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By S Steffen, S Talu, J Poulsen, G Watt, A van As, J S. Ooi

The economic success of cave mining projects is significantly influenced by the secondary fragmentation size distribution of the caved orebody and making the fragmented ore available for extraction. If the cave does not propagate as predicted, it may lead to stalled cave growth and/or localised preferential caving. This can cause significant ore loss and the inclusion of excessive waste in draw columns, both of which damage the economic value of the project. Uncontrolled caving can have severe consequences for the safety and economics of mines. Such safety risks include air blasts due to the formation of excessive air gaps and damage to infrastructure due to surface subsidence. Monitoring the cave-back delivers critical feedback that is required to exert control over its propagation and reduce the likelihood of adverse consequences. Current methods for monitoring cave propagation include access through open holes, microseismic monitoring systems, time domain reflectometers and extensometers. All of these monitoring systems rely on stable holes for installation and ongoing data collection. However, cables in holes often get sheared due to ground movement in the seismogenic zone well ahead of the cave front, rendering the systems useless. To resolve this issue, Elexon Mining, with the support of Rio Tinto, developed the Networked Smart Marker system, which is based on Elexon’s Smart Marker technology. This system provides a more robust and versatile alternative to other cave monitoring systems as the data is transmitted wirelessly through rock, and thus is not vulnerable to hole shearing/dislocation experienced with current cave monitoring systems. Installations at the Argyle block cave have proven that the Networked Smart Maker system can continue to provide information on the cave-back’s location long after all conventional monitoring systems have failed. This paper summarises the findings from these installations and highlights the benefits for all geotechnical monitoring systems reliant on the stability of drill holes to remain functional.CITATION:Steffen, S, Poulsen, J, Van As, A, Talu, S, Watt, G and Ooi, J S, 2016. Wireless system for monitoring cave-back propagation, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 251–256 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

Air tabling of zircon-rich non-conductor products containing quartz enables most of the fine quartz present to be rejected without a markedloss of zircon. The coarser quartz in the air table feed can be separated from the zircon by screening one or more air table products, the oversize products containing most of the quartz and little of the zircon. Air tabling, with or without screening, is more efficient than wet tabling alone for the removal of fine quartz, but not for the removal of coarse quartz. Practically all of the quartz can be separated from the zircon by using wet tabling in conjunction with hydraulic classification, or by using air tabling in conjunction with dry launder treatment, in which a degree of sizing takes place that is advantageous for subsequent air tabling.INTRODUCTIONBack-dune and inland beach sand deposits usually contain fine wind-blown quartz, and neither spiral nor wet table concentration, alone or in conjunction, makes a clean separation of heavy minerals from quartz. Many rutile plants recover rutile and zircon from a low-quartz, wet-table concentrates by means of magnetic and electrostatic separation; some rutile and zircon are lost in the table tailings. Other rutile plants, and two of the ilmenite plants in Western Australia, recover rutile or ilmenite respectively, from a spiral concentrate containing several per cent of quartz, and then subject the non-conductor product to an additionalgravity concentration process to separate the zircon from the quartz. Some zircon is lost in the additional gravity process, but all of the rutile or ilmenite in the spiral concentrate is, or should be, recovered as high-grade concentrate. The higher recovery of rutile or ilmenite by this treatment method is offset by the expense of drying part of the feed twice, as a wet process is usually used to separate the quartz...

