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By Kevin Cunningham

"Litigation resulting from neighboring structures with settlement and/or lateral movement or improper pile design and faulty soils engineering analysis, are a multi-faceted opportunity for law firms. These types of claim scenarios are an attorney’s dream, and can obliterate a Deep Foundation Contractors profit and more importantly, can be avoided with a progressive approach to risk management in design and project management.The following (4) case studies will be examined and dissected to discern certain lessons learned for risk management solutions to avoid these deep foundation related challenges in the future.1) Pipe Flotation – Soil Conditions Not Anticipated in Specifications or Contract2) Easement Encroachment – Easement Dimensions Not Recognized Until Completion of Project3) Subjacent Lateral Support – Neighboring Structure Wooden Pile Unprotected Causing Structure to Settle4) Improper Pile Placement - Construction & Design Caused Retail Store to SettleSpecific Deep Foundation project challenges involving: buoyancy calculations regarding subsurface soil characteristics, design factors taking existing subsurface sewer line easements into account, structural instability as result of excavation causing exposure/heavy rainfall to existing wooden piles supporting adjoining building and improper pile location resulting from faulty pile design will be described with risk management recommendations to avoid these challenges in the future.From the very start of construction on any project deep foundation and excavating work poses numerous engineering and technical challenges for developers, contractors and engineers. Dealing with changing or hidden conditions is one of the most difficult challenges facing any contractor or engineer on a project. Relying on incomplete or inaccurate engineering reports is another common problem. Other challenges include dealing with technical errors or oversights that are deeply embedded in the project specifications or bid process.No matter what is the origin of the problem or how it manifests, deep foundation contractors, design professionals and engineers should be ever-mindful of good risk management practices that can prevent serious disputes that can result in costly litigation."

Jan 1, 2015

By Bernard B. Vannoy, Howard W. Gault, Ramesh Bobba

"Treviicos-Soletanche Joint Venture (JV) and the US Army Corps of Engineers (USACE) have installed a 3800-foot long, 275-foot deep and minimum 2-foot wide secant pile barrier wall at Wolf Creek Dam in Jamestown, KY. This paper describes the methodology employed by the JV and USACE to evaluate the overlap, thickness, and position of the barrier wall. It addresses the contractual requirements, positional uncertainty, and evaluation procedures.These procedures evolved over the course of the project as various issues were identified and procedures developed to evaluate these issues. During the project, it became clear that the JV and USACE could ascertain that the wall thickness and overlap requirements could be met if the overlap based upon Koden data was at least 0.7’ in the left-right direction. For a small number of piles with overlaps between 0.5’ and 0.7’, the piles are contractually compliant yet contain a minor degree of uncertainty in the overlap. Initially, the USACE assumption was that the amount of uncertainty of verticality measurements would require more than a 1-foot measured overlap in the left-right direction to confirm an actual, contractual 6-inch overlap. With time and experience, the limit of measured overlap was reduced in accordance with greater understanding of the equipment capabilities and tolerances. Other lessons learned include the need for Quality Control/Assurance personnel to collect data at the same starting point for every pile.For every pile the JV and USACE compared analog and digital data to provide confidence that the correct digital data was used for overlap calculations. Perhaps the most important lesson learned was the importance of the JV and USACE working together and sharing all data. Overlap analysis was performed by the JV’s Barrier Wall Specialist and a small number of USACE personnel. This resulted in a high level of experience and expertise within a small group.IntroductionThe Treviicos-Soletanche Joint Venture (JV) and the US Army Corps of Engineers (USACE) have installed a 3800-foot long, 275-foot deep, and minimum 2-foot wide secant pile barrier wall at Wolf Creek Dam in Jamestown, KY. The wall was installed through a 6-foot wide Protective Concrete Embankment Wall (PCEW) which was installed two feet into rock. The PCEW protects the embankment from erosion of drilling fluids during subsequent operations. Below the PCEW the piles were installed to a specified elevation (staggered at 475’ and 473’ below the 748.2’ work platform). The Ordovician limestone and shale bedrock is flat lying with few vertical fractures. These conditions facilitate the advancement of pilot holes with very low deviations (with considerable credit to the JV’s drillers and steering engineers). The pilot holes were spaced on 31.5-inch and 35-inch spacing. Subsequent enlargement of the pilot holes to 50’ resulted in a continuous wall. This paper addresses the requirements and procedures to assure that the wall was as wide, deep and continuous as specified."

