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By Esperidiana A. B. Moura, Célio H. Wataya, Roberta A. Lima, Rene R. Oliveira

Biodegradable starch/copolyesters/silica nanocomposite films were prepared by melt extrusion, using a twin screw extruder machine and blown extrusion process. The influence of the silica nanoparticle addition on mechanical and thermal properties of nanocomposite films was investigated by tensile tests; X-rays diffraction (XRD), differential scanning calorimetry (DSC) and Scanning electron microscopy (SEM) analysis and the correlation between properties was discussed. The results showed that incorporation of 2 % (wt %) of SiO2 nanoparticle in the blend matrix of PBAT/Starch, resulted in a gain of mechanical properties of blend.

Jan 1, 2015

By H. J. Garcia

Biodegradation of cyanide by microorganisms isolated from solids previously exposed to cyanide has been investigated. Initial sodium cyanide concentration was 300 ppm at pH 10.5. The kinetics of biodegradation were found to be first order with respect to cyanide concentration, and the overall reaction rate constant is k = 0.102 day-1. The activation energy and the frequency factor were determined to be { A }Ea = 5.45 Kcal/mol and A = 1.28 x 10-2 sec-1, respectively. Based on these values, thermodynamic properties of an intermediate activated complex were assessed. All tests resulted in cyanide concentrations less than 0.1 ppm in about 35 days at 250C, whereas at 350C the time of biodegradation to reach this cyanide level was 30 days. Kinetic data were also established to relate biodegradation to amount of inoculum. The maximum theoretically-attainable rate, Vm , and the optimum amount of inoculum, K , were determined to be 4.8 x 10-4 M NaCN/day and 7.5 % of amount of inoculum. With respect to the mechanism of biodegradation, cyanide was shown to decompose to carbonate, bicarbonate and ammonia. Titrimetric analyses revealed concentrations of 5.6 x 10-3, 4.8 x 10-3 M, and 70.2 ppm for carbonate, bicarbonate and ammonia, respectively. The average cell population was determined to be 3.75 x 108 cells/mL.

Jan 1, 1994

By Madgwick J. C

Four manganese dioxide leaching microorganisms, an Achromobacter spp, Aspergillus niger, Elllerobacter cloacae and Elllerobacter agglomerails were purified from sucrose enriched crude mixed cultures which contained at least sixteen, non-leaching, morphologically different, colony types. Fastest leaching rates were obtained from the original enrichment's mixed cultures (1.26 g Mn++ I/d) while best yields of Mn++ m terms of sugar use came from Achromobacter and A. niger being 0.84 and 0.89 g Mn++/g sucrose respectively. The peak efficiency in manganese reduced, per carbohydrate used, coincided with the exponential growth phase for Achromobacter. The two Elllerobacter species performed better in stationary or senescent growth phases.

Jan 1, 1985

By Madgwick J. C

Microaerobic biodegradation oflow-grade manganese dioxide slurry tailings was demonstrated in enrichment cultures treated with dilute molasses at 30°C and pH 5·8. Supplementary nitrogenous nutrients, yeast extract addition and pH adjustment were not required.Continuously stirred, air-limited reactors were superior to still intermittently agitated cultures, in that, at 5 per cent (w/v) MnOz tailings and 5 per cent (w/v) molasses, the yield of 0.12 g Mn++/g molasses, the rate ofleaching of 1·06 g Mn++/l/d and a recovery of Mn++ of 58 percent from MnOz were 2·8 times, 1·7 times and 1·9 times greater, respectively. The best compromise in yield (0·45 g Mn++/g molasses) and rate ofdissolution (0·73 gMn++/l/d) was at 1 per cent (w/v) molasses in a stirred reactor.Where leaching organisms were separated from sterile ore by a bacteria impermeable membrane leaching was shown to be some 20 per cent due to diffusible metabolites and 80 per cent due to a direct contact between the bacteria and the ore particle's surfaces.

