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By X. Meng

A kinetic model for batch leaching of various metals with different lixiviants has been developed. Overall material balances for reactants and products at the solid/liquid interface were formulated with various types of heterogeneous reactions in place at the interface. The solutions to these mass balances have been identified analytically as well as numerically using a Runge-Kutta method. Applications of these numerical solutions to various leaching systems using the rotating disc or powders have been discussed. Examples of the metal dissolution systems considered in this study include cobalt, nickel, copper and gold in acid, cyanide or ammoniacal solutions.

Jan 1, 1994

By Hanguang Wu, V. Izaxon, Sukumar Bandopadhyay

This paper presents an analysis of the heat transfer process between the mine ventilation air and the frozen rockmass. The heat transfer model takes into account not only by the mutual change in air and rockmass temperatures, but also by the phase change of ice-water- ice. Based on the analysis presented here it is concluded that the mine thermal regime can be regulated by having the air enter the mine through mined-out excavations or development airways.

Jan 1, 1995

By Chester R. Harris

With the passage of the Occupational Safety and Health Act (OSHA) on December 29, 1970 and the formation and growth of the OSHA Agency it spawned, public consciousness of occupational safety was raised. It became accepted that employees had the right to "a safe and healthful workplace". With the possibility of OSHA inspections, employ ers (particularly those with large workforces) began to give serious con sideration to engineering controls, safety programs, and training in a more uniform manner than previously.

Jan 1, 1991

By R. Spears, J. B. Vincent, S. Donald, J. Litaker

Previous efforts to remove and concentrate heavy-metal ions from wastewater streams via metalloprotein affinity metal chromatography (MAMC) were limited to the metal transport protein transferrin. Extension of the technique to the enzymes carbonic anhydrase and carboxypeptidase A, which possess different metal affinity properties, is described. Preliminary results indicate that the technique is capable of selectively removing and separating late first-row transition metal ions from aqueous solution. The results suggest that by properly choosing the matrix, i.e., protein or enzyme, MAMC may he applicable to problems involving a wide range of heavy-metal-hearing aqueous solutions.

Jan 1, 1996

By F. J. Susko

The US Bureau of Mines is using Fourier-transform infrared (FT-IR) analysis to investigate the bonding mechanisrn that occurs during the dewatering of clay slurries. High-molecular-weight polymers are used as flocculating agents in these processes. This investigation presents the results of an FT-!R study of calcium-exchanged montmorillonite treated with polyacrylamide (PAM) and polyethylene oxide (PEO). Both thin film and attenuated total reflectance (ATR) spectroscopic techniques were employed to study this clay polymer system. Results suggest PAM is adsorbed to the clay via the nitrogen atom of the polymer. A waterbridge is involved in the bonding between the clay at d PEO. Evidence also suggests that PEO may be adsorbed directly onto the surface of the clay.

Jan 1, 1991

By Leonard A. Eros

In many mining applications it is not practical to use gravity takeups. In these situations hydraulic takeups are often utilized. Performance specifications are often compromised by designs which have inherently high internal friction and inefficient hydraulic designs. This results in performance which does not match the requirements of the conveyor system. A computer model has been built to check unit efficiencies and field measurements have been taken which verify the results.

Jan 1, 1993

By S. K. Kawatra, A. K. Bakshi

An on-line rheometer was developed to monitor the slurry rheology of a thickener underflow. The thickener processed a chalcopyrite flotation concentrate having a top particle size of 125 µm and a solids content of 30% to 60% (by weight). The slurry also contained residual flotation reagents, resulting in hydrophobic particles. Polymeric flocculants and lime were added to the thickener to flocculate the particles. Using the on-line rheometer, the slurry was found to exhibit pseudoplastic behavior with no yield value. It was also determined that factors other than the percent solids were responsible for changes in the slurry rheology.

Jan 1, 1999

By Shaoxian Song, Shouci Lu, Jingyon Gou, Pan Yiuwen

The calculated potential energies of interaction between hydrophobic particle of three minerals (rhodochrosite, quartz and talc) and air bubble show that the energy of hydrophobic interaction is the dominant factor for their attachment. An attachment rate equation, integrating particle -bubble collision and adhesion by introducing a "capture efficiency", has been put forward. It was found that the hydrophobic particle-bubble aggregates can not be disconnected in the bulk zone of flotation cell, whereas in the impeller zone the breakup may occur, particularly for the coarser particles captured by bubble. Finally, the flotation rate constant was estimated theoretically and verified by experiments.

