Search Documents

By W. P. Yant

The widespread use of toluene in industry and the importance of air analysis in industrial-hygiene surveys have created a need for a simple and accurate method for determining toluene vapor in air. Most of the methods used to determine small quantities of toluene in liquid or vapor form are based on the measurement of its physical properties. Methods based on fractional distillation, determination of specific gravity, use of the interferometer, use of the spectrograph, and sorption on solid sorbents with subsequent determination of gain in weight have been employed. Distillation and specific-gravity methods are not applicable to the small quantities of toluene found in the air, and use of the interferometer, spectrograph, and sorption methods either are not specific for toluene in the presence of other volatile substances or require expensive equipment.

Jan 1, 1936

By R. M. Becker

As part of the Bureau of Mines program for examining the Nation's iron and titanium resources, magnetic, gravity, and geologic surveys were made to permit an estimate of the extent and magnitude of the Iron Mountain, Colorado, titaniferous magnetite deposit. Gabbro is the dominant rock type of the area. Within the gabbro are lenses of titaniferous magnetite, 5 to 25 feet wide and as much as several hundred feet long. These lenses comprise a zone which has scattered occurrences of magnetite for 2,200 feet. To the west, the gabbro grades into a strip of pyroxenite that in turn borders a large monzonite mass. A wedgelike broadening of the pyroxenite with depth accompanied by little or no increase in the titaniferous magnetite is considered a reasonable interpretation of the field data. The iron deposits appear to be limited and discontinuous.

Jan 1, 1961

By R. K. Koch

The Bureau of Mines developed a zircon sand molding process for static casting of small titanium or zirconium shapes. Castings with unfinished weights up to 3.5 kg (7.7 lb) were produced in an inductoslag furnace and castings up to 7 kg (15.4 lb) were poured in a consumable electrode skull-casting furnace. Molds and cores were made by ram-molding, foundry-grade zircon sand (AFS gfn 93 to 95) bonded by grade D waterglass and tempered with water. Molds and cores were cured either at 250° C (482° F) or 900° C (1,652° F). Castings from the higher temperature molds broke cleanly from the sand while the lower temperature molds produced castings that had to be cleaned by sand-blasting. However, low-temperature cured molds and cores have a number of advantages as follows: (1) A faster, less energy-consuming curing cycle is used; (2) expended cores are water soluble which greatly facilitates core removal; and (3) enough of the binder in crushed expended molds is reactivated by temper water so that the molding mix can be reused five times without any fresh binder additions and up to twenty times without exceeding a total cumulative binder addition of 52 ml/kg dry sand. Crushed used molds that had been cured at 900° C had no detectable binding strength when mixed only with temper water. A large number of oxide and silicate mold washes were studied for improved casting integrity. The most effective wash found for zirconium or titanium casting was monoclinic zirconia (325 mesh).

Jan 1, 1977

By Paul Zinner

An exhaustive program of geologic studies and mapping has been conducted by the Geological Survey in the Iron River district of Michigan since May 1943. Means of contributing to the success of these studies were sought by the Bureau of Mines, and eventually a program involving geophysical studies and core-drilling was undertaken in the area. All of the work was done either to develop data that would contribute directly to geologic studies or to investigate geophysical methods that might be used as a primary means for the discovery of minable iron ore.

Jan 1, 1949

By L. R. Burdick

This paper presents a review of published investigation dealing with the importance of sulfur compounds in the deterioration of materials or providing some basis for estimating the extent of loss shareable to such air pollution. Materials included are cement, stone, metals, paint, leather, paper, sand cloth. The investigations may be divided into two classes, one of the laboratory type in which the sulfur content and the humidity of the air were controlled and the other dealing with the exposure of materials to atmospheres not under control. The first type of work has shown that cement is subject to deterioration by the action of sulfur dioxide gas. The experiments with stone indicate that although limestone takes up sulfur dioxide, from the air, moist sulfur dioxide-air mixtures alone cannot be used for establishing- the comparative weathering- qualities of the different types of stone by accelerated test methods. Laboratory tests indicate that sulfur compounds in the air accelerate the corrosion of iron, steel, zinc, copper, and nickel at normal air temperatures and at certain relative humidities. It has also been indicated that certain types of paint are, affected by high sulfur dioxide concentrations, and that paper is attacked by sulfur dioxide in the atmosphere. The investigations of the second type show the amount or variation of corrosion in different localities and under different types of exposure. The investigations (10) (18)4/ during which sulfur determinations were made indicate that sulfur dioxide is a main controlling factor in the corrosion of iron and steel but according to Quick (18) may not be for some nonferrous metals. In general, the laboratory tests do not Jive definite data on the loss due to sulfur compounds at the concentrations normally found in the air. The data from atmospheric exposures are not complete from the standpoint of the exact effect of the sulfur compounds. Damage to materials so exposed is affected by factors such as other chemical contaminants, humidity, rainfall, solid deposits, and sunlight. A simple scheme has been devised in Great Britain which is considered to provide a measure of the attack of sulfur compound, on building materials (1). Small cylinders coated

