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Grinding with an electrochemically inert grinding media (i.e. high chrome white iron, or Magotteaux’s Duromax® alloys) shifts the pulp potentials to more oxidising conditions, increases the dissolved oxygen content and reduces the EDTA extractable iron concentration when compared with milling with electrochemically active grinding media (forged steel). These changes in pulp chemistry produce cleaner particle surfaces, reduce reagent consumption and increase concentrate grades and recoveries. This paper presents a robust laboratory test program that is able to not only demonstrates these effects but also provide an indication of the magnitude of the improvements that are possible. While laboratory studies are interesting, the proof is in the pudding! So, the paper provides an overview of plant trials conducted at a number of operations around the world, including: Newcrest’s Cadia Operation, Oz Minerals’ Prominent Hill Mine and Glencore’s Ernest Henry Mine. These successful plant trials clearly demonstrate that selection of the right grinding media alloy will yield savings in grinding media consumption and reagent consumption as well as increases in revenue through improved copper, gold and molybdenum recoveries. INTRODUCTION The key to a successful separation in mineral processing is the preparation of particles with adequate liberation under the correct pulp chemical conditions. While the importance of liberation on flotation separations is generally understood and well documented in the literature (Johnson, 1987; Jackson, Sutherland, Gottlieb & Quittner, 1989; Young, Pease, Johnson, & Munro, 1997; Greet and Freeman, 2000), the importance of pulp chemistry is more nebulous, particularly with regard to the impact of grinding media. Extensive work examining the electrochemical interactions between grinding media and sulphide minerals has been completed (for example, Iwasaki, Reid, Lex & Smith, 1983; Natarajan and Iwasaki, 1984; Yelloji Rao and Natarajan, 1989(a); Yelloji Rao and Natarajan, 1989(b)). Broadly, these studies indicate that most sulphide minerals are more noble than the grinding media used during comminution, therefore a galvanic couple between the media and the sulphide mineral(s) exists, which increases the corrosion rate of the grinding media. The corrosion products of the grinding media, iron oxy-hydroxide species, invariably precipitate on to the surfaces of the sulphide minerals thereby affecting their floatability (Johnson, 2002).

Jan 1, 2019

By Ana Adé

The use of gold compounds in homogeneous catalysed organic reactions has been undervalued for many years due to the preconceived opinion that gold is an expensive and extremely chemically inert metal. However, recent reports have changed this assessment and gold salts in small amounts are known to display high catalytic activity.[1] Thus, it has been reported recently that anhydrous AuCl3 catalyses the formation of C-C and C-O bonds (usually mediated by hydrochloric and other protonic and Lewis acids).[2] Some examples include Michael type additions, selective cross cycloisomerisation/dimerisation of propargyl or allenyl ketones, benzannulation between o-alkynylbenzaldehides and alkynes or cyclisation of alkenyl furans. It is noteworthy that some of these reactions[2a] can be also catalysed by silver salts but with much lower yields. The 1,3-dipolar cycloaddition of nitrones to alkenes is a powerful synthetic method that has found numerous applications in the synthesis of a variety of carbon frameworks.[3] Several laboratories have focused on the development of Lewis acidic reagents to modulate the selectivity of the reaction.[4] Despite the extensive study performed, there are not many examples in which a metallic complex catalyses the dipolar cycloaddition. Most of these reactions require the presence of a metallic complex and nitrone in a 1:1 molar ratio. Recently, we have carried out stoichiometric reactions of the N-benzil-C(2-pyridil)nitrone, 1, with different dipolarophiles in the presence of zinc and silver compounds.[5] Apart from an increase of the reaction rate and the selective formation of one of the possible isomers, we have shown the formation of zinc and silver-nitrone complexes during the reaction, which behave as the intermediates in the cycloaddition process. As suggested by the results obtained with silver complexes, we decided to test gold derivatives (in the oxidation states of I and III). Interestingly, we have found that they can be used not only as stoichiometric reagents but they can also mediate these cycloadditions in catalytic amounts (5 to 10 mol % respect to the nitrone). Here we present the results on the 1,3-dipolar cycloaddition reaction of the N-benzil-C(2-pyridil)nitrone (2-PyBN), 1, and methylacrilate, 2, (Eq. 1) catalysed by gold(III) derivatives.

