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By C J. Moran

Given that the mining industry is committed to sustainable development principles and that Australia is experiencing changes to the regulatory environment that aim to modernise the water sector and encourage adoption of consistent approaches, there is a well defined need for the Australian minerals industry to develop a water accounting framework. This requires: key terms and definitions for water metrics for use in the Australian minerals industry that is consistent with the wider water sector, a suite of metrics representing key components of an operationÆs water balance, a calculation method for some of the metrics, and a reporting protocol. This paper presents the methodology that was used to derive these four components. Existing accounting frameworks were reviewed and key terms and definitions that were consistent with current requirements were proposed. A calculation methodology was developed to obtain some of the key indicators and variables that cannot be easily measured directly (water loss through evaporation is an example). The adopted terms and definitions dictated model development, with the conclusion that a systems approach was the most effective calculation process. To test the proposed definitions and calculation methodology, values for water metrics were derived for eight sites. The proposed framework and definitions could deal with the specific situations selected as case studies. The associated calculation methodology produced complete accounts at various levels. Some elements of the accounts could be directly checked against available data and simulations. The framework captured well variations in the reuse efficiencies; reuse efficiency could even vary for similar processes. It is concluded that this preliminary accounting framework provides a consistent language and metrics for quantifying and communicating water management, both at the intersection of the site with the surrounding landscape (through detailed reporting of site inputs and outputs) and within operational activities. Using this consistent framework for quantifying and documenting water use within an operation will provide a platform for compiling and comparing minerals industry water use with other sectors. This may support benchmarking activities within regions or companies and help demonstrate leadership amongst water users in water resource stewardship. The approach presented here is applicable to a wide variety of mining and processing activities, and biophysical environments, and can be adopted as the first step towards developing national water accounts for the Australian Minerals Industry.

Jan 1, 2009

By S J. Schafrik, M Long

There are several factors that are increasing the need for new graduates to be ready to design and manage more autonomous operations at mines. Autonomous controls and systems range from the start-up, control, and shutdown of processing plants to the autonomous operation of vehicles. These operations require the workers, engineers, and management to have additional skills for programming, debugging, tasking, and maintaining the equipment. The future survivability of many mining operations will be influenced by a company’s willingness and ability to understand, accept, and utilise this technology for safe and productive operations. This is an educational opportunity and challenge that needs to be addressed throughout the student’s experience, from first year to graduate level. This paper discusses the lessons learned from a decade of multidepartment effort at all student levels and many courses that are able to incorporate data science, controls, and autonomous design into the already topic-rich national curriculum. This approach also exposes other engineering disciplines to the mining industry which is a valuable recruiting tool for talent outside of the mining engineering departments.

Sep 1, 2024

By A Dix

Fire suppression systems are but one of the many technologies currently available to manage operational tunnel risks. However, the actual reasons for their use are often shrouded in mischievous discussions of the marketing variety.The international tunnelling community still stands divided on the merits (or otherwise) of fire suppression systems. For some the debate focuses on their cost compared to the theoretical benefits they bring to human safety.Long standing concerns about their potential adverse effects in an emergency are often at odds with the experience from tunnels which use them. High installation and operational costs are cited as reasons not to use them, yet toll road operators and insurers increasingly use them as a risk mitigation strategy for toll revenue protection.Fact or fiction, myth or reality, should such systems be seriously entertained or are they just another expensive gadget in the escalating array of expensive toys for modern tunnels? Ultimately this presentation argues that they have their place as a risk mitigation measure to achieve a range of objectives. The exact circumstances for their use ultimately fashioning their design and operational characteristics. This is an abstract only. No paper was prepared for this abstract.