Jan 1, 2015

By Ross T. McGillivray, David S. Graham, Dan A. Brown, Steven D. Dapp

"The Selmon Expressway includes an elevated structure extending across several miles of weathered karstic limestone geology, and represents a challenge for design because of the high variability of the material and the difficulty in characterizing the strength. The nature of the epikarst in this region of Tampa is such that variability can be extreme within distances of only a few feet. The weathered rock includes extremely soft soil infill within solution features on and within the formation. The limestone is so weathered that coring typically does not yield useful samples for strength testing, and in-situ Standard Penetration Testing (SPT) tests often encounter refusal blow counts. Thus the challenge for foundation design includes two components of reliability risks: the uncertainty associated with the ground conditions at a given foundation location plus the uncertainty associated with the foundation performance at a given location even when the stratigraphy is determined.This paper describes the design approach that has been implemented successfully for two projects at the Lee Roy Selmon Crosstown Expressway (LRS) in Tampa, Florida: the assessment and remediation of the reversible elevated lane (REL) foundations constructed in 2004, and the elevated expressways widening project constructed in 2012. Included in this design approach is a method developed for computing axial resistance in this local geology. Design for axial loading relies primarily on the development of side resistance, which was considered less subject to performance risks than base resistance. The calculation method incorporates a statistical analysis of SPT data, tempered by engineering judgment, to characterize stratigraphy at a given location into either soil, intermediate geomaterial (IGM) or rock.IntroductionThe subsurface stratigraphy of sites underlain by weathered limestone formations can be highly variable with respect to material layer thicknesses and strengths, even over short horizontal distances. This is the case for much of Florida, and particularly the Tampa area. These conditions present a challenging environment for the design of drilled foundations because of the need for a reliable determination of subsurface conditions at each foundation location, as they relate to the expected axial performance. Contributing factors include:"

Jan 1, 2015

By Ambarish Ghosh, Chitralekha Ghatak, Tanumaya Mitra, Tarun Sengupta, Sajib Das, Sankar Kumar Nath

"Currently construction of important structures like bridges, flyovers and high rise buildings in and around Kolkata are in full swing. These structures have mostly pile or well foundations. The design methodology and construction techniques are being employed keeping in view both the safety and economy of the project. The data presented in this investigation have been taken from Geotechnical Investigation report of Component B in connection with construction of Extradosed Cable Stayed Bridge over River Hooghly in Hooghly and Nadia district of West Bengal, India. The investigation site is located within close proximity of Eocene Hinge Zone which is being taken as the principal contributor of Earthquakes in and around Kolkata. Considering the importance of the project detailed and exhaustive geotechnical investigation has been carried out and site specific response spectra have been generated for analysis and design of the bridge. This paper presents site specific response spectra, liquefaction analysis and comparison of lateral load carrying capacity of pile using Winkler approach and IS 2911 guidelines.INTRODUCTIONPile foundations are used to transfer the load of the super structure through soft soil deposit to deeper bearing stratum by means of skin friction or end bearing or both. Pile foundations are regarded as a safe alternative for supporting structures in seismic areas and have been used for this purpose in non-liquefying as well as liquefying soils. But their design in case of potentially liquefiable soil is quite different from that of non liquefiable soil. In liquefiable soil the progressive buildup of excess pore water pressure will cause stiffness degradation and loss of strength which in turn will induce additional shear force and bending moment in the pile. The mechanism of pile behavior in liquefying soil has been investigated by several investigators in the recent years based on observations of pile performance during earthquakes and studies in the centrifuge and Shake Table tests. Exhaustive geotechnical investigation has been carried out along the proposed alignment of the Extradosed Cable Stayed Bridge i.e., along Baropara, Bansberia ROB, Ishwar Gupta Bridge, Saraswati River to collect disturbed as well as undisturbed soil sample, to develop average soil profile and to determine the design parameters. The proposed project site is very close to Eocene Hinge Zone, which is basically a strike slip fault, capable of generating an earthquake of Mw 6.7. Thus it is evident that the proposed Bridge needs to be designed considering the adverse geo-hydrological condition as well as the earthquake aspects needing special attention following the state-of-the-art technology as guided by relevant codes and published literatures. Considering the soil profile of these locations ground response analysis has been carried out using equivalent linear method to determine the site amplification. Site specific response spectra have been developed for the four zones and zone factors have been determined. The computed zone factors are 0.198g, 0.195g, 0.195g and 0.20g for the four zones respectively, much higher than the zone factor 0.16g, which is for zone III, as stipulated in IS 1893:2002."