Jan 1, 1962

By Honeycombe R. W K, Greenwood J. N

Powder metallurgy has been developed rapidly in the last twenty years by overseas metallurgists. The technique of making the powders and their subsequent pressing and sintering into useful forms has' only been introduced into Australia under the stress of war-time economic conditions.The technique involved has very little in common with our usual methods of fabricating engineering alloys by melting the ingredients to a homogeneous mass, followed by casting to shape or casting to ingot form and shaping by application of pressure-so-called mechanical working. On the other hand, the technique includes operations, such as milling and sizing, familiar to the primary metallurgists.The compacting of metal or other powders finds important application in two outstanding fields of engineering production: (a) in making porous bearings and contact brushes, in which such a material as powdered graphite can be incorporated; (b) in making cutting tool tips of hard -carbides, which have a melting point too high to make casting feasible, and which would be too brittle in the cast condition in any case. In both these cases; the final article can be made of the desired shape and size (subject to shrinkage allowances) whilst the compact is in a soft and readily machined condition a consideration of great importance in connection with the hard carbides.In order to develop the necessary equipment and technique and at the same time to assisil in the war effort, it was decided to divert the research work of the Metallurgy Department of the University of Melbourne to the problems associated with the production of hard carbides from local raw materials and the sintering of such into tips for cutting tools. Since this work was started at least two industrial concerns have started to produce these materials in the Commonwealth.The work. to date has included (a) the purification of crude cobalt oxide from Risdon and the reduction of this to metal Particles of less than 10 p. diameter; (b) the production of tungsten powder from King Island scheelite and its conversion into tungsten carbide with particle size less than 4 p. diameter; (c) the sintering of the latter product, using the former as a bond; (d) the production of titanium carbide from titanium dioxide; (e) the separation of columbium and tantalum oxides from a Northern Territory tantalite, and the conversion of these into the respective carbides.

Jan 1, 1942

By Misra V. N, Cheng C. Y

Two types of Mt Tom Price hematite iron ore from Hamersley Iron P/L were tested using a Humboldt Wedag Jones P40 wet high intensity magnetic separator (WHIMS). The parameters tested were magnetic intensity (7000, 9000 and 11 000 Gauss), groove plate type (8R and 12R) and gap width (2.5 and 1.8 mm). It was found that at 9000 gauss magnetic intensity, reasonably high-grade and recovery in the concentrate were obtained. At 2.5 mm plate gap width, the 12R groove plate performed slightly better than the 8R groove plate. Further testwork is recommended to optimise the magnetic intensity, feed flowrate and pulp density, wash water pressure and flowrate with 12R and 8R groove plates at 2.5 mm gap width.

Jan 1, 1999

By J. B. Brodie, C. Pelletier

"The vulnerability of Canadian and U.S. companies, their directors, officers and employees to onerous penalties associated with violations of environmental statutes and common law actions has provided the impetus for the increasing use of environmental audits. This trend is developing in direct proponion to the cost and difficulty of obtaining liability insurance. Companies operating in British Columbia should be cognizant of developing legislative and enforcement trends and their implications for individual and corporate responsibility. Canadian mining companies doing business in the U.S. should be particularly aware of the environmental exposure which may be assumed with property acquisition or by operations which produce or use any of an ever-increasing list of regulated substances.The environmental audit is now a key component of prudent business planning which will identify noncompliances and environmental liabilities, outline defensive strategies, and assist in a legal defence should charges be laid. This paper will discuss the purpose and mechanics of an environmental audit with emphasis on those features which will maximize protection against statutory and common law actions.IntroductionThe environmental audit is but one weapon in a comprehensive defensive strategy for corporate and individual survival in an increasingly litigious world. The principles of the environmental audit have been formulated as a logical response by management to an ever-growing list of environmental vulnerabilities, which often have the potential to result in plant shutdowns, prosecutions or fmancial liability of major proportions. Accordingly, the audit may play a critical role in maintaining profitability as well as assisting in the defence of a company and its employees against actions taken by regulatory agencies and citi7.cns under statute and common law. Should convictions result from these actions, the penalties are likely to be ameliorated by the demonstration of due diligence through management policy supporting the audit procedure.An awareness of environmental sensitivities, strict adherence to licensing requirements, and planning for environmental emergencies are now generally considered to be as important to profitable performance as operating costs, metal prices, and labour peace. Why is this so? The increased priority given to environmental matters is partly a result of changing attitudes amongst the mining profession, but perhaps more importantly, it is also a direct consequence of the proliferation of ever more stringent environmental legislation, the targeting of management for responsibility and the draconian penalties imposed for violations of such legislation. Contributing to this trend are recent court decisions involving disputes of an environmental nature in which the standard of care required for a successful defence now requires almost super-human diligence in environmental management. The principle of ""strict liability"" (in which negligence or permit violation does not have to be shown) is also being increasingly applied in the resolution of civil actions."