Jan 1, 1986

By K. A. Natarajan, M. R. Sabari Prakasan

"Biodegradation of sodium isopropyl xanthate using two types of bacterial strains, Paenibacillus polymyxa and Pseudomonas putida, is demonstrated. At concentrations higher than 50 mg/L, the presence of xanthate in the growth medium resulted in bacterial toxicity, retarding growth kinetics. Adaptation through serial subculturing in the presence of higher xanthate concentrations resulted in the development of xanthate-tolerant bacterial strains. Stress proteins secreted by bacterial cells grown in the presence of xanthate were isolated. Bacterial cells could utilize xanthate as a growth substrate, degrading xanthate species in the process. Acidic metabolic products generated by bacterial metabolism promoted efficient xanthate decomposition. Probable mechanisms for the biodegradation of isopropyl xanthate are illustrated.IntroductionDifferent types of alkyl xanthates (ethyl, isopropyl, amyl, etc.) have been used as flotation collectors in the concentration of sulfidic ores for several decades. Large quantities of waste water and xanthate-containing effluents are generated by ore flotation processes, posing considerable environmental challenges. Billions of cubic meters of such process waste waters are produced annually across the world, most of which are discharged to the environment, often without any treatment. Leakages and accidental release of xanthate reagents from manufacturing plants and during transportation and storage can also contaminate the environment. Residual concentrations of xanthate reagents are encountered in waste effluent, which are found to be toxic to aquatic life and unfit for human consumption (Harris, 1984; Okibe and Johnson, 2002). Further, direct recycling of such waste waters for plant operations can compromise water quality standards required for process operations. The presence of residual xanthate in recycled waters from flotation plants deleteriously influences flotation processes. Xanthate can be easily decomposed at low pH values; however, CS2, which is more toxic, will be produced by the acidification of neutral and mildly alkaline xanthate-containing solutions. Physico-chemical methods such as flocculation, chemical oxidation and decomposition and physical adsorption used to remove residual collector reagents from mill process waters are often expensive and not environment-friendly (Oliveira and Rubio, 2009; Cheng et al., 2012; Molina et al., 2013,)."

Jan 1, 2015

By Luciano B. Oliveira, Luis G. C. Marques, Sergio N. Monteiro, Marcos V. M. Fagundes

"Biodiesel production is normally associated with large plantations of oily vegetables such as soybean and colza, in large rural areas. However, in the municipal limits of the city of Rio de Janeiro, southeast of Brazil, biodiesel is being produced from wastes commonly generated by typical urban activities such as sewage sludge, discarded fat from meat markets and post-used cooking oils. In the present work, the experience of producing biodiesel from urban wastes in Rio de Janeiro is assessed. The type of precursor materials, equipments and logistics are presented. The environmental and economical advantages as well as the drawbacks are discussed.IntroductionThe interest for a liquid fuel that could substitute those obtained from petroleum started more than one hundred years ago when Rudolph Diesel tested his no-spark internal combustion engine, impelled by compression, with peanut oil. By that time, petroleum was beginning to be extracted in large scale and no one was concerned with the future environmental problems and its eventual depletion. In the last century, the successful association of petroleum based fuels with the automotive industry was an almost insurmountable obstacle to any attempt to use nonmineral oils [1]. In addition to the greater efficiency and, by then, lower price of the diesel from petroleum, the use of plain vegetable oils introduced undesirable carbon deposits and reduced the engine lifetime. Today, the situation is reverse. The continuous increase in the price of petroleum and, above all, its contribution to climate changes are strongly motivating the use of biofuels to replace those obtained from fossil fuels such as petroleum, natural gas and coal [2].In the case of the common petroleum derived diesel, many countries are now engaged in large scale substitution programs. The USA should produce more than 700 million litters of biodiesel, while the European Community is expected too produce around 6.5 billion litters in 2008. In Brazil, the federal biodiesel program imposed a minimum of 2% addition to the common diesel. This would demand a production of 800 million litters in 2008 [3]. The Brazilian biodiesel is made from a diversified source of vegetables mainly castor bean, African palm and soybean. The main producers are agrobusiness firms located in large rural areas of the Brazilian hinterland [4]."

