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By Sean Gallagher, Rhys Llewellyn, Jay Mattos

This paper contains the results of an examination of accident, injury, employment, and production information reported to the U.S. Department of Labor's Mine Safety and Health Administration (MSHA) and provides information on some of the measures longwall mine operators are using to prevent accidents In all industries, technological advances play a key role in determining those who will survive as competitive participants in an increasingly global marketplace. While mining is among the most basic of industries, technological change is neither unfamiliar nor unwelcome to miners. Historically, technological advances in mining, particularly coal mining, have tracked closely with fluctuations in demand. In the early 1900's, coal accounted for more than three quarters of all the fuel consumed in the U.S. To meet this tremendous demand, underground cuffing machines were introduced, resulting in faster, more efficient coal extraction. Transporting coal to the surface, however, remained labor intensive. In the 1920's, nearly all underground coal was still being hand loaded. Demand for coal then declined as the price of oil, natural gas, and electricity became competitive. In the late 1930's and throughout the duration of World War II, coal demand and production was high. By 1940, more than half the coal mined was being mechanically conveyed to the surface. In 1948, the continuous mining method was introduced in the U.S., further accelerating the extraction process. By the 1950's and 1960's, however, coal production again declined as railroads converted to diesel fuel and gas and oil provided a larger share of the home heating market. Underground coal mines required even more mechanization to remain competitive as an energy source. The first longwall system was introduced in 1960. By 1995, longwalls were producing more than 189 million tons of clean coal annually, surpassing continuous mining production for the second straight year. The mining of coal and other materials has not come without a huge loss of life and considerable human suffering. More than 103,000 workers died from injuries in U.S. mines in the last 85 years. Between two and three thousand miners died each year from the turn of the century until 1931, many from underground fires and explosions. The U.S. has witnessed a tremendous drop in fatalities in underground coal mines. Credit for that is due to safety inspections and enforcement activities, better safety awareness and practices among management and labor, improved ventilation, the use of safer equipment, and increased mechanization which removed many miners from the hazards at the face and also reduced the size of the mining work force. There is little doubt that longwall mining has greatly increased underground coal mine productivity. The degree to which longwall mining has contributed to a safer work environment for underground miners is more difficult to ascertain.

By Charles L. Parsons

During the past year, in producing 500,000,000 tons of coal we wasted or left underground, in such condition that it probably will not be recovered in the future, 250,000,000 tons of coal; we turned loose into the atmosphere a quantity of natural gas larger than the total output of artificial gas during the same period in all the towns and cities of the United States; we also wasted or lost in the mining, preparation, and treatment of other important metalliferous and non- metalliferous minerals from 10 to 50 per cent of the year's produc- tion of such minerals. These losses serve to indicate the importance of inquiries and investigations by the Federal Government for the purpose of lessening the waste of essential resources-investigations on the same general lines as those looking to a reduction in the loss of life in the mining operations of the country and the far more exten- sive investigations looking to the more efficient production and use of agricultural products, both of which are being conducted by the Federal Government. In a consideration of the possible activities of the individual, the State, and the Federal Government in behalf of a less wasteful use of our mineral resources certain facts and principles should be kept clearly in mind, namely: That the present generation has the power, and it will exercise the right, to use as much of the country's resources as it actually needs; there can and there will be no such thing as stinting the present gen- eration by bottling up resources for the use of the future. That the Nation's needs are not likely to be curtailed; these needs will increase with the extent and diversity of the Nation's industries, and they will increase more rapidly than population increases, for the reason that the per capita consumption of mineral products is rapidly increasing; and That the men of this generation will not mine, extract, or use these resources at continuous financial loss to themselves in order that some- thing may be left for the use of future generations; there can be no such thing as a mineral industry without profits.

