Search Documents

This study examines the surface alteration and flotation behaviour of synthetic moncheite, PtPd(BiTe)2, in the presence of pentlandite. The telluride minerals contribute around 20% ~ 30% and up to 45% of the PGM present in the Platreef ore and are considered to be slow floating as there is evidence of these minerals reporting to the tailings. It was proposed that oxidation products from other minerals and grinding media would affect the mineral surface composition and floatability thereby causing inadvertent depression of moncheite due to precipitating ions. ToF-SIMS analyses (time of flight secondary ion mass spectrometry) was used to characterise the mineral surface as well as the extent of surface alteration. Microflotation was used to deter-mine the hydrophobicity of the synthetic minerals. Conditioning of moncheite in the presence of pentlandite reduced the flotation response of the + 38 -106µm size fraction from > 99% to 56%. This was due to pentlandite dissolution products (iron and nickel hydroxy species) which formed overlayers on the mineral surfaces thereby inhibiting the adsorption of collector. In addition, further grinding of these samples, with and without pentlandite conditioning showed a negative effect on recovery due to the fineness of the particle size distribution and there was no advantage gained from any possible exposure of fresh sites in the sample.

Jan 1, 2014

By M. Kadiyski, V. Stoyanova, E. Visariev, V. Stoilov

"The present study deals with copper losses in slag from copper smelting. Copper slag cooling at Aurubis Bulgaria is traditionally done in pits. A new type of slag-cooling is introduced in the site, involving cooling ladles. In a previous study, the ladle cooling process was studied in detail, showing an improvement in the recovery of copper in the slag after flotation. The main reason for better recovery of copper is the increased cooling time, which allows for the accumulation and aggregation of copper droplets. The effects of the newly introduced slag cooling process are studied using optical microscopy and scanning electron microscopy. Cooling in pits and in ladles is compared, based on copper droplet size, distribution and content. Specialized image processing software is employed on images taken with an optical microscope. The results are then compared with a similar technique, available in SEM software. The availability of phase-analysing image software in combination with electron dispersive X-ray spectroscopy makes it possible to study the morphological properties, distribution and chemical composition of the copper droplets. The obtained results confirm the initial conclusions about size, distribution and composition of the copper-bearing particles. A large amount of copper particles is examined showing an obvious increase in their size from pit- to ladle cooling. The results show an increase in the average size of the droplets, which doubles from pit-cooling to ladle-cooling. There is a well-pronounced tendency of decrease of the percentage of droplets in the smallest fraction (<5 µm) in the ladle-cooled slag. In addition, the number of droplets in the larger fractions increases, compared to the ones in the pit-cooled slags. It is believed, that the developed methodology for analysis provides a relatively quick and reliable solution for comparison of the cooling rates in the slag. INTRODUCTION In the process of copper smelting and converting, iron-silicate slags are produced that contain various amounts of dissolved and entrained copper. Different physical and chemical techniques are employed for the valorisation of the remaining metals in the slag – magnetic separation, leaching, roasting, flotation, etc. According to Gorai et al (2003), about 2.2 tons of slag is produced per ton of metal. In 2016, about 20 million tons of copper have been produced globally (www.icsg.org). At an average of 0.5 percent copper content after treatment, these slags contain more than two hundred thousand tons of copper which is lost due to inefficient processing."

Jan 1, 2018

By O. D. Khmelnitskaya

The research on selecting of an efficient technology of pyrite cinders complex treatment, sulfuric acid production wastes, have been made. The grades in the initial product were 2.04 g Au/t, 35.0 g Ag /t, 0.38%Cu, 1.1% Zn. Laboratory tests on cyanide technology, thiourea and sulphite leaching were carried out. Magnetic and flotation beneficiation and biohydrometallurgical technology were tested. After considering the results of the tests, the most economically efficient technology of pyrite cinders complex treatment with cyanide leaching of precious metals was determined. The technology involves water washing of soluble copper and zinc compounds, lime treatment and cyanide leaching of gold and silver, detoxification and utilization of mineral wastes. The precious metals are recovered from solutions by cementation onto zinc. Copper is recovered from rinse waters by SW/EW and then zinc is precipitated as hydroxide. All the solutions and organic agent are used in recirculation and therefore the technology is practically waste-free. Mineral wastes can be used as iron-containing materials for cement industry. The technology has been tested in pilot-plant scale under continuous operation with complete re-circulation of cyanide solutions. In this process recovery of 54% Au, 45% Ag, 30% Cu and 50% Zn has been achieved.