Jan 1, 1988

By Shahab Alizadeh, Ahmad Khodadadi Darban, Mehdi Mohseni, Mahmoud Abdollahy

This study probed the selective separation of lanthanum and yttrium in a nitrate medium in the presence of aluminum and calcium impurities using di-(2-ethylhexyl) phosphoric acid (D2EHPA). The factors studied in a central composite design (CCD) included extractant concentration, pH, concentration ratio of total impurities to rare earth elements, and interaction of these three factors. The extraction mechanism and types of extracted metal-containing species were delineated by the slope analysis method. The obtained thermodynamic data showed that lanthanum and yttrium extraction by the D2EHPA extractant was exothermic. The extraction of both rare earth elements was accompanied by an entropy reduction. The negative magnitude of ΔS in yttrium extraction reaction suggests stronger D2EHPA-Y(III) complexation relative to La(III). As entropy decreased and enthalpy increased, the extraction process became unspontaneous. Using the proposed flowsheet, lanthanum and yttrium products with > 90% purity were obtained.

Aug 10, 2021

A simple and cost effective technique to increase fragmentation and burden velocities without making major modification to the overall blast design is with ALTERNATE VELOCITY LOADING OR BOOSTERING OF ANFO. The technique requires the placement of a cartridge or slug of explosive, having higher density and detonation velocity than ANFO, every few feet in an ANFO column. The greater the difference in density and detonation velocity of the Alternate Velocity Load to ANFO, the more pronounced are the results. Emulsions were selected as the Alternate Velocity test explosives because they detonate closer to ideal conditions than most other commercial explosives.

Jan 1, 1989

Variations in product distribution in the carbon-sulphur dioxide system due to variations in reaction temperature, sulphur dioxide concentration in the feed gas, and gassolid contact time were studied in detail for a brown coal char. The results were compared with those for two wood chars, a coke prepared from Liddell coal and two cokes prepared from Ac1and coal. Conditions were chosen such that gas-solid diffusion rates did not hinder chemical attack of the carbon.With brown coal char under suitable conditions, the selectivity of sulphur in the sulphur dioxide fed, to either elemental sulphur or carbon disulphide, was in excess of 90 per cent. The wood chars gave very similar product distributions Ito brown coal char. However, the cokes from Ac1and and Liddell coals were respectively approximately three and seven times less reactive than the brown coal char.The approximate carbon holdup required to just achieve total conversion of sulphur dioxide, and thereby achieve high selectivity to elemental sulphur, is given as a function of reaction temperature.

Jan 1, 1974

By Zorigtkhuu Davaanyam, Bern Klein, Stefan Nadolski, Amit Kumar

"The High Pressure Grinding Rolls (HPGR) is a relatively new comminution technology that has been shown to be more energy efficient compared to semi-autogeneous (SAG) mills. Full and fair consideration cannot be given to HPGR-based comminution circuits in early stage projects, because presently pilot scale testing is required for assessing and sizing; pilot scale testing requires bulk samples weighing more than one tonne. A CAMIRO research program was conducted at the University of British Columbia to develop bench scale tests that would reduce the quantity of sample required to assess HPGR.Three test procedures were developed.1. The Direct Calibration Methodology calibrates piston press test results to pilot scale test results such that piston press tests can then be used to determine the energy–size reduction relationship for a range of ore types.2. The Database Calibrated Methodology, which is similar to the Direct Calibration Methodology except that it calibrates piston press tests against a database of pilot scale and piston press tests.3. The Semi-Mechanistic Methodology was developed to use piston press test results as an input for an HPGR based energy-size reduction performance model.Through utilization of these methodologies, the energy–size reduction performance of an HPGR can be predicted with minimal sample requirement. In addition, piston press testing is far more cost effective, faster, and accessible than pilot-scale HPGR testing.IntroductionOne could argue that in the future, decisions regarding selection of comminution circuits will be made primarily on the basis of energy consumption. The following facts and predictions support the argument:"

Jan 1, 2015

By Steve Kral

For an industry that provides more than half of the nation’s energy needs, the U.S. coal industry still attracts negative publicity. However, the nation’s energy appetite continues to increase. And political leaders and the public are beginning to understand that alternative fuels will not be enough to keep up with that appetite. Does that mean the nation will now embrace the coal industry? No, according to speakers at the Rocky Mountain Coal Mining Institute (RMCMI) meeting. The industry still needs to sell the public on coal’s advantages over other fuels. And the industry must continue to develop technology that will allow coal to meet and exceed strict clean air and clean water regulations.

