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By Frank van der Meer, Lea Quincke

"High Pressure Grinding is applied to achieve size reduction of the particles by inter-particle breakage and to generate micro-cracks in the product particles as a contributing factor in e.g. leaching or mineral liberation. As alternative to classification, a closed circuit operation for HPGR can be established by product recycling, where a proportion of the coarser edge material and parts of the center material are split-off to be recirculated to achieve a finer final (center) discharge product for subsequent processing steps as ball mill grinding or beneficiation. As a result of the product recycling, the content of fines in the feed material increases and may affect the grinding efficiency in terms of production of fines and the generation of micro-cracks in the particles. In the scope of this paper, the effects of the proportion of fines in HPGR feed on grinding efficiency and micro-crack generation were evaluated. Grinding tests were executed with different feed size distributions, from a fines-void situation (truncated feed) to a fines-abundant situation (high product recycle). The evaluation of grinding efficiency and generation of micro-cracks was done by particle size analysis, Bond Work Index tests, impact tests on HPGR feed and products, and X-ray computed tomography of single product particles. This publication summarizes the main aspects of the outcome of these investigations."

Jan 1, 2014

By Lei Zhang, Xianjun Lu1, Minjie Lian, Liyang Zheng

In order to investigate rheological behaviour of fine tailings backfill pastes, the fine iron ore tailings (size fraction of -0.074mm accounts for 70%) from Fuquan Mining Co., Ltd. of Sinosteel Corporation (Shandong, China) was investigated. The rheological parameters such as slump, viscosity and yield stress of the tailings pastes under different densities were measured in detail, and the effect of paste density on the rheological property and the relationships of different rheological parameters of the pastes were also discussed. According to the results, the rheological behaviour is in accordance with the pseudoplastic fluid in a wide range of paste densities (solid content, w/w) of 65% to 80% and the pastes turn to be Bingham fluids at higher shearing rates. Along with the increase of paste density, the slump drops gradually and the viscosity and shear stress increase gradually. However, the variation extent of the rheological parameters varies at different density ranges. According to the variation pattern of the rheological parameters at different paste densities, the flow ability of the pastes can be classified into three zones. The high fluidity zone was observed at the density range of 65%-69% where the rheological parameters vary slightly along with the paste density, the moderate fluidity zone was observed at the density range of 70%-76% where the rheological parameters vary significantly along with the paste density, and the low fluidity zone was observed at the density range of more than 76% where the rheological parameters vary sharply along with the paste density and the critical density for this sudden variation is about 76%. Furthermore, linear correlations of slump/viscosity and slump/yield stress were observed. It is possible to predict the viscosity and yield stress of the pastes based on the slump measurements.

Jan 1, 2014

By Katsunori Okaya, Toshio Inoue

"Movement of mill charge in the centrifugal mill is essentially dissimilar from that in the vibration mill with circular path despite the apparently similar mode in the motion of mill body. This dissimilarity is the reason for the substantial advantage regarding the comminution intensity of the centrifugal mill over the conventional vibration mill accounting approximately to one order of magnitude.Bradley et al. (1983) developed a math model regarding the mill charge as a lump. This model is presented in a simple equation with which motion of the mill charge can be predicted in terms of the parameters describing the specification and the operation of the centrifugal mill. This equation can be used to explain the power draft of the mill as well as the stability of mill operation. More recently, on the other hand, a numerical simulation technology called discrete element method (DEM) has become a vital vehicle for estimating the motion of the grinding media in the mill. The authors developed a mill simulator called ‘Mill Solver’. Mill Solver is designed to simulate various types of mills including centrifugal and vibration mills. The principle of this simulator is to calculate individual kinetic events of interaction of balls in the mill in a minute time interval, hence the mill performance can be constructed for estimation."

Jan 1, 2003

By Cristian Melipichun, Leopoldo Gutierrez

The effect of the presence of fine particles of kaolinite and montmorillonite on the induction time for attachment of bubbles to particles of a copper concentrate rich in chalcopyrite was evaluated in this study. The results obtained from induction time measurements were correlated with data of concentrate recovery achieved from micro-flotation experiments. The effect of the presence of fine clays on the stability of air-water foams was also studied through measurements of the foam volume generated in a glass column under different conditions of air flowrate and MIBC concentrations. The experimental results showed that induction time values increased under the presence of fine clays. These data agreed with results obtained from micro-flotation experiments that showed that copper concentrate recovery decreased when clay particles were added. Although a complete explanation for these results is not available, the fact that experimental observations indicated that fine clay particles tend to adsorb on gas bubbles, suggests that the interactions between fine phyllosilicate particles and air bubbles have to be taken into account when studying the effect of clays on froth flotation. Foamability tests showed that the presence of fine clay particles increased the foam volumes only at high additions of clays and low dosages of MIBC. The results obtained at higher dosages of MIBC showed that the foam volumes decreased with the addition of clays under all the experimental conditions tested.

