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By A. Cadieux, J. -B. Pineault, C. Allaire

The temperature measurement of the molten metal in the aluminum transformation process is of prime importance. This is particularly the case for aluminum treatment furnaces, such as holding and melting furnaces. Such reverberatory type of furnaces involve a thermal gradient across the metal line which limits the life of conventional thermocouple protective ceramic shields, due to the action of locally induced thermal stresses. This paper presents a novel thermocouple assembly using a composite refractory protective shield allowing long term resistance to such above conditions. Example of results obtained from various tests in aluminum holding furnaces are presented. The results confirm the superiority of the novel thermocouple assembly, as compared to conventional thermocouple units.

Jan 1, 2004

Mining Association of Canada ! Represent base and precious metal, diamond and oil sands producers as well as nonferrous metal smelting and refining ! Member companies account for the vast majority of Canada?s mineral and metal production ! Mining is a major economic sector in Canada ! 13% of total exports ($47 billion) ! Employment near 400,000 ! 4% of GDP The Kyoto Protocol ! November 18, 2004 -- Russia deposited its instrument of ratification with the United Nations ! The Kyoto Protocol entered into force on February 16, 2005 ! The Kyoto Protocol is now an international and legally binding agreement to reduce GHG emissions world wide ! Canadian GHG target = 6 percent below 1990 ! First Commitment period 2008-2012

Apr 1, 2005

By J. H. Baek, S. Alexandrovskii, D. W. Lee, B. K. Kim

Nano-phase titanium carbide was synthesized by Mg-thermal reduction process using a novel route of Mg-thermal reduction. The processes are based on I) feeding of TiC14+CxC14 x = 1, 2 ) solution into liquid magnesium, 2) Mg-reduction of metal chlorides, 3) TiC formation by the reaction of released Ti and C atoms, and 4) vacuum separation of residual liquid phases of Mg and MgCl2. In this study, the process for titanium carbide production with composition close to stoichiometry and the minimum content of impurities was optimized with the various process parameters such as concentration of initial solution, its feeding rate and reaction temperature, as well as a kinetic study.

Jan 1, 2004

By G. Brooks, M. Hamed, S. Nightingale, K. Coley

The Marangoni effect plays a significant role in slag line corrosion of refractories. Previous experimental studies for various refractory /slag systems and mathematical models are reviewed and show that Marangoni flow is important in slag line corrosion under static conditions. Recent work by the authors is presented which also shows significant slag-line corrosion of MgO refractory in SiO2-CaO-FeOx-MgO slag. The rate of attack of the MgO was marginally slower in the case of slags containing alumina. A semi-empirical model developed by Hrma based on mass transfer control described reasonably well the observed progression of corrosion with time. Further work is proposed to evaluate this model.

Jan 1, 2004

By T. Cutard, H. Marzagui, E. Ouedraogo, M. Roosefid, M. Prompt, C. Deteuf

The present work is achieved in the framework of a French national program on modeling and experimental characterization of the thermo-mechanical properties of refractory materials (PROMETHEREF). This research program is aimed to establish fair models and experimental database and to make it available to industrial partners for numerical simulation of industrial structures made of these materials. The present paper focuses on two silica-alumina refractory castables, an andalusite based one and a bauxite based one. We will present the first rheological characterization results achieved at room on normal and preheated samples of these two refractory castables. Refractory castables are characterized with the help of four points bending tests, compression tests and tensile tests.

