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By Ralph W. Bailey, William B. Price

INTRODUCTION ARSENIC, antimony and phosphorus are now used in the brass industry as standard inhibitors in preventing dezincification in [ ] condenser tubes. This subject has been thoroughly covered by Barry,1 who described the testing procedure by total immersion of suitable specimens in a I per cent cupric chloride solution at definite temperatures. Effects of dezincification were then determined by loss in tensile strength and elongation of the test specimens after definite periods of immersion. In the crystallography of the chemical elements as tabulated by William Hume Rothery,2 phosphorus (metallic), arsenic, antimony and bismuth are placed in group V-B and the type of crystal lattice for arsenic, antimony and bismuth is given as rhombohedral. The Metals Handbook3 [ ] lists them as "rhombohedral hexagonal," with the additional notation that for arsenic this is the ordinary form at 20°C.; other modifications known or probable at other temperatures. In view of these statements and of the fact that phosphorus, arsenic and antimony are effective in increasing the resistance to dezincification, it was natural to assume that bismuth would act in the same manner. A series of tests was therefore carried out employing the methods described by Barry. Much to our surprise, bismuth did not inhibit dezincification, but rather seemed to accelerate it. Tensile-test speci-

Jan 1, 1942

By Ralph W. Bailey, William B. Price

ARSENIC, antimony and phosphorus are now used in the brass industry as standard inhibitors in preventing dezincification in [ ] condenser tubes. This subject has been thoroughly covered by Barry,1 who described the testing procedure by total immersion of suitable specimens in a I per cent cupric chloride solution at definite temperatures. Effects of dezincification were then determined by loss in tensile strength and elongation of the test specimens after definite periods of immersion. In the crystallography of the chemical elements as tabulated by William Hume-Rothery,2 phosphorus (metallic), arsenic, antimony and bismuth are placed in group V-B and the type of crystal lattice for arsenic, antimony and bismuth is given as rhombohedral. The Metals Handbook3 [ ] lists them as "rhombohedral hexagonal," with the additional notation that for arsenic this is the ordinary form at 20°C.; other modifications known or probable at other temperatures. In view of these statements and of the fact that phosphorus, arsenic and antimony are effective in increasing the resistance to dezincification, it was natural to assume that bismuth would act in the same manner. A series of tests was therefore carried out employing the methods described by Barry. Much to our surprise, bismuth did not inhibit dezincification, but rather seemed to accelerate it. Tensile-test speci-

Jan 1, 1942

By J. A. Herbst, J. L. Sepulveda, J. D. Miller

Effective bismuth removal from flue dust residues has been accomplished for flue dusts from both zinc and copper smelters. Selective dissolution of bismuth, with respect to silver and lead, can be achieved by the proper manipulation of temperature, sulfuric acid addition and sodium chloride addition. Optimum levels of these variables were determined using a response surface technique to maximize the objective function: Y = %Bi/(1 + %Ag). In the case of the flue dust residue from a zinc smelter, which contains bismuth as an impurity (0.05%), 86% bismuth removal can be realized with less than 1% combined silver and lead dissolution. Similarly, in the case of flue dust from a copper smelter, which contains bismuth as a primary constituent (3.3%), 93% bismuth removal was obtained with little dissolution of silver and lead values.

Jan 1, 1977

By J. D. Miller

The processing of residues derived from various operations in the mining and metallurgical industry for by-product recovery is becoming more prevalent. A principal target for by-product recovery is flue dust produced by conventional smelting operations. Flue dust from zinc smelters has been processed for many years for the recovery of cadmium (1,2). The cadmium recovery technique which consists of a selective sulfation roast, followed by a water leach and zinc dust cementation, produces a lead cake residue (see chemical analysis in Table I), which consists primarily of lead sulfate.

Jan 1, 1975

By Toshiki Hayashi, Shoichi Asahina, Kenitsu Hosokura

Sumitomo Metal Mining Co., Ltd.'s Kunitomi Smelter has been treating in the blast furnace copper concentrate containing bismuth. The bismuth is concentrated in the electrostatic precipitator dust and the converter dust. Bismuth contained in the converter dust is leached by a mixture of salt and sulfuric acid, and is then recovered by a cementation process using scrap iron. The bismuth cake thus recovered and the electro- static precipitator dust are reduced to crude bismuth metal which is further refined to a high purity bismuth metal by the pyrometallurgical refining process. Details of this process are elaborated in this report.

