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By Joseph W. Town

The Bureau of Mines conducted studies related to SO2 air pollution to determine attritioning rates, SO2 sorption rates, and sulfur loads that could be obtained on commercial alkalized alumina sorbent pellets. Fluidized-bed attritioning rates ranged from 0.025 pct/hr for alkalized alumina with a crushing strength of 4 kg to 0.075 pct/hr for 0.5 kg crushing strength mate¬rial. Airlift attritioning rates ranged from 0.50 pct/hr for 3 kg crushing strength alkalized alumina to about 3 pct/hr for 0.5 kg material. Attritioning rates for the commercial alkalized alumina were comparable to those obtained for sorbent pellets prepared in the Bureau of Mines laboratory. Sorption rates were related to S02 concentration in flue gas, temperature, and presence of nitrogen oxides in the gas stream. Sorption rates at 300° C were 0.35 X 10-6 gS/gp/sec (grams sulfur per gram pellet per second) in 0.045 pct so, gas, 5.1 x 10-5 gS/gp/sec in 0.34 pct SO2 gas, and 65 X 10-5 gS/gp/sec in 10 pct SO2 gas. For the 0.34 pct S02 gas, sulfur loads of 0.10 gS/gp (the projected load for regeneration) were obtained in 47 min at 130° C and in 116 min at 300° C. The presence of either NO or NO2 in the 0.34 pet S02 gas increased the SO2 sorption rates 2 to 3 times at 300° C, but had no effect at 130° C.

Jan 1, 1969

By W. G. Bradley

THIS PAPER describing the quarrying, mining, and crushing of gypsum at the Blue Diamond mine, 11 miles from Arden, Nev., on the Union Pacific Railway, is one of a series on gypsum mining being prepared for and published by the Bureau of Mines. These papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent operating expenditures only and not total costs. It is recognized that publication of total production costs might in some instances cause embarrassment to individual producers as well as to the industry as a whole. On the other hand, operating costs are essential to the technical discussion and study of the methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue.

Jan 1, 1932

By J. W. Holcomb

Many mines are opened into the coal beds by shafts; and, at some of these operations, the same cages or skips that are used for hoisting coal also are used for transporting men into and out of the mines. At some mines, separate man-and-material shafts are maintained, and the cages in these are utilized for transporting men and supplies only. In most instances, these cages are operated either singly or in pairs by a hoisting engine installed in a building near the shaft. Single ropes from the tops of the cages pass over bull wheels on the head frame to either electrically or steam-driven hoisting engines that require engineers to operate them. There are records of several instances where hoisting engineers have become incapacitated suddenly while hoisting men, and the passengers on the cages were killed or injured. Where the same cages are used for hoisting cars of coal and for lowering and hoisting men, especially where self-dumping cages or skips are used, safety pre¬cautions must be taken, such as providing steel bonnets for the cage deck, enclosed sides, adequate handholds, gates for closing the end openings, safety catches, and locking devices to prevent accidental dumping. Some of the newer hoisting installations are of the elevator type; where an operator rides in the cage in the same manner as an elevator operator in a building. These cages have single or multiple decks and are primarily for transporting men; but, in some instances, supplies also are transported. They are a great improvement over the installations where the same cages are used for hoisting cars of coal and transporting men.

Jan 1, 1952

By L. C. IlsLey

"Nearly every piece of electrical equipment used in mines ""breathes."" In other words, motors, controllers, rheostats, switches, and other similar equipment, even though encased in seemingly tight compartments, breathe in the atmosphere that surrounds them.As the apparatus is used, the temperature of metallic parts is changed generally in positive direction through the heat by friction and the heat due to the electric current. When the apparatus is idle it gradually cools down to the temperature of the surrounding atmosphere.This increase of temperature during operation and return to normal temperature when operation stops alternately raises and lowers the temperature of the atmosphere within the compartments which, in strict accordance with Charles' law -will expand or contract in proportion to any given temperature change.As compartments are not gas-tight, such expansion and contraction will force the atmosphere out of the compartment =on expansion and suck the surround¬ing atmosphere into the compartment during contraction, hence the term ""breathing.""Investigators2 of explosion-proof equipment have recognized that such an interchange would take place and have designed their equipment to safeguard possible explosions within the compartments."

