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By Gerardo Fuentes

Arsenic extraction from Chilean copper concentrates up to nearly 99% was achieved, using hydrothermal reactions. Arsenic appears in nature in more than 200 mineral species, being arsenopyrite (FeAsS), enargite (Cu3AsS4), and tennantite (Cu12As4S13) the most common species. In addition, arsenic is present in a large amount of copper concentrates, produced in northern Chile. Medical statistics show that in northern Chile, the amount of cancer to the lung, skin and bladder are the highest in the country. The latter situation, demonstrates the importance of studying metallurgical processes that do not generate atmospheric pollution. The hydrometallurgical processes such as hydrothermal treatment in autoclave reactors, do not produce gaseous emissions. On the other hand, the arsenic remains in solution from where it can be transformed in scorodite by widely known methods. Previous works about hydrothermal treatment of enargite have shown the feasibility of transforming the enargite of the copper concentrates into chalcocite or mineral species of the chalcocite family such as djurleite, digenite and for this reason enrich the concentrate in copper and pass the arsenic to solution. For this research, two Chilean copper concentrates were used, concentrate 1 with 5.5% arsenic and concentrate 3 with 1.8% arsenic. These concentrates were subjected to a complete chemical and mineralogical characterization. Later these concentrates were carry out to batch tests of hydrothermal treatment. Also, these concentrates were subjected to grinding to have different particle sizes. For the hydrothermal tests, a liter capacity Autoclave Engineer reactor was used. Characteristic of this reactor was the maximum temperature 350°C, 5000 PSI pressure, and 900 rpm agitation speed. Kinetic tests were carried out with the two concentrates maintaining the same solid: liquid relationship, the same agitation velocity and the variables studied were treatment temperature, time of reaction, concentration of copper in the solution and grain size of the concentrates. The conclusions of the study indicated arsenic extraction of the order of 93.98% from the concentrate 1 and arsenic extraction of the order of 98.74% from concentrate 3. After the hydrothermal treatment, the solids and solutions were characterized chemically, by electron microscopy and X ray diffraction. Also the solids were characterized by grainsize through a particle size analyzer (MICROTRAC). Results of batch treatment shows that arsenic can be release almost completely from real copper concentrates using this hydrothermal process and the next stage will be a scale up process in order obtain results for pilot plant design. INTRODUCTION Arsenic is an impurity that appears associated with copper minerals forming enargite, tennantite, tetrahedrite, and that due to the pyrometallurgical treatment either in conversion or roasting furnaces, it goes into the atmosphere together with the sulfur dioxide. A great quantity of literature can be found to eliminate arsenic or try to separate arsenic from copper. The methods used are mainly leaching processes with or without pressure (Padilla, Jerez & Ruiz, 2015) with different reagents like chloride media (Herreros, Fuentes, Quiroz & Viñals, 2003) or chloride media with sulphuric acid (Riveros & Dutrizac, 2008) or sodium hypochlorite (Mihajlovic, Strbac, Zivkovic, Kovacevic & Stehernik, 2007). It is known too that Chile is the first copper producer in the world and a great quantity of its minerals are in the north of the country, in Antofagasta.

Jan 1, 2019

By L. Avramovic, B. Han, R. Jonovic, Z. Stevanovic, K. Haga, S. Dimitrijevic, A. Shibayama, L. Godirilwe, Y. Takasaki