Jan 1, 1995

By P. L. Webster, S. D. Thompson

The Coal Mine Belt Capacity Simulator (CMBCS) was originally developed to provide an improved belt capacity simulation through more detailed, flexible and realistic modeling of belt loading. While this model offered improved capacity design for conveyor belts and surge bins, it lacked the capability to simulate some key protection and segregation applications for bunkers. Recently, CMBCS was extended so that these latter bunker applications could be considered. In addition, a fear minor extensions were made to improve the model's flexibility and of efficiency. These various extensions and the steps taken to verify and validate them are described. The associated modifications in the model's input and output as well as the model's current requirements and availability are also discussed.

Jan 1, 1992

By K. Kim, T. M. Yegulalp

A numerical model is being developed to assess the enhancement of ore permeability by improving fracture connectivity with micro-hydrofracturing. As part of this project, a generic two-dimensional percolation model was developed to test the impact of various field conditions on permeability. Field data from Cyprus Minerals' Mineral Park mine was used to establish the statistical properties of the observed fracture systems. Results of statistical analyses of field data and examples of the use of the percolation model are presented

Jan 1, 1997

By Jeffrey C. Reid

Computer processing and high resolution graphics display of geochemical data were used to quickly, accurately, and efficiently obtain impor¬tant decision-making information for tin (cassiterite) exploration, Seward Peninsula, Alaska (USA). Primary geochemical dispersion patterns were determined for tin-bearing intrusive granite phases of Late Cretaceous age with exploration bedrock lithogeochemistry at the Kougarok tin prospect. Expensive diamond drilling footage was required to reach exploration objectives. Recogni¬tion of element distribution and dispersion patterns was useful in subsurface interpretation and correla¬tion, and to aid location of other holes. Tin was its own best pathfinder. Arsenic, also a useful pathfinder element, forms a discrete halo peripheral to tin mineralization. The arsenic halo is expressed in hand specimens by asenopyrite and/or scorodite staining.

Jan 1, 1989

By P. Somasundaran, T. Chen, Diptabhas Sarkar

We have developed a layer-by-layer deposition technique for preparation of nanocomposite particles. Using this process, it was possible to make nanocomposites of various oxides with desired local composition and microstructure. The attachment of the shell particles to core particles was achieved using controlled polymer adsorption. Removal of excess polymer was accomplished without detaching the pre-adsorbed polymers by a specific stepwise washing scheme. The inherent chemistry of the process makes it easy to incorporate functional fillers over core particles. The nanosized filler materials will replace the shell particles in the present process and the polymer bridge would be chosen by taking into consideration the respective surface chemistries of various shell and core particles.

Jan 1, 2003

By J. Andrew Leach, Robert T. Tape, Thomas G. Harper

A practical approach to elope stability design of heap leaches up to 90 m (300 ft) high is presented based on recent experiences with heaps throughout the Western U.S. Shear strength parameters for foundations, ore and liner systems are considered, with particular attention given to frictional contacts between geomembranes and clay or geotextiles. Stability of both ore and containment dikes is discussed including the effects of seismicity, staged dike construction, progressive heap development and in-heap solution levels. Design criteria and methods of analyses are presented along with techniques for improving stability.

Jan 1, 1987

By W. H. B. Blackburn, D. M. S. Bhatia

Twenty-six in situ analyses of cubic galena crystals from a Mississippi Valley-type deposit were undertaken with a laser microprobe emission spectrograph to study the variation of nine trace elements from the crystal center to its periphery, both along the diagonal and vertical. The general trend is an outward increase in the concentrations of Ag, Ga, Ge and In, with As showing the opposite trend. Bi, Cd and Sn showed no discernable trends. Sb was not detected. These variation patterns may serve as a model for similar studies of other Mississippi Valley-type deposits.

Jan 1, 1987

By Joseph Cervik

Methane drainage methods can be broadly classified as surface or underground. Surface methods make use of vertical and slant holes. The underground method discussed in the present paper involves horizontal drilling from shaft bottoms and from locations along the periphery of mines. Every foot of hole drilled in coal from under- ground locations is productive and gas flows increase as hole length increases. Therefore, underground techniques have a great potential for producing large-volume flows of methane. Pumps to dewater the horizontal holes are not necessary because gas pressure forces the water out of the hole. Methane can be recovered through the use of a simple and inexpensive gas-water separator. Hydraulic fracturing, which has been used successfully to stimulate gas flows from vertical holes, has not proved practical in the case of horizontal holes.