Mar 8, 2011

By S Jeffrey, S Mundell, F Arboleda

In the current cycle of low commodity prices and rising costs, mine managers continue to focus on optimising mine performance and productivity. A critical component of strengthening performance and productivity is ensuring material is routed correctly and efficiently through the core mine production activities of drilling, blasting and grade control.By the time a blast is planned, an enormous amount of intellectual property has been invested in the exploration, resource development, feasibility studies and mine planning activities. The value of that knowledge is either realised or diminished during mine production. Efficient execution of the process is critical and is reflected by the quality and timeliness of the information produced.Multiple teams are involved in the mining extraction process. These teams are all under time pressure to keep the mine equipment operating. One of the root causes of this pressure is the dependency between the teams. They do not operate in isolation, but are a link in a chain depending on the outcomes of each activity. It is essential communication is efficient so tasks can be completed according to the production schedule. Unfortunately, communication fails when unintegrated systems are used because of:- different teams seeing different data, hence there is not an overall, up-to-date view of progress and priorities- lack of cross-functional visibility of data leading to failure to identify errors in time to address or correct issues- teams tending to be siloed and focusing on their part of the process rather than the overall objective.With different systems used for the parts of a common goal, supervisors and managers lack visibility of the process. This makes it difficult to identify process improvement opportunities.Streamlined communications help consolidate all data and activities resulting in improved cooperation between mine production teams. This outcome increases the confidence and efficiency of material routing decisions. It also reduces potential impact to mine performance from errors in early stage tasks like drilling and grade control. Having everyone collaborating off the same trusted data, helps teams identify with common goals and find business improvement opportunities as they appear.CITATION:Arboleda, F, Mundell, S and Jeffrey, S, 2016. Driving mine performance through communication, in Proceedings International Mine Management Conference, pp 117-124 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 22, 2016

By N Redwood, N Fowkes, A Bassom, S Durkin

"It is well known that from time-to-time a vehicle will interact with a bund or windrow and often the barrier is insufficient to safely arrest that vehicle. The result of such an incident is often catastrophic. Regulations around the requirement for edge protection near pit edges vary between jurisdictions. Generally in Australia regulations tend to be around placing the responsibility on the mine operator to provide ‘adequate’ or ‘appropriate’ edge protection. Guidelines often place a minimum height of bund at between half and two-thirds the diameter of the largest tyre on-site.Safescape has identified the opportunity to improve safety in open pit edge protection and is currently developing the Edge Protector (EP) product. The EP is designed to create a vertical front face to a conventional broken rock safety bund. The fundamental premise of the product is that by creating a vertical front face to the bund, trucks cannot easily drive up over the bund and instead have to push through the rock to get to the other side.In addition to providing a safer system for arresting vehicles, the vertical front face also means that extra space is made available in the haul road. This can either be used to facilitate larger trucks or when designing a new mine, with an increase in overall pit slope.This paper outlines the research and development of a new edge protection product. Discussion will include project objectives, economic incentive for mines to apply the system, mathematical analysis of the truck/bund interaction and physical testing of the product.Citation:Durkin, S, Fowkes, N, Redwood, N and Bassom, A, 2016. Innovative Approach to Open Pit Edge Protection, in Proceedings Ninth AusIMM Open Pit Operators' Conference 2016, pp 138–149 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 15, 2016

By G H. Park, Y J. Jun, J H. Park

The carbon solubility of the CaO-Al2O3-FeO-SiO2-MgO slag, the main system formed in the Ruhrstahl-Heraeus (RH) vacuum degasser, was measured at 1873 K to understand the effect of slag compositions on the carbon contamination in the ultra-low carbon (ULC) steels. The stable form of carbon was demonstrated to be carbonate by plotting the log [(wt%C)/aC] ratio against the log p(O2) which ranged -11 < log p(O2,atm) < -9. The carbon solubility of the CaO-Al2O3-FeO-SiO2-MgO slag can be estimated using thermodynamic model. The distribution ratio of carbon increased with increasing concentration of FeO due to the FeO reduction reaction and increased basicity of slag. The carbonate capacity of the CaO-Al2O3-FeO-SiO2-MgO slag can be expressed as a linear function of the activity of lime and the optical basicity.

Jun 19, 2024

By Kubo H, Kubita K, Morinara M

A quantitative method for predicting the mechanical properties of zinc alloys is proposed on the basis of the molecular orbital calculation of electronic structures. A new parameter which is the s-orbital energy level, Mk , of alloying elements in zinc was introduced into this method. This Mk parameter correlates with the electronegativity and the atomic radius of elements. The compositional average of this parameter varied linearly with the tensile strength and the hardness of commercial alloys and some alloys developed by Mitsui. This electronic method was very convenient in designing high performance zinc alloys efficiently.

Jan 1, 1993

The mathematical modelling of rock fragmentation by blasting is one of the most difficult and challenging problems of applied mathematics. Not only is complex mathematics required but there is incomplete understanding of the basic physics and chemistry involved. The possibility of getting the physical basis of a model correct by simple mathematical and experimental procedures is demonstrated for the novel process of fragmenting rock by high-pressure arc discharges. While the importance of obtaining the correct physical basis for a model is emphasised, high-pressure arc induced fragmentation of rock is shown to be a powerful laboratory tool for the study of blasting.