Pyrite (FeS2) and chalcopyrite (CuFeS2) which could not be recovered, are present in mine tailings discharged from Bor copper mine. About 0.3% of copper (Cu) is contained in these tailings, therefore it can be considered as a useful copper resource. At the same time, pyrite is known to promote acid mine drainage, therefore it is necessary to detoxify the tailings. An efficient method has been proposed to recover copper and reduce the environmental impacts of tailings by a combined hydrometallurgical process of high pressure leaching (HPL), solvent extraction (SX) and electrowinning (EW) process. HPL process yielded high copper leaching rate (>95%) when water (H2O) was used as a leaching media. On the other hand, pyrite contained in the tailings was converted to iron oxide by high pressure leaching. Stability evaluation of the residue obtained from high pressure leaching, confirmed almost no elution of metal ions. The percentage of copper extracted and stripped from the Cu-loaded organic phase reached 97.4%. Moreover, it was confirmed that a low iron concentration in the electrolyte of copper electrowinning, resulted in the improvement of current efficiency of copper electrodeposition. INTRODUCTION Mine tailings are a by-product obtained from the flotation process and there are billions of tons of already existing tailings all over the world. Moreover, several billion tons of additional copper tailings will inevitably be produced in the coming years (Onuaguluchi & Eren, 2012). With the declining average copper ore grade, alternative sources of copper are highly sought, mine tailings have a comparable copper grade to that of low-grade ores (0.2–0.3%) therefore, it can be said that copper mine tailings present a very important source of secondary raw material for copper production (Antonijevi´c et. al., 2008). Consequently, it is necessary to confirm the possibility of the valuable metals (such as copper) recovery from mine tailing in which copper content is about 0.2–0.3%. Our group investigates the flotation and high pressure leaching processes for recovering of copper from mine tailings. Previous work on related samples include copper and nickel flotation tailings from Botswana, and a low–grade copper ore sample from Chile. Impurities, which are associated metals in mine tailing such as iron (Fe) and aluminum (Al) co-dissolve into the solution during the HPL treatment process. Therefore, separation of copper from impurities is necessary for selective extraction of copper from mine tailings and upgrading the copper concentration in the leachate to enable further purifying of Cu by electrowinning. Thus, it is important to investigate the possibility of applying solvent extraction for concentration of copper from leachate solutions of mine tailings (Onuaguluchi & Eren, 2012; Antonijevi´c et. al., 2008). In this study, LIX-84I was used as an extractant of copper from the leachate of high pressure leaching of mine tailing. As a fundamental solvent extraction investigation, the extraction behavior of copper was studied using a simulated solution of the leachate from the high-pressure oxidative leaching of mine tailing. The effects of; solution pH, extraction time, extractant concentration and phase ratio on copper extraction and sulfuric acid (H2SO4) concentration on stripping were investigated.

Jan 1, 2019

By P. E. Weidmark

"PART I - Published PapersBallivy, G., and Dupuis, M., ""Laboratory testing for the design of grouted rock anchors""; Proc 6th Pan Am Conf Soil Mech Found Eng; Lima; 1:277-291; 1979.Ballivy, G., Ladanyi, B., and Gill, D., ""The effects of moisture content on the strength of fissured rocks""; Proc 1// 1ntnl Congr 1.A.E.G.; Madrid; //:2:7-16; 1978.Baumgartner, P., and Stimpson, B., ""Development of a tiltable base friction frame for kinematic studies of caving at various depths""; Int J Rock Mech Min Sci Geomech Abstr; 16:4:265-267; 1979.Bawden, W.F., and Roegiers, J.-c., ""Discussion and interpretation of the mathematics governing radial flow in a single horizontal rock fracture""; ISBN 07727-7002-6; Dept Civil Engng publication 79-11; Univ Toronto: 134p;1979.Chatterji, P.K., Smith, L.B., and Insley, A.E., ""Construction of Saline Creek Tunnel in Athabasca oil sand""; Can Geotech J; 16:1:90-107: 1979.Coates, D.F., and Gyenge, M., ""A case history of pit slope design""; Proc 4th ISRM Congr; Montreux, Switzerland; Sept 1979; 1:Theme IV:591-596; 1979.Crawford, A.M., and Curran, J.H., ""A dynamic direct shear machine for determining the time-dependent behaviour of rock joints"": Dept Civil Engng publication 79-08; Univ Toronto; 1979.Crawford, A.M., and Curran, J.H., ""A displacement discontinuity approach to modelling the creep behavior of rock and its discontinuities""; Dept Civil Engng publication 79-09; Univ Toronto; 1979.Crawford, A.M., and Curran, J.H., ""A higher-order displacement discontinuity element""; Dept Civil Engng publication 79-10; Univ Toronto; 1979.Cruden, D.M., ""A computer-based system for rock mass description""; Proc 1// Intnl Congr I.A.E.G.; Madrid; //:2:155-159; 1978.Cruikshank, D.J., and Curran, J.H., ""A.B.LE. approach to modelling of fluid flow in fractured rock masses""; Proc 7th Cdn Congr Appl Mech; May 1979; Sherbrooke, Que; 887-888; 1979."

