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By Ryan G. Wade, Mark K. Larson

Researchers at the National Institute for Occupational Safety and Health (NIOSH) are studying the time-dependent response of rock stressed along weakness planes. The objective is to improve mine safety by reducing the number of roof falls that cause injuries and fatalities to miners. Researchers conducted direct-shear tests on mudstone overcored from a coal mine roof. Results showed frictional strength weakens with displacement along the shearing planes. Results of direct-shear creep tests also showed time-dependent deformation. Test measurements were compared to classical analytical models. Results suggest that risk of roof collapse may be decreased through layout and support design to reduce creep rates and thus slow progression toward failure.

Provide an economic alternative to drill-blast excavation with the same ability to excavate openings of varied orientation, shape, and size. Approach Develop an efficient, adaptable, mechanical excavation machine that produces unconfined tensile failure in rock. How It Works A drill-split fragmentation machine that combines a drill and a unique splitter has been developed. The drill and splitter are mounted on a carriage that positions the splitter in a hole immediately after it is made by the drill. The splitter creates force loads that cause the rock to fragment, and the process is repeated for excavation. The unique splitter applies both radial and axial loads to the rock mass, which produces an excavation action comparable to pulling a plug. This excavation action distinguishes the radial-axial splitter from typical demolition splitters, which require a free surface parallel to the axis of the splitter toward which to break rock.

Jan 1, 1989

By Thomas V. Falkie, R. Venkataramani

The method of analysis was to test a large model containing potentially significant variables and on the basis of the results obtained, to reduce the model to one containing only the essential significant variables. This stepwise procedure of "scanning" a large proposed model and subsequently condensing the model consisted of two cycles of the same series of computational procedures. Data Preparation A majority of the variables measured were continuous over a specific range of values; for example, the variable "Width Ratio" varied in practice from 0.25 to 1.00. However, "dummy" values were assigned to certain operational variables in order that these varia¬bles would have numerical expression. The following variables were described in this manner. Variable "Dummy" Value x3: Development/Pillaring 0, if pillar extraction was being done 1, if development mining was being done x4: Boxcut/Open Cut 0, if a box cut was being made 1, if an open cut was being made The variables under consideration are represented symbolically as follows: Y: Loading rate (tons per minuts): TONS/MIN x1: Ratio, width of cut/width of cutter: WDRATIO x2: Ratio, height of cut/diameter of cutter: HTRATIO x3: Development or pillaring: D/P

Jan 1, 1972

Design and test a high-production coal mining machine that generates less respirable dust. Background Current coal cutting systems generate excessive amounts of airborne respirable dust and fines during the mining process. Dust control technologies, including dust dilution by ventilation and suppression by water sprays, are not always able to reduce dust levels sufficiently. The U.S. Bureau of Mines (USBM) has designed a cutting system that reduces respirable dust generated by the cutting action of the drum. This cutting system, based on geometric principles developed in the 1500's, makes use of a constant depth, linear cut to remove coal at deeper cut depths and at lower rotary speeds than a conventional rotary drum. A comparison of the linear and rotary cut paths is shown in figure 1. Approach A full-scale prototype of the linear cutting concept was valuated under laboratory conditions to determine its performance relative to standard rotary drums. Results of these evaluations show production of fewer fines, or more uniform product size, a significant reduction in the amount of airborne dust, and reduced torque and power requirements (figure 2). On the basis of these results, a contract effort was undertaken by McCracken and Associates of Bristol, TN, to design a linear cutting head for underground testing.

Jan 1, 1995

By G. S. Rice, H. P. Greenwald

"Experience and experiment have goth shown that a cloud of coal-dust in air can be inflamed and an explosion developed only when a certain minimum concentration of the dust in air has been equaled or exceeded. Those who have had experience in the handling of coal know that dust is frequently present in the air and may be of sufficient density to obscure an ordinary electric light at a distance of 40 or 50 feet; yet flames may be, and times without number have been, introduced into such clouds, when no additional coal-dust has been stirred up, with no effect other than the burning of the dust particles which actually enter flame. Evidently the density of the dust cloud is insufficient to give self-supporting combustion.The minimum amount of dust in air required to give a spreading flame will vary with a number of factors such as the composition of the dust and its size. This amount in a unit space may be considered analogous to the lower limit of inflammability of fire damp (methane) in air, although the variation in limit of explosibility of gas is small even when conditions of the experiment are altered. In large-scale determinations of the lower limit of inflammability of coal-dust there is no certain method by which a sample of the dust cloud can be snatched and its density determined. It is necessary to produce the best possible dust cloud from a known weight of dust, in a known volume and assume - probably with considerable error - that the dust cloud is reasonably uniform. The dust cloud must be formed and the source of ignition applied to it simultaneously; this is generally accomplished by the use of blow-out shots of black blasting powder, dynamite, or similar explosive so prepared as to blow out like a cannon shot, or by a gas explosion. The more violence attending the source of ignition, the greater is the probability that all the dust is raised in a uniform cloud; and the greater the length or intensity of the flame, the greater are the chances of ignition. As a result one may obtain a variation in apparent minimum density with different sources of ignition. This difference is more apparent than real and must remain until devices for instantaneous sampling of dust clouds during explosions are perfected."