Jan 1, 2008

By Bernard Vigneault

Les critères de qualité de l?eau pour les métaux visant à protéger la vie aquatique sont présentement basés sur les concentrations totales. Cependant, la complexation (association de ces métaux avec des ligands en solution) peut diminuer de façon importante la toxicité des métaux sur les organismes aquatiques. Pour évaluer l?importance de la complexation pour diminuer la toxicité des métaux dans les effluents miniers et métallurgiques, nous avons étudié la spéciation des métaux et la toxicité chronique de différents effluents miniers et métallurgiques. La phase dissoute des effluents a été échantillonnée à l?aide de la dialyse in situ et la spéciation du cuivre, du zinc et du cadmium a été calculée à l?aide du modèle d?équilibre chimique WHAM. Les concentrations de métaux libres ont également été mesurées à l?aide d?une technique d?échange ionique. Les concentrations de métaux libres calculés et mesurés indiquent que la complexation est importante dans les effluents miniers, particulièrement pour le Cu. Pour relier la spéciation des métaux et la toxicité chronique, nous avons mesuré en parallèle l?inhibition de croissance de l?algue Selenastrum capricornutum et des larves du poisson Pimephales promelas de même que l?inhibition de la reproduction du cladocère Ceriodaphnia dubia. (tests de toxicité chronique inclus dans le programme de suivi des effets environnementaux du règlement fédéral sur les effluents de mines de métaux). En absence de thiosels, aucune mortalité a été observée pour l?ensemble de ces tests et il n?y a pas eu également d?inhibition la croissance de la larve de poisson P. promelas. L?inhibition de la croissance de l?algue S. capricornutum, n?est pas reliée aux concentrations de métaux traces mais plutôt par aux concentrations de calcium. Les inhibitions de la reproduction du cladocère C. dubia sont reliées aux concentrations de métaux dissoutes et libres et non pas aux concentrations totales de métaux, démontrant l?importance des effets de la spéciation chimique sur la toxicité des métaux. Nos résultats indiquent que l?inhibition de la croissance de l?algue l?algue S. capricornutum est due aux concentrations élevées de calcium retrouvées dans les effluents miniers et que les concentrations totales de métaux ne peuvent être utilisées pour prédire la toxicité chronique vis à vis le cladocère C. dubia.

Nov 1, 2002

By J. Juilland

Over 10 percent of the United States of America or 41 percent of the Federal lands is managed by the Bureau of Land Management (BLM) as Public Lands. The mission is to manage the use of these lands and their resources. The way in which BLM carries out its mission is being refocused under the concepts of biodiversity and ecosystem-based management for the benefit of various human needs including environmental, social and economic values. The Bureau is developing methods to integrate the renewable and non-renewable resources programs into the concepts of biodiversity and ecosystem-based management. Exploration, development and extraction of energy or mineral resources on Public Lands are affected. The statements that following the next few pages are my personal views as a scientist (economic geologist -mining technologist) who is and has been involved for the last twenty years in the multiple-use management of Public Lands. They are not necessarily the position of the Bureau of Land Management, although much of the information on which I base my views comes from my experience with the BLM. The Bureau of Land Management (BLM) manages over 10 percent of the United States (270 million acres or 108 million hectares) which is 41 percent of the Federal Lands. Lands managed by BLM are known as Public Lands as opposed to the National Forest Lands which are Federal Land Policy and Management Act (FLPMA) of 1976 which in Sec. 102 states ??that it is the policy of the United States (7) ?that management be on the basis of multiple use and sustained yield??, the mission of the BLM is rapidly refocused under the concepts of biodiversity, ecosystems, and ecosystems-based management for the benefit of the environment, human needs and socio-economic values.

