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By D. J. Bauer

A solvent-extraction system employing selective stripping of a pre loaded organic phase was investigated for recovering Sm203 from a light-group rare-earth mixture. The samarium concentrated in the organic phase, and a >99-pct-pure samarium oxide product was obtained at 76-pct recovery in a 20-stage operation using di(2-ethylhexyl) phosphoric acid (EHPA) as the organic phase. The stripping agent was a 1.5-pct hydrochloric acid solution containing 200 g NH4C1/1.

Jan 1, 1972

By Edward D. Thimons

The Bureau of Mines conducted a state-of-the-art study of techniques currently employed to close large openings in underground mines. A large opening was considered to be any opening over 10 feet high and having a cross section of at least 200 square feet. Five salt mines and one limestone mine were visited to observe various methods of sealing large openings. Because of the variations in conditions from mine to mine, no definite conclusions could be drawn as to which is the best method. In mines where waste material is available, stoppings built by piling waste material are efficient and economical. Where waste material is not available properly constructed brattice cloth stoppings are superior to those built from wood, concrete block, or urethane foams.

Jan 1, 1975

By Oliver Bowles

This report covers the character, properties, origin, occurrence, and uses of the traprocks and describes briefly the methods and equipment employed in quarrying and preparing them for market. Production of traprock occupies an important place in industry. In 1960 the output in the form of crushed stone reached nearly 58 million tons valued at $87 million. Traprocks are also shaped into blocks of dimension stone for monuments, building construction and decoration, and specialized products such as surface plates.

Jan 1, 1963

By Oliver Bowles

This report covers the character, properties, origin, occurrence, and uses of the traprocks and describes briefly the methods and equipment employed in quarrying and preparing them for market. Production of traprock occupies an important place in industry. In 1960 the output in the form of crushed stone reached nearly 58 million tons valued at $87 million. Traprocks are also shaped into blocks of dimension stone for monuments, building construction and decoration, and specialized products such as surface plates.

Jan 1, 1963

By J. B. Gayle

Coke-pushing difficulties have been the subject of much controversy but relatively little scientific investigation. Nevertheless, continuing pushing difficulties can greatly decrease the life of a coke oven and should therefore be considered in the selection of the blend and operating conditions used for coke production. The present Federal Bureau of Mines investigation was undertaken to correlate results of previous investigators and to supplement these results to the limited extent practical by us of an experimental slot-type oven. To this end, pushing pressures have been determined routinely for Tuscaloosa oven tests conducted during the past 10 years. Nevertheless, the accumulated information remains incomplete in many respects, and in view of the recognized inadequacies of the data, publication is now undertaken only because of the scarcity of published information on this important problem and the discontinuation of carbonization studies with this oven.

Jan 1, 1961

By L. A. Grant

This paper describing the concentrator practice of the Montana Mines Corporation at Helena. Mont., is one of a series of articles on milling methods and costs being prepared by the United States Bureau of Mines. The Spring Hill mine and mill are located 4 miles south and west of Helena, Mont., near the head of Grizzly Gulch. The mine portal is on the east slope of the gulch, and the mill is directly opposite on the west slope. Grizzly Gulch is one of the tyro gulches which unite at the south end of Helena to form Last Chance Gulch, on which the main street of Helena is built.