Jan 1, 1939

By K. Robert Dorman

This Bureau of Mines report describes laboratory and field experimentation in building mine ventilation stoppings, air-door frames, and fan bulkheads with a civil construction technique. Shotcrete is applied to a free-standing, three-dimensional wire-truss panel, which is easily cut and rapidly erected. In mines where shotcrete equipment is available, this technique should be faster and cheaper than conventional block-and-mortar or monolithic concrete construction.

Jan 1, 1980

By L. G. Trudell, J. W. Smith, K. E. Stanfield

Oil- yield data are presented for 40 sets of core samples and 83 sets of drill cuttings collected in 1952-62 from drilling operations in the Uinta basin of eastern Utah . This accumulated information on the location , extent , and richness of oil shales of the Green River formation is used to appraise the deposits as a source of oil and related products . Core samples used in the study were obtained specifically for evaluating oil shale , and they were satisfactory for this purpose , except they did not completely penetrate the formation . The drill- cutting samples were inferior to the core samples and yielded more erratic results . Consequently, oil yields based on cuttings should be regarded as indicative , rather than definite , until substantiated by other means . In general , the oil- yield data indicate Green River oil shale in Uinta basin is not as thick or as uniform as that in the Piceance Creek basin of western Colorado . However , it is an important potential source of oil . Estimates that beds 15 feet or more thick that average 25 gallons of oil per ton represent at least 120 billion barrels of oil in place are supported by the recent oil- yield data .

Jan 1, 1964

By P. C. Good

High-purity chromium was prepared in massive form by the electrolysis of chromium trioxide solution at high temperatures. The metal thus obtained, containing 50 to 150 p.p.m. of oxygen, 20 p.p.m. of nitrogen, and traces of metallic impurities, could be hot-worked to rod and sheet and drawn to wire ductile at room temperatures. Optimum concentrations and operating conditions were established for the deposition of chromium from chromic acid baths containing sulfate, fluoride, and silicofluoride ions. Current efficiencies of 13 percent were attained with baths containing sulfate ion, and efficiencies of 40 to 44 percent with baths containing fluoride and silicofluoride ions. Cation exchange resins were used for removing metallic impurities from chromic acid solutions containing sulfate ion; solutions containing fluoride and silicofluoride ions were purified by recrystallization.

Jan 1, 1960

By W. J. Fene

The lowest number of fatalities from coal-mine explosions in the United States in any year since records have been kept was the total of 8 in 1949 and again in 1950. Even incomplete records as far back as 1870 reveal a larger annual loss of life from explosions. From 1890 to 1948 the lowest annual loss was 32 in 1946. A smaller total of 15 fatalities was reported in 1952. Figure 1 shows the total yearly loss of life from explosions in all coal mines since 1880. Those in anthracite mines alone are shown by the shaded area. The erratic variation of the chart line shows the difficulties that have confronted the industry in the struggle to control and eliminate mine explosions. Potential hazards have existed in marry mines without realization that only a small change in conditions could initiate a disaster. Many disasters causing great loss of life occurred in mines that had been regularly operated without incident for long periods. Although the number of coal-mine explosions causing great lose of life has been kept down in recent years, the exceptions still make the record anything but satis¬factory. There have been almost no widespread explosions for several years, but in a few instances many lives were lost from afterdamp. Although the violence and spread of mine explosions may be controlled, the loss of life may be heavy if many of the men happen to be in the path of the smoke and gases. For these reasons, the strictest controls must be maintained to eliminate all factors that might combine to cause even a small ignition of gas or dust.

