can be achieved in the industrial flotation plants, in particular those processing complex, multi-component feeds requiring multiple stages of flotation separation. We are currently developing an IT platform consisting of computer-aided decision support tools for arriving at the preferred flotation circuit and the appropriate reagent chemistry for a given ore deposit and/or a given plant."

Jan 1, 2014

By Bronwynne K. Williams

"In deriving flotation kinetic models, the froth phase was, until recently, either ignored or treated entirely empirically. The behaviour of the froth is now known to be usually important and sometimes dominant in determining flotation performance. Hence numerous methods have been developed for sampling the flotation froths and models incorporating the effects of the froth behaviour have been derived.Such models will assist in determining more accurate estimations of the kinetic parameters utilised in the designing of industrial scale plants thus reducing the incurred costs of over designing. In particular, improved models for batch tests may lead to more effective use of batch testwork for prediction of continuous plant behaviour. A more detailed model is thus proposed which allows for a more realistic approach to the flow distribution in the froth phase.PROPOSED MODELThe batch flotation process is split into two stages in time, namely before the froth begins to overflow and after. The assumptions made, and hence the calculations, are different for each stage.The air enters the slurry at t=0 and generates froth. The superficial velocity of the air through the cell is given by go. It is assumed that the rate of froth breakage (gb) is constant during the first stage. The froth rises with a uniform net velocity throughout the cell and no mixing is assumed to occur.After the froth begins to overflow, the velocity distribution of the gas is modeled by segmenting the froth phase as shown in Figure 1. A model for bubble breakage rate or measurements of froth velocity allows one to obtain the volumetric rate of concentrate froth production. The entrained water and associated particles and a drop-back mechanism are also allowed for in the model."

Jan 1, 2003

By R. Shiva Kumar, G. Sreedhar, S. Sharma

Some of the Indian origin iron ore deposits located in Bellary, Karnataka province are having peculiar characteristics of Iron ore deposits (Hematite) having Iron above 64% and 30-40% lump (-30+6mm) recovery which are not suitable to use in blast furnace due to not meeting the specification of Tumbler Index and Abrasion Index. In general for high grade Iron ores, process flow sheet involves crushing and screening (dry/wet). In the contest of high grade Iron ores located at Bellary sector of Karnataka state in India, lump generated from this process could not attain the required physical properties (Tumbler Index, Abrasion Index) and metallurgical properties , even though the grade of the lump ore is above 64% Fe. Washing techniques like Drum scrubber and Log washer play major role in improving the metallurgical properties of Iron ore lumps by removing the light and hard layers of clay, silica coated over the lumps. In this study the effects were compared of drum scrubbing and log washing on iron ore lumps. It is found that by incorporating simple washing technique i.e. drum scrubbing or log washing, Tumbler Index of Iron ore Lumps could be increased from 74% to 78% which is acceptable for use in Blast furnace. From the Drum scrubber and Log washer tests, it is clear that Log washers have an edge over Drum scrubber in removing hard coated clay on surface of Lumps. This simple washing technique facilitate us to utilize the lumps directly in blast furnace and eliminate the unnecessary crushing and grinding of the ore so as to meet the specifications of Sinter fines and pellet feed.

