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By C. Liu

Corrosion behavior of the stir zone in a friction stir weld of dissimilar A12024/AZ31 alloys was investigated in the immersion test in distilled water (pH=6) for different times. Microstructures and the distribution of chemical elements were analyzed by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). Due to the difference in the corrosion potentials between A12024 and AZ31, the AZ31 alloy constituent in the stir zone was susceptible to the corrosion attack in the distilled water. The corrosion attack was found to occur in the narrow region of the AZ31 alloy adjoining the A12024 region, where there was a low ratio of anode-to-cathode surface area. The corrosion attack became more severe in the AZ31 alloy regions with increasing immersion time. The A12024 alloy region in the stir zone of the weld was protected by cathodic reactivity due to sacrificial anode AZ31 alloy.

Jan 1, 2007

By W. P. Armstrong, O. Owens

"The process of arriving at the size and grade of· (a) a newly discovered body of mineralization, (b) a potential ore resource, (c) an orebody proposed for mining, or (d) the ore reserves in a mine, requires fundamental geological, and geometrical determinations as well as physical and chemical analyses. This paper outlines geological and geometrical features considered critical, in the authors' experience, in realistic reserve determination. These are discussed under the headings ""The Four Cs"". They include the Character, type or nature of the mineralization; the Continuity of various types of mineralization in the deposit; various key concerns in the Calculation besides the mathematics; and the Classification section which refers to basic considerations in classifying a mineral estimate. It is suggested that the responsibility for the calculation of a Resource or Reserve should be that of a geologist experienced in the ore type under review. Further, it should be the responsibility of the board of directors of the company owning the deposit to ensure that a sufficiently experienced person is chosen to carry out the process. IntroductionThe key issue of ore reserves is that they are intended as, a clear-as- possible statement of metal in place in a mineable orebody. Precise, widely understood definitions help convey understanding of the figures, but accuracy requires careful geological input before the calculation is made and a definition is applied. Many recent new mining operations in Canada have experienced serious shortcomings between original ore reserve figures and what was mined. This suggests deficiencies in the actual tonnage and grade calculated in advance of production. The authors suspect that much of the problem is due to a less-than-adequate outline of the orebody before calculating reserves for production or alternatively, treatment of grade and thickness data without regard to an orebody outline. Careful consideration of mineralization and ore continuity is one of the most important aspects of ore geology. Ore reserve calculation should be more than a mathematical exercise."

Jan 1, 1994

By H. Sakurai, M. Kato, F. Tanaka

The Mitsubishi Continuous Copper Smelting/Converting Process employs an electric furnace (CL- furnace) for settling the slag/matte mixture formed in the smelting furnace. The conditions in the CL- furnace change its settling efficiency, resulting in high variability of copper losses in slag. Modifications of the operation and maintenance procedures for the CL-furnace have significantly and sustainably reduced the copper losses in Gresik smelter to below 0.7%. A series of flow patterns evaluation in the CL-furnace demonstrated how the chemical reactions and settling conditions of the CL-furnace has been improved by the new operating procedures. Settling mechanisms for the matte droplets in the CL-furnace is also discussed using image analysis of solidified slag. INTRODUCTION The Mitsubishi Continuous Copper Smelting/Converting Process employs an electric furnace (CL- furnace) for settling the slag/matte mixture formed in the smelting furnace. Since the top-blowing in the S- furnace agitates the molten bath strongly, matte droplets are dispersed over the slag phase when melts flow out of the S-furnace. Thus, the CL-furnace has an important role to settle and recover matte droplets efficiently. Since many papers have ascribed major part of copper losses to matte droplets suspended in slag (Tanaka 2007; Genevski et al., 2008; Starodub et al., 2016), flow patterns of slag in the CL-furnace can affect greatly on the profitability of smelters which have adopted the Mitsubishi process. PROCESS DESCRIPTION Figure 1 illustrates the Mitsubishi process schematically. The Mitsubishi process is the only system for continuous production of blister copper from copper concentrates and consists of 3 furnaces connected by enclosed launders those ensure the minimum emission of fugitives. In a smelting furnace (S-furnace) copper concentrates are fed with flux, oxygen-enriched air to form a mixture of slag and matte which cascades down to a slag-cleaning furnace (CL-furnace). The CL-furnace settle matte droplets in the mixture on the crucible from which matte is siphoned to a converting furnace (C-furnace), while discharging the cleaned slag (CL-slag). The C-furnace converts matte to blister copper by the top-blowing of oxygen- enriched air.

