Search Documents

By John G. Henning

The Porcupine Joint Venture operates the Dome Mine in South Porcupine, Ontario. Dome underground began production in 1910. It is the longest continuous operating gold mine in Canada, producing in excess of 15 M ounces. More than 900 underground stopes have been mined and hundreds of miles of drifts, sublevels and raises developed. Underground mining methods included shrinkage, cut and fill and longhole. Not all stopes were backfilled upon completion, particularly the longhole stopes. The Dome open pit was designed above the underground mine workings such that, as the pit is excavated, it intersects underground drifts and stopes. Potential operational problems associated with the interactions between the stopes and the pit walls may occur, necessitating pit wall redesign, ground support installation and operational rescheduling. Each intersection of the pit with the underground mine workings is closely evaluated to maintain a safe working environment and wall stability. This paper discussed how risks to pit wall stability are assessed, mitigated and monitored.

May 1, 2004

By David W. H. Ellis

This presentation will discuss over 2 dozen past, present and future oils sands projects in Alberta. The very early projects as well as the most recent along with the ones that never got off the ground and the ones in production are all included. For each, the following will be given (where known): owners, location, type (mining/SAGD/refinery), production, capital budget, spent to date, status. Some overall impacts will be discussed.

May 1, 2004

By Peter Fullagar, Adel Vatandoost, Steve Walters, Toni Kojovic

"Traditional comminution tests are a vital component in every mine plant design. Comminution behavior governs both the cost of equipment and its operating efficiency. Most comminution tests are conducted off site on a limited number of samples, owing to the high costs and long lead times involved. Therefore a strong incentive exists to find alternative means for efficiently characterizing comminution behavior for a truly representative suite of samples. The potential for inferring comminution behavior from drill core is investigated in this paper. Our approach involves development of small scale comminution tests on the one hand, and measurement of a wide range of core attributes on the other. Our focus is the relationship between petrophysical properties and comminution behavior.Petrophysical properties of archival diamond drill core from the Ernest Henry Mine (Queensland, Australia) have been measured using a Geotek multi-sensor petrophysical core logger. We have investigated the relationship between the petrophysical properties and the corresponding small scale A*b and estimated Bond mill work index test results for 2m composites of the core. Core samples were petrophysically classified by means of cluster analysis. Comminution behaviour was then modeled for each cluster via multiple regression. The results suggest that prediction of the comminution behavior on the basis of petrophysics is viable at Ernest Henry.INTRODUCTIONMineral processing is the most important downstream operation for mining engineers and metallurgists since most mined materials are subjected to some type of comminution or beneficiation operation (SME, 1992). Comminution or size reduction is typically the first stage of processing. Size reduction steps (crushing and grinding) in any plant consume large amounts of energy, normally more than 50% of total energy (Weiss, 1985). Therefore, it is desirable to obtain laboratory results to design the size reduction equipment appropriately. One of the main factors that control the selection of hard-rock crushing equipment and the design of a crushing circuit is the mechanical character of the ore(s). Work index, density, abrasivity, compressive strength and clay content are essential parameters for ore characterisation (SME, 1992)."

Jan 1, 2009

By John R. Craynon

Science and Sustainable Development Each of the ?pillars? of sustainable development are directly impacted by mining. We need science to understand exactly how mining contributes to each. Overview of presentation ? History of mining and sustainable development ? Role of stakeholders in measuring/accepting contributions of mining to SD ? Identified ?shortfalls? in understanding mining and SD ? Science needs