Jan 1, 2014

By Sonia Helle, Ursula E. D. Kelm

"From a metallurgical point of view, acid leaching of oxide zone copper ore is considered in the first place in terms of ore grade, whole rock mineralogy, rock granulometry, crushed aggregate size distribution, porosity, permeability and corresponding fluid flow characteristics. Despite exhaustive physicochemical and general mineralogical characterization, drops in copper recovery occur and are often attributed to and “unquantified mineralogical misbehaviour” of the gangue phases. This study establishes an experimental link to monitor and quantify the chemical interaction of chrysocolla, malachite and atacamite with reactive gangue phases.Laboratory-scale sulphuric acid (15%) leaching in small columns is carried out using a synthetic rock composed of 57% quartz, 1% ore phase, and 42% reactive gangue. Gangue phases were selected to represent mineralogy found in argillic, advanced argillic, and propylitic alteration zones. Exotic copper ores of Codelco Norte (in particular Mina Sur) served as model for the modal distribution of mineral phases. Natural reactive gangue phases (<200 Tyler mesh) were chosen as pure as possible: Saz-1 and Swy-1 montmorillonites, KGa-1B and KGa-2 kaolinites (all Clay Mineral Society, USA, Source Clays) Nau-2 nontronite, Imt-1 illite (both Clay Mineral Society Special Clays) and Chilean mordenite, laumontite and bentonite. Ore phases are: mineraloid chrysocolla from Radomiro Tomic (Codelco Norte), reagent grade malachite and a purpose synthesized atacamite-paratacamite mixture. Complete chemical, physicochemical and mineralogical characterizations were carried out for ore and gangue phases.The following observations hold for samples with and without mineralization: Smectite-rich gangue increased up to 75% in volume. Once wet, air-filled vesicles formed due to the rapid sealing effect of overlying smectite in the column. No volume change occurred for illite, mordenite and kaolinite gangues. For kaolinite mixtures acid puddles formed on top of the column during initial leaching due to the delamination and barrier formation of this phyllosilicate. Fluid recovery was <60% for expandable phases and reached up to 80% for non-expandable mixtures. These observations confirm the very low extractions obtained in ore with a combined smectite – kaolinite gangue for Mina Sur. The most important mineralogical changes observed in the solid residues are: reduction of basal smectite phase reflections (XRD), and slight loss of illite intensities. This is also reflected in the major element composition of the residues, which demonstrate a loss of Mg, Mn, Ca, Na, K followed by Fe, Al and Si; with their proportions depending on the starting materials. Furthermore, alunogen and meta-alunogen formed, with related phases coquimbite (illite) and godichite (nontronite) also depending on gangue mineral chemistry. For laumontite samples, meta-alunogen and alunogen precipitated from the leachate."

Jan 1, 2003

By V. G. Prikhodko, G. I. Sukhinin, I. V. Yarygin, A. V. Fedoseev, S. A. Novopashin

"The first experiments on the vacuum drying of spherical clay sample are presented and the theoretical model of the process is considered. The model is based on the solution of the heat and the moisture transfer equations with the effective thermal conductivity and water diffusion coefficients for wet porous clay-like medium. The time and radial dependence of the temperature and the moisture were calculated for different initial conditions. The results obtained for the time dependence of the moisture content are in good agreement with the experimental results obtained in the initial period, when all the moisture in the sample did not freeze to form an ice crust. INTRODUCTION Capillary-porous materials very often occur in nature and in industry. A porous medium is a solid matrix with voids, or pores, which are continuously connected. These pores are usually filled with fluids or moisture, water vapor and air that can pass through the medium because the voids are interconnected. The void fraction in the solid matrix is referred to as the porosity. Porosity or void fraction is a measure of the void (i.e. ""empty"") spaces in a material, and is a fraction of the volume of voids over the total volume. The moisture content in porous media determines the properties of the porous body, its mechanical and thermo-physical properties, such as density, plasticity, viscoelasticity, swelling, cracking, and so on. Complex processes of heat and mass transfer occur in porous bodies when they are heated or cooled, during drying or freezing (Luikov,1966). The course of these processes depends essentially on the physical-chemical composition of the solid matrix of the porous body, on its fractal dimension, porosity and morphology. The clay and clay minerals are the most important porous materials in the history of the mankind (Mukherjee, 2013). Clay is a very fine grained, unconsolidated rock matter, which is plastic when wet, but becomes hard and stony when heated. It has its origin in natural processes, mostly complex weathering, transported and deposited by sedimentation within geological periods. Clay is composed of silica {SiO2), Alumina (Al2O3) and water (H2O) plus appreciable concentrations of oxides of iron, alkali and alkaline earth, and contains groups of crystalline substances such as quartz, feldspar, and mica. Building materials, bricks, and tiles, pottery, porcelain and faience are made from clay. Clay is used in the food and medical industry, and, not least, in the mining industry as a carrier containing aluminum, silicon and other valuable elements, as well as metals (copper, gold) as constituents, contained in the pores in the form of micro- and nano-particles or grains."