Jan 1, 2014

By H. Lieberwirth, M. Hesse

"Selective comminution (SC) is beneficial for the treatment of primary raw materials, especially if it is utilized in the pre-concentration process. Pre-concentration processes are applied in mineral processing to relieve subsequent processes and to achieve a higher efficiency. SC is also a promising method for the treatment of low-grade ores and waste dumps. With SC, various components can be separated such as valuable minerals from waste, ore from wall rock and different ore varieties within a deposit. SC is a property of a comminution system and leads either to a preferred crack propagation in one component (called preferential breakage) or to a preferred crack propagation along the grain boundaries (called interfacial breakage). SC results from different comminution behavior of various components in the feed material. For mechanical comminution, the preferential breakage seems to be the most important case of SC. Hereby SC generates only the difference in the particle size which can finally be used as a sorting parameter. A sorting process which uses SC depends on three parts: the feed material, the comminution machine and the separation machine. The feed material defines the potential for SC. Differences in properties like strength, toughness and density which are related to comminution are often used. The comminution machine has to exploit this potential. The extent of the exploitation can be influenced by the machine design, material and operational parameters. After SC, the various components are still combined in the product. So ultimately, a separation machine is needed. At preferential breakage, a simple screening machine can be used. The basics about SC will be presented at first. This contains relationships between material properties, the kind of loading in the comminution machine and the SC effect. These basics can be used for example to exploit a potential to SC for a pre-concentration step or to avoid the SC for a higher efficiency of subsequent processes. Based on recent investigations with impact load, the influence of the important parameters compressive strength, density, particle size and impact velocity to the SC will be shown, using examples of lead-zinc ore comminution and fluorspar processing."

Jan 1, 2018

By Vincent C. Smith, Agit Singh, Daniel de V. van der Spuy, Bernard Muller

"Process control in the minerals industry is made difficult by factors such as the multivariable nature of the processes, noise, many disturbances, the changing nature of the processes, nonlinearities, process constraints, slow responses and large deadtimes. A good example of such a process is a milling circuit, where all these problems are experienced. Since model predictive control (MPC) effectively handles most of these difficulties, Mintek decided to develop, customise and test an MPC controller for milling control.Conventional MPC uses a dynamic model of the plant to calculate the future (predicted) plant outputs based on the movements of the manipulated variables in the past. The future moves of the manipulated variables can then be calculated using an optimisation algorithm that will minimise the difference between the setpoints and the predicted outputs. The least squares optimisation method is the quickest, but it does not cater for process constraints. Constraints can, however, be handled explicitly by using a quadratic programming optimisation method. This method ensures that the variables stay within the constraints at all times, but the calculation procedure is much more computationally intensive.• modifying MPC for the Minerals Processing IndustryIt was found that in order to obtain good, robust control using MPC in the minerals processing industry, the conventional MPC algorithm had to be adapted. The MPC controller was first tested on an extensive milling simulator, which was specifically developed for that purpose. Problem areas were identified and the MPC controller was specially adapted to accommodate for these difficulties. Some of the adaptations to the conventional MPC algorithm and special features added were as follows:Since milling plants contain many integrating processes (e.g. sumps), and integrating errors can cause offsets and poor control, it was essential that integrators be handled explicitly. This problem was solved by adapting the algorithm and also using an integrating error portion to compensate for integrating errors.Constraints on the inputs and outputs adversely affected the control. The controller using simple least squares optimisation was tuned with the constraints in place, while the maximum expected setpoint changes were made. This ensured that the process would be able to handle most setpoint changes up to these expected values without violating the constraints. A later improvement on this method was the incorporation of a quadratic programming algorithm to perform the optimisation. This method handles limits explicitly and was shown to perform better than the least squares methods (at the expense of a much higher computational cost)"