Jan 1, 2014

By N. A. Dementyeva

To improve gold recovery from preg-robbing carbonaceous ores a technology including gravity, flotation, recleaning of the flotation concentrate, intensive cyanidation of the gravity concentrate and carbon-in-leach (CIL) process for intensive cyanidation tailings and the recleaned concentrate was developed. The final flotation tailings are shipped to tailings disposal. Total gold recovery by the proposed technology from the ore with the head grade of 0.8 g/t was 83.9%. The gold loading onto the activated carbon from CIL process was 6.5 g/kg.

Jan 1, 2014

By Jihoe Kwon, Daeyang Lee, Mario Fujimura-Kashiwagui, Heechan Cho

"Calcium carbonate is one of the most widely used mineral in today&apos;s industries such as plastic, paper and pigment. There are many essential physicochemical properties required by each industry field but the most common requisite is size. One way to achieve appropriate size is grinding. Grinding is typically an energy intensive process, consuming about 40% of total energy cost in mineral process. Due to that reason, optimization of grinding process is a critical element to achieve price competitiveness. Two different type of grinding apparatus were hired to find out optimum condition in terms of energy efficiency. Utilizing samples containing 10, 20, 30 and 40% solids concentrations, a 1l batch type attrition mill was operated as the first grinding step at various operating speed with 1? to 5? grinding media in order to study the optimum operating conditions to reach submicron particles. Next, a 0.15l vertical beads mill was tested as next step with 100? to 500? grinding media to study the optimum conditions in the submicron range. Net energy and the specific energy input was measured to reach stated size ranges. Also, using a back-calculation based on the population balance model further operating conditions were studied. There were several competitive combinations which showed significant energy efficiency improvement when compared with the single step grinding."

Jan 1, 2014

By Shailin Lalloo, Allan B. Nesbitt

A fluidised bed was exposed to high gravities by placing it in a centrifuge. The bed expansions were measured and compared with the bed expansions predicted by the Richardson-Zaki model (1954). The Richardson-Zaki model was found to predict effectively the fluidisation behaviour of defined particles in this increased gravity environment.

Jan 1, 2003

By M. L. Liu

This work reports the results about the determination of mean activity coefficients and relative partial molar free energies for copper sulfide mineral bioleaching solutions by potentiometric method at 25ºC. The experimental potentiometric data were obtained by combining a solid state membrane-cupric ion selective electrode (Cu2+ ISE), containing a KNO3 filling solution, and an Ag/AgCl electrode. The measurements were performed in different series of copper sulfide mineral bioleaching solutions. The non-ideal behavior of the system was described on the base of the Pitzer ion-interaction model for mixed salts. Meanwhile, the relative partial molar free energies of bioleaching solution were investigated. The determination of the thermodynamic properties offers a basic data for the study of copper sulfide mineral bioleaching solutions.

