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By H. P. Dibbs

An account is given of the application of neutron activation analysis to the rapid, non-destructive determination of copper in minerals, using a 14-MeV neutron source. Elements that interfere in the determination of copper by this method are given, together with the errors in the estimation of copper that result from the presence of varying amounts of these elements. The possible use of a compact "sealed-tube" 14-MeV neutron generator for the field assay of copper in minerals is discussed.

Jan 1, 1970

By B. I. Whittington

This paper examines the effect of cation type (i.e. NH4+, Na+ and K+) and anion type (i.e. SO42- and C1-) on the extraction of nickel during the pressure acid leaching of a Western Australian laterite ore. The results are compared with testwork conducted with other Western Australian nickel laterite ores and the possible process implications of adding an additive to a plant autoclave are considered. Addition of either (NH4)2SO4, Na2SO4 or K2SO4 increased both the nickel extraction and the acid consumption, provided that the level of additive was not too great. For example, the nickel extraction of 93% increased to above 96% in the presence of additives, but decreased to 94% when, for example, NH4 levels increased from 7 kg/t ore to 21 kg/t ore. The relative stability of the jarosite species formed when additives were present influenced the amount of jarosite in the residue and, hence, both the final free acidity and overall nickel extraction. The use of Cl- versus SO42- salts as additives had little effect on overall nickel extraction or overall free acid values, although the presence of SO42- additives appeared to enhance nickel extraction kinetics over the first 60 minutes of the reaction. In contrast, manganese extraction was enhanced by the presence of Cl- additives.

Jan 1, 2004

Real time analysis of ore quality between the mine and mill provides major benefits to copper mining and processing operations. Prompt gamma neutron activation analysis (PGNAA) is a proven technique that has been successfully applied for real time conveyed flow multi-elemental measurement. The advantage of PGNAA is that it measures through the full conveyed cross section continuously and provides representative element measurement without the need to constantly sample coarse (primary crushed) conveyed flows. High specification PGNAA analyzers enable accurate measurement over time increments as short as thirty seconds. Elements such as copper can be measured to a precision of 0.02% copper which is sufficient for high confidence in decisions for bulk flow diversion. Increments of eight tonnes are being diverted through a bulk ore sorting application to remove batches of waste from mill feed as well as divert material to different stockpiles based on ore quality. Longer measurement increments of two to five minutes are suitable for blending control of ores to reduce feed quality variability and to control average ore quality within a target range. Feed blends can be adjusted as frequently as required but typically multiple measurement increments are composited to produce a rolling average ore quality. The paper details two case studies where analyzers have been successfully used to measure conveyed flows for blending and bulk diversion applications. The real time measurements of ore composition are also used for ore reconciliation, in metal accounting and providing process operators with advance warning of ore quality changes that may affect grinding performance and cause process upsets. Real time ore quality measurement has proven beneficial in improving copper processing performance through better utilising plant capacity in a leaching operation, optimising ore feed quality, and reducing unnecessary processing of waste. INTRODUCTION Representative real time elemental analysis of conveyed ore quality using fully penetrative technologies has been available to the minerals industry since the 1990s. The Prompt Gamma Neutron Activation Analysis (PGNAA) technique was developed into a conveyed material analyser and soon adopted by the cement and coal industries which recognised the benefits in real time quality management. These commodities were ideally suited to this measurement technique as operations generally involved conveying bulk material prior to processing. Measured quality was used to divert material to different destinations or used to control blending for improved quality consistency. Uptake in the minerals industry, however, has been slow until the last ten years, and particularly until the mid-2010s.