Jan 1, 1990

By A Jewbali, R Perry, R Inglis, L Allen

"The use of conditional simulation to characterise mine plan uncertainty is increasing for the assessment of risk in mining projects. While the development of grade uncertainty profiles is relatively straightforward and can be validated using standard geostatistical techniques, the addition of geological uncertainty to evaluate total risk remains problematic. Some of the problems associated with geological uncertainty methods include the clustering of data in favourable geologic units, difficulty in training image definition and the inability to address change of support issues for categorical variables. Despite these obstacles, the importance of geological uncertainty as a contributor to total uncertainty has prompted Newmont to explore and evaluate the use of various techniques (and combinations of techniques) on different deposit types.Two orogenic deposits of different geological complexity were selected for the study: Subika, a shear zone-hosted deposit, and Merian, a deposit containing gold mineralisation associated with quartz vein zones and stockwork within which are found higher-grade quartz breccia zones. Newmont trialled various categorical simulation approaches to determine the applicability of these methods for each deposit type and the effect of parameter choice on the width of the uncertainty interval. Some of the techniques that were trialled include multiple point statistics methods, sequential indicator simulation using local probabilities as well as variations of these methodologies.The goals of this study included: gaining an understanding of which techniques may work best in which deposit types gaining an understanding of the intricacies of each method gaining an understanding of the effect that each method has on total uncertainty analysis.This paper presents a comparison of the various techniques and makes recommendations for their use in uncertainty analysis.CITATION:Jewbali, A, Perry, R, Allen, L and Inglis, R, 2014. Applicability of categorical simulation methods for assessment of mine plan risk, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014, pp 85–98 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 24, 2014

By A L. Wills

Cliffs Natural Resources Pty Ltd (Cliffs) operates iron ore mines in the Koolyanobbing region of Western Australia. Ore is mined from three separate hubs and trucked to Koolyanobbing. There it is crushed and screened to lump and fines finished products and railed to Esperance port for export to Asian customers. Cliffs is renowned in the marketplace for its consistent product quality. In 2010, 9 Mt of ore was exported to Asia.Over the last three years, Cliffs has systematically refurbished its product quality system (PQS), to improve efficiency of production while maintaining its high standard of product quality. Particular attention has been given to reducing inventory, which has required significant modifications to the production process design.In redesigning the production process, emphasis was placed on maximising the application of the inherent blending in each of the production process steps and dedicated blending was only introduced where essential. Simulation modelling and statistical analysis of process capabilities were utilised to develop a system that optimises inventory, minimises rehandle, eliminates several decision-making steps and maintains a pull focus throughout the value chain.The new planning functions are now fully integrated and effectively control long-term grade variability rather than relying on long-term stockpiling. The production process design and the daily crusher blend plan are used to control short-term grade variability. With the upgrading of the planning processes the accuracy and consistency of algorithms for lump per cent and lump and fi nes grades became more important and an increased geometallurgical function has been added to the company.The continuous stockpile management system was upgraded to increase the effectiveness of the daily crusher blend planning process and is now the sole intervention point in the production process for grade-based decisions. Grade control systems were modified to utilise advances in software and geostatistics to deliver accurate short range planning models. The reconciliation and sampling systems have also been refurbished with an emphasis on practical application and feedback loops.Accountability and transparency are provided by management reports that are generated from a centralised data warehouse and the introduction of a corrective action system. Standardised reports are available to all stakeholders and a quarterly KPI scorecard assists the management review process.The successful rejuvenation of the PQS has culminated in operational efficiency through the implementation of an integrated end-to-end process flow. Shareholder value is maximised through maximising recovery of the resource and minimising costs. Customer focus is maintained by reliably delivering product with acceptable and low grade variability.