Jan 1, 2014

By T. M. Bhatti

The main purpose of present study was to characterize the dissolution of uranium from low-grade black shale with indigenous isolated strain of Acidithiobacillus ferrooxidans (BSAF-01). The nature of shale is quartzite-schistose and contains uranium content of 0.005% U3O8 (50 ppm U3O8). Uranium is present in the tetravalent oxidation state (U4+) in the shale matrix. The main minerals identified are graphite, quartz, pyrite, mica minerals (phlogopite, biotite, sericite, and chlorite), microcline, K-feldspar and kerogen (hydrocarbon-compounds). Bacterial oxidation of pyrite was an acid-generating system and produced sulfuric acid and ferric sulfate during this biological phenomenon. A series of bioleaching experiments were conducted in shake flasks for leaching of uranium from black shale. The leaching experiments were performed at 50% pulp density using indigenous Fe- and S-oxidizing bacterium (Acidithiobacillus ferrooxidans). Bioleaching data revealed that about 90% ~ 95% U3O8 was leached out from black shale ore. Uranium dissolution from shale depends on pH (pH 1.5~1.9), redox potential (=500 mev) and the concentration of Fe2+ and Fe3+ ions in the leaching environment. The oxidative leaching of U4+ involves a redox reaction with Fe3+ as an oxidant and bacterial re-oxidation of Fe2+ in acidic leaching environment. Uranium leaching efficiency was attributed to the sulfuric acid and ferric sulfate production during bacterial oxidation of pyrite.

Jan 1, 2014

By A. Qaredaqi, M. Mohammadi

Wet High Intensity Magnetic Separators, for short, WHIMS are used for recovery of Iron ores with low magnetic susceptibility. A Jones patent WHIMS with "grooved plates" matrix is being used in Dry Tailing processing line in Hematite Recovery Plant at Golgohar mining & Industrial Co. for recovery of Hematite. In this kind of separators Matrices are used for increasing the Magnetic field intensity and providing high magnetic field gradient. The laboratory WHIMS in Golgohar Iron Ore and Steel research Institute is capable to provide a background magnetic field strength up to 0.85 Tesla and in presence of ‚expanded metal? matrix, magnetic field intensity could increase up to 0.9 Tesla. More than 50% of feed particles in this separator were finer than 36 micron and recovery of these particles needs more magnetic field intensity. Hence, ‚Grooved Plates? matrices with Js= 2 Tesla and 3.8 mm gap were constructed. Measurements indicated that magnetic field intensity around the matrix will increase to 1.25 Tesla. Graph of Magnetic field intensity around the matrix to background magnetic field intensity was plotted and a model with Rsquare= 0.9 was offered. In addition, magnetic field gradient and magnetic force were calculated. In WHIMS with feed top size of 150 micron, the main effective forces on separation process are the magnetic force and the hydrodynamic drag force. With assuming that the particles are smooth and spherical and the flow is laminar, Recovery of fine magnetic particles is problematic in this separator because of drag force. Considering these facts and mentioned model, finest particles that are recoverable in different magnetic field intensities were calculated. Computations illustrated that with magnetic field intensity more than 0.8 Tesla, particles as fine as 4 micron are theoretically separable but it should be noted that in practice a larger attractable particle size would be expected.

Jan 1, 2014

By G. M. Savov

Copper recovery via Solvent Extraction (SX) process is a well-known technique, which is practiced commercially for approximately 40 years. The main advantages of the SX process are: an absence of using high temperatures (not more than 50oC), complete recycling of barren solutions, very high selectivity at removal and purification of metals, metal conversion to a form, suitable for easy subsequent recovery. Despite the wide acceptance of Solvent Extraction, it does have some shortcomings, namely SX employs large quantities of volatile organic substances. This leads to huge plant ?footprint? of SX circuits. The SX is very sensitive to low temperatures and quantity of total suspended solids in feed solutions and this causes bad phase disengagement times and therefore poor process performance. And most important ? low grade solutions (with copper concentrations below 1 gram per litre) are very unattractive for treatment via Solvent Extraction process, because capital costs for SX plants are not a direct function of copper tenor in the feed. The combined process with Ion Exchange (IX) and Solvent Extraction ? further called IX/SX by IONTECH Engineering was developed. This combination eliminates SX negative characteristics shown above. The key findings of the IX/SX process are; (1) recovery of copper from pregnant leach solutions with metal concentrations, varying on a broad range; (2) can be operate effectively with very low-graded copper pregnant leach solutions; (3) the construction of large ponds for pre-filtration of the pregnant leach solutions is not necessary; (4) working with turbid solutions and solutions containing large quantities of suspended solids; (5) winter operation without troubles; (6) strongly reduces organic losses; (7) technological approach lead to plant sizes reducing. This paper reviews the main stages of the combined IX/SX process, the applications for metal recovery and introduces projects where the process is applied. Key findings of the process are also presented. A comprehensive technical comparison between processes has been carried out. This paper also evaluates the advantages of using combined IX/SX technology as a purification and separation step in copper production process, with the aim of further increasing the overall copper recovery and to ensure that a suitable copper concentration in the advanced electrolyte is achieved. The implementation of a Ion Exchange (IX) process in the classic Solvent Extraction-Electrowinning process(SX/EW) is found to be beneficial for processing of pregnant leach solutions both from spent and new copper heaps and dumps, acid mine drainage and other industrial streams without any preconditioning as well as in terms of achieving improved recoveries and copper cathode quality.

