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By A. McLean, S. Dawson, N. D. G. Mountford

"IntroductionIn order to predict the accepted industrial practice for the year 2000, it may be helpful to first consider the rate of development of scientific knowledge. If the speed with which man can travel on commercial vehicles is taken as a criterion for determining the rate of progression, then it can be seen from Figure 1 that advancement in our present century is very rapid. Likewise, if computer technology is used as a criterion for the measurement of scientific advancement, it becomes evident that technological evolution can be highly exponential. These two examples are sufficient to demonstrate that engineers and managers cannot afford to regard scientific development as being linear with respect to time if they are to avoid underestimating the needs of society.Within this framework of overall development, the time required for individual ideas to progress from inception to regular application has decreased considerably. For example, X-rays first discovered by Roentgen in the 1890's and now used widely in medicine and engineering, required a developmental period of some eighty years. The motorcar evolved from early beginnings at the turn of the century to a position of great social impact in sixty years. Rectifier materials used in high frequency radar to the present explosion in communications, required forty years. As illustrated in Figure 2, the period is shortening rapidly.The use of sound waves appears to be following a similar path. There is now a considerable body of knowledge concerning their behaviour and exceptional advances have been made. In medicine and engineering the sonic approach to examination is well established, and acoustic testing forms the basis of several diagnostic and quality control applications. With respect to metals engineering, ultrasonic testing has contributed to the understanding of the relationship between the size and number of internal defects and the probability of premature failure. This has allowed the designer to incorporate appropriate safety factors in his designs; but more importantly, the realization of the deleterious effect of inclusions on the performance of the final product has resulted in a continuous pressure on the material suppliers to reduce the number of defects in their products.It is not only the designer who is demanding defect free material but also the fabricator, as material breakdown during manufacture can be prohibitively expensive. Examples of this can be found in both the aluminum and steel industries where ultra clean sheet is required to ensure that rejections are minimized during beverage can manufacture and other deep drawing operations."

Jan 1, 1988

By A Sadri, S Smith

In the metal and mineral industry, different empirical techniques are used to estimate the remaining thickness of the lining within an operating furnace. The disadvantage and costly factor when using these methods is that production needs to be halted. Hatch has developed an accurate and reliable technique based on stress wave propagation principles to determine the condition of the remaining lining whilst the furnace remains online and operational.The technique involves test data collected and compiled to generate 3D imagery used to assist operators and maintenance planning personnel with valuable information showing areas of metal penetration in the lining, remaining lining thickness, exact location of voids, cracks, poor contacts and deterioration due to chemical attack. In this paper, the principals of the AU-E technique will be explained both theoretically and practically. In addition, the use of ultrasound technology for determining the condition of copper cooling elements will be briefly addressed.

Jan 1, 2006

By William C. Peters

The experiences of exploration crews with mineral land acquisition could be graphed to show a correlation with the natural law that everything tends to become more so. A single step, such as that of taking a series of deep soil samples, is sometimes delayed until some sense can be made from floating unpatented claims which are obscure in orientation as well as position-placer claims, overlapping lode claims, location posts with empty Prince Albert cans and claims with no apparent assessment work for ten years. Add to this some patented claims without monuments, a state or federal withdrawal area which may or may not invalidate preexisting claims, a loosely defined tunnel site, and some ranchers who understandably resent the separation of surface rights from mineral rights.