Jan 1, 1931

By E. J. HOFFMAN, J. c. W. FRAZER

The apparatus and methods described in the following pages were devised and used by the writers in connection with certain investiga- tions of the technologic branch of the United States Geological Sur- vey, especially those bearing on the improvement of furnace condi- tions and on efficiency in the use of fuel. The Bureau of Mines, which has charge of such analyses and tests of fuels as were formerly made by the technologic branch of the Sur- vey, is using the same apparatus and methods in connection with similar investigations that are being carried on at the testing plant of the bureau at Pittsburg, Pa. The furnace conditions prevailing both in small plants and in large industrial establishments in this country are frequently far from satisfactory. If such conditions are to be improved, they must be more thoroughly understood, and means must be found to insure complete combustion of the fuel, and yet to permit operation with such an excess of air as will result in the greatest efficiency. In this work the services of the chemist are indispensable. A very important problem is the determination of the small percentage of unburned combustible matter that escapes from the furnace in the flue gases. Under ordinary circumstances so little as 0.1 per cent of unburned combustible matter in a furnace gas is equivalent to about 1 per cent of the fuel used; and for the determination of such small percentages of gas more accurate and refined methods are required than have ordinarily been available heretofore. It is the purpose of this paper to describe some apparatus and methods which have proved satisfactory to those engaged in the chemical work of the investigations mentioned. While these methods and apparatus have been designed more particularly with regard to analysis of furnace gases, their use is by no means limited to that purpose. The reader will readily see their applicability to other uses in which the sampling and analysis of gases are involved.

Jan 1, 1911

By I. AITKENS

The basic mining law of Cuba is contained in the basic Spanish mining decree having the effect of law December 29 , 1868. This legislation has remained substantially unchanged , with the exception of a few minor administrative changes made by the present Government . These changes provide for the register of mines , oil wells , and operations of such nature , and also provide for the keeping of records showing the value of minerals taken out . By Royal decree of April 17 , 1883 , the law of mines enacted for the Peninsula ( Spain ) on July 6 , 1859 , and the General Bases of December 29 , 1868 , were declared in force in Cuba . In order to encourage the mining of iron org , in 1883 the Crow of Spain issued a royal decree to the following effect.

Jul 1, 1931

By L. Mark Irwin, R. A. Marsyla

The objective of this laboratory investigation was to develop a mattesmelting process for the recovery of copper from industrial smelter dusts . Experimentation was conducted on three samples of Cottrell precipitator dust from a northern Michigan smelter with variations in the following conditions : Temperature , charge composition , pelletization , and moisture content . Based on chemical analyses of the furnace slags , poorest recovery of copper was effected in smelting dry charges regardless of composition . Some improvement was noted with uniformly moistened charges and still more with pelletized (but dry) mixes , but best results were obtained from smelting moist , self - fluxing pellets . Under favorable conditions , experiments yielded furnace slags with an average copper content of only 0.15 percent , which is well below that of industrial copper reverberatory slags .

Jan 1, 1963

By Ernest V. Deshayes

The Colorado Minerals Co. calcite properties in Archuleta and Hinsdale Counties, Colo., (fig. 1) were examined by Bureau of Mines engineers in 1943. The demand for optical calcite during the war prompted the examinations and resulting development programs on the Meadows and Seavy ranch properties near Pagosa Springs, Archuleta County. Development was begun on the Meadows property in November 1943 and continued to the Seavy ranch property. The work consisted of stripping the overburden from the calcite areas and excavating pits and trenches with a bulldozer. The pits and trenches exposing the most promising calcite veins were then deepened by hand, and one shaft was sunk to a depth of 30 feet. A total of 36 trenches and 9 pits were excavated by bulldozer and. hand methods (figs. 2, 3, and 4). The calcite deposits occur as veins and irregular bodies filling fractures in the Mancos shale of Cretaceous age. The fractures persist for considerable distances along the strike, although the calcite filling may not be continuous for more than a few feet. The widths of individual veins range from a few inches to several feet. The calcite crystals uncovered at the surface and in pits, trenches, and shafts were found to be unsuitable for optical purposes because of fracturing and color in the crystals.

Jan 1, 1949

By Ralph B. Adair

The Bureau of Mines conducted laboratory and continuous pilot plant flotation tests to determine the feasibility of recovering commercial-grade mica from an Alabama graphitic-mica schist. Preconcentration of the ground ore on a Humphrey's spiral was employed to reject the heavy minerals and part of the quartz in a product virtually free of mica. The acid-cationic mica flotation process recovered over 89 percent of the mica in a product containing 98.7 percent mica. Grinding of the mica concentrate in a fluid energy mill produced a product with a bulk density of 12 lb per cubic foot.

