Search Documents

By E. A. Sondreal

The Bureau of Mines investigated the use of lignite char for producing carbon disulfide; CS2 production rates were as high as when wood charcoal was used as raw material. The maximum space velocity for CS2 produced in the bench-scale study was 9,280 hour-1, reacting sulfur and lignite char at 792° C. The reaction temperature and the temperature at which the char was carbonized were the two most important factors in determining CS2 production rates. Increasing the carbonization temperature in nitrogen from 400° to 900° C advanced the temperature at which carbon disulfide was first produced from 550° to 850° C. The average activation energy for reacting chars with sulfur was 44,000 cal/g mole. The reaction was first order with respect to the partial pressure of sulfur. Increasing the rate of sulfur admission caused a decrease in rate of production at otherwise similar conditions. Rates were not affected by either char size or sodium carbonate catalysis. High space velocities at moderate temperatures using inexpensive lignite chars could offer an economic advantage in the manufacture of carbon disulfide provided that yields were attractive.

Jan 1, 1967

By Lindsly. Ben E.

"The recovery or partial recovery of the oil remaining in oil sands after the usual methods of production have become unprofitable is perhaps the greatest problem in the petroleum industry today. The amount of this oil remaining in the sand is variously estimated by those familiar with the subject to be 25 to 90 per cent of the original content.2Lewis3 states, ""The estimate of 80 to 90 per cent of the oil left underground does not seem incredible.""It is estimated by the writer that approximately 91 per cent of the oil originally held in the Elliott pool, was still in the formation on January 1, 1924, and that it would take at least 12 years, at the 1923 rate of production, to further reduce this quantity by one per cent of the original content.The progress made in the oil industry during the past few years relative to the prevention of evaporation losses; to improvement in cracking processes, whereby the gasoline yield from many crudes has been doubled and trebled; to the increased recovery of gasoline from natural gas; and many other developments, remarkable as they are, can be applied only to that comparatively small portion of petroleum products which are raised to the surface. A device or process which would cut development costs to one-half would probably result in a much smaller profit to the oil industry, than the profit derived from an additional 10 per cent recovery of the total amount of oil in a pool. Various methods have been used and many others proposed, for the increase of oil recovery from normally depleted sands.In France, oil sands are being mined by means of shafts and galleries. In other places, notably the Bradford, Pennsylvania field, the yield has been increased by means of water flooding, wherein water is introduced into the sand to displace oil, and drive it to producing wells."

Oct 1, 1926

By Wesley T. Holmes II, Lloyd H. Banning

Electric - smelting studies were made on titaniferous materials obtained from the Klukwan and Snettisham , Alaska ; Choteau , Mont .; and Iron Mountain , Wyo . , deposits with the objective of determining the feasibility of producing pig iron and an enriched titania slag in one test series and pig iron alone in another test series . In addition , related studies were conducted to determine the amenability of Choteau crude ore to wet -magnetic separation and to determine the quality of steel that could be produced from the titaniferous pig iron . The continuous smelting tests were made in a three - phase , submerged - arc , electric furnace , and the laboratory steelmaking tests were made in a singlephase electric - arc furnace . A continuous , belt - type , wet - magnetic separator was used in conjunction with a ball mill and a spiral classifier in recovering titaniferous magnetite from the crude Choteau ore . Pig irons containing less than 0.05 percent phosphorus or sulfur were readily produced from the titaniferous materials ; iron recoveries ranged from 92 to 98 percent . The Choteau ore was ground to minus 65 - mesh to produce a concentrate containing 60 percent or more iron . The steel produced from the titaniferous pig iron was a high - quality product .

Jan 1, 1964

By W. H. Coghill, B. W. Gandrud, F. D. DeVaney

"The self-fluxing iron ores of Alabama are the foundation of the thriving iron and steel industry of that State. In addition to these deposits of self fluxing ores there are seams containing practically the same percentages of iron but too much silica. These ores at present are valueless, but if they could be concentrated by reducing the silica content, the ore reserves of the Birmingham district would be greatly augmented. A detailed report on the iron-ore deposits of the district, describing the types of ore and their extent, has been published.In forwarding its mineral conservation policies the United States Bureau of Mines has given some attention to the siliceous ores of this district.The low cost of gravity concentration gives this process first rank in the beneficiation of iron ores. For this reason many experimenters have tried to concentrate the Alabama iron ores on tables. In the face of the early failures a new trial has been made and the results have justified the effort.In this work more attention than formerly has been given to the physical, properties of the ores. The removable siliceous gangue is in the form of oolitic grains which ""shell"" out like corn, leaving the hematite as rich high-grade ""slime"" and as clean granular grains. The ""slime concentrate"" may be recovered by well known desliming processes. The oolitic grains and granular hematite are separated on tables."

