Search Documents

By S. Lubbe

South Africa and Australia are the biggest suppliers of zircon sand to the international zirconium industry. However neither South Africa nor Australia is well known for zircon beneficiation. Geratech Zirconium Beneficiation Ltd (GZB) continued with additional research on sodium hydroxide (NaOH) cracking of zircon sand during 2002-2003. In 2003 GZB started extracting zirconium from zircon sand by means of NaOH cracking on a commercial scale. Experience has shown that temperature profile and atmospheric control inside the furnace is crucial for the beneficiation of zircon sand. Silica carryover to zirconium chemicals could result if a high temperature is used. Once the sodium silicate is extracted from the sodium zirconate and dissolved in hydrochloric acid, two distinct routes can be followed to precipitate various zirconium chemicals. The most common route is to precipitate zirconium oxychloride crystals (ZOC), with subsequent purification from all contaminants (crystal route). Less known is the process (liquid route) that involves the direct precipitation of zirconium basic sulphate (ZBS). This route will yield a less pure product, with contaminants such as silica and titanium. An important factor in this route is the prevention of silica gel formation, which could hamper final product filtration. For applications like paint drying (zirconium octoate) or antiperspirants (zirconium hydroxychloride) low levels of contaminants have no effect on the final product. The advantage of the liquid route is fewer production stages compared to the crystal route. The disadvantage of the liquid route is that the market for the products will be significantly smaller. The optimum solution could be a plant design that could cater for both routes. Another example of an application of zirconium chemicals is the use of ammonium zirconium carbonate (AZC) in the paper industry. Zirconium basic carbonate (ZBC) is dissolved in ammonium carbonate to produce AZC solution. AZC is used mainly in European countries in the paper industry. For example, carton boxes were initially produced with formaldehyde as the binder, however, it has now been replaced with AZC since formaldehyde is considered toxic. AZC reacts with the cellulose fibres in the paper to act as the binder. The resulting product is not toxic, and printing ink dries very quickly due to the porous paper structure. Other applications of zirconium chemicals involve the use of acid zirconium sulphate tetrahydrate (AZST), zirconium orthosulphate (ZOS), potassium zirconium carbonate (KZC), and zirconium hydrous oxide (ZHO). Fluoride-based zirconium chemicals like zirconium tetra-fluoride (ZrF4) and hexafluoro-zirconic acid (H2ZrF6) are used in the aluminium industry. Zirconium oxide (Zr02) can be produced from any of the abovementioned precipitated chemicals via a high-temperature decomposition process. The physical properties of such oxides can differ tremendously, depending on the final application. The fired density of sanitaryware is typically 5.8 g/cm3, compared to milling media at >6.1 g/cm3. The required fired density is achieved by controlling the precipitation and decomposition conditions for these two oxides. The same applies to stabilized and mixed oxides, for example where zirconium oxide acts as an oxygen carrier in fuel cells.

Jan 1, 2012

By Charles S. Barrett

NUMEROUS determinations1-7 of the tex-ture of cold-rolled polycrystalline iron, steel, and ferritic alloys have been made with good agreement among the various observers as to the principal features of the texture common to all, but there has been no adequate explanation of the texture in terms of the behavior of individual grains. This study presents an explanation of the texture based on the observed rotation of single crystals when deformed in a manner similar to a grain in the aggregate, a method we have found useful in leading to a better understanding of compression and tension textures;8,9,10 in particular, the aim has been to determine experimentally the end orientations of rolled single crystals of iron. These are discussed in connection with the point of view of Wever1 and of Boas and Schmid2 that the rolling texture is a simple compression texture (compression normal to the rolling plane) superimposed on a simple tension texture (tension in the roll-ing direction), and the point of view of Kurdjumow and Sachs3 that three ideal end orientations exist.

Jan 1, 1940

By Steve Dubnewych

The Joint Water Pollution Control Plant, operated by the Sanitation Districts of Los Angeles County, treats wastewater generated by over three million people. A new tunnel and ocean outfall is being considered to meet future hydraulic demands and provide long-term redundancy for the Districts? existing tunnels, portions of which were constructed as early as the 1930s. The detailed process used to evaluate the feasibility of various tunnel and out-fall locations is described. Challenges include a geologic profile with mixed face and squeezing ground conditions; high water pressures; active fault crossings; gassy and contaminated ground conditions; and liquefaction, slope stability, and lateral spreading concerns in the area of the riser and diffusers.