Jun 1, 1927

By H. D. Baylor

This paper, describing the operations of the Louisville Cement Co. in quarrying limestone for the manufacture of quicklime, is one of a series being prepared for and published by the United States Bureau of Mines on stone quarries throughout the United States. Those papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent operating only and not total costs. It is recognized that publication of total costs might in many instances cause embarrassment to individual operators as well as to the industry as a whole. On the other hand, operating costs are essential to the technical discussion and study of the methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue. ACKNOWLEDGMENTS The author acknowledges the assistance of J. H. Lemmon, plant superintendent, Charles Taylor, plant engineer, and F. H. Compton, chief engineer, of the Louisville Cement Co. in the compilation and preparation of this paper.

Jan 1, 1932

By J. Nielen van der Merwe

For the last 3 decades, coal pillars in the Republic of South Africa have been designed using the well-known strength formula of Salamon and Munro that was empirically derived after the Coalbrook disaster. The database was recently updated with the addition of failures that occurred after the initial analysis and the omission of failures that occurred in a known anomalous area. An alternative method of analysis was used to refine the constants in the formula. The outcome was a new formula that shows that the larger width-to-height ratio coal pillars are significantly stronger than previously believed, even though the material itself is represented by a reduced constant in the new formula. The formula predicts lower strength for the smaller pillars, explaining the failure of small pillars that were previously believed to have had high safety factors. Application of the new formula will result in improved coal reserve utilization for deeper workings and enhanced stability of shallow workings.

Jan 5, 1999

By J. M. Mutmansky

"The objective of this study was to produce coal dusts for laboratory research that are similar to mine airborne dusts in chemical, mineral, and physical characteristics. In this investigation, dusts produced in laboratory comminution equipment were compared with continuous miner- generated dust for similarity in physical characteristics. Mining-generated dust (MGD) and bulk coal samples were first collected from an underground mining operation. The bulk samples were then processed in the laboratory for size reduction in various comminution devices. These laboratory- generated dust (LGD) samples were subjected to size and microscopic analyses. Physical properties of the dust particles were studied on a scanning electron microscope (SEM ). A numerical shape coordinate system (SCS) was also developed and applied to 300 particles from each sample. Statistical analysis was then performed on the collected data and characteristics of the MGD and LGD samples were compared. IntroductionIn many biomedical studies, researchers routinely introduce a dust mass into an experimental environment to assess the response of a biological entity, usually lung macrophages in vitro or a live laboratory animal, to the dust mass. To provide data of maximum usefulness, it is highly desirable to use dust with characteristics of actual mine airborne dust. The primary objective of this research was to produce dusts in the laboratory similar in chemical, mineralogical, and physical characteristics to mine airborne dusts. This paper outlines the evaluation of the physical characteristics of the lab-generated dusts.Particle shape analysis is perhaps the least-developed area in mineral-related particle science and technology. There are still no standard methods or instruments to scientifically quantify particle shapes. To date, many attempts have been made to characterize particle shapes. These procedures can be roughly classified into three categories:"

Dec 1, 1995

By L. C. IlsLey

In the normal operation of mines, the aggregate effect of many seemingly minor op rations may be very important as respects economy and safety. Anion: these operations is the method employed in coupling and uncoupling mine cars. For economic reasons the equipment in mines has not been protected as well as railroad equipment. It is pertinent that haulage accidents rank second in severity among mine accidents, and that manual coupling of cars has been one of the most frequent causes of such accidents. One study4/ revealed that coupling was responsible for about 20 percent of haulage accidents underground. A review of early conditions on steam railroads, which were responsible for the introduction of safer methods of coupling cars, indicates how conditions in might be improved. THE STORY OF RAILROAD COUPLING As any considerable improvement in mine-car coupling probably will follow lines somewhat similar to those that brought order out of chaos for the railroads, it seems appropriate to review briefly the steps taken to improve railroad coupling from the days of link and pin couplings of various types to the adoption of the standard ?M.C.E? automatic coupler.