Jan 1, 2004

By R. K. Kandasami

"Naturally occurring geomaterials such as sandstone, limestone and other soft rocks, residual soils are composed of a particulates held together through a cohesive matrix, usually composed of argillaceous or siliceous cementing agents. Geo-materials such as these have been reconstituted in the laboratory using ordinary Portland cement in lieu of the naturally occurring cohesive matrix, in addition to using sand particulates. This cohesive frictional granular ensemble is an ideal model material for understanding the mechanical behaviour of transitional geomaterials such as soft rocks. An important consequence of this cohesion that pervades the inter particulate system is the enhanced tensile strength when compared to a purely granular ensemble. The assessment of strength of these soft rocks and cemented sands is often understood in the framework of continuum mechanics, i.e. considering the cemented sand to be a continuum, and performing simple elemental tests such as uniaxial compression or tension tests. A simple model to describe the behaviour of these cemented sands has been to use elements such as springs, sliders, and dashpots in parallel to describe the existence of a cohesive and frictional component of strength (Jiang et al. 2007). In the framework of continuum mechanics, the mechanical response of these cemented sands have been modeled using traditional plasticity theory, for example utilizing variants of the traditional Mohr Coulomb model, Modified cam clay (Sun and Matsuoka 1999) etc. The typical sand models are amended to include the effects of cohesion, as proposed by Lagoia and Nova (1995).The mechanical response of cemented sands is understood to be transitional to the behaviour of a typical particulate assemblage and a quasi-brittle material. However, the effect of length scale in these material systems has not been investigated. This paper presents a series of uniaxial compression experiments conducted on weakly cemented sand specimens of various sizes. The effect of length scale in these weakly cemented sands is investigated through unconfined compression tests."

Jan 1, 2015

By J. A. Haskin

The Engineering Department at Flin Flon has the following responsibilities: 1. Underground Surveying. 2. Open-Pit Surveying and Supervision of Blasting. 3. Mine Geology and Examination of Prospects. 4. Design of Plant Additions and Improvements. 5. Miscellaneous Field W ork, Reports, etc. The entire surface plant, as well as the underground workings, are located by co-ordinates based on a triangulation system covering an area approximately one mile long by one-half mile wide. The origin of this system and one end of the base-line is the southwest corner of Township 67, Range 29, west of the Principal Meridian. The bearing of the base-line was determined from the township boundary, which runs true north, so that all other bearings are almost astronomical. This is a great convenience when our surveys must be tied to mineral claims, rights-of-way, and land subdivisions. As the base-line extends across Flin Flon lake, its measurement across smooth ice was simple and accurate. The length, slightly over 1,600 feet, has been adjusted for the temperature and tension of the standard tapes used and checked sufficiently to ensure a maximum error of 1 : 15,000. Each angle was repeated ten times, but as no special refinements were used, errors of as much as four or five seconds are possible. The elevation of the origin of the triangulation system was approximately 1,050 feet above sea level. The use of this true elevation in our surveys would have resulted in negative elevations underground as soon as the mine reached a depth greater than 1,050 feet. To avoid this complication we therefore added 4,000 feet to this elevation. The collar of the Main shaft, for example, which is actually 1,072 feet above sea level, appears in our records as at elevation 5,072. Underground surveying, which follows standard practice, is done by two mine surveyors who share three helpers. The meridian is taken underground from two wires hung in either of the two vertical shafts.

Jan 1, 1935

By T. Melfi, M. James

Attaining required mechanical properties in welds made using the double submerged arc welding (DSAW) process is difficult, and it is becoming more difficult as the strength level of the base materials continues to increase. Producing weld metal with adequate mechanical properties involves factors that are often overlooked and not taken into consideration. Not least amongst these problems is simply finding information to use in selecting the appropriate flux/wire combination. Most of the available data on flux/wire combinations provided by consumables manufacturers is generated using the multiple pass welding procedures required for classification per specifications such as AWS A5.17 and A5.23. This data really gives no insight into the properties that can be expected in a DSAW application. Also, base plate composition plays a very significant role because of the fact that base plate dilution can be as high as 70% in DSAW welds. This means that if any elements are present in the base metal that are deleterious to mechanical properties, they will also be present in significant quantities in the weld deposit. Some of these elements can decrease toughness and increase hardness (increased hardness is a concern if the pipe is intended for sour service). Some of these problems can be mitigated by proper selection of welding consumables. Selection of proper welding consumables means selecting an electrode that provides the appropriate alloying elements to obtain the desired level of impact toughness while also keeping the hardness within any specified limits. In order to attain the necessary impact toughness, selection of a flux with an appropriate composition (in terms of its basicity and its ability to control the nitrogen content of the weld deposit) is required. As with all welding processes, the mechanical properties of DSAW welds are also highly dependent on the welding procedures. This work clarifies how to select appropriate consumables to meet a given set of requirements, and also how to achieve the optimum mechanical properties from those consumables.