Jan 1, 2019

By J. A. Finch, G. Labonté

"A long-standing objective has been to obtain interpretable measurements of the oxidation-reduction potential in mineral slurries. For this purpose several sensing electrodes (black platinum wire, platinum foil and spiral, gold foil and spiral, and sulphide minerals such as chalcopyrite and galena) were investigated to determine their response to the presence of sulphide minerals in the pulp, and to the addition of reagents commonly used in flotation. The observed discrepancies between the electrodes may be explained using a combination of the classical mixed potential model for complex solutions and the probability of contact between the mineral particles and the sensing electrode. It is shown from laboratory testwork that gold spirals are preferred over platinum electrodes. Finally, some of the practical aspects of using the electrochemical measurements in a plant environment are discussed.IntroductonThe interpretation of flotation of sulphide minerals in terms of electrochemical (electron transfer) processes has brought new possibilities for process control of selective flotation. Investigations on massive and compacted particulate bed electrodes have shown that the flotation of a given mineral in the presence of a collector can be controlled by the potential induced on the mineral surface. Also, phenomena such as collector less (self-induced) flotation, activation by heavy metal ions, and natural selectivity sustained by galvanic coupling during flotation might also be controlled by electrochemical means.The technique for measuring electrochemical potential in slurries is an adaptation of that used for solutions. The measurement of the oxidation-reduction potential of a solution (ORP , Redox, Eh) is usually carried out by immersing a noble metal electrode (platinum, gold or silver) and a non-polarizable reference electrode: Standard Hydrogen Electrode (SHE), Standard Calomel Electrode (SCE), or silver/silver chloride (Ag/AgCl) in the solution. (The abbreviation Eh implies the SHE is the reference electrode.) The potential difference between the two electrodes is measured using a high impedance electrometer. ASTM standard D 1498-76 (revised 1981)(1) covers the practical details of such measurements; however, it does not deal with their meaning either in complex solutions or in mineral slurries ."

Jan 1, 1988

By M. Leroux, C. J. Martin, S. R. Rao, J. A. Finch

"The effect of nitrogen on the flotation separation of sulphides from complex ores from Brunswick Mining and Smelting (New Brunswick) and Mattabi Mines (Ontario) was investigated. The most significant finding was enhanced pyrite floatability after as little as 3 minutes nitrogen conditioning. This was used in a novel sphalerite/pyrite separation process developed on the Brunswick ore. After aeration and Cu/Pb bulk flotation in air using xanthate the slurry was nitrogen conditioned, xanthate added and the pyrite floated in nitrogen. As an example up to 70% pyrite recovery with about 20% sphalerite recovery was achieved. Sphalerite was recovered from the pyrite tailings and the pyrite concentrate by copper-activation, raising the pH to 10 and floating in air. About 65-70% recovery at 35-40% Zn grade was achieved compared to 25% Zn grade by the conventional route. The process offers a promising alternative to current practice which seeks to depress pyrite at all stages. A possible mechanism of the effect of nitrogen is presented. INTRODUCTIONUse of gases other than air in froth flotation has been reported from time to time. [Podobnik and Shirley, 1982; Lin and Metzer, 1975]. Of all the gases, nitrogen would appear to hold the greatest practical promise because of its easy availability and chemical inertness. It is used in froth flotation in chalcopyrite-molybdenite separation [Redfearn, 1983]. The use of nitrogen in polysulphide chalcopyrite. this case is mainly to reduce the oxidation of a compound (Nokes reagent) used as a depressant for There is no reported use of nitrogen in the flotation of other sulphide minerals."