May 1, 1929

"D bed, Ky., coaL, washing characteristics RII 5140coking coal, reserves, estimate RI 5037Pa., coal, washing characteristics RI 4834, 4941D bed mine, Ky., coal, washig characteristics"

Jan 1, 1960

By T. H. Jeffers

Significant amounts of cobalt are present in readily accessible spent copper leach solutions. The Bureau of Mines investigated the feasibility of extracting cobalt from these solutions in a multiple-compartment ion-exchange (MCIX) column. The effects of aqueous flow rate, resin flow rate, column height, and compartment height on cobalt extraction were determined. Cobalt extractions of 92 pct or higher were achieved at solution flow rates of up to 5.5 gpm/ft of column cross-sectional area and an aqueous-to-resin flow ratio of 40:1. Overall cobalt extraction increased as the column height increased, but cobalt extraction per unit of length was more efficient in 8-and 12-ftco1umns than in an 18-ft column. Solvent extraction procedures were utilized to purify and concentrate the MCIX column eluates and produce a cobalt sulfate solution containing 70 to 80 giL Co. Metallic cathodes containing over 99 pct Co were e1ectrowon from this solution. Zinc, nickel, and copper byproducts were also recovered during processing of the ion-exchange eluates. Estimated total capital cost for a commercial-scale 10,000 gpm of a spent leach solution containing 26 million. With credits for zinc, nickel, and copper estimated net operating cost was $9.36/lb Co.

Jan 1, 1987

By M. L. Wang, S. R. Short, E. M. Daniloff, E. L. Petsonk, D. M. Mannino, G .. R. Wagner

"Background—It has been suggested that health related job selection is a major cause of the healthy worker effect, and may result in inaccurate estimates of health risks of exposures in the working environment. Improved understanding of self selection, including the role of airway hyperresponsiveness, should improve accuracy in estimating occupational risks.Methods—We evaluated symptoms of the respiratory tract, lung function, occupa¬tional and smoking histories, and airway responsiveness from a cross sectional sur¬vey of 478 underground bituminous coal miners and non-mining controls. Workers with abnormal spirometry were excluded from methacholine testing.Results—Methacholine responsiveness (= 15% decline in forced expiratory volume in one second) was associated in both miners and controls with reduced ventilatory lung function and an increased risk of respiratory symptoms. Miners with the longest duration of work at the coal face had a low prevalence of methacholine responsiveness, compared with miners who had never worked at the coal face (12% v 39%, P < 0.01). Throughout their mining careers, miners who responded to methacholine were consistently less likely to have worked in dusty jobs than miners who did not respond to methacholine.Conclusions—These results provide evidence that workers who are employed in dusty jobs are less likely than their unexposed coworkers to show increased non-specific airway responsiveness, pre-sumably as a result of health related job selection. Surveys of workers in which responsiveness data are unavailable may underestimate the effects of dust exposure on respiratory health."

Dec 1, 1996

By F. S. Crawford

Companies which have been engaged in safety work for a number of years are becoming increasingly aware of the fact that it is not enough to supply guards for various pieces of machinery and equipment and to supply safety inspection to see that rules are being carried out. Studies of many safety organizations have demonstrated that the accidents which could have been prevented by proper guards constitute only a small percentage of the total acci- dents, and amount to perhaps not more than 15 per cent. Evidently, if success is to be attained in preventing all accidents which it is humanly possible to prevent, a company must have the cooperation of every employee. Mining particularly presents probably the greatest hazards of any industry. Prevention of accidents. is made increasingly difficult because men often work alone, although generally in pairs, and only in the concentrated systems of mining do they usually work in groups of more than three or four. Supervision is difficult, therefore, and much reliance must be placed upon the individual workmen. In mining, as perhaps in no other occupation, it is of the greatest importance that individual workmen should receive continuous safety education. Within the last few years safety education has come to the front as one of the most important of accident-prevention measures, although it is true that its importance has been repeatedly stressed by the United States Bureau of Mines and other national safety organizations since the inception of the safety movement many years ago. A review of the safety educational methods of some companies in the Lake Superior district should be of interest. Perhaps better methods are in use in other parts of the country, but the methods shown have been instrumental in many cases in reducing the number of accidents. In one mine in the district whose methods are described the frequency of accidents has been reduced to zero within the last two years. A number of other mines in the district have recently gone into the class having no lost-time accidents for considerable periods of time. One company in the Lake Superior region, operating over 30 mines, succeeded during one month of 1930 in operating every mine without having a single accident which caused lost time beyond the day of the injury. Records like these are increasing in number, and while it is believed that they are the combined result of different means of safety activity, it is undoubtedly true that many of these results were obtained through safety educational methods.