Jan 1, 2015

By Kessi E. Zicko, Eric A. Hackenberg, Paul J. Lewis

"Following snow melt and spring rains in 2011, a landslide measuring approximately 600 feet long and 300 feet in slope length occurred within the southbound roadway embankment of a heavily travelled 2-lane divided highway in North Central Pennsylvania. Driven steel piles were designed to stabilize the embankment slope. Factors affecting the selected stabilization technique included an adjacent reservoir, wetlands, the length and depth of the failure plane, extent of glacial lake deposits, excess pore pressures in the foundation soils, and an area of archaeological interest. Field reconnaissance and subsurface explorations including borings, instrumentation, geophysics, and laboratory testing indicated that glacial lake deposits were present in the toe region of the embankment. Instrumentation proved key in measuring excess pore pressures and in locating the failure plane, and geophysics was utilized to estimate the extent of the soft glacial lake deposits and to estimate pile lengths. The existing condition of the embankment was modeled in computer slope stability analyses, which were also used to help assign soil parameters. Significant costs were associated with constructing a berm due to the impacts on adjacent site features. Therefore, multiple rows of driven steel H-piles were designed for installation along the toe of the embankment. The design lateral load in the piles was based on slope stability analyses, and the pile size and number of piles were based on lateral pile computations with modified p-y curves to account for installing piles in an active landslide. The relationship between the factors of safety from slope stability and the LRFD pile design was significant in determining pile loads for lateral analyses.INTRODUCTIONA landslide developed along the lower portion of the southbound embankment of State Route 15 in Tioga County, Pennsylvania. The road passes through a steep valley and is located along the southern extent of the Tioga Reservoir. Although no damage to S.R. 15 was attributed to this landslide, the close proximity of the slide to the road posed a concern for the long-term stability of this section of roadway.This paper presents a summary of the site history; the subsurface conditions based on borings, instrumentation, a geophysical survey, and laboratory testing; slope stability analyses including alternatives assessment; and the pile design.SITE HISTORYS.R. 15 was originally located in the valley along the Tioga River and traversed through the towns of Tioga and Mansfield. Although the reason is unknown, it is interesting to note that Old S.R. 15 curved away from the river in the area of the landslide. In the mid 1970’s, S.R. 15 was relocated to the eastern hillside prior to construction of the Tioga-Hammond Reservoir by the U.S. Army Corps of Engineers. The relocated highway was constructed in stages. Two lanes of relocated S.R. 15 were initially constructed to carry one lane of northbound and one lane of southbound traffic. At this same time, the majority of the fill was placed for two future lanes immediately to the west, which would eventually allow for two lanes in each direction. The two eastern lanes would then carry northbound traffic after completion of the two southbound lanes to the west."