Aug 1, 1931

By Howard E. Parkinson

A brief description is given of various Bureau of Mines research activities that have begun since July 1974 and are not being reported on by others at the Third West Virginia University (WVU) Conference on Coal Mine Electrotechnology. An essential feature of the various projects is that they are pragmatic. The projects are applied research and are carried out both by the Bureau in-house research group and by other research groups through contract research. Projects have been directed toward wired-type communications with a special effort to modify the wired systems so as to be more effectively used. The projects are in three groups: Pager phone systems, trolley line phone systems, and guided-wire wireless communications. Also, a brief sketch is given of research that is essential for further developments in mine communications. From the early results of these various projects, the Bureau has good reason to project that there will be improved performance of existing communication systems and that communications will be extended to other individuals working in areas that are excluded from present mine communication systems.

By R. Barany

The heats of the glass-crystal transformation of nepheline (Na0.7794K0.2206AlSiO4) and wollastonite (CaSiO3) and the heat of formation of nepheline at 298.15° K were determined by solution calorimetry. For the glass-crystal transformations, the heat values were -9.0 ± 0.3 kcal/mole for nepheline and -8.1 ± 0.2 kcal/mole for wollastonite. The heat of formation of nepheline was -34.8 ± 0.6 kcal/mole from the oxides and -501.0 ± 0.5 kcal/mole from the elements.

Jan 1, 1966

By Matthew J. DeMarco, Anthony T. Iannacchione

Coal bumps have presented serious mining problems in the U.S. throughout the 20th Century. Fatalities and injuries have resulted when these destructive events occur at the working face. Persistent bump problems can result in abandonment of large reserves or lead to premature mine closure. Through the years, alternative techniques such as artificial supports, extraction sequencing, destressing, pillar design changes and specific pillar retreat practices have been successfully implemented to mitigate coal mine bumps. Several techniques have evolved for room-and-pillar operations that control the way the roof rock breaks, regulating the manner in which stresses are redistributed in the mined section. Special mine layouts employed in longwall mines have also proved to be successful in safely redistributing or containing excessive loadings. However, with ever increasing production rates, greater overburdens and new mining systems, the need to evolve even more effective bump control designs will continue to challenge the U. S. coal mine industry.

By R. Barany

This paper reports determinations of heats of formation (from the oxides and elements) of crystalline cadmium metasilicate and crystalline lead meta-silicate by hydrofluoric acid solution calorimetry. The results, in conjunction with known entropy values, yield free energies of formation. There are no earlier data of this type for cadmium metasilicate. The results of this investigation for lead metasilicate deviate from the literature values (which are less reliable) in the direction of increased thermodynamic stability. Both cadmium and lead metasilicate are much less thermodynamically stable with respect to their constituent oxides than are the corresponding compounds of the alkaline earth metals.

Jan 1, 1959

By M. M. Tilman

The Bureau of Mines conducted research into the dispersion strengthening of lead by the coprecipitation method. Commercially available reagents in water solutions were reacted to form homogeneous precipitates of lead and aluminum compounds. The resulting precipitates were roasted to oxides and reduced in hydrogen to form mixtures of lead powder and alumina. The powders were isostatically pressed into billets which were extruded into rods. The rods were rolled into strip to provide material for testing. Alloys containing 0.5, 1, 2, and 3 nominal volume-percent A1203 were tested in short-time tensile tests and in tensile creep tests. An alloy of Pb-3 volume-percent A1203 exhibited an average tensile strength of 8,570 psi after rolling to 75-percent reduction at 125° C but had no measurable elongation. Alloys of lower A1203 content provided a better compromise between tensile strength and ductility. For example, an alloy of Pb-0.5 volume-percent A1203 had an average tensile strength of 6,590 psi with 9-percent elongation after rolling to 75-percent reduction at 125° C. Creep rates of dispersion-strengthened Pb-A1203 alloys were below 1 percent in 10,000 hours at stresses of 2,000 to 4,000 psi.

