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By D. A. Livingstone

Abstract Golden Manitou Mines, Limited, nine miles east of the town of Val d'Or in northwestern Quebec, are presently milling, at the rate of 1,000 tons daily, a relatively complex 3.11-phide ore and producing, in decreasing order of value, zinc, silver, gold, lead, and copper. The products are a zinc concentrate, a silver-lead-copper concentrate, and a silver-gold precipitate from cyanidation. Although several independent pre-production metallurgical investigations into the treatment of the ore were carried out, current practice is different from any of the recommended methods and, while still leaving room for improvement, is considerably more effective than earlier performance. Flow-sheet developments from the commencement of operations in 1942 are dealt with briefly, showing the reasons for making numerous changes, the shortcomings of the various schemes tried, and, finally, covering data pertinent to present-day practice. From the recovery standpoint, silver has presented the greatest difficulty. The writer's association with the Company coincided with the start of production. Characteristics of the Ore The predominant metallic minerals present in the ore, in decreasing order of their abundance, are: pyrite, sphalerite, galena and chalcopyrite, with lesser amounts of argentiferous tennantite-tetrahedrite, arsenopyrite, covellite, bornite, and chalcocite. The sphalerite is mostly light in colour, sometimes colourless, and practically free from combined iron. Some of the sphalerite is very closely associated with minor amounts of pyrite, chalcopyrite, and galena. Pyrie is abundantly disseminated as medium to fine grains; more rarely it is massive and contains occasional grains of sphalerite, galena, and chalcopyrite.

Jan 1, 1952

By M. A. Bergougnou, I. Inculet, K. I. Burgess

This paper describes the electrostatic methods of separating various minerals, reviews the principles of fluidization and outlines the technique of electrostatic sorting in fluidized beds. The application of the method to the benefication of coal is emphasized.

Jan 1, 1970

By C. R. Ross

"THE ASSESSMENT of pneumoconiosis-producing dusts in mines and other industries is usually undertaken for one or more of three reasons: (1) To compare dust exposures at particular operations with standards of permissible dustiness in order that hazards may be evaluated and preventive procedures initiated where required.(2) To study particular operations with the objective of improving dust control devices or procedures by locating dust sources. (3) To obtain data which, along with the results of medical investigations, may assist in understanding the causes of dust-induced diseases or aid in the establishment of permissible standards of dustiness. Most dust measurements are made for the first of these reasons -to evaluate dust hazards so that they may be controlled. For this purpose, four quite different assessment techniques have been in widespread use for many years. One of these is based on the konimeter, an instrument familiar to most .Canadian mining men; a second on the impinger, which is also widely used in Canada, and almost exclusively so in the United States; a third on the thermal precipitator, used extensively in Britain and South Africa; and a fourth on the tyndallometer, a light-scattering instrument used in Germany."

Jan 1, 1960

By Ralph W. Edie

"IntroductionTHIS PAPER deals with chemical and mineralogical changes in wall-rocks associated with pitchblende mineralization in the Gold-fields area of Saskatchewan. The localities at which the rock specimens studied were collected, and descriptions of the various rock-types referred to, are given in a previous paper by the author (5).The geological field work upon which this paper is based was carried out while the writer was employed by the Eldorado Mining and Refining Company during the summers of 1948, 1949 and 1950. The laboratory work§ consisted largely of quantitative spectrographic analyses for both major and minor elements, supplemented by an examination of 250 thin sections of both altered and unaltered rocks.Character of the AlterationHydrothermal alteration, with associated pitchbende mineralization, is widespread in the Goldfields area of Saskatchewan. The most intense alteration is restricted to the immediate vicinity of fault or breccia zones, but large areas are affected to a minor extent.In detail, the relationship between alteration and pitchblende mineralization is complex, as individual veins do not in general have separate alteration halos. Pitchblende generally occurs in gash-like calcite veins or stringers in wide, fractured zones associated with faulting. Large, lenticular and tabular masses of slightly to intensely altered rock occur in the same wide fracture zones as the mineralized veins. However, vein deposition appears to be-long to a later fracturing period, after hydrothermal alteration was more or: less completed. Generally, the veins transect and are confined to highly altered rock, but on the other hand many highly altered zones intersected in diamond drill-core are barren of mineralized veins."

