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By Xu C

This paper describes the structure and operation of an interacth.. computer program for mineral industry financial analysis and production planning. It includes comprehensive risk analysis with correlated variables and optimal production scheduling using Lane's balancing cut-off grades and the general dynamic programming approach.

Jan 1, 1995

By T Goswami, G Brent

In response to concerns over greenhouse gas (GHG) emissions and an imposed cost in some jurisdictions, many mining houses have committed to reductions in their GHG emissions. However, mining faces particular challenges in this regard, notably from increasing strip ratios. Furthermore, mining activity around the globe is not expected to decrease in the foreseeable future as mineral demand is driven up by the aspirations of rapidly-developing nations. Novel approaches will thus be needed if any reductions in energy consumption and GHG emissions of mining are to be achieved.This paper presents some directions for the mining industry to pursue in reducing their GHG impact, focusing on the difference that blasting methods can make. Importantly, large productivity and revenue gains can also be realised from these methods.Key directions considered here include optimising resource recovery and quality through:reducing coal damage and loss from throw blastingrecovering thin coal seamsproducing cleaner coal with less dilution.Blast design can also significantly improve the productivity of surface mining by:improving muck pile shapingimproving mine equipment productivityimproving scheduling.We show how a particular blasting method can eliminate coal loss in overburden throw blasting and can lead to large increases in coalmine profitability. Thin seams that were previously wasted can also be recovered with this method. Furthermore, the method has been implemented to combine several separate drill and blast cycles into a single cycle, leading to productivity gains.An illustrative example is given to show how increased coal recovery can increase revenues and more than offset any potential GHG emissions liabilities. Overall mine energy and GHG emission intensities can thus be reduced.CITATION:Goswami, T and Brent, G, 2015. Blasting approaches to increase mine productivity and reduce greenhouse gas emissions in surface coal mining, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 635–644 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By G Anderson, V Lawson, P Voigt

Glencore operates zinc concentrators at both Mount Isa and McArthur River. Both orebodies have a history of complexity and required the development of new technologies to maximise the value from these long-life assets. The Mount Isa orebodies were plagued since operations started in 1931 with complex mineral textures making separation challenging and many areas uneconomic. Examples are given in Figure 1 with different grain sizes from the same orebody in different areas. The McArthur River deposit, located in the Northern Territory, was discovered by Mount Isa Mines geologists in 1955 (Logan, Murray and Williams 1990). The extremely fine-grained nature of the ore was quickly recognised and the difficult separation of the minerals was soon obvious. The geographical, metallurgical and economic factors resulted in the orebody not being developed until the technologies for the mineral separation had been developed. The development of the IsaMill allowed for an economic mineral separation flowsheet to be developed and ore treatment commenced in May 1995 (Nihill, Stewart and Bowen 1998). CITATION: Lawson, V, Anderson, G and Voigt, P, 2018. Developing technologies for a complex orebody, in Proceedings Complex Orebodies Conference 2018, pp 116–118 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

By J P. Sykes, C Gemell, A Trench

The perceived and actual impact of government mineral policy upon the government share from gold mining revenues is assessed for ten key countries in which the gold sector is of relevance in advancing economic growth. Five African and five South American jurisdictions are considered, namely Burkina Faso, Ghana, Mali, South Africa and Tanzania from Africa; and Brazil, Chile, Colombia, Guyana and Peru in South America.Both the headline corporate income tax rate and royalty level are identified as poor indicators for the total government share. In addition, significant differences between industry perception and actual government tax levels are identified by this study. The quantitative financial analysis shows that there is no clear relationship between individual taxation rates, taken in isolation, and the overall average effective tax rate (AETR) paid by the project over its life. Neither companies nor governments should use individual taxation rates, or industry perceptions, in isolation to assess the overall competitiveness or equity of a country’s minerals taxation regime – such analysis can be very misleading.In this study, the perceived impact is determined from the well-established Fraser Institute survey published each year, and in 2014 compared 122 minerals jurisdictions globally. The actual impact is determined from quantitative modelling of the financial performance of a hypothetical gold mining project in each country. The technical parameters of the project are held constant; instead the differing mineral policies in each jurisdiction are applied to determine the resultant impact upon the relative share of the economic rents delivered to both private and public sectors. In the quantitative analysis, the total government share varies from 36.3 per cent in South Africa to 66.5 per cent in Ghana.CITATION:Gemell, C, Sykes, J P and Trench, A, 2016. Is perception reality? Evaluating the fiscal attractiveness of international jurisdictions for gold mining investment, in Proceedings International Mine Management Conference, pp 227-238 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 22, 2016

