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By G T. Hefter, P Singh

The effect of using SO2 as an anodic depolariser in the electrowinning of copper from aqueous acid sulphate solutions has been studied using cells without/with a ceramic diaphragm. In all cases SO2-saturation of the electrolyte/anolyte decreased the anode potential by 68 to 75 per cent largely due to a change in the anode reaction from the oxidation of water to the oxidation of SO2 . However, poor quality deposits and low current efficiencies are encountered if SO2 is allowed free-access to the copper being deposited at the cathode. This situation is easily avoided by using a diaphragm to restrict SO2 to the anode compartment and for these conditions the resultant copper deposits are of a similar (high) quality to those obtained in the absence of SO2.

Jan 1, 1999

By Xu C

This paper describes the structure and operation of an interacth.. computer program for mineral industry financial analysis and production planning. It includes comprehensive risk analysis with correlated variables and optimal production scheduling using Lane's balancing cut-off grades and the general dynamic programming approach.

Jan 1, 1995

Coal washery wastes comprise tailings, finer than 0.5 to 0.1 mm depending on the sophistication of the washery, and coarse reject, typically finer than 50 mm. Subaerial disposal of coal tailings slurry at about 30 per cent solids by mass results in the formation of a delta with an average slope of about 1 in 100, representing one extreme. The ravelling of coarse reject on loose-dumping, results in an angle of repose slope with an angle of about 37o (1 in 1.3), representing the other extreme. The pumped co-disposal of coal tailings and coarse reject results in the formation of an upper delta with an average slope of about to one in ten, between the two extremes. The depositional behaviour of these three waste streams is discussed and compared in this paper. The important depositional and material parameters, and a theoretical description of the processes involved, are also presented. Comparisons are made between the depositional behaviour of the various coal washery waste streams, and natural depositional systems, such as rivers, alluvial fans, and scree slopes.

Jan 1, 1998

By Qi P. H

Gold dissolution can be achieved with a number of complexing ligands, all with varying degrees of stability. Processes based on the use of halogens have been known for many years. Beside providing the necessary complex- ing role, the halogens under the appropriate conditions are very effective oxidants for gold. Of the halogens, the gold iodide complexes are the most stable in aqueous solution. Iodine can establish the desired oxidation poten- tial for oxidizing gold, and unlike chlorine and bromine, the oxidizing potential of iodine is mild enough to avoid the oxidation of impurity constituents like metal sulfides. A series of experiments to investigate the fundamental electrochemistry of gold in different halide solutions was performed. Cyclic voltammograms of gold in the presence of 10-2 M chloride, bromide and iodide, respectively show that for a given potential the rate of oxidation is much faster in iodide solution than in either chloride or bromide. An overlay of linear sweep voltammograms for the anodic oxidation of gold in iodide and the cathodic reduction of iodine species on gold provides an effective method for examining the dissolution of gold in iodideftodine solution. The dissolution rates obtained from both electrochemical and actual leaching results are compared. Optimum leaching conditions are analyzed in terms of the iodide/iodine concentrations. Conceptual processes for the recovery of gold and iodide and the regeneration of iodine are discussed.

Jan 1, 1991

The mining. operations of Bougainville Copper Pty Limited are located at Panguna on the Island of Bougainville which is part of the Territory of Papua and New Guinea. Mineralisation in the Panguna area was first established by C.R.A. Exploration Pty Ltd in 1964. Exploration work since then has established ore reserves estimated to be 760,000,000 tons of.0.47% copper and 0.4 dwt./ton gold. An economic feasibility study completed in July of this year has enabled a decision to be made to proceed with a major mining operation. The ore will be mined by open cut methods and will be treated in a conventional concentrator with a nominal capacity of 90,000 short tons per day. The concentrate will be pumped as a slurry through a 15 mile long pipeline to a port established on the east coast where it will be filtered and dried ready for export. Other supporting facilities for the mine include two towns, a 135 megawatt steam power station, and access roads.

Jan 1, 1970

By Higuchi K

In this paper, the history of Japanese coal and gas outbursts is presented and circumstances and countermeasures at the time cf outbursts are summarized statistically. Then the present meth- ods for prevention used practically in Japan are introduced. From statistics, it was reconfirmed that Japanese coal and gas outbursts have occur- ed frequently in the district of geological disturbance, symptoms immediately before out- burst occurrence were the phenomena in connec- tion with failure of a coal seam and outbursts have occurred many times when the number of boreholes had not been sufficient to degas. One of the principal protective method adopted in Japan is the large diameter gas drainage boring which also posesses a stress relief effects. There is a tendency to make diameter of borehole larger to increase both stress relief and degassing effects.