By Shadia J. Ikhmayies

The SnO2/CdS/CdTe thin film solar cells were fabricated on glass substrates by using the spray pyrolysis (SP) technique for the deposition of the SnO2 and CdS layers and vacuum evaporation for the CdTe layer. The transmittance curves were used to investigate the interdiffusion in the two interfacial regions SnO2/CdS and CdS/CdTe by taking the first derivative of the absorbance as a function of wavelength. The appearance of new bandgaps around the bandgaps of SnO2:F, CdS:In and CdTe layers is a strong evidence on the interdiffusion in the two interfacial regions and/or the formation of quantum dots.

Jan 1, 2010

By Keith Pucalik

Understanding Vibrations fr om Blasting focuses on explaining blast vibrations and their effects on people and homes while keeping an eye on the importance of the use and significance of explosives in our daily lives. Unlike many predecessors, this film will help blasting pro f e s s i o nals explain blast vibrations and address many of the layman’s most fre q u e n t l y asked questions. The film can be used in pubic hearings, given to homeowners during preblast surveys, or played at educational seminars for professionals. The film can also be used after blasting has begun and residents have already experienced vibration events.

Jan 1, 2004

By E. D. Palmes

A new type of personal sampler for quantitative estimation of atmospheric concentrations of contaminant gases was first reported from this laboratory in 1972. The sampler requires no pumps or flow regulators and employs instead the motion of the gas molecules them-selves to furnish the power for sampling. Under this grant, work was completed on development of a kit for the field determination of both NO2 and NO. Detailed instructions for the preparation of the samplers and the use of the kit was supplied to the Technical Project Officer. Attempts were made to adapt the same type of sampler to the measurement of SO2 and CO. Both gas chromatographic and turbidimetric procedures for the final estimation of the S02 proved to be unsatisfactory. For CO no reagent was found which would react sufficiently rapidly with this gas to utilize the essential feature of the diffusion sampler, the maintenance of a diffusion gradient which is at least approximately numerically equal to the ambient concentration. A number of publications on use of the NO2 sampler, both at occupational and community air pollution levels, have resulted from this work.

Jan 1, 1979

By Peter Townsend, Sergei Diachenko, Allan Moss

The Palabora Mining Company has successfully extended the life of its operation by developing a 30,000tpd block cave underground mine below the now closed open pit. The process of transitioning from surface to underground mining has been technically, operationally and managerially challenging. This has been due to a number of factors; in particular, the development of a block cave in a very competent rock mass. The competence of the rock mass is clearly demonstrated in the open pit that preceded the block cave, one of the steepest deep open pit excavations in the world. With cave breakthrough, however, the pit was ?instantaneously? deepened by 400m causing a major failure of the northwest wall involving close to 100Mt of waste material.

Jan 1, 2006

By O. C. Blade

Studies on more efficient utilization of petroleum have been made for 50 years by the Bureau of Mines. As part of this work, the Bureau has analyzed thousands of samples of crude oil by its standardized routine method, and many of these analyses have been published, sometimes in special compilations, other times in connection with reports of research on petroleum. This report is a finding index for all analyses published from 1921 to 1959, and brings up to date the information in Information Circular 7470 3 and in the appendix of Bulletin 490.4 The routine method of analysis and the equipment originally were described in a report by Dean and associates. 5 This report has long been out of print, but Bulletin 490, bringing the procedure and its modifications to date, was published in 1951. 6 Briefly, the procedure consists of testing, by standard methods, small samples of a crude oil for gravity, sulfur, color, viscosity, pour point, and (more recently) nitrogen; and, by a standardized procedure, distilling a portion of the crude oil and determining certain properties on the separated fractions and residuum. Careful records are made during the procedure, and the distillation data obtained are used to compute the approximate amounts of products present in the sample--such as percentages of gasoline, kerosine, gas oil, and lubricants. The principal data and results are recorded on a standard analytical report form. An analysis of a sample of crude oil from a recently developed field is shown in table 1. Compilations of these analyses, sometimes in tabular form and usually for specific geographic areas, are published from time to time. Analyses often are included in connection with other studies, such as engineering field reports.

