Search Documents

By B. J. Dalton

The Bureau of Mines Helium Research Center has as a long-range objective the development of an equation of state for helium that will allow all of the thermodynamic properties to be calculated within the accuracy with which they are known. If this objective is to be realized, a method of calculation must be known. This report gives the principles of the method we use in such problems. A computer program was developed for predicting these properties, including those at the critical point, that is perfectly general and applicable to any equation of state. To demonstrate the efficacy of our method, this computer program was used to evaluate thermodynamic properties of a Redlich-Kwong fluid in the two-phase region. Expressions for calculating various thermodynamic functions specific for this particular equation of state are derived. Numerical values are tabulated and graphs are presented for all functions calculated. It is shown that for a Redlich-Kwong fluid there are finite discontinuities in (1) the second temperature derivative of the Gibbs free energy or chemical potential at the critical point, (2) the second derivative of the vapor pressure curve with regard to the temperature on passing through the critical point, and (3) the measured heat capacity at constant volume on passing through the critical temperature when the calorimeter is filled to the critical density. It is also shown that the heat of vaporization is infinite for a Redlich-Kwong fluid at absolute zero.

Jan 1, 1969

By L. A. Stewart

"SUMMARYThis paper describes most of the chrysotile-asbestos deposits of Arizona. Mining methods are discussed briefly and asbestos-mill flowsheets are incorporated. Arizona asbestos mines are the only sources on the American continents of naturally iron-free chrysotile spinning fiber that is so urgently needed for electric-cable coverings, especially on warships.Asbestos was first recorded and recognized in Arizona in 1872, and a minor amount was produced from a deposit in the Grand Canyon in 1900. The discovery of a deposit in the Salt River district in 1912 initiated intensive prospecting, and deposits soon were developed. The total Arizona production of all grades of asbestos through 1953 is estimated at 30,000 to 35,000 tons.The deposits of the Central Arizona region, which are discussed in this paper, are scattered over nearly 2,000 square miles. The annual output is relatively small, because the asbestos occurs in thin, discontinuous veins and only in areas where intrusions of diabase are adjacent to or crosscut certain favorable units of the pre-Cambrian Mescal limestone. This stratigraphic limitation, combined with other essential geologic conditions, tends to restrict the size of the deposits.Virtually all of the deposits are in rugged, mountainous country, and many of the mines are on steep canyon walls. In the average mine, production of 1 ton of commercial asbestos requires removal of 30 to 40 tons of waste rock. Mining and transportation costs consequently are high.Several deposits of chrysotile that is somewhat harsh and of moderate tensile strength have been known for years but were not worked because of the former exacting demands of industry for high-strength, soft asbestos. However, improve¬ments in asbestos fiberization and spinning technique, combined with the urgent need for asbestos, have made this so-called semisoft fiber desirable, and deposits of this type now are being exploited."

Jan 1, 1955

By James H. Russell

The Bureau of Mines, U.S. Department of the Interior, in cooperation with the Department of Energy, has attempted to increase the activity of nickel catalysts for converting synthesis gas, derived from coal, to a substitute natural gas. This report describes the effects of low-level additions of B, Ca, Ce, Co, Mn, Mo, Pd, Re, Ti, Y, Zn, and Zr on the methanation activity of Raney nickel. The methanation rate at 320° C and the resistance to poisoning by 2 ppm H2S were used to compare catalysts. The effects of the additions were small, and the experimental variances were large, necessitating the use of statistical methods to identify significant effects. Co, Ti, Y, and Zn improved the resistance to H2S poisoning, but only Co improved the methanation rate In some individual catalysts containing Ca, Mo, or Mn, both the methanation rate and resistance to H2S poisoning were improved.

Jan 1, 1980

By E. J. Gleim

A list of permissible mine equipment, tested and approved previous to January 1, 1942, was published In Bureau of Mines Information Circular 7207.3/ The present list covers additional equipment approved during the calendar year 1942. The items have been numbered to indicate the order in which each type of machine or device was approved in its particular classification. Thus, Information Circular 7207 gives four air compressors on the Bureau's active list, and the present circular gives the fifth to be approved. Items 90 and 94 under Loading; Machines land Conveyors also appear in Information Circular 7207. These numbers are repeated hero to show that approval was granted during 1942 for additional voltages on machines previously listed one voltage only. Equipment listed in these circulars is approved by the Bureau of Mines only when found upon inspection and test to comply with minimum standards of safety as outlined in schedules prepared on the basis of many years of experience in dealing with safety problems of the coal-mining industry. The use of such equipment in mines known to be gassy, as well as in those which may become so, is earnestly recommended in the interests of safety. This circular is published so that the industry may be kept informed as to the many types of machines, devices, and lamps that arc available for reducing explosion and other hazards incidental to coal mining. The present paper and Information Circular 7207 together give the complete list of all available permissible .Mine equipment.