Jan 1, 2015

By William G. Ryan, David S. Graham, Dan A. Brown, Rich A. Lamb, Paul J. Axtell

"The St. Croix River Crossing project on the Minnesota-Wisconsin border has been in the process of planning and public debate for two decades, with several changes in alignment. During the course of the earlier planning process in 1995, a drilled shaft load test was performed to obtain preliminary design information. There were some difficulties in maintaining stability within the weak sandstone bearing formation, and the measured axial resistance was relatively low. Subsequent experience by the Minnesota Department of Transportation with similar weak sandstones on the I-35W project suggests that improved construction techniques using modern drilling fluids may offer opportunities for improved performance. During final design in 2012 a second load test program was performed of a full scale test shaft constructed using polymer drilling fluids. The stability of the socket excavation in the weak sandstone appeared to be greatly improved and the measured axial resistance significantly higher.This case history illustrates the excellent performance that drilled shafts can provide in even relatively weak sandstone bedrock as well as the profound influence on axial resistance associated with the construction techniques used. The improved resistance values obtained by the new load test with more recent construction technology allowed the foundation scheme to be substantially optimized with respect to the number and size of required drilled shafts, reducing the size, cost, and risk of the coffercells and footings.IntroductionThe Minnesota Department of Transportation (MnDOT) has awarded the first phase of a bridge construction project that will cross the St. Croix River between Oak Park Heights, MN and St Joseph, WI. The first phase construction contract involves building the river pier substructures including groups of drilled shafts beneath each tower leg. A general location of the bridge project is provided in Figure 1.Prior to award of the construction contract, two separate design-phase axial load tests were performed on non-production drilled shafts with rock sockets. Both tests were static, bottom-up tests using the Osterberg Cell (O-cell). The first test was performed in 1995 when final design and construction was thought to be imminent. After years of public debate and literally, an act of Congress, design of the project was finally restarted and a second load test performed in 2012. The 1995 test was conducted on the Minnesota bank approximately 900 ft southwest of the St. Croix River bank. The 2012 test was conducted in the river about 2,100 ft northeast of the1995 test location. A plan-view of the project indicating the test program locations relative to the bridge alignment is provided in Figure 2."

Jan 1, 2015

By Richard Stone, Rouzbeh Afsharhasani, Moses Karakouzian

"Caliche, a hardened sedimentary deposit of calcium carbonate that occurs worldwide, generally in arid or semiarid regions, is frequently encountered in Las Vegas, Nevada. The presence of a caliche layer in a soil profile affects the response of deep foundations to axial load. This paper studies the stiffening effect of caliche layers on the elastic settlement of a pile foundation. In order to evaluate the response in a layered soil-caliche profile, finite element analyses were performed on a typical-sized single pile and a pile group, both having constant diameter and length of the pile. The results indicate that the stiffening effect from the caliche is noteworthy, and a layer with a relative thickness of at least one pile width, regardless of its location, reduces the pile settlement for both single piles and group of piles systems by at least 50%.IntroductionThe presence of cemented materials in the soil profile influences the settlement response of foundations. One type of cemented material that can be found in arid places around the world is a sedimentary deposit of calcium carbonate called caliche. Caliche, a hardened sedimentary deposit of calcium carbonate, is common in arid and semi-arid urban areas, such as Las Vegas, Nevada (Wyman, et al. 1993).Caliche is mostly observed in lacustrine, river, and alluvial fan deposits (Jr.C.C 1970). It is also found in Central and Western Australia, the Kalahari Desert, the High Plains of the Western U.S., and the Sonoran Desert of the U.S. and Mexico.Some conditions required for the formation of caliche are that country or basement rocks must be a carbonate type, carbonate must be present in the soil zone of the area, climate regime is semi-arid to arid, there exists widespread capillary activity, and carbon dioxide (CO2) is present in the environment. As a result, caliche occurs as a product of the carbonization process (Atabey, Atabey and Kara 1998). In such areas where foundations are constructed on thin rock layers (caliche), special geotechnical design conditions should be considered, particularly if the supporting rock layer is underlain by a weaker material."