Jan 1, 2003

By Érica Linhares, Anderson Silveira Lopes, Aline Costa

In the production units of ferromanganese alloys wastewater are generated. They mainly arise from gutters of drainage water from warehouse of raw material (manganese ore, reducing agents and other), product and slag. This wastewater, in general, may contain particles that will suffer difficulty to naturally decant, giving the water turbidity and color characteristics. Thus, this study aims to characterize the effluent, the treated water and the sludge from the sedimentation tank from the one main Brazilian plant. The investigated characteristics were: turbidity, total solids (TS), suspended solids (SS), dissolved solids (DS), pH, Eh, COD (chemical oxygen demand), residue classification and chemical analysis by ICP - OES. The turbidity before treatment was 417 NTU and after passing through the tank, 44 NTU, a figure slightly higher than the emission standards for Class 1 regulated by the Brazilian environmental legislation in force. The values for TS, SS and DS of the effluent were 225, 114.3 and 110 mg/L, respectively. For the treated water the values were 93, 48.3 and 45 mg/L for TS, SS and DS, respectively. The sedimentation process was able to reduce by 21 % of the COD. In the test of loss on ignition (LOI) from the tank bottom sludge were observed losses of 29.35 %, while the volatile analysis found 20.70 % of volatiles in the sample. It was determined that the concentrations of Al, Fe, Mn and S are, respectively, 0.1875 mg.L-1, 0.3071 mg.L-1, 0,789 mg l-1 and 0.00828 mg.L-1, values above the maximum allowed by law. Based on the analysis of X-ray diffraction, the identified minerals in the sludge were quartz, muscovite, kaolinite, calcite and albite.

Jan 1, 2014

By Joseph Kelly, Christopher Kelsey

This revolutionary super-fine crusher has the unique capacity to generate fine and ultra-fine products from single stage reductions of coarse or fine mineral feeds. The crusher consists of a rotating compression chamber and an internal gyrating mandrel. The axis of rotation of the shell is displaced relative to the axis of the vertically mounted mandrel. The inner surface of the compression chamber is machined as double cone frustums at an angle equal to the displacement angle. Crusher feed is accelerated into a compacted particle bed, which lines the inside of the compression chamber. The depth of the compacted bed progressively increases until the mandrel is engaged. The mandrel is then free to rotate with the compression chamber. Continued feeding increases power draw and triggers the counter rotating mandrel gyration drive. The gyrating mandrel delivers multiple compressions at high pressure to the rotating particle bed. High concentrations of energy are harnessed within a small active volume over short retention times. The combination of extraordinarily high power intensity and extreme compressive force results in primary compressive fracture and induced secondary tensile failure. The axially displaced rotation of the compression chamber effectively distributes the breakage forces throughout the particle bed. This paper covers open circuit, pilot trials on magnetite, perlite, garnet, marble and a copper/pyrite concentrate. Particular emphasis is placed on the extraordinary results achieved with trials on zircon and highly refractory fly ash. The extreme duties were deliberately chosen to demonstrate the crusher’s application scope and potential to impact capital operating and maintenance costs as the technology matures. Super-fine crushing, once considered impracticable has the potential to offer compelling options for the generation of ultra-fine products.

Jan 1, 2014

By Janusz S. Laskowski

It is customary to assume that wettability plays an important role in coal flotation, and it is well established that while hydrophobic metallurgical coals float easily, low-rank less hydrophobic coals are difficult to float. However, coal surface wettability plays a dominant role in many coal preparation unit operations. As it will be discussed in this paper, it affects coal-dewatering, selection of flocculants, fine coal pelletization and briquetting, and even coal handleability.

Sep 1, 2012

By Guanzhou Qui

The utilization status of copper ore resource, the application and development of biohydrometallurgy technology in the world was reviewed. Furthermore, according to the analysis of the characterization of Zambia?s copper resource, biohydrometallurgy technology was shown to be a good way to explore and utilize the enormous low grade copper resource, such as ore tailings and low grade copper ore in this country. Through the cooperation of CSU, China and MMMD, Zambia, ?CNMC-CSU Demonstration Base of Biohydrometallurgy Technology in Zambia? was launched and several biohydrometallurgy plants are being constructed, that indicates the biohdyrometallurgy technology would be applied soon in Zambia and even in the whole Africa. Biohydrometallurgy technology stands as an efficient alternative to the traditional pyrometallurgy process can be the key to unlock mineral resources value. Keywords: biohydrometallurgy, Zambia, copper processing, CNMC-CSU