Jan 1, 1953

By R. D. Brown

In his March 31, 1977 budget, Finance Minister Macdonald has attempted the delicate balancing act of stimulating the economy without reinforcing the inflationary pressures which Canada is continuing to experience. Several tax changes of benefit to the mining industry, as well as measures designed to encourage oil exploration in frontier areas, are among the budget proposals. Additional earned depletion of 66- 2 /3 %, which may be offset against income from any source, will be available on drilling costs in excess of $5 million incurred between March 31, 1977 and April 1, 1980 in connection with an exploratory well in Canada, including the continental shelf . Other changes include more favourable treatment of resource property dispositions, less restrictive rules r elating to "successor corporations" , increased capital-cost allowance on railway spur lines, the inclusion of certain production royalties in Canadian development expenses and the application of the lower "manufacturing and processing" tax rate to sulphur production. To encourage business capital spending, the 5% federal investment tax credit it to be extended an additional three years to mid 1980 and broadened to include spending on scientific research and development. The rate of credit will also be selectively increased on a regional basis, to 7.5 % in certain designated areas in Saskatchewan, Manitoba. Northern. Ontario and Quebec, and to 10% in the Atlantic provinces and the Gaspe.

Jan 1, 1977

By Mary A. Wells, Amir Hadadzadeh, Mark A. Whitney, Stephen F. Corbin

In an effort to produce less expensive titanium sheet via roll compaction, the room temperature compaction behavior of titanium sponge granules (99.9% pure, Alfa Aesar) was studied under uniaxial die compaction. The titanium sponge granules were irregularly shaped, with a high degree of porosity, having a maximum particle size of 3mm. Manual die compaction was conducted using a Carver hand press, in a hardened tool steel die with 12.61 mm inner diameter. Uniaxial die compaction in a hardened tool steel die with 9.50 mm inner diameter was also performed using a Gleeble® 3500 thermal-mechanical simulation testing system which allowed for controlled deformation rates. Compaction behavior of the titanium sponge was studied using well-established compaction equations (Heckel, Panelli-Filho and Ge), and it was observed that compaction rate influences the room temperature compaction behavior of this material. The Heckel analysis of the titanium sponge showed that the behavior of the material could be analyzed in two compaction pressure regimes. In the low pressure regime (<100 MPa) the granules exhibited high compressibility, while; in the high pressure regime (>100 MPa) lower compressibility of the titanium sponge was observed.

Jan 1, 2015

By P. Clinton Milne

Uranium mines in Washington State include the producing Midnite and Sherwood mines and several mined-out deposits, the most productive of which was the Daybreak mine. The Midnite mine is generally classified as a hydrothermal deposit consisting of tabular orebodies in Precambrian pelitic and calcareous metasedimentary host rocks. The host rocks occur as roof pendants in a Cretaceous porphyritic quartz monzonite intrusive; the quartz monzonite averages 12 ppm U308 The uranium deposit appears to have undergone a complex genesis, involving a series of depositional and enrichment stages. The Sherwood uranium deposit, approximately 4 miles south of the Midnite mine, occurs near the bottom of a basal Late Cretaceous to Paleocene arkosic conglomerate. The conglomerate lies nonconformably on the porphyritic quartz monzonite that is associated with the Midnite deposit. The Sherwood and Midnite uranium deposits may have had a similar genetic history linked by a common uraniferous pluton source, ground-water action, and/or leaching of uranium-rich ash flows from now-eroded, overlying, Eocene volcanics. The Daybreak deposit, in northeastern Spokane County, consists entirely of secondary uranium mineralization (metaautunite) in a quartz monzonite pluton. Mineralization is confined to a low-angle fault zone and is most highly concentrated at the intersection of primary and secondary shears. Both hydrothermal and ground-water origins are feasible. Besides the Midnite-Sherwood area, 14 other areas in the western Okanogan Highlands physiographic province and Cascades region have favourable characteristics for uranium potential. Criteria include the existence of uranium occurrences, Tertiary basin sediments with intercalated volcanic and volcaniclastic rocks, favourable geochemical data, alkaline plutons associated with uranium occurrences or borders of Tertiary basins, and structural controls.