Jan 1, 2002

By N. Vayenas, G. Yuriy

"The combination of a predictive reliability assessment model and discrete-event simulation can be an effective methodology to study the impact of equipment failures on the capacity of production systems in mines. In our case, a predictive reliability assessment model using genetic algorithms is combined with a discrete-event simulation model to analyze mine equipment systems.Discrete-event simulation involves modelling of real-life systems based on variables and events that occur or change at distinct points in time. The Simul8 simulation software, by Visual Thinking, is used in this research. It is a two-dimensional (2D), discrete-event simulation/ animation software tool for creating realistic depictions of manufacturing and materials handling systems.The simulation model developed for the purpose of this research represents a typical two-level, sub-level stoping section of an underground mine in the Sudbury region in Ontario, Canada. This 2D model was created to assess the impact of equipment failures to a mine’s production throughput. In more detail, using mean time between failures (MTBF) data of scooptrams derived from a reliability assessment model based on genetic algorithms, LHD failures are incorporated into the simulation model. These failures cause production interruptions to the development cycle and consequently loss of hauling capacity.Another purpose of this research work is to demonstrate how low-cost simulation tools such as Simul8 can be successfully applied to model underground hard rock mining operations. The research discussed in this paper is carried out by the Laurentian University Mining Automation Laboratory (LUMAL)."

Jan 1, 2005

A large lab apparatus was designed using a scale-down methodology based on the design legacy of the current FLSmidth commercial forced air flotation machines. This new apparatus, along with a new test methodology, was used to evaluate new rapid prototype concepts. The apparatus was designed to monitor bubble size, power, pumping capacity, Jg, velocity profiles, froth character, and tip speed. The methodology developed follows a sequence that goes from hydrodynamic tests and solids suspension tests to a flotation kinetic test. This methodology has been demonstrated to be a good tool to determine the effect of machine design changes on flotation.

Jan 1, 2012

By Vaughan J. P

The Pegmont deposit is a stratiform Pb-Zn sulphide body occurring in a thin, iron-rich metasedimentary unit situated near the top of the Kuridala Formation, a part of the Mary Kathleen Group of the Middle Proterozoic"Eastern Geosyncline" succession of the Mount Isa-Cloncurry district. The deposit appears to have developed in a shallow basin or depression on a sea or lake floor.Detailed chemical and mineralogical study of seven diamond drill cores through the ore horizon shows that in addition to galena and sphalerite the orebody contains a large range of iron-rich silicates and aluminosilicates.Further, five drill cores selected to represent a section from basin centre to basin edge exhibit clear and systematic chemical and mineralogical changes in the ore horizon in both a vertical and, most importantly, ill a lateral sense.Reconstruction of the sedimentary environment of the ore horizon as a whole shows this to be a silicate facies of a phosphatic, manganiferous iron formation or, more accurately, of "ironstone" in the sense of James (1966, U.S. Geol. Surv. Prof. Paper 440, chapter W).On the basis of both mineralogy and chemistry this silicate facies may be subdivided into three microfacies according to the dominant iron silicates characteristic of each: a fayalite microfacies, a hornblende-clinopyroxenemicrofacies, and a garnet microfacies. Significant Pb-Zn sulphide concentrations are confined almost entirely to the fayalite microfacies.

Jan 1, 1979

By Adeyemi Adesina, Subhabrata Mishra, Syed Mohammed Mustakim, Malaya Kumar Jena, Shaswat Kumar Das

Utilization of low-grade manganese ore adopting the carbothermic reduction roasting process is a proven method to produce high-grade manganese ore. To minimize industrial waste and protect the environment, gas cleaning plant sludge (GCPS), which is a solid waste from steel industries, was employed as a reductant to perform the reduction roasting process. The optimum conditions to carry out reduction roasting of the low-grade manganese ore were found to be: a roasting temperature of 950 °C, a residence time of 2 h, 40% GCPS as reductant, and magnetic separation at 5000 G for a manganese ore size of –10 mm. A lowgrade manganese ore comprising Mn grade 31.27% and Fe grade 19.78% having a Mn/Fe ratio of 1.58 containing a high silica content of 26.48% was used for the carbothermic reduction roasting having mineral phases of pyrolusite (MnO2) and hematite (Fe2O3) as found from XRD. The gangue minerals were separated during the magnetic separation, and the upgraded product was obtained, which reached a maximum value of TMn 49.5% with RMn 76.55% and TFe 62.19% with RFe 42.51%. In the study, activated charcoal (AC) was also taken as a reductant for comparative analysis; the experimental results revealed that GPCS performed better than that of the AC, showing potential to be used as a reductant in metallurgical industries. However, the resultedMn/Fe ratio was very low for the reduced sample; therefore, it can be used for smelting along with high-grade manganese ores as a feed.