Jan 1, 2018

By Hakan Gürsoy, Kemal Bilir, Bahri Öteyaka, Ali Uçar, Oktay Sahbaz

"Jet diffuser flotation column (JDFC) is a flotation device resembles Jameson flotation cell (JFC) in terms of operational principles, but it has significant difference structural points of view. This difference is an essential change in the downcomer to provide an increase of performance of the cell for the coarse particles. By using the hydrodynamic and fluid mechanics principles (Sahbaz et al., 2013) downcomer was changed as a diffuser, therefore turbulence at the end of the downcomer was reduced to provide better aggregate stability and homogeneous dissipation of the bubbles in the separation tank. According to experimental results carried out in pilot scale JDFC, not only higher flotation performance comparing with Jameson cell was obtained specifically for coarse talc particles in a certain condition, but also quiescent froth layer was acquired. In these tests, vertical pipe of JDFC having inlet diameter of 6 cm and outlet diameter of 11.5 cm was used with separation tank having the diameter of 39 cm. By using the data, pilot scale JDFC having 410 cm vertical pipe integrated with separation tank was produced and flotation tests were carried out by using the naturally hydrophobic mineral (talc). Finally, the talc recovery obtained as 94% by the use of JDFC, while Jameson cell has the recovery of 77% for the particle size of 250 µm."

Jan 1, 2014

By Leopoldo Gutierrez, Esau Arinaitwe, Marek Pawlik

"The effect of various polymers, including: anionic carboxymethyl cellulose (CMC), polystyrene sulfonate (PSS), humic acids (HA) and non-ionic hydroxypropyl cellulose, on the wettability of Athabasca bitumen was evaluated through dynamic contact angle measurements using the captive bubble technique. The tests were carried out as a function of pH at a constant ionic strength (0.01 mol/L sodium chloride). The evolution of the three-phase contact angle between the solution, bitumen and an air bubble was followed as a function of time over a period of ~6 minutes. The contact angle data were modelled using a first-order kinetic equation. The results were analyzed in terms of the initial contact angle, the evolution rate constant, and the steady-state contact angle value. In the case of anionic polymers, a pronounced decrease in the initial contact angle value was observed at pH 3. Under acidic conditions, there was no significant effect of CMC observed on the steady-state contact angle value but PSS and HA significantly decreased the steady-state contact angle value. At pH 8.5. the anionic polymers did not affect the wettability of the bitumen surface but they significantly decreased the contact angle evolution rate. These results suggested that CMC is not capable of permanently lowering the hydrophobicity of bitumen, and the polymer only slowed down the evolution of the contact angle to the steady-state value. The results also showed that polystyrene sulfonate and humic acids were capable of making bitumen hydrophilic but only under acidic conditions. Only hydroxypropyl cellulose (HPC) produced a large decrease in the steady-state contact angle under alkaline conditions (pH 8.5). The kinetics of contact angle evolution in the presence of HPC was also drastically lowered. The results were discussed in terms of the chemical composition of the polymers and their different affinities towards the bitumen surface."

Jan 1, 2014

By Lev O. Filippov, Inna V. Filippova

"Flotation of metal-organic precipitate in column is sensible to the hydrodynamic conditions determined by the diameter and dispersion of rising bubbles. Thus, the dissipation energy in the system resulting of ratio between superficial fluid velocities (gas and feed) in the column is main parameter for precipitate flotation in pilot or industrial scales. The knowledge of aggregate structure can lead to better understanding and control of many solid-liquid separation processes (sedimentation, filtration, thickening and flotation). Many authors highlight the importance of structural properties (i.e. floc density) for different industrial applications.This approach was applied to achieve the flotation of molybdenum precipitate obtained with organic collector a- benzoin oxime for molar ratio 1:2. Flotation tests were carried out at lab and pilot scale with rigorous control of the size distribution of bubbles and the values of dissipation energy in the systems.Structural evolution of Mo precipitate and the destruction phenomenon were described by using of the various fractal dimensions, which were deduced from experimental data of laser sizer devices and optic microscopy pictures of precipitate. The boundary fractal dimensions Df of large aggregates allows the detection of a structural scaled organisation of the precipitate flocs (elementary germs-microflocs-flocs). The fractal dimension of the particle mass distribution Dm=1.94+/-0.15 suggests, for the floc structure, a cluster-cluster aggregation process either with structuration or breakage phases.The destruction process characterised by a fractal dimension Dg controls the final size distribution. The floc destruction occurs for the lowest values of the dissipation energy (0.02 – 0.05 W/kg). The relation between Dg and the system dissipation energy Et (for various energy E dissipated in the agitation cell) involves the different breakage mechanisms of aggregates in function of the aggregation bonds (Fig. 1).Besides, the destruction of floc produces very fine particles (elementary germs or/and microfloc according to E), and thus induces the difficulties of bubble-particle attachment during the precipitate flotation in column. Yet, very small bubbles, which increase the collision probability, would make the flotation feed rate decrease. The optima ratio between superficial gas and feed velocities are determined for bubble size and flotation results control at pilot scale. Thus, it is possible to providing the catastrophically changes of precipitate column flotation by using the following established experimental relation: the mean diameter d of the flocs under the action of dissipated energy Et follows a power like law (d~Et -0.5). This allows estimating the size distribution of flocs for the E values which can appear in column."