Sep 1, 2012

By Peter Ay, Elena Geldt, Satyanarayana Narra, Claudia Glaser

"As part of an extensive research and development project, the technical and technological implementation of the patents DE 10 358 245 B4 and WO/2006/056172 was developed with the goal to present a system for the innovative roll- agglomeration method exhibiting a) a modular setup, b) high productivity and c) suitability for the use of fibres of different applications and product qualities (high technical availability). The processability of the rarely adapted raw fibre materials into high-value intermediates brings forward their application in various processing industries dealing with the production of fibre reinforced plastic composites, heat and sound insulation materials as well as with the gas and liquid cleaning systems. The innovative fibre agglomeration presented in this work is performed by a combination of rolling and pressing the fibres inside a geometrically pre-defined roller table, in which the fibres are forced to bound through entanglement / interlocking and develop into agglomerate. The agglomeration process is carried out in a circular roller path with a rectangular cross-section. For improving the adhesive properties, and thus the quality of the agglomerates, the boundary surfaces can be covered / patterned / lined / coated with various materials. The resulting roll-agglomerates are characterized by different quality parameters such as mass, shape, porosity and stability. The properties of the agglomerates can be modified based on the end-product requirements by slightly modifying the process parameters such as filling ratio, residence time, roll-geometry, procurement of the boundary surfaces, etc. as well as the input material properties such as fibre type, fibre fineness, fibre length, etc. This work carries extensive work on the roll-agglomeration system to assess the effectiveness and the variability based on the product specifications. Agglomerates were produced with wide variations of system parameters with varying roller table liners and based on evaluation of the produced agglomerates with respect to their mass, the geometrical dimensions, their porosity and stability."

Jan 1, 2014

By Milind Sabne, Pradip, P Kapur, Beena Rai

"The efficiency of an industrial flotation circuit depends on (a) the selectivity and the kinetics of the reagent combination selected for the separation (b) the hydrodynamic conditions prevailing in the flotation cell (essentially equipment design parameters) affecting both the pulp and froth phase (c) the operating parameters such as feed rate, pulp density, pH, temperature etc. including the mineralogy, particle size distribution and relative proportion of liberated and composite particles of constituent minerals in the feed to flotation circuit and (d) the circuit configuration itself. We have developed a molecular modelling based reagent design and selection framework to assist mineral engineers to arrive at the preferred reagent combination based on a rigorous, scientific and quantitative comparison of various options available for this purpose. Similarly we have also utilized a general circuit design methodology proposed by Kapur and Mehrotra in 1974. The advances thus made in modelling both the reagent chemistry as well as circuit design, along with the availability of sophisticated, automated tools for characterization of ores (liberation as well as mineralogical composition of the different flotation streams) provides a scientifically rigorous, quantitative, robust framework for design and optimization of complex flotation circuits. We illustrate in this paper the power and the utility of our rigorous optimization based approach to designing industrial flotation circuits for the beneficiation of a multi-component feed with the help of few case studies from our own work. With the proposed methodology, higher levels of process efficiencies can be achieved in the industrial flotation plants, in particular those processing complex, multi-component feeds requiring multiple stages of flotation separation. We are currently developing an IT platform consisting of computer-aided decision support tools for arriving at the preferred flotation circuit and the appropriate reagent chemistry for a given ore deposit and/or a given plant."

Jan 1, 2014

By Gülay Bulut, Ferihan Göktepe

Pyrite is the most abundant and widespread sulphide mineral and its flotation has been investigated by many researchers. It is well known that, pyrite is floatable under acidic conditions and recovery drops with increase in alkalinity due to changes in solubility of iron hydroxides on the pyrite surface. Most of the works also revealed out that pyrite displays variable behaviour in flotation circuits. This behaviour mainly related with origin and mineralogical composition of ore, liberation size, electrochemical behavior of minerals constituting ore, the trace and minor element content of the mineral, texture, application variables belonging to flotation circuits. In this study, copper activation effect was examined on different origin of pyrites. The experiments were performed with five high grade samples of pyrite from the different mining districts of Turkey. The pyrite samples were different from each other with respect to either their physical or chemical properties; they were different physical appearances and contained different associated minerals. In the micro-flotation tests, 1x10-4 mole/L copper sulphate and 1x10-4 potassium ethyl xanthate were used as flotation reagents. First of all pyrite samples were floated using only xanthate at different pH. Results showed that best floatation results obtained at acidic pH range for all pyrite samples. When copper ions were used to activate, all pyrite samples floated at neutral and basic pH values, too but depending on the samples, recovery and pH ranges were slightly changed.