Jan 1, 1994

By Paul MacLean

MAC TSM ?Mining and Biodiversity Conservation 1.Corporate biodiversity conservation policy, accountability and communications 2.Facility-Level biodiversity conservation planning and implementation 3.Biodiversity conservation reporting ?Activities indicative of level AA -AAA (formerly 4-5) performance: ?Independent verification ?Integration into broader business strategy and planning processes ?Engagement with communities of interest ?Commitment to actively partner with other organisations for biodiversity conservation

May 1, 2011

By M Baker

Biodiversity offsets are conservation actions intended to compensate for the residual, unavoidable harm to biodiversity caused by development projects. The use of biodiversity offsets in the context of mining has significant potential for enabling mining to take place in areas with biodiversity values, where it would not otherwise be possible to meet the relevant legal tests under the Resource Management Act 1991, and potentially the Conservation Act 1987. This paper looks at the concept of biodiversity offsets (and environmental compensation generally) both in New Zealand and internationally, and considers how lessons learned overseas may be adapted for this country. In New Zealand the practice of biodiversity offsets and environmental compensation is ad hoc and variable. The challenge with biodiversity offsets is to establish a transparent and coherent means of identifying the overall priorities and objectives of adopting such an approach, as well as how the relevant values are measured and protected. Establishing a methodology for quantifying biodiversity value, and the need for clear policy guidelines on biodiversity offsets are identified as key areas in need of wider discussion.

Jan 1, 2007

By J. B. Davis

Isotope analyses distinguish biogenic sulfur ores from non-biogenic ores, but do not distinguish bioepigenetic from biosyngenetic ores. Sulfur deposits of salt dome caprocks and of bedded Permian evaporites of west Texas, however, are clearly bioepigenetic. Anhydrite, introduced by salt diapirs into geologically younger sediments, is converted biogenically to sulfur and calcite in the presence of petroleum; for example, in Challenger Knoll, a salt dome at a water depth of 3600 m in the Gulf of Mexico. Bedded evaporites of west Texas in association with petroleum show an obvious epigenetic replacement of the anhydrite layers by biogenic sulfur and calcite

Jan 1, 1978

By M. Misra, I. A. H. Schneider

The flocculation of -38 pm calcite, hematite and kaolinite aqueous suspensions by the yeast Candida parapsilosis and products derived from rupture of the microorganism was studied. Flocculation of hematite suspensions by the microorganism and its derivatives readily takes place between pH 2.8 and 11.4. Maximum flocculation occurs at about pH 6.5. Flocculation of calcite suspensions by the microorganism and its derivatives readily takes place between pH 7.0 and 11.8. Maximum flocculation occurs at about pH 10.0. Flocculation of kaolinite suspensions was less than that for the other two minerals. However, a soluble fraction derived from the rupture of the organism functioned as a good flocculant for the mineral, albeit at an increased concentration, between pH 2.6 and 11.5. Maximum flocculation occurs between pH 6.8 and 7.2. An attempt is made to relate the behavior of the various systems to the surface characteristics of the minerals and the surface and chemical properties of microorganism and its derivatives. Experimentation used to evaluate the flocculation includes actual flocculation tests, microelectrophoresis measurements and scanning electron microscopy.

Jan 1, 1994

By M. Misra

The bacterium?Mvcobacterium Phlei has a demonstrated potential to be used for the flocculation of a variety of finely divided minerals. The microorganism possesses both hydrophobic surface and high negatively electrostatic charge. It can adhere to many mineral surfaces ?if the charge and hydrophobic interaction? between the microorganism and the minerals are favorable to adhesion. Experimental results showed that the dolomitic phosphate slime from Florida and fine hematite can be :readily flocculated from dilute suspension.. In the case of dolomitic phosphate slime, a consolidated sediment containing 24'-25 weight% :solids can be obtained from .a dilute slurry .in a short time. Sediments obtained from hematite flocculation are rather massive and more .consolidated than phosphate slime. Mycobacterium Phlei has a specificity for selective flocculation of hydrophobic fine coal particles from pyrite and ash containing minerals. Because of mutual hydrophobic interaction of coal and Mycobacterium Phlei, it was noticed that coal particles appear to be strongly held in the aggregate by adhesion or bridging of bacteria. However, Mycobacterium Phlei is not a good flocculant for either associated pyrite or ash present in coal.