Sep 1, 2012

By Y. B. Zhang

China is rich in iron ore resources, but most of these ores are low-grade, polymetallic and refrac-tory ones. Furthermore, with the rapid development of chinese iron & steel industry, the comprehen-sive recovery of these ores is becoming more and more important. The tin, zinc-containing complex iron ores are typical polymetallic and intractable ones, and great reserves of them are found in China. At present, they have not been efficiently utilized. In this paper, based on the investigation of basic physicochemical properties of the tin, zinc-bearing iron concentrates, taken from a mineral processing plant, the mineralogy reason that these concentrates are so intractable and refractory is found out, using advanced microscopic testing methods, such as optical microscope (OM), Scanning Electronic Microscope (SEM), X-ray diffrac-tion (XRD), etc. It is found that the symbiotic relationship of iron, tin and zinc metallic minerals are very complicated, and magnetite in the concentrate is closely symbiotic or enwrapped by fine cassi-terite and sphalerite. So it is difficult to separate tin and zinc completely from the iron concentrates by simple regrinding and physical separation method. This investigation provides theoretical guid-ance for developing new approaches for utilizing these concentrates.

Jan 1, 2014

By Lev O. Filippov, Inna V. Filippova

"Flotation of metal-organic precipitate in column is sensible to the hydrodynamic conditions determined by the diameter and the dispersion of rising bubbles. Thus, the dissipation energy in the system resulting of ratio between superficial fluid velocities (gas and feed) in the column is the main parameter for precipitate flotation in pilot or industrial scales. The suggested limiting factor is the aggregate stability under the turbulence created by the rising bubbles. The stability of precipitate is related to the structural organisation of aggregates, which determines the size distribution of particles during precipitation and flotation stages.Structural evolution of Mo precipitate and the destruction phenomenon were described by using of the various fractal dimensions. The fractal studies allow the detection of a structural scaled organisation of the precipitate flocs. The fractal dimension of the particle mass distribution Dm=1.94+/-0.15 suggests, for the floc structure, a cluster-cluster aggregation process either with restructuring or breakage phases.The destruction process, which occurs for the lowest values of the dissipation energy E (0.02 . 0.05 W/kg) was characterised by a fractal dimension Dg of size distribution. Besides, the destruction of floc produces very fine particles, and thus induces the difficulties of bubble-particle collision during the precipitate flotation in column."

Jan 1, 2003

By C. Suazo, O. Alruiz, A. Hofmann, I. Fernandez, W. Kracht, N. Mora

"Compañía Minera Dona Inés de Collahuasi, CMDIC, has developed a methodology that allows estimating economic benefit taking into account the variability of the ore characteristics (geometallurgical models). Currently, the grinding model allows predicting the treatment capacity, specific power and balls consumption for short, mid and long term planning. An alternative impact test to estimate SAG grinding parameters is presented in order to bring the geometallurgical model from mid and long term to short term planning. The impact test uses either the production bench or geological drill holes. This allows Geologists increasing the density of grinding parameters within the block model improving the geostatistical estimation of the rest of the blocks. The test requires a small amount of sample to obtain the requires grinding parameters for the grinding model in comparison to the well known grinding test and also, it can be performed easily and quickly by the geology team of a mining company. The alternative grinding test is presented in this article. The grinding model using this short grinding test has been successfully used in mining planning and the accuracy of the model is demonstrated using monthly average instantaneous throughput from January 2013 to March 2014, showing an average relative error of 5% and an R2 value of 0.9. Also, 111 individual variability samples were divided into two each, in order to compare the estimated grinding parameters based on this alternative test to the grinding parameters obtained from the conventional grinding test. The comparison shows an average relative error of 4% and an R2 value of 0.9."