Aug 1, 2013

By J. Yue

"Mount Milligan mine is located in northern British Columbia. The concentrator employs conventional SABC grinding circuit with bulk sulphide flotation processes. Commissioning started in September of 2013 and nameplate production of 60,000 TPD was reached in the fourth quarter of 2015. As is typical with many mill ramp ups, bottlenecks developed as throughput increased. Since then, plant modifications and new control philosophies in the comminution and flotation circuits have been implemented and evaluated. The mine-to-mill collaboration played a key role in reaching target throughput rates by improving blast fragmentation and implementing temporary pre-crushing. Results of the projects as well as ongoing challenges/bottlenecks and solutions will be discussed.IntroductionMount Milligan Mine is a copper-gold producer located approximately 253 km northwest of Prince George in British Columbia. Production commenced in September 2013 and reached nameplate capacity of 60,000 TPD in December 2015. Average head grades for the mine life average 0.18% Cu and 0.39 g/t Au.Circuit DesignOriginal process design began with run-of-mine ore from the pit crushed through a 60-110 gyratory crusher, conveyed to a live ore stockpile and fed to the mill via four variable apron feeders. The concentrator circuit employs SAG mill - Ball mill - Pebble Crusher (SABC) grinding configuration to grind the ore down to a target P80 of ~200µm. It is then fed to two parallel trains of flotation tanks, each consisting of five 200 m3 tank cells with the first two being roughers and last three being scavengers. Concentrate streams from roughers and scavengers are separately reground with a closed circuit Tower mill and two open circuit ISA mills operating in parallel, respectively.Three stages of cleaners upgrade roughers/scavenger products to 25% Cu followed by a cleaner scavenger stage. The final concentrate is then thickened and filtered to approximately 9% moisture and shipped off site (Figure 1)."

Jan 1, 2017

By S. Dessureault, J. Porter, M. Woodhall

Information and communication technology (ICT) is seen as a key source of future productivity improvements in mines. The information technology infrastructure (ITI) necessary to achieve these productivity improvements will come in the form of data integrated from multiple source systems throughout the mining value chain. Two pure approaches are available: supplier-controlled or operations controlled data structures; each strategy has its own advantages and disadvantages. Case studies involving the South African mining industry are used to demonstrate the advantages of using hybrid-controlled data structures. Depending on the level of operational control, new skills are also necessary to be learnt by mining professionals including: information engineering; creating consistent and quality data; and process improvement techniques that use the integrated data for improving the operation.

Jan 1, 2004

By Y. X. Zhao

This paper briefly describes the characteristics and induced factors of coal mining bumps based on the investigation of recent bumps accidents occurred in China. According to the theory of non-equilibrium thermodynamic and dissipate structure, the process of strain energy accumulation and dissipation in the ?Coal-Surrounding Rock? system (CSRS) is discussed during the preparation of coal bumps. In addition, a series of experiments are conducted to analyze the relationship between bump-prone property and micro-structural characteristics of coal. The process of coal bumps induced by propagation of fractures and deterioration of coal mass properties are also analyzed systematically.

May 1, 2009

By Michael Hood

An overview is given of some of the major mining research activities in Australia. Automation of mining equipment is not an objective in its own right. The objective is to improve the safety and the economic performance of mining operations. Automation can be a useful method for achieving this objective. There is a strong focus on mining equipment automation and related issues and specific examples of ongoing and recently completed automation projects are described.

May 1, 2002

By Jose R. Hernandez-Aguilar

"This paper revisits data from previous studies (Hernandez-Aguilar, 2010, 2011) to better understand the link between metallurgical performance and pulp-zone bubble size (Db) in full-scale flotation systems. To obtain conclusive evidence exclusively related to the pulp (collection) zone, the experiments were designed in those studies to control both the bubble generation method and the influence of the froth zone on the overall metallurgical performance in industrial and pilot-scale flotation columns. The results showed that Db had a significantly larger effect on the recovery of coarse (> 75 µm) particles compared to the effect on fine (< 16 µm) particles. It was observed that, under certain practical conditions, the recovery of coarse particles was close to zero, but dramatically increased by reducing Db. The evidence revealed an inconsistency of the so-called “k–PSb” model: at constant froth recovery, increasing Sb (i.e., the rate of production of bubble surface area) did not always result in higher recovery, as the model predicts. Furthermore, the evidence showed that it was not the Sb but the bubble size that proved to be a more reliable link to metallurgical performance. Only in the presence of suboptimal-sized bubbles (Db > 2 mm) did the froth zone seem to play a role, possibly reflecting an effect of pulp-zone bubble size on froth stability. However, the role of the froth was negligible for Db < 1 mm.High-resolution mineralogical measurements performed on process samples revealed that, regardless of the degree of liberation, Db had a profound effect on the shape of the recovery-by-size curve, particularly the coarse particle size fraction. This observation is key as it implies that the loss in efficiency associated with floating the coarse particles was not the result of neither particle hydrophobicity nor particle detachment issues: even in the absence of mechanical agitation, liberated and highly hydrophobic coarse particles did not seem to attach to the bubbles in the first place, an inefficiency that was corrected by reducing bubble size. The data analysis suggests that poor attachment efficiency can practically affect both fine and coarse particles but via different mechanisms which are discussed here."