Jan 1, 1980

By R. L. Bruening, L. Navarro, R. M. Izatt, N. E. Izatt, S. R. Izatt

Green chemistry principles will be discussed, and examples will be given of the use of Molecular Recognition Technology (MRT) to selectively separate valuable metals such as rhenium and palladium from various copper refinery feed streams. Recovery of these metals has numerous advantages including (i) conservation of valuable resources, (ii) prevention of environmental damage, and (iii) elimination of capital and operating expenses due to re-processing or disposal of metal-bearing streams. INTRODUCTION Refining of copper ores has a long and successful story. The history of copper, one of the first metals mined in human history, illustrates the global challenges faced as a result of increased demand for major metals and for by-product specialty metals found with them in trace amounts (Izatt et al., 2014). Copper has valuable properties, which have sustained its use over the centuries. It is an ideal material for creation of novel materials. Some desirable properties of copper that have proved valuable in our high-technology society include suitability for alloying with many other metals; ease of joining by soldering and brazing; good combination of mechanical qualities; high resistance to corrosion; suitability for many artistic purposes; and, of great importance in the modern era, efficient and economic use as a conductor of electricity. Copper mining in the U.S.A. began in the late nineteenth century in Montana (Izatt et al., 2014). The estimated total amount of copper mined globally before 1800 is about 5 million tons, four times less than is mined in a single year today (Flanagan, 2018). Production of copper in the U.S.A. has remained fairly constant at about 1,300,000 to 1,400,000 metric tons per annum from 2013 to 2017. Specialty metals such as bismuth, rhenium, molybdenum, and others that have become essential in our 21st century technology, and precious metals such as silver, gold, and the platinum group metals (PGMs) are concentrated by geochemical processes in trace amounts in copper ores. These specialty and precious metals were discarded into tailings in early mining operations, since limited extractive technologies existed and uses for most of them were limited. Thus, economic benefits for recovering them were limited, primarily, to silver and gold. Today, copper processing is the main, and often the only, commercial source for certain of these elements (Izatt et al., 2014). For example, molybdenite (MoS2) is the predominant ore mineral of molybdenum mining (Pohl, 2011). Cu-Mo-Au porphyry ore deposits supply ~75% of the world’s copper, 50% of the molybdenum, nearly all of the rhenium, and 20% of the gold. Typical ore grades are 0.5–1.5% copper, 0.01–0.04% molybdenum, and <1.5 g/ton gold. Molybdenite is the primary source for rhenium, among the rarest of metals, which is an essential component of super alloys, such as turbine blades in the aerospace industry (Pohl, 2011). Most rhenium is obtained as a by-product of molybdenite from copper mines in Chile. The case of rhenium raises an important issue. Continued availability of rhenium, selectively concentrated in copper ores, depends on continued mining and processing of copper. Since the mining company’s main interest is typically in copper production, continued recovery of rhenium and other specialty elements present in the ore body is at risk. Dependence of specialty metal supply on continued mining of major metals exists in several additional cases including indium, gallium, selenium, tellurium, germanium and bismuth (Pohl, 2011). PGMs, on the other hand, are typically mined for their own value, which far exceeds that of associated base metals. However, copper ores often contain marketable amounts of platinum and palladium, making their separation of interest, if this can be done economically.

Jan 1, 2019

By C. Diaz, S. W. Marcuson, K. I. Burgess

Deep roasting in fluid bed roasters is the first unit operation in Inco&apos;s "roast-reduction smelting" process for the treatment of nickel sulphide concentrates. The roaster product, a low sulphur calcine, is reduction smelted with coke in an electric furnace to yield a sulphur-deficient matte which is then converted to low (<1%) iron matte in Peirce-Smith converters. Due to the deep roasting, a minimal amount of sulphur dioxide is evolved in the smelting and converting stages. Sulphur is eliminated from the concentrate almost exclusively in the roasters in a single, continuous, strong, gas stream suitable for treatment in an acid plant. This paper discusses the commercial scale testing of deep fluid bed roasting of nickel concentrate at Inco&apos;s Thompson Smelter as part of two commercial scale campaigns on roast reduction smelting conducted in 1981-1982. Slurry feeding, practised during the second campaign, permitted excellent control of the air/concentrate ratio in the roaster and, in turn, good control of sulphur elimination (about 80% of input). Smooth autogenous operation with high oxygen efficiencies (about 95%) was promoted by operating at bed temperatures of830°C to 850°C with calcine recycle. High throughputs and the desired metallurgy were achieved. The extensive testwork conducted during the two experimental RRS campaigns demonstrated thot deep fluid bed roasting of nickel concentrate at high oxygen efficiency is a technically viable operation.