Jan 1, 1953

By A. W. Fahrenwald

Coarse sand flotation, both alone and in conjunction with gravity concentration, is a subject of research at the U. S. Bureau of Mines Field Office, Moscow, Idaho. One of the most important results of this work which is being carried out in cooperation with the University of Idaho, has been the development of a concentration process embodying flotation, classification, and tabling, in the order named. The flow sheet of the process is given in Figure 1. The type of feed desired for this process is coarser than is common in present "all flotation" practice, and is about the size of table feed.

Jan 1, 1929

By O. C. Blade

"INTRODUCTION This report on the properties of aviation gasolines and aviation jet fuels produced in the United States during 1952 was mode under a co¬operative agreement between the American Petroleum Institute and the Bureau of Mines of the United States Department of the Interior.Analytical data are presented for 94 samples of aviation gasoline which include for the first time in this series of reports, data on five samples of grade 108/135 aviation fuel. Data also are given for 34 samples of aviation jet fuel. The analyses were made on samples typical of the manufacturers' production in their laboratories and the results sub¬mitted to the Bureau of Mines for compilation. The products of 20 manufacturers of aviation gasolines and of 16 producers of aviation jet fuels are represented.SUMMARYA comparison of certain properties of the commercial aviation gasolines produced in the United States during 1950, 1951, and 1952 is presented in table 1, the 1952 data being average values from tables 3 through 7 of the present report. Trends in certain characteristics of these fuels may be seen in figures 1 through 5 which also indicate the minimum and maximum values. As may be observed, the properties of commercial aviation gasolines have not varied greatly during recent years. A list of aviation-fuel survey reports published by the Bureau of Mines is given on page 7.Table 2 presents a summary of data from table 8 and compares properties of aviation jet fuels of 1952 with summarized data on jet fuels of October 1951."

May 1, 1953

By G. W. Birge

Fifteen coal samples, representing the Winifrede, Chilton, Alma, No. 2 Gas, Powellton, Eagle, Douglas, Sewell, Beckley, Pocahontas No.4, and Pocahontas No.3 beds in Wyoming County, and five samples, representing the Fire Creek, Pocahontas No.6, and Pocahontas No.3 beds in Mercer County, W. Va., were carbonized at 9000 C by the Bureau of Mines-American Gas Association (BM-AGA) method, and yields of products and physical properties of cokes were determined. Expansion characteristics of the majority of samples were determined in the Bureau of Mines sole-heated oven. Chemical analyses and agglutinating values were determined for all coals. The coals were mostly strongly coking and low in ash and sulfur content. Dry, mineral-matter-free fixed-carbon content of the Wyoming County coals ranged from 63.0 to 83.4 percent. The Mercer County samples were all low volatile in rank. Yields of carbonization products were generally in accord with yields from similar rank coals of the Appalachian region. Because of their expanding tendencies, most of the medium-and low-volatile coals would require blending with lower rank coal for normal coke production.

Jan 1, 1965

By THOMAS SOULE, R. I. C. Manning

The Phelps Dodge Corporation considers safety a major operating problem , both from the humanitarian standpoint , for this company has a real interest in the welfare of its employees , and from the economic standpoint , for it has found the safe way to be the most economical . In turn , a feeling among employees that the company really has their interests at heart has a wonderful psychological effect . It is bound to bring forth more and better work and to attract and keep workmen of the better class . There is keen competition between the various branches of this corporation for a trophy that is awarded each year to the one having the best accident record . This trophy was won by the Nacożari branch of the Moctezuma Copper Co. in Mexico in 1926 and 1927 , and the Morenci branch won the trophy in 1928 and 1929 .

Oct 1, 1930

As part of its regular program to provide timely information on domestic mineral commodities, the Bureau of Mines conducted an engineering appraisal of more than 1,300 lode and placer gold deposits in the United States to deter-mine their gold production potential. While these deposits were estimated to contain over 400 million ounces of gold, only 9 million ounces, or slightly more than 2 percent, was found to be producible at $35 per ounce under prevailing mining and metallurgical technologies. The study revealed that any significant increase in available gold in the United States is most likely to come from the discovery of new sources, intensive exploration and development of the more promising known mineralized areas, and development of new or improved mining and metallurgical techniques.