Jan 1, 1991

By Ana Elisa Casas Botero

The Rhodococcus opacus microorganism was evaluated as a biocollector for flotation of barite. The electrophoretic behaviour of the mineral, before and after R. opacus interaction, was evaluated and showed that the cells adhesion shifted the mineral zeta potential curves. Adhesion tests were suggested a high affinity of the bacteria for barite. The experiments of the adsorption rate of the R. opacus on the mineral surface showed fast kinetics, achieving a maxim of cell adsorption after 5 minutes. Adsorption isotherm curves for barite could be categorized as Langmurian (L) type II. The best bioflotability results for barite achieved values around 75% for a R. opacus concentration of a R. opacus concentration of 250 ppm in the pH around 5.0. The studies were compared with the flotation of barite using a traditional collector. The bioflotation experiments were discussed considering the obtained adhesion tests. The results were supported by the Thermodynamic approach for selected pH values. The fundamental flotation studies showed the paramount potential that R. opacus presents as a biocollector and its possible application in the mineral flotation industry.

Jan 1, 2014

By Youngsoo Song, Hyunjung Kim, Junhyun Choi, Siyoung Q. Choi, Gahee Kim

In this study, for the first time, to confirm the effect of bacterial growth phase on the malachite flotation were investigated in a well-controlled Hallimond tube system. The test results showed that the bacteria in the stationary phase exhibit two-fold greater floatability than those in mid-exponential phase. To understand the observed flotation behavior, complementary cell characterization tests and cell attachment tests were conducted. Interestingly, the bacteria at both phases exhibited similar surface properties as well as almost identical amount of cells attached onto the malachite, suggesting that the growth phasedependent flotation behavior cannot be attributed to the variation of cell surface properties and the extent of cell adsorption. On the other hand, cell detachment tests revealed that the amount of cells detached from the malachite surface is greater for the mid-exponential phase than the stationary phase due to the higher fluid drag applied to the cells at the mid-exponential phase, which was explained by the differences in the size and shape of attached bacteria onto the malachite surface. These morphological characteristics were found to cause the bacteria of mid-exponential phase to be separated highly sensitive and easy from malachite surface due to the fluid flow. Second, scale-up selective bioflotation tests were carried out in a 1 L Denver cell in malachite–silica binary mixture systems. Through the tests, we optimized the cell concentration and the malachite fraction in the feed. Overall, high malachite selectively was observed under optimized conditions (both recovery and grade showed more than 90%). The trend was in agreement with classical DLVO interaction energy profiles, which show the relative magnitudes of the adhesive forces between the mineral and the attached cell under equal hydrodynamic conditions.

Jan 1, 2016

By G. Kim

The influence of bacterial growth phase on the flotation behavior of malachite has been investigated in a well-controlled Hallimond tube system. The microflotation tests were conducted for malachite (45?53 µm) using different amounts (bulk phase concentration=1×108?5×109 cells/mL) of Rhodococcus opacus (R. opacus) as a collector, which was grown at mid-exponential versus stationary phase, at a constant speed (340 rpm), pH (6), and malachite-bacteria interaction and flotation time (each 10 min). Hug differences between R. opacus cells in mid-exponential and stationary phase was observed from the results for electrophoretic mobility and flotation tests. Specifically, the isoelectric point of the cells in the stationary phase was lower than that in the mid-exponential phase, suggesting that the amount and distribution of surface functional groups onto cell surfaces are likely different. Additionally, the cells in stationary phase led to significant increase in the flotability compared to those in mid-exponential phase over the background bacterial concentration level of 1×108?5×109 cells/mL. Furthermore, the flotation efficiency tended to increase with increasing cell dosage for stationary phase cells while no distinct difference was observed for mid-exponential cells.