By J A. de la Torre, I R. Cerna, G K. Karadjian

The La Colorada underground mine in Zacatecas, Mexico is a mechanised cut-and-fill silver mine with a capacity of 1250 t/d. The project focused on training the mine’s experienced operators for a fleet of underground trucks, through the use of a training simulator. The project was run by the simulator vendor, in collaboration with the mine’s maintenance, safety and production management.A training program was created targeting maintenance reduction, productivity improvement and increased utilisation and availability. Operators were first acclimatised to the simulated environment, had their current performance baselined, then received targeted coaching, with the process repeated to reinforce learnings. Concurrently, production, maintenance, and safety data was being measured in the real world to measure skills transfer. Due to limited telemetry available from the equipment, many of the data points for the project were sourced from maintenance logs, and accounting data.Equipment failure data measured from unscheduled maintenance records showed an overall 6.5 per cent decrease in unscheduled maintenance following the implementation of the training program. This rate of reduction correlated with the significant decrease in equipment abuse behaviours measured within the simulator during this period. Additionally, overall maintenance activities showed a significant decrease, confirming that reductions in unscheduled maintenance were not achieved through increases in scheduled maintenance. The reduction in equipment damage also increased availability and utilisation of the truck fleet. This highlights that the maintenance improvements not only reduced maintenance costs, but made the fleet available for more production. Moreover, the variability of the operator performance was decreased by 86 per cent, and the difference between their best operator and the worst is less than the baseline; this showed a gap where machine abuse, productivity and cost are impacted directly.This project illustrated that even small-scale mining operations with an experienced operator workforce can achieve positive return on investment (ROI) from simulation-based training. It also highlights that in the absence of equipment telemetry, alternative data sources such as accounting data and maintenance logs can be used to quantify ROI from training.CITATION:Karadjian, G K, de la Torre, J A and Cerna, I R, 2017. Innovations in underground hard rock operator efficiency – through simulation-based training technologies and processes, in Proceedings 13th AusIMM Underground Operators’ Conference 2017, pp 53–58 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 16, 2017

By de Bruin J H

A method new to Australia was used for sinking a vertical shaft at Broken Hill in the development of Pasminco Southern Operations No 5 Ventilation Shaft. The 6 m diameter shaft of 820 m depth was planned with a construction method which allowed access for ground support as sinking proceeded by mechanical excavation.The vertical shaft boring machine, known as the V-Mole, was originally developed in West Germany. The machine operates in a manner similar to a full face TBM but vertically and the cuttings drop down a previously constructed raise. The raise is subject to stringent tolerance on verticality and must remain stable for the duration of reaming.

Jan 1, 1993

By M Lak, R Amiri, A Haratian, M Asghari, S Haji

In recent years, due to advances in designing of various magnet assemblies, a wide range of magnetic materials with different properties can be concentrated. Jalal Abad iron ore beneficiation plant, which is located in Iran, Kerman province, is currently producing iron ore concentrate with the capacity of 0.8 Mt/a by having medium intensity magnetic separators (MIMS) with rougher and cleaner stages that finally leads to the production of an iron concentrate with the Fe grade of about 65 per cent. In this plant, the rougher tailings directly goes to the thickener as the final tailings and cleaner tailings feeds to the ball mill for regrinding. Since some hematite particles with weak magnetic properties cannot be recovered from only these two stages of magnetic separation, the obtained tailings from this concentration plant has approximately an iron grade of 25 per cent to 27 per cent. Accordingly, laboratory processing tests were conducted on the obtained representative sample of the final tailings. Based on the experimental results performed on final tailings, a new magnetic drum separator with a specific magnetic assembly was designed that could finally lead to product with iron grade range of 58 per cent to 60 per cent with relative and total weight per cent of 8.6 per cent and 3.86 per cent. Finally, it could be concluded that feeding of magnetite particles to the existing drum separators, due to their high magnetic field intensity, cannot efficiently lead to improvement of the grade of concentrate. Therefore, pilot magnetic separation tests were done on the final concentrate for evaluation of product upgrading probability. Consequently, by increasing another stage of cleaning and by decreasing the magnetic field intensity, the final product grade could be enhanced from 65 per cent to 67 per cent.