Jul 11, 2011

The first geological maps of parts of Australia were produced in the 1830s and 1840s, many being for purely practical purposes, such as indicating the occurrence of coal, iron and other essential materials. Mineral location maps were also first made about the same time.More systematic geological mapping commenced in the 1850s when large parts of New South Wales and Victoria were studied in government-sponsored surveys by geologists such as Samuel Stutchbury, Alfred Selwyn and Reverend William B. Clarke. Their work coincided with the opening up of most of the major goldfields of eastern Australia, which led to the establishment of Departments of Mines in the separate Colonies (later States within the Commonwealth of Australia).A few companies employed consultant geologists at this time, and the mapping by Frederick Odernheimer is particularly notable. Geological study of Australian ore-deposits and mineralisedareas was influenced by the continental European geological ideas of men such as Odernheimer as well as by those from England. Both geological and mineral maps were a feature of Colonialdisplays presented at major international exhibitions during the second half of the nineteenth century. The maps accompanied rock and mineral collections which showed the known and potential mineral wealth of the Colonies. Such displays raised interest in the potential for development amongst government officials, entrepreneurs and investors in Australia and abroad.By the 1880s most of the Colonies had produced basic geological maps, and several maps of the whole continent had been published. Although systematic mapping of the continent become a reality only in the 1950s, the nineteenth century geological and mineral mapping formed the basis for the development of the major coal, artesian water, and metalliferous mining regions of Australia.

Jan 1, 1990

By Jianmin H, Shuqin L

This paper analyses problems associated with cement based technique in metal mines, and provides a new mining technique of packing the tailing sand and water into solidified material. In the new technique, the cementing agent is a solidifying material containing a high percentage of water and tailing sand. The sand and water solidify into the packed body at the same time. The slurry of the packed body varies widely in concentration and suitability for different mining conditions. It consists of two liquid materials, each composed of a cementing agent, tailing sand and water. The thick liquids are transported to the packing place at the same time. Their pumping property is good; they do not solidify or block up the pipe during transportation. At the packing place, the two liquids are evenly mixed.The mixed liquid flattens out well and its solidifying speed is so fast that it solidifies into a packed body within a very short period of time. The compressed strength of the packed body can reach 1.2-5MPa in one day, which satisfies the requirements of different mining conditions. By using the new mining technique, all the tailing sand can be used again in the packed body and it is low in cost and investment. The mechanisation is easy and thus the working efficiency is increased and the use of labour decreased. Contamination problems caused by i. Dr & Prof. Beijing Graduate School, China University of Mining Science and Technology,Beijing,China 2 Northern .Jiaotong University, Beijing,China 3. Beijing Graduate School, China University of Mining, Science and Technology

Jan 1, 1992

By R F. Cota, C Freeman, A Heberle

"The Lamego mine is an underground gold mine in the Iron Ore Quadrangle in Minas Gerais state, Brazil. The mine produces 48 to 50 koz per annum, as part of the larger Cuiabá-Lamego Complex. This combined unit is AngloGold Ashanti’s largest gold producer in the Americas, contributing with 310 to 320 koz per annum.The mine started production in 2009, utilising cut-and-fill mining methods.A mining method change was trialled in 2014, introducing open stope methods. The key benefits proposed from this change are considered to be: improved safety by eliminating re-entry mining methods reduced mining costs/increased productivity from utilising bulk-mining operations.The results from the trial were encouraging, and open stoping participation expanded beyond a trial.Production from open stope areas reached 180 000 t (40 per cent of total run-of-mine; ROM) in 2015. While the change in mining method resulted in higher production rates, it also introduced a critical issue in terms of stope recovery rate.Average underbreak (unplanned loss of ore) in the larger open stopes reached 21 per cent in 2015. To manage this ore loss, a project targeting higher recovery was structured with three primary components: analyse current performance to define contributing factors (design process gaps, operating practices) investigate corrective actions apply corrective actions and maximise team engagement to ensure changes become standard practice.Within six months of commencement, a range of contributing factors had been identified, and the majority of the associated corrective actions implemented, including increased team engagement to ensure changes were not ‘once off’ actions.The outcomes show a clear reduction in underbreak (average ~12 per cent for 2016), with further improvement opportunities identified. The challenging target is now to achieve a further reduction to 10 per cent underbreak as the average for 2017. The results contributed 1400 oz and additional US$ 0.5 million to the cash generation profile for 2016.CITATION:Heberle, A, Freeman, C and Cota, R F, 2017. Increasing stope recovery in an underground gold mine by using effective analysis, corrective action and employee engagement processes, in Proceedings 13th AusIMM Underground Operators’ Conference 2017, pp 117–122 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Oct 16, 2017

