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By Eugene F. Poncelet

This paper attempts to analyze the phenomena involved in the fracture of brittle solids by simple compression. Glass squares standing on edge, and compressed between two parallel steel jaws, developed jagged fractures, roughly parallel to the compression. Polarized light disclosed the presence of high local stress concentrations indicating poor contact all along the contact surfaces with the steel jaws. Teszar has shown that partial contact between the jaws and such a compressed solid causes tensile stresses in the free surfaces of the solid normal to the compression. Furthermore, Scoble has shown that in brittle solids fractures are caused by, and develop normally to, a sufficient tensile stress. It follows that such "partial-contact" cracks must be expected. With optically flat jaws and specimens, no "partial-contact" cracks developed. Instead, very smooth cracks vertical to the compression appeared 'upon release of the pressure. Investigation showed that the friction with the rigid steel opposed the return of the glass to its original width, after creeping on the steel as compression built up, thus setting up tensile stresses in the glass surfaces. It was not found possible to eliminate these "release" cracks. Compressed to destruction, such specimens flew to dust. A Microflash photograph taken during the explosive disintegration revealed: (I) oblique parallel fragmentation cracks, 30" off the direction of the compression; (2) transverse forking fragmentation cracks, normal to the former; (3) release cracks parallel to the compression; (4) a disintegration cloud. Given a distribution of submicroscopic cracks of random orientation throughout the glass, Griffith has shown the highest tensile stresses to be located at the tip of the cracks 30" off the direction of the compression. Although the preexistence of such cracks or flaws in unstressed glass is doubtful, they can be generated by the distorting forces set up by the compression itself. Atoms, in a structure held together by Morse-type forces or bonds, have under tension both a stable and an unstable state-of equilibrium. The difference in energy level between these two states is a function of the tension, and this difference must be borrowed from the thermal energy level of the bonds to reach the unstable state and result in a broken bond. As the fraction of the bonds having at any instant a sufficient thermal energy level is a known function of that level, it is possible to determine, in function of the prevailing tension, the fraction of the bonds that are broken. Upon breaking of the bond uniting two atoms at the tip of an advancing crack, the two atoms accelerate away from each other, causing in the solid propagation of a

Jan 1, 1944

By Eugene F. Poncelet

This paper attempts to analyze the phenomena involved in the fracture of brittle solids by simple compression. Glass squares standing on edge, and compressed between two parallel steel jaws, developed jagged fractures, roughly parallel to the compression. Polarized light disclosed the presence of high local stress concentrations indicating poor contact all along the contact surfaces with the steel jaws. Teszar has shown that partial contact between the jaws and such a compressed solid causes tensile stresses in the free surfaces of the solid normal to the compression. Furthermore, Scoble has shown that in brittle solids fractures are caused by, and develop normally to, a sufficient tensile stress. It follows that such "partial-contact" cracks must be expected. With optically flat jaws and specimens, no "partial-contact" cracks developed. Instead, very smooth cracks vertical to the compression appeared 'upon release of the pressure. Investigation showed that the friction with the rigid steel opposed the return of the glass to its original width, after creeping on the steel as compression built up, thus setting up tensile stresses in the glass surfaces. It was not found possible to eliminate these "release" cracks. Compressed to destruction, such specimens flew to dust. A Microflash photograph taken during the explosive disintegration revealed: (I) oblique parallel fragmentation cracks, 30" off the direction of the compression; (2) transverse forking fragmentation cracks, normal to the former; (3) release cracks parallel to the compression; (4) a disintegration cloud. Given a distribution of submicroscopic cracks of random orientation throughout the glass, Griffith has shown the highest tensile stresses to be located at the tip of the cracks 30" off the direction of the compression. Although the preexistence of such cracks or flaws in unstressed glass is doubtful, they can be generated by the distorting forces set up by the compression itself. Atoms, in a structure held together by Morse-type forces or bonds, have under tension both a stable and an unstable state-of equilibrium. The difference in energy level between these two states is a function of the tension, and this difference must be borrowed from the thermal energy level of the bonds to reach the unstable state and result in a broken bond. As the fraction of the bonds having at any instant a sufficient thermal energy level is a known function of that level, it is possible to determine, in function of the prevailing tension, the fraction of the bonds that are broken. Upon breaking of the bond uniting two atoms at the tip of an advancing crack, the two atoms accelerate away from each other, causing in the solid propagation of a