Jan 1, 2015

By Swaminathan Srinivasan, Aaron J. Muck

"When an opportunity arises to combine state-of-the-art concepts with advanced modeling tools, engineers need to take what they know and apply forward thinking to geotechnical solutions to promote the state-ofpractice. Such an opportunity was seized during the design and construction of the Great American Tower in Cincinnati, Ohio. The forty-one story Great American Tower at Queen City Square – currently the tallest building in Cincinnati – has not only changed the downtown skyline, it is also contributing to the advancement of the state-of-the-art use of auger cast-in-place (ACIP) piles as settlement reducers. Predicted settlements of a traditional mat foundation were excessive, and the costs and construction time associated with traditional ACIP piles extending to bedrock were not preferred. A mat supported on a limited number of ACIP piles, with the piles primarily acting as settlement reducers, was evaluated as the preferred foundation type.Promoting the unique soil-structure interaction of the foundation system with confidence required the use of sophisticated numerical modeling tools. Traditional standard penetration test boring data (SPT) was initially used to develop a numerical analysis of the soil-structure interaction using FLAC 3D software. The model was further modified with cone penetration (CPT) and pressuremeter testing (PMT), along with actual load test results on several ACIP pile elements of varying lengths, but all tipping above bedrock. Through a combined design team effort, and detailed numerical modeling analysis, ACIP piles were recommended for reducing mat foundation settlement. Instrumentation during and post-construction confirmed design assumptions and predictions. Integrating sound geotechnical concepts, and using advanced geotechnical analysis and design methods, traditional mat and ACIP pile foundations were successfully integrated into a unique foundation support system.INTRODUCTIONThe Great American Tower at Queen City Square in Cincinnati, Ohio is located within a region dissected by historical geologic deviances associated with the meander of the Ohio River and glacial progression/recession. Combining a challenging geology, with the development of a high-rise office building afforded the design team an opportunity to combine state-of-the-art soil-structure interaction concepts and method with traditional geotechnical engineering concepts. Such a combination required a variety of field tests, collaboration with the design team and owner, and geotechnical-structural modeling during the design phase. During construction, in addition to materials testing and observation, a variety of instrumentation systems were employed. Together, the data was used to corroborate the design model and make adjustments during construction and further substantiate design assumptions following construction."

Jan 1, 2015

By Mingmei Zhu, Xin Qiu, Xiaofei Dou, Yu Wang, Tiancheng Lin, Bing Xie

In this study, the slag forming route of the single-slag steel melting when smelting medium phosphorus hot metal was investigated. The CaO-SiO2-FeO-MgO-MnO-P2O5 as hexahydric slag system was adopted in the converter. The effect of slag composition on liquidus was calculated by FactSage, the isogram of phosphorus distribution ratio was calculated by using the regular ion solution model, combining these two tasks, the theoretical slag forming route was obtained. Through experiments, the actual melting point ofthe corresponding components on theoretical slag forming route was obtained, in this way, the theoretical slag forming route was confirmed. Then, the theoretical slag forming route was applied to industrial test in a 210t BOF. After using the new slag formating route, the dephosphorization ratio was increased 3.6% while the auxiliary materials consumption was reduced, and the cost of steelmaking was reduced.

Jan 1, 2015

By Adegbenjo Adewale Oladapo, Ibitoye Simeon Ademola, Ladiipo Olufemi Akinbiyi, Adegbola Adekunle Amos, Adeboje Taiwo Bode, Raji Fatai Olasunkanmi

The combined effects of the addition of Silicon (Si) as alloying element and low temperature annealing on the tensile properties of 70/30 brass with Nickel (Ni) and Iron (Fe) contaminants is investigated in this paper. Melts of cartridge brass were made to which 0, 0.5, 1, 2, 3 and 4 wt % of Si was added. These were sand cast into rods of 600 mm by 10 mm diameter and were thereafter machined into standard tensile test samples. Some of these samples were annealed in a muffle furnace at temperatures of 250, 300, 350, 400 and 450 oC respectively and the others were used as control. Subsequently, all the heat treated and non heat treated samples were subjected to tensile tests on a Hounsfield Extensometer and the load – extension plots retrieved were analyzed. Microstructural characterizations of the samples were carried out using Accu-Scope Optical Microscope. The results showed that cartridge brasses subjected to alloying and annealing treatments had improved tensile and yield strengths. However, the tensile properties were increased and maintained within acceptable limits at stress relieve annealing temperatures.