Jan 1, 1969

By C. E. Munroe

In order to meet the emergencies of the world wr, tne quantities of explosivea produced in the Unitecl States, and the number of explosives plants were onti:.1.1.:l,lly ncreased so that when the armistice was declared the Government had on hand larg ..mounts oi militazy explosives in excess of existing military needs. Tle stor3.gs of these explosives entailed a liirge expense and their protection neessitatei the employment of m'3.l'lY men who could be better employed otherwise in the military estlish.11ent. Moreover, mar.y ex.ploives, like QJ.l other material, deteriorate on prolonged storage, They lose tht precise definiteness of properties and behavior on which reliance· is placed in military operations, The continued expen3e and d3.nger ttending storage of theae explosives might be diminished by dcst1et1on of the surplus beyond immediate needs, but such·deetniction is danger• ou5 qnd coetly. Hence, the evident solution o! the problem was the salvage d prompt ut111zation of the ru.rplua •

Aug 1, 1922

By J. E. Miller

This paper reports experimental determinations by the Bureau of Mines of compressibility factors to 4,000 pounds per square inch absolute (p.s.i.a.) for helium at temperatures from -10° to 130° F. and for 16 helium-nitrogen mixtures at 70° F. This information is needed for computing accurate discharge volumes and is necessary for determining an average-density value for use in orifice-meter formulas. In thermodynamic calculations, several functions of the compressibility factor with pressure and temperature are required. The data in the original publications (6, 8)5 of this study have been reexamined and have been given a more comprehensive treatment. The recalculated compressibility factors are higher by approximately 0.2 percent because in the earlier work a linear relationship between the compressibility factor of helium and pressure was assumed.

Jan 1, 1961

By George R. McCormick

Because several new and unusual synthetic minerals were found in the system MgO-MgF₂ - SiO2 with Li * , or Nat a similar system with Geo₂ replacing Sio , plus Lit was investigated . In addition to the expected compounds of germanium , Ge - fluor - hectorite and a Ge - fluor- chrysotile were synthesized . Protoamphibole was not observed . Data are given for 69 compositions prepared in the system MgO- MgF₂ - Ge02 at 6.94 percent LiF .

Jan 1, 1964

By Andrew J. Fergus

The purpose of this study was to provide basic information to aid further research on beryllium mineral flotation. Contact-angle and microflotation (Hallimond tube) methods were used to study collector action and flotation response of beryllium minerals and associated gangue minerals with representative commercial surfactants. Chrysoberyl received prime attention. Results indicated that selective flotation of beryl and chrysoberyl from fluorite and quartz is possible with sodium isooctyl phosphate below pH 2, and fluorite and topaz are readily collected by both anionic and cationic surfactants. Several modifying reagents were studied at one pH and one level of collector concentration. Aluminum sulfate, starch, and sodium silicate proved to be depressants in chrysoberyl flotation.

Jan 1, 1968

By H. C. Fuller

Depletion of iron ore in the Nation's large deposits has directed attention to other sources. One of these is the titaniferous iron ore of the Iron Mountain, Wyo., area. Tests were made to determine the feasibility of smelting this ore, which contains about 20 percent titanium dioxide (Ti02), in an electric-arc furnace to produce pig iron. Initial tests, which were made in a 30-pound-capacity induction furnace, demonstrated that the iron could be easily reduced to metal and that limestone was a suitable and effective flux. Larger scale tests then were made in a 50-pound-capacity electric-arc furnace to obtain the more detailed information necessary for the planned continuous operation of a still larger arc furnace. The principal facts determined by preliminary batch-smelting studies were that (1) 9 pounds of limestone flux was required for each 100 pounds of ore smelted, (2) expensive coke was not required because coal proved to be a satisfactory reductant (near stoichiometric carbon was optimum), and (3) overreduction, which produced a viscous slag, must be avoided.