Jan 1, 2019

By D. A. Bordin, C. J. Newman, R. J. St. Eloi

"The requirements for a metallurgical acid plant treating smelter gases are both unique and demanding in terms of sulphur dioxide treatment and emission control. Since start up in 1981, the copper smelter at the Kidd Creek Division of Falconbridge Limited has undergone several major expansions. The expansion and modification of the acid plant has been an integral part of this process. Both production demands and government regulations dictate that this metallurgical acid plant be unique in terms of operating flexibility. The variable capacity to treat a wide range of sulphur dioxide concentrations, and the operating flexibility to control emissions are the topics of this paper.INTRODUCTIONThe Kidd Creek Division of Falconbridge Limitied is a base metal mining and metallurgical complex located in Timmins, Ontario. The discovery of the original copper-zinc-silver orebody was announced in April, 1964. Mining operations began in 1966 with a 9000 tonne per day concentrator coming on stream in November of that year. In April 1972, a 108 000 tonne per year zinc plant was commissioned. Over the years the facilities have been expanded, such that the concentrator now has the capacity to process 13 000 tonnes of ore per day . To expand zinc production, the world's second installation of the Cominco/Sherritt pressure leaching facility was completed in 1983 to bring total zinc production capacity to 125 000 tonnes per year. In 1973, serious planning for a smelter operation began. In early 1975, after studying both continuous smelting and flash smelting processes, a decision was made to proceed with the technology offered by Mitsubishi Metal Corporation of Japan. The Mitsubishi Continuous Smelting Process was to be used for the smelter and the Onahama No.3 tankhouse technology for the copper refinery.The smelter, which uses the Mitsubishi Continuous Smelting Process for the continuous production of blister copper from concentrate, went on line in June 1981. It has been expanded from its original capacity of 60 000 tonnes to 100 000 tonnes per year of copper.From the very early design stages for the metallurgical complex, the company had adopted a policy of constructing and operating modern plants which would meet existing and anticipated environmental standards. With this in mind, the decision was made to utilize the proven technology of fixing sulphur dioxide emissions, in the form of sulphuric acid. A 636 tonne per day single absorption contact acid plant was built to serve the zinc plant in 1972. In 1981, an 883 tonne per day double absorption contact plant was built to serve the needs of the copper smelter. The copper smelter acid plant has since been expanded to a design capacity of 1692 tonnes per day and it is the main focus of this paper."

Jan 1, 1989

By G. W. Norval, V. G. Papangelakis, G. A. Moldoveanu

Smelting has been the primary method of treatment for refractory copper sulfide concentrates such as enargite (Cu3AsS4), but the pyrometallurgical processing generates elevated levels of volatile arsenic. The present research investigates a novel hydrometallurgical process of oxidative dissolution of enargite at ambient conditions in the presence of chlorine dioxide (ClO2), a very powerful oxidant generated in solution by the reaction between a strong acid (HCl or H2SO4) and sodium chlorite (NaClO2). The effects of initial oxidant concentration, particle size, agitation speed and temperature on dissolution kinetics and copper extraction were investigated. It was found that a stoichiometric ratio of ClO2:Cu3AsS4 = 9:1 were needed to completely and congruently dissolve the mineral with fast kinetics (<15 minutes) under ambient temperature. The dissolution extent (metal extraction) increases with increasing ClO2 concentration and decreasing particle size of solids, but is not influenced by temperature or agitation speed.