Jan 1, 2014

By G. Y. Zhou

During Zijinshan copper heap bioleaching, pyrite was leached in plenty resulting in high ferric concentration in solution. It has affected bioleaching and extraction processing greatly. It results much acid and iron in solution and bad effect to extraction processing. The paper studied the influence factors in the course of pyrite leaching and ferric ion chemical oxidation, especially studied the redox potential for copper bioleaching so as to find key factors affecting the dissolution difference between chalcocite and pyrite. The results show that the redox potential is important factor. Copper and pyrite leaching rates are 95% and 11% respectively and there is great dissolution difference between them at redox potential 700 mV (SHE). During pyrite bioleaching, the indirect action of bacteria gives priority to bioleaching cooperating with the direct attack of microbial cells attached to the mineral surface. Redox potential is determined by ratio of ferric and ferrous, ferric in solution was supplied by the way of oxidation of T. f bacteria, sufficient bacteria concentration and active character were two vial factors of controlling redox potential. It is indicated that copper can be selectively bioleached during copper bioleaching by controlling redox potential of bioleaching. The conclusion will provide theoretic foundation on balance of acid and iron during bioleaching for copper of higher S/Cu ratio. The experinment proved that bacteria activation was decreased on condition of both low pH value and intermittent aeratation during bioleaching. It resulted that the oxidation velocity of ferrous ion was decreased and redox potential was controlled. The dissolution of pyrite was depressed. It would be possible to actualize selective leaching of secondary sulfide copper ore during bioleaching process.

Jan 1, 2014

By J. Gong

Fine mineral particles pose two challenging problems in froth flotation, i.e., ineffective recovery of fine hydrophobic particles and mechanical entrainment of fine hydrophilic particles. The first problem has attracted much research effort while the second problem has received much less attention. We have recently proposed a method to deal with mechanical entrainment, i.e., utilizing the flocculating power of polymeric depressants to flocculate fine gangue particles and making the flocs big enough so that the mechanical entrainment of these particles can be reduced or eliminated. In this paper, we report results on the use of polyethylene oxide (PEO) in controlling quartz gangue in the flotation of sulphide ores. PEO was found to flocculate fine quartz and lower its entrainment. It was also found to modify air/water interfacial properties and acted as a frother, which could increase gangue entrainment. Nevertheless, when used at starvation dosages, PEO was found to significantly improve the grades of the floated sulphide concentrates.

Jan 1, 2014

By Avinash Tripathi

It is now well known that the size distribution of the particulate solid has a significant effect on the breakage behavior of particles in the wet as well as dry modes of ball milling operation. In the context of the size discretized batch grinding kinetic model, grinding behavior of particles is characterized by the breakage rate parameters, k, and breakage distribution parameters, B. Understanding the nature of variation of these two sets of parameters with particle size distribution is important for simulation and control of operation of production mills. However, so far it has not been possible to track the variation of both the set of parameters with grinding time simultaneously. In this paper an attempt has been made in this direction by using a modified functional form approach with time dependent constants. Keywords: dry and wet ball milling, breakage rate and distribution parameters, effect of particle size distribution

Sep 1, 2012

In the present work, the influence of coagulant, polymeric flocculant structure type and mode of addition on flocculation performance and dewatering behaviour of plant mineral waste tailings of diverse mineralogy (kaolin, quartz, goethite/hematite feldspar, gibbsite, rutile, and Illite) is investigated. High molecular weight, non-ionic polyacrylamide homopolymer and anionic (acrylate) and cationic (quaternary acrylate) copolymers were used in orthokinetic flocculation of colloidal-ly-stable, aqueous dispersion of negatively charged particles. It is demonstrated that, through prudent selection and mode of addition of polymer structure types, synergistic effect between certain cationic and anionic flocculants can be readily achieved, leading to significantly improved dewaterability of the heterogeneous mineral waste tailings.