Jan 1, 1988

By Mark Liskowich

When is it the proper time to initiate engagement with various stakeholders, including Indigenous communities? This paper will demonstrate what stage of a project’s evolution is the appropriate time to initiate a stakeholder engagement plan. It will look at aspects to consider when identifying the communities to involve. It will describe the contents of a Stakeholder Engagement Management Plan as well and touch on how tried and true options analyses, such as a Multiple Accounts Analysis can be used to inform the results of the engagement, guide the development of your project and clearly document the engagement process. It will illustrate the benefits of initiating engagement at the appropriate point in your project’s schedule, and the limitations of doing so too early and at later stages of the project engineering. The benefits of this approach can be realized within any legislative Jurisdiction including the Canadian Environmental Assessment Act 2012 and Canada’s new Impact Assessment Act.

Jan 1, 2020

By K. M. Ed

AN explosive is a solid or liquid substance which, when fired by some means, changes into a gaseous product occupying a volume very much greater than its original volume. The great speed at which this change takes place causes the explosive to exert a sudden blow on adjacent material. It is this action which is effective in blasting operations when the explosive, confined in a shot-hole, is fired. All explosives are similar in one respect, in that the change into the gaseous state is accompanied by the production of hot gases or flame. This results from the rapid combustion of the solid or liquid ingredients. Ex-plosives differ greatly, however, in the speed at which the reaction takes place. Black blasting powder, for instance, reacts comparatively slowly, hence the flame persists for an appreciable length of time. High explosives, on the other hand, react much more quickly; consequently, the flame is of much shorter duration. In 'closed-light' or 'gaseous' coal mines, the use of ordinary explosives is generally prohibited, due to their inherent ability to ignite gas or coal-dust by reason of the flame which they produce when fired. For instance, black blasting powder, which produces a flame of long duration, is not ordinarily considered safe to use in such mines; neither are ordinary dynamites, as their flames, while shorter than that of black blasting powder are, nevertheless, of sufficient temperature and duration to cause ignition of fire-damp or coal-dust. For this reason, specially formulated high explosives, called 'permitted' explosives, should invariably be used in such mines.

Jan 1, 1940

By M. R. MacIver, M. P. Pawlik

"An image analysis method based on chord length distributions is applied to the batch settling of polyacrylamide flocculated kaolin suspensions. Two features of the interaggregate void space, the void chord length distribution mean and the white-to-black distribution ratio are extracted from an image series obtained over the two hour settling experiments. This approach produces three signal values, from two different probability distributions that can be measured as an indication of underlying sediment bed density and aggregation state. Further work is required on the physical interpretation of the signal, the image acquisition conditions, and the parameter selection methods. It is suggested that this chord length based feature extraction technique may be a useful signal to monitor during batch settling or thickening.INTRODUCTIONFew in situ techniques are available that can be used to directly measure aggregate properties within sediment beds in thickeners or secondary settlers. Typical process variables monitored include rake torque and height, bed level and pressure, feed rate and density, underflow rate and density, settling rate, and overflow turbidity; yet these process variables are only weakly related to process dynamics (Concha et al. 2014). Additional process monitoring signals, based on the direct measurement of aggregate properties could improve solid-liquid separation control and allow the extraction of more detailed information from batch settling experiments.Several optical methods exist for measurement of moving suspensions of aggregated solids in the dilute concentration regime, such as focused beam reflectance measurement (Peng and Williams 1994), and the turbidity fluctuation method (Gregory 1985). In the more concentrated region of a thickener, acoustic backscatter penetration and attenuation measured with an acoustic probe and changes in the underlying solid concentration in the highly concentrated, near-bed region of a thickener as a function of height and time (Hunter et al. 2012). While machine vision for froth monitoring has been thoroughly studied with at least five commercialized technologies (Aldrich et al. 2010), its’ application to the study of thickening has been limited."