Jan 1, 1994

By E. Ghali, B. Arsenault

Aluminum alloys play an important role in the manufacturing of air and ground vehicles. However, with such alloys, corrosion damage is often found on structural components subjected to fatigue loading. The alloying provides large benefit in terms of the high specific tensile strength (ultimate strength/density ratio) to the aluminum alloy but causes the aluminum alloy to be more sensitive to localized corrosion due to complex microscopic heterogeneities such as secondary phases. This paper investigates thermal spray coating namely arc spraying to evaluate the protection against environmentally assisted cracking (EAC) and localized corrosion on Aircraft structural 7075 T651 aluminum alloys. In particular, EAC and pitting corrosion at the interface coating-substrate are a challenge for thermal spray protective coatings on aluminum alloys under cyclic load and immersion. To address these issues, different surface preparation techniques prior to arc spraying were considered such as chemical de-oxidation, laser ablation, shot peening and grit blasting. Results indicate that surface preparation and improved coating process parameters play an important role to provide a coating conferring a protection against both localized corrosion and EAC.

Jan 1, 2006

By Robert Boutilier

For more information on what the social licence means, see the following: Joyce, S. and Thomson, I. 2000. Earning a social licence to operate: Social acceptability and resource development in Latin America. The Canadian Mining and Metallurgical Bulletin, 93(1037) Nelson, J. and Scoble, M. 2006. Social License to Operate: Issues of Situational Analysis and Process. Vancouver, BC: Department of Mining Engineering, University of British Colombia. Thomson, I. and Boutilier, R.G. 2010. The Social License to Operate In P.Darling, (Ed.), SME Mining Engineering Handbook: Littleton, CO: Society for Mining, Metallurgy and Exploration. Much of what has been written and said about the social license to operate focuses on what the company has to do or not do. But the social license is a two-sided relationship. We also need to look at what the community has to do, or not do, in order to be capable of issuing a social license that is meaningful.

May 1, 2010

By Russell Spry

THE cyanide plant of the Cariboo Gold Quartz Mining Company, Limited, at Wells, B.C:, in the Barkerville section of the Cariboo mining division, was erected during the latter part of 1932 and placed in operation in January, 1933. The initial capacity of the plant was about 50 tons daily. This was increased to 100 tons at the end of 1934 and stepped-up to 150 tons in September, 1935. It is expected that further plant extensions, for milling a total of 200 tons daily, will be required during the early part of 1936. Recent additions to the mill have been so planned as to permit ready expansion to 275 tons daily when underground development warrants the milling of this tonnage. It is the purpose of this paper to outline briefly the steps taken to bring the plant to its present capacity and to comment on possibilities for further plant expansion. The gold in Cariboo Gold Quartz ore occurs as free gold in the quartz and on pyrite surfaces. Some of it is very finely divided, specks l/10,000 inch having been observed microscopically, according to Dr. G. Hanson. In addition to pyrite, which comprises probably 15 to 20 per cent of the mill feed, galena and sphalerite are present, with small amounts of arseno-pyrite and chalcopyrite. Sulphobismuthites-chiviatite, galenobismutite, cosalite, etc.-occur more or less frequently in certain sections of the mine. Following tests on Cariboo ore by the Mines Branch, Department of Mines, at Ottawa, treatment of the ore by straigh t cyanidation was recommended and a 50-ton plant employing continuous counter-current decantation was erected. This plant was built as a pilot mill, the intention being to erect a larger mill after metallurgical treatment had proved successful over an extended period. This original installation, however, has been enlarged and retained as an operating unit, additional equipment being added to it as capacity increases have been required.

Jan 1, 1936

By B. Skrotzki, E. Augenstein, C. Rockenhäuser

"The aluminium alloy 2618A is an Al-Cu-Mg alloy with additions of Fe and Ni, which is designed for long-term operation at elevated temperature in transportation and aerospace industries. The alloy degrades due to coarsening and dissolution of GPB zones and coarsening of S-Phase precipitates (Al2CuMg). This work investigates the overageing process at the application relevant temperatures of 190 °C for durations ranging up to 25,000 h. The nm-sized precipitates were selectively imaged along the <001>a direction of the Al matrix using dark-field transmission electron microscopy. The resulting images were then evaluated and allow the statistically relevant determination of radii distributions and the average radius of the precipitates dependent on temperature and heat treatment duration. Ostwald ripening of the S-phase does not describe the ageing process adequately. Instead, the evolution of GPB zones during the initial ageing regime needs to be considered in addition to the coarsening process of the S-phase. DSC measurements were performed to determine the presence of GPB zones in different ageing states. This will allow a quantitative description of the ageing process and a comparison to samples aged under external load.INTRODUCTION Alloy 2618A is an Al-Cu-Mg alloy, which is part of the 2XXX series of aluminium alloys. It is used in aerospace and transportation industry due to its desirable material properties for long term operation at elevated temperatures (Polmear, 2006). Fe and Ni are added to form intermetallic compounds, which retain microstructural stability at elevated temperatures (Bergsma, Li, & Kassner, 1996; Elgallad, Shen, Zhang, & Chen, 2014; Oguocha, Yannacopoulos, & Jin, 1996; Wang & Yi, 2006). The size and distribution of the nm-sized S-phase formed from the supersaturated solid solution (SSSS) during heat treatments mainly controls the strength (Khan, Starink, & Yan, 2008; Liu, Zhang, Ding, Sun, & Chen, 2003; Parel, Wang, & Starink, 2010; Shih, Ho, & Huang, 1996; Wang, Starink, & Gao, 2006). The S-phase has the composition Al2CuMg and is orthorhombic under equilibrium conditions (Heying, Hoffmann, & Pottgen, 2005; Perlitz & Westgren, 1943). Early experiments proposed the following decomposition of the S-phase sequence during heat treatments (Hardy & Heal, 1954; Silcock, 1961):"