Oct 1, 2003

By Scott D. Long

"Abstract-Grass roots exploration has an emphasis on good precision at low (sub-economic) concentrations of an element, in order to identify "anomalies" which may lead to drilling targets. Although it is wise to have well-defined quality controls in place during early stage sampling, the control procedures at this stage tend to be rudimentary. When a deposit warrants detailed delineation, the need for accurate geological characterization and assaying of ore-grade rock must be supported by appropriate quality control procedures.As a project returns more promising results, and the likelihood of the project warranting a prefeasibility study increases, it is time to tighten quality assurance requirements and quality control protocols. Delays in instituting adequate quality control and verification procedures may lead to costly remedial actions that can also delay completion of the prefeasibility or feasibility study. Sometimes, as a project matures, the quality control and quality assurance aspects fail to keep pace with the changing nature of the work: an increasing emphasis on precise and accurate assaying of oregrade rock.A resource model is like a house of cards. The foundation of the house is the geological observations, the sampling methods and the geological interpretations performed upon those samples. Upon the sampling, which includes all the sub-sampling steps of sample preparation, rest the assay results. The quality of the assays can be no better than the quality of the sampling. Good assaying technique will preserve all biases and imprecisions introduced during sampling and sample preparation; it cannot remove them. If the sub-samples and/or assays are bad and must be redone, all the succeeding levels of the house of cards must also be rebuilt, or at least patched up.From geological observations, a geological interpretation is built, the quality of which is critical to the construction of an acceptable resource model. Geological elements are difficult to assess, and are not discussed here; they are dependent upon the expertise of the geologists involved. Geological knowledge contributes essential quality control elements to resource/reserve determinations (Sinclair and Postolski, 1999; Postolski and Sinclair, 1999).This paper consists of five sections: (1) overview of quality control protocols, (2) maintaining quality control of databases, (3) quality control of drill sampling, (4) optimizing crushing and grinding requirements, and (5) quality control of assay data acquisition."

Jan 1, 1998

By Brian Hall

For some years, the mining industry has been consistently delivering returns below the market average. One of the causes is a disconnect between what is perceived to drive value creation by many industry analysts and senior corporate executives, and what actually drives the intrinsic value of mining operations. The perverse effect is that strategies that should increase value are perceived to have the potential to drive share prices down, and vice versa. This paper challenges common perceptions of what drives a mining company?s value. Anecdotal evidence suggests that the key drivers of value in the market, and hence in many boardrooms, are such things as increasing the reserves and production rate, and reducing unit operating cost. However, while the quoted reserves may satisfy ore reserves reporting code requirements to be economic, this does not imply that they are optimal. Often, a proportion of the quoted reserve reduces the potential value of the operation. Metal price increases, increased production rates, and operating cost reductions are all seen as conditions or actions that can improve value, and lead to cutoff grade reductions, thereby increasing ore reserves. However, modern cutoff theory and studies conducted by the author and his colleagues show clearly that, while breakeven cutoff grades will fall in these circumstances, optimum cutoffs may be much less volatile, and may even increase. Results from case studies indicate that value is maximised by right-sizing, not maximising, the production capacities, and by optimising the cutoff strategy. Values of many existing underground mining operations can be increased significantly by a substantial cutoff grade increase. Also, an increase in downside risk, and hence reduced returns, can occur using typical life-of-mine planning strategies if prices received are lower than predicted. Since this is often the case, low industry returns may be a direct result of typical strategic mine planning processes. Relatively simple cost-effective techniques are available to provide senior decision makers with information needed to assess the tradeoffs between their many conflicting corporate goals, and the balance between risk and reward. Often this information is not being generated at all. If it is, decisions affecting the value of the company are occurring by default at relatively low levels within the hierarchy, with senior executives apparently unaware of them or their potential impact. The paper concludes that without a re-evaluation of the way mining projects are valued, to demand proven value optimisation from mining plans by boards and mining analysts, the industry will continue to deliver below average returns.

May 1, 2003

By Philip Peck

Mine closure issues ?Narrow issues: ?Environmental focus; ?Broad issues: ?Social issues and sustainability; ?Continued importance of mining; ?Historical legacies from closed mines; ?Barriers to development; ?Migration [ir]reversibility Dealing with closure issues ?A matter of choice ?Option 1: Engagein solving closure problems as best possible; ?Option 2: Exit, leaving the playing field to firms not interested in solving problems ?Option 3: Delay, till better time to enter or until early entry [by others] fails and pick property up cheap [?].

May 1, 2006

By Linruo Zhao, Qi Yang, Akihiro Sato

TiN coating has a wide range of tribological applications from wear reduction of cutting tools to erosion protection of gas turbine engine compressor components. The performance of TiN coating depends on its microstructure, mechanical properties and adhesion strength which are influenced by the coating deposition process. In this study the effects of cathodic arc deposition conditions on the microstructure, hardness, adhesion and erosion resistance of TiN coating were investigated experimentally. It was found that varying deposition temperature, substrate bias and N2 pressure could derive a processing window in which TiN coating with superior erosion performance can be fabricated.