Jan 1, 1912

By Henry Kreisinger, F. K. Ovrız

Some of the investigations conducted by the Bureau of Mines have for their object the collecting and disseminating of information regard- ing methods by which the fuels of the country may be most effi- ciently used. As the analysis of flue gases tends to develop better methods of firing, which in turn reduces waste of fuel, the Bureau of Mines in this bulletin presents for the benefit of those in charge of boiler plants and all other persons interested detailed information on methods of sampling and analyzing flue gases, and on the utilization of the analyses in promoting boiler-room economy. This bulletin is intended to be a companion to Technical Paper 80," and is written in plain and nontechnical language, as far as pos- sible, so that it may be readily understood by persons who have not had the advantage of a technical education. Whenever possible, illustrations of apparatus and methods of handling have been used rather than elaborate descriptions. The material presented in this report is arranged in two parts. The first part contains the description of the apparatus and the methods used in sampling and analyzing flue gases. The second part gives experimental results obtained with the different methods of sampling and collecting flue gas that are recommended in the first part of the report. Only simple apparatus and methods are considered, as they are accurate enough to show the large heat losses due to the use of too much air, and are also accurate enough to indicate any incomplete combustion losses of economic importance. Without doubt the loss due to large excess of air is the greatest one in the boiler room, and can usually be greatly reduced by making proper use of gas analysis. Before engineers in the isolated industrial plants can be induced to analyze for small traces of combustible gases, they must be first taught how to analyze for carbon dioxide (CO), and they must learn to appre- ciate the great possibilities of reducing loss from large excess of air. Furthermore, in the face of the great difficulty of obtaining a fair

Jan 1, 1915

By D. T. Randall

In carrying out a general plan of ascertaining more efficient and more economical methods of utilizing the fuel resources of the United States, in order to prevent unnecessary waste and thus conserve the available supply, the United States Geological Survey made a series of experiments on the combustion of fuel in house- heating boilers. As it was realized that steam boilers of the ordinary types used for heating private houses are often installed and operated under conditions unfavorable to fuel economy and smoke prevention, these experiments were made with briquets, raw coal, and washed coal, so as to determine what is to be expected of these fuels in a representative house-heating plant, properly installed and operated. Briquetted coal had been frequently tested in the hand-fired furnaces under the Heine boilers in the Survey fuel-testing plant at St. Louis. The results were so satisfactory as regards economy and smokelessness that it was decided to conduct a series of tests to determine the value of this fuel for domestic heating purposes. Beginning in October, 1906, a number of evaporation tests were made on the house-heating boiler installed to heat the buildings occupied by the structural-materials laboratory, both briquets and coal being used. After these tests were well under way, it was thought advis- able to conduct some additional tests under conditions more constant than could be maintained at this plant. A carload of briquets was shipped to the University of Illinois engineering experiment station at Urbana, Ill., where two house-heating boilers of a size commonly used in residences were available. This equipment permitted more uniform conditions of pressure and capacity, making the results more valuable for comparison. Tests were made with this fuel at Urbana in June and July, 1907. The present paper is an account of both series of tests, and includes also details of tests made at Urbana on three standard fuels in the spring of 1908. Perhaps the most important result obtained is that showing the relative value of different fuels for domestic purposes. From Table 16. on page 39, it is possible by comparison to arrive at the probable value of any fuel in any part of the country. The figures in the table

Jan 1, 1911

By K. L. Cashdollar

A project to evaluate the South African bagged stone dust explosion barrier was successfully completed at the National Institute for Occupational Safety and Health (MOSH), Pittsburgh Research Laboratory's (PRL), Lake Lynn Experimental Mine (LLEM) during the period November 1999 through May 2000. The tests were conducted in a three- entry section of the LLEM. Two types of explosions were used to evaluate the distributed and concentrated bagged barrier performance in a multi-entry mine section. The fuel zone of the first explosion type was only in the center B-drift. In the second explosion type, coal and stone dust mixtures were place in all three drifts. A total of six explosions, including two baseline and four barrier evaluation explosions, were conducted. Of the four barrier explosions, the distributed and concentrated barriers were each evaluated against the two explosion types. For these explosion tests, the distributed barrier extended from about 74 to 170 m and the concentrated barrier from about 74 to 104 m in B-drift. The distributed barrier successfully stopped flame propagation in both types of explosion tests. The flame extended further for the explosion tests where the dust was loaded in all three entries compared with dust loaded only in the center entry% but in both cases the flame was stopped within the barrier zone. The concentrated barrier was also successful in stopping flame propagation m both explosion tests. From the full-scale experimental mine test results, it can be concluded that both bagged barrier designs were effective in stopping coal dust explosions in the multiple entries of the LLEM.