Nov 8, 2021

By Shoobridge PH

Operating difficulties during 1977 with the Imperial Smelting Furnace operated by Sulphide Corporation Pty. Limited at their Cockle Creek zinc-lead smelter were found to be caused by premature softening of sinter in the upper shaft of the furnace. This soft- ening was shown to be a consequence of raw materials and operating policies which led to unusually high levels of both lead and silica in a sinter of low basicity. A programme of softening tests and micro-examination of a range of sinters established that premature softening occurred when lead and silica increased to the point where a lead-calcium silicate with a low lime content became the major continuous phase in the sinter. This information was used to define a range of compositions which kept the softening temperature acceptably high for furnace operations.

Jan 1, 1978

By E Donskoi

In order to develop downstream processing routines for iron ore and to understand the behaviour of the ore during such processing, extensive mineralogical characterisation is required. To determine mineral associations, mineral liberation and grain size distribution, imaging techniques have to be used. There are two main imaging techniques used for the characterisation of iron ore, ie, Optical Image Analysis (OIA) and Scanning Electron Microscopy (SEM). In this article a QEMSCANTM system is used as an example of SEM methodology and results obtained from it are compared against results obtained by the CSIRO ‘Recognition3/Mineral3’ OIA system.Both OIA and QEMSCANTM systems have advantages and drawbacks. Even though the latest QEMSCANTM systems can distinguish between major iron oxides and oxyhydroxides, it is still problematic for QEMSCANTM to distinguish between iron ore minerals very close in oxygen content, eg haematite and hydroheamatite, or between different types of vitreous goethite.QEMSCANTM also can misidentify minerals with close chemical composition, ie haematite as magnetite and vitreous goethite as haematite. In OIA, iron minerals with slight differences in their oxidation or hydration state are more easily and directly recognisable by correlation with their reflectivity. In both methods, the presence of microporosity can result in some misidentification, but in SEM methods misidentifi cations due to microporosity can be critical. Low resolution during QEMSCANTM analysis can significantly affect the textural classifi cation of particle sections.The main conclusion of this study is that, for low iron content ores or tailings, QEMSCANTM can provide much more detailed information on the gangue minerals than OIA. However, for routine characterisation of iron ores with high iron content and containing a variety of iron oxides and oxyhydroxides, OIA is a faster, more cost-effective and more reliable method of iron ore characterisation. A combined approach using both techniques will provide the most detailed understanding of iron ore samples being characterised.

Jul 11, 2011

By L H. Chapman, I J. Kelso, N H. S Oliver

Utilisation of modern 3D visualisation tools, can improve our ability to correlate between different datasets, and thus to produce more accurate geological models. Here, we present an application of such techniques to the Century Zinc Deposit, northwestern Queensland, Australia. This stratiform orebody is the second largest Zn resource in the world (167.5 Mt at 8.2 per cent Zn, 1.2 per cent Pb, and 33 g/t Ag). It is hosted in the Page Creek Syncline affecting Mesoproterozoic shales and siltstones of the Wide Supersequence of the Isa Superbasin. As in other deposits, (eg McArthur River, Lady Loretta, George Fisher and Dugald River), the mineralised sequence is bound by an important regional structure, the Termite Range Fault, which partly intersects the deposit along its Eastern side. This fault is thought have been active during sedimentation and probably also during mineralisation of the lowest part of the Wide Supersequence. The anastomosing geometry of this fault system and crosscutting relationships with other NE trending structures indicate that it was reactivated several times from Mesoproterozoic to at least late Devonian times (>1000 million years in total); as a result, the ore sequence is subdivided into several fault blocks.Using two different computer modeling packages (GOCAD and 3ds max), we have reconstructed and restored the stratigraphic horizon with the highest Zn content, realised a series of isopach maps for each mine scale stratigraphic unit, plotted the three-dimensional distribution of Zn, Pb, Ag, Fe and SiO2, and have begun to evaluate the degree of correlation between thickness changes and sulphide zoning. With this approach it is possible to better understand the timing of mineralisation from a genetic perspective, because the origins of the orebody are controversial. Three-dimensional reconstruction is a vital tool for identification of syn-sedimentary and post-sedimentary fault activity. In conjunction with sulphide precipitation, these are factors that greatly influence the stratigraphic thickness distribution. Post-sedimentary deformation can be recognised directly by core logging and pit mapping, but the effect of tectonic movements during sedimentation (growth faults in particular), that represents a substantial variable when we attempt to reconstruct basin evolution, is difficult to evaluate without this methodology. The 3D models improve our understanding of the local basin architecture, identifying similar grade characteristics at different structural levels and thus suggesting that much faulting and folding are post-mineralisation events. In addition, we identified several growth faults adjacent to thickened layers, representing two possible sedimentary depocentres. These thicker domains apparently relate to the highest Pb content. If further analysis of rocks, thickness and grade distributions support this preliminary correlation, then a syn-sedimentary model for mineralisation might be applied, and would contrast with the sub-surface model for mineralisation of Broadbent et al (1998).