Jan 1, 2014

By Jacob Masliyah, Zhenghe Xu, Lujie Yan

"Understanding adsorption mechanism of polymeric organic process modifierssuch as carboxymethyl cellulose (CMC) on talc hasbeen a major challenge due to anisotropic nature of talc basal planes and edge surfaces. The main objective of this study is to investigate the adsorption of CMC on the basal planes and edge surfaces of talc.Smooth basal plane and edge surfaces of talc were prepared successfully by simple cleavage and sophisticated ultramicrotome cutting method, respectively. The prepared surfaces were characterized by atomic force microscope (AFM) imaging to be sufficiently smooth for colloidal probe force measurements using AFM. Anisotropic surface charge characteristics were determined,with the basal planes to carry a permanent negative surface charge and edge surfaces featuring a pH-dependent charge characteristic. The adsorption of CMC on talc basal plane and edge surfaces at pH 9 in KClaqueous solutions of various ionic strengths wasinvestigated by in situ AFM imaging technique. Themorphology of adsorbed CMC on talc basal planes and edge surfaces was found to be significantly different, due to different binding mechanisms involved. Interaction of CMC with the talc basal plane was found to bedominated by hydrophobic interactions while its binding with the talc edge surface was mainly through chemical complexation and hydrogen bond. The amount of CMC adsorbed on both talc basal planes and edge surfaces increased with increasing ionic strengthof solutions. The methodology developed in our study opens the door to probe polymer adsorption on anisotropic phyllosilicate surfaces, which can help us better understand the mechanism of polymer adsorption on specific mineral faces."

Jan 1, 2014

By Per Svedensten

One of the most significant behaviour of a crushing plant is the constant variation in the process. The variation is caused by two major effects. The first and constantly changing is the rock material properties. During operation rock material with different strength and particle size distribution is fed to the plant which makes the performance of the equipment to vary. The second and more slowly changing variation is caused by wear on the processing equipment. These effects must be predicted in order to be able to optimise a crushing plant. This paper demonstrates how Monte Carlo simulation can be utilised to study and operate crush-ing plants. By introducing Monte Carlo simulation the varying process can be study and also optimised. To maintain the optimised process performance supervision is needed. This paper demonstrates how results from the Monte Carlo simulation can be utilised for process supervision. Charts for process measurements can for example be derived. These can then be used to guide decision making and understand how the variation and performance of the plant changes over time.

Jan 1, 2014

In this study, selective flocculating of diaspore using anion macromolecular reagent as flocculant was tested to separate diaspore from alum-silicate minerals. Firstly, the effect of pH on settling behavior of diaspore and kaolinite dispersions has been investigated. The results show that the maximum settling speed of diaspore and kaolinite appeared re-spectively at pH7 and pH3.33 which is close to the point of zero charge (PZC) of diaspore (6.8) and kaolinite(3.5). This result is in well agreement with the double electric layer theory. Secondly, the settling behavior of diaspore and kaolinite particles in different anion flocculant solution have been researched. The results indicate that flocculant solution concentration significantly affect the selectivity and the flocculating performance of anion molecular. In high concentration solution, both diaspore and kaolinite have faster settling rate compared to blank solution. How-ever, in low concentration solution, the anion macromolecular can enhance the settling rate of diaspore remarkably but has no apparent effect on the settling rate of kaolinite. This result suggests that the tested anion flocculant is a promising reagent for de-silica of diasporic bauxite. Lastly, FTIR method was employed to probe the adsorption mechanism of flocculant on diaspore and kaolinite. The results reveal that there are anion flocculant characteristic bands on the spectra of diaspore but no obvious characteristic bands of flocculant on the FTIR spectrum of kaolinite. This result is in good correspondence with settling test.

Jan 1, 2014