Jan 1, 2018

By Chris Carr

This paper describes the process employed and the work undertaken to enable the surrender of the mine permit relating to the two tailings deposits at the abandoned Red Mountain Mine site near Rossland, BC. The first phase of the work undertaken was to provide urgent remedial work for protection of the environment, primarily through rehabilitation or replacement of surface water drainage systems. The second phase was to up-grade the water management systems to the appropriate level given their consequences of failure. The final phase of work is to ensure long term geotechnical stability of the facilities to the same level of risk. Establishment of a sustaining fund will facilitate long term monitoring and maintenance of the facilities.

May 1, 2002

By Neda Zangeneh

Production efficiency from low permeability gas shales require techniques to optimize hydraulic fracture completions. One completion strategy involves the simultaneous or near simultaneous hydraulic fracturing of multiple horizontal wells to maximize the fracture network area and stimulated reservoir volume. However, changes to the in-situ stress field caused by an earlier hydrofrac on subsequent hydraulic fractures are not accounted for in traditional hydrofrac design calculations. Presented here are the results from a set of transient, coupled hydro-mechanical simulations of a rock mass containing two wellbores using the discontinuum-based distinct-element method. The results demonstrate the influence of stress-shadows generated by a hydraulic fracture on the development of subsequent hydrofracs from an adjacent well. It is shown here that these interactions have the potential to change the size and effectiveness of the hydraulic fracture stimulation by changing the extent of the hydraulic fracture around the secondary well.

Jun 1, 2012

By So-Yeong Lee, Moosang Lee, Seung Hwan Ahn, Ho-Sang Sohn, Jongshin Chang

It is necessary to understand the characteristics, phase changes and chemical reactions of flue dusts introduced from a furnace to an off-gas line in order to achieve the stable operation and the improvement. This study is to develop the dust reaction model for chemical reactions of dusts in an uptake shaft of smelting furnace and a waste heat boiler. Phase equilibria and reaction paths in this system were determined by thermodynamic calculation with experimental and industrial data. The oxidation reaction rate of dusts was determined by the gas film mass transfer controlling. And the sulfation reaction rate was evaluated by the unreacted shrinking core model. Kinetic parameters were estimated by reference data including industrial ones. The present study with the developed model shows various effects of temperatures, dust particle sizes, and O2 gas partial pressures on dust reactions. INTRODUCTION The flue dusts from a copper smelting furnace move along a furnace off-gas stream into an uptake shaft and a waste heat boiler (WHB) and electrostatic precipitator(s). It is necessary to control the dust quality in order to stabilize the operation because the sticking behaviors differ depending on the phase of dusts. Phase changes of dusts are caused by chemical reactions at given conditions such as temperature and partial pressure of gases. Therefore, it is required to understand the phase changes and chemical reactions of dusts in order to perform the improvement and stable operation. The present study carried out the investigation to understand their fundamental knowledge. Especially, this study was focused on the kinetics of chemical reactions of flue dusts, developed the model. In particular, the scope of development and utilization of the model was defined as the uptake shaft of the Mitsubishi S furnace and the S-WHB radiation section in the Onsan smelter. Information needed for the modeling work referred to data from these processes.