Jan 1, 1959

By Gregory M. Molinda

Extremely difficult ground conditions were encountered in the main belt entry in a room and pillar mine in West Virginia. Several generations of supplemental support, including cable bolts, cribbing, and Heintzmann jacks and beams failed to halt roof falls that threatened workers safety and the life of the mine. Polyurethane (PUR) was injected into 27 intersections in the roof and the results were monitored by borehole video camera. The mine had averaged 2-3 falls in the beltway per year and, since the roof injection, no roof falls have occurred. Pre- and post injection monitoring of test holes showed that stability can be achieved without filling all of the existing void spaces. Video logging showed that the project goal of building a beam from 2-6 ft into the roof was successful. Pre-injection monitoring of roof fractures uphole can delineate the zones to target for reinforcement, and avoid pumping PUR into large voids to little effect. Multiple-injection zones can be identified, and the entire intersection drill hole array can be optimized based on knowledge of the fractured zones. In addition, pre-monitoring can prevent excessive hydrofracturing in solid zones. Polyurethane injection is a proven method of rock stabilization in even the weakest, most broken ground. Optimization of the injection design by pre-injection video diagnostics can greatly contribute to the successful and efficient roof stabilization.

By Brian H. Greene

The U.S. Army Corps of Engineers, Pittsburgh District, is in the final phases of modernizing the locks and dams on the Monongahela River. One facet of this modernization is to replace the existing Locks 4 located on the Monongahela River approximately 40 river miles upstream from Pittsburgh, Pennsylvania. The existing locks consist of a 56-foot x 720-foot main chamber and a riverside 56-foot x 360-foot auxiliary chamber built in the 1930s. Two new lock chambers, each 84-foot wide by 720-foot long, will be constructed at the location of existing Locks 4 and will be named Charleroi Locks. The purpose of the new project is to facilitate navigation on the lower Monongahela River. Pittsburgh is currently the second largest inland waterway port in the nation, and the new locks will be an important component of the navigational infrastructure. The existing lock walls are of mass concrete construction and are founded on wooden timber piles driven to rock through alluvial sands and gravels. The new lock walls were designed to be supported by approximately 300 reinforced concrete drilled shafts, varying in diameter from 4 to 6 feet. To handle axial loads, the drilled shafts were designed for end bearing, with some skin friction. The tips of the shafts will be founded within competent rock. Since the walls will undergo lateral loads, the drilled shaft design also had to consider this loading condition. Some of the drilled shafts will be installed within coffer boxes, which will incorporate a tremie concrete seal down to top of rock. Complicating the design even further was the fact that some portions of the new walls will be supported by shafts that extend some 9 feet above top of rock through alluvial soils, producing a cantilever effect. The first phase of the new lock construction was initiated in the summer of 2005 with a contract awarded to replace the river wall. This required shutting down the existing riverside lock chamber and diverting all river traffic to the longer existing land chamber. The foundation of the new river wall will use 144 drilled shafts. To optimize the design embedment of drilled shafts in rock for the river wall, an exploratory drilling program was conducted by the contractor in July and August, 2005. Based on the quality of the sedimentary bedrock, the shafts will be embedded in rock from 31 to 38 feet. To achieve adequate end bearing resistance, the tips of each shaft will extend through predominantly claystones into a more competent siltstone unit for a minimum embedment of one foot. The contractor also performed an exploratory pile driving program to aid in the construction of the drilled shaft casing and the cut off walls that will encapsulate the river wall. Two demonstration drilled shafts located outside the footprint of the new river wall, will be constructed prior to the drilling of any production shafts. The demonstration drilled shafts will verify that the contractor is able to meet the design criteria and quality requirements of the contract. The river wall contract is currently underway and is scheduled to be completed in 2010.