Jan 1, 1979

By Balmer Neilly

We are regularly told that before making a new investment one should seek the advice of his banker. If we were to place the subject matter of this paper before bankers. other than those who have experience in our mining camps, their reply would probably be evasive. However, if for example: a mining company asks them for a loan and offers as security certain mining investments, they are, in most cases, explosively candid. The idea is preposterous, unless, under Section 88 of the Bank Act, the mining company is able to deposit with the bank, gold or silver bullion, to an amount sufficiently in excess of the loan, to provide for what the banker describes as a reasonable margin of safety in case of contingencies. In addition the directors of the mine personally must jointly and severally guarantee payment of the loan. With any of these conditions missing the banking atmosphere becomes chilly. The local manager explains that the general situation, and particularly European conditions, are so unsettled that head office has warned him that his discretionary powers must not be exceeded under any circumstances.

Jan 1, 1924

By F. Ajersch, M. Rigaud, M. Jallouli

"Le gonflement des boulettes d&apos;hématite à été étudié à l&apos;aide d&apos;une méthode de mesure standard ISO ainsi qu&apos;à l&apos;aide d &apos;une méthode de mesure dilatométrique.La première méthode a servi à l&apos;étude des boulettes haute silice (5% SiO2) dont l&apos;indice de basicité (IB = CaO + MgO -i- SiO2 + Al2O3) a été ajustée soit à l&apos;aide d&apos;une addition de dolomie, soit à l&apos;aide d&apos;une addition de pierre à chaux, soit à l&apos;aide d&apos;une addition de ces deux composes. L&apos;indice de basicité variait de 0.05 à 0.12. Les résultats de gonfle ment obtenus à 1000?C dans une atmosphère de 40 CO - 60 N2 ont permis de montrer qu’indépendamment de l&apos;indice de basicité c&apos;est la dolomie qui contribue le plus à diminuer le gonflement par rapport à la pierre à chaux. L&apos;utilisation de l&apos;indice de basicité comme critère de sélection des boulettes est discutée.La méthode dilatométrique a servi à l&apos;étude du gonfle ment de deux types de boulettes préparées à partir de deux concentrés de fer et dont la teneur en silice a été fixée à 2.5% et 0 5%. Ces deux types de boulettes ont reçues les mêmes additions de liant en quantité et en nature. La détermination en continue du gonflement, à 950?C dans 40 CO - 60 N2, a permis d&apos;une part de mieux cerner le niveau de réduction auquel correspond le maximum de gonflement et d&apos;autre part de montrer que l’allure des courbes de gonflement est étroitement liée à la nature du liant. Une augmentation de la teneur en silice des concentres contribue à diminuer le gonflement des boulettes.Des essais de réduction de gonflement non isothermes ont été réalisés à des montées de température à 10 et 20?C/min. Les résultats indiquent que le gonflement déterminé dans les conditions non iso thermes est inferieur à celui obtenu lors des essais isothermes. On discute alors de la validité des essais standards de gonflement qui sont utilisés pour prédire le comportement des boulettes lors de leur réduction dans un haut fourneau."

Jan 1, 1983

By J. S. Moretzsohn, D. F. Graham

"Airborne Synthetic Aperture Radar (SAR)was acquired over the Carajás Mineral Province, within the rainforests of the Amazon, which hosts the world’s largest Fe-ore deposit(Santos, 1986). Significant chemical weathering exists in this humid environment. PrevalentAu mineralization is thought to be generally associated with deformation zones in Archean schists.Radar data have proven to be very useful as an aid to geological mapping in the tropical rainforests of the Amazon Basin in Brazil. In these densely vegetated areas, a sense of regional structural trends is obtained as a con-sequence of the sensor/terrain geometry. The top forest canopy is the main terrain reflector of X-band radar energy, and consequently is the main terrain surface feature expressed in processed radar imagery. Radar is important for extending t,he continuity of mapped structural lineaments. Differential weathering is related to variations in radar image texture which is used to infer gross lithologic variations and relative age relationships of major rock units. Specifically, quartzites and banded iron formation are highlighted in the radar imagery due to their unique tonal and textural appearance, in contrast to schists, gneisses and metavolcanic rocks. As tropical areas are typically enveloped in cloud or mist, radar data are invaluable in providing information for logistical planning of field mapping activities."