Jan 1, 1943

By Rose L. Ballard

This chapter summarizes data on crude nonfuel mineral production for the United States, its island possessions, and the Commonwealth of Puerto Rico. Included also are the tables that show the principal nonfuel mineral commodities exported from and imported into the United States and that compare world and U.S. mineral production. The detailed data from which these tables were derived are contained in the individual commodity chapters of Volume I and in the State chapters of Volume II of this edition of the Minerals Yearbook. Although crude mineral production may be measured at any of several stages of extraction and processing, the stage of measurement used in this chapter is what is normally termed "mine output." It usually refers to minerals or ores in the form in which they are first extracted from the ground, but customarily includes the output from auxiliary processing at or near the mines.

Jan 1, 1985

By Barry W. Klein

The performance of the U.S. economy in 1977 was similar to that in 1976 which, in turn, had been a considerable improvement over 1974-75. In 1977 real gross national product (GNP) showed a similar, but some-what slower, growth pattern compared with 1976. Real GNP increased sharply in the first quarter of the year followed by smaller increases for the remaining three quarters. With only two exceptions, the monthly unemployment rate declined or remained steady throughout 1977, falling to a low for the year in December. The inflation rate in 1977 was slightly higher than in 1976, but the rate still remained far below that of 1974-75. Total U.S. output as measured by GNP in current dollars rose 10.8% in 1977. Real GNP in constant 1972 dollars increased 4.9%, and inflation, as measured by the implicit price deflator, rose 5.6%. In real terms, gross private domestic investment for residential structures increased 19.3% in 1977, only slightly below the 22.9% rise in 1976; State and local government expenditures increased 1.1 % in 1977; and personal consumption expenditures for services rose 4.5%.

Jan 1, 1980

By A. M. Stubbs

The Bureau of Mines has devised a procedure to selectively extract and recover chromic oxide (Cr203) from waste high-temperature shift catalysts that contain approximately 6 pct Cr and 62 pct Fe, both in oxide form. The Bureau's procedure consists of roasting the waste catalyst with sodium hydroxide (NaOH) or sodium carbonate (Na2C03) followed by water leaching. The chromium from the leach liquor was recovered utilizing an oxidation-reduction reaction with pH adjustment to form a hydrous chromic oxide (Crp3oXHp) precipitate. The roast-leach procedure produced chromium extractions greater than 89.7 pct, with product recovery in excess of 99 pct from the leach liquor. The costs of the NaOH and Na2C03 roast processes, including sizing and equipment-related recommendations, were determined by the Bureau's Office of Process Evaluation. The economic evaluation indicates that producing a Crp3 product, at the present time, is not competitive with the present-day cost of imported chromites. The estimated average operating cost for both processes was $5.44/1b of recovered Cr203 concentrate. However, this procedure offers a potential alternative to the disposal of this waste through landfiIl.

Jan 1, 1988

By W. M. Weigel

"Sand is one of the most useful and, fortunately, one of the most common mineral commodities. By far the largest proportion of the production is used in construction, including all forms of building, concrete and paving, sand for this purpose is produced in every State in appreciable amounts. Excluding send used for railroad ballast, molding sand stands not in tonnage produced, followed by glass sand.Special sands. In addition to the above, many grades of sands, with special characteristics, are used in industrial processes, and may be classed in a group as ""special sends"". This includes filter sand, sand blast sand, engine sand, abrasive send, fire or furnace send, special flooring sand, roofing sand used as a finish for prepared roofings and pottery placing sand sand blast and filter sand have been discussed in previous reports.Very few send companies depend upon the production of any one of these grades, as their source of revenue. They are generally especially prepared from the bank run of sand by different methods of screening or washing, or may, in some instances, be by-products from the production of ether grades. Many companies not now producing them might be able to supply local demands by a slight addition to their plant. In nearly all cases, they command a better price than the usual grades of building sand.Definitions and Properties.Engine sand, or traction sand, as it is sometimes called, is used to prevent the slipping of the driving wheels of locomotives, or other self-propelled vehicles, on wet or slippery rails. Its greatest use is, of course, for railroad locomotives, but street cars use considerable amounts and mine locomotives require its use. As the send must be very dry when used, most consumers have their can drying equipment, so it is often shipped damp, with its natural water content on what resulting from washing by the producer."