Jan 1, 2005

By Lei Pan, Roe-Hoan Yoon

"Sea water flotation is becoming a reality due to shortages of fresh water. To better understand the mechanisms involved in sea water flotation, we have studied the effects of KCl and MgCl2 on the surface forces present in the wetting films of water formed on hydrophobic surfaces. The measurements have been conducted using the force apparatus for deformable surface (FADS), which is capable of measuring both the surface and hydrodynamic forces responsible for bubble-particle interactions. The results obtained with the gold surfaces hydrophobized with butanethiol (C4SH) show that the wetting films of Ultrapure water do not rupture despite the relatively high water contact angle (??= 80o) and the presence of a long-range hydrophobic force with a decay length (D) of 25 nm in the film. The film is metastable with its equilibrium thickness (he) at 140 nm, where the repulsive double-layer force is equal in magnitude to the capillary force as shown in Figure 1. The film loses its metastability and ruptures in a 10-2 M KCl solution, in which the double-layer force decreases substantially due to the decrease in Debye length (?-1) while the decay length of the hydrophobic force remains as large as 23 nm.The effects of MgCl2 has also been studied using a C4SH-coated gold surface with a water contact angle of 87o. It has been found that in a 10-4 M solution double-layer force decreases due to the decrease in the negative ?-potentials and Debye length, which should help destabilize the wetting film. However, the film remains stable due to the decrease in the decay length of the long-range hydrophobic force from 45 nm in Ultrapure water to 14 nm in the MgCl2 solution. Thus, the results obtained in the present investigation support the view that the difficulties in sea water flotation may be due to the presence of MgCl2 rather than the presence of NaCl in sea water (Ramos, et al., 2013)."

Jan 1, 2016

By D. Monder

Fuel cells are promising sources of electrical energy because of their exceptionally high efficiencies and low environmental emissions. Solid oxide fuel cells (SOFC) are high temperature, ceramic electrolyte cells, which unlike most other fuel cells, can work with a variety of fuels besides pure hydrogen, including hydrocarbons and hydrogen sulfide. In this presentation I present the models we have built for a single H2S fuelled SOFC. The goal is to model the electrochemical reaction coupled with mass transfer, fluid flow and current/voltage distribution in an yttria stabilized zirconia electrolyte fuel cell assembly operated between 750 and 850 °C. Two models of the above SOFC are discussed in this work, 1) an algebraic model derived by integrating a one-dimensional model along the thickness of the cell, and 2) a two-dimensional finite element axi-symmetric model. Important physical and kinetic parameters in the 1-D model are fitted using experimental data sets at three different temperatures and reasonable fits are obtained for the data sets at 800 °C and 850 °C. However, the third data set at 750 °C does not give a good fit using this model. We need to apply the curve-fitting to more data sets to investigate it further. The main conclusion that can be drawn from the present study is that the ohmic resistance of the cell is very high. Contact resistances are believed to be the reason behind this although there could be contributions from resistive interphases. The 2-D model also gives reasonable fits to data sets. One of the publications by the laboratory group doing the experimental work in our department presented very interesting data that shows the cell performance being a strong function of fuel flow-rate. We want to model this behaviour and will have to depend on the 2-D model as the 1-D model does not have flow-rates as parameters.