Mar 5, 2021

By K H. Esbensen, K Engström

The conclusion from the debate over the last decade in the mining sector is that, for grade control, reverse circulation (RC) drill sampling gives more reliable results due to less sampling problems than blasthole samples. However, by conducting the latter with well-controlled procedures there still exist fair possibilities to counteract the major blasthole sampling problems and achieve fit-for-purpose representativeness, especially if based on minimal loss of fines. In the present PhD study, extensive replicate experiments and variographic characterisations are conducted to evaluate the performance of manual blasthole (BH) sampling and sectorial segment sampling. The experiments were performed in Luossavaara-Kiirunavaara AB (LKAB)’s Leveäniemi open pit mine in the north of Sweden. The experimental area is an apatite-magnetite iron ore deposit of the Kiruna type, with the demand to exhibit a maximum of local heterogeneity to allow the experiment the largest possible conclusion powers. Gathering and splitting the complete BH drill cutting cones (fines cone, coarse cone) served as an authoritative reference on which to assess the representativity of the two BH sampling methods.Results show that manual BH drill sampling is able to produce samples with an acceptable accuracy and precision if performed properly and with insight. Based on variographic comparison, segment sampling shows similar precision for chemical grades as the manual sampling, while the particle size distributions were more deviating for segment sampling than for manual sampling at the high and low size ranges. Possible reasons for these partly surprising results are discussed.For further investigation of the performance of BH versus RC drill sampling, a second experiment has been planned on a parallel profile. This will result in an unprecedented opportunity for a full variographic comparison between RC and BH sampling, aimed at designing specific, fit-for-purpose sampling procedures as a function of ore quality, cut-off grades and important contaminant levels.CITATION:Engström, K and Esbensen, K H, 2017. Blasthole sampling (replicate and variographic experiments) in LKAB open pit iron ore mines – fit-for-purpose representativity?, Australia, in Proceedings Eighth World Conference on Sampling and Blending , pp 85–96 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2017

By Gerald Verbeek, Erick Baziw

Cone penetration testing (CPT) is a popular and cost effective tool for geotechnical site characterization. CPT consists of pushing at a constant rate an electronic penetrometer into penetrable soils and recording cone bearing (qm), sleeve friction (fs) and dynamic pore pressure (u) with depth. The measured qm, fs and u values are utilized to estimate soil type and associated properties based predominantly on empirical correlations. The cone bearing measurements are highly susceptible to additive measurement noise for sandy, silty and gravelly soils. This measurement noise results in high peaks due to interbedded gravels and stones and low peaks due to softer materials or local pore pressure build-up. To date there has been little progress in filtering this additive noise aside from ad hoc techniques, which include discarding qm measurements and smoothing/averaging qm measurements. This paper outlines a qm filtering technique which attempts to put structure into the estimation problem. In this case, the dynamics of the cone bearing measurements are modelled within a state-space mathematical formulation and a Kalman filter (KF) is then utilized to obtain optimal estimates of qm. The mathematical details of the qm KF algorithm are outlined in this paper along with the results from a challenging test bed simulation.

Sep 8, 2021

By Gerald Verbeek, Erick Baziw

Cone penetration testing (CPT) is a popular and cost effective tool for geotechnical site characterization. CPT consists of pushing at a constant rate an electronic penetrometer into penetrable soils and recording cone bearing (qm), sleeve friction (fs) and dynamic pore pressure (u) with depth. The measured qm, fs and u values are utilized to estimate soil type and associated properties based predominantly on empirical correlations. The cone bearing measurements are highly susceptible to additive measurement noise for sandy, silty and gravelly soils. This measurement noise results in high peaks due to interbedded gravels and stones and low peaks due to softer materials or local pore pressure build-up. To date there has been little progress in filtering this additive noise aside from ad hoc techniques, which include discarding qm measurements and smoothing/averaging qm measurements. This paper outlines a qm filtering technique which attempts to put structure into the estimation problem. In this case, the dynamics of the cone bearing measurements are modelled within a state-space mathematical formulation and a Kalman filter (KF) is then utilized to obtain optimal estimates of qm. The mathematical details of the qm KF algorithm are outlined in this paper along with the results from a challenging test bed simulation.