Jan 1, 1976

By R. W. Pauls

"Many tens of thousands of hectares of forested land will be disturbed and reclaimed in the surface mineable Athabasca oil sands area during the next few decades. The surface area disturbed by Syncrude’s Mildred Lake development alone exceeds 10 000 ha to date. It is not clear that reforestation of disturbed areas will best accommodate the aspirations of all stakeholders, particularly traditional users of the land. A five-year research program by Syncrude Canada Limited and the Fort McKay First Nations has examined the feasibility of raising bison on land reclaimed after disturbance by oil sands development. Forage productivity and carrying capacity for bison was comparable to that of grasslands elsewhere in Alberta. Concerns regarding compaction of newly rebuilt soil by bison traffic proved unfounded. Bison demonstrated weight gains typical for ranched bison and calving rates averaged 90%, a value typical for ranched bison. The animal husbandry problems encountered were typical of those occurring on bison ranches elsewhere in Alberta. An economic analysis indicates that a 1000 ha bison ranch on reclaimed land has a net present value that compares very favourably with a similar area supporting commercial forest. Subject to approval by Alberta Environmental Protection, the current research project will be expanded as a pilot commercial ranching venture in order to explore its commercial viability as a business venture by the Fort McKay First Nations. At the same time, measures will be implemented to resolve various regulatory issues associated with commercial bison production in the oil sands area.BackgroundSyncrude Canada Ltd. (Syncrude) is proposing, in its land reclamation strategy, a feature that is, depending on one’s background and perspective, regarded as an innovative approach to land reclamation, a threat to the regional forest industry, a creative response to aboriginal stakeholder concerns, a reneging on reclamation commitments, an opportunity to provide an ongoing economic base for postoil sands regional economy, or an environmentally unsound use of the land. These diverse and sometimes strong reactions have been generated by the proposal to introduce bison, either free-ranging or commercial ranched, to the reclaimed landscape."

Jan 1, 1999

By V. B. Achanti, A. W. Khair

This paper deals with the effects of various bit geometric parameters on the failure characteristics of rock material. Improving the rock-cutting efficiency of continuous mining machines has proven to be an interesting research topic during the last few decades. In the current study, an automated rotary rock-cutting simulator, duplicating a continuous miner, was used to study these parameters in the laboratory. The improvement of bit performance in terms of its life, cutting efficiency, dust production and energy consumption has drawn widespread attention. Research has demonstrated that optimizing bit parameters can result in efficient fragmentation of rock. Indiana limestone rock material was used in this study. The bit tip angle, bit tip size, bit spacing, depth of cut and cutting velocity of the rotary drum were varied to investigate the failure characteristics. The cutting pressure, penetrating pressure and the depth of cut were monitored on the simulator during the cutting process. Airborne dust and settled dust were measured for each experiment. Then, the specific airborne dust and specific energy were determined for each type of bit. Triaxial tests were carried out to correlate the failure angle of the rock in the static case to the dynamic cutting process failure. The physical and mechanical properties of the rock were also determined to assess their influence on the wear characteristics of each bit.

Jan 1, 2000

By V. B. Achanti

This paper deals with the effect of various bit geometric parameters on failure characteristics of rock material. Improvement of rock cutting efficiency of continuous mining machines has been an interesting research topic for the last few decades. In the current study, an automated rotary rock cutting simulator, duplicating a continuous miner, was utilized to study these parameters in the laboratory. Improvement of bit performance in terms of its life, cutting efficiency, dust production and energy consumption has drawn wide spread attention over the years. Research shows that optimizing bit parameters can result in efficient fragmentation of rock. Indiana limestone rock material was utilized in this study while bit tip angle, bit tip size, bit spacing, depth of cut and cutting velocity of rotary drum were varied to investigate the failure characteristics. The cutting pressure, penetrating pressure and the depth of cut were monitored on the simulator during the cutting process. Air borne dust and settled dust were measured for each experiment. Then, the specific airborne dust and specific energy were determined for the each type of bit. Triaxial tests were carried out to correlate the failure angle of the rock in static case to dynamic cutting process failure. The physical and mechanical properties of the rock were also determined in order to assess their influence on the wear characteristics of each bit.