Jan 1, 1986

The weathering profile, in arid terrains, is commonly capped by different kinds of hardened crust, whose formation is related to recent or former climates. One may distinguish silcretes, calcretes and the ferruginous (or ferro-aluminous) laterites. the present keynote address mostly deals with the lateritic regolith and, moreover, the influence it has on mineral exploration. The lateritic regolith, also called "cuirasse", is a result of a massive accumulation of Fe (and/or Al) oxides on top of weathering profiles developed during former, probably seasonal humid, climatic episodes, and whose preservation depends on the characteristics of later climates. The total thickness of such weathering profiles commonly exceeds 50 m, with an almost complete substitution of the rock forming minerals by secondary minerals as kaolinite and Fe-Al oxi- hydroxides (hematite, goethite, boehmite, gibbsite). Such an alteration of the primary minerals assemblage is of course accompanied by significant changes of the chemical composition, as concerns major and trace elements. The latter are distributed amongst the main secondary mineral phases or trapped in some primary resistant minerals, but may also be leached, totally or partially. Gold is also affected by lateritic weathering, as shown for instance by morphoscopic and geochemical studies of gold grains collected in the different horizons of the profile, which indicates some dissolution followed by reprecipitation.

Jan 1, 1988

By Kanchibolta S. S, Brunton I, Tapia-Vergara F

The Split digital image processing system has been implemented in three Australian mines for analysing the size distribution of rocks from the images taken from muckpiles, conveyor belts and tipping trucks. This paper presents an overview of t

Jan 1, 1998

By Carter NB

A statistically-designed experimental program has been used to study compositional and processing variables which influence the development of strength and reducibility of iron ore pellets. The effects of chemical composition and processing variables were investigated by indurating laboratory-made green pellets, of known composition, under approximately isothermal conditions in a pot- grate simulator. Some findings from a six- variable study are summarized in the form of contour diagrams and emphasize the importance of interactions between the variables. Production of strong, highly reducible pellets is possible over a considerable range of combinations of temperature and firing time. Abrasion index (AI) and cold compression strength (CCS) improve as both these variables increase, but reducibility (R) declines, so a compromise is required. When the lime level is too low to form enough slag for bonding, the AI and CCS may be inadequate. Larger additions of lime tend to improve AI and CCS, with only slight effects on R. Finer grinding of the balling feed (i.e. higher Blaine index) tends to improve Al and CCS without

Jan 1, 1980

By Thirumalai K, Peluso R. G

The United States has more than 45 billion tons of economic coal reserves in seams above 10 feet thick and current underground production from thick seams represent less than three per cent of the total production. A tripling of underground production from thick seams is necessary within the next 10 years to meet U.S. coal production demands. An analysis of underground accident and production data is presented in the paper. A study of accident and injury distribution in different coal seam heights in the eastern and western part of the United States in seams ranging in thicknesses from 5 to 15 feet indicates that the seam thicknesses do not produce adverse impact on underground injury incidence. Accidents associated with roof falls and haulage account for about 70 per cent of underground mining injuries.

Jan 1, 1976

Studies of Theological effects in grinding hold promise for improving this energy-intensive process. Six surveys of the Hellyer ball mill were conducted. The stream and sizing data from these surveys were balanced by JKMbal to compare the mill

Jan 1, 1994

The sulphide ores of the Kalgoorlie goldfield have long been looked upon as' refractory, involving special metallurgical treatment. For many years two kinds of treatment have been practised-(l) wet treatment, including fine grinding, amalgamation or concentration of the free gold, concentration of the sulphide minerals with subsequent roasting and cyanidation, and cyanidation or bromo-cyanidation of the residue from the concentrating operation; (2) dry-crushing of the ore and roasting the whole of thecrushed ore, amalgamation of the gold in the calcine during fine grading, followed by cyanidation. The wet treatment was advanced a stage further when, in 1929, the Lake View and Star Ltd. adopted large scale flotation. As a consequence, however, further metallurgical problems were introduced. This paper covers the investigation, ,of one of the most prominent of these problems.Flotation preceded by strakes was satisfactory to a point.The flotation concentrate consisted largely of auriferous pyrite and tellurides, and the gangue minerals in the concentrate were practically barren.Several sources of loss of gold values were, however, found to be associated with this circuit, viz.-(a) There was the loss of gold in the flotation tailing.(b) Loss by dusting during roasting of the flotation concentrate.(c) Loss of gold in the cyanided residue.