By R. Karl Zipf

Use of Salamon's stability criterion in underground mine design can prevent the occurrence of catastrophic domino-type pillar failure. Evaluating the criterion requires computation of the local mine stiffness and knowledge of the post failure behavior of pillars. This paper summarizes the status of the practical use of this important criterion and suggests important research to improve our capabilities. Analytical and numerical methods are used to compute the local mine stiffness. Work to date in computing local mine stiffness relies mainly on elastic continuum models. Further work might investigate local mine stiffness in a discontinuous rock mass using alternative numerical methods. Existing post failure data for coal pillars are summarized, and a simple relationship for determining the postfailure modulus and stiffness of coal pillars is proposed. Little actual postfailure data for noncoal pillars are available; however, numerical models can provide an estimate of post failure stiffness. Important factors controlling postfailure stiffness of rock pillars include the postfailure modulus of the material, end conditions, and width-to-height ratio. Studies show that the nature of the failure process after strength is exceeded can be predicted with numerical models using Salamon's stability criterion; therefore, a method exists to decrease the risk of this type of catastrophic failure. However, the general lack of good data on the postfailure behavior of actual mine pillars is a major obstacle. Additional back-analyses of failed and stable case histories in conjunction with laboratory testing and numerical modeling are essential to improve our ability to apply the stability criterion.

Jan 5, 1999

By Deno Pappas, Gregory Molinda, Eric Bauer, Christopher Mark, Daniel Babich

Groundfalls are much more likely to occur in coal mine intersections than in entries. NIOSH is using the experience of U.S. coal mines to determine the factors which influence intersection instability and provide guidelines for the safe excavation and support of intersections. Detailed field investigations have resulted in a database of U.S. coal mines containing 12 mines and 639 roof falls so far. By using the roof fall rate as the outcome variable, correlations between roof geology (CMRR), intersection span, and roof support have been established. Case studies have indicated that replacing 3- way intersections with 4-way intersections may not reduce the total number of roof falls. Additionally, the size of intersection spans tend to decrease with lower (weaker) CMRR. Protocols have been established for the collections of roof bolt parameters. The performance of individual roof bolts can now be tracked with roof fall rate.

By Jeanne A. Zimmer, Charles D. Taylor, Edward D. Thimons

Strategies for monitoring methane levels during roof bolting in an extended cut entry were evaluated. Testing was conducted at the Pittsburgh Research Laboratory’s methane test gallery. Operating conditions were varied and methane releases at the face and drill holes were simulated. Methane readings were taken at the face, and at locations outby the face. Results show that, when the major source of methane was at the drill holes, the highest methane readings were at locations on or 6.1 m (20ft) inby the bolting machine. Methods for selecting better outby sampling locations, when the majority of the methane is released at the face, are examined. During roof bolting it is easier to sample at these outby locations rather than at the face. Further testing is needed to determine what relationship exists between methane concentrations at the outby locations and at the source of the methane release.

In Maryland, coal mining is confined to Garrett County and the western portion of Allegany .County. Terrain in both counties is predominately level with rolling hills; state law prohibits surface mining in steep slope areas. The Conemaugh and Allegany geologic formations contain five major minable fields or basins. These include: Upper Youghiogheny, Lower Youghiogheny, Castleman, Upper Potomac, and Georges Creek. Maryland's coal reserves are estimated to exceed one billion tons. Approximately 490 million tons of bituminous coal are considered recoverable using conventional mining methods. After World War 11, deep mining declined in Maryland, and by 1977 surface mining accounted for 91 percent of the total production. Since then, production at underground mines has recovered, accounting for 69 percent of the coal production in 1991. Maryland's permanent regulatory program was fully approved February 18, 1982. Its Abandoned Mine Land Program was approved June 16,1982.