Sep 1, 1931

By H. J. Heinen

A technique offering promise as a metallurgical processing sequence the recovery of molybdenum (Mo) from the sulfide mineral--molybdenite?was investigated. The method consists of two steps: (1) electrosynthesis of pure dimolybdenum carbide (Mo2C) from molybdenite (MoS2) and (2) interaction of Mo2C and molybdic oxide (MoO3) to produce pure molybdenum metal. Two molten salt systems were satisfactory for electrosynthesizing Mo2C. The first was a mixture of potassium chloride (KCl), potassium fluoride (KY), and sodium metasilicate (Na2SiO3), and the second consisted of sodium fluoride (NaF), KF, sodium tetraborate (Na2B4O7), and sodium carbonate (Na2CO3). Yields up to 0.42 gram of Mo2C per ampere-hour were obtained. The carbide, mixed with monitored amounts of MoO3, was converted to molybdenum metal of 99.9 percent purity by sintering at 1,500° C.

Jan 1, 1965

By Edward L. McHugh

Twelve properties in the Riverside Mountains have moderate to high potential, for silver, gold, copper, and molybdenum. Six properties in the Big Maria Mountains have moderate potential for zinc, lead, copper, silver, iron ore, and limestone. The Big Maria Mountains also have occurrences of building stone. Four properties in or near the study area have low-grade gold-silver-copper resources totalling more than 300 thousand tons (270,000 t). An estimated 29 million tons (26 million t) of limestone and dolomite, and 620,000 long tons (630,000 t) of iron ore are in the Big Maria Mountains section of the study area. INTRODUCTION The Big Maria Mountains Wilderness Study Area covers about 50,538 acres (20,453 ha) near the Colorado River in eastern Riverside County, California (fig. 1). The study includes portions of both the Big Maria and Riverside Mountains. It lies north of Blythe, California and south of California Highway 62 in the Mojave Desert province of the California Desert Conservation Area. The study area consists of two mountain ranges surrounded mostly by broad alluvial slopes or bajadas. It extends for 25 mi (40 km) from the Riverside Mountains on the north, to the south end of the elongate Big Maria Mountains.

Jan 1, 1982

By Daryl R. Tweeton

The Bureau of Mines conducted experiments to measure the influence of environment on the friction and wear of a steel-quartz system at several speeds and loads. In each test a quartz block was pressed against a rotating ring of low-carbon steel. Environments used were moist air, dry air, dry nitrogen, water, aqueous oleylarnmonium acetate (ClsH35NH3+-OCOCH3), and aqueous aluminum chloride (A1C13). The sliding speeds were 2.2, 13, and 33, cm/sec, and the loads were 6.8 and 13.6 kg. The coefficient of friction, the wear, and the roughness of the surfaces were measured, and the wear debris was examined. The coefficient of friction was significantly lower in moist air at 2.2 cm/sec than for any other combination of environment and speed employed, and was generally an inverse function of the oxidizing ability of the environment. The coefficient of friction increased somewhat with increasing load. The wear of the steel rings was greatest in dry air at all speeds and loads. The wear of the quartz blocks at 180 rpm was greatest in dry air, but at 12 rpm it was greatest in nitrogen. Friction and wear in aqueous oleylarnmonium acetate and in aqueous aluminum chloride were similar to effect in water alone.