Jan 1, 2016

By J. E. Dutrizac, R. J. C. MacDonald, J. B. O'Reilly

"Sometime around 3000 B.C., primitive metallurgists working in the mountainous regions of Asia Minor bordering on the Black Sea (Pontus) produced a soft, easily fused metal today known as lead. It appears certain that the first metal was made by reductive smelting of galena, but whether this recovery arose by the accidental inclusion of galena in the stones of a fire hearth or whether it occurred as a consequence of simple pyrometallurgical experiments on a series of interesting ""stones"" will likely never be known with certainty. The properties of galena, high metallic lustre, great density and facile cleavage, must have excited the ancients, and such ""stones"" would have been the object of primitive testing111 - Shortly after the discovery of lead, the ancients found that the controlled oxidation of this metal at elevated temperatures yielded smaller amounts of a more interesting material, silver. Again, it is uncertain if the production of silver by primitive cupellation techniques was the result of a fireside accident or the consequence of a deliberate experiment, but the important fact is that silver was produced shortly after the discovery of lead. The techniques for making lead and silver spread gradually throughout the entire civilized world, likely as a result of both technology diffusion and independent rediscovery. The physical properties of lead could not have been overly attractive to the ancients, but silver was a different matter altogether. The gleaming white lustre and relative immunity to oxidation quickly assigned silver to the precious materials category, a status it still enjoys. In early times, argentiferous galena was inevitably processed only for its silver values; lead was generally an unwanted byproduct and was frequently discarded as litharge (PbO) during the cupellation process. The silver was eagerly sought, however, and resulted in considerable mining activity culminating in the famous Athenian silver mines at Laurium at the southern end of the Athenian peninsula."

Jan 1, 1999

By Adrian White

Agenda Overview of pastefill at Kidd Mine Pipeline wear and the need to monitor Steel Loop monitoring Steel Borehole monitoring Monitoring pipe linings

May 1, 2013

By D. Runnels, A. Allaire, J. Fournier, Y. Sylvestre, F. Robichaud

The Goldex operation of Agnico-Eagle Mines (AEM) commenced operations in the spring of 2008. Following some months of initial operation, the grinding circuit capacity was under-performing according to the original design throughput. BBA Inc. (BBA) was commissioned, in February 2009, to study the different options and recommend the quickest and most cost-effective solution to increase the grinding circuit throughput rate. The mandate was to increase the throughput of the grinding circuit to beyond the original design of 7,000 tpd to 8,000 tpd or greater, while retaining the existing SAG and ball mills. The circuit was modelled using JKSimMet software to evaluate the different options, each with a number of different operating parameters. The option of secondary crushing of the SAG mill feed was retained. Comparison of the different options and simulation outcomes, design of the secondary crushing circuit, operating conditions, and initial adjustments in the design and operating results of the new grinding circuit are discussed in this paper.

Jan 1, 2012

By George P. Demopoulos

In this paper the author will provide an overview of over 20 years of research & developments in the area of hydrometallurgical arsenic immobilization that culminated recently in the industrial implementation of the atmospheric scorodite process. The paper will consider various aspects of arsenic fixation in the non-ferrous metal industry from the iron-arsenic co-precipitation process employed to arsenic-bearing effluent solutions; to autoclave processing of arsenical copper and gold feedstocks and the fate of the in-situ formed iron sulphato-arsenate precipitate phases; the precipitation and stability of scorodite; the possible stabilizing role of mineral phases like yukonite, and the development of "scoroditeplus" processes employing novel encapsulation strategies. Emphasis is placed on the characterization and long-term stability of the various forms of arsenic-immobilized phases under either oxic or anoxic conditions over a wide pH range and the establishment of critical links between process parameters and hazardous material stability, contributing thus to advancement of new generation safe and sustainable waste management technologies.

Jan 1, 2014

By Louise Laverdure

The Canadian mining sector has to be innovative and invest in the development of sustainable mining technologies to maintain its international leadership. Natural Resources Canada (NRCan) collaborated with the Canada Mining Innovation Council (CMIC) to define the Green Mining Initiative (GMI) and in order to focus its R&D activities on industry and other stakeholders? needs. The GMI was launched in 2009 to spur innovation in the mining sector and further enhance its environmental performance. The initiative, led by CANMET- Mining and Mineral Sciences Laboratories (MMSL), takes a holistic approach looking at the entire mining life cycle, from design to closure and beyond, through four innovation and research pillars: ? Footprint Reduction, ? Innovation in Waste Management, ? Mine Closure and Rehabilitation, and ? Ecosystem Risk Management. The Canada Mining Innovation Council has also been creating a new initiative on Sustainable Mining, which will bring further focus to environmental aspects of mining, and engaging wide range of research providers to develop research programs complementary to GMI goals.