Jan 1, 1992

By J. C. Edwards

Fire experiments were conducted in the Safety Research Coal Mine (SRCM) at the National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory, with coal, diesel-fuel, electrical-cable, conveyor-belt, and metal-cutting fire sources to determine the response of fire sensors to products-of-combustion (POC). Metal oxide semiconductor (MOS) and smoke fire sensors demonstrated an earlier fire detection capability than a CO sensor. This capability was of particular significance for a conveyor-belt fire in which the optical visibility was reduced to 1.52 m with an increase in CO of less than 2 ppm at a distance of 148 m from the fire. Application of a neural-network program to the sensor responses from each type of fire source resulted in correct classifications of coal, diesel-fuel, cable, belt, and metal-cutting combustion with a mean of 96% of the test data correctly classified.

Jan 1, 2000

By Joseph A. Holmes

The perpetuation of the supply of anthracite coal in Pennsylvania is a national as well as a State problem. Any investigation that shows how larger percentages of this coal may be saved in mining, without excessive cost, and without dangerous subsidence of the overlying surface ground, has a national as well as a local interest. Messrs. Conner and Griffith, who conducted the investigations described in this report largely for the city of Scranton, are consulting engineers for the Bureau of Mines for investigations similar to those they have already made in connection with their Scranton work; and this report is published by the bureau in response to numerous requests, because of the fact that the information it contains will prove useful in the general solution of similar problems in many of the country's coal fields. A study of the accompanying maps will show that the city of Scranton is underlain by 11 separate beds of coal, varying in thick- ness from 2 to 24 feet. It is estimated that before mining opera- tions were begun these beds of coal contained underneath the present city limits of Scranton 600,000,000 tons of coal. The 27 collieries operating within the city limits, working independently of each other, had excavated and removed, up to March, 1911, an aggregate of 198,000,000 cubic yards of coal and accompanying rock, or 3,000,000 cubic yards more than the total amount of material excavated and to be excavated by the United States in constructing the Panama Canal. This fact illustrates something of the magnitude of the problem that the city of Scranton, with the aid of these engineers and of a special commission or advisory board, has undertaken to solve. The excavation has included 177,000,000 tons of coal and 44,000,000 tons of rock and accompanying refuse. This leaves about 420,000,000 tons of coal still to be removed. As a result of other investigations and of experience in adjacent anthracite mines, Messrs. Conner and Griffith and the advisory board of engineers have advised that, as far as may be necessary to prevent dangerous surface subsidence, the spaces remaining beneath the city of Scranton from the excavation of the above-described material should be filled with sand and other materials by flushing or other processes. This operation is expensive, but it is believed to be not beyond the reach of what is practicable, nor in excess of the value of the coal that may be removed and the amount of damages that may result from the caving in of the surface if such a plan is not carried out. No one realizes so fully as do the authors of this report the need of additional tests and other investigations before the data now pre- sented by them can be fully accepted as sufficient for all purposes in the solution of the problem; and it is expected that at some early date a more extensive series of similar tests can be made by the Bureau of Mines under the supervision of Messrs. Conner and Griffith on a larger scale and under a greater variety of conditions. The field examinations made for the Bureau of Mines by N. H. Darton, which are described briefly in a chapter of this bulletin and will be discussed at length in a bulletin to be published later, indicate the extent and distribution of the sands, gravels, and other materials in the Scranton-Wilkes-Barre district available for flushing purposes if further tests indicate their relative merits; and it is expected that the relative merits of these different materials will soon be tested under such conditions as will furnish the desired information.