Jan 1, 2014

By John Redstone, André R. Laplante

"Le rebroyage des concentrés d&apos;hématite en usine (Sidbec-Normines, Port-Cartier) et en laboratoire a été modélisé selon le modèle de Reid (1965).L&apos;effet du pourcentage solide sur la cinétique de broyage a été étudié en usine. La fonction de sélection corrigée (pour tenir compte de l&apos;effet du pourcentage solide sur le temps de rétention) augmente lorsque le pourcentage solide augmente de 80 à 84 pourcent. Cette amélioration est contrebalancée par une augmentation de la quantité de pulpe court-circuitée, à des pourcentages solides supérieurs a 81%. La densité optimum de broyage se situe à 84 pourcent.Comme alternative au mode d&apos;opération actuel, l&apos;assemblage des broyeurs en série plutôt qu&apos;en parallèle a également été simulée. Le moins 44 µm passe alors de 68.1 à 72.5 pourcent, ce qui correspond à une capacité supplémentaire de 32 tonnes à l&apos;heure par broyeur. Ces résultats doivent toutefois être interprétés avec prudence, car la cinétique de broyage n&apos;est généralement pas linéaire lorsque le taux d&apos;alimentation est plus que doublé.IntroductionL&apos;usine de bouletage de Sidbec-Normines Inc. a été décrite par Morimoto (1977), Lévesque et al. (1979) et Pabst (1979). La section de broyage des concentrés contient six broyeurs à boulets en parallèle et en circuit ouvert, d&apos;un diamètre de 5. 18 mètres et de 10.36 mètres de longueur. Ils contiennent chacun environ 350 tonnes de boulets d&apos;acier forgé de 3.8 cm de diamètre. Le concentré est broyé de 10 pourcent moins 150 µm (100 mailles) à 65-68 pourcent moins 44 µm (325 mailles), à un pourcentage solide de 78 à 80 pourcent. Cette fragmentation poussée exige une consommation d&apos;énergie de 32 kWh/tonne. Cette énergie est surtout libérée sous forme de chaleur, la pulpe étant déchargée a une température de 68-72° C. II en résulte un milieu de broyage corrosif, et une consommation de boulets élevée, de 3.4 à 4.0 kg / tonne broyée."

Jan 1, 1983

By J. G. Patterson

"The depressive action of sodium cyanide on chalcocite has been investigated and found to be unstable. Flotation results show that with the addition of sodium cyanide to the system chalcocite is initially depressed but rapidly recovers with time, provided there is sufficient oxygen present.lt is proposed that the unstable depression is due to the reaction of cyanide with adsorbed xanthate and copper ions at the chalcocite surface to form soluble copper complexes. When all the free cyanide has so reacted, xanthate anions can then re-adsorb on the chalcocite surface and the flotation will recover. Results are presented to verify the the above mechanism."

Jan 1, 1968

By Norman R. Ball

"Many people in the mining and metallurgical industries were brought up to embrace Henry Ford&apos;s pronouncement that ""History is bunk"" but it is not generally known that the same Henry Ford created and paid for one of the finest technological museums in the Western World. I am aware that many people feel that industry history is something you ask aging executives to do or that history is a clip-andpaste compendium of pictures re-discovered every 25 years or on the occasion of issuing a press release on plant expansion. Moreover, there are many who fear historians as somewhat deranged individuals interested only in corruption, injustice and sensational labour strife. Good history lies somewhere between the controlled P.R. handout and the hysterical attack. Writing good history is a difficult creative act based on the application of experience, insight, wide knowledge and careful reasoning to available evidence. To date, the Canadian mining and metallurgical industries have achieved a great deal but left too little evidence and it is this lack of evidence which must be corrected before it is too late. It is the purpose of this article to stimulate thoughts with regard to archives, one of the more important vehicles for the preservation of such evidence."