Jan 1, 1976

By Donald E. Redmon

This Bureau of Mines report examines the injury experience in the quarrying industry for the years 1964-65. Twenty-eight tables for each year are presented in which disabling work injuries are summarized by department, source of injury, extent of disability, part of body injured, and nature of injury. Correlative information on employment, worktime, and operating activity is also presented.

Jan 1, 1973

By James V. Kelly

"INTRODUCTION In the course of Bureau of Mines investigations of iron ores near Scappoose, Columbia County, Oreg. during 1942, occurrences of laterite were noted in road cuts and outcrops at many localities in the county. In 1944, the State of Oregon Department of Geology and Mineral Industries completed a preliminary examination of alumina-iron-bearing laterite occurrences in Washington County north of Hillsboro, Oreg.3/ Their report suggested that the lateritic material might be amenable to treatment by the Pederson process for the commercial production of iron and alumina. In order to determine the extent and character of some of the reported lateritic occurrences, the Bureau conducted preliminary explorations in Columbia County near St. Helens, Oreg., from January through June 1945. Almost simultaneously the Alcoa Mining Co. began to explore nearby areas. Their work was continued and expanded after the Bureau's work had been discontinued. This report presents the data obtained from the exploratory work of the Bureau of Mines.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral re¬sources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, O. C. Ralston, chief, analyzes samples and performs beneficiation tests.Samples were assayed at the Reno, Nev., laboratories of the Bureau of Mines under the supervision of A. C. Rice, acting supervising engineer, and at the Albany, Oreg., laboratories under the supervision of Dr. B. A. Rogers, chief, Albany Division, Metallurgical Branch."

May 1, 1947

By John E. Kelley

Laboratory equipment, which simulates abrasive impacts between steel and minerals that might be present during pneumatic transport of coal, was used by the Bureau of Mines to characterize the potential explosion hazard of such collisions in an atmosphere of fine coal dust, air, and methane. A variety of coal mine rock materials, including sandstone, limestone, and pyrite-bearing limestone, were impacted with specimens of pipeline steel. Tests were con-ducted in atmospheres containing zero to 6.4 vol-pct methane mixed with zero to 300 mg/l coal dust. Coal dust in air alone was not ignited by abrasive impacts, but additions of as little as 1 vol-pct methane to the coal dust and air mixture resulted in ignitions. Steel impacting against sandstone caused ignitions in mixtures of coal dust, air, and methane, and the probability for ignitions increased with an increase in methane. No ignitions occurred with impacts of steel on lime-stone or pyrite-bearing limestone, even when large showers of sparks were produced. Studies of the effect of tangential collision velocity showed that no ignitions of coal dust, air, and methane occurred below 900 fpm (4.57 m/sec). Ignitions in coal-air-methane mixtures were found to be caused by a hot friction-induced smear on the impacted rock at the impact site rather than by sparks. High-speed photography was used to verify this observation.

Jan 1, 1976

By Gary P. Sames

This U.S. Bureau of Mines study was conducted in eastern Kentucky drift mines as part of an ongoing research program to characterize the outcrop barrier zone. "Hillseams" were identified as the dominant geologic cause of roof instability unique to the outcrop barrier zone, with many roof fall injuries and fatalities attributed to them. Hillseam is the eastern Kentucky miners term for weather-enlarged tension joints that occur in shallow mine overburden where surface slopes are steep. Hillseams are most conspicuous within 200 ft laterally of a coalbed outcrop and under 300 ft or less of overburden. Hillseams form by stress relief, and therefore tend to parallel topographic contours and ridges. They can intersect at various angles, especially under the nose of a ridge, and create massive blocks or wedges of roof prone to failure. Examples of hillseams are described in both outcrop and in coal mine roof to establish their geologic character and contribution to roof failure.

Jan 1, 1989

By A. Z. Dimitroff

An improvised rock-dust disseminator, consisting of a 10-gallon galvanized metal milk can that dispenses rock dust in return air currents by the injection of compressed air has reduced the float dust explosion hazards at the Koehler coal mine, Koehler, N. Mex.