Jan 1, 1912

By H. A. Doerner

The Rare and Precious Metals Station of the U. S. Bureau of Mines has investigated several cases in which widely divergent amounts of molybdenum were reported by a number of custom laboratories to which quartered portions of the same sample had been sent for analysis . On an oxidized lead ore containing considerable vanadium and a little molybdenum , the amount of the latter reported ranged from 3.14 to 0.24 per cent M003 . The high results were due to the fact that vanadium was estimated with , and reported as , molybdenum . When analyzed by the method described in this paper , 0.15 per cent Moog was found, which is a fair agreement with the lowest figure previously reported . In another and more unusual example , a fine- grained rock containing considerable graphite was submitted for analysis . As a white residue could not be obtained by treating this material with acid , several chemists decomposed the ore by a prolonged fusion with soda ash and nitre and leached the melt with hot water in crder to insure the dissolution of any and all the molybdenum present . After precipitating and filtering the silica from the solution , acetic acid , ammonium acetate , and lead acetate were added to precipitate lead molybdate . The solution contained phosphorous derived from the ore , which precipitated as lead phosphate . The latter was mistaken for , and reported as , molybdenum. As two different chemists used essentially the same procedure , their results , although incorrect , checked . Other chemists using different methods found no molybdenum . From these and other instances it is evident that reputable and conscientious assayers may make serious errors in determining molybdenum, and even duplication of results by different chemists does not necessarily insure against error . The elements most likely to cause trouble are vanadium, tungsten, uranium , arsenic , antimony , titanium, tin , phosphorous , and chromium . The precautions necessary to eliminate these and other impurities vary with the type of ore and the method of analysis . Most texts present methods of limited application and omit or fail to emphasize adequately such precautions . No one method can be given that will best fit every case , but the following procedure has been selected as being the simplest reliable method for such occasional determinations of molybdenum in an ore as are encountered in customs work.

Sep 1, 1930

By L. C. IlsLey

A preliminary investigation has recently been made by the U. S. Bureau of Mines to determine whether or not the ordinary mine- type telephone is entirely safe in gaseous atmospheres . Two well known makes of mine- type phones were purchased for this investigation . It is not conceivable that the current necessary for talking over telephones could ignite gas . However , such phones are provided with efficient magnetos , and it was believed that danger might result from the ringing of the magneto . Again , while this type of phone has been designed to have a certain measure of dust and moisture tightness , evidently it has not been designed as an explosion- proof device . either with regard to cover joints and fastenings or strength of castings . Therefore , the problem was simplified . First it was assumed that owing to the construction of the telephones the gas would penetrate into their interior , and the question was to ascertain whether or not the gas would be ignited from the operation of the magneto .

Jan 1, 1922

By G. Molinda, D. Dolinar

Each year, about 2,000 falls of supported roof occur in the more than 800 underground U.S. coal mines. Therefore to help improve the design of primary support systems, the National Institute for Occupational Safety and Health (NIOSH) conducted a nationwide study of roof falls in over 2,500 km of roadways at 37 coal mines. Information on the roof falls as well as other geotechnical, mining, geologic and roof bolting factors were collected and quantified Then a multi variate statistical analysis was conducted on the data with the roof fall rate being the outcome variable The results were used to derive preliminary design guidelines for predicting the roof bolt length, capacity, and pattern required to effectively reduce the roof fall rate. The equations are fairly limited by a relatively high statistical variance in the data. Also reported is a recent survey of U.S roof bolt manufacturers that shows a significant change in bolt types used over the last ten years.

"Correlatina Lung Crackle Usina Holographic lnterf erometryAli Afshari, MS, West Virginia University, 1989The Effect or Surfactants on Suppression of Non-Wettable ParticlesAli Alaboyun, MS, Mineral Engineering, The Pennsylvania State University, 1989Geochemical Characterization of Kerogem, ShaJes, and Coal .Refme ~ted with Allegheny Fonnationof Cases of Northern West VirginiaDick Andre, MS, West Virginia University, 1987Particle Concentrations in a Hazelton Inhalation ChamberShahram Bavani, MS, West Virginia University, 1985Use and Potential of Luer Holographic Interferometry and Subsidence Model Study of an Underground.Room and Pillar MineRichard Begley, MS, West Virginia University, 1984Development of a Mechanistic Model for Prediction of Subsidence in a Longwall MineRichard Begley, PhD, West Virginia University, 1990.Redesign of Micro-Orifice Unifonn Deposit ImpactorSteve Behm, MS, University of Minnesota, 1991A Fracture Mechanics Study of Crack Propagation Mechanism in Coal: The Mechanics of Fine FragmentFonnationZ. T. Bieniawski and R. Karl Zipf, Jr., Mining Engineering Department, The Pennsylvania State University,University Park, PA. Final Report, October 1, 1988A Mathematical Model for the Prediction of Ambient Dust Concentrations in Mine AtmospheresR. Bhaskar, MS, Mining Engineering and Operations Research, The Pennsylvania State University, 1984Spatial and Temporal Behavior of Dust in Mines-Theoretical and Experimental StudiesR. Bhaskar, PhD, Mining Engineering, The Pennsylvania State University, 1987Experimental Studies of Dispersion and Deposition of Fane Particles in a Wind Tunnel and Mine AirwayKlaus Bode, MS, Mining Engineering, The Pennsylvania State University, 1991Perf'onnance of the High Yield Technology PM - 100 - Particle 11ux MonitorRobert Caldow, MS, University of Minnesota, 1987Development of Improved Methods for Monitoring and Control of Diesel Particulate in an Underground CoalMineD. H. Carlson, B. C. Cornilsen, P. L. Loyselk, X. Shan and J. H. Johnson, Michigan Technological University,Houghton, Ml. Final Report, June 15, 1991"