Jan 1, 1999

By A. Y. Senchenko, Y. V. Kulikov

"Different methods aiming at specific energy calculation and design of AG/SAG circuits are used in mining. They include JK DWT/SMC test, SAGDesign test and CWi/RWi/BWi tests. The simplest methods with no secret equations and giving energy required for grinding in kWh/t were proposed by F.?. Bond and J.H. Starkey. D.J. Barratt proposed to use results of CWi/RWi/BWi tests for AG/SAG mill sizing. The present paper gives an alternative for forecast of specific AG/SAG energy. The principle is similar to the theory proposed earlier and consists in cumulative AG/SAG energy calculation using indices of rod and ball grinding (RWi+BWi) without impact crushing index (CWi). Then total energy is divided between two grinding stages using special formulas based on extensive statistical information. The forecast indices of AG/SAG and ball grinding are similar to the SAGDesign testing results. Hereinafter the predicted indices are used for mill sizing of the whole grinding circuit. The method considered in the paper enables prediction of AG/SAG energy based on the test results according to Bond method. The proposed method version was not widely published earlier. The aim of the work was to elaborate cost-effective, reliable and accessible way to determine specific AG/SAG energy. At this stage of method development, it is recommended to use it only for works at preliminary Geometallurgy stage (Scoping, Pre-Feasibility). At design stage the obtained data should be confirmed by appropriate testing using alternative JK DWT/SMC and SAGDesign methods.INTRODUCTIONAppropriate crushing and grinding testing is required to design efficient comminution circuits. It is obviously important to obtain accurate information about ore hardness properties since the main energy consumption at the plant is associated with comminution processes. Moreover, it is required to apply the processes that make it possible to minimize operating costs and efficiently use capacity of the installed equipment installed.When studying ore hardness properties, it is required to take into account that breakage of the material is performed using different equipment. That is why accurate selection of the equipment and the circuit calculation without relevant testworks is impossible. Ideally, the testworks should provide answers to the following questions: determination of ore hardness properties, determination of specific energy consumption for comminution as well as obtaining of sufficient amount of statistically significant results from the tests. The results from crushability and grindability testworks in the first place provide assessment of ore hardness properties and in addition correlate with throughput of the respective equipment. The data obtained can be used for modeling of comminution circuits at the stage of the technology development"

Jan 1, 2016

By S. Klingmann

ABSTRACT In this paper, we used data collected from the Gibraltar mine to analyze the effect of the TyreSense tire monitoring system on tire performance by reducing tire wear and preventing premature tire failure or damage. We analyzed the relationship between tire temperature, tire pressure, and tire failure or damage to help better understand the importance of controlling high tire temperature and pressure. The results enhance and expand the knowledge of the management of tire operational pressure and temperature.

Jan 1, 2014

By V. A. James

The new electrolytic copper refinery situated at Copper Cliff, Ontario, has been in operation for over a year and a half. This plant is operated by the Ontario Refining Company, Limited. The associated companies behind the enterprise are the International Nickel ?company of Canada, Limited, the American Metals Company, Consolidated Mining and Smelting Company of Canada, Limited, and Ventures, Limited. The plant was an outgrowth of the rapid development of copper resources in the nickel-copper ores of the Frood and other great mines in the Sudbury district, and of the desire to have all primary production units grouped together as compactly as possible. Starting anode furnace operations in June, 1930, and electrolytic refining on July 1st of that year, after a record-breaking construction programme completed in only fifteen months, the plant soon settled into its stride and the usual starting-up difficulties were .rapidly overcome. The rated capacity of the plant, namely, twenty million pounds of refined copper per month, has, of course, never been reached, due to depressed business conditions and latterly to the world copper agreement limiting production. It may be said, however, that the present installation has proved its ability to produce in excess of its rated capacity, and with relatively minor additions to plant and equipment that capacity can be doubled. Owing to the severity of the winters, when temperatures of from 20 to 40 degrees below zero are to be expected, the building of this refinery involved a number of problems in insulation, layout, ventilation, etc., which were rather unusual in copper-refinery construction.

Jan 1, 1932

By Gordon T. McKenna

"Syncrude Canada Ltd. is developing new concepts in lease-closure landscape design for its Oil Sands Leases 17 and 22 in northeastern Alberta. Closure planning is becoming an integral part of the planning cycles and of the lease operation. By incorporating closure planning into the day-to-day operation, the company will achieve acceptable lease closure in an economical manner. Ultimately, Syncrude will achieve lower operating costs through innovation in mine planning and a reduction in residual liabilities.New concepts being evaluated for lease-closure landscape design include: designing for closure, use of landforms and natural analogs, self-armouring bouldery ground, robustness in design, landform grading, terrain analysis of reclaimed land, geotechnical hazard assessments, choices in closure design timeframes, passive maintenance, determining post-closure monitoring goals, engineering tailings, engineering other substrates, use of test plots and field demonstrations, geomorphologic monitoring of reclaimed lands, defining closure goals, and visiting other mines. These concepts are being formalized under the new discipline of Landscape Engineering."

