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By O N. Antzutkin, A V. Ivanov, W Forsl

Polycrystalline and surface complexes (at synthetic sphalerite, ZnS, and galena, PbS) of zinc(II) and lead(II) ions with eight different O,OÆ-dialkyldithiophosphate (Dtph) substances have been prepared and comparatively studied by means of 31P CP/MAS NMR spectroscopy. The 31P resonances have been assigned to dithiophosphate groups with terminal S,SÆ-chelating or bridging coordinations in the mono-, bi-, tetra- and polynuclear complexes respectively. The bridging coordination of two neighbouring zinc(II) ions by O,OÆ-dialkyldithio-phosphate ligands was established at the surface of synthetic sphalerite.The adsorption mechanism of dialkyldithiophosphate on synthetic galena includes formation of a surface complex as well as surface precipitation. Principally different coordination modes of the reagent were discovered at the surfaces of galena and sphalerite (ie terminal S,SÆ-chelating coordination to the lead atom).Derivatives of monothiophosphoric and phosphoric acids were displayed as hydrolysis products of dialkyldithiophosphates at synthetic PbS.

Jan 1, 2005

Two significant TBM boreability predic- tion models are outlined. Predicted advance rates are compared with actual advance rates taken from twenty case histories. The results show that a simple low cost method that uses one machine parameter and one rock parameter compares very favourably with a high cost sophisticated method which also includes information regarding discontinuities in the rock mass. The effect of rock texture on drillability is also examined. A method of quantifying rock texture has been developed and is outlined. Experimental results show that the developed TEXTURE COEFFICIENT returns highly statisti- cally significant correlations with drilla- bility data in a wide range of rock types.

Jan 1, 1987

By Lynch AJ, Musgrove NH

The behaviour of chalcopyrite and pyrite in the rougher-scavenger and regrind-retreatment circuits in the Warrego concentrator is discussed. The effects of change in xanthate addition on the separation of chalcopyrite and pyrite is described. The effect of the regrind mill on the (flotation rate of particles containing chalcopyrite and pyrite is discussed with particular reference to the importance of removing sub-mesh particles from the feed to the regrind mill.

Jan 1, 1975

The mining of remnant coal reserves at the Liddell Open Cut is subject to a number of risks. These risks are of both a technical and financial nature. Liddell Open Cut is principally a conventional truck and shovel/loader operation, supplemented by a highwall coal augering operation. There are significant areas of divergence from more conventional operations including working in close proximity to a major dam, working up dip from an operating underground mine, and working through areas where there has previously been underground extraction. In addition the site has major long-term rehabilitation requirements. This paper, rather than concentrating on specific detail of areas of risk, presents the spectrum of geological, design, operational and post-mining risks that accrue to the various areas of activity in this open cut operation. The balance of this paper then provides an outline of the strategies employed by Liddell Coal to manage their potential impact.

Jan 1, 1994

By Slater R

The initial planning and detail design phase leading to the development of a 7.5 m internal shaft to service the deep 3000 and 3500 copper orebodies at Mount Isa, Queensland is well advanced. The choice of internal shaft access was made over alternative methods such as a decline from existing levels and borehole hoisting. The resulting access development requirements and shaft configuration for production have been determined. Several techniques are being studied for shaft development. These include the application of blind shaft drilling and large hole reaming methods as well as conventional sinking techniques. As the 3000/3500 Orebodies extend from 1000 metres to more than 1800 metres below the surface, high stress conditions and ground temperatures ranging from 45CC to 62CC are anticipated. The effect of these on the methods being investigated to create a favourable working environment will influence the final choice. Exploration diamond drilling is in progress to confirm the geology of the orebodies so that planning for their extraction including refrigerated ventilation concepts can proceed.

Jan 1, 1982

By Walker K, Burton RC

An outline of the ventilation and refrigeration requirements of deep South African gold mines is presented. This is followed by a brief description of the history of controlled recirculation in mines and the practical and economic benefits such schemes can offer. The potential hazard of a fire in a recirculation system is discussed.The major part of the paper describes the first large-scale field trial of controlled recirculation to be conducted in South Africa. Emphasis is placed on the monitoring system that was used for data acquisition during the trial, and also on a safety system designed to shut off the recirculation fans in the event of a fire.The paper concludes with a review of the latest development work taking place on recirc-ulation safety systems.