Jan 1, 2017

By C. Schuffeneger

"The design of SAG milling circuits for mining projects requires the incorporation of the energy consumption considerations and the evaluation between different flexibility-adding options to absorb the time-dependent variation in the ore lithology. In order to expand the focus of the engineering design, a higher level of deepness and quality in the baseline information must be achieved to elucidate all of the constraints on throughput, energy consumption and product quality generating a design optimization consistent with an integrated vision of the process. This paper presents a review of a collection of typical examples of the copper and gold mining project in the Chilean Andes, in which both process and energy efficiency criteria are considered when the focus is to deliver an integral solution that incorporate those areas in the design. The intensive use of energy in the SAG milling, the process continuity and the quality of the product are a function of the proper design and selection of grinding equipment and plant layout, aligned with the mining plan and associated with projected future expansions and production increases.INTRODUCTION Autogenous and Semiautogenous grinding technology, large diameter and short length mills, begins with the Handsel design. During the decade of 1930’s, Handsel-Hardinge studies led to cascade mill development. Nowadays, 80 years later, continuous improvements in design and technology have been conducted to a completely new generation of gearless SAG mills that have led to an increasing capacity at the concentrator plants. Considering the existing alternatives, SAG mills are the most implemented option for the grinding circuit today. This work presents a review of the SAG mill implementation parameters and circuit considerations and its correlations in the most recent projects in Chile with an ore treatment capacity above 50 ktpd since the decade of the 90’s up to now. From this period, the tendencies will be analyzed using project design data. Based on process design information, the recent SAG mill history in relevant projects related to the new generation of commercial SAG mills, technical associated considerations and performance will be discussed. Circuit selection based on energy utilization will be revised to bring up a more holistic perspective on the SAG mill circuit design concepts. As is now well known, the heart of every concentrator plant are the grinding mills. Higher demands on throughput, availability and power consumption optimizations require not only high performance electrical equipment but also a well selected grinding circuit. The energy efficiency issues associated to the circuits design will be reviewed."

Jan 1, 2012

"Gravity concentration remains the main separation method for fine iron ore and is used extensively for treating various minerals. Gravity concentration methods separate minerals of different specific gravity by their relative movement in response to gravity and one or more other forces, the latter often being the resistance to motion offered by a viscous fluid, such as water or air (Wills, 2006).Spirals concentrators are one of the gravity concentration equipment used for beneficiation of minerals. Spirals are typically used for processing of fine minerals (-1mm) size fraction. The main operating variables for a spiral concentrator are the feed rate, the solids concentration, the wash water addition and the position of the cutters or splitters used to separate the tailings, middling and concentrate streams (Sadeghi, Bazin & Renaud, 2014).The aim of this study is to investigate the effect of feed rate, solids concentration and wash water on grade and recovery on iron ore material. The Multotec SC20HC/7 WW spiral was used for the experimental test work. The spiral was tested at varying solids concentration and feed rate. The wash water rate was also varied to establish the best washing rate. The splitter positions were kept constant. Optimization of these variables is expected to provide optimum conditions for a good compromise between grade and recovery.INTRODUCTIONSpiral concentrators are simple low energy consuming devices that separate minerals mainly on the basis of density. Spirals are widely used in mineral processing as a method for preconcentration and have proven to be metallurgically efficient and cost effective.Spirals have a wide application, they are used in iron ore processing, coal, gold, chromites, mineral sands, glass sands, and in soil cleaning.Separation on a spiral is achieved through a combination of forces that act on particles as they move down the trough of the spiral. The main forces known to act on the particle on a spiral are the gravitational forces, centrifugal force, hydrodynamic drag, and lift and friction forces (Kapur & Meloy, 1998). Apart from the forces acting on a spiral, the properties of the slurry flowing on a spiral including, solids concentration, feed rate and wash water also plays an important role in the separation on the spiral.The relationship between separation efficiency and feed rate was shown to be linear, with a decrease in efficiency at higher flow rates. Previous work on flow profile by Holland - Batt (1990) indicated that any increase in the feed rate to a spiral results in a greater part of the additional flow volume reporting to the outside of the trough. The flow on the outside of the trough becomes energized and consequence to that the heavy particles find it hard to settle and escape this region to the inner region. This effect has a high impact on recovery of heavy minerals, since any increase in volumetric flow on the spiral is not made available for recovery in the inner region of the spiral."