Jan 1, 2006

By John J. Sammarco

Abstract- Emergency shutdown systems (ESDs) for mining machinery provide critical functions to safeguard miners. Traditionally, ESDs were realized with simple hardwired circuits; today, there is a growing trend to use programmable electronic technology such as programmable logic controllers (PLCs). This paper describes an analytical study to quantify the safety integrity of a PLC-based ESD and a hardwired ESD. The safety integrity level of each design approach was determined by quantifying the average probability of failure on demand (PFDavg) as described by the recommendations for programmable electronic mining systems published by NIOSH and the IEC 61508 international standard. The safety analyses addressed system architecture, hardware failure probability, proof test interval, diagnostic coverage, and human error probability. The results indicated that a same level of safety, safety integrity level 3 (SIL 3), could be attained when evaluating random hardware failures. Neither approach could attain SIL 3 if manual activation was used. Human error was the limiting factor where, using human reliability analysis, PFDavg < 1 x 10-1; thus, the ESD does not meet SIL 1. It is apparent that automatic verses human¬activation of the ESD is a very important safety consideration. Manually actuated ESDs can only achieve SIL 1 regardless of the technology; therefore, additional independent safety layers of protection are needed to exceed SIL 1. Secondly, it is apparent that the technology choice is very important. The PLC-based ESD was much simpler to design and to validate safety1.

Jan 1, 2007

By Fabian Kirsch

Cyclic behaviour of axially loaded piles has been an issue since studies revealed that the capability to transfer skin friction into the ground is highly depending on the level and the number of load cycles the pile is subjected. It has been shown that degradation of skin friction due to axial cyclic loading leads to accumulating displacements and a severe reduction in pile capacity. In Germany the DIN 1054 as well as the Recommendations of the Working Group 2.1 ?Piles? of the German Geotechnical Society (EA-Pfähle) require the consideration of cyclic loading for the assessment of both the displacements and the capacity. Up to now no broadly accepted design method exists, which enables the engineer to give a reliable judgement on the pile capacity under axial cyclic loading and the displacements respectively. Instead numerous design charts make it possible to distinguish between stable and instable loading levels in order to ensure a design on the safe side. A newly developed design approach based on engineering models is presented which delivers a calculation algorithm for the remaining axial pile capacity after a defined number of load cycles to allow for the analysis of stability of the foundation. Furthermore the computation of accumulating displacements is made possible. The results are verified with pile load tests undertaken at Dunkirk, France and showed that the axial capacity after cyclic loading calculated with the newly developed design approach predicts actual capacity with an accuracy of ±20%.

Jan 1, 2011

By R. G. Lett

Gaseous products resulting from rapid pyrolysis of coal and coal/inhibitor mixture&apos;s by a ruby laser and a flash-tube were monitored on-line by time-of-flight mass spectrometry. The distribution of stable gases from the coal is not Greatly influenced by the addition of small quantities of powdered flame inhibitors. Preliminary studies of the reaction of elementary radicals with coal and coal/inhibitor mixtures are described. The different types of experiments are discussed with regard to possible modification and application to studies of flame inhibitor action.

Jan 1, 1973

By Preston C. Holloway

Transformational roasting involves the heating of a material along with specific additives to induce mineralogical changes in the starting material. By controlling the chemical composition, roasting atmosphere, temperature and time of reaction, the mineral transformations induced during roasting can be engineered to control the distribution of valuable, or harmful, metals and to produce new mineral assemblages that are more amenable to conventional methods of metals recovery or to environmentally safe disposal. To date, this type of process has only been applied to the recovery of a limited number of metals, but current research is looking to expand the application of these techniques to the recovery of metals from a wider range of materials. An introduction to these techniques is presented along with preliminary results from their application to metals recovery from zinc bearing wastes, such as zinc ferrite leach residues and carbon steel electric arc furnace dust.

Jan 1, 2006

By Herbert H. Einstein

Instability of rock slopes often occurs in the form of excessive movement of bodies that are bounded by discontinuities. The well known limit equilibrium analysis for wedges and blocks suffer, however, from procedural simplifications and from the basic deficiency of limit eguilibrium analysis--the rigid body assumption. Thus, stability analysis for 2-and 3-plane wedges with a wide range of additional features regarding failure modes and external forces have been developed. The deficiency, due to the rigid body assumption, was corrected by an approach that includes the effects or the in-situ stress field and of the stiffness of discontinuities. The final step in making limit equilibrium approaches more valid was achieved with the method of artificial supports which makes it possible to identify among all possible failure modes the critical one and to determine the corresponding factor of safety. The analytical development includes the creation of appropriate computer codes and routines for programmable pocket calculators.