Jan 1, 2003

By Heinrich Hutchison, Thomas von Moltke, Roelof F. Sandenbergh, Katarina P. Cerovic

Although the cyanidation process for gold leaching has been applied for more than a hundred years, some aspects of it, such as the passivation of the gold and the depassivating action of heavy metals, are still not well understood. In this work the anodic behaviour and surface composition of gold in alkaline aqueous cyanide with lead additions were investigated using polarization experiments and XPS. It was found that lead in the solution activated the gold at low concentrations, somewhat more positive than the reversible potential for gold, but that the activity again decreased at higher concentrations of lead. The potential range for the activation of the gold coincides with that where underpotential deposition of lead occurs, i.e. –200 to –600 mV(SCE), as indicated by the surface composition of the gold, shown in figure 1. Note that the concentration of lead on the surface of the gold only increased with time in the bulk plating potential range for lead, where gold is not activated by the presence of lead. It is also shown that up to 20 mg/L of lead added to the solution will activate the gold, provided that bulk plating of the lead is avoided. It is also important to avoid reducing conditions during leaching, where bulk plating of lead may occur, if the gold is to be activated by lead to achieve a high leaching rate, as the bulk plated lead screens the surface rather than activating it.

Jan 1, 2003

By Hideki Yamamoto, Norihiro Murayama, Junji Shibata

"Hydrothermal syntheses of zeolite from coal fly ash were carried out by using various alkali sources. NaOH, Na2CO3, KOH, K2CO3 and their mixture were applied for an alkali source of zeolite synthesis. The various physical properties of the reaction product, such as the kind of zeolite crystal, cation exchange property, surface texture and so on, was investigated through the zeolitization reaction from fly ash. The mechanism of zeolitization reaction was considered from these results.Zeolite P(NaP), hydroxysodalite(HS) and chabazite(K-CHA) are synthesized as zeolite species, when fly ash hydrothermally reacts in various alkali solutions at 393K. The crystal structure of the products obtained in NaOH solutions for 3h changes from NaP to HS with increasing NaOH concentration. K-CHA formation in KOH solutions needs 10h of reaction time, which is longer than that of NaP or HS.Dissolution, condensation and crystallization steps exist in the zeolitization reaction from fly ash, and the particle surface of products remarkably changes in each step. The fly ash is spherical particles and the surface is smooth(Fig.1(a)). The dissolution of fly ash occurs in the heating process until 393K, and the particle surface changes like unevenness(Fig.1(b)). In case of NaP, the condensation of aluminosilicate ions takes place at 373-393K, and the amorphous aluminosilicate is deposit on the unreacted fly ash(Fig.1(c)). The crystallization of NaP already begins to occur at 393K and the surface is covered with fine zeolite crystals for 24h(Fig.1(d))."

Jan 1, 2003

By James A. Finch, Linda Restrepo, Mitra Mirnezami, Amy Buchanan, Maryam Hashemi

Settling rate studies on slurries from Cu/Zn flotation plants occasionally reveals two aggregation maxima at pH 8-10 and 10-12 (Figure 1). From measurements on sphalerite and silica suspensions the double maxima could be replicated. These maxima correspond to the effects of Zn and Mg ions. The aggregation mechanism of both ions is related to the formation of the corresponding hydroxide precipitate. A combination of chemical and electrostatic bridging by the hydroxides is considered to be the aggregation mechanism.