Jan 1, 2015

By Luis Magallanes-Hernández

"Industrias Peñoles, S.A. de C.V. (Peñoles) in Mexico, is a major silver producer. The Peñoles Mining Division has eight Mining Operations and in seven of them, flotation is used to concentrate the metal and mineral values. Common metals and minerals values are: metallic gold and silver, gold-silver alloys, silver sulphide minerals (acantite, pyrargirite, argentite, proustite); lead sulphide mineral, galena; zinc sulphide mineral, sphalerite; and copper sulphide minerals (chalcopyrite and bornite).In the last years, a special emphasis has been given to using modal analysis to identify ore mineralogical limitations, in order to direct efforts into key areas where opportunities exist to improve the metallurgical results.This work aims to share Peñoles mineralogical and metallurgical results, through presenting, discussing and drawing conclusions on these results; as well as pointing out areas where more work is needed to improve the Concentrator´ performance.PEÑOLES BACKGROUNDPeñoles´s mission is to add value to non-renewable natural resources on a sustainable manner. It was established in 1887, and it is a mining group with integrated operations in smelting and refining non-ferrous metals, and producing chemicals. Peñoles is the world’s top producer of refined silver, metallic bismuth, and sodium sulphate, the leading Latin American producer of refined gold, lead, and zinc.Peñoles Mining Division is integrated into eight mining business, located on five different states in Mexico. Metal productions for the Mining Division during 2003 were: 343 thousand gold ounces, 48.4 million silver ounces, 81.3 thousand tons of lead, 235.1 thousand tons of zinc, and 10.6 thousand tons of copper."

Jan 1, 2005

By Michael B. Cortie

Mesoporous gold sponge has the unique property of being both metallic and highly resistant to oxidation. It has potential application in catalysis, in bio-sensors, in optical coatings, in analytical chemistry and, as we show here, as the basis for a new kind of ultra-capacitor. Due to the cost of gold, the most probable niche for a gold-based ultra-capacitor would be in the high-power/high-energy regime, a region where gold would compete with devices based on RuO2. A high internal resistance limits the power that can be usefully drawn from existing carbon-based ultra-capacitors, and that this problem can potentially be overcome by gold-based devices. A simple proof-of-concept ultra-capacitor based on mesoporous gold is described and its behaviour during charge and discharge cycles examined. In this work a step change in the input or output voltage of the device was used as the controlling parameter. There was also a residual faradaic current resulting from traces of undissolved aluminium left over from the AuAl2 precursor used to make the sponge, and some charge storage due to polarization of the solution. Deconvolution of these three effects was not entirely accomplished, but an ostensible capacitance of about 7 to 14 mF/g Au was demonstrated. Further improvement from these early results seems likely.