Jan 1, 1943

By M. G. Zabetakis

This publication presents a simplified graphic method for determining the explosibility of mine atmospheres under mine-fire conditions from mine- atmosphere composition data. Sometimes it is necessary to seal part of a mine during a fire to exclude air and thus extinguish the fire. Unfortunately, liberation of methane and formation of hydrogen and carbon monoxide in the sealed area may create an ex- plosive or flammable atmosphere if enough oxygen is present to support combustion. On the other hand, the oxygen concentration may be reduced through combustion processes and the concentration of inert gases (nitrogen and carbon dioxide) increased enough to render the atmosphere within the sealed area non-explosive. Before an area is unsealed, it is extremely important to know if the sealed atmosphere contains Flammable gases in proportions that might form explosive mixtures when air is introduced. If an explosive mixture forms and the fire is rekindled, a gas explosion will result. Various experimental methods may be used to determine the explosibility of a particular mine atmosphere; however, these methods usually are impracticable in the field.

Jan 1, 1959

By J. G. Groetsch

Municipal solid waste (MSW) contains about 8 pct ferrous metallics which are typically recovered by magnetic separators at municipal resource recovery facilities. At present, only about 182,500 ton/yr of MSW magnetics are being processed for remelting out of the -11 MMton/yr discarded. The Sn in MSW magnetics makes this material difficult to recycle to the steel industry. An electrolytic method using stannous fluoborate-fluoboric acid for removing Sn was evaluated. Optimum concentrations of Sn in the electrolyte and the effects of impurities such as Al, Cu, Fe, and Pb on Sn recovery from the electrolyte were evaluated. Operating parameters were 60 to 65 g/L fluoboric acid and 20 to 30 g/L Sn using stainless steel electrodes at a current density of 60 A/ft2. Tests were run with postconsumer scrap4 and MSW magnetics. Good results were obtained with MSW magnetics, after pretreatment by reshredding, magnetic separation, and air classification. The final Sn content of the MSW magnetics scrap was reduced from 0.18 to 0.017 wt pct. Heat and solvent treatments of MSW magnetics to remove coatings did not significantly improve Sn removal beyond that obtained with material that had only been mechanically pretreated.

Jan 1, 1984

By Isaac A. Zlochower

This paper presents data on the limiting (minimum) oxygen concentration (LOC), in the presence of added N2, of methane (CH4), propane (C3H8), ethylene (C2H4), carbon monoxide (CO), and hydrogen (H2), and some of their binary mixtures. It also addresses the issue of the flammable concentration (flammability) limits of these pure gases in air. The study is based on spark ignited explosions in large, spherical laboratory vessels (120-L and 20-L) using a 7% pressure-rise criterion for explosion propagation. The results of the study are compared with the older values which used long flammability tubes with a diameter >5 cm together with visual evidence of substantial upward propagation. They are also compared to results reported recently using a 12-L spherical flask with a visual flame propagation criterion. Finally, they are compared to results reported in Europe using more modest flammability criteria and smaller chambers. The findings reported here show excellent agreement between the 120-L and 12-L results, good agreement with the 20-L results, and reasonable agreement with the earlier flammability tube values for the lower flammability limits. They disagree, however, with the more conservative European values. These results and those from the 12-L experiments also feature lower LOCs than are given by traditional flammability tubes. A model for the LOCs of such fuel mixtures based on the Le Chatelier mixture rule for lower flammable limits is seen to reasonably fit the observed results on binary mixtures and can accommodate more complex mixtures as well. One such set of ternary mixtures containing CH4 and 1:1 CO:H2 is well fitted by the model.