Jan 1, 2003

By Xiong Dahe

"SLon vertical ring and pulsating high gradient magnetic separator utilizes the combined force field of magnetism, pulsating fluid and gravity to beneficiate weakly magnetic minerals with the advantages of large beneficial ratio, high recovery, matrix not easy to be blocked and excellent performance.We have developed SLon-750; SLon-1000; SLon-1250; SLon-1500; SLon-1750 and SLon-2000 VP HGMS. Now more than 200 of them have been successfully applied in China.Application in Qi Dashan Mineral processing Plant of Anshan Iron and Steel Company: The iron ore consists of magnetite and hematite. In 2001, six SLon-1750 magnetic separators are applied to control the tails grade of fine hematite. The results of flowsheet is: feed grade 30.15%Fe, concentrate grade 67.00%Fe, iron recovery 75.86%. The results set up the historic high record of this plant and the processing coast is greatly reduced.Application in Gushan Iron Mine of Ma Anshan Iron and steel Company: There are 6 SLon-1750 and 4 SLon-1500 magnetic separators applied in this mine to treat refractory hematite ore. The feeding grade is about 45%Fe. The final iron concentrate grade is about 60%Fe and the iron recovery is about 76%. The results are much better than the previous gravity flowsheet.Application in Meishan Iron Mine of Shanghai Baoshan Iron and Steel Company: The mined ore consists of magnetite, hematite and siderite. Because of a relatively high content of phosphorus, the iron concentrate could not meet the market requirements. Now 18 SLon-1500 magnetic separators are applied to reduce phosphorus, which is reduced from about 0.4%P to 0.246%P. The quality of iron concentrate is greatly upgraded.Application in Panzhihua Ilmenite Processing Plant: In the past, the -0.045mm ilmenite fraction was discarded in to the tails because of lack of high efficient equipment. In 2001, the plant built up a magneticflotation flowsheet to recover the fine ilmenite from the -0.045mm fraction with 6 SLon-1500 magnetic separators. The total results are: feed grade 11%TiO2, concentrate grade=47% TiO2, recovery 44%. Each year the flowsheet recovers 60,000t fine ilmenite concentrate."

Jan 1, 2003

By Janusz S. Laskowski

"Frothers offered by different manufacturers are marketed with some information on their chemical and physical properties (e.g. density, viscosity, color, water-solubility, safety/toxicity, etc.). But frothers are used in flotation to generate fine bubbles and to stabilize the forth, and this information is only provided in a very qualitative description of the visual appearance of bubbles and froths. The terms “powerful” and “selective”, which have been commonly used to characterize frothers, have intuitive rather than scientific meaning.This paper introduces the DFI (Dynamic Foamability Index) plotted vs. CCC (Critical Coalescence Concentration) diagrams to classify flotation frothers (Fig. 1). The frothers characterized by low CCC and high DFI values have properties of strong flotation frothers, while those with high CCC and low DFI values are more selective. The proposed frother classification system, based on simple CCC and DFI measurements, provides, for the first time, a solid ground-work for characterization of the flotation frothers."

Jan 1, 2003

By P. Saha, D. M. Chakrabarti, National Metallurgical Laboratory, P. Bhattacharyya, B. R. Sarkhel

The estimated reserve of the phosphatic soils at the Sukulu hills region of Uganda upto a depth of 60 meters is of the order of 200 million tonnes and analyses 10-12% P2O5. A 5-tonne sample of the phosphatic soil was received at the National Metallurgical Laboratory (NML), India for beneficiation studies. The ore occurred as a naturally degraded soil deposit and the slime contained earthy lateritic minerals which made it extremely sticky. Microscopic examination revealed the presence of limonite, magnetite (martitised), hematite and goethite as major minerals along with apatite and quartz. Presence of clay was indicated by earthy smell on moistening the sample. It was observed that getting rid of the slime was as important for adequate beneficiation of the ore, as it was difficult. Earlier studies on samples of the same ore at the NML and abroad established that it was necessary to pass the ore through a series of three stages of desliming, each consisting of a step of rigorous attrition scrubbing followed by hydrocycloning, for effective elimination of the sticky slimy coating which stubbornly adhered to mineral grains. Studies were carried out at the NML in two phases to develop a flowsheet for beneficiation of the phosphatic soil. In the first phase, reproducibility of the results obtained by employing a flowsheet developed abroad was confirmed along with suggesting some modifications of the flowsheet. Then 200 kg. of concentrate was produced following the recommended flowsheet for evaluation of its suitability for production of fertilisers. To remove the limonitic slimy coating, which stubbornly adheres to the other mineral grains, it was necessary to subject the ROM ore, after screening out the +840 micron size fraction which contained only 1.75% P2O5 , to three stages of hydrocycloning each preceded by attrition scrubbing. Then only conventional beneficiation techniques could be effectively employed to upgrade the ore.