Oct 1, 2003

By Brian Hart, Hong Zhong, Liuyin Xia, Kyle Douglas

"The application of hydroxamic acid as flotation collectors is fast becoming of significant interest for the selective flotation of oxide minerals along with upgrading oxidised based metal ores and minerals. In the hydroxamate molecule, both O and N atoms in the -CONHOH group are identified as coordination atoms in many complexes and their characteristic structure determines the strength of the chelation complex between the hydroxamate and metal ion. The chelating performance of hydroxamates with transition metals including Cu, Ni, Zn, Fe, Cr, Mn and Co, the alkaline-earth metals (Be, Ca) and heavy metal (Pb) has been studied. Cytec has developed and patented a range of alkyl hydroxamates as flotation collectors for oxidised base metal sulphides, metal oxide minerals and precious metals. This paper introduces two new structures of hydroxamate collectors (Cyclohexyl and 4-tert-butylbenzoyl hydroxamates) and evaluates their characteristics relative to alkyl and benzoyl hydroxamates. Laboratory small-scale flotation tests were conducted with ilmenite and wolframite. The use of 4-tert-butyl benzoyl hydroxamate resulted in a best flotation performance for ilmenite. A relatively low cyclohexyl hydroxamate dosage was required in the flotation of wolframite to obtain comparable results to the alkyl and benzoyl hydroxamates. It is also shown a significantly improved flotation performance with 4-tertbutyl benzoyl hydroxamate in the flotation of ilmenite plant ore in comparison to the oleic acid or fatty acid collectors typically used for ilmenite flotation.INTRODUCTIONHydroxamic acid has been reported as an effective collector in small-scale flotation tests for a wide variety of oxide minerals and ores including copper (Lee et al., 1998, Lee et al., 2009), iron (Quast, 2000), tin (Sreenivas and Padmanabhan, 2002; Wu and Zhu, 2006), tungsten (Marinakis and Kelsall, 1987; Xia et al.,2004), and rare earth metal minerals (Ren et al., 1997; Pradip and Fuerstenau, 1991; Assis et al., 1996; Pavez et al., 1996; Zheng et al., 1996; Chen et al.,2005).As part of our previous research project, a selected suite of hydroxamic acid collectors including fatty, aromatic and modified hydroxamates (naphthoyl, cyclohexyl, benzoyl, octyl, 4-tert-butyl benzoyl, salicylic hydroxamates) were tested in order to examine their potential for recovery and selectivity of rare earth minerals. In these tests it was shown that the flotation performance with the hydroxamate collectors was significantly better than the phosphoric acid collectors on no slimes removed samples (Brian, et al., 2014; Liuyin, et al., 2014 and unpublished internal technical reports). Furthermore the tests revealed that for most of the hydroxamate reagents tested, their dosage requirements to achieve recoveries at the same levels was less than that for the phosphoric acid collectors. Recovery of both La and Ce was significantly better for the salicylic hydroxamate and that Nb, Y and Zr recovery were favoured by the octyl and benzoyl hydroxamates (Brian, et al., 2014; Liuyin, et al., 2014). Comparison among the hydroxamate collectors showed that the flotation and recovery performance of cyclohexyl (CHH) and 4-tert-butyl benzoyl (TBH) was not as good as the other hydroxamates for rare earth recovery."

Jan 1, 2015

By Bern Klein, Randy Blaskovich, Reem Roufail

"Morphology is a tool that is rarely used for mineral breakage mechanism evaluation. Ground particles are typically assessed for their size distribution. They are also visually analyzed using image analysis. However, image analysis is not a comprehensive evaluation of the particle surface texture. It evaluates particle’s size parameters such as area, diameter, and perimeter amongst other features. On the other hand, morphology analysis takes the particle assessment to another level of detail. Morphology analysis evaluates particles’ roundness, elongation and angularity that would indicate the degree of roughness of the particle. According to Roufail and Klein (2009), rougher surfaces are generated due to breakage along grain boundaries – intergranular breakage. Mill operation, particularly mill speed, dictates the dynamics in the mill. Stirred mills are known to break the particles via abrasion under standard operation. However, if the dynamics of the grinding media in the mill are changed, the particles could be more exposed to impact and compression loading that would lead to a different mode of breakage.In this paper, the effect of material properties and mill operating conditions on particle morphology will be studied. Hard non-sulfide versus soft sulfide minerals are compared, namely quartz and galena, respectively. Extreme mill speeds are tested covering the range of 1000 to 2000 rpm for a 4-litre Netzsch (ISA) mill. In addition to particle size distribution, micro-analysis is executed in the form of morphological analysis using a tested manual roughness point counting technique.INTRODUCTIONGrinding in general and stirred milling in particular are processes that are used to break particles to liberate metal-bearing minerals for further separation downstream. The energy required to achieve the target particle size versus maximum possible liberation has been studied intensively and it is usually the breaking point for the grinding system chosen in a process flowsheet. Operating conditions are dictated by the energy consumption. Becker et al. (2001) related different forms of energy such as input, specific, volume/mass specific energies to stress intensities and final product fineness. Other research studies focused on energy input in a stirred mill (Zheng, Harris and Somasundaran, 1996)."