Jan 1, 1970

By Dale S. Hursh, William A. Brooks

Introduction US dependence on external energy sources is dangerous because of unstable political situations existing in key energy exporting countries. So, recent national energy policies call for increased reliance on domestic energy sources. Coal ranks as the most feasible domestic energy source due to its abundant reserves and continental distribution. But to efficiently extract these coal reserves, huge sums of capital funds are needed. Due to the depressed economy, lenders of capital funds are forced to be more stringent with loan applications. This results in fewer loans granted. In many cases, it is uncertain if funding can be obtained. Furthermore, the greatest level of domestic mine financing is expected to be in the coal sector. Demand for capital in the domestic coal industry is anticipated to increase 80% by 1990. The Chase Manhattan Bank in New York warns that these future needs cannot be met by the present capital markets. This article analyzes the current and expected situations of the capital markets available to the domestic coal industry, including: • current and expected future types of financing used in the domestic coal industry; • problems the domestic coal industry may encounter as it seeks capital; and • the future availability of capital funds as concluded from analysis of the first two items. Background Information Regardless of industry, all projects or ventures can be divided into four basic stages: generation; evaluation; selection; and execution. Within the mining industry, one can break down these stages to draw a clear picture of mine development, as shown in Fig. 1. Each successive stage has a corresponding risk level. This risk level defines the type of financing available to the mine operator. Mining Venture Risks A coal mining venture can be characterized by its unique blend of technical and financial risk. As the mine moves through different development stages, varying proportions of each of these risks are encountered. It is these risks that the lender evaluates to determine project suitability. For a coal mining venture, the major complexities generally occur with the technical risk. These include: • quantifying the coal reserves: • assessing the feasibility of the mining method; and • evaluating the design of the wash plant. The reserve risk is gauged by the amount of measured, mineable, and saleable reserves. The greater the latter amounts, the lower the risk. Secure title to the reserves plus title for any surface areas required are also of concern to the banker. Feasibility of the mining method and evaluation of the wash plant design should verify that the project can be completed according to the engineered spec-

Jan 9, 1982

By Terry S. Maley

Federally owned mineral deposits generally fall into one of three categories: (1) minerals locatable under the General Mining Law of 1872; (2) minerals leasable under the Mineral Leasing kt of 1920; and (3) minerals salable under the Materials Act of 1947. Unlike valuable deposits of gold, silver, copper, iron, lead, etc., which may be locatable, industrial minerals are acquired through a variety of methods depending on use, composition, and date of acquisition. Table 1 may be used to establish the method of acquisition for most industrial minerals.

Jan 1, 1987

By Jom Gentry

Acrylamide chemical grout (C3H2NO) has been successfully used for over 50 years to control groundwater and stop infiltration. This paper will address three unique projects involving the control of groundwater with each study providing special circumstances and geological conditions: encapsulation of radioactive hazardous waste in the United States, a tailings dam for a large copper/gold mine in Argentina and 27 miles of leaking subway in Canada. The primary reasons for selecting acrylamide grout were based on the following characteristics: thinnest chemical grout on the market, a true solution grout which contains no suspended solids in the blended product, flexible gel set times, and a 362 year half-life in soil as determined by the U.S. Department of Energy.

By Daniel Magill, Jim Gentry

"Acrylamide chemical grout (C3H2NO) has been successfully used for over 50 years to control groundwater and stop infiltration. This paper will address three unique projects involving the control of groundwater with each study providing special circumstances and geological conditions: encapsulation of radioactive hazardous waste in the United States, a tailings dam for a large copper/gold mine in Argentina and 27 miles of leaking subway in Canada. The primary reasons for selecting acrylamide grout were based on the following characteristics: thinnest chemical grout on the market, a true solution grout which contains no suspended solids in the blended product, flexible gel set times, and a 362 year half-life in soil as determined by the U.S. Department of Energy.INTRODUCTIONChemical grouting has been successfully used for over fifty years to control the movement of groundwater in a wide variety of applications including:•, Hazardous Waste Containment•, Subways & Tunnels•, Mines & Tailings Dams•, Concrete & Earthen Dams•, Underwater Structures•, Beneath/Around Underground Structures•, Mainline Sewers, Laterals, Manholes•, Large Soil Stabilization ProjectsThis presentation will review three projects where chemical grout was utilized to address some very difficult water control challenges, each providing special circumstances and geological conditions:1. Pre-construction seepage control at a mine tailings dam2. 27 miles of leaking subway3. Encapsulation of radio-active hazardous wasteThe reasons for selecting acrylamide grout as the solution for controlling groundwater in these selected projects were based on the following characteristics:1. Acrylamide grout is the thinnest chemical grout on the market2. No suspended solids which allows acrylamide grout to travel anywhere water can travel3. Flexible gel set times from 5 seconds to 10+ hours4. U.S. Department of Energy studies conclude that acrylamide chemical grout has a 362 year half-life in soil and can reduce the permeability of rock/soil to less than 10-8 meters per second (m/s)"

Jan 1, 2017

By M. E. Williamson

A seafloor based robotic drilling system is being developed for the National Institute of Ocean Technology in Chennai, India to support a National initiative for marine methane hydrate research. The system will be capable of core sampling to 150m below the seafloor in 3000m of water under telemetric control of an operator onboard a research vessel at the surface. Unlike previous robotic drilling systems, this unit (designated the ACS) will use wireline methodology to reduce the number of tool handling operations required to complete the borehole (conventional rod drilling requires 2025 tool handling operations to complete a 100m hole, while wireline requires only 48 operations to reach the same depth).