Jan 1, 2005

By Y. Kocaefe, S. Afshar, D. Kocaefe, Z. Kunt, C. Allaire

Interaction of aluminum with silica based ceramics Jose M. Soto, Jeffrey D. Smith, William G. Fahrenholtz. Department of Ceramic Engineering University of Missouri-Rolla Rolla, MO 65409-0330 USA ABSTRACT Interactions between A356 aluminum (Al-Si alloy) and dense fused silica (FS) riser tubes used for low-pressure casting of aluminum alloys were evaluated using a sessile drop approach. The tubes have a short service life, but cost and thermal shock resistance make them an effective solution. The main problem encountered during use is the reaction of aluminum with silica to form alumina and silicon, which causes failure. Tests have been conducted on as-fired (uncoated) and modified (coated) tubes. Experiments were carried out in a horizontal furnace at 1225°C under argon to minimize the effect of the aluminum oxide on the interactions at the alloy-silica interface. Images of the drop were acquired and contact angle values were estimated for uncoated and coated samples, but no significant differences in the contact angles were observed. Scanning electron microscopy revealed the presence of cracks at the interface between the reaction zone and the unreacted silica. The presence of reaction products (silicon in the reacting alloy and aluminum in a reaction zone between the alloy and the unaffected silica) has been confirmed using energy dispersive spectroscopy. A two layer coating system was found to be effective in reducing penetration of the aluminum alloy. The interactions between bed media and aluminum have been studied under static and dynamic flow conditions. An experimental system was set up simulating a small filter. Desired flow field can be created around alumina particles and velocities can be adjusted. A mathematical model was developed to predict the velocities, and this was validated using data from a visualization study. The interaction zone on the surface of the particles was analyzed with optical microscopy and SEM. This paper presents the study and compares the results under static and dynamic flow conditions.

Jan 1, 2004

By R. V. Typliski, G. J. Labarre

"Hudson Bay Mining and Smelting Co., Limited, Flin Flon, Manitoba, has developed a metallurgical wastewater treatment system employing two-stage lime neutralization, sludge recirculation and conventional mechanical thickening.Laboratory investigations, initiated in 1970, led to the construction of a pilot-scale minewater treatment plant, at Schist Lake Mine, in early 1971. This plant, treating 600 cubic metres /day of wastewater containing 30-60 mg/1 zinc. demonstrated metal extraction efficiencies of 99% under normal operating conditions.On the basis of this pilot work, a second pilot-scale treatment system was established in 1975 at the Flin Flon metallurgical plant to treat zinc refinery process waste water. Through numerous improvements, including automatic con¬trol equipment, the system has evolved to a full-scale operation capable of treating 800 cubic metres/day of wastewater containing 4-11 gm/1 zinc. Treated effluent contains 0.2-20 mg/1 zinc. The hydroxide sludge produced returns to the metallurgical process for the recovery of metals while clarified effluent discharges to waste.With the system, Hudson Bay Mining has achieved its original goal: the reduction of environmental contamination, while realizing a return from metal recovery.IntroductionWith the goal of reducing environmental contamination, Hudson Bay Mining and Smelting began laboratory testwork, during the late 1960's, into the methods and technology for neutralizing and removing heavy metals from acid mine drainage. Based on lime treatment, early tests showed much promise and culminated in the construction of a pilot-scale test plant at Schist Lake Mine in early 1971.This pilot system utilized technology developed in laboratory studies, and related to work then underway by state authorities in Pennsylvania coal mines. The basic operation consisted of a lime slurry tank, baffle reactor and a free-settling basin. Through three summers of operation, the Schist plant, capable of treating 600 cubic metres/day of minewater, produced a heavy-metal extraction of 99% under normal conditions. Although successful in proving the treatment chemistry, the plant displayed deficiencies in sludge densification and handling."

Jan 1, 1980

By A. J. Rigby

Anode vessels are often relined with refractory every one to two years and a typical reline time can take between 16-20 days. Modem refractory designs using dense, corrosion resistant brick applied directly to the vessel shell in the high wear areas around and above the tuyeres and at the slagline can yield a lining life of up to 4-5 years before a complete reline is necessary. Installation methods using brick delivery on roller conveyors through an endwall access port and complete anchoring of the brick to allow for lining self-support can take days off the installation time. It is possible, therefore, to reduce the refractory relining period by 50% and increase lining life by 100% compared to typical anode repair schemes. Cu2007

Jan 1, 2007

By R. W. Thompkins

The two largest contributors to silicosis in machine men are dust from drilling and dust from blasting. With the advent of the shatter-cut method of blasting, the evils of blasting dust were greatly reduced. The problem of dust from drilling has been attacked from two different angles: (1) The adoption of dustless frontheads or enlarged water tubes, both of which have proved capable of reducing dust concentrations; and (2) The adoption of better ventilation. Many operators are loath to adopt dustless frontheads or enlarged water tubes on Leyner drills because of the increased repair costs on drills, and also because it has been found difficult to enforce 'the proper usage of dustless machines: for example, workmen sometimes plug the vents in the fronthead.