Jan 1, 2015

By Edwin Adoyi Ali, Zainab Shehu Aliyu, Adele Dzikwi Garkida, Muhammad Dauda

Feldspar from Matari, Nigeria was analyzed using SEM, XRD and XRF techniques for microstructural analysis, mineral phase analysis and chemical composition analysis respectively. Qualitative and quantitative XRD analyses revealed the presence of microcline 59.6%, albite 34.7% and quartz 5.71%. The XRF results showed that the feldspar contains 67.32% SiO2, 17.54% Al2O3, 11.33% K2O, 2.75% Na2O, 0.12% CaO, 0.01% MgO, 0.02% MnO2, 0.10% Fe2O3, 0.00% Ti2O, etc and 0.14% LOI. SEM/EDX analysis shows the presence of microcline feldspar as the dominant phase, exhibiting lamellar twinning. The XRD has also revealed that potash has the highest peak, indicating its high concentration. The 0.10% Fe2O3 present is within the permissible level (0.1-0.3%) for glass making and also within the potash feldspar specifications (0.17%). The Matari feldspar is a microcline type, rich in potash, alumina and silica, enabling it meet the standard specifications for alumino-silicate glass.

Jan 1, 2015

By Fabio J. Esper, Wildor T. Hennies, Guillermo R. Martín-Cortés, Francisco R. Valenzuela-Díaz, Antonio J. Santana de Araujo, Maria G. Silva Valenzuela

Seeking to replace carbon-black as filler of rubber in the production of vulcanized goods, researchers from University of São Paulo have studied different materials types as minerals, vegetal or wastes agricultural and industry. Results of rubber composites filled with MA1 a waste of mineral treatment provided by Esper Industries are presented. MA1 was characterized through X-ray diffraction; Thermal analysis; Scanning Electronic Microscopy; and others laboratory methods. The composite and shaped masses were evaluated by these methods plus their mechanical properties such as tensile strength, elongation at break and hardness. Exceptional results were obtained in the mechanical properties evaluated, better than those obtained with the traditional carbon-black. Seeing the kind of material used as filler, it can conclude that the environmental benefit is present, as well as economic development, giving credibility to the use of these alternative material in replacement carbon black.

Jan 1, 2015

By XUEWEN WANG, Bowen Li, Mingyu Wang

A novel technology characterized by higher extraction of vanadium and recovery of valuable elements was developed to recover vanadium from stone coal. The brief flow of the novel technology mainly includes low temperature sulphation roasting, water leaching, recovering potassium, aluminum, copper and selenium, solvent extraction enrichment vanadium, precipitation of red vanadium, removal sodium from red vanadium and calcinations. The total recovery of vanadium reached 76.3%, which was higher than the current applied technology. The novel technology was environmentally-friendly and could extract vanadium from the stone coal, in which the content of V2O5 was less than 0.8%.

Jan 1, 2015

By Xi-Shan Li, Qian Li, Yong-bin Yang, Tao Jiang, Jie Ge

Compared with other pretreatments of sulfur & arsenic-bearing gold, double-layered pellet roasting has an advantage that sulfur dioxide and arsenic trioxide volatilizing from this refractory gold ores can be solidified into the coating without emission during the roasting. However, the separation of coating from roasted double-layered pellet should be focused on in the novel pretreatment. Based on the difference of physicochemical characteristics between roasted solidified coating and pellet core, several separation methods including grinding, drop impact and water quenching method had been systematically studied in this paper. The results showed that magnetic and gravity concentration could not obtain a satisfactory separation effect. The optimum separation rate of grinding was only 38.94% at grind time 12min, but it increased to 85.05% by drop impact under drop height 0.75m, drop times 20 and impact angle 45°, and that of water quenching taking advantage of slaking reaction of lime could approach 75.32%.

Jan 1, 2015

By Tobias Dubberstein, Hans-Peter Heller

The viscosity of Fe-Cr-Mn-Ni TRIP/TWIP (Transformation Induced Plasticity, Twinning Induced Plasticity) steel with varied nickel content is investigated using a vibrating finger viscometer. The viscosity of the melt is calculated from the change in power input in the field coil by an immersed finger into the liquid steel to maintain a constant peak-to-peak amplitude of the sine wave of oscillator compared to the idle state. Nickel content in steel is varied from 3 wt% to 9 wt%. The dynamic viscosity (η) at 1600 °C for 3 wt% Ni is 3.73±0.14 mPas, for 6 wt% Ni 3.50±0.03 mPas, and for 9 wt% Ni 3.93±0.09 mPas. There is a kink from low to high nickel content in viscosity values of Fe-Cr-Mn-Ni alloys. This phenomenon can be explained by a change in coordination number in the melt, as reported for Fe-Ni binary system in literature. The availability of viscosity data delivers relevant input to model free fall atomization processes of FeCrMnNi alloys.