Jan 1, 1996

By M. F. Goudge

MAGNESIA refractories and magnesium metal are both essential war commodities. The need for magnesium, which had just made its debut as a commercial metal a few years before the outbreak of the present war, is widely known because this new and valuable light metal has already received much publicity. Less widely known but equally important in the war effort are magnesia refractories. They are indispensable to the efficient functioning of the great metallurgical plants producing steel, nickel, copper, and other metals, where, because of their resistance to extreme high temperature and chemical attack, they are used in lining the furnaces, which are operated at a white heat. The demand for refractories in the metallurgical industries rose rapidly upon the outbreak of war, and now, in consequence of the continued great expansion under way in the manufacture of steel, nickel, copper, and other metals, the need for magnesia is greater than ever. Since 1915, part of the Canadian requirements of basic refractories has been supplied from the deposits of magnesitic dolomite in Argenteuil county, Quebec. The products from these deposits are excellent for many uses, but the magnesitic dolomite has too high a content of silica and lime to be used in making a type of magnesia brick required in nickel converters, and in the roofs of reverberatory furnaces used in the copper and steel industries. There is now a large and growing demand in Canada for bricks and shapes for these uses. This demand has always been supplied from the United States. Makers of these products in the United States, in turn, formerly imported most of the necessary high-grade, dead-burned magnesia from Austria and Manchuria. Not only are these sources closed, but refractory chrome ore from the Philippines is no longer available and chrome refractories may have to be in large part replaced by magnesia.

Jan 1, 1942

By J. E. Hawley

"IntroductionA STUDY of the trace elements in the ash •of coals from nine seams in the Sydney coalfield, Nova Scotia, was undertaken at the suggestion of Dr. W. A. Bell, Geological Survey of Canada, as a part of a larger study of these and other Nova Scotia coals being made by the Geological Survey and the Nova Scotia Department of Mines under the direction of Dr. P. A. Hacquebard.The main purpose of this investigation has been to •determine if a knowledge of the trace element distribution might be of assistance in the recognition of individual seams, the distinction of which is not always easy or positive in folded and faulted strata by ordinary stratigraphic and structural means.The study has been so conducted as to afford information on the variation of trace elements in individual petrographic intervals or divisions in each of the seams examined, intervals determined by Dr. Hacquebard on the basis of their banded ingredients, vitrain, clarain, durain, fusain, etc, as observed under the microscope in polished sections. The results, as well, indicate the trace element composition of the coals of the area as a whole, and quantitative data for fifteen elements are given, along with concentrations of thirteen other elements, stated in terms of intensity ratios. Data on distribution of germanium, though considered here along with other elements, are dealt with elsewhere*."

Jan 1, 1955

By A. J. Monhemius

This paper reviews the history of modern iron-control processes in hydrometallurgy. Attention is paid to processes developed in the electrolytic zinc industry for removal of iron from zinc sulfate leach liquors and the problems faced by the industry in the safe disposal of the iron residues produced by these processes. Past lessons learned are projected onto current efforts to develop hydrometallurgical processes for treatment of copper sulfide concentrates. It is argued that any attempt to create a \u201chydrometallurgical copper smelter\u201d will fail, unless methods are developed that can recover iron in a form that can be directly used by the steel or pigment industries.

Jan 1, 2017

By William B. Hetherington

Communities are the foundation upon which the whole structure of society rests and upon which the nation builds its hope for the future. They are not established to serve any one particular generation, nor any one element or group, but should be erected to render a lasting service to all who are to follow. They play a very vital and important role in the lives and welfare of the people, in their industrial, business, and social relations, and in the economy of the nation, of which they are the fundamental assets. Communities and civic governments are destined to be vital factors in the national welfare in the days that are to come. Any improvement in national or world conditions must have its origin within the communities. Any attempt at solution of the community problem must give some consideration to the fundamental elements which exist in every community, and to the underlying principles, and ways of life and thought, upon which community life is based. The community is, in its essence, a number of people living and working more or less closely together, sharing common rights, privileges, conveniences, and comforts, which would be impossible for the individual to obtain for himself by his own efforts alone, or in any other way than by the mutual exchange of persona! services and resources. In this way, men have increased the returns from their labour and commerce, have raised the standard of their living, with better social, educational, and recreational facilities, and enjoy a greater personal security.