Jan 1, 1943

By V. Pouyafar

Semi-Solid metal alloys, as used in SSM processing, have a special microstructure of globular solid particles suspended in a liquid matrix, which makes them behave differently in forming processes. The sensitivity of semi-solid slurries to temperature variations and their history and rate dependant behavior, make process design and control difficult. Precise selection of the process parameters is necessary in part production. Therefore, a numerical analysis and simulation of the process can be a valuable tool in process design. In this work we proposed a structural dependent model to account for the thixotropic behavior of semi-solid metals. The parameters of the model were then determined using rheometery tests. The results show a good agreement between the model and the experiments.

Oct 1, 2011

By M. Hosseinzadeh

By changing the quality of consumed refractory bricks in burner zone of sarcheshmeh copper complex anod kiln removing of carbon precipitation phenomenon was studied. For blister deoxygenation LPG is blowing in anod kiln and cause destoring microsturcture and bonding of refractory bricks. Studies are shown that in a part of the bricks which have a temperature of 800 - 1000 °C , iron content phases in magesia - chromite bricks are like catalist and cause increasing the rate of carbon precipitation reactions . In a way that in comparsion of two bricks with best and medium quality with different analysis, this problem is more critical in best quality bricks containing high iron oxide. Therefore special magesia spinel bricks suggested and installed in burning zone.

Jan 1, 2004

By M. R. Coffin

In recent years, improved operation of the Kidd smelter has resulted in an increase in blister production capacity. Due to manpower and equipment limitations anode production and treatment rates could not be increased without incurring significant additional operating expenses. The option chosen to expand casting and refinery capacity to meet the available blister supply was to increase the anode thickness while maintaining the same anode exchange cycle in the refinery. This has resulted in a cathode production increase of almost 10% for minimal expenditure. Equipment and process modifications required to cast and refine the thicker anodes are discussed in this paper, along with the Six Sigma methodologies used to identify them. Key areas covered are Hazelett continuous caster operation, refining process parameters, plating performance and cathode quality.

Jan 1, 2007

By M. J. Hadianfard

The effect of holding at temperature on fatigue life of a 10 vol% particulate SiC reinforced Titanium alloy has been investigated. The influence of holding time at 600°C on fatigue of this material has been studied by using tension-compression tests, scanning electron microscope and image analysis. The specimens were heated to 600°C by using a controlled atmosphere furnace; hold at this temperature for time ranging from 0 to 100 hours, and then fatigue tested at room temperature under controlled constant plastic strain. The number of cycle to failure found to decrease with increasing of the holding time. In addition the fracture mechanism and number of debonded particles has been significantly influenced by holding time at 600°C.

Jan 1, 2004

By E. Paransky, M. Rigaud, G. Paschek, S. Palco

Some of the negative impacts of carbon addition on the strength of castables are yet to be overcome in order to fulfill its potential benefits for oxidation resistance. This paper reports the results of recent studies conducted at CIREP on the effects of different types of carbon additives on the thermo-mechanical properties of magnesia-based castables. Experimental techniques included measurements of the hot modulus of rupture (HMOR), hot modulus of elasticity (HMOE), as well as the wedge-splitting test (WST). The comparison of evolving microstructures was carried out employing scanning electron microscopy with microanalysis attachment (SEM/EDS) and X-ray diffraction (XRD). HMOR values of 12 MPa at 1300°C have been reached in MgO-Si02-C castables containing up to 7% carbon.

Jan 1, 2004

By W. Lo, M. Brothers, G. Oprea, G. Richard, T. Troczynski

Magnesia-chrome and chrome-magnesia are the most used refractories in contact with iron-rich non-ferrous smelting slags. The corrosion by slag always brings chromium oxide into the slag, causing the precipitation of crystalline phases at the process temperature. This secondary effect of the chromium-bearing refractory dissolution was studied in this work, emphasizing the effect of the other chemical components of the slag at various temperatures. The experimental results showed that the presence of chromium and lead contribute, although in different ways, to the formation of complex spinel phases and their precipitation at temperatures in the range of 1250-1400°C. The XRD and SEM/EDS results were discussed for refractory-slag mixes containing 0-20% Cr2O3 and 0-11% PbO.

Jan 1, 2004