Jan 1, 2009

By Gregory Krohn

This report investigates the effects of adding a layer of extra padding to the palm area of leather gloves typically worn by low seam coal miners. The first study showed that added glove padding provides more potential protection but does not affect manual dexterity. The second study, in a simulated low seam coal mine, showed no significant differences using padded and non-padded gloves in crawling, shoveling, timbering, and cart pushing task completion times. In general, subjects preferred the padded gloves although they expressed some complaints about awkardness and loss of sensitivity. Recommendations are given for the design of padded gloves that will provide comfort, protection, and maximum hand sensitivity for miners.

Jan 1, 1980

By A. Adams

The Bureau of Mines determined the composition of the vapors liberated during thermal decomposition of aluminium nitrate nonahydrate. Small samples were heated from room temperature to 5500 C with initial heating rates from 500 to 2000 C/min. Gases were rapidly swept away from the heated chamber with Ar and subjected to immediate analysis in order to minimize reaction between the components. In addition to H20, four N-containing compounds were identified: HN03, N02, NO, and N20. Nz could not be determined in the presence of the nitrogen oxides, and at-tempted separation from the oxides led to the formation of more nitrogen. Relative amounts of each component were found to vary over a period of time; however, total amounts measured with different heating rates were reasonably constant and were typically as follows: 84.2 pct HN03, 7.1 pct N02, 4.3 pct NO, and 4.2 pct N20. HN03 and NO were determined from chemical reactions with a permanganate solution, N20 was measured with a mass spectrometer, and NO2 was measured with a spectro-photometer. Details of the methods used are described. Since NO2 and NO can readily be converted to HN03, about 96 pct of the N from the decomposition can be recovered as HN03

Jan 1, 1987

By R. L. Hopkins

Some typical thiacyclopentanes and thiacyclohexanes were synthesized to provide reference compounds needed for the identification of sulfur compounds in crude oils. Two general methods of synthesis were employed: (1) cleavage of 2-alkyltetrahydropyrans with hydrogen bromide followed by the reaction of the resulting dibromoalkanes with sodium sulfide and (2) the catlyzed reaction of cyclic ethers or 1)4-or 1)5-alkanediols with hydrogen sulfide. Both methods produced mixtures of 2-alkylthiacyclopentanes and 2-alkylthiacyclohexanes with 2-alkyltetrahydropyran as the starting material. The structures of the reaction products were established by analysis for sulfur; desulfurization; gas-liquid chromatography (GLC); mass, infrared, and nuclear magnetic resonance (NMR) spectra; and an alternate synthesis. The synthesis of the cyclic sulfides contributed substantially to the identification of 10 members of this class of sulfur compounds in crude oil.

Jan 1, 1967

By P. R. Bremner

The United States is more than 90 pct dependent on imported bauxite a source for aluminum, but it has vast nonbauxitic aluminum resources, such as kaolinite, anorthosite, alunite, etc. As part of a program to devise processes for treating these resources, the Bureau of Mines investigated a bench-scale leaching process using hydrochloric acid (HC1) and fluoride to extract aluminum from Wyoming anorthosite. HC1 and fluoride-to-aluminum (F/Al) mole ratios were studied with respect to aluminum extraction for single-stage, cocurrent, and countercurrent leaching modes. Using 95 pct stoichiometric HC1 and a F/Al mole ratio of 0.27, 90 pct of the aluminum was extracted by countercurrent leaching. Single-stage leaching with the same amount of acid and fluoride extracted 48 pct of the aluminum. Three fluoride sources, CaF2, Na2SiF6, and H2SiF6, were used and gave similar results on aluminum extractions.