Jan 1, 1971

California's coal resources are estimated to be 100 million tons, of which 50 percent is lignite, 40 percent subbituminous, and 10 percent bituminous. The occurrence of coal in California is rather limited and is restricted generally to the foothill regions of the western slopes of the Sierra Nevada Mountains. Significant quantities of coal have been mined in five areas: Ione in Amador County, Alberhill in Riverside County, Stone Canyon in Monterey County, CorralHollow in Alarneda County, and Mount Diablo in Contra Costa County. Most of the coal was rnined in the early 1900s and was used locally for fuel. Current mining operations are located in Amador County near the city of Ione. The two producing mines supply fuel to a mine-mouth co-generation power plant. The fuel coal is processed prior to burning to extract montan wax. Because California does not have primacy, coal mining in the state is regulated by the Office of Surface Mining's Albuquerque, New Mexico, Field Office.

Jan 1, 1992

By Charles D. Litton

Experiments were conducted to determine the optical scattering properties of diesel particulate matter (DPM) and various combustion aerosols from both flaming and smoldering combustion sources at discrete angles of 151 and 301 in the forward direction and at a light source wave length of 635 nm using a simple light scattering module. In addition to the scattering data, simultaneous measurements were made of the total aerosol mass concentration; light extinction at an average wave length of 546nm; and the response of a common bipolar ion chamber typical of residential smoke detectors modified to allow the aerosols to flow through the chamber. The results of these experiments indicate, for DPM and combustion aerosols, the intensities per unit mass concentration depend not only upon whether the aerosolis DPM or combustion aerosol but also upon the type of combustion aerosol. The results also indicate that the ion chamber responses are greatest for DPM, followed by the response to flaming combustion aerosols (FCA)and lowest for smoldering combustion aerosols (SCA). For light scattering, the greatest intensities are found for SCA, followed by the intensities from FCA, and lowest for DPM. This report describes the experiments, their results, and the use of these results to developed sign criteria for early warning fire sensor capable of the rapid and reliable detection of fires in atmospheres that may or may not be contaminated by the products produced from diesel engines. © 2002 Elsevier Science Ltd. All rights reserved.

By Alexander May

In this Bureau of Mines publication stability constants for complexes of diethylenetriamine, 2-aminoethyl sulfide, triethylenetetramine, and 1,8-diamino-3,6-dithiaoctane with copper, nickel, zinc, and cadmium were deter-mined. The amine complexes were found to be much more stable than the analogous thio complexes. The results are interpreted in terms of possible molecular structure of the complexes.

Jan 1, 1974

By Roy F. Abernethy

This report describes a method developed by the Bureau of Mines for the determination of beryllium in coal ash. Samples are put into solution by standard wet chemical procedures. Interfering elements are complexed with Na2EDTA, and the beryllium is separated by extraction of its acetyl acetone complex with chloroform or carbon tetrachloride. Final determination is made with Beryllon II.

Jan 1, 1970

By Samuel W. McNary

In August 1984 the U.S. Bureau of Mines conducted a study of the mineral resource development potential of the Badger Canyon-Antelope Creek area, within the Boulder-Pioneer wilderness study area, about 5 miles northeast of Ketchum, 10. The purpose of this study was to investigate in greater detail an area which was designated by the U.S. Geological Survey (USGS) and the Bureau as having a moderate mineral resource potential for zinc, molybdenum, lead, and silver, and a low potential for copper. One hundred twenty-eight soil samples were taken along a 6,2S0-ft traverse on the ridge separating Badger Canyon and Antelope Creek. 5 Five rock samples were collected from old prospect pits and mineralized outcrops. All samples were analyzed for gold. Silver, copper, lead, zinc, molybdenum, arsenic, antimony, vanadium, and mercury. The metal concentrations in the soil samples along the traverse are irregularly distributed. Samples collected near old prospect pits tend to be high in lead and zinc, undoubtedly a reflection of underlying galena-and sphalerite-bearing quartz veins. All of the copper and mercury values in the soils are less than the detection limit, as are most of the lead, molybdenum, and antimony values. Except for lead and zinc values, the metal concentrations in the rock samples are low. Galena and sphalerite were observed in quartz vein samples collected at the old prospects. The results of the study indicate that the galena-sphalerite-bearing quartz veins and veinlets are too narrow, widely-spaced, and low in metal values to be economic. Low concentrations of metals in the soil and rock samples, combined with the lack of major mining activity in the past, indicate that the area has a low likelihood for economic development.