Jan 1, 1980

By J. Hanna, J. Jung

Researchers at The University of Alabama have recently developed a two-step method for the treatment of phosphorus sludge. The process includes the bulk removal of phosphorus by physical separation techniques followed by the remediation of the residual P4 in the sludge using a novel, wet, air-oxidation technique known as "HSAD." Tests made on electric furnace, phosphorus sludge samples have demonstrated that an essentially complete and fast removal of the contained P4 can be achieved by the HSAD wet oxidation treatment. Further studies were made to determine the applicability of the two-step process to sludges of different origins, pretreatments, storage conditions and P4 contents. The present work discusses the mechanisms and factors controlling the HSAD, wet, air-oxidation remediation approach.

Jan 1, 1993

By T. M. Sukel

Engelhard Corporation is one of the leading producers of kaolin based products in the world, having acquired the assets of Freeport Kaolin company in 1985. Much of the production technology used in the kaolin industry was pioneered by Engelhard and Freeport, including Ultraflotation for improving product brightness, delamination to produce kaolin platelet products, calcination to produce ANSILEX® high opacity titanium dioxide pigment extender and pipeline slurry operations to economically transport kaolin from the mine to beneficiation facilities. Engelhard traces its roots back to 1870 when the Edgar family discovered kaolin behind their property in Bonhamtown, New Jersey. Today the company produces the broadest line of premium coating pigments with extensive sales throughout the world. The international scope of the company's business has led Engelhard to evaluate kaolin deposits throughout the world as possible grass roots production sites. Most kaolin products are used in the paper industry -- the largest volume end-user 80% of the total market -- as filler and coating pigments. Lower volume specialized applications include fillers and reinforcements for plastics and TiO2 extender pigments for paints and coatings.

Jan 1, 1987

By Q. Lin, D. Z. Wang

Molecular design plays an important role in development of new flotation reagents. Group electronegativity calculation is a main method of molecular design. It is commonly used in calculating the hydrophilic-hydrophobic balance of reagents, particularly in designing chain length of flotation reagents for located minerals. But there is a limit to group electronegativity method. The method can only apply to those of [Ø]known straight-chain compounds ([Ø] is the hydrophobic energy of each -CH2- , determined by experiment). In this Paper, we propose another new calculation method: fragment method of flotation reagent. The method could be used as a supplement of group electronegativity method to design and calculate flotation reagents without any limitation. With the fragment method, we can calculate the hydrophilic-hydrophobic performance of any known or unknown reagents including those complicate structure compounds such as cyclic, branch, heterocyclic and so on by summing the appropriate structural elements (fragment). The principle, calculation stages and some results of designing new-type flotation reagents by fragment method are presented in this paper.

Jan 1, 1995

The objective of the fines flotation step in a coal preparation plant is to maximize coal recovery subject to a constraint on the allowable ash in the concentrate. The objective is achieved when the incremental ash is driven to a target value determined by an economic constraint. In this paper, a phenomenological flotation model and ash analyzer combination are identified that allow the development of a soft sensor for incremental ash and subsequently a model-based strategy which manipulates key flotation variables to achieve the control objective. A combination of plant tests and computer simulations are presented to evaluate control-system performance in one operation.

Jan 1, 1999

By J. L. Hendrix, M. Ahmadiantehrani, G. Ramadorai

The concept of hypochlorite treatment prior to cyanidation in the heap leaching of low grade carbonaceous gold ores is discussed. Laboratory column leach tests using a low grade carbonaceous ore were performed to investigate the effects of pH, hypochlorite consumption and concentration, and bed height on total gold extraction. At high pH, hypochlorite stability increases and thus, hypochlorite consumption decreases. At room temperature, total gold extraction is proportional to hypochlorite consumption. However, at some point additional hypochlorite consumption does not increase gold extraction. Gold recoveries of 10% and 80% are achieved at 12 and 167 lb/ton hypochlorite consumption, respectively. Increasing hypochlorite concentration increases the rate of extraction. For a given hypochlorite consumption, gold extraction increased with decreasing ore bed height. Finally, using calcium hypochlorite results in higher gold extraction than using sodium hypochlorite at a fixed hypochlorite consumption.

Jan 1, 1992