Jan 1, 1997

By Jr. Watts, B. K. Cantrell, K. L. Bickel, J. F. McDonald

"A field trial was conducted at an underground gold mine to evaluate diesel fuel derived from soybean oil (soy-methyl-esters or “biodiesel”) as an alternative to commercial, low-sulphur, number 2 diesel fuel (D2). A 2.7 m3, 18-ton load-haul-dump (LHD) unit, powered by a naturally aspirated, indirect injection (pre-chamber), 100 kW diesel engine was used as the test vehicle. The LHD was equipped with a diesel oxidation catalyst. The LHD operated satisfactorily on the biodiesel fuel. Operators observed a slight decrease in power and an absence of black smoke.Diesel particulate matter (DPM) concentrations were monitored for a six-week period while the LHD was operated with either the biodiesel fuel or the D2 fuel. DPM concentrations were measured in the mining section’s clean air intake, exhaust and on the LHD. Reduction in DPM emissions was determined from the measured difference in DPM concentrations between the clean air intake and the exhaust. The biodiesel fuel reduced energyspecific DPM emissions approximately 75%, from 3.6 ± 1.8 g/kW-hr to 0.86 ± 0.27 g/kWhr. Time-weighted average DPM exposure, measured near the LHD operator, was reduced from 0.67 ± 0.13 mg/sm3 to 0.28 ± 0.12 mg/sm3, or approximately 58%, when the biodiesel fuel was used. IntroductionDiesel exhaust consists of noxious gases and diesel particulate matter (DPM). Recent attention has focussed on the potential carcinogenicity of DPM and the potential health impact on miners. The National Institute for Occupational Safety and Health (NIOSH) recommended that whole diesel exhaust be regarded as a “potential occupational carcinogen”, and that reductions in workplace exposure would reduce cancer risks (NIOSH, 1988). The International Agency for Research on Cancer (IARC) declared that “diesel engine exhaust is probably carcinogenic to humans” (IARC, 1989)."

Jan 1, 1997

By W. Noel O?Brien

Introduction Since 1930 numerous improvements have been made in equipment designed for the mechanical removal of broken ore in underground mining operations. New applications of mechanical equipment, as? well as improvements and adaptations of well established systems, are being made continually. It is the purpose of this paper to discuss present-day equipment for the removal or transfer of broken ore by means of a powered hoist and scraper arrangement. The terms used throughout the paper are those commonly employed in the trade literature and by mining men. The terms slusher hoist, hoist, and scraper hoist are used inter-changeably to mean a machine, powered by compressed air or electricity, with drums for the winding of wire rope. The tail rope, also known as the pull-back rope or return rope, drags the empty scraper toward the tail-sheave, that is, back to the loading point. No attempt is made to cover the entire field of application of scraping methods. Rather it is the? writer&apos;s desire to emphasize the fundamental principles of scraping practice and design and to relate them to some modern applications. The available literature on scraping practice has been freely used. together with personal observation and information and advice of practising engineers and representatives of companies manufacturing slushing equipment.