Jan 1, 1986

By Thomas J. Fisher, Thomas Novak

Strong circumstantial evidence suggests that lightning has initiated methane explosions in abandoned and sealed areas of underground coal mines. The Mine Safety and Health Administration (MSHA) investigated several of these occurrences within recent years. The investigated explosions occurred at significant depths, ranging from 500 ft to 1200 ft. Data from the National Lightning Detection Network indicate a definite correlation between the times and locations of the explosions with those of specific lightning strikes. This paper addresses the question, "Can lightning cause potential differences capable of igniting methane-and-air mixtures at overburden depths at which underground coal mining occurs?" A mine depth of 600 ft was selected for this initial study. Computer simulations were performed, with and without the presence of a metal- cased borehole extending from the surface to the mine level. CDEGSTU software from Safe Engineering Services & Technologies, Ltd (SES) was used for the simulation.

By M. G. Zabetakis

Amyl nitrite (C5H11NO2) is a pale-yellow liquid with an ethereal fruity odor and a pungent aromatic taste. Its use in first-aid treatment of cyanide poisoning has been suggested by Chen and his coworkers. Although not the most effective treatment, it is the only one that does not require intravenous injections and is, therefore, very suitable as a preliminary measure, which only involves breaking a capsule near the patient's nose until intravenous injections can be given. In the case of the sodium nitrite -sodium thiosulfate treatment, for instance, such injections require about 15 minutes. As amyl nitrite "Pearls" (small capsules containing liquid amyl nitrite) are placed in many first-aid kits by various companies that handle, store, or use hydrogen cyanide gas, it appeared advisable to investigate the explosion hazards of this material in air and oxygen. Accordingly, tests were made to determine the limits of flammability, temperature range of flammability of amyl nitrite saturated with air and with oxygen, and minimum ignition temperatures of this material in air and in oxygen.

Jan 1, 1952

By E. G. King

Low-temperature heat capacity determinations of the minerals goethite and pyrophyllite were made in the temperature range from 510 to 298° K. The entropies at 298.15° K were evaluated as 14.43 ±0.15 cal/deg mole for goethite and 56.6 ±0.5 cal/deg mole for pyrophyllite. The entropies of formation from the constituent oxides are -4.4 ±0.2 cal/deg mole for goethite and -12.3 ±0.6 cal/deg mole for pyrophyllite. The standard free energy of formation of goethite from its oxides is ?G°298.15 = 0.16 ±0.20 kcal/mole.

Jan 1, 1970

By R. V. Ramani, C. B. Manula, A. Owili-Eger

Network analysis of mine ventilation systems is not new, having been traced back to 1854. A Committee Report (1970) has also reported the extensive work done in this respect in the United Kingdom, Japan, U.S.S.R., South Africa, United States, and other countries. Wang, et al (1970) developed a computer program which is an improvement over the earlier one developed by Wang et al (1967). The program has been recently modified and extended to include methane emission features by Owili-Eger (1973). This computer program incorporates all the novel features of the earlier programs. These include the capabilities of mesh selection, free splitting, internal or external fans, natural ventilation pressure and fixed quantity branches. The program is written in Fortran IV and, in effect, is an experimental mine in which many ideas can be tried out. The computer produces, besides the input data and certain computational data, the quantities and head losses in the branches, the head losses to be adjusted in the fixed quantity branches and the fan operating point. The last named program, hereafter to be referred to as the PSU/MVS, is presented in Appendix I. The application of this program is demonstrated in this manual through a series of selected examples. Application of the methane generator program is not included here as a detailed report on the subject is available elsewhere (Ramani et al, 1975).

Jan 1, 1975

By S. P. Kinney, A. C. Fieldner, S. H. Katz

"1 Introduction The regrettable death of James S. Cunningham, Foreman Miner, attached to Bureau of Mines Rescue Car No. 2, while wearing a half-hour type oxygen breathing apparatus in a gasoline storage tank at Trinidad, Colorado, raised the question as to the possibility of gasoline vapors permeating the rubberized fabric of the breathing bags of such apparatus.It is known that most gases and especially certain organic vapors permeate rubber, by solution or a similar process. The rubber becomes saturated with the gas and if a concentration of gas is maintained on one side of the rubber sheet it slowly gives off gas from the other side. It of course takes some time for the gas to diffuse through the rubber and the length of time before it reaches the other side is proportional to the thickness of the rubber. The amount of gas that passes through per unit of area in unit time increases with the concentration of gas and also varies with the structure and composition of the rubber.It has been suggested that the gasoline vapor could not have penetrated into the interior of an oxygen breathing bag because the pressure is greater on the inside, but this is not true as the process of permeation by solution in the rubber is affected only by the difference in the partial pressures of gasoline vapor on the inside and outside of the bag. The positive oxygen pressure on the inside can only prevent the entrance of gasoline vapor through measurable holes, and has no effect on permeation by diffusion through the rubber."

Dec 1, 1919