Jan 1, 1961

By Martin H. Stanczyk, I. L. Feld

Continuous open - circuit attrition grinding of a coarse commercial kaolin to produce paper - coating clay , which must have a particle size analysis of 70 percent or more minus 2 - micron equivalent spherical diameter ( esd ) , was studied by the Bureau . The coarse clay , containing about 11 percent minus 2 -micron esd material , was ground in a 10 - inch- diameter attrition grinder using continuous single- and multiple - stage grinding circuits . The clay feed rates varied from 10 to 480 pounds per hour . In some tests , the influence of varying loads of sand grinding media on particle size reduction was studied . Batch grinding tests also were made for comparative purposes . Multiple- stage grinding gave better results than single - stage treatment when equivalent raw clay feed rates were used . In the best test made , a product containing about 80 percent minus 2 - micron esd material was obtained when grinding 60 pounds of raw clay per hour using a three - stage grinding circuit . Power consumption in the test was about 318 kilowatt -hours per ton of clay treated or 475 kilowatt - hours per ton of minus 2 - micron esd material produced .

Jan 1, 1963

By R. P. Maloney

The economic viability of four depleted mines near Kennicott, Alaska, was determined by the Bureau of Mines to assess their profitability if they were developed today and thus estimate cost data for a medium-sized mine, mill, and town complex. This information should help the State and Federal Governments appraise the potential development of similar-sized mining operations in Alaska. Modern conventional mining and milling techniques were assumed, and I capital and operating costs were derived using flowsheets and standard costing methods. A total capital investment of $37.6 million was necessary to install a 1,000-ton-per-day shrinkage stope mine, flotation-type mill, and support facilities; capital requirements were divided about evenly among the three components. Operating costs, including labor, supplies, power, water, and ' indirect and fixed costs, totaled $42.79 per ton of ore; the mining accounted for nearly one-half the cost. To obtain a 12-percent discounted cash flow rate of return on investment, the analysis showed that the ore could be mined and milled, and the concentrate could be trucked via public roads to a dock facility in Valdez, Alaska, barged to Tacoma, Wash., and smelted and refined for 34.7 cents per pound for copper and 104.0 cents per ounce for silver. The average May 1972 price was 52.6 cents for copper and 158.3 cents for silver. The same set of data was used to examine the economic viability of the mine with the cost of constructing a private road from McCarthy, Alaska, To Valdez, Alaska. The 148-mile road added $53.3 million to the original capital costs and raised the required price of copper to 57.4 cents per pound and the required price of silver to 172.0 cents per ounce. The additional coat of building, maintaining, and paying taxes on a private road from McCarthy, Alaska, to Valdez, Alaska, would make this venture uneconomical.

Jan 1, 1973

By M. J. Ferrante

The Bureau of Mines recovered rhenium powder from scrap tungsten alloy containing approximately 25 percent rhenium. Oxidation of the scrap at 950° C separated volatile rhenium heptoxide from tungsten trioxide. Minor amounts of tungsten, iron, and nickel were removed by selective precipitation from a rhenium solution from which was recovered crystalline ammonium perrhenate. Experimentation showed that hydrogen reduction of minus 325-mesh ammonium perrhenate at 1,000° C produced rhenium powder averaging 2.1 microns in size (Fisher Sub-Sieve method). The powder contained <50 ppm of total metallic impurities and 1,070 ppm of total interstitial impurities. Sintered compacts had a density of 95 percent of theoretical. Approximately 96 percent of the rhenium contained in the scrap alloy was recovered.

Jan 1, 1969

By P. M. Sullivan

This report describes a new application of electroamalgam metallurgy in recovering all the zinc as refined metal from galvanizers&apos; sal skimmings. Pure zinc was recovered by electrolysis of skimmings leach liquors in amalgam cells. The following information was gained as a result of literature studies and subsequent laboratory investigations. 1. Reports in the literature indicate that pure zinc can be recovered from chloride solutions with the aid of amalgam cells. From Europe it was reported that amalgam cells could be used to recover pure zinc and chlorine from leach liquor obtained from pyrite cinders following a chloridizing roast.

Jan 1, 1956