Jan 1, 1967

By Michael S. Miller

In 1985, at the request of the Bureau of Land Management, the Bureau of Mines studied a 50,57U-acre portion of the 90,345-acre Twin Peaks Wilderness Study Area (CA-020-619A) in order to evaluate its identified resources. The area studied is located about 45 miles northeast of Susanville, CA, in Lassen County, CA, and Washoe County, NV. The area is underlain by Tertiary volcanic, volcaniclastic, and intrusive rocks. Quaternary stream, lake, and landslide deposits overlie the older rock. There are no mines or mining claims in the study area. One mineral resource, pozzolan, was identified. Mining claims, inactive in 1985, have been staked adjacent to or near the northwest corner of, and also southeast of, the study area. Examination and sampling of 17 mineralized sites, delineated mostly by prior geochemical surveys, showed at least 30 million tons of subeconomic pozzolan resources and small or low-grade occurrences of gold, silver, copper, lead, zinc, nickel, molybdenum, zeolites and clay.

Jan 1, 1986

By Robert W. Smith

In a certain application2/ it was necessary to compute the beta function B(p, q) for a certain set of values p and q. Since t he set of p and q values was much mo re finely spaced than those in any published tables, the authors decided to make their results available in this report. In connection with this application the functionB(p, q) was needed at various points in the p, q plane at intervals of 0.05, 0.05<p = q< 10.00. Fletcher, Miller, and Rosenhead2/ state that the only tables available in the desired range are those of Rearson.4/ However, the interval used by Pearson was not small enough for the present application. For this reason it was decided to calculate B(p, q) for p = q =0.05 (0.05) 10. 00.2/ This table is published because of the fundamental importance in mathematical analysis of the complete beta function.

Jan 1, 1953

By Frank S. Wartman

[ ]

Jan 1, 1927

By A. C. Johnson, McHenry Mosier

The Bureau of Mines has adapted its activities to needs of national defense and to conditions brought about by the war program . Its work is now oriented solely to war problems . After studying about 1,600 deposits of war minerals , exploration projects have been undertaken on 96 of the most promising , of which 56 have proved successful . These have indicated that 56 million tons of ore of commercial or near -commercial grade can be utilized to meet war requirements . Included in this amount are 1 million tons of tungsten ore ; 4 million tons of chromite ore, 10 million tons of manganese ore , 2 million tons of antimony ore , 1 million tons of mercury cre , and 28 million tons of iron ore . Work done in connection with exploration projects included 172,000 feet of surface trenching , 210,000 feet of drilling , and 21,000 feet of shaft sinking . Nearly 100,000 samples were taken, on which 500,000 analyses were made . Extensive metallurgical tests were made on ore from many of these deposits , both in the laboratory and in pilot plants , in connection with research to develop metallurgical processes for their treatment .

Jan 1, 1943

By G. W. Jones

[A survey of the Ii terature reJ.l....ting to iE;li tion temperatures of acet-ylene-air and acetylene-oxygen mixtures reveals rather &apos;.&apos;fide disagreement in the reported results. In SO!&apos;:1e instances the i ition temperatures of acet?-ylene-air mixtures were reported to be lower than those of acetylene-oTjgan mixtlU&apos;es, which is contrary to experience &apos;tri th other combustibles. &apos;:10 clea.r up some of t!le reported discrepancies, the authorn have icvestigated the igni tion temperatures of acetylene both in air anri oxygen, and their results are presented in this report.]

Jan 1, 1941

By Robert L. Rough, William E. Eckard

Laboratory data obtained from a Bureau of Mines rotary air core of a well near Sugar Grove , Warren County , Pa . , were instrumental in initiating hydraulic fracturing in the area to stimulate oil recovery from Glade sand oil reservoirs . This report outlines the general geology , lease development , reservoir- rock characteristics , and oil - production history of Glade and Clarendon sand reservoirs in Warren County . The methods of well completion for single- stage and multiple- stage hydraulic fracturing of old and new wells are discussed , and a range of hydraulic fracture treatment data from 29 Glade sand and 10 Clarendon sand wells is presented . A composite decline curve representing oil - production data from six wells shows probable results of hydraulic fracturing . Average cumulative oil production during the first 100 days after hydraulic fracturing with a sand - carrying liquid is compared with production after conventional shooting with liquid nitroglycerin .

Jan 1, 1964