Jan 1, 1965

By W. H. Carrington, A. C. Richardson

"INTRODUCTION The Powhatan mine of the Franklin Coal Mining Co. is located in the western part of Jefferson County, Ala., on the Louisville and Nashville Railroad, 40 miles west of Birmingham. The Mary Lee bed at this point yields coal with fair coking qualities, but with an ash content as mined so high as to prohibit its use in the production of metallurgical coke. At present the entire output of the mine is washed in single-compartment jigs and marketed as locomotive and domestic fuel.Figure 1 gives a typical seam section of the Mary Lee bed at the Powhatan mine. This section shows that the bed is divided by rock partings into three benches. In many parts of the mine, particularly in the older workings the roof rock is so weak that it can not be held without excessive timbering. This condition has restricted the operation in many parts of the mins to the middle and bottom benches of coal. The 6 inches of draw rock between the top and middle benches is very strong and makes an excellent roof requiring only a normal amount of timbering to support it. In the newer workings of the mine the character of the rock above the top bench is strong and it is believed that in the future it will be possible to work all three benches. This study was undertaken for the purpose of determining the washing characteristics of the Mary Lee bed at Powhatan and the effect on these characteris-tics of including or omitting the coal from the top bench. It was also the purpose of the study to show whether it would be possible to produce a washed product sufficiently low in ash to be used for the manufacture of metallurgical coke. This paper is one of a series of reports on the washability of Alabama coals which is being prepared by the U. S. Bureau of Mines and tin University of Alabama. With the cooperation of the coal producers of Alabama. It contains the results of screen sizing and float-and-sink tests of representative samples of run-of-mine coal, and the results of table tests on the minus 3/16-inch sizes of the raw coal."

Apr 1, 1933

By W. E. Anable

The Bureau of Mines studied the purification of commercially available yttrium by melting it in a 100-kw electron-beam furnace. Button-scale melts were made to determine the ultimate purification that could be attained by melting yttrium at 1,733° to 1,770° C at low pressure (0.05 to 0.1 micron) for 1 to 120 minutes. In addition, numerous melts were made to study the effect of doping yttrium with carbon, 17 selected metallic additions, and 3 compounds. Except for nickel and zirconium, the metallic impurities in yttrium were lowered significantly on extended treatment; silicon was lowered only slightly. The nonmetallic impurities} oxygen, nitrogen, and carbon, were not lowered except on short exposures. In isolated instances, the oxygen content was lowered from 5,860 ppm to about 5,000 ppm. In most instances the carbon con-tent was lowered from 545 to about 220 ppm in 20 minutes and then increased again. It was concluded that yttrium cannot be purified by direct heating or by the doping technique employed.

Jan 1, 1965

By Henry M. Harris, Hal J. Kelly

Electrical dewatering tests are described in which the laboratory cells were designed for continuous operation using an endless metal belt as the anode . The test slurries were dilute , containing from 2.5 to 14.4 percent solids (specific gravity of 1.02 to 1.10 ) that were all minus 8 microns in size . Recovery of the solids of low water content was the practical objective of the investigation . Process variables evaluated and reported are : The effect of feed rate , amount of electrolyte , samples from different sources , and the use of two cells in series . These variables are evaluated on the basis of yield of clay per kilowatt - hour , recovery , and the amount of solids in the deposited clay . Recovery , yield , and solid content of the belt anode product are interdependent , and changes that will improve one of these characteristics often are accomplished at the expense of the others . Tests in which recoveries range from 50 to 60 percent usually result in yields of 8 to 9 kilograms (kg ) of dry clay per kilowatt- hour (kwhr ) . Under these conditions , the solid content of the deposited clay approximates 50 percent . One test sample , composed of kaolinite , showed very high yield , 13 to 16 kg per kwhr ; high recovery , 53 to 58 percent ; and 52 to 54 percent solids in the cake .

Jan 1, 1964

By F. W. Cox

Exhaust emissions were measured from 25 aircraft turbine engines using Jet A fuel. Analytical apparatus, procedures, and results are described. Carbon monoxide, carbon dioxide, nitric oxide, nitrogen dioxide, and aldehydes were measured at engine operating modes representing power levels used in airline operation. Carbon monoxide, hydrocarbon, and aldehyde emissions were highest at idle and lowest at takeoff; oxides of nitrogen were lowest at idle and highest at takeoff. Of the total oxides of nitrogen emitted, nitrogen dioxide constituted from 10 to 100 pct, depending on the exhaust gas temperature. Engines retrofitted with smoke-reducing burner cans produced less carbon monoxide, hydrocarbon, and aldehyde emissions, and slightly more oxides of nitrogen then engines with standard burner cans.

Jan 1, 1972