Jan 1, 2010

By X. Z. Yuan

Contamination introduced by the impurities from the feed stream can impact the PEM fuel cell performance dramatically. The presence of these unwanted trace species such as CO, H2S, NH3, can adversely affect the fuel cell functioning. It has been reported that the major impact of CO and H2S contamination on the fuel cell performance is kinetic while the effect of NH3 contamination is speculated as membrane conductivity reduction only. In this paper, a model regarding the NH3 contamination is described and the mechanism of the NH3 contamination is illuminated by the model calculations.

Jan 1, 2005

By W. Melnyk, L Pokhilenko, J. A. McDonald, A. Hall

The Camsell Lake property comprises 270 000 acres located about 240 kilometres northeast of Yellowknife in the Northwest Territories. Kimberlite has been located in two areas of the property:

Jan 1, 2001

By Amin Jafari

Macrosegregation has always been an important issue with the solidification processes, particularly in Direct-Chill Casting of Aluminum alloys, where uneven properties, surface and bulk defects and limitations in productivity can be arisen due to macrosegregation in the cast product. Following the global attempts to practically predict the macrosegregation, in the present work, a numerical model was developed based on an industrial scale DC casting process to simulate the solidification and macrosegregation in an Al-4.5%Cu billet. Interesting aspects of this investigation are concerned with an efficient numerical scheme to keep simplicity, consistency and desired physical resolution of the solidification phenomena together. In the mathematical model, coupled conservation equations of mass, momentum, energy and species were solved numerically using finite volume method. A different numerical scheme, called SIMTLE, was introduced to link the energy and species equations with the phase diagram of the alloy. Calculations were performed on an industrial case and obtained results were compared to available experimental data to assure the performance of the model. Different macrosegregation features were predicted and discussed on the solidifying Al-alloy billet.

Oct 1, 2011

By Geoff Goodyear

UHNL Corporate Profile ? Providing Helicopter Services since 1963 ? A Newfoundland Company head-quartered in Goose Bay, Labrador ? Operations, while primarily Atlantic Canadian, extend across Canada, the Arctic, Greenland ? 16 aircraft, all single engine / VFR Typical Industry Mission Profiles & Work Environments ? Types of missions include: ? Air Taxi & Executive Transport ? Mineral Exploration ? Forest Fire Suppression ? Medivac ? Wildlife Management & Research ? High Angle Rescue and Ice Blasting ? External Load & Long Line ? Mountainous Terrain Operations ? Aerial Application ? Power line Patrols & Construction The Helicopter ? Essentially the same aerodynamic principals as fixed wing but with some mechanical variations on the theme

May 1, 2001

By C. G. Kemsley

THE ore as hoisted is very wet, and difficulty was experienced i~ screening it to remove the fines before going to the secondary crusher. In fact, the fines had a tendency to form balls and roll down the screen, and only a small percentage was removed. Their inclusion with the other ore going to the Symons secondary crusher caused excessive spring action and pounding between the adjustment ring and main frame, resulting in abnormal wear between the two. To overcome this, it was decided to wash the fines through the primary screen, and use an Akins classifier to de-water the screenings, pumping the overflow from the classifier up to the mill and discharging the oversize onto the mill-feed belt.

Jan 1, 1945

By Z. D. Hora

has been no commercial production of either perlite or pumice in British Columbia. Several promising occurrences are known to exist but their development has been delayed due to difficult access and / or remote locations. The Empire Valley perlite deposit is located 120 km east of Clinton. The deposit appears to be a flat-lying volcanic flow 50 to 70 m thick that is part of an Eocene rhyolite and dacite volcanic assemblage. The Francois Lake perlite deposit occurs on the north shore of Francois Lake where perlite is part of a rhyolitic volcanic sequence. The exposure of perlite is about 13 m thick and is considered to be Eocene or Oligocene in age. The Uncha Lake perlite deposit is located about 5 km south Industrial Minerals in Canada of Uncha Lake. Perlite appears to be intercalated with porphyritic rhyolite flows that are comparable to those at Francois Lake. Showings are widespread but poorly exposed and thicknesses are unknown. The Mount Meager pumice deposit is located in the Lillooet River valley at the base of Plinth Mountain. Coarse pumice agglomerate forms a large talus slope that is undercut by the river. Unsorted, angular fragments up to 50 cm in diameter are intermixed with up to 30 per cent of sand and silt-sized particles. The exposed zone is about 200 m long and 50 m high; it is being considered as a source of lightweight aggregate.