Jan 1, 2003

By T G. Vizcarra, T J. Napier-Munn, A T. Karbowiak, M G. Hart

Squeezing extra performance from existing equipment (‘sweating the assets’) is key to continuous improvement initiatives, particularly during times of cost cutting where the option of spending additional capital to facilitate circuit upgrades can be severely constrained. A common challenge, however, is identifying the best combination of settings for different process variables, as their effects can be camouflaged by interactions with other process variables and, of course, noise in historical data.This paper describes a recent investigation at Boyne Smelters Limited to identify strategies to coarsen the product of its dry, fixed-speed, open-circuit AG mill, without the need for installing pre-screens prior to the mill. The product is used as insulation material for the reduction of alumina to aluminium, and an excessively fine product was inhibiting the ability of the cover material to dissipate heat from the underlying anodes. The approach was to undertake a series of experiments, designed according to statistical criteria, to elucidate the effect of key process variables (feed blend and power draw) upon the product sizing. The results provided clarity about what strategies would encourage the production of a more desirable mill product (with some surprises). The study is a good example of how properly designed experiments can identify hidden potential in processing circuits, thereby mitigating the need for capital-intensive upgrades.CITATION:Vizcarra, T G, Hart, M G, Karbowiak, A T and Napier-Munn, T J, 2018. Getting the most from existing processes: using cleverly designed experiments to optimise the line 3 AG mill at Boyne Smelters Limited, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 207–216 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

Professional engineers of today require a wide array of experience and knowledge. It is true that commonly engineering degrees do teach the technical requirements well, but do fall short in the way of teaching other non-technical issues of professionalism to the student. Today calls for an engineer who does not only have a high standard of the technical knowledge required for their degree, but also has a broad range of experience in areas that are becoming increasingly important in engineering. The importance of social responsibility, liability and interpersonal relations is high. Through the face of the changing world, it has become clear that there is a need for a new type of engineer, who has a broad range of expertise, as well as the typical technical abilities required. This paper will outline these non-technical issues and propose ways of combining these ideas into the mainstream engineering degree.

Jan 1, 2004

By M J. Nugus, J G. McLellan, T G. Blenkinsop

High fluid pressures and deformation have been instrumental in the formation of high-grade gold lodes at the Archaean granite greenstone 12 Moz Sunrise Dam gold deposit in Western Australia. Historically, predicting the location of these lodes has been difficult due to the irregular nature and high-grade nugget characteristics of the deposit. Recent exploration successes and the discovery of the Vogue system have led to an improved knowledge of the deep extents of the mine. This new structural and gold distribution data has enabled a new 3D interpretation of the system and has provided a better insight into the links between deformation, fluid pressure evolution and gold deposition. Here we employ 3D geomechanical and coupled fluid flow modelling to better constrain areas of high strain partitioning, rheological failure and focused fluid flow, which provides a substantially increased predictive capacity for further within-mine exploration. The localisation of deformation in and around the main felsic porphyry and major shallow shear zones provides critical insights into fluid pathways that have contributed to the distribution of fracture networks and ultimately gold deposition during late stage deformation events. Understanding the relationship between deformation events, fluid pressure evolution and the partitioning of strain is paramount in understanding the distribution of gold and for focusing on future target areas.CITATION:McLellan, J G, Blenkinsop, T G and Nugus, M J, 2013. Fluid pressure, geomechanical evolution and predictive targeting of the Sunrise Dam gold deposit, Western Australia, in Proceedings World Gold 2013 , pp 419-426 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By Leahy G. J, Moxon N. T, Nicol S. K