Jan 1, 1998

By Wallace W. Roepke

The Bureau of Mines has a well-established health and safety research effort directed to fundamental studies of the mine cutting system. This report describes the ignition danger of using cutting bits with flat wear area on still-intact carbide inserts.

Jan 1, 1983

By M Goers, M Almond

"The use of reverse circulation (RC) drilling for grade control sample collection was selected by the Pueblo Viejo Mine Geology department at the recommencement of the operation in 2010. This method was selected because it allows: for multi-bench drilling (60 m hole depth, four benches of mining) to aid mine planning and provide a detailed close spaced drill data comparison with the reserve model angled drill holes to optimise the drill hole interception of the vertically controlled mineralisation dry sample collection in areas of excessive surface and groundwater mining operations to commence with the long assay return period (due to the need for the samples to be shipped overseas for analysis) until the on-site laboratory is operational.To date, 118 302 m of drilling has been completed throughout the operations of two open pits: Monte Negro and Moore. Two drill rigs (contractor and site-owned and operated) with three generations of sampling systems have been used to date. Throughout the drilling a 20 per cent quality assurance, quality control (QAQC) sample check (blanks, field duplicates and standards) have been used to check the drilling and laboratories performance. In addition, a total of 1104 fines samples were collected to compare the drill chip samples collected and the fines lost with two of the sample systems used.The drilling to date has highlighted the need for a complete and coordinated system to be used before sufficient confidence in the quality of the samples collected is achieved.The complete system must be set-up and coordinated to obtain the best quality sample possible. This complete package includes: drill bit size and shape for the rock being drilled and mineralisation targeted face sampling hammers with the correctly sized hammer shrouds sample hose routing to reduce sample flow turbulence and choking blow-down valves to eliminate drill hole water that has entered the drill string during rod changes correct drilling techniques targeting sample quality a sample system that captures the fines for inclusion into the sample.These improvements can be obtained without reducing the drilling rates.The measurements required to demonstrate the improvement in the sample quality will be the focus of future work within the department.CITATION:Goers, M and Almond, M, 2012. Bit to bag - The importance of a total coordinated system in reverse circulation drilling, in Proceedings Sampling 2012, pp 65-72 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 21, 2012

By A. W. Khair, M. Ahmad, Gehi. L. D.

"This paper presents an analysis of the effect of the dynamics of bit wear on dust generation. Two surveys have been conducted in order to assess the mechanism and type of bit wear and to evaluate the impact of bit wear on the productivity of the continuous miners. Used bits were collected from the underground coal mines and these used bits were utilized in laboratory coal cutting. The effect of bit wear on dust generation has been quantified and its impacted on dust generation and ventilation system has been exemplified.INTRODUCTION Research has reduced the prevalence of Coal Workers Pneumoconiosis from 15 to 5 percent according to NIOSH reports (Breslin 1982). However CWP still have not been eliminated as a hazard to mine workers. To prevent coal workers from having black lung MSHA has established a very strict standard for coal mine operations (2.0 mg/m3 with silica content equal to or less than 0.1 mg/m3,). There are numerous coal operations still experiencing great difficulty with meeting the 2mg/m3 dust standard. Among these are the longwall sections and continuous mining sections. In order to meet the rising demand of energy and coal, the number of longwall operations and continuous mining operations would have to be increased. Thus a long term research commitment is required to develop basic solutions that are more generic and greater benefit to the mining and mineral industry.In continuous-mining operations, the miners are exposed to the dust produced during the fragmentation of the coal from the face plus the dust produced during loading and transferring of the coal. The fragmentation process generates most of the respirable dust. The amount of dust generated during fragmentation depended on the coal properties, cutting parameters and cutting bit configuration. Bit wear changes bit configuration, therefore, it also affects dust generation. Bit wear can be defined as the removal of material from surface as a result of mechanical action. In soft coal mines bit wear may not be a serious problem but in hard coal seams bit wear is very significant. In addition, as the good coal seams are depleted, the operators are mining thin seams and the seams with rock partings. During cutting these seams operators are sometimes forced to cut roof and floor rock or rock partings which result in more rapid wear of bits."