Oct 1, 1924

By Syd S. Peng

The design of retort interchamber pillars is important in determining surface stability over in situ retort mines and to the health and safety of miners, particularly with respect to possible escape of heat and toxic gases from retort chambers. Stress distribution in retort interchamber pillars, roof, and floor was examined with the aid of linear, finite-element analysis using data from experimentally determined mechanical properties. Properties determined included elastic moduli, strength, and creep constants in laboratory tests on core covering a 100-foot depth interval in the oil shale from the Piceance Basin in Colorado. The most critical stress concentration was found in the rib side of the interchamber pillar at a height above the floor line of 1.25 times the width. Guidelines for pillar design that consider pillar strength, creep, and retorting temperature effects are proposed.

Jan 1, 1981

By Jacqueline H. Jansky

The Bureau of Mines conducted a study to determine the relation-ship between geologic features and linears. Cleats, kettlebottoms, and roof rolls were mapped and superimposed on the linear plots for a coal mine in West Virginia. No clear relationships were evident. This may be due, in part, to the mining practice of leaving head coal, which obscures geologic features that may exist in the roof. Future studies should concentrate on mines where roof is extensively exposed.

Jan 1, 1982

By W. W. Odell

"It has long been recognized that coke is a more desirable fuel than bituminous coal in water-gas apparatus of present design, but still considerable headway has been made in the use of the latter fuel as a substiaute for coke. This is particularly true in the Central States where the supply of high-grade coke has been very limited and uncertain during the past few years, and where coking coals of low sulphur content were available in quan¬tities. In fact, with, the present difference in price of coal and coke, it is possible to realize a marked saving when using a coking bituminous coal as generator fuel.Difficulties have been encountered in the use of such fuel, but they have, to a large extent, been overcome. One of the chief obstacles in the use of the more general utilization of bituminous coal for water-gas manufacture, is the fact that, with normal operation, the capacity per unit of time is reduced. This of course is a serious problem for plants operat¬ing at capacity with coke fuel. However, this difficulty can, to a large extent, be remedied by a changed method of operating, and can be entirely remedied by a combination of the latter with a change in the design (or proportions) of a water-gas set. The preceding statement, the reader will understand, refers more particularly to a carburetted water-gas set.In the manufacture of water gas from coke, present practice requires that for continuous 24-hour service the heat of combustion of all the carbon monoxide (CO) generated during the air blow be utilized in addition to the sensible heat of the gas coming from the generator. This is doubly true when making carburetted water gas from bituminous coking coal. The reasons why this is so are apparent when the following factors are considered."

Nov 1, 1920

By Joseph Cervik, Gerald L. Finfinger

This Bureau of Mines publication reviews underground methane drainage pro- grams being conducted in various coalbeds. Equipment used in drainage programs such as drills, underground pipelines, and methane monitoring systems is described.

Jan 1, 1980

By D. H. Chambers

Digestion studies were undertaken to develop a method for the rapid dissolution of high-temperature ferroalloy scrap. Laboratory tests showed: (1) dissolution of alloy scrap with ferric ion as the leaching agent was a moderately rapid method of digestion; (2) the dissolution process can be considered as a typical reaction of a metal with chlorine gas, although evidence was obtained to show dissolution as a two-step process, one step as the reduction of ferric ion by the soluble alloy constituents and the other as the oxidation of ferrous ion with chlorine gas; and (3) the attack of ferric ion on the alloy was a function of alloy composition, ferric to ferrous ion ratio, and area of contact between leach solution and alloy. The exceedingly complex nature of alloy compositions and dissolution products generally precluded satisfactory analytical determinations. Results of moderate accuracy were obtained using complex modifications of standard analytical and spectrographic techniques.

Jan 1, 1968

By H. W. Kilau

The U.S. Bureau of Mines examined the wettability of bituminous and subbituminous coals before and after exposure to ambient air atmosphere, as part of an ongoing project investigating the coal-wetting abilities of surfactant solutions intended for the suppression of dust during coal mining operations. Exposure periods were generally 7 days or less, and the changes in wetting response were measured with a capillary penetration apparatus. Wetting solutions tested included a nonionic surfactant, two anionic surfactants, and pure distilled water. After exposure, higher ranked bituminous coals treated with nonionic surfactant solution and pure water showed increased wettability, but lower ranked subbituminous coals showed decreased wettability. With the anionic surfactants, the coals demonstrated opposite responses. The wettability changes appeared to be related to the coal moisture content. These changes may be amplified by specific, but incompletely understood, interactions between surfactant polar groups, absorbed water, and the coal surface.