May 1, 2011

By K. Koyama

As a study to establish a new energy-saving copper recycling process, the copper deposition at a cathode and oxidation of copper(I) at an anode from ammoniacal alkaline solutions containing Cu(I) or Cu(II) were investigated in order to examine the feasibility of electrolysis in this solution.. The current efficiencies were greater than 95% in the current density range of 200 to 1000 A m-2. The current efficiency decreased with the increasing Cu(II) concentration and temperature. In the batch-type electrolysis at the anode, during the initial stage, the current efficiencies were 100%, and the anode potentials ranged from 0 to 0.15V vs. SHE at a current density of 100 A m-2. During the subsequent stage, the current efficiency decreased with time, and the anode potential was around 1.35V vs. SHE where oxygen evolution at the anode surface was observed. As a result, the present electrolytic method can be the core technology in the said copper recycling process.

Jan 1, 2007

By Michel Jebrak, Claude Bellehumeur

Regional and orientation geochemical stream sediment surveys were carried out by the Quebec Department of Energy and Resources in southwestern Quebec, over a part of the Mont Laurier Terrane of the Grenville Province. The area contains some small stratiform zinc deposits. The response of Zn mineralization to geochemical surveys is weak; the known mineralization is not dermed by anomalous samples and consistent patterns. This study uses a technique that increases the geochemical signature of Zn mineralization in filtering out geochemical background components related to lithologies and surficial conditions. The background variations were modelled using principal component analysis, and the filtering technique consists of the partial reconstruction of the data matrix from results of principal component analysis. The filtering procedure considerably enhances the Zn anomalies located in the catchment basins of Zn deposits, and defines some new anomalies in proximity to the marbles of the Mont-Laurier Terrane, the principal metallotect of Zn mineralization.

Jan 1, 1993

By N. Bahrani

Knowledge of the state of stress in the Earth?s crust is very important to the safe and efficient development of underground excavations in mining and civil engineering projects. A number of methods have been developed over the past 40 years to assess the stress field in the rock mass. These range from local estimates derived from compilation of regional stress databases to back-analysis of field observations to dedicated in situ measurements. The Geomechanics Research Centre (GRC) at MIRARCO has a long history of undertaking in situ stress characterization and measurement. In this paper, the stress measurement techniques used by the GRC, including overcoring and undercoring in addition to borehole breakout back-analysis, are briefly reviewed. The limitations and application of each technique for different ground conditions and the challenges involved during the field work and in interpretation of the results are discussed. A successful stress measurement campaign is not limited to acquiring valid local measurement, but must include a careful interpretation and integration of the measurement with other geological and geotechnical context information. Based on our experience, it is suggested that all available stress indicators and data are combined and integrated with the local geological and geomechanical conditions to derive a consistent stress characterization for a given site.

Aug 1, 2013

By Ruan Chi, Zhenyue Zhang, Zhengyan He

In order to understand what governs the leaching of exchangeable rare earth (RE) and impurities and enhance the RE leaching process, the effects of the concentration of ammonium sulfate, pH and leaching temperature on the migration of RE and aluminum (Al) during the leaching of weathered crust elution-deposited rare earth ore was studied. The elution curves for ammonium ion (NH4 +) were also studied to reduce the consumption of the leaching agent. It was found that a high concentration of leaching agent can enhance the leaching process of RE and Al, reduce the breakthrough volume of NH4 + and more rapidly obtain the equilibrium of NH4 +. However, excessive leaching agent can both increase the cost and the burden on the environment. There is almost no variation on the elution curves of RE and Al in the pH range of 4-8 and control of the pH of the leaching agent can be omitted. It is better for the leaching work to be done in summer since higher temperatures can enhance the RE leaching process and improve the use ratio of ammonium. Using 0.1 mol/L ammonium sulfate for leaching 250 g RE ore, 95.42% RE extraction can be obtained when the volume of leachate is 102.6 mL. At this moment, only 18.17% of NH4 + is used to exchange RE and 49.22% of NH4 + is left in the leachate that can be reused as leaching agent by replenishing ammonium sulfate. The results of our studies can provide theoretical guidance for high efficiency and low consumption exploitation of RE ores.