By Gaétan Bourdages

A clarification technology used by municipalities to produce high-quality drinking water, polish sewage treatment plant effluent and handle combined sewer overflows has recently found new applications in the mines and iron and steel industry. This patented process, known as ACTIFLO®, utilizes microsand in a ballasted flocculation process to enhance the settling characteristics of suspended solids, increasing the efficiency sufficiently to achieve a clarifier footprint that is smaller than the one of a conventional clarifier. ACTIFLO® rise rates vary from 40 to 170 m/h with a total system hydraulic retention time of about 10 minutes. The result is a clarification system so compact that a full-scale system can operate as a trailer-mounted unit for temporary applications or as a permanent installation in facilities with space limitations. This paper explains the process and presents case studies in which this innovative technology was used at mines and steelmaking facilities to meet compliance requirements.

Feb 1, 2008

By B. Mishra

Several reactive metal purification processes using molten salts generate effluent from which significant quantities of metal can be recovered prior to discardinglrecycling the salt. A Salt-scrub [SS] process has been applied where the reactive metals are recovered as a metal-gallium alloy by calciothermic reduction of the metal compounds. The SS alloy compositions were produced by mixing, pressing and sintering the metal-powders. Measurement of metal recovery has been studied for cerium, silver, tin and lead. The process has been optimized for variables such as the metal quantity per kg of effluent salt, amount of excess calcium over stoichiometry, stirring rate and time and holding time at reduction temperature. Over ninety-seven percent metal recovery has been obtained under optimized conditions. The development of an alloy for efficient Salt Scrub processing reduces a major contaminated waste disposal problem as well as recovering the valuable reactive metal. Surrogate metals have been used in this work to study the behavior of plutonium.

Jan 1, 1994

By S. J. Liu

The conventional collector for bauxite mineral is oleic acid, which is highly insoluble and must be used in high dosage in bauxite flotation operations, that is the great drawback of oleic acid in use. A series of hydroxamic acid were synthesized, and their collecting ability to certain minerals in bauxite: diaspore, kaolinite were studied. The collecting power of various reagents to diaspore in an incremental sequence were shown as follows: benzyl hydroxamic acid<amylic hydroxamic ac-id<heptylic hydroxamic acid<oleic acid<octylic hydroxamic acid; while the incremental sequence of the collecting power to kaolinite was like this: benzyl hydroxamic acid<amylic hydroxamic ac-id<heptylic hydroxamic acid<octylic hydroxamic acid<oleic acid. It could be seen that octylic hydroxamic acid had the capability of high collectivity and good selectivity, and octylic hydroxamic acid was chosen to use in the following experiments. Reduced zeta potential showed the adsorption of the anionic collector on the mineral. By the adsorptive capability and IR tests, the adsorption of octylic hydroxamic acid on diaspore was determined to be chemical absorption, which was greater than that of oleic acid, as it was physical absorption. Results of floatation experiments on manually mixed minerals indicated that the collectivity and selectivity of octylic hydroxamic acid were better than oleic acid.

Jan 1, 2014

By T. Clinton Taylor

QUALITATIVELY, galena (native lead sulfide) reacts with aqueous solutions of the xanthates,1 and has its surface sufficiently altered so that there is a tendency for air bubbles to attach themselves to the mineral crystals where there was no such effect before the treatment. This property is utilized in froth flotation operations where the mineral sulfide particles are raised into the froth and the gangue whose surface is not altered remains behind. The results of a study of this reaction were reported" recently and certain tentative suggestions about the interaction of galena and the alkali xanthates were offered. In this paper, there is set down the results of a detailed quantitative investigation of the ions involved in this inter-action with a view to finding out more about the condition existing imme-diately at the surface of a crystal like a heavy metal sulfide after treatment with an organic reagent. Past experimental experience showed that finely ground galena shaken with aqueous potassium xanthate abstracts xanthate ion and at the same time sulfate ion, reducing ions of the type (SmOn)= where the ratio of m to n is less than 4:1 (as in sulfate), sometimes hydroxyl ion are thrown into solution.,