Jan 1, 1982

In this U.S. Bureau of Mines report, proposed narrow-vein and longwall mining concepts using drill-split technology (described in part 1 of this series) and in situ liner concepts (described in part 2 of the series) are combined and applied conceptually to environmental problems. Proposed applications deal with (1) acid mine drainage (AMD), (2) solid waste disposal, (3) site remediation, and (4) pollution prevention through innovative industrial design. For control of AMD from abandoned hillside mine workings, it is proposed that source veins be re-mined, processed for residual values, then backfilled using an impermeable compound backfill mix. For solid waste disposal, "vertical landfills" are proposed, consisting of trash-backfilled underground rock quarries. Vertical landfill activities take place in in situ lined containments that geohydrologically isolate the mining-backfilling activities. Site remediation through the creation of in situ underliners, for the capture of toxic leachates, and pollution prevention through the underground storage of toxic, flammable, and explosive materials in in situ containments, are proposed.

Jan 1, 1995

By R. T. Johansen

The wettability of petroleum reservoir materials by water and crude oil has been recognized as an important factor in determining waterflood behavior. The problem of simulating and studying reservoir conditions and characteristics, to produce laboratory results congruous with field experience, has been examined by many methods. (1, 2, 3, 4).4/ The most generally accepted approach to this problem is determining wettability of the porous medium by imbibition methods; or, after solvent extraction, predetermining the wettability of the samples by coating the surface of the medium to render it preferentially oil-or water-wet (3, 5). The emphasis of wettability studies has been placed on the characteristics of the reservoir materials with little consideration being given to the fluids themselves. Therefore, the wetting tendencies of crude oils have been investigated by a recently developed method (6). Imbibition and the more general phenomena of capillary pressure are the most direct ways to measure wettability. The simplest type of capillary pressure observations involves the use of an interfacial-tension capillarimeter, which does not produce as separate values either interfacial tension or contact angle. Actually, these quantities do not have independent significance in reservoir engineering, and the property of wettability they are intended to evaluate is given, immediately by capillarimetric measurements.

Jan 1, 1961

Reduce the time, complexity and expense of dissolving metal and mineral samples in solution in preparation for chemical analysis. Approach In earlier research, the Bureau of Mines developed a rapid and inexpensive method for the dissolution of mineral and metal samples in plastic pressure bottles heated in a boiling water bath. Using this technique, samples could be prepared for chemical analysis in less than one hour compared with several hours by traditional dissolution methods (see Technology News No. 85, December 1980 for further details). By heating in a microwave oven, sample dissolution time can be reduced to approximately 5 minutes.

Jan 1, 1983

By John S. Dunning

This is one of a. series of papers being prepared for and published by the United States Bureau of Mines, describing raining and milling methods at crushed-stone plants throughout the United States. These papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent operating expenditures only and not total production costs. It is recognized that publication of total production costs might in man; instances cause embarrassment to individual producers as well as to the industry as a whole. However, operating costs are essential to technical discussion and study of the methods employed. The attention of the reader is specifically called to this differentiation in order that the scope of the cost tabulations shall not be misunderstood. This paper deals with the quarrying and crushing methods used at the Avon Mountain trap-rock quarry of the Atlas Sand, Gravel & Stone Co., in West Hartford, Conn.

Jan 1, 1936

By J. C. Hartley

The most important single operation in mining is the ventilation of underground areas in a manner conducive to the health and safety of employees. Adequate volumes of pure air must be supplied at the working faces, along the haulageways, and wherever men work, so as to dilute and carry away the methane liberated from the coal and adjoining strata, noxious gases evolved by the use of explosives, and the carbon dioxide exhaled by men and formed by oxidation of carbonaceous material, as well as any other gases, and also dusts which may be found in mine workings. A sufficient quantity of air must also sweep abandoned or worked-out areas of the mine to prevent the accumulation of gases, where sealing methods are not utilized to isolate old workings. Air, in a quantity adequate to meet the needs of the particular mine to which it is applied, is necessary, and supplying it can be made very expensive through failure to observe good practices in its direction and apportionment." Leaky stoppings, doors, and overcasts rob the working faces of air and add to the ventilating cost by burdening the fans with fugitive air,

Jan 1, 1944