Jan 1, 2016

By Erol Yilmaz

This poster presents results obtained from an experimental test set-up called CUAPS (curing under applied pressure system) allowing to assess the performance and quality of cemented paste backfill (CPB) materials. CUAPS can be used for carrying out a series of tests: one-dimensional consolidation, saturated hydraulic conductivity, pore-water pressure dissipation, and curing under uniaxial stress. The poster presents CUAPS testing preliminary results including uniaxial compression tests (UCS) and mercury intrusion porosimetry (MIP). It was demonstrated that CUAPS-consolidated CPB materials cured under time-dependent stresses provide higher UCS values than standard mould (undrained and unconsolidated) CPB samples. This may be explained by the release of excess pore water within backfill that gives rise to a significant reduction in the total porosity of fresh CPB materials prior to hardening and thus, to higher mechanical strength (UCS) gain. The results obtained from MIP highlighted a good correlation between CUAPSconsolidated and mould-unconsolidated CPB samples. MIP results were also related to UCS values in order to predict the final CPB mechanical strength.

Nov 1, 2008

By P. A. Christopher, R. H. Pinsent

"The Adanac molybdenum porphyry deposit near Atlin, in northwestern British Columbia, was discovered in 1905. It was explored extensively between 1967 and 1980.The deposit is within a complex, multi-phase, quartz monzonite stock that is a satellite of the post-accretionary, Surprise Lake Batholith. Biotite K-Ar dates range from 703 ± 2.4 Ma to 71.6 ± 2.1 Ma, indicating a Late Cretaceous age of emplacement.The deposit comprises an irregular-shaped ring or halo peripheral to a quartz monzonite porphyry dome, or ""cupola': The shape of the ring, and of a smal~ fine-grained quartz monzonite intrusion, and the presence of higher-grade mineralimtion on the eastern flank of the cupola, suggest partial control by a preminera/ structure. The deposit is truncated by a steep, northwesterly dipping, normal fault (Adera Fault) that down-dropped the northern half of the deposit by a minimum of 100 mThe deposit lacks strong zonal alteration but there are narrow envelopes of potassic alteration around some veins and local zones of intense wall-rock silicification. There is considerable retrograde alteration along postminera/ faults and fractures.Molybdenite occurs in veins and fractures, many of which are relatively flat-lying. They occur in all phases of quartz monzonite. Molybdenum is the only element of economic significance. There are vein and skarn occurrences with tungsten, tin, lead, zinc and precious metals peripheral to the deposit.In 1981, Placer Development Limited reported an ""undiluted mineable mineral reserve"" of 151 971 000 tonnes grading 0.063% Mo at a cutoff grade of 0.04% Mo and a strip ratio of 1.5:1."

Jan 1, 1995

By M. Rafieazad, P. Fathi, X. Duan, M. Mohammadi, A. M. Nasiri

"Direct metal laser sintering (DMLS) is a metal additive manufacturing technology that creates highly complex components by fusing metal powder into a solid part. In this study, the impact of surface roughness on corrosion resistivity of AlSi10Mg_200C alloy manufactured through DMLS was investigated. The as-printed DMLS-AlSi10Mg _200C alloy was subjected to various surface finishing processes including grinding and sandblasting. The corrosion performance of the surfaces was then evaluated using potentiodynamic polarization testing and electrochemical impedance spectroscopy (EIS) in a 3.5 wt.% NaCl solution to mimic seawater environment. Surface characterization and corrosion morphology of the samples were assessed by Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray (EDX) spectroscopy. The results of this study show that the surface finishing process and the resultant surface roughness has a significant impact on the corrosion resistivity of the DMLS-AlSi10Mg_200C alloy in the seawater environment.INTRODUCTION Direct Metal Laser Sintering (DMLS), also known as Selective Laser Melting (SLM) (Sames, List, Pannala, Dehoff, & Babu, 2016), Laser Beam Melting (LBM), or Laser Metal Fusion (LMF) (Herzog, Seyda, Wycisk, & Emmelmann, 2016), is an additive manufacturing process that utilizes a precise, high-power laser to micro-join powdered metals and alloys layer by layer to form almost fully dense and functional components in three dimensions from the 3D computer-aided design (CAD) data. Complex geometries not possible with conventional manufacturing processes can be readily manufactured with high accuracy using the DMLS process with no need to time-consuming tooling."

Jan 1, 2018