Jan 1, 1989

By T. E. Gray

This report describes the preparation characteristics of the significant coalbeds in Boone County, W. Va., as determined by the Bureau of Mines. It is one of a series describing the coals suitable for producing metallurgical coke, either as mined or after beneficiation. Over 6.3 million tons of coal was produced in Boone County, W. Va., in 1959, of which almost 5.5 million tons was mechanically cleaned in eight preparation plants. On December 31, 1959, it was estimated that almost 8 billion tons of coal remained in the county in beds 24 inches or more in thickness. Thirteen samples were collected from nine coalbeds and washability tests were made on these samples.

Jan 1, 1961

By Jack C. White

As part of an investigation of the production of alumina by the nitric acid leaching of kaolinitic clay, the Bureau of Mines designed, built, and tested a fluidized-bed system for the calcination of aluminum nitrate nonahydrate to alumina, while recovering nitric acid. The calciner consisted of an 8-in-square by 36-in-tall vessel containing 18 in of fluidized solids. Molten aluminum nitrate, sprayed directly into the fluidized solids, formed sandy, granular alumina by growth of successive layers on fluidized particles. Solids were fluidized in a dense bed at temperatures of 250° to 500° C with steam, air, or mixtures thereof. Decomposition of nitrate ranged from 4 to 10 pet during single-pass steam or air fluidization, respectively. Alumina dust losses and low throughput are significant unsolved problem areas.

Jan 1, 1982

By R. D. Leitch

Tests have recently been conducted by the Bureau of wines on the ignition hazard of exposing heated filaments of electric mine lam bulbs in an explosive mixture of methane and air. This investigation was undertaken in order to settle a question that had arisen in connection with the safety of miners? electric lamps. For several years, in view of former studies made by the Bureau and reported in Bulletin 524, the fact that the heated filaments of even low voltage, lour candlepower bulbs constitute a danger was generally accepted by the Bureau's engineers. These early tests, as well as subsequent tests, were conducted with Pittsburgh natural was as the testing medium.

Jan 1, 1925

By Charles Vaught

This is the second in a series of four articles that discuss underground firefighting preparedness. As with the first article in the May-June issue, it is based on interviews with 214 miners conducted at 7 underground mines (?A? through ?G?) by researchers of the National Institute for Occupational Safety and Health?s (NIOSH) Pittsburgh Research Center [Vaught et al. 1996].In the first article, the authors presented an overview of the study conducted by NIOSH on mine fire response preparedness and provided a general perspective on underground mine fires. In this article, we will describe miners? preparedness to evacuate a fire and their experience with incipient fires.

Jan 1, 1997

By J. E. Zeilinger

This Bureau of Mines report describes the preparation characteristics of the significant coalbeds of Clarion County, Pa. Of the 15 samples collected, 1 was of metallurgical quality as received, 4 could be sufficiently upgraded to provide acceptable products, and the remaining 10 samples could not be upgraded to metallurgical quality because their sulfur contents could not be lowered to meet the standard. For steam or power generation, 1 sample was of low sulfur content as received, 1 sample could be upgraded to low sulfur content, and 10 samples could be upgraded to medium sulfur content. The original sulfur content of the remaining three samples can be appreciably reduced by removal of the sink 1.58 specific gravity material; however, these coals would be classified as medium sulfur coals both before and after removal of the sink material.

Jan 1, 1968

By Robert L. Crosby

The Bureau of Mines investigated the substitution of cement copper powder for commercial copper powder in an Fe-7 pct Cu-l pct C powder metallurgy alloy. Copper powders from six different commercial cementation operations were separately upgraded by screening and hydrogen reduction. They were then mixed with commercial iron and graphite powders to form the Fe-7 pct Cu-l pct C alloy. Various chemical and physical properties were determined on the upgraded cement copper and the alloy powders. Mechanical, physical, and chemical properties were determined on green and sintered specimens made from the alloy powders. Mean tensile and bending strength of sintered specimens were significantly lower than the means from specimens made from commercial metal powders. The lower strengths are apparently related to poor sinterability.

Jan 1, 1970