Oct 1, 2021

By Marilia S. de Magalhaes

Keywords: sinter, characterization, agglomeration, iron ore Iron ore sinters are the main burden of blast furnaces for pig iron production. The evaluation of these agglomerates is very important due to their properties affect indirectly the productivity and costs of production of the steel industry. In the sintering plants, the standard procedure of sinter assessment has been carried out by particle size control, bulk chemical analyses, tumbler and/or shatter tests and determination of reduction degradation and reducibility indexes. Microscopy techniques have just been applied to characterize sinters produced in pilot conditions, however, these techniques, the classical ones and the less traditional, allow enhancing the industrial sintering process assessment. For investigation of the phases, microstructures and fabric, reflected-light and scanning electron microscopy(backscattered electrons images) were used; for micro analytical chemical examination, energy-dispersive X-ray spectrometry; for Kikuchi patterns registers, electron backscattering diffraction. In addition to the microscopy techniques, the magnetic behavior was depicted by means of magnetic susceptibility measurements. Iron ore sinters are made up by hematite, magnetite, silicoferrite of calcium and aluminium and silicates. These phases develop either during sintering or, in some proportion, represent remnants of ores and fluxes; this is the case of some hematite and Mg-bearing silicate, respectively. From the magnetic susceptibility results, three different behaviors were determined, which are directly related to the magnetiteproportion in the samples. The phase association and proportion, the sintering conditions andthe quality assessment are some features appraised by such procedures, which reveal themagnitude of this proposal in sintering plants.

Jan 1, 2005

By C Li, D O’Dea, R Moreno-Atanasio, T Honeyands

The behaviour of iron ore granules in the feeding process of sintering is significantly influenced by the material properties of the granulated mix. Therefore, the measurement of key material properties of the iron ore granulated mix is indispensable prior to the simulation of the sintering process based on the discrete element method (DEM). In this paper, three key property parameters of the iron ore granulated mix, apparent density, elastic modulus and rolling friction coefficient, were measured in laboratory-scale experiments. For different sintering processes, the moisture content of the granulated mix normally varies according to the specific requirements for granule size distribution and operating conditions. Therefore, understanding the effect of moisture content on the property parameters of iron ore granules is very helpful in accurately determining the property parameters for DEM simulation work. In this paper, six groups of iron ore granule samples with six levels of moisture contents were prepared through granulation and the trends in apparent density, elastic modulus and rolling friction coefficient with the increase of moisture content were plotted and analysed based on the measurement results. The results show that as moisture increases from 6.9 per cent to 9.1 per cent, the apparent density decreases from about 3000 to 2800 kg/m3. With moisture increasing within the same range, the elastic modulus first decreases from over 200 MPa to below 100 MPa and then reaches a relative constant value of about 40 MPa at higher moisture contents. Rolling friction coefficients are measured using two methods with both indicating a similar trend, with the rolling friction coefficient first decreasing and then rising as moisture increases from 6.9 per cent to 9.1 per cent. The relationship between µr and µ’r is assumed to be similar to that between static and dynamic friction coefficients.CITATION:Li, C, Moreno-Atanasio, R, O’Dea, D and Honeyands, T, 2017. Variation in property parameters of iron ore granulated mix with moisture content, in Proceedings Iron Ore 2017, pp 79–84 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

A rotating disc geometry was used to provide a uniformly accessible surface for a kinetic study of copper cementation with zinc in sulphate solution. For copper concentrations of the order of 10 p.p.m., a porous, adherent deposit is formed on the zinc surface and this has a significant influence on the reaction rate. When the specific mass of deposit is less than about O· 35 mg/cm2 the surface may be considered as smooth and the rate is described by simple convective counter diffusion of zinc and copper ions through a laminar diffusion boundary layer to the deposit-solution interface. In the presence of additional deposit, the diffusional mass transfer rate is increased by increased surface roughness.The rate under these conditions is first order, with the degree of enhancement independent of further increases in the specific deposit mass. The enhancement in rateis, however, directly related to the initial mass flux and the species involved in the reaction.Preliminary work showed the same mechanism to apply to cementation from chloride solution, solutions of high zinc concentration, and cementation of copper with iron..

Jan 1, 1970