Jan 1, 1979

By Dolly Chakraborty, S. Ranganathan, S. N. Sinha

Pre-reduction of chromite outside the submerged-arc furnace (SAF) can significantly lower the specific power consumption in the SAF process. Conventional processes for the pre-reduction of the ore operate at relatively high temperatures, at 1400-1500°C. It is possible to enhance the rate of reduction at low temperatures by optimizing the flow rate of inert gas over the reaction site. The influence of the flow rate of inert gas on the rate of reduction of chromite ore was investigated. The rate of reduction initially decreased wit the flow rate of the gas. It increased subsequently at higher flow rates to be followed by a decrease again. There was an optimum flow rate at which maximum reduction could be obtained. It was possible to achieve high levels of reduction at 1200°C by optimising the flow rate of the gas. The degree of reduction obtained was comparable to that obtained at 1400-1500°C, by conventional process routes.

Jan 1, 2007

By E. L. Rawlins

Systematic leakage surveys of natural-gas transmission lines not only aid in the conservation of gas, but can be made to show direct financial returns of large magnitude. 1. Such surveys reveal the actual leakage from the lines, and indicate repairs to be made in order, to eliminate unnecessary waste. 2. Tests on lines, after repairs are made, show the actual saving that has been accomplished. 3. Tests on newly constructed lines reveal the presence of leakage that should be eliminated before the lines are put into service.

Jan 1, 1926

By W. Kracht

Frothers are surfactants used in floatation to aid generation of small bubbles. Studying events at the moment of bubble creation is a challenge because of the short time frame. This presentation introduces a novel acoustic approach. The technique has the resolution capable of detecting events that occur within 1-2 ms. The transition from coalescence to non-coalescence is tracked as a function of surfactant concentration and gas rate through the capillary. Results are given for some common flotation frothers and n-alcohols (C4-C8). A stress model is used to give a qualitative explanation to the observed action of frothers on coalescence prevention. Results for salt (sodium chloride) are included for comparison).

Jan 1, 2009

By A. K. Anyimadu

Ongoing development work on ultra-fine grinding for various applications at the Group?s concentrators has been conducted by Anglo Platinum over the last few years. Current potential applications for mainstream grinding and concentrate grinding are the subject of a group-wide research and development programme. The first 10 000-litre 2.6 MW IsaMill was jointly developed by Anglo Platinum, Xstrata Technology and Netszch for installation at the Western Limb Tailings Re-treatment project in Rustenburg, South Africa. The unit was commissioned in late 2003/early 2004,and has operated in an intermediate concentrate regrind application successfully since. This paper describes the operational performance to date, as compared with the original duty specifications and objectives. The first mainstream M10 000 IsaMill with a 3 MW drive will be operational in November 2006 at the Potgietersrus Platinum (PPL) ?Platreef? Sandsloot Concentrator in South Africa?s Limpopo Province. Keywords: Western Limb Tailings Re-treatment Plant, IsaMilling, Platreef, platinum, palladium, PGMs, tailings.

Jan 1, 2007

By Johannes Moeljono, Werner Wenzel, Heinrich Wilhelm Gudenhau

As an important mechanism for increasing production of the suction-draft-sinter process, it has been shown that gas permeability through the sinter layer plays an important role. Methods to increase production rates have been indicated and suggestions for carrying out the process have been made to improve the rate of production, reduce the fuel consumption, and at the same time obtain a uniform sinter. Laboratory experiments were conducted at the Institute for Ferrous Metallurgy of the Technical University at Aachen to illustrate these methods. Methods of Increasing Gas Penetration Through Sinter Layers The following are of fundamental importance in determining the process cycle during the sintering of iron ores: 1) Generation of maximum temperature, since its form and range determine sinter quality. 2) Propagation velocity of the temperature maximum which controls the attainable output. 3) The convective heat transfer which influences the velocity of travel of the temperature maximum.

Jan 1, 1974