Jan 1, 2003

By Ashok M. Raichur, S. P. Vijayalakshmi

"Recent advances in technology and the growing environmental concern have laid emphasis on the usage of fine clean coal. Coal fines are also generated in large amounts during various coal processing operations and are difficult to be treated, handled and disposed. Since most of the operations use water as the carrying medium, the fines so generated contain lot of moisture. Conventional technique for processing coal fines includes flocculation by a polymeric reagent followed by moisture removal using a rotary drum or a pressure plate filter, which produce a product with more than 30% moisture. Polymeric flocculants though required in small amounts, need high shear mixing for good performance and operate only in a narrow pH range. Moreover they increase the viscosity of the solution by many folds. Hence it becomes imperative to emulate newer methods for efficient fine coal processing. One such method is the novel use of microorganisms in coal processing.The present investigation deals with the utilization of two gram-positive microorganisms, Mycobacterium phlei and Bacillus subtilis, as bio flocculants and dewatering aids in fine coal processing. Preliminary characterization done on J-coal and M.phlei showed that they are negatively charged over most of the pH range. B.subtilis was found to possess positive charge below pH 4.7. The adhesion studies proved the high potential of microorganisms for adsorption to surfaces. Adhesion tests were conducted at various experimental conditions by varying parameters like pH and ionic strength of the suspension. Results obtained showed that adhesion is always higher in the presence of an electrolyte like KNO3 and most of the adhesion takes place in 15 minutes. With change in pH the amount of B.subtilis adhering on to J-coal remained almost constant and for M.phlei it decreased at higher pH values. Increase in ionic strength did not increase the adhesion of bacteria. Flocculation experiments confirmed the ability of the bacteria to act as bio flocculants. It was seen that about 98% of the coal settled in about 2 minutes on the addition of bacteria along with the addition of the electrolyte. The electrolyte was found to be indispensable for efficient flocculation of the coal suspension and for the attainment of a clear supernatant after flocculation. Also the optical micrographs revealed the formation of large, tight flocs when the electrolyte is present along with the bacteria. Further, flocculation tests were done in the pH range of 2-10 and the flocculation efficiency was found to be independent of pH."

Jan 1, 2003

By Nicolás Caussade

"The IMPC 2014 slogan "Optimizing Water and Energy Usage for Sustainable Mining" refers to the ever decreasing availability of fresh water and energy, which has turned out to be a crucial aspect in assuring the competitiveness of the mining sector in Chile and the Andes region in general. The concern for sustainability and the supply of water and energy is nowadays part of the top priorities of mining countries and communities. This is also the case for Antofagasta Minerals. Several years ago its mining group implemented an energy policy based on intelligent, strategic and sustainable management, in order to successfully face the challenges imposed by the market. It is called an intelligent policy because it intends to provide energy through a diversified range of sources, which includes the development of in-house alternatives. It is also a policy focused on efficient energy consumption and one that is strategic. Because it is in line with the characteristics of the mining activity, it is developed for the long term. Finally, what makes the policy sustainable is that it gives priority to energy usage from renewable resources and as such, the required capacities have been developed to generate innovative solutions that respond to the restrictions that characterize the industry today."

Jan 1, 2014

By Victor Avdokhin, Valery Morozov, Valery Stolyarov

"The adaptation-determination method provides for keeping given relationship between concentrations of ionic and molecular components of a pulp liquid and correction of parameter of the model on the basis of analysis of ore composition, technological parameters of flotation, and cost of valuable components.• optimisation program “ADDEFLOT” and combined analyzer of pulp “RA-931”An adaptation-determination method provides for two-level control of bulk and selective flotation of polymetallic ores. The lower level provides for control of reagent dosing on the base of control of ionic composition parameters in the pulp liquid phase. The control goal is to keep the basis relationship among parameters of ionic composition (ions A, B, C) in pulp liquid phase given by equations of type:• alg[A] + blg[B] + clg[C] = K (1)Values of a,b,c coefficients are uniquely determined by a physico-chemical model used. Kind of the model depends on mineral composition of an ore and reagent regime applied. As parameter of ionic composition, also values of one or two parameters (or their combinations) can be used, for instance, pH, concentration of sulfide ions, ions of collector.The upper level of control is based on calculation and use of technological results of selective flotation. At the level, an adaptation of the model (1) is conducted. A principle of the adaptation is in determining (and including in pre-setting function of the lower level) such value of K parameter, at which maximal economic effectiveness of the process is reached. As a criterion of economic effectiveness of the process, a function of losses of several valuable components, taking into account cost of the metals lost, is used. For 2-component ore, in simplified form, the function is as follows:"