By Q Yu, G Ren, Z-Y Chen, J Yang

The wedge shape theory of the rock fragmentation range in bench blasting is presented according to the dynamic characteristics of rock fragmentation by blasting in open pit under the condition of hole-by-hole initiation. The finite element software ABAQUS was used to analyse the rock fragmentation mechanism. The rock mass stress contours, crack propagation and damage evolution of different moments were obtained. The results showed that the wedge shape theory of blasting is closer to the rock fragmentation in hole-by-hole blasting and is useful to the design and calculation of charge weight.CITATION:Yang, J, Chen, Z-Y, Yu, Q and Ren, G, 2015. The wedge theory of borehole charge design for bench blasting and its numerical simulation, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 169–176 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By E Gabriel, J C. Koppe, A Gomes and P Crispim, R Schaarsdmit, I Pablos

Drill and blast (D&amp;B) is one of the most important production operations in open pit mining. The resulting fragmentation of the D&amp;B reflects in the downstream unit operation. Good fragmentation of the ore will minimise the cost of loading, hauling and crushing. The understanding of the geological model integrated with a software system for bench face surveying and planning of blast layouts based on three-dimensional images can help to achieve the fragmentation goals of the mine operation. A case study integrating these tools was carried out in a large iron mine in Brazil. The iron ore in the study area consists of hard and friable itabirites. More than three different ore types may occur on the same bench. Under these conditions, data integration becomes necessary to improve the results of blasting. A blasting plan was based on the generated geological model. The methodology helps understanding the factors that can interfere in the fragmentation process, allowing defining actions that can improve the blast design in those places that fragmentation wasn’t achieved. This condition is important for a continuous improvement of the drilling and blasting operation. In comparison with the previous blasting carried out at Itabira mine, which did not take into account the geological model, substantial improvements in fragmentation were observed, eliminating the need for secondary blasting.CITATION:Schaarsdmit, R, Pablos, I, Koppe, J C, Gabriel, E, Gomes, A and Crispim, P, 2015. Geological modelling and bench face survey to improve blasting fragmentation, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 401–406 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

The pyroclastic-filled Voorspoed kimberlite pipe has a low grade due to significant internal dilution which translates to a marginal business case. The site, with excavations, tailings dumps and buildings remnant of mining from 1906 to 1912 is to become De BeersÆ benchmark mine in South Africa. In a climate of skills shortages and lean structures, a geological service to optimise exploitation of this complex resource was established. As historical mining removed the higher-grade centre of the pipe, initial production was in the weathered upper benches along brecciated pipe margins. Trenching and blasthole logging before blasts helped to mitigate the effects of the drastic contact deviations that occur when working with an inferred geological model. However, identification of unfamiliar weathered kimberlite and delineation of unmodelled internal waste posed challenges. Efficient grade control by demarcation and allocation of individual truck loads will be vital to continue profitable mining at Voorspoed. Further challenges arose across disciplines. The first yearÆs planned production of mostly weathered kimberlite was processed through a plant designed for VoorspoedÆs unusually competent ore. The high clay content of the weathered material led to clogged chutes and overloaded fines disposal, hampering efforts to commission the plant. Resolving this problem involved mining æout of planÆ to provide a blend of fresh and weathered kimberlite. The calculation of an accurate mine call factor was hindered by a lack of haul truck monitoring, process stoppages and stockpiling in the plant during commissioning. Updating of the geological model to incorporate the contact changes observed in the pit was slowed by the need to first understand how 40 years of exploration data was integrated to create the model. A plan, involving focused mine geology practices, is in place to upgrade a portion of the resource from Inferred to Indicated level of confidence. These challenges are not limited to new mines but will be ongoing as new information is constantly gained at Voorspoed and many mining operations.

Jan 1, 2009

By N Patel, S Narendranathan, T Mok, J Lowe

The Hazelwood Mine (HM) commenced operations in the 1950s and was originally operated by the State Electricity Commission of Victoria (SECV) prior to it becoming privatised. ENGIE, the current owners of the Hazelwood Mine ceased operations in 2017 and have since transitioned the site into the rehabilitation and closure phase, which is to encompass a full pit lake as part of the final landform. A key aspect of HM closure is the maintenance of long-term stability of the pit slopes to deliver a final landform which is safe and sustainable, particularly given its proximity to critical public receptors. The Princes Freeway, which is the primary access route to the Latrobe Valley (LV), and the Morwell Township are both located immediately to the north of the HM. With due consideration of the mine void and nearby public receptors, the authors performed slope stability assessments of critical mine