Nov 1, 1995

By L. D. Gehi, A. W. Khair, M. Ahmad

This paper presents an analysis of the effect of the dynamics of bit wear on dust generation. Two surveys have been conducted in order to assess the mechanism and type of bit wear and to evaluate the impact of bit wear on the productivity of the continuous miners. Used bits were collected from the underground coal mines and these used bits were utilized in laboratory coal cutting. The effect of bit wear on dust generation has been quantified and its impacted on dust generation and ventilation system has been exemplified.

Jan 1, 1993

By I. Y. Bausov, L. G. Stolarczyk, R. E. Pillmore, A. J. Hillard, J. T. Duncan

"Prevalence of lung disease in younger miners surprised industry regulators, congressional members, researchers and black lung clinic staff members. Mitigation researcher focused on low-coal mining in the Appalachian regions until Miners Colfax Medical Center (MCMC) Black Lung Clinic examinations discovered 25 of 72 Wyoming coal miners with lung disease. To reverse recent upward trend in lung disease, research programatic have been directed at reducing exposure to respirable “float” dust. This paper suggests broadening the scope of research to include boundary detection in efforts to improve outcomes. Beginning with a better understanding of biochemistry of anaerobic bacteria methylation processes precipitating sulfur and heavy metals into thin seam boundary layers. Expanding research and development objective to focused on minimization of bit-pick crushing cone volume and preventing mining thin boundary coal layers and out-of-seam dilution. Black lung clinical evaluations of miner will confirm outcomes directed towards reduced occupational disease and smoke stack emissions. INTRODUCTION Miner exposer to bit-tip crushing cone volume, fragmentation and auger movement generated respirable “float” dust and boiler emissions are related science-technology –engineering-mathematics (STEM) problems. Formidable but not intractable problems are driven by oxidation of upper flood plain elements in the periodic table and biochemical metabolic presses occurring in coal basin. Because of burial compaction, quartz and trace heavy metals (Fe2+, Mg2+) are concentrated in thin seam boundary layers. By not cutting through thin boundary coal layer and out-of-seam into hard quartz containing rock layers, miner lung disease and smoke stack emissions are minimized. Cutting bit-pick elastic wave hydrodynamic principle force vectors in the coal layer must be aligned to minimize respirable dust generation, constrained by fragmentation size. Dust abatement by water spray and machine design are effective; but for, failure to address cutting cone dust volume generation and its distribution along run-of-mine (ROM) transportation systems the boiler. Real-time precision thickness measurements by integrated cutting drum (icDrum) sensor, machine man-interdiction from a dust free control room, is a cost effective way to prevents respirable dust exposure. The recommended STEM research and demonstration initiative addresses issues raised by discoveries of increased rate of lung disease discovered in young miners and concerns over emissions from coal-fired electric generation stations (Global Warming). In-mine demonstrations must be validated by on-site MCMC mobile Black Lung Clinic data acquisition and analysis."

Jan 1, 2016

By W. Gibson Jaworek

It has become apparent in recent years to everyone intimately concerned with the future of the American fuels industries that the growth in demand for energy has become a topic receiving considerable attention, and that investigators are leaning more and more toward a mathematical approach to deduce what pattern that growth will follow. Though coal has been included by necessity In all-studies of future energy markets, it has not been the subject of mathematical analysis or description as frequently as has been total energy or some of the other fuels, particularly petroleum, It is the intent in this particular paper, to subject bituminous coal consumption to a preliminary mathematical scrutiny which can lead to a more logical estimation of the general level of bituminous coal consumption for the next decade, as well as formulating an approach toward describing how coal consumption may vary as the result of the annual variations in activity in the United States, economy, The approach utilized is more sophisticated than the mere projection of the historical trend of bituminous coal consumption. Such a projection would lead to a continuation of the recent decline, indicating that coal consumption would reach zero some thirty years from now. On the other hand, the mathematical analysis described here is a relatively simple, straightforward approach and- is not intended to represent the-ultimate in mathematical economic analysis as now practiced, It is hoped that this will contribute to our knowledge of bituminous coal markets. Even more, it is hoped that it will help arouse a greater interestin utilizing mathematical and statistical analysis when studying the bituminous coal industry. - Since this is a preliminary study, comments and criticisms are anticipated.