Feb 27, 2013

By Y S. M Tabatabaei, R Hosseini Tabata

Application of Acidithiobacillus ferrooxidans bacteria to flotation of Sarcheshmeh low-grade copper sulfide ore was studied. Sarcheshmeh low-grade ore contains pyrite, which causes some problems in the flotation of copper minerals. In this study, A ferrooxidans was used to change the surface chemistry of pyrite and copper sulfide ores and consequently, their flotation behaviour. In the presence of A ferrooxidans and xanthate as a collector, pyrite was depressed whereas chalcopyrite and other sulfide minerals were unaffected. In addition, the pulp pH remained unchanged. It was shown that the surface chemical properties of the bacteria could be manipulated successfully to achieve the desired effects in a flotation process. The results showed that the recovery of pyrite in the presence of the bio-depressant is 50 per cent lower than when no bacteria were present. At the same time the recovery of chalcopyrite remained unchanged.

Jan 1, 2004

By A. Eslami, H. Tabatabaei, M. Kolandoozan, Z. Manafi, A. R. Shahverdi, M. Noaparast, M. Oliazadeh

Application of Acidithiobacillus ferrooxidans bacteria to flotation of Sarcheshmeh low-grade copper sulphide ore was studied. Sarcheshmeh low-grade ore contains pyrite, which causes some problems in the flotation of copper minerals. In this study, A. ferrooxidans was used to change the surface chemistry of pyrite and copper sulphide ores and consequently, their flotation behaviour. In the presence of A. ferrooxidans and xanthate as a collector, pyrite was depressed whereas chalcopyrite and other sulphide minerals were unaffected. In addition, the pulp pH remained unchanged. It was shown that the surface chemical properties of the bacteria can be manipulated successfully to achieve the desired effects in a flotation process. The results showed that the recovery of pyrite in the presence of the bio-depressant is 50% lower than when no bacteria were present. At the same time the recovery of chalcopyrite remained unchanged.

Jan 1, 2004

The uptake of zinc, lead, and copper by the flora of the Tui Base Mine area near Te Aroha is described.Vegetation and soil samples were taken from two traverses across the Raukaka Lode. Results. after statistical analysis, indicated that Beilschmiedia tawa was a suitable species for biogeochemical prospecting for lead and that SchefJlera digitata was satisfactory for zinc.The tawa showed a negative anomaly for lead over the vein itself but not over the adjacent dispersion halo. It was concluded that lead concentrations greater than 230 p.p.m. in the wood ash of the tawa and zinc concentrationsgreater than 540 p.p.m. in the leaf ash of S. digitata denoted threshold values for anomalous mineralization in the soil beneath. Although both species contained copper, neither indicated a soil anomaly for this element.

Jan 1, 1969

By W. J. Wolfe

"THE DETECTION OF BURIED MINERAL DEPOSITS by chemical analysis of vegetation (biogeochemistry) or visual observation of plant cover type (geobotany) is based on fundamentally simple principles. The root systems of vegetation collect aqueous solutions from a large volume of moist ground below surface and act as efficient sampling mechanisms by providing a composite sample of a reasonably large area. These aqueous solutions constitute a source of ore-associated metals that may ultimately be concentrated in the upper parts of the plant. Although certain plant species have a limited ability to break down primary minerals and extract elements, biogeochemistry normally detects only metals capable of moving in solution. Metal concentrations in the underlying soil must therefore exist in a form that is immediately available for uptake by the root systems - generally in the ionic state in aqueous solution or in readily exchangeable form on the surfaces of soil clay minerals. As a result, biogeochemical responses are closely related to variables such as soil pH, Eh, exchange capacity and complexing agents that control metal mobility in the surface environment. In terms of cost, reliability and anomaly contrast, soil geochemistry will normally be more useful than biogeochemistry in locating buried mineralization in regions of residual overburden or thin transported cover. However, in areas where the root systems penetrate thick deposits of transported post-mineralization overburden, plants can provide an effective mechanism of sampling below the transported material. Biogeochemical research in Canada, Scandinavia and the U.S.S.R. has therefore focused on the potential use of plant prospecting methods (1) in areas where the upper horizons of podzolic soils do not provide an adequate response to anomalous conditions under thick deposits of glacially transported till and (2) in widespread regions of peat and muskeg terrain where near-surface mineral soils are absent."

Jan 1, 1971