Jan 1, 2015

By Jiann-Yang Hwang, Ying Qin, Shu-Jing Zhu

Metallurgical Oil Sludge (MOS) is a byproduct created in the process of steelmaking. More than a million tons of MOS are generated each year throughout the world. The material contains hazardous components such as heavy metals and pathogenic organics, which can cause serious environmental problems and health issues. Landfill, combustion, and pyrolysis have been investigated for the disposal of MOS. However, these methods are unsatisfactory since they are unable to reach the clean environment goal. In this study, we investigate the possibility of using MOS as a reductant in a high temperature metallurgical process. The results are reported and discussed.

Jan 1, 2015

By Min Chen, Lei Xu

Sintering behavior and performance of high alumina refractory based on the ternary subsystem MgAl2O4-CaAl4O7-CaAl12O19 were investigated using ZrO2 as an additive up to 8 wt.% by solid state reaction sintering. It was found that the added ZrO2 could dissolve in the CA6 grains in the form of a solid solution, which enhanced the isotropic growth of CA6 grains and then improved the sintering. As a result, the densification process was improved and areas with enrichment of ZrO2 showed a more compact structure. With further increase of ZrO2 addition, tetragonal ZrO2 were found to locate in the grain boundaries for exceeding the solid solubility limit, which enhanced the thermal shock resistance, indicating that addition of ZrO2 exhibited a positive effect on sintering behavior and performance of this refractory. In addition, it is considered that the optimal amount of ZrO2 addition was about 4% considering the performance together with the cost.

Jan 1, 2015

By Valdeci Paula Alvarenga, Sergio Luiz Costa, Itavahn Alves da Silva, Filipe Bueno Carvalho, Varadarajan Seshadri, Carlos Antonio da Silva

Use of fluorspar in steel refining operations is one of the environmental concerns and as such reduced consumption of this material or substitution of the same is one of the objectives. Industrial runs were carried out at Aperam Steel making convertor unit (Timóteo, MG, Brazil) using recycled/briquetted slag for partial or complete substitution of fluorspar. Samples were collected from the metal bath and slag after oxygen blowing to assess dephosphorization with several combinations of recycled/briquetted slag and fluorspar. The results showed that partial substitution of fluorspar by BOF slag briquettes did not affect the efficiency of dephosphorization. In general average Phosphorus content was reduced to 0.010% in the case of partial substitution compared to 0.016% in the regular refining procedure with no substitution. This replacement also resulted in 40% reduction of the fluorspar consumption in the converter

Jan 1, 2015

By Sylvain Gouttebroze, Mohammed M'Hamdi

In a previous work, a small scale Bridgman furnace has been used to study silicon bi-grain crystallization at different cooling rate. This work expands the analysis by studying the mechanical interaction between the crucible and ingot during the solidification and cooling. The thermal model is based on a 2D-axisymetric heat-transfer model. The flux histories are then transferred to the ingot-crucible 3D-model. Anisotropic Elastic and Crystal Plasticity model are used to model the silicon deformation. Four different assumptions are applied to model the mechanical contact crucible-ingot and three grain misorientations are considered. The results show the strong impact of the alumina crucible contraction on the stresses and deformations in the silicon ingot.

Jan 1, 2015

By M. Jahazi, P. P. Bhattacharjee, K. Chadha

The present work investigated the effect of strain reversal during high pressure torsion on the evolution of microstructure, texture and hardness properties of two different materials with different dynamic recovery behavior, namely, high purity (99%) Aluminum (2N-Al) and Aluminum-Magnesium (Al-2.5%Mg) alloy. In the two aluminum alloys subjected to different routes, the evolution of the ultrafine structure followed same trend. At lower strain level, sub grains with prominent LAGBs network were observed and at higher strains, ultrafine equiaxed grains separated by HAGBs were observed throughout the disk. The texture evolution in monotonically and strain reversal processed 2N-Al and Al-2.5%Mg showed presence of typical torsion texture components at different strain levels. The strength of the components was observed to follow different trends depending on the processing routes.

Jan 1, 2015