Jan 1, 1984

By Wencheng Gao

An attractive way to beneficiate magnesium chloride and aluminum chloride is to prepare Mg-Al spinel, an excellent refractory material. Mg4Al2(OH)14?3H2O, the precursor of spinel, can be prepared using a co-precipitate method from aqueous MgCl2-AlCl3 solutions. The co-precipitation process of magnesium-aluminum from acidified chloride solutions by using NaOH or NH4OH as base neutralization agent was studied. Co-precipitation was conducted from different mixed solutions ? at initial CAl=0.0625M and Mg/Al molar ratio from 0.5 to 10, the temperature range from 30 to 90 °C. The effect of other parameters, including base type, method of base addition, base addition rate, aging time, background electrolyte and concentration were also investigated. The co-precipitation process was monitored by potentionmetric(pH) measurements. The experimental pH curves were characterized by two platforms separated by a steep jump in pH at Mg/Al molar ratio 0.5~6. The first platform was centered at about a pH of 3.8 and the pH of second platform was varied with different conditions. When the Mg/Al molar ratio was up to 6~10, the first platform in pH was almost disappeared. Furthermore, the shapes of pH curves were also affected by base type, base addition rate and method of base addition. Experimental results showed that the first platform in pH was connected with Al precipitation, and the second platform was involved with Mg. The final co-precipitates were characterized by XRD, TGA-DTA, particle size analysis, SEM and TEM. We found both Mg/Al molar ratio and temperature proved to be the key parameters controlling the formation of Mg4Al2(OH)14?3H2O phase. At solution Mg/Al ratio=0.5~4, the main precipitate phase was Bayerite (Al(OH)3) admixed with Mg4Al2(OH)14?3H2O; at Mg/Al ratio=4~6, the main phase was Mg4Al2(OH)14?3H2O admixed with some Mg(OH)2; while from Mg/Al ratio=6~10, the systems were mixtures of Mg(OH)2 and Mg4Al2(OH)14?3H2O.

Oct 1, 2011

By J. H. Hodgson

"Those of us who have been concerned with the problem of geophysical exploration in southwestern Ontario have followed the development of the Poulter method with much interest. I have much appreciated the opportunity of reading an advance copy of Dr. Poulter's clear exposition and of preparing the following brief remarks on the probable applicability of the method to the Palaeozoic area of southwestern Ontario.During the years 1944 to 1946, the Ontario Department of Mines, in co-operation with the Union Gas Company and the Dominion Natural Gas Company, operated an experimental party in the hope of establishing a seismic technique appropriate to the •area. The results were completely negative. During two summers' field work, no reflections whatever were obtained except in one area near Windsor. It is the •purpose of these remarks to inquire whether Dr. Poulter's techniques might yield favourable results.It was the conclusion of the report on our work that two principal causes contributed to the failure of the method. In the first place, the geological column possesses few elastic discontinuities and those that exist appear to have low reflection coefficients. In the second place, the area is drift-covered in general. This drift complicates the situation by absorbing seismic energy and by giving rise to groups of complicating refracted phases which obscure the entire interesting section of the record. The situation is further complicated by the high reflection velocities and the relative shortness of the Palaeozoic section, these factors combining to bring in a reflection from the basement in about half a second."

Jan 1, 1950

By W. T. Boyes, J. M. Harrison

"Squall Lake Gold Mines, Limited, owns a group of claims at Squall lake, northern Manitoba, about 75 miles east of Flin Flon and 3 to 4 miles north of the Nor-Acme mine at Snow lake. Gold mineralization was discovered in this locality several years prior to 1944, but it was only in that year that a comprehensive examination of the occurrences was begun. Development work to the end of 1946 has been encouraging and the deposits show interesting relations to rock structure.GEOLOGICAL SETTINGThe gold occurs in a sill of biotite-hornblende diorite at or near its contact with gneisses derived from arkosic sediments . In detail, the contact between the diorite and the arkose to the southeast of it is irregular, with interfingering of the two rock types. On the northwest side of the sill, between it and Squall lake, the rock is staurolite schist (see accompanying sketch-map).Several mineralized shear zones are known, of which those shown are the most important. Within the zones, the diorite is silicified and somewhat carbonatized. Fairly coarse arsenopyrite is the chief sulphide mineral in these zones but, locally, they contain also pyrite and pyrrhotite. Where quartz and chlorite are present, rather coarse gold is associated with them. In that part of the main zone where gold assays have been most consistent, the diorite is rich in albite."

Jan 1, 1954