Experimental work is described in which extremely dilute aurocyanide liquors are treated with novel surface-active complexing agents to produce a hydrophobic aurocyanide species. Subsequent aeration of these liquors causes accumulation of such species at the air-water interface and the aurocyanide complex is transferred to a froth concentrate. A detailed performance assessment of this process is made and this knowledge used in the design of a pilot plant facility. Early results indicate the feasibility of the selective recovery of aurocyanide ions from reclaimed residue dam water (approximately 0.2ppm Au) with upgrade ratios of the order 180:1. A further study was made applying ion flotation to the recovery of gold from a carbon-in-pulp (CIL) feed liquor (approximately 1.0ppm Au). The probable economics of this process compared to conventional CIL processing is also described. Successful development of countercurrent ion flotation for concentrating solids-free gold solutions may offer a lower cost alternative to existing gold ore processing technologies, or in more secondary applications such as concentrating dilute gold solutions or heap leach runoff. The technology may also have more generalised applications to other heavy metal process- Ing.

Jan 1, 1991

Universal Resources Ltd has acquired a large portfolio of high quality exploration projects in two of Australia's most prospective regions for base and precious metal exploration: the Mt Isa Inlier (the Mt Isa-Cloncurry area) of North West Queensland, and the southern Lachlan Fold Belt in New South Wales. Drilling techniques commonly employed by the company for mineral exploration include diamond core drilling, air core drilling, reverse circulation (RC) drilling, and rotary air blast (RAB) drilling. Using examples from these two regions, each drilling technique is briefly described and compared, with particular reference to the specific advantages and disadvantages of each method for: sampling size, sample representivity, recovery, integrity and potential contamination. The applicability and implications of the different drilling techniques described for subsequent mineralogical and metallurgical evaluation work are discussed.

Mar 1, 2010

By Lemberg D. W, Friday R. G

Potential means of lowering overall costs to permit deeper stripping include : 1. the use of larger diameter blastholes in highly-fissured strata (to reduce drilling costs); 2. dewatering from semi-permanent bores to reduce blasting costs (by maximising the use of bulk ANFO) and promote highwall stability; and 3. the use of inclined blastholes, bulk AN, staggered V1 patterns, adequate backfill and more cost-effective stemming columns. Each of these is covered. The pumping of bulk watergels continuously raises the blasthole water column, thereby perpetuating the demand for these blasting agents. This must be a principal consideration when choosing between a bulk and a packaged watergel. Any packaged product should exhibit dimensional permanence and an energy yield per metre length equal to that of bulk ANFO. Possible ways in which controlled trajectory blasting (CTB) could benefit deeper stripping operations are outlined. By allowing the maximum use of bulk ANFO, de- watering may be a prerequisite of a viable CTB Operation.

Jan 1, 1981

By J Robinson, L D’Uva

"The Gold Fields group and Gekko Systems have successfully worked together on multiple projects, including at the St Ives, Agnew and Granny Smith operations in Western Australia, and the Damang operations in Ghana, with gravity recovery design, technology installation and optimisation the key driver on each occasion.In 2014, Gold Fields Australia identified an opportunity to challenge the historical thinking at Granny Smith and reassessed the benefit of upfront gravity gold recovery. The historical approach had been to employ gravity on the tailings stream of the carbon-in-pulp (CIP) circuit, recovering sulfide minerals into a concentrate from spiral concentrators for further liberation of gold via a regrind circuit.Gekko was engaged to assess the implementation of a gravity circuit within the grinding area, and to perform a comprehensive gravity recoverable gold test program. Test data was fed into the AMIRA P420 BCC Gravity Model to confirm the gravity recovery potential of the ore, and for process design basis generation. Height, space and capital limitations proved to be a design challenge. However, collaborative learnings throughout the project ensured the design and operation of a reliable and economic gravity gold circuit. Ultimately, the Granny Smith gravity circuit was a success, satisfying all the project objectives and yielding consistent, measurable benefits. On average, the gravity circuit recovers 33 per cent of total gold, resulting in an increase to overall gold recovery by 0.7 per cent.This paper highlights the key project drivers for Gold Fields, and the development of the Granny Smith free gold gravity circuit. It details application of test work and modelling, and the challenges and learnings encountered during the design, installation and commissioning stages. This paper seeks to demonstrate that continuous improvement in a long standing operation can be beneficial to overall circuit flexibility and increased ounce production.Citation:D'Uva, L, Robinson, J and Bell, T, 2016. Defying Gravity - Brownfield Continuous Improvement, in Proceedings 13th AusIMM Mill Operators’ Conference 2016, pp 135–144 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Oct 10, 2016