Jan 1, 1951

By Frank Otten, Jochen Greinacher

"In July 2017, Deilmann-Haniel signed a contract with IOO Slavkaliy to sink two 750 metre (m) deep freeze shafts for the Nezhinsky Potash mine in Belarus. This is the second shaft project where this technology is employed after two over 1,000 m deep shafts for a potash project in Saskatchewan, Canada, have been sunk by the application of the Herrenknecht Shaft Boring Roadheader (SBR) technology. Developed to sink shafts for green field projects in soft to medium hard rock, in frozen or unfrozen geology, the machine technology utilizes a roadheader-type cutterhead on a telescopic boom to mechanically excavate the rock, and a pneumatic mucking system to convey the muck from the face into the buckets. This leads to a manless face during the sinking cycle and thus a significant improvement in terms of workplace safety. For the Nezhinsky project, the SBR design was significantly modified in close cooperation between Deilmann-Haniel and Herrenknecht, based on the available experience and the special requirements of the project. Such modifications have been for example the adaptation of the Pneumatic Mucking System to cope with wet material as well as dry as originally planned or the shaft lining moving from shotcrete application to jump for and tubbing installation for which a step-change hands-off tubbing erector for the placement of segments was designed. Further modifications to optimize the machine technology for the requirements during shaft sinking were applied on the two machines for the Slavkaliy project as well as several revisions to match the special project requirements. The SBR is suitable for soft and medium hard rock up to 100 MPa UCS. The main design limits are maximum weight of the machine with 400 tonnes and length or height of 50 m due to the depth of the pre-sink. The Pneumatic Mucking System was changed in all components, sheaves and rope arrangement were redesigned and the concept of the hoist system was also re-engineered. The SBR in Belarus is configured for a daily sinking rate of three metres and all systems behind the cutting boom are not the bottle neck of the whole system. The works on site started in November 2017 including freeze hole drilling, construction works, site setup, installation of hoists winches, permanent headgears and other components required for sinking. The SBRs arrived on site in June/July 2018 and were preassembled on surface and then lowered into the 50 m pre-sink. SBR #1 started full face sinking in mid-December 2018, and SBR #2 in late January 2019. By the end of February 2019, the machines were at 150 m and 100 m depth respectively, and achieved up to 3.6 m/day concrete lined shaft. The SBR and the sinking system, the experiences, problems, technical solutions and performances of this challenging project will be presented in this paper."

Jan 1, 2019

By Roorda H. J, R. R. Saddington, Curlook W

THE copper-nickel sulfide ore deposits of the International Nickel Company of Canada, Limited contain the minerals pyrrhotite, pentlandite, and chalcopyrite. In the extraction of the nickel, copper, and iron, much of the processing involves oxidation of the metals as well as sulfur. Roasting plays a predominant role at several stages in the operations which prepare the constituent metals for refining. Copper, nickel and iron concentrates of various grades, ranging from low-grade nickeliferous pyrrhotite to high-grade nickel sulfide, must be partially or completely oxidized. Figure 1 shows the main points at which roasting is conducted at INCO. Roasting experience at INCO dates back to the time when lump ore was partially roasted in heaps. It has progressed through single hearth roasters, sinter machines, multiple-hearth roasters, flash roasters, and more recently has centered on the development and utilization of fluid bed roasters. The primitive, slow, and inefficient method of heap

Jan 1, 1961

By L. H. Van Loon, E. G. Crayston, A. F. Heather

"IntroductionTHE PROPERTY of Madsen Red Lake Gold Mines. Limited. comprises fifty-eight claims located between Russet and Faulkenham lakes in Baird and Heyson townships of the Patricia portion of the District of Kenora. The mine is seven miles •by road from the hamlet of Red Lake. This latter centre is .connected to the Trans-Canada Highway at Vermillion Bay, Ontario, by provincial highway No. 105 which has a total length of one hundred and thirteen miles.The Madsen property went into production on August 11th, 1938, with a milling plant rated at 300 tons per twenty-four hours. Changes made in the crushing plant during October, 1938, allowed a •finer feed to be delivered to the mill and increased the milling •capacity to 400 tons per twenty-four hours. During 1948, steps were taken to add an additional 400-ton capacity unit to the milling plant. This latter work was completed by May, 1949, giving the present total milling .capacity of 800 tons per twenty-four hours.It was realized in the early 1940's that, eventually, considerable material suitable for backfilling in the mine would be required. As there were no large deposits of gravel or sand anywhere near the mine, officials of the Company considered it advisable to investigate the feasibility of using mill tailings for mine •backfill. Since Madsen mill tailings contain approximately 80 per •cent of minus-200-mesh material, it was not considered practical to use them for underground backfill without first removing the finer material. as the slimes present in a product of this fineness would without doubt preclude any drainage whatsoever. Table I gives a sizing analysis of Madsen mill tailings and Table II a quantitative chemical analysis of the ore."