Jan 1, 2019

By Darrell McClarty, Roger Payne, Matt Haggis, Michael Courtin, Deborah Berthelot

"Over forty years of uranium mining in the Elliot Lake region of Ontario (I 956-1996) has resulted in the production of over 300 million pounds of uranium. With the completion of mining activity, Rio Algom Limited and Denison Mines Limited are utilizing progressive environmental technologies and management systems to reduce and manage the environmental risks associated with the 150 million tonnes of potentially acid-generating tailings in nine regional waste management areas. Water covers designed to reduce oxygen entry and thereby significantly inhibit acid generation have been applied at six of the sites with the Quirke site serving as a demonstration site for the Mine Environmental Neutral Drainage program. All five of Rio Algom Limited' s effluent treatment plants are monitored and controlled from a central control station utilizing a Supervisory Control and Data Acquisition (SCADA) system based on ""Fix Dmacs"" technology. Scheduling, auditing and reporting of plant operating and environmental monitoring programs for the entire watershed are controlled utilizing the Regional Environmental Information Management System (REIMS). Proper application of these technologies and management systems facilitates delivery of cost-effective environmental monitoring, care and maintenance programs at these sites and provides tools to demonstrate compliance with all environmental performance criteria.IntroductionCost-effective management of multiple tailings management areas distributed throughout a 35 km watershed requires the application of leading-edge environmental technologies. Long-term monitoring, care and maintenance costs must first be minimized through the application of decommissioning technologies that inhibit acid generation and minimize the release of contaminants from the sites. On-going operating costs must then be controlled through the application of environmental management strategies that optimize the allocation of resources while ensuring compliance with regulatory and Company environmental requirements.Using sites in the Serpent River Watershed as an example, this paper demonstrates the effectiveness of water covers as a decommissioning strategy to inhibit acid generation. In addition, the Telemetered Environmental Operating Control System and Regional Environmental Information Management System are reviewed as examples of the application of environmental technologies to the management of environmental programs."

Jan 1, 1998

Concentrator Improvements -1990-1995Back to Basics ?pilot plant versus plant opportunities identified ?understand process fundamentals & baseline -1996-2000Point ?C?Projects ?strategy to improve global competitiveness ?structure implemented to generate & drive ideas ?capital investment for life of mine asset renewal - 2001-200?Six Sigma Methodologies ?emphasis on data, measurements & analyses ?dedicated, highly trained personnel on projects 1990-1995 Improvement Phase??Philosophy??back to basics?approach?understand what each piece equipment needed to do?understand reagents, control variables?confirm operating strategies ??probe, stabilize, institutionalize??test theories, confirm with lab and plant trials?process stability (equipment reliability, controls)?enhanced operator guidelines, operator training?focus on continuous improvement?optimize existing equipment capability?stop looking for ?magic?solutions 1990-1995 Improvement Phase??Technical?finer grind, same equipment?optimize media size/shape to grinding application?balanced available ball mill power to applications?lowered cyclone feed densities where possible?improved selectivity, same equipment?balanced available cells to applications?streamlined process (eliminate process steps)?added cleaning stages where required?understanding pulp/mineral surface chemistry?lowered flotation pulp densities 1990-1995 Improvement Phase??Effort?numerous studies to understand process?liberation and mineralogical characterization?pulp and mineral surface chemistry?flotation kinetics and entrainment?extensive internal and external manpower?Brunswick, Noranda Technology Centre?CanMet, AMTEL, MinnovEx, Lakefield Research, McGill University?small capital expenditure

May 1, 2002

By Tong Gao, Jingyu Qin, Xiangfa Liu, Zengqiang Li, Yaoxian Zhang

"The recycling of aluminum materials is a green industry while Al–Si–Fe is a typical scrap aluminum alloy. The key point of recycling Al–Si–Fe alloys is to separate Al and Fe. A method by introducing Al–Si–Fe alloy into Mg melt has been investigated in this work. A separation layer with gathered Fe–rich and Al–poor Fe3Al0.7Si0.3particleswereobtained at the bottom of the cooled ingot, indicating that ß–Al5FeSi phase evolves to Fe3Al0.7Si0.3,and quantities of Al are released to the upper Mg matrix simultaneously. However, the evolution of Al3Fe by adding binary Al–Fe alloy into Mg melt is different. It is supposed that element Si plays an important role in the phase evolution procedure, thus affects the performance of this method.INTRODUCTIONThe rapid development of aeronautic, automotive and aerospace technologies strongly depends on the consumption of materials while sustainable development is the future direction. Aluminum is a recyclable material and Fe is one of the most common impurities. Fe can be introduced into Al alloys by adding low–purity alloying materials and by using unprotected ferrous crucible, tools, or equipment (Belov, Eskin, & Avxentieva, 2005; Lu& Dahle, 2005).For instance, wear–resistant rings are usually inserted into piston head when producing Al–Si pistons and an infiltration procedure by putting the cast iron rings into Al melt before casting is always essential. As a result, both the re–melting of pistons and the reuse of Al melt for infiltrating rings lead to the enrichment of Fe element, which can be even high to5 wt.%(Viala, Peronnet, Barbeau, Bosselet, & Bouix, 2002).It is widely known that coarse ß–Al5FeSi particles will form in high Fe–contained Al–Si–Fe alloys which is harmful for the mechanical properties. In the past decades, several methods to eliminate the harmful effect of ß–Al5FeSi have been investigated which can be widely referred (Munson, 1967; Lee, Kawamura, Inoue, Cho, & Masumoto, 1997; Suárez–Peña& Asensio–Lozano, 2006; Eidhed, 2008).These methods can be divided into two kinds. One is to aggregate and remove the Fe–rich phase through the methods of centrifugation, gravity filtration or magnetic separation. The other way is modifing the morphology of flake–like ß–Al5FeSi by overheating the melt or adding neutralized elements. However, these traditional methods are rarely used due to respective disadvantages, while the commonly used method in industries is using primary aluminum for dilution. However, only less than 30wt.% of scrap Al can be added into primary Al melt for each melting work while it also results in the decrease of product quality simultaneously(Zhang, Liu, & Liu, 2016)."