Jan 1, 2011

By J. Andrew Cornier, Mike Cooper

"Upon successful completion of the AG/SAG Mill project (Cooper et al., 2001) the Brunswick Mine concentrator was configured with single line processing through the AG/SAG mill, followed by two parallel ball mill and flotation circuits. The Stage Grinding project was undertaken to utilize a pre-flotation stage on the AG/SAG mill primary cyclone overflow and simplify the flowsheet by consolidating the two ball mill and flotation circuits, resulting in single line processing fi-om AG/SAG mill to final concentrate. Concurrently, the reclaim water supply capacity was increased to enable flotation cleaning at lower percent solids.Benefits from the Stage Grinding project include revenue enhancement from increased zinc grade and recovery combined with additional lead recovery. Further benefits included a reduction in the number of process pumps, reduction in loss associated with spillage to sumps and process simplification through efficient use of equipment layout.The Stage Grinding project was implemented in six phases over a period of seven months in 2000. Each phase was commissioned during scheduled concentrator shopdays with minimal additional downtime required. One year after project approval the Stage Grinding project was completed at a total cost of $1 1.8 million.INTRODUCTIONThe Noranda Inc. Brunswick Mine, located near Bathurst, New Brunswick, is one of the world’s largest leadzinc mines. Milling of ore began in 1964 from the No. 12 orebody, with an expansion in 1966 to accommodate ore fkom the No. 6 open pit located several kilometers away. In 1980 the pit was exhausted and the concentrator rationalized to accept a design feed rate of 10,500 tomes per day from the No. 12 mine. In excess of 100 million tomes have been milled to date, representing over three-quarters of the known reserve. The concentrator employs differential froth flotation to produce lead, zinc, copper and leauzinc bulk concentrates. The ore is massive sulphide, with approximately 20% valuable minerals, 60% pyrite and 20% silicates."

Jan 1, 2002

By Jörg Fischer-Bühner

Conventional 22ct Au jewellery alloys are comparably soft in the as-cast and soft-annealed state and hardening by cold-working is the only way of giving strength to the jewellery. The paper first focuses on hardening of 22ct jewellery alloys by conventional means, i.e. solid solution hardening with base metals (aiming particularly at an increased as-cast hardness) as well as precipitation hardening by alloying with base metals beyond the solubility limits and subsequent age-hardening heat treatment. Co-additions of ~2% turned out to result in most pronounced solid solution hardening up to ~100 HV1 in an investment cast & quenched state. Subsequent heat treatments, consisting of solution annealing at 850°C for 1h followed by water quenching and ageing at 300°C ? 400°C for ~ 1h lead to pronounced age-hardening with a peak hardness of ~ 260 HV1. In contrast, 22ct Au alloyed with Ni, Fe or Sb display no age-hardening effect within the same range of heat treatment parameters. The 2nd part of the paper reports on some preliminary trials to enhance the hardening effect of the base metals by additions of suitable elements, which possess a strong tendency to phase formation with the added base metal during ageing treatments. It is shown, that the age-hardening behavior of 22ct and 990/995 Au alloyed with Co or Ni can be remarkably influenced by additions of Sb. A total of only 10wt%0 of CoSb or NiSb-additions lead to a peak hardness of ~ 150 HV1 for a 22ct Au and ~ 100-120 HV1 for 990 Au , which is obtained already after very short ageing times (20-40min) at 300-400°C after solution annealing at 700°C / 1h / water quenching. It is suggested that the age-hardening mechanism in these alloys consists in precipitation of intermetallic CoSb- and NiSb-phases.