Jan 1, 1937

By R Wei, Y Peng

With the depletion of high-quality ores, the efficiency of extracting difficult gold ores through flotation and leaching becomes very important in the mining industry. Iron contaminants, sulfide and carbonaceous coatings on the surface of gold and gold bearing minerals significantly hinder the recovery of gold during gold processing. As the surface of gold minerals is easily contaminated, coatings of iron oxides and iron hydroxides originated from the grinding process and oxidation of iron sulfides will cause a retarding effect on both gold flotation and leaching.To mitigate the processing issues caused by undesirable surface coatings on gold minerals, a new technology in treating surface coatings of iron contaminants has been developed. The pulp potential and pH of the slurry are altered to allow dissolution of surface coatings which are further excluded by the use of complexing reagents. The current work shows that iron contaminants can be removed from the surfaces of gold through Eh-pH adjustment and chelation which result in significantly improved gold flotation response. The addition of complexants aids the formation of iron chelates to prevent the iron species in the solution from forming iron oxide and iron hydroxide in the flotation conditions.CITATION:Wei, R and Peng, Y, 2014. Mitigating the effect of surface coatings on gold processing, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 187–192 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By S Serp, M Duchateau, P Chevreux

Molten salt reactor (MSR) is a promising advanced reactor system aiming to the transmutation of minor actinides such as americium in order to reduce the inventory of ultimate nuclear waste. The fuel is a molten salt in which actinides are homogeneously dissolved in the liquid phase. A chloride salt may be retained for this concept, as it provides low melting point, high solubility of actinides, harder neutron spectrum. To avoid corrosion and precipitation issues, molten salt composition has to be carefully controlled with impurity content as low as possible. Obtaining pure actinide chlorides without contaminants such as oxide, oxychloride, hydroxide and water is still a challenge. To prepare actinide-bearing salt, the chlorination of actinides oxides was investigated in an unstirred reactor under flowing gas as solid-gas reaction. The carbochlorination of PuO2 were performed in the temperature range of 600 to 800°C with chlorine gas as a chlorinating agent and the presence of solid carbon. PuCl3 was successfully synthesised by this method and characterised by X-ray diffraction measurements but some impurities such as oxide phase remain inside the formed product. Refinements of anhydrous and hydrated PuCl3 phases by Le Bail method were also performed for crystalline materials definition. Conversion mainly depends on the chlorinating temperature and the contact between the oxide and the chlorinating agent. A conversion value of 70–80 per cent was achieved at 700°C from PuO2 with quite high specific surface area. The conversion rate was not improved with increasing the chlorination time. The volatilisation of Pu was observed during the carbochlorination experiments. To avoid a loss of Pu caused by sublimation, the chlorination temperature should be limited to 650°C despite that the conversion of PuO2 to PuCl3 was enhanced by increasing temperature. Both carbochlorination and hydrochlorination of AmO2 were also carried out leading to the formation of AmCl3. These first results suggest that americium oxide was chlorinated more readily than plutonium oxide. The purity of produced PuCl3 and AmCl3 still deserves further investigations.

Jun 19, 2024

By Leahy G. J, Moxon N. T, Nicol S. K

Experimental work is described in which extremely dilute aurocyanide liquors are treated with novel surface-active complexing agents to produce a hydrophobic aurocyanide species. Subsequent aeration of these liquors causes accumulation of such species at the air-water interface and the aurocyanide complex is transferred to a froth concentrate. A detailed performance assessment of this process is made and this knowledge used in the design of a pilot plant facility. Early results indicate the feasibility of the selective recovery of aurocyanide ions from reclaimed residue dam water (approximately 0.2ppm Au) with upgrade ratios of the order 180:1. A further study was made applying ion flotation to the recovery of gold from a carbon-in-pulp (CIL) feed liquor (approximately 1.0ppm Au). The probable economics of this process compared to conventional CIL processing is also described. Successful development of countercurrent ion flotation for concentrating solids-free gold solutions may offer a lower cost alternative to existing gold ore processing technologies, or in more secondary applications such as concentrating dilute gold solutions or heap leach runoff. The technology may also have more generalised applications to other heavy metal process- Ing.

Jan 1, 1991

By Manca PP, Rossi G, Lipari D, Knissel W, Massacci G, Licheri P, Fioravanti E, Helms W, Lai S

Mining of the massive complex sulphides orebodies of Campo Pisano and San Benedetto (Southern Sardinia, Italy), dates back to before Christ, though their exploitation with modern technology was only resumed in the middle of the last century. The increasingly adverse economic conditions and the weakness of both country rock and mineralization were concurrent in forcing the Company's management to develop suitable high-productivity stoping methods. In the framework of a project fi- nanced in part by the Commission of the European Coranunities, and carried out in cooperation with the Universities of Cagliari (Italy) and Clausthal (Germany), a cemented backfill stoping method was developed. The concrete mix preparation and placement facil- ities, study of the cement mixes and endeavaa-s to optimize the methods are described. The monitoring system for measuring stress evolution within the emplaced backfill is illustrated together with the successful replacement of part of the Portland cement