Jan 1, 2014

By G. S. Hansford, G. E. Searby

"Ferrous iron oxidation kinetics was measured in continuous culture at temperatures between 65 and 75ºC, using thermophilic microbes suitable for high temperature bioleaching. The resulting specific oxidation rates were modelled as a function of the ferric/ferrous iron ratio. The results were compared to those obtained by conventional mesophilic microbes.Microbially mediated ferrous iron oxidation is a vital sub-process in the mesophilic bioleaching of sulfide minerals and is expected to be of similar importance at elevated temperatures using thermophilicmicrobes.A thermophilic archaeal culture used in chalcopyrite bioleaching was successfully grown in continuous culture on ferrous sulfate, indicating the capability of the microbes to sustain growth for long periods on the energy provided by the conversion of ferrous iron to ferric iron, the primary leaching agent in sulfide mineral bioleaching.Steady state data was obtained at residence times of between 70 and 10 hours, with washout occurring at residence times between 11 and 9 hours, corresponding to a maximum growth rate (µmax) of between 0.09 and 0.11 hr-1. The reactions were followed by measurements of the solution redox potential, soluble iron concentrations, and offgas analysis of the oxygen and carbon dioxide utilisation rates."

Jan 1, 2003

By R. Peter King, Claudio L. Schneider, Reiner Neumann

Predicting the liberation spectra that is produced from breakage of two-phase ores under the random fracture assumption can be accomplished by measuring the conditional, on length, linear grade distribution directly from images obtained from a representative sample of the unbroken texture. The technique tremendously simplifies the prediction problem by avoiding the multiple convolutions that arise from the traditional method based on a description of texture from a measurement of the chord length distributions associated with each phase in the unbroken texture. For a 3-phase system, the phase transition probabilities associated with the textural information make the traditional calculation an almost insurmountable mathematical problem. The direct measurement procedure on the other hand can be expanded to three phases comparatively easily.

Jan 1, 2003

By Manisha Singh, Manikanchan Sarkar

"Presently the global steel production is mainly based on iron ore sourced from high grade hematite deposits. India has large deposits of good quality hematite ore but with the prevailing practice, such deposits are depleting fast and getting exhausted. However, apart from such high grade iron ores, India is also endowed with large reserves of low grade iron ore, such as BHQ (Banded Hematite Quartzite), BHJ (Banded Hematite Jasper), BMQ (Banded Magnetite Quartzite) and Magnetite. In the present situation, it has become necessary to focus attention on upgradation of these low grade ores to produce useable concentrate. It augurs well that already substantial investigation work has been carried out in this respect and a few plants have been set up in India and abroad. One important aspect in this regard is the process route options with optimum yield and grade. Some of these low grade ores, particularly magnetite, are found to contain high phosphorous level, removal of which poses a major challenge. Since the grade is low, substantial upgradation necessitates fine grinding for appropriate liberation. Fine grinding is energy intensive and needs attention to achieve economy in this regard. Large quantity of tailings is generated in the process, wet disposal of which gives rise to a lot of hassles and hence, possibility of dry disposal of the same needs to be explored. The experience of the authors, with regard to aforesaid aspects which has been gained in course of carrying out relevant assignments is presented in this paper."

Jan 1, 2014

By P. Banerjee, P. Dash, S. Sriramoju, A. Suresh, R. Lingam, T. Ray

"One single property that influences the quality and market value of coal to the maximum extent is the ash content. The lower the coal ash higher is the energy utilization and potential for different applications. Even though Indian coal washeries aspire to produce coal with low ash, the intimate distribution pattern of ash bearing minerals in the coal matrix becomes the real bottleneck, as it brings down the clean coal yield to the impractical value. Because of this fact, most of the Indian washeries are operated to produce coal with 14-15% ash content at the yield of around 40%. In this context, with an objective to produce low ash coal at higher yield, a novel chemical beneficiation route has been explored to demineralize the high ash containing Indian coals. In this present work, the production of low ash clean coal from high ash Indian coals using chemical leaching process has been studied at pilot plant level. The leaching process parameters such as reaction temperature, reagent concentration, reaction time, coal-liquid ratio and agitator speed have been optimized for the flotation tailings sample from a captive washery of Tata Steel. The results obtained show that 67% demineralization could be achieved in a single stage of leaching process with a product yield of more than 65%. For further demineralization, multistage leaching was carried out and the results showed that 75-85% demineralization could be achieved with significant reduction in alumina to silica ratio. Additionally, the phosphorus content is also significantly reduced from 0.20 % to 0.022 %. Further, it is interesting to note that there is no increment of sodium content in the product coal after chemical treatment."