Oct 1, 2003

By J. Don Scott

Analytical predictions of the rate and magnitude of settlement of deposited oil sands tailings slurries generally overestimate how fast pore pressures will dissipate. Field deposits of nonsegregating tailings to mature fine tailings show continued high pore pressures near the surface which impede surface reclamation. In geotechnical analyses which predict the consolidation behavior of soft soils a finite strain theory is used. Effective stress-void ratio and void ratio-hydraulic conductivity relationships determined from laboratory large strain consolidation tests, are used in the finite strain predictions. This theory, however, cannot predict the full range of sedimentation, consolidation and pore pressure dissipation which occurs in large scale deposits of thixotropic tailings slurries. A new large strain consolidation model which assumes that the creep rate of the slurry exceeds the pore pressure dissipation rate is being investigated. This model is relevant for rapidly deposited, low permeability thixotropic slurries where the upwards drainage path increases by several meters a year, such as, in oil sand fine tailings ponds and nonsegregating tailings deposits. The model will be verified by analyzing the 10m high column of fine tailings at the University of Alberta which has been monitored for over 20 years and in which the excess pore pressures are still very high.

May 1, 2004

By Gaby Steinbach

A novel synthesis is described for the preparation of supported gold catalysts for low-temperature CO oxidation. The novel route is a variation of the inverse co-precipitation method and requires amphoteric metal hydroxides, with zinc and aluminium hydroxides chosen. Catalysts were prepared by inverse co-precipitation (ICPa) and by the novel route (ICPb) and tested for CO oxidation at 60ºC. Preliminary results showed the novel route to be superior to ICPa; the catalysts prepared by ICPb showed higher catalytic activities. The effect on catalytic activity of parameters such as pH, calcination temperature, washing of precursor and calcined catalysts and ageing was investigated. A preparation pH of 9 and a Zn to Al mass ratio of 3 proved to be optimal. It was possible to remove residual chloride by washing thereby enhancing catalyst performance. Ageing and Mg citrate addition were also shown to improve catalyst performance. Characterization of the catalysts revealed that better activities were obtained when the support was more crystalline and had a higher surface area. The presence of carbonate-containing species in the support decreased catalytic activity. 197Au Mössbauer Spectroscopy revealed the presence of Au3+ when catalysts were heat-treated at temperatures of 200ºC and below. Catalysts calcined at 400º had 75% of the gold present as Au0, with the remaining gold present as Au3+.

Oct 1, 2003

By C. V. Umipig, G. G. Hutalle, E. E. Israel

TVI Resource Development (Phils) Inc. Canatuan mine is a polymetallic ore deposit located in the Province of Zamboanga del Norte on the island of Mindanao in the Philippines. The deposit consisted of an oxidized capping of gossan overlying a Besshi type volcanogenic massive sulphide lens which is near surface and flat lying. Construction and development of a sulphide processing plant began in early 2007 and commissioned in November 2008. During the initial stages of sulphide operation, high copper (Cu)-low zinc (Zn) ore was fed to the plant. Marketable copper concentrate at 91-95% recovery was produced utilizing a high-pH bulk sulphide rougher flotation and 2 cleaning stages. Because of increased levels of Zn of the ore body, a Cu/Zn separation circuit was initiated in early 2010 following an intensive laboratory test work program. This Cu/Zn separation circuit was necessitated because of the copper ion pre-activation of the sphalerite that lead to the zinc being readily recovered to the copper rougher concentrate. In-situ activation of zinc (in the pit and stockpiles) was caused by the leaching of secondary copper minerals in the ore (particularly from the dominant copper species, chalcocite and covellite). This problem required the development of metallurgically complex and intensive reagent regime to effectively depress the activated sphalerite. As well, the immediate reactivation of zinc after it has been depressed, at the onset of Cu/Zn separation flotation, added additional metallurgical complexity to the process. Subsequent to the Cu/Zn separation circuit, an unconventional, yet proven effective, simultaneous cyanide detoxification-zinc flotation circuit was set-up to recover the zinc. Laboratory test work results realized Cu-Zn recovery differential from a Cu/Zn separation circuit of over 40-45%. This performance has been achieved in the plant, at 72% Cu overall recovery. With the gradual improvements on-going with zinc circuit capacity and effective zinc separation being achieved, zinc recovery has currently reached 40%.

Jan 1, 2012