Jan 1, 1960

By John A. L. Campbell

Surface dependent processes, such as froth flotation and flocculation, are important or potentially important techniques for combating some of the current major problems in coal preparation. In order to correctly apply or imporve a surface dependent process, it is of paramount importance to understand the interfacial phenomenon, especially the double layer properties, exhibited by the solid. The specific objective of this research was to determine the properties of the bituminous coal/liquid interface by an electrokinetic method, streaming potential, and to relate the findings, wherever possible, to the existing unit operations of froth flotation and flocculation. The electrokinetic properties of both the whole coal and its lithotypes were investigated. As part of the total investigation, the role played in the double layer by the reagents commonly employed in the surface dependent process was also established (1). These data will be presented at a latter date.

Jan 1, 1969

By Theodore Nagel

Fuel-oil, natural gas and coke oven gas, producing the higher temperatures of open-hearth current practice, have been gradually displacing producer gas the lowest cost fuel for open hearth operations. The lower temperatures of combustion products from producer gas is caused by nitrogen dilution. Practical Application of Combustion Thermochemistry One pound of carbon burned to CO produces 3,960 B.T.U. and one pound of carbon burned to C02 produces 14,140 B.T.U. The second unit of oxygen uniting-with gasified car-bon (-CO) produces (14,140 - 3,960) 10,180 B.T.U. which is;(10,180 - 3,960) 6,220 B.T.U. more heat than produced by the first, unit of oxygen forming CO by uniting with solid carbon. A review of the relative combustion heating values of commercial gaseous fuels reveals CO requires a minimum of air for combustion, and because of minimum nitrogen dilution and the high thermal release from CO higher temperature combustion products are produced from CO than from natural gas or from coke-oven gas under similar combustion conditions. Inert nitrogen diluent lowers the calorific value of fuel gas and its diluting effect is cumulative in lowering the temperature of the products of total, combustion. It is not only logical but, practical in partial combustion, converting bituminous coal to gas, to generate the gas, with reduced nitrogen dilution.

Jan 1, 1936

By Theodore Nagel

Fuel-oil, natural gas and coke oven gas, producing the higher temperatures of open-hearth current practice, have been gradually displacing producer gas the lowest cost fuel for open hearth operations. The lower temperatures of combusts on products from producer gas is caused by nitrogen dilution. Practical Application of Combustion Thermochemistry One pound of carbon burned to CO produces 3,960 B.T.U. and one pound of carbon burned to C02 produces 14,140 B.T.U. The second unit of oxygen uniting with gasified carbon (CO) produces (14,140 - 3,960) 10,180 B.T.U. which is (10,180 - 3,960) 6,220 B.T.U. more heat than produced by the first unit of oxygen forming CO by uniting with solid carbon. A review of the relative combustion heating values of commercial gaseous fuels reveals CO requires a minimum of air for combustion and because of minimum nitrogen dilution and the high thermal release from CO higher temperature combustion products are produced from CO than from natural gas or from coke-oven gas under similar combustion conditions. Inert nitrogen diluent lowers the calorific value of fuel gas and its diluting effect is cumulative in lowering the temperature of the products of total combustion. It is not only logical but practical in partial combustion, converting bituminous coal to gas, to generate the gas with reduced nitrogen dilution.