Jan 1, 2003

By Sung. Hyejin, Kyoungkeun Yoo, Oh-hyeok Kown

The sediments near coasts and ports in Korea have been found to be contaminated with heavy metals and organic matters. So far the sediments have been dumped to landfill sites or ocean. However, the number of available landfill sites is decreasing and ocean disposal of wastes was strictly prohibited. Although physical separation processes have been found to be useful for the remediation of contaminated soil with heavy metals, because the sediments consist of fine particles, it is difficult to remove heavy metal component by physical separation processes. Furthermore, the sediments contain organic matter, so there is a concern about strong stink during the sediment treatment. The present study is aimed to develop the treatment process for removing heavy metals and organic matter from the contaminated sediments. The heavy metals and organic matter were oxidized and dissolved by electro-generated chlorine, and the chlorine used is regenerated and circulated in the leaching process. This system has economic and environmental advantages to reduce the wastewater and the oxidant consumption. The leaching results show that the metal removal efficiency increased to more than 99%, and more than 50% of organic matter was decomposed.

Jan 1, 2014

By K. H. Luo, J. Y. Liu

An experimental study on interparticle breakage of three iron ores was carried out by compressive stressing of particle-bed in a piston-die device. The feeds to the particle-bed stressing were five narrow size fractions in the size range of 0.2~3.2 mm respectively and a wide size fraction of 0/4.0 mm. The pressures applied were in the range between 30 and 360 MPa. The results show that the energy absorption of the particle bed increases linearly with the pressure; the increase of the product fineness with the pressure declines as the pressure goes up; and the product size distributions resulting from interparticle breakage of different narrow size fractions have no self-similarity. Using data obtained from the piston-die compressive stressing test, the suitability of a previously-developed material-characterization model for interparticle breakage was verified for these ores. It is shown that the particle-bed compression test conducted with piston-die device in lab-scale may provide a cost-effective way of studying and modelling size-reduction of ore materials by interparticle breakage.

Jan 1, 2014

By Vincent C. Smith, Agit Singh, Daniel de V. van der Spuy, Bernard Muller

"Process control in the minerals industry is made difficult by factors such as the multivariable nature of the processes, noise, many disturbances, the changing nature of the processes, nonlinearities, process constraints, slow responses and large deadtimes. A good example of such a process is a milling circuit, where all these problems are experienced. Since model predictive control (MPC) effectively handles most of these difficulties, Mintek decided to develop, customise and test an MPC controller for milling control.Conventional MPC uses a dynamic model of the plant to calculate the future (predicted) plant outputs based on the movements of the manipulated variables in the past. The future moves of the manipulated variables can then be calculated using an optimisation algorithm that will minimise the difference between the setpoints and the predicted outputs. The least squares optimisation method is the quickest, but it does not cater for process constraints. Constraints can, however, be handled explicitly by using a quadratic programming optimisation method. This method ensures that the variables stay within the constraints at all times, but the calculation procedure is much more computationally intensive.• modifying MPC for the Minerals Processing IndustryIt was found that in order to obtain good, robust control using MPC in the minerals processing industry, the conventional MPC algorithm had to be adapted. The MPC controller was first tested on an extensive milling simulator, which was specifically developed for that purpose. Problem areas were identified and the MPC controller was specially adapted to accommodate for these difficulties. Some of the adaptations to the conventional MPC algorithm and special features added were as follows:Since milling plants contain many integrating processes (e.g. sumps), and integrating errors can cause offsets and poor control, it was essential that integrators be handled explicitly. This problem was solved by adapting the algorithm and also using an integrating error portion to compensate for integrating errors.Constraints on the inputs and outputs adversely affected the control. The controller using simple least squares optimisation was tuned with the constraints in place, while the maximum expected setpoint changes were made. This ensured that the process would be able to handle most setpoint changes up to these expected values without violating the constraints. A later improvement on this method was the incorporation of a quadratic programming algorithm to perform the optimisation. This method handles limits explicitly and was shown to perform better than the least squares methods (at the expense of a much higher computational cost)"

Jan 1, 2003