Jan 1, 1985

By Kelley BC, Filmer AO

The chemical oxidation kinetics of sphalerite by Fe(III) was studied at various temperatures and size fractions in sulphate media. The kinetics of Zn extraction followed a pore diffusion control mechanism with an apparent activation energy of 54-58 kJ mole. This figure, although high for a pore diffusion control process, is consistent with other studies carried out in sulphate media. An empirical statistical model, relating the extraction time to % Zn extraction, average particle size and temperature, is described by log 1 = 12.22 - 0.017% Ext. - 1.76 log D Av t - 2954 T Parallel studies were also carried out investigating the biological oxidation of sphalerite utilizing the acidophilic autotrophic bacterium Thiobacillus Ferroxidans. The effect of such kinetic parameters as pulp density, particle size and Fe(III) on bacterial growth rate and consequently zinc extraction rate, were studied and where appropriate, optimum conditions for bacterial growth were specified. Based on the results of chemical and biological leaching studies, it was apparent that rapid zinc extraction from sphalerite was predominently due to oxidation by Fe(III). The biological oxidation process catalyses the oxidation and regeneration of Fe(III). The proposed combined chemical-biological leach system was simulated in semi continuous fashion. The sphalerite oxidation rates obtained in this system were similar to that predicted by the chemical leach empirical model. 1. Senior Research Metallurgist, CRA Research, Boolaroo, N.S.W. 2. Group Leader-Hydrometallurgy, CRA Research, Boolaroo, N.S.W. 3. Senior Research Scientist, Biotechnology Australia, Roseville, N.S.W. 4. Senior Experimental Officer, Biotechnology Australia, Roseville, N.S.W.

Jan 1, 1986

The Oregon-Idaho graben evolved after widespread Uwleiitic flood basalt volcanism associated with the arrival of the plume head of the Yellowstone hotspot beneath southeastern Oregon approximately 17-16 Ma. The north- to north- northeast-trending, 50 km-wide graben evolved between 15.5 and 10.5 Ma during east-west extension. The graben is part of a middle Miocene back-arc rift (1,100 km long) that includes the northern Nevada rift, the Baker and LaGrande grabens, and the Chief Joseph dike swarm of the Columbia River Basalt Group. The graben ceased to be a volcano- tectonic depression as the cross-cutting western Snake River plain began to evolve at approximately 10.5 Ma.

Jan 1, 1995

The purpose of this paper is to discuss briefly the problems encountered in designing and sinking No 7 shaft, and to present the methods employed in the operation.The illustrations accompanying the paper show the details of the construction of the equipment used in completing No 7 shaft, consequently the descriptions appearing in the text are brief outlines only. Mineral leases Nos 7 and 8, held by the Broken Hill South Limited, comprise an area of 69.5 acres. The length of the holding is approximately 2500 ft.The western orebodies, which are the main producing masses, enter the property at the northern bonndary. Generally, the dip of the orebody is to the west, and the pitch to the south, but local variations occur and even a reversal of pitch has been noticed. The angle of dip is approximately 70 degrees and the angle of pitch 45 degrees.

Jan 1, 1932

The paper highlights the conceptual developments in rock mechanics applied to quantify the effect of bolts in the stabilization of joints and yielding soft rocks. NOTATION Aa = stress change after excavation Eä EE, Eä = moduli of intact rock, single joint and jointed rock Eb = elastic modulus of the bolt k, = normal stiffness of joint Ab = cross section area of the bolt A, = area of influence per bolt ab = axial bolt stress e, = axial strain of the bolt eä e,, ej, = strains of intact rock, joint and jointed rock Ai = area of the joint ,r+ = shearing resistance of the bolt (at the joint) a = normal stress at the joint plane aäa3 = major and minor principal stresses c;, 4i; = cohesion and friction angle of the joint 0 = angle between the bolt and the joint a = inclination of the joint to the vertical axis P = bolt density parameter u, = convergence of unsupported tunnel section u, = convergence of bolted tunnel

Jan 1, 1992

By Thomas CG, Armstrong GJ, Lynch KS

A small glass walled pot grate has been used to simulate drying of iron ore pellets in a travelling grate plant. This equipment has enabled the effect of decreasing grind and de- creasing pellet bulk density on plant production to be quantitatively predicted. These predic- tions are compared with plant experience. The use of the laboratory simulator in comparing the effect of various additives on plant production is also described and substantial improvements in both the goethite and free-water drying periods are predicted.