Jan 1, 2018

By G. G. Campbell

"HistoricalBARYTES was mined in Nova Scotia as early as 1874 from a deposit at Five Islands, on the north shore of Minas Basin. The first record of the presence of the mineral at the Walton site appears in a report by Selwyn in l893, who states: ""Barytes in considerable quantity occurs in veins in lime-stones at Walton and Pembroke"". The exact site of the present workings was marked •on a map published by Fletcher in 1905.The economic •possibilities of this deposit, however, were not recognized until 1940, at which time we were at war with Germany, who up to that time had supplied 50 per cent of the world's requirements.At that time the Nova Scotia Department of Mines, recognizing the need for certain strategic minerals, induced Canadian Industrial Minerals, Limited, to send prospectors into 'the area to look for manganese. No manganese deposits were found, but a deposit of barytes was directed to their attention, and exploration and development work on the occurrence was proceeded with.IntroductionThe south shore of Minas Basin between the Avon river at Windsor and the Stewiacke river at Maitland has long been known as a potential source of mineral wealth. It had attracted the attention of mineralogists and in the past had produced considerable tonnages of manganese ore and gypsum. Depletion of ore in surface and near surface deposits resulted in a dwindling production, until today only deposits of gypsum are worked."

Jan 1, 1952

By R. G. Achter, E. Wilson

"This paper describes the work undertaken to renovate the Pipe Open Pit drainage system, incorporating measures to improve effluent quality. It describes the technical feat of drilling an l l-inch-diameter hole from the bottom of the open pit for a distance of 1100feet to intersect an underground drift. An innovative method of checking the inclination of this hole is also described. The paper outlines the construction required on the 1500-foot level of the underground mine to facilitate water impoundment and slime settling, as well as the instrumentation for control of water flows. IntroductionThe Manitoba Division of Inco Metals Company operates two mines-an underground mine at Thompson and an open pit at Pipe. The Pipe Open Pit is located 20 miles southwest of the City of Thompson, approximately 400 miles due north of Win nipeg(Fig. 1).Surface diamond drilling of the Pipe ore body was sta rted in 1959. In 1961, a shaft was sunk to a depth o f 1,570 feet to carry out further exploration work and obtain bulk ore samples for metallurgical testing. Site preparation to mine the upper portion of the orebody as an open pit was initiated in 1966 and by late 1967, the removal of silt and clay overburden was in progress. The contractor completed the dredging in the fall of 1969. Over 12 million cubic yards of muskeg, clay and silt was removed, which in some places was 150 feet deep over the orebody. Production began in early 1971, by which time the top three benches of rock had been excavated and the orebody exposed.The Pipe No. 2 Mine main shaft was started in 1970 and completed in 1973 at a depth of 3,160 feet. Development for exploration purposes was carried out on the 1500 and 2460 levels, and permanent pumping facilities were installed.The surface dimensions of the open pit are 2,200 by 1,600 feet, with the long axis striking northeast. The walls are designed with a 45- to 50-degree slope and the ultimate design depth is 720 feet. The present depth of the pit is 520 feet and production capacity is 6,800 tons of ore per mine day."