Jan 1, 1936

By D. P. Morton

SINCE 1023, which closed the speculative era in the bituminous coal fields of the United States, there have been wide annual fluctuations in the national production of bituminous coal. These changes in annual output have been variously attributed to: (I) increased competition from petroleum products, natural gas and hydroelectric power; (2) lower unit consumption of coal; and (3) fluctuations in the general business level. The purpose of this paper is to measure, from a practical standpoint, the net effect upon the annual trend of bituminous coal production, and to give those who are interested a basis for estimating in advance the probable output of bituminous coal. It can readily be shown that changes in the level of general business affect the national production of bituminous coal more than does any other factor. Therefore it is necessary to use some standard measure of the relative business level for purposes of comparison. The Federal Reserve Board Index of Industrial Production offers the basis for such a measure.' This Index, a weighted composite of 81 different series, rests upon the averages of the years 1935 to 1939 as loo, and is presented graphically in Fig. I. Even a cursory examination of the chart will indicate a definite uptrend for industrial production over a period of years. This uptrend is due to at least two factors: (I) an actual increase in national population, and (2) a probable increase in the per capita consumption of goods. This means that there is no such thing as a fixed Normal, rather Normal is a variable, tending to increase from year to year. In order to measure the amount of annual increase in normal, the Index of Industrial Production must be studied in relation to its major components, Durable Goods and Nondurable Goods. Durable Goods are those made from the lasting materials such as iron, steel, other metals, lumber, stone, cement, clay, glass. Nondurable Goods are those for early consumption, such as foods, textiles, tobacco, chemicals, paper, gasoline, and goods made of leather and rubber. The purchase of Durable Goods may be postponed, but Nondurable Goods must be purchased currently unless the standard of living is lowered. The Federal Reserve Indexes of durable and nondurable goods are shown graphically, 1920 to 1939, on Fig. 2 (pp. 764-765 of ref. I). It is apparent that fluctuations in the production of nondurable goods are not nearly so wide as in the production of durable goods, and that the curve of Industrial Production (Fig. I) would fall between the two curves on Fig. 2. It would, however, seem logical that both curves should follow the same long-term trend, or that over a period of two to three decades the relative proportion of durable and nondurable goods, in periods of normal production, should he the same. It is neces-

Jan 1, 1941

By A. W. Gauger

WITHOUT QUESTION the Commonwealth of Pennsylvania contains the most remarkable coal deposits of the whole world. Within its borders ,are to be found excellent coals ranging in rank from the high volatile bituminous of the western part of 'the state through the low volatile or semi-bituminous of central Pennsylvania to that aristocrat of solid fuels, anthracite, found in the East. . . . But while other states and even the Federa1 Government have recognized the needs of the coal industry, Pennsylvania has not. Though bituminous coal represents one of the most important industries in the state, far more important in annual productive wealth than agriculture, for example, hundreds, of thousands of dollars have been spent on agricultural research whereas little or nothing has been spent on coal investigation.

Jan 1, 1932

By R McIlwraith, B Breul

"This paper discusses the successful use of bituminous geomembranes (BGMs) in mining applications since their development in 1974. It explains and illustrates the structure of a BGM composite, which is a geomembrane manufactured by impregnating a polyester geotextile with a compound of bitumen, elastomer and filler. Examples of applications of BGMs in the mining industry are also presented in the following contexts.Storage of solid waste: storage of mining waste at mines in Canada heap leach pads in France, Peru, Chile and Turkey at the base of a mining waste landfill in Brazil capping of solid mining waste in Chile and Canada temporary capping of mining stockpiles in Australia (with possible reuse of the BGM for other works).Examples of the application of BGMs for the storage of liquid waste in mining containment reservoirs in Canada, Guatemala and Peru will also be given.For each example given, reasons are supplied that supported the choice of BGMs by the clients and consultants, drawn from the following advantages of the BGM:BGMs have excellent puncture strength, due to the internal polyester reinforcement, as well as excellent ultraviolet resistance. This often eliminates the need for a cushion geotextile or cover soil over the BGM.BGMs have a very long life expectancy, in excess of 300 years, in subsoil conditions (Breul et al, 2004).BGMs can be installed in very harsh climatic conditions. They are suitable for high wind environments as their heavy mass per square metre makes them resistant to wind uplift. The low coefficient of thermal expansion means that BGMs are suitable for installation in mines where very low or very high temperatures are expected. This reduces construction delays and allows for a quicker use of the mining facility.The fact that the BGM can be installed by the mine’s own workforce, after appropriate training from the BGM manufacturer, allows for a more flexible construction sequence on the mine.Ability of the BGM to connect to other materials such as concrete, steel, rock and other geomembranes that may be on the mine site.The technical advantages of a BGM enabled the engineering consultants to prepare solutions for their mining clients that had a lower environmental risk, had a faster completion schedule and were overall a cheaper option than with a polymeric geomembrane.CITATION:Breul, B and McIlwraith, R, 2015. Bituminous geomembranes in mine construction, in Proceedings Tailings and Mine Waste Management for the 21st Century, pp 289–296 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jul 27, 2015