Jan 1, 1944

By Stanley D. Michaelson, Ben. H. Slothower

The depletion of most high-grade ore reserves coupled with growing demands for metals and fuels has made it necessary to bring into production increasingly lower grade deposits. Improvements in technology have made lower grade ores economically recoverable in spite of major increases in labor and material costs and the initial investments required to open new mines and build their metallurgical and service plants. To remain competitive, managements of mining companies must keep abreast of and exploit these often complex technical developments. The proper application of these improvements in technology requires extensive and detailed study. In addition, managements of mining and other industries are becoming more deeply involved in public affairs and the myriad of other nontechnical problems common to all industries. These involvements, plus the demands of evaluating technological developments as well as the necessary work related to the routine administration of operations, have required mining managements to delegate additional study and review functions to staff services. To help overcome the problems involved in adopting the best technologies, managements have generally expanded their engineering and research staff services. Integrated, base-metal-producing companies, having open pits, concentrators, smelters, and refineries, are generally more research and engineering oriented than are most smaller mining companies and quarries. However, mining methods for even the simplest open pits and quarries are improving rapidly, and installations of these improvements are essential to combat increasing costs. Because of this, the managements of smaller operations may also require enhanced engineering staff services to realize the potential benefits.

Jan 1, 1968

By H. Van F. Furman

As the cyanide-method for the extraction of gold from ores is extensively used in the United States and elsewhere, and appears destined to prove a factor of increasing importance in the metallurgy of gold, a description of the latest laboratorymethods may prove of interest. The history of the development of the process in the United States has been analogous to that of all new processes. Many failures are to be recorded and a few successes. It is the opinion of the writer that, had the following simple tests been better understood, many of the failures would not have occurred, and we should probably have a larger number of successful plants in operation. While the process is not simple, but requires a high degree of chemical and engineering skill, the determination of the adaptability of an ore to the method is generally not difficult. While the laboratory-results will not always coincide with the actual results obtained in the mill, they will serve as a guide and control on the working of the mill, and mill generally suffice to determine if the ore can be

Jan 1, 1897

By Charles A. Mitke

The Copper Queen mine is composed of seven divisions which are operated through the following shafts: The workings of the different shafts are connected by motor-haulage drifts on the even numbered levels. The general location of the ore-bodies and workings is illustrated by the vertical projection of orebodies of the district as shown in Fig. 1. The Uncle Sam, Southwest, and Czar workings have many connections to the surface through raises and extensive cracks that were caused by moving ground. These divisions are cool and are ventilated entirely by natural means. The Holbrook is ventilated partly by natural and partly by artificial ventilation, while the Spray, Gardner, Lowell, and Sacramento are ventilated entirely by mechanical means. In some of the divisions mentioned above a considerable quantity of air exhausts through shafts of adjoining properties.

Jan 1, 1916

By F. S. Sinnatt

This paper is the outcome of an extended investigation carried out in association with Dr. L. Slater. The inquiry had been continued in various directions and a number of results are quoted from an investigation recently completed by S. H. Jenkins. In projecting the work some five years ago, the author had in view a general attack on the problem of the spontaneous combustion of coal from an angle that had received little attention. The basic idea was to obtain a "slow motion study" of the active combustion of coal. This included an examination of the conditions prevailing in a mass of coal at the moment when active combustion ceases. It was thought that, if the factors governing the extinction of combustion in coal could be definitely established, it might offer an explanation of the manner in which the spontaneous combustion of coal originates. The inquiry arose from a detailed study of the properties of fusain that the author began in 1918. Fusain seemed to possess characteristics quite distinct from the coal with which it was associated, for if it were collected into a heap and one portion were heated by a small flame the combustion would traverse the whole mass. This combustion was not accompanied by smoke and passed slowly through the heap of material. Later, it was found that coals, including anthracites, would behave in a similar manner provided they were in the form of powder and that the particles were smaller than a certain size. The limiting size of particles is a definite characteristic of the coals investigated. In view of the fact that fusain exists with coal