Jan 1, 1980

By J. Lu, M. Mohammadi, C. Pelletier, B. Wassink

Chemical reduction of selenate by chromous ions is proposed as a novel method to remove selenate from sulfate-bearing solutions Chromous ions were generated by electrochemical reduction of chromic ions using an electrochemical cell. The investigation was conducted in sulfate medium and under various concentrations of chromous ions (0.0062 to 0.05M), pH 1 to 2.2 and temperature 10 to 60°C. Selenate ions were rapidly reduced by chromous ions to hydrogen selenide. The overall reaction at a chromous/selenate molar ratio of 8 or higher can be expressed by the following reaction. At an initial chromous/selenate molar ratio below 8, the products are hydrogen selenide and elemental selenium. At a lower chromous/selenate molar ratio and pH, more elemental selenium and less hydrogen selenide are produced. The reduction kinetics is controlled by both chromous ion and hydrogen ions concentrations. The reaction rate is first order with respect to selenate, hydrogen ion and chromous ion concentrations. It was found that the selenate reduction rate with chromous is independent of the concentration of sulfate present in the solution. The general rate equation was proposed and the rate constant was calculated as k= 0.38 M-2s-1. An activation energy of 58.7 kJ/mol was obtained in the temperature range from 10 to 50°C. Nearly 100% of selenate can be reduced to H2Se from solution containing 17 ppm selenate in less than 30 minutes at pH 2.2 and 60°C. Various strategies have been tested to remove the produced H2Se from solution. INTRODUCTION Selenium in nature is mostly associated with metal sulfide minerals such as copper, iron, zinc, and lead sulfides (Zingaro & Cooper, 1974). The extraction of metals from ores has the potential for selenium contamination of ground and surface water which can pose an environmental and health concern. Therefore, selenium contamination in the receiving environment is a key issue for many industries (specifically copper industry) and the treatment of wastewater contaminated with selenium is a growing challenge. The effective removal of selenium from contaminated water is very important to support sustainability in the copper industry and the other industries with selenium pollution issues.

Jan 1, 2019

In the last 30 years numerous mining plants have been developed in North America but only a handful of these have required freezing the area where the shaft was sunk. The most recent mine shaft to be sunk using this technique is located on an island off the coast of Louisiana. The project required the input and skills of numerous people in several companies, including the owner, engineers and contractors. The Cote Blanche installation is one of several mines in the area which extract salt from a dome which extends under the Gulf of Mexico. The geology of this area is, however, markedly different from others in the region because there is approximately 460 ft of water logged soil above the salt dome. Because it is not possible to sink a shaft in ground that is this soft, the overburden where the shaft is located must be frozen before excavation can take place. The Cote Blanche mine is a producing facility which was built in 1958 by the Carey Salt Company. The original facility included a 14 ft diameter production shaft and a 7 ft-8 in diameter service/ventilation/escape shaft. This system was installed by The Cementation Company. In 1996 the owner decided to improve both the mine ventilation and production hoisting system by installing a third shaft. This shaft would be designed to extract 650 tons per hour from a depth of 1600 ft and provide 500,000 cfm of ventilation to the mine at a maxium design pressure of 4 in WG. These parameters resulted in a requirement for a 16 ft finished inside diameter concrete lined shaft and a headframe designed as a pressure bulkhead. Because the mine would operate from one level only, the most efficient hoisting system for the application was determined to be a ground mounted koepe running on rope guides. With these criteria fixed Cote Blanche embarked on a program which would see construction start in June 1998 with the first salt produced in February 2001 at a cost of $US18M. The major players in the design and construction were G.L. Tiley & Associates Ltd., BLM Bharti Engineering, Freezewall Inc., Phillips Mining, Geotechnical and Grouting Inc., Don Hart Consulting and Dynatec International.

May 1, 2002

By J. Shibata, N. Murayama

"Rare earth elements are present in more than 100 minerals, of which monazite, bastnaesite and xenotime are typical. Rare earth elements have excellent chemical and physical properties for industrial use in functional materials such as phosphors, magnets, electronic components, abrasives and catalysts. China produces more than 90 % of the world’s rare earths, and Chinese trends significantly influence the demand and price of rare earths. From the viewpoint of resource securement, it is desirable to separate and recover rare earth elements from low-grade resources and wastes. Phosphate gypsum, which is a by-product of wet phosphoric acid manufacturing, contains low concentrations of rare earth elements. In this research, the separation and recovery of rare earth elements from phosphate gypsum were investigated. A series of recovery methods including washing of phosphate gypsum, leaching of the rare earth elements with sulfuric acid, adsorption and desorption of rare earth elements by using ion-exchange resin, and precipitation of rare earth oxalates were carried out. The separation of rare earth elements from Ca2+ simultaneously leached from phosphate gypsum was also investigated."

Jan 1, 2014