Jan 1, 1954

By G. Eaton

Safety management is an important mortal and business function in construction. Contractors have traditionally tracked and reported lagging indicators, e.g. fatalities and lost-time accident rates, to measure their safety performance and stay in compliance with relevant regulations. Over the last several decades, contractors became more proactive in their approach to safety and developed programs that track leading indicators, e.g. safety audits and safety climate. In particular, safety climate measures workers? perception of safety management and its effectiveness in the workplace. Past literatures indicated that, while some industrial construction contractors ignore safety climate measures, others are limited by a lack of a formal means to measure safety climate. In this study, a survey approach is used to measure an industrial construction contractor?s safety climate through three key areas: management commitment, job control, and general safety climate. As a pilot study, a total of 214 individuals at a fabrication facility participated in the survey to verify the validity and effectiveness of the proposed survey approach. This survey study also confirms that job control and management commitment have a positive correlation and that worker demographics have an effect on respondents? perceptions of management commitment.

Aug 1, 2013

By V. S. Sastri, M. Elboujdaïni

"Corrosion rates of silicon brasses, highzinc yellow brass, low-zinc yellow brass, leadedtin bronze and silicon bronzes in both permanent-mold and sand-cast conditions were determined in soft water of pH 3, 5 and 8, and hard water of pH 8 at 70°C by electrochemical polarization technique. The alloys in permanent- mold condition showed greater corrosion resistance than sand-cast condition. Corrosion rates obtained from weight loss measurements showed no observable trend of a difference between permanent-mold and sand-cast alloys.The corrosion rates decreased with increasing pH of the medium. Silicon bronze and silicon brass showed high corrosion resistance while leaded-tin bronze showed the least resistance. Addition of small amounts of aluminum improved the corrosion resistance of silicon bronzes and silicon brasses. Alloys in permanent- mold condition showed greater resistance to dezincification than sand-cast alloys when average pit depth parameter is considered."

Jan 1, 1997

By D Maschemeyer

The cobalt production of the Chemical Metallurgical Division of Sherritt Gordon Mines Limited was supplemented, from May, 1962, to June, 1964, by processing 3,500 tons of a calcined cobalt-nickel concentrate. This paper describes the reduction roast -aqueous sulphuric acid leach process and the operating practices employed in recovering cobalt, nickel and copper from this oxidized by-product of a lead-copper operation. Incorporated in this paper is a description of how this process was integrated with the existing ammonia leach -hydrogen reduction process for the recovery of nickel and with the soluble cobaltic ammine process for the recovery of cobalt. Introduction T HE Chemical Metallurgical Division of Sherritt Gordon Mines Limited at Fort Saskatchewan, Alberta, has recently completed ten years of operation utilizing the ammonia leach process for the recovery of nickel, cobalt and copper from sulphide concentrates, matte and other materials amenable to this process. A continuing development program, along with the expansion of certain facilities, has enabled the refinery to attain a production rate of 31, 000,-000 pounds of nickel per year by hydrogen reduction. This represents an increase of approximately 85 per cent over the original design capacity of the plant.