Mar 1, 1992

By V. P. Bhavanandan, S. B. Dubbs

The mucus secreted in the respiratory tract provides the first barrier against inhaled particulate and gaseous toxicants. The major component of mucus which is responsible for the physical properties and protective functions of the respiratory mucus is mucin. We have initiated investigations to determine the effects of coal mine dust on the synthesis of respiratory mucin by rat trachea under in vitro and in vivo conditions. In this study we have established optimum conditions-:ro-r~ the asceptic growth and mucin secretion of rat tracheal explants in culture. The best outgrowth of ciliated epithelial cells and maximum mucin production was obtained in CMRL 1066 medium containing 10% fetal calf serum. The explants continued to secrete mucin even after three weeks in culture. For the estimation and characterization of mucins the tracheae were cultured in the presence of [3H] glucosamine and [35S] sulfate or [14C]leucine. The mucins were isolated from the medium by gel filtration, treatment with hyaluronidase, ion exchange chromatography and CsBr density gradient centrifugation. Precipitation of polyanionic material in the culture media with cetyl pyridinium chloride and fractional extraction with NaCl also yielded mucin free of glycosaminoglycans, but in low yields. The tritium label in the purified mucin was distributed in sialic acid (50%) galactosamine (37%) and glucosamaine (13%). The density of purified mucin as determined by CsBr gradient centrifugation was about l.43g per ml in comparison to l.46g per ml for human respiratory mucin with a carbohydrate content of about 80% by weight. Alkaline borohydride treatment released saccharides which contained about 80% of the radioactivity. The effect of adding varying amounts of coal dust to the culture medium is under investigation. (Supported by U.S. Bureau of Mines Grant G1135142, Project 4210).

Jan 1, 1989

By H. H. Storch

Methane is the chief constituent of natural gas, and large quantities of it are also obtained in coke-oven gas and in the off-gases from cracking higher hydrocarbons. Perhaps the most important potential chemical use of methane is in the production of higher hydro- carbons, both aliphatic and aromatic. The results of a relatively large number of researches have been published in the technical and patent literature on the thermal decomposition of methane, the objective being an industrial process for the production of "antiknock" motor fuel. No industrially feasible process has, however, been developed. An inspection of the literature on this subject indicates that the chief difficulty in the way of accomplishing this object lies in controlling the decomposition so that undesirable products are eliminated. A considerable number of quantitative experiments have been reported, the results of which provide only a vague and confusing picture of the various steps in the thermal decomposition of methane. The reaction mechanism has not been subjected to rigorous fundamental study, and the necessity for such a study is obvious if further progress is to be made. The thermal decomposition is only one of the reactions of methane which are of potential industrial importance and which require further fundamental investigation. The oxidation, hydrolysis, and halogenation of methane are other reactions which must be studied further. In view of the importance of methane as a raw material for various industrially desirable products, it is appropriate that a survey be made of the important facts concerning the physical and chemical properties of methane which will serve as an aid in subsequent experi- mental work. No attempt will be made to present a complete chronological review, but rather a condensed critical description of the important literature will be presented.