Jan 1, 1933

By Carl Benedicks

IT is well known by every one who has had to deal with boiler tubes that these are often seriously affected by a sort of corrosion, occurring as a local pitting, that frequently causes a perforation of the tube in a rather short time. The characteristic appearance of this corrosion is shown in Fig. 1. A very similar corrosion occurs in condenser tubes (Fig. 2).1 A study of the microstructure or local chemical composition of the metal (iron; 70 :30 brass) fails to reveal any cause for this pitting. Of course one might possibly assume the starting point-to be some oxide particle, causing an electrolytic local action, but this in no way explains the continued corrosion, progressing even when the assumed oxide particle must have disappeared. By the excellent work done by the Corrosion Research Committee of the Institute of Metals, and communicated, in October, 1923, to the Institution of Engineers and Shipbuilders in Newcastle-on-tyne, stress was laid on the fact that a content of entangled air has a very obnoxious effect. In the following correspondence, Sir George Goodwin stated that "engineers have, for a long time past, regarded air as the big enemy to be fought against in all questions of corrosion"2 and Kenneth Fraser pointed out that the most vital point is "the avoidance or removal of possibly the chief cause of present day corrosion, i. e. entrapped air and gases brought out of solution."&apos; In their reply, however, the authors state that they had "never for a moment believed that entangled air was responsible for the beginnings of corrosion, and express the opinion that the gradual liberation of air could not account for localized corrosion."4 On consulting the many textbooks on corrosion, as that

Jan 4, 1925

By W. H. Bassett

In considering the effects of reducing gases on hot solid copper the following conclusions have been reached. (1) Depth of deoxidation of copper heated in reducing gas is greater the smaller the amount of cuprous oxide originally present in the copper, the range studied being from 0.015 to 0.136 per cent. oxygen. It is suggested that the reason for this difference in depth of deoxidation is that, when the copper is low in cuprous oxide, the reducing gas is diluted less by the gas that is formed in the reaction than when the copper is high in cuprous oxide; and the greater the concentration of the reducing gas the deeper the deoxidation. (2) The rate of deoxidation is much mire rapid at the beginning of exposure than at the end, a condition especially noticeable at temperatures around 900° C.; that is, deoxidation is retarded as the depth penetrated by the reducing gas increases. (3) Within the accuracy of the experiments arsenic in copper up to 0.5 per cent. has no tendency to increase or decrease the action of a reducing gas on the cuprous oxide present in the copper. IN 1912 pieces of 0.365-in. hard copper rod 1/2 in. long were heated in a porcelain tube in an electric furnace, while illuminating gas was passed through. An approximate analysis of this gas is: FIG. 1.-EFFECT OF TIME AND TEMPERATURE ON DEOXIDATION RATE OF 0.365-IN. COPPER BY ILLUMINATING GAS; COPPER PLUS SILVER, 99.983 PER CENT. Hydrogen 38 per cent., carbon monoxide 30 per cent., illuminants 13 per cent., methane 10 per cent., ethane 3 per cent., carbon dioxide 3 per cent., nitrogen 2 per cent., oxygen 0.4 per cent. After heating for various lengths of time at various temperatures, samples were quenched

Jan 1, 1926

By W. C. Schroeder

PRACTICAL experience has shown that at elevated temperatures solu-tions containing sodium hydroxide may attack stressed steel in a manner that cannot be explained in terms of ordinary corrosion. Because the ductility of the metal has been greatly reduced during the reaction, the entire phenomenon is usually called "embrittlement." Thus, after several years of operation caustic evaporators have been so badly embrittled that rivets could be cracked off with the blow of a hammer. Since fine intergranular cracks are almost always present in the zone of fracture, it has often been assumed that a process of selective corrosion in grain boundaries was responsible for the failure, although this has not been clearly proved experimentally. Concentrations of sodium hydroxide below those necessary for the uniform, rapid attack of the steel surface are reported to be most effective in producing embrittlement2,3. In the operation of steam boilers a similar type of failure has been found, mainly in riveted seams or other capillary spaces where the solu-tion may concentrate and where high stresses may also exist. It is believed that in such localized areas the dissolved solids may reach a value many times the few hundred parts per million prevalent in the body of the boiler. While this type of boiler failure has been the subject of investigation for a period of 20 years&apos;, an understanding of its mecha-

Jan 1, 1936

By C. G., Fink

The dissolution of gold by cyanide solutions was studied by determining the time required for the solvents to dissolve gold leaf. Minute traces, even 0.5 ppm, of sulphide ion retard the dissolution of gold, and this behavior cannot be accounted for by the presently accepted hypotheses involving oxygen-depletion or thiocyanate formation. On the other hand, traces of the salts of lead, bismuth, mercury, and thallium considerably accelerate the dissolution. The beneficial effect of lead is dependent upon the pH and cyanide ion concentration of the solution.