Aug 2, 2023

By S Udayakumar, S Biswal, N Sarmadi, V Sahajwalla, F Pahlevani

Recent times have witnessed a notable momentum in the interest surrounding technology dedicated to harnessing waste as valuable resources, prompted by the mounting challenges posed by waste accumulation and the swift depletion of natural resources. The carbon dissolution process within a molten iron bath stands as a pivotal reaction within the metal processing sector. The current study explores the utilisation of waste graphite electrodes (WGE) (obtained after being utilised in an electric arc furnace) as a secondary resource of carbon for dissolution into liquid iron. Experimental investigations were carried out at 1550°C using the sessile drop approach. High purity iron powder was used and the carbonaceous substrates were prepared from the ground WGE. The carbon pickup was determined using a suitable carbon analyser. Furthermore, an examination of the interfacial area between the molten iron and the WGE substrate was conducted beneath the metallic droplet, which effectively represents the iron/carbon interface. This interfacial analysis was carried out on two different samples obtained after a varying period of heat treatments at 1550°C. The interface layer was investigated using scanning electron microscopy (SEM) in conjunction with energy-dispersive X-ray spectroscopy (EDS).

Jun 19, 2024

By O Arafat, K M. Bartholomew

A voracious consumer of energy and grinding media, the modern ball milling circuit has a huge direct cost impact on a mineral processing operation. Through optimisation, grinding also has the potential to unlock great improvements in recovery and throughput, but how can the complex interactions between mills, classifiers, tonnage, ore-type and downstream recovery be measured, understood and managed in a systematic manner?Functional performance analysis provides the tools and insights needed to measure, understand and improve the two key process efficiencies in ball milling circuits: classification system efficiency (CSE) and mill grinding efficiency.CSE measures the composite performance of the classification system as a whole. In short, the purpose of the classification system is to ensure that grinding mill energy is used to grind coarse particles while minimising overgrinding. CSE is simple to measure in the plant and it provides immediate feedback to the plant metallurgist, mill superintendent and management about the performance of the classification system and the amount of wasted energy in the grinding plant.Mill grinding efficiency measures the capacity of the grinding mill to convert feed-sized material into product-sized material on a tonnes per kilowatt hour basis. It is normalised based upon the ore resistance to breakage, so it provides feedback about the ‘health’ of the milling process under varying operating conditions and ore types. Mill grinding efficiency is measured at the same time as CSE through circuit sampling.Functional performance analysis combines CSE and mill grinding efficiency to provide a measureable, manageable optimisation objective. It also provides a link to tonnage, ore type and recovery. As a result, systematic optimisation of a grinding circuit is a measureable and manageable process to meet business objectives.CITATION:Bartholomew, K M, McIvor, R E and Arafat, O, 2014. Functional performance of ball milling circuits – a plant metallurgist’s tool for process characterisation and optimisation, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 227–232 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

A thick sequence of alkaline intrusions and volcanic rocks underlies a Quaternary caldera on Liliir Island. The sequence is host to a still active sub-aerial hydrothermal system and associated epithermal gold mineralisation. Sub-horizontal alteration horizons exhibit progressively increasing chondrite norma-lised (La/Lu) en and (La/Sm) cn ratios from unaltered shoshonites, to the potassic alteration zone, to the argillic altera-tion zone to the advanced argillic alte-ration zone. The increasing fractionation of HEE, and especially of LHEE, up the alteration sequence is the result of de-creasing pH, temperature and alkalinity of the hydrothermal fluids with increa-sing alteration intensity. HRE3 were especially mobile in argillic and advanced argillic alteration units characterised by acid fluid conditions and large fluid volumes. Abundant Cl, S and CO2 within the hydrothermal fluids and thus abundant REE complexing agents and large fluid volumes favoured the mobility of REE during hydro-thermal alteration of the volcanic rocks and intrusions. Steam escape, mixing of the gases with groundwater and a change from a magmatic neutral chloride hydro-thermal system to a meteoric acid sulphate system was accompanied by liquid/vapour ratio changes, pronounced alkalinity, pH and temperature decreases, and fluid/rock ratio increases. This caused the mobili-sation, fractionation and deposition of PF.F.

Jan 1, 1990