Jan 1, 1932

By J. D. Davis

Coke Since the beginning of manufacturing of metallurgical coke in the United States, which dates from about 1859, Pennsylvania has main tamed supremacy in coke production Available statistics for the year 1880 show an output of 3,338,300 short tons, which was neatly trebled by the end of the succeeding 10 years. From this time on the increase was steady, though not rapid, and in 1922 the total production was 13,991,892 tons, which is approximately 37 per cent of the total coke production of the United States. The main reason for the rapid development of the coke industry in Pennsylvania lies in the abundance of coals particularly adapted to beehive coking, for which purpose the Pittsburgh bed in the Connellsville district has long been looked upon as standard At first practically all metallurgical coke was made in beehive ovens, the only exception being the short lived and wasteful method of coking in piles, byproduct owns did not make then appearance until after 1893 The suitability of a beehive coking coal cannot be accurately predicted from its chemical analysis, but it can be said, perhaps, that the volatile matter should be about 32 per cent, and that the oxygen content should not be mole than 10 pet cent or less than 4 per cent The sulphur and phosphorus content should be small-not over 1 25 per cent sulphur and under 0 02 pen cent phosphorus-and the ash content should not be over 7 per cent The Pittsburgh bed at Connellsvnlle fills these requirements well, as may be seen from the following representative analysis. Analysts of coal from Pittsburgh bed Moisture 1 70 Volatile matter 31 10 Fixed carbon 59 80 Ash 7 40 Sulphur 0 85 B t u 13,990

Jan 1, 1928

By D. B. Starkey

Investigation into the expressions of the field produced by a loop over a conducting half space or in an infinite conducting half space are well documented. Reasonably complex descriptions of the effects of stratification also are reported. However, a model which must contain all of these complexities because of transmission to depths of 15,000 feet and also include the pertibation of the field by a verticle cylindrical steel casing loses its facility in the field or for quick, accurate approximation to field magnitudes and phase. This paper describes the results of two field tests to determine the attenuation and phase versus depth and frequency of an electromagnetic wave (induction field). A simple two-layer model is postulated to predict the magnitude and phase of the induced field which does not require sophisticated computing tools. Correlation of the model with experimental results show agreement of most amplitude measurements to within 3 db and most phase measurements to within five degrees. The tests were conducted in a 7400 foot deep well in Nevada and an 11,000 foot deep well in Wyoming which had conductivities ranging from .0025 mhos/m to .25 mhos/m. The surface transmitting dipole had an area of ~ 10 6 feet squared and constant frequency signals of 1.5 Hz to 20 Hz were transmitted through the earth utilizing less than 65 watts of power. Model Description The magnetic field intensity components generated by a magnetic dipole immersed in an infinite homogeneous medium can be expressed in spherical coordinates as: [ ] where N, I, and (p a ) are the transmitting antenna turns, current, and effective area, respectively, and r is the range from the loops circumference to the measurement point. The case of interest for these experiments, however, is the special case of coaxial dipoles, i.e., ? = 180° . For this case H?= 0 and H reduces to: [ ]

Jan 1, 1973

By G. S. Scott

The flammability of trichloroethylene vapors in air has been determined in a 7-inch cyclindrical vessel. Saturated flammable mixtures were formed with air at atmospheric pressure between 30° C (86° F) and 82° C (180° F); the trichloroethylene concentrations at these temperatures are 12.5 (lower) and 90 (upper) volume-percent, respectively. Further study is necessary to assess the effects of different variables on the flammability of this material. INTRODUCTION Trichloroethylene (TCE) (ClHC = CCl2), sold under various trade names (Blacosolv, Perm-A-Clor, Tri, Triad, Triclene, Trivec, Tromex, Vapoclean, Vapoclor, Westrosol, etc.), is an important industrial chemical. A summary of its physical and chemical properties is given in table 1. It is used to degrease metals, leather, and textiles, to extract residual oils from vegetable oil cakes, for dry cleaning, and in soap. It is a powerful solvent for fats, resins, bitumens, rubber, sulfur, and phosphorus. Several explosions in which trichloroethylene was involved prompted an investigation by the Bureau of Mines to determine the conditions under which such accidents can occur.

Jan 1, 1963