Jan 1, 1950

By Charles Hardy

ACTIVATED alumina is an aluminous material which may be 1 classified chemically as a partially dehydrated aluminum trihydrate having a high porosity and a perma¬nent physical structure. In general, it may be employed effectively and economically for the complete removal of water vapor from gases and vapors; for the selective adsorption of certain as especially those of the higher boiling points, and as a catalyst or catalyst carrier. Other forms of alumna are available and may be employed similarly but not so effectively nor can reactivation be accomplished with uniformity over many cycles without deterioration. The adsorption-reactivation cycle of activated alumina can be repeated many times without any apparent depreciation ill

Jan 1, 1934

By R. W. Smith, K. A. Altman

The use of activated alumina for the removal of selenium from heap leach detoxification solutions was studied at a laboratory scale. Three different aluminas were studied, one unmodified and two chemically modified to function better in a basic pH range. The best performer, Discovery Chemicals DD-6, readily accumulated selenium oxyanions. Furthermore, it could be stripped of selenium and several metals by a mild caustic solution (pH 11.5 – 12.0) and regenerated for further use. Tests using - 600 µm, + 300 µm (28 x 48 mesh) material indicated that 96 % could be removed from solution and using – 1.18mm, + 600 µm (14 x 28 mesh) material 91 % could be removed. However, soluble silica can accumulate on the activated alumina and subsequently interfere with its regeneration and should be removed from the detox solution prior to use of the adsorbent.

Jan 1, 2003

An effective electrowinning process in hydrometallurgical industry requires fluoride levels in the base metal solution to be less than 10 mg/l. Selective removal of the fluoride ions from base solution is thus desired, if fluoride was added to control calcium and magnesium in the circuit. Consequently, adsorption of fluoride onto activated alumina was studied in a batch and a column set-up. The effects of base metal solution pH, temperature, initial concentration and flow rate on activated alumina performance were investigated in either a batch or column configuration. A two-level factorial experimental design was implemented in studying column dynamics. Results demonstrate that activated alumina is an effective adsorbent for selective removal of fluoride from base solution. In the batch operation, fluoride was removed to values below the maximum allowable concentration (10 mg/[l]) when pH was = 8. In the column adsorption step at 55°C and 600mg/[l] initial concentration, up to 16 bed volumes were processed before breakthrough level was reached. Desorption step using 1% sodium hydroxide solution achieved an elution of 8 bed volumes. The activated alumina (AA) had a capacity of 8.65 gF/[l]AA at the 10mgF/[l] fluoride breakthrough level during the column adsorption test. Keywords: Fluoride; activated alumina; adsorption; recovery; regeneration.

Jan 1, 2009

By Kent von Maubeuge, Charles R. Landis

The global bentonite industry is a dynamic market balancing a range of end uses with an ever growing number of bentonite producers. In addition, markets in developed countries are elevating the level of detail and transparency for materials reporting in programs, such as the Registration, Evaluation, Authorization and restrictions of Chemicals (REACH) program in the European Union. Bentonite is impacted by programs of this nature. The majority of the bentonite products sold around the world are sodium bentonites. These sodium bentonites consist either of natural sodium bentonites, or naturally occurring bentonite dominated by divalent interlayer cations (Ca+2 andMg+2) subsequently exchanged with sodium cation. The latter variety is often called “sodium-activated“, or “soda-ash treated” bentonite. Once exchanged with sodium, these bentonites are often difficult to distinguish from natural sodium bentonites using common commercial testing protocols. Due to their similar colloidal and bulk chemical properties; the lack of test procedures designed specifically to identify this product feature; and the failure to completely or effectively explain their differences, sodium-activated bentonite is often considered to be identical to natural sodium bentonite in the industry. This article defines both general types of sodium bentonite and presents a technique that could serve the industry as a tool to confirm the variety of sodium bentonite in question. Specifically, geochemical properties such as carbon (C13/C12) and oxygen (O18/O16) isotopic ratios can distinguish activated, even slightly activated bentonites, from bentonites not introduced to additional sodium during manufacture.

Jan 1, 2004