By J T. Smit

The theory of froth flotation developed slowly, in almost all cases lagging behind practical developments in the operation of flotation processes. This was largely the result of a lack of understanding of the required basic principles of chemistry and physics, many of which were being developed at the same time. A review of some of the early theories propounded is worthwhile, and should encourage those who are presently studying or practicing flotation to exercise some care in claiming a complete understanding of the underlying phenomena in the art. This paper considers theories presented up to and including those in Principles of Mineral Dressing by Antoine M Gaudin (1939). Of course, developments since that time are important, but they are beyond the scope of this discussion.

Jan 1, 2005

By Adeloju S, McQuade CV, Riley SJ

Metal contamination of sediments can be an issue for minesites discharging water. Water sampling of receiving waters is frequently undertaken. Sampling and analysis of sediment is less common. The variability of receiving environments makes the formulation of a generic sediment sampling strategy virtually impossible. Each situation needs to be carefully assessed before sampling is undertaken. This paper outlines the approach taken for one such survey.The main factors that need to be considered in a survey of surficial sediments are sample representativeness and sample variability. A simple data set from one site within a regional survey is used to illustrate the importance of these factors. The metal content of sediment is shown to vary significantly over small spatial scales.The variability associated with the spatial distribution of samples within a site is shown to be the most significant source of variability in the study. This variability could bias the results of a study if not planned for in the sampling methodology. Taking multiple samples from within each site (sub-site samples) and combining the data gives a more representative indicator of overall conditions than a single sample. The optimum number of sub-site samples to be taken from each sampling site was found to be 15.It is shown that a composite of sub-site samples can give a good indication of the average site metal content, while considerably reducing the sample preparation and analysis effort.

Jan 1, 1998

By A D. Pradana, D R. Pradana, Y H. Putra, Z Zulhan, T Hidayat

The high temperature processing of nickel laterite ore is currently dominated by the Rotary Kiln- Electric Furnace (RKEF) technology. The ratio of SiO2/MgO (S/M) in the ore is one of the critical parameters that determines the success of the RKEF process. Incompatible S/M ratios in the ore can cause aggressive chemical interaction between the slag and MgO refractory. The slag-refractory interaction at conditions relevant to nickel laterite ore smelting was investigated in the present study. Synthetic mixtures representing the slag compositions of nickel laterite ore smelting were prepared by mixing MgO, SiO2, Al2O3, CaO, Fe2O3, and Fe and heating the mixtures in steel containers at 1300°C under an argon atmosphere for 3 hrs. Pure MgO crucible were used as containment material in the melting process of the mixtures to represent the MgO refractory. The kinetics of the slagrefractory reaction were investigated using samples with selected initial S/M ratios of 2.0 and 3.0 (wt/wt) (with constant CaO = 3 wt per cent, Al2O3 = 5 wt per cent, FeO = 10 wt per cent) by performing melting at 1500°C in MgO crucibles for 5, 30, and 120 mins under an argon atmosphere. The effect of the S/M ratio in slag on the slag-refractory interaction was also investigated by performing melting of mixtures with different initial S/M ratios of 1.75, 2.0, 2.5, and 3.0 (wt/wt) in MgO crucibles at 1500°C for 120 mins under an argon atmosphere. After the melting process, each sample was quenched in water, mounted in resin, ground, polished, and coated. The interaction between the slags and MgO refractory was then evaluated by analysing the polished samples using a scanning electron microscope equipped with an energy dispersive spectroscopy (SEM-EDS). Thermodynamic simulations using FactSage™ 8.0 thermochemical software were performed based on the experimental slag compositions, refractory, and conditions to support the evaluation process. The results show that a higher S/M ratio in slag leads to a higher tendency for the refractory component to dissolve into the slag. A higher S/M ratio in slag also leads to an increasing extent of solid-state diffusion of iron oxide into the remaining refractory grains. The dissolution of MgO into the slag is rapid; the MgO concentration in the final slag increased by 2.4 wt per cent and 5.7 wt per cent at initial S/M ratios of 2.0 and 3.0 wt/wt, respectively, within 5 and 30 mins of the melting process.

Aug 21, 2024