Jan 1, 1972

By L Cooper, J Sharma, M J. Hendry

Thick clay tills below potash mine tailings and brine ponds are important natural barriers protecting fresh water aquifers in Saskatchewan. Centrifuge modelling was applied to assess geochemical processes and impacts of dilute brine (0.1 M NaCl) migration through clay till core samples obtained from non saline, unoxidised clay till at a mine site. At accelerated gravity of 876 + g, during each day of centrifuge modelling, flow driven through a 52 mm length core simulated transport through a 45 m thick clay over ~2100 years. Hydraulic conductivity, monitored continuously before and during brine permeation, was low and relatively constant (8.5 + 10-12 m/s), confirming that confining stresses prevent permeability increase. Core density and porosity measurements confirmed that reactive transport occurred under realistic in situ conditions. Breakthrough (defined by C/C0 = 0.5) of non-reactive Cl- occurred at 25 days. The slight delay for Na+ breakthrough, associated with small increases in Ca2+ and Mg2+ concentrations in the effluent were attributed to ion exchange, but carbonate reactions were relatively unimportant. Cation exchange analysis of core samples was inconclusive without corrections for porewater Na+ and carbonate dissolution. Geochemical processes that were observed during centrifuge modelling were successfully simulated using the 1D geochemical transport code PHREEQC. Solute transport was dominated by diffusion with limited ion exchange to delay Na+ migration. Brine would not break through a 45 m thick clay for tens of thousands of years. Based on these findings, the thick clay till at this site, if laterally extensive and undisturbed by drilling activity, is likely to act as an effective natural barrier to vertical brine migration over the long term.

Jan 1, 2003

Structural Controls Interpretation of regional aeromagnetics, radiometrics and satellite image data has identified three structural domains (fig 2): The Fairyland Domain: a general N - S structural trend. The Cracow Domain: a general NW - SE structural trend. The Bald Mountain Domain: a general N- S structural trend. Known mineralisation is confined to the Cracow Domain in which there occurs two major NW - SE trending fault zones. The Cracow Fault Zone (CFZ) and the Immy Creek Fault Zone (ICFZ). Enhanced detail of the CFZ (fig 3) shows three main structural trends within it: NW-SE structures which include the mineralised White Hope South fault zone and the Golden Mile fault zone. NE-SW structures which have an influence on mineralisation in the Orange Creek, Fernyside and Golden Plateau areas. N-S structures comprising several major structural zones.

Jan 1, 1990

In 1997, the Australian coal industry through Standards Australia committee MN-001 Coal and Coke recognised the need to produce a Standard giving some instruction on how to inspect and audit mechanical sampling systems. A Guide was developed by sampling subcommittee MN-001-04 and in 1999 the Standard was released as AS4264.5 æGuide to the Inspection of mechanical sampling systemsÆ Coal and Coke. Since that time the author has assisted with other committees in developing the Guide for other commodities such as concentrates and a generic standard for particulate materials. (AS4433.6 released 2000). The Coal and Coke guide is also currently a work item for ISO Standards. This paper is focused primarily on auditing and inspection procedures for coal mechanical sampling systems. It highlights the need for at least a three level inspection protocol where the operators manning the system maintain operational checks, the operators are regularly supervised by the company managing the system and once per year an independent auditor inspects the whole system to ensure compliance with design and standards. It does not cover short- and long-term maintenance of individual systems. With companies already certified to the ISO9000 series, this guide forms the framework to bring the operation and inspection of their mechanical sampling systems into line with these principles.

Jan 1, 2005

By Kubo H, Ninomiya R, Ojiro T, Sato T

New high-strength Zn alloys for moulds are demanded from the automobile and electric industries in Japan, because the s rength of Zn moulds is still not high enough for the mass production. There are two approaches to improve the strength of Zn alloys. One is to increase the Al content. ZA alloys (ZA-8, ZA-12, ZA-27) were developed through this approach. The other is to increase the Cu content. But it is known that an increase in Cu generally depresses the castability of Zn alloys, so that the alloys with increased Cu have been rarely studied until now. In this study a reconciliation between the strengthening and the castability of Zn alloys by enriching both with Al and Cu has been attempted. Accordingly we have studied on the Zn alloys containing 4 to 25 mass per cent Al and to 24 mass per cent Cu have been studied. Their fluidity, which primarily corresponds to the castability of the alloy, were measured first and 19 alloys were selected based upon their fluidities and casting temperatures. Mainly the mechanical properties of all 19 alloys were tested and some were found to be excellent in both strength and castability. Z1009 (Zn-IOAI-9Cu-0.02Mg alloy) cast in a sand mould has the tensile strength of 360 MPa while ZAS (Zn-4AI-3Cu-0.04Mg alloy), which is the most popular alloy for moulds, is 215 MPa. Z2520 (Zn-25AI-20Cu-0.02Mg alloy) cast in a sand mould has a Vickers hardness of 178, compared to 107 for ZAS and 104 for ZA-27 (Zn-27AI-2Cu-0.02Mg). Furthermore the castability of Z1009 is as good as that of ZAS. The underside shrinkage occuring in casting ZA-27 is restrained in Z2520.