Jan 1, 1943

By M. A. Upham

"MINING is Canada's second largest basic industry, producing material with a gross value of 2.5 billion dollars, led only by agriculture with 2.9 billion dollars. It pro-vides employment, directly and in-directly, for three quarters of a million people. Since the Second War, the value of mineral production in Canada has tripled. Economists forecast that over the next 15 years its value will triple again. Canada is a basic and leading supplier of nickel, iron, copper, zinc, lead and uranium. It is also a major oil producer, leads the world in the production of asbestos and in five years will be the leading producer of potash, a basic constituent of fertilizer.It can be seen that Canada's wealth and economic progress lies in being a primary producer of economic minerals and in building secondary industries to manufacture finished products from these raw materials. Canada's future in the field of mineral production looks bright, with our resources just starting to be tapped. Outside of the large expanse of Soviet Russia, we are by far the world's most fertile mineral exploration area."

Jan 1, 1967

By M. Gangal, M. Grenier, D. Mchaina, S. Hardcastle

"Exposure to airborne respirable silica in surface and underground mine operations is known to be the cause of industrial lung diseases. For this reason, silica is a regulated substance and worker exposure must be monitored regularly. Diesel exhaust also contains substances which are potential caricinogens. In an underground setting, diesel particulate may be the main component of what is referred to as respirable combustible dust (ReD). Although diesel particulate or soot is not at present a rigorously regulated substance, new epidemiological data is prompting North American institutes and agencies to regulate diesel soot or RCD exposure. This paper describes a method where by silicaand RCD exposure may be determined using a single personal sample. In this method, an airborne respirable dust sample is obtained and analyzed nondestructively for silica components using an on-filter X-ray diffraction method. Filters are then ashed at 500°C in a muffle furnace over a four-hour period to determine mass loss due to RCD burning. Using on-filter X-ray diffraction analysis as opposed to redeposition of dust samples onto another analytical substrate allows the"

Jan 1, 1992

By David G. Meadows

During the last decade Antofagasta Minerals? Los Pelambres Mine has dramatically increased its ore throughput following the fast initial phase ramp up through a series of planned incremental expansions. The original 85,000 mtpd, two SAG line plant was commissioned in 1999 and rapidly exceeded nameplate tonnage in only a few months. Following this, the inclusion of a pebble crushing circuit resulted in throughputs in excess of 114,000 mtpd and a recent, final third line SAG and ball mill addition have taken the plant to over 175,000 mtpd even with increasing ore hardness and changing ore feed characteristics. The progressive changes are described in this paper together with how the technical challenges have been met.

Jan 1, 2012

An Atomic Force Microscope (AFM) was used to measure the surface forces between glass sphere and silica plate in CnTAC1 (n=12, 14, 16, 18) solutions. The results showed the presence of long-range attractive forces that can be fitted to single exponential functions. With a given surfactant, the attractive force increased with increasing concentration, and reached a maximum at the point of charge neutralization (p.c.n.). The decrease in the attractive force above the p.c.n. is probably due to the inverse orientation of the surfactant molecules. A plot of the log (p.c.n.) vs. the number of carbons in the hydrocarbon chains of the Cn TACI homologues showed a linear relationship with a slope of -0.37, indicating that the surfactant adsorption entails a decrease in free energy by -0.85 kT per mole of CH2 (or CH3) group. These results suggest that the adsorption of long-chain surfactants is controlled by hydrocarbon chain association during the process of forming surface hemi-micelles (or domains). Possible origins of the long-range attractions are discussed on the basis of the results presented in this communication.

Jan 1, 2006