Jan 1, 2014

By Nicolás Luis, Qi Liu, Gonzalo Montes-Atenas

"The prediction of froth flotation performance is still an unresolved topic. Classic industrial models based on particle size, elemental and mineralogical information provides recovery results with deviations that may become significant. One possible reason for this deviation may be the fact that the current liberation analysis provided by electron microscope based techniques does not take into account the outmost surface layer composition of liberated particles. In order to complete the description provided by the liberation analysis, other spectroscopy techniques measuring the extreme surface of the minerals can be tested. For instance, X-ray Photoelectron Spectroscopy (XPS) is a technique which measures the first tens of nanometers providing elemental composition over the particle surface and allows resolving the elemental associations present at the surface sample. However, this information needs to be statistically robust, reproducible and most importantly representative of what is occurring in the process. The aim of this research work is to develop a statistical model based on particle population to evaluate the feasibility of turning the XPS technique into a metallurgical tool. The model consists of classic statistical population arranged in a bed of heterogeneous particles with a known grade and mineral liberation. The simulations showed that the XPS results statistically followed a well-defined pattern. The statistical results were confronted with pilot plant results obtained from a rougher bank when processing a copper sulfide ore from a Chilean mine site. It was observed that the probability function distribution was in agreement with the experimental data. Further analysis on how the XPS results provide valuable information improve the computation of froth flotation recoveries is also discussed."

Jan 1, 2014

By P. A. Harvey

Previous studies have reported that inorganic electrolytes can enhance floatability of coal. The research has shown that the enhancement, if any, is highly dependent on changes in solution pH, type of electrolyte, and electrolyte concentration. The reasons for this are still not clear. In this study the floatability of coal particles in mono and divalent salt solutions was investigated. The zeta potential and hydrophobicity of the coal was measured experimentally, and a modified Hallimond tube was used to determine the floatability of coal particles by single bubbles, where the collision efficiency was equal to unity. The experimental information was used in conjunction with the Hogg-Healy-Fuerstenau equation to quantify the electrical double layer interaction. It was found that for low electrolyte concentration (less than 0.1 M) solutions the flotation recovery of coal particles was less than that for distilled water, and decreased with increase in concentration. Conversely, at electrolyte concentrations above 0.1 M, flotation recovery increased with increasing concentration (Figure 1). Both of these results are consistent with previous observations, but are inconsistent with expectations when considering the possible influence of electrical double layer interaction. Modelling of the system indicates that the electrical double layer is compressed with increasing electrolyte concentration, resulting in an increase in flotation recovery due to a diminishing of the (electrical double layer) repulsion between the bubble and the coal particles. Moreover, for electrolyte concentrations above about 0.1 M the electrical double layer is completely depressed and would have little further influence, if any, on the flotation process. Therefore, the electrical double layer interaction is not the principal determining factor for the flotation of coal in electrolyte solutions.

Jan 1, 2003

By Kobus (J. J. ) Rossouw, P. Chris Pistorius, Johannes Sono

"Different coal properties are important in SL/RN (coal-based rotary kiln) direct reduction of iron ore, and in electrical smelting of prereduced iron ore. Laboratory simulation was used to evaluate two candidate coals, which were similar in volatile content and rank, but differed in reactive maceral content. The tests served to evaluate both the reduction rate (during direct reduction) and the dissolution rate of carbon from the coal into an iron bath.Reduction rates of mixtures of magnetite and devolatilised coal were assessed isothermally, using samples of 55 grams. The off-gas analysis was used to follow the extent of reduction. Results are shown in Figure 1 a). Coal B was expected to be more reactive, based on its higher content of reactive macerals (77%, compared with 61% for Coal A). In line with this, Figure 1 a) does show a higher reduction rate with this coal. However, increasing the reduction temperature increases the reduction rate substantially,especially for the less-reactive Coal A.For the dissolution experiments, samples (mass: 250 g) were melted in an alumina crucible (under a nitrogen atmosphere), to give a starting composition around 1%C. When the desired temperature was reached, 25 g of char was added on top of the melt, through a feeding port. Results are shown in Figure 1 b). The more-reactive Coal B was less crystalline (the graphite crystallite size estimated from X-ray diffraction was 4.6Å, compared with 11.4Å for Coal A). This is associated with a lower dissolution rate in iron."

Jan 1, 2003