Jan 1, 1992

By I Arburthnot, N Lawler, C Loan

The function of a thickener is to optimise and accelerate the process of gravity sedimentation. The desired end product (be that maximised concentrated solids or clarified liquid) determines how the thickener is designed and operated.Significant internal research, together with extensive on-site piloting, by Outotec has resulted in the determination that the application of the appropriate amount and type of shear to hindered settling aggregates can result in a substantial change to the sedimentation process. A new patented technology, called shear enhanced thickening (SET), has been developed. SET results in considerable design implications for full-scale thickeners, including a substantial reduction in required footprint and/or significant increases in underflow density.The development of SET, combined with laboratory and pilot scale verification, will be discussed along with the introduction of this technology to a number of full-scale thickeners. The associated implications and benefits for industrial thickeners are outlined.CITATION:Loan, C, Lawler, N and Arburthnot, I, 2012. Industrial scale results from shear enhanced thickening technology, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 341-346 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

By Ruston R

When coal mining first commenced in Australia, the principle objective was low cost production with development directed toward recovery of 'easy' coal. Future expans- ion of these early mines into major under- ground operations was neither envisaged nor planned. As the demand for coal grew, these mines were expanded to increase output. however, the absence of initial ventilation planning brought about ad hoc systems wh;ch required continual repair and upgrading. These systems proved satisfactory in the short term because the majority of undergrouni coal mining operations were carried out at relatively shallow depths where gas emission rates were low. By comparison, coal is now being won at depths exceeding 500 metres with a corresponding increase in gas flow from the working seams and adjacent strata. The following paper addresses, firstly, the planning and institution of a ventilation system in a mine where previous inefficiencies were many, and secondly, the value of pre- planning a mine ventilation system in the early stages of mine development, and the need to continually review and upgrade the plan to account for unforeseen ^hanges.

Jan 1, 1983

By Dinuzzo P, Wychie J, Desoe C

The Selwyn Gold-Copper Mine is located 150 km southeast of Mount Isa within Proterozoic units of the Mount Isa inlier (Figure 1). Mineralization in the mine area is associated with strongly sheared ironstones and iron rich schists at the base of the mid- Proterozoic Staveley Formation. The ironstone horizons outcrop as a series of dominant ridges over a 10 km strike. Economic gold-copper mineralization has been defined in 4 separate zones within a 3.5 km length of the outcropping ridges. A current combined geological resource for the deposits is 5.3 million tonnes of 5.0 g/t Au and 2.02 Cu. Weathering of the deposits has resulted in a pronounced vertical zonation of mineralogy, especially copper, within the ore zones. This has produced 3 separate ore types which require different treatment techniques. The categorization is based on copper content and zones are termed leached (surface), oxide and sulfide. Ore removed from the pits will be mainly leached and oxidized with minor sulfide near the pits final depths, while the underground ore will be from the sulfide zone with minor oxide in some areas.

Jan 1, 1989

By L Clarke, R N. Campbell, F Bourke, J Anderson

Lithological units have been classified geotechnically with mechanical tests and discontinuity measurements from the GRD Macraes Limited, Macraes Gold Project and Rotowaro coal mine open pits, New Zealand. Using these measurements slope stability probability classifications (SSPC) have been quantified based on an adaption of Hack's (1998) SSPC system which places less influence on rock quality designation and unconfined compressive strength than previous slope/rock mass rating systems. The Hack weathering susceptibility rating has been modified by using the chemical index of alteration values from XRF major element analysis. Slaking and weathering is an important parameter in slope stability in the Waikato Coal Measures and Otago schist lithologies and hence a non-subjective method of assessing slaking/weathering in relation to the chemical index of alteration has been introduced. Other major components of this adapted SSPC system are the inclusion of rock moisture content and rock strength anisotropy effects on slope stability. This paper explains the systematic approach of using the adapted SSPC system to classify slope stability probability. The main modifications of Hack's SSPC system are the introduction of rock intact strength derived from Mohr-Coulomb failure criteria which has been adapted for varying moisture content, weathering state and confining pressure. It is suggested that the subjectivity in assessing intact rock strength within broad bands in the initial SSPC system is a major weakness of the initial system. Initial comparison of rock mass friction angles, cohesion and strengths derived from the adapted SSPC are compared with results derived from modified Hoek-Brown criteria, MRMR and SMR classification systems. The advantage of the modified SSPC system is that slope stability probability, maximum batter and overall slope height and overall slope angle for open pit walls can be predicted in addition to orientation dependent and orientation independent stability. Examples are provided, using the modified SSPC system to predict initial optimum pit slope designs in proposed greenfield mine sites.

Jan 1, 2000