Jan 1, 1993

By Craw D

Quaternary warping and uplift of antiformal schist ranges in Central Otago, New Zealand, has resulted in recycling of alluvial gold from widespread, generally weakly auriferous, Miocene fluvial gravels that unconformably overlie the schist, into aprons of fan sediments along the range margins. Basement erosion during uplift has been limited and so gold input from sparse gold-bearing quartz veins in the schist has been relatively minor. In an eluvial cycle on the slopes of the ranges, chemical remobilization of gold occurs during oxidation and erosion of the Miocene sediments. The typically fine-grained (300-400¦m) gold undergoes chemical modification and grain size enhancement of up to two orders of magnitude, and much of it is redeposited in a large number of relatively small alluvial fans along the range margins. Groundwater mobility within the fans results in minor additional gold mobility and grain size Enhancement.

Jan 1, 1995

By S S. Kanchibotla, D La Rosa, R W. Pesch

The Porgera Joint Venture and Dyno Nobel have commissioned a joint project to optimise the drill and blast operations to increase the overall profitability of the mine. One of the aims of this project is to increase the throughput of semi autogenous (SAG) mills by optimising the blast fragmentation. A number of test blasts were conducted during the period May 2000 to January 2002 and the ore from these blasts was campaigned through the mill. The data from these trials suggested up to 15 per cent increase in the SAG mill throughput with high energy blast designs. However, changes in ore geology (shape, structure and hardness) and potential ore dilution/loss and wall damage have raised concerns about the economic benefits of these designs over the entire orebody. The lack of a system to track the economic benefits of these modified designs has also compounded these concerns. PJV and DynoConsult, the consulting arm of Dyno Nobel have initiated steps to minimise the potential for ore dilution and wall damage resulting from these modified designs. DynoConsult worked with Julius Kruttschnitt Mineral Research Centre (JKMRC) to develop and implement a blast management system to track the quality of blast implementation and down stream process benefits. This paper discusses the implementation of the system and the results achieved to date.

Jan 1, 2003

The operation of quarries for the production of crushed stone and aggregates, depends heavily on rock blasting efficiency, which usually represents a major share of total production costs. After investigating the causes of this situation, a series of technical aspects have been detected, and they are described for the purpose of contributing to the minimization of costs, which also reduces the effects of blasting on the environment. Utilization of empirical design methods, of inadequate explosive types, and of erroneous drilling pauems with respect to rock properties, are the main factors to be corrected, as a consequence of poor engineering criteria, with scarce use of computational methods and field instrumentation. Several concepts of blasting optimization are pointed out, and their application to industrial operations in a Portuguese limestone quarry indicated clear trends for the reduction of production costs, as well as some of the deleterious consequences of blasting on the environment.

Jan 1, 1990

The Blackwater Coal Mine is a modern open cut operation using large draglines for over- :)urden removal and shovels, loaders and trucks to mine and haul coal to the crushing and coal ?reparation plant. Operations at the mine are described in sequence following through overburden removal to the railing of product coal from the mine site. The close operating connection between the mine and washery, which results from the blending of raw coal into clean product via the qashplant bypass system, is stressed. Some features of special interest at Blackwater Mine, such as land reclamation and slope stability,are outlined.

Jan 1, 1974

The application of methods using large diameter down holes has become an important facet in both the development and stoping operations of mines within the Aberfoyle group. Holes of up to 98 metres (vertical) and 78 metres (inclined) have been successfully used in stoping operations. A number of rises have been developed to meet ventilation, servicing and escape-way requirements. The most ambitious rise to date has been a..vertical 93 metre long by 4.50 metre square ventilation rise. Although some early problems were experienced, the ultimate successful completion of this rise has enabled the technique to be incorporated with confidence in future mining plans. This paper summarises experience in long hole rising techniques, their evolution from the original cratering concepts, and the approach to further development of these techniques.

Jan 1, 1982