Jan 1, 1965

By D. Milne, G. Snell

"A new method to predict stope hangingwall failure in underground excavations is proposed. This method compares movement rate for stope hangingwalls, determined from changes in strain or deformation, with changing opening geometry. This geometry is represented by the effective radius factor (ERF), a measure of relative distance to supporting abutments from an opening surface point. This strain-ERF (SERF) approach is applied to an instrumentation program for Brunswick mine near Bathurst, New Brunswick. The SERF method for this case study predicted failure at an ERF of 13.9 m and hangingwall failure actually occurred at an approximate ERF of 12.4 m.RÉSUMÉ Cet article propose une nouvelle méthode permettant de prévoir la rupture de l’éponte supérieure des chambres d’abattage dans les excavations souterraines. Cette méthode compare la vitesse de mouvement des épontes supérieures des chambres d’abattage, déterminée à partir des changements aux niveaux des contraintes ou de la déformation, à la géométrie variable de l’ouverture au jour. Cette géométrie est représentée par le facteur du rayon effectif (ERF, de l’anglais Effective Radius Factor), une mesure de la distance relative jusqu’aux appuis latéraux de soutènement à partir d’un point de la surface d’ouverture au jour. Cette approche contraintes-ERF (SERF, de l’anglais strain-ERF) est appliquée à un programme d’instrumentation pour la mine Brunswick située près de Bathurst, dans le Nouveau-Brunswick. Pour cette étude de cas, la méthode SERF prévoyait une rupture à un ERF de 13,9 mètres (m); la rupture de l’éponte supérieure s’est effectivement produite à un ERF d’environ 12,4 m.INTRODUCTIONUnderground stope design can be improved with the installation of field instrumentation. The most commonly used instrumentation for monitoring rock mass behaviour around open stopes is extensometers. The y-axis of Figure 1 represents how the changing rate of movement, measured using either displacement- or stress-type instruments, can be observed over time. The magnitude of movement measured by extensometers can give an approximation of the load on installed support (Milne, Pakalnis, & Lunder, 1996) and a changing rate of movement can indicate approaching instability."

Jan 1, 2018

By D. Haraguchi, S. Izawa, C. Tokoro, S. Owada

"Arsenic is widely known as a toxic element for humans, animals and plants. Because of more stringent wastewater standards not only in Japan but also around the world, research for appropriate and efficient treatment method for arsenic is becoming increasingly important. Coprecipitation or adsorption process using ferrihydrite is widely implemented for dilute As(V) removal from wastewater. In this study, the sorption mechanism of dilute As(V) with ferrihydrite in coprecipitation or adsorption process was investigated. To accomplish this, we conducted batch experiments of coprecipitation or adsorption and compared these results for sorption isotherm and zeta potential. These experimental results showed that sorption mechanism in coprecipitation process depends on the initial As/Fe molar ratio; simple twodimensional adsorption onto the surface of ferrihydrite when the initial As/Fe molar ratio was < 0.4, and some three-dimensional uptake with ferrihydrite when it was = 0.4. We also evaluated the sorption mechanim by analysis of X-ray diffraction (XRD) and X-ray Absorption Fine Structure (XAFS). XRD or XAFS spectra showed that surface precipitation of amorphous ferric arsenate was formed when the initial as/Fe molar ratio was = 0.4, beyond the thermodynamic bulk precipitation range for ferric arsenate.INTRODUCTIONArsenic is toxic to animals, including humans, and long-term exposure to arsenic via drinkingwater causes cancer of the skin, lungs, urinary bladder, and kidneys, as well as other effects on the skin such as changes in pigmentation and thickening (Ghosha et al., 2008). Elevated levels of arsenic are often present in the environment as a result of the weathering and dissolution of minerals as well as in response to numerous anthropogenic sources including the discharge of mine wastes, coal fly ash and the use of pesticides that contain arsenic (Nriagu, 1994; Singh et al., 2007). Indeed, the potential for arsenic exposure affects many people, as evidenced by several million people in Bangladesh and India being at risk of exposure via drinking water obtained from contaminated groundwater sources (Ahmed, 2001).Acid mine drainage (AMD) containing arsenic is a global environmental problem (Dold, 2008; Liang and Thomson, 2008) that also affects Japan, which has many abandoned or closed mines that have been generating AMD for the last few decades (Masuda et al., 2008). Several such facilities in Japan produce AMD containing dilute concentrations of arsenic that exceed Japanese effluent standards (0.1 mg/dm3) (METI, 2006). For example, AMD from the abandoned Horobetsu sulfur mine, the largest AMD source in Japan, contains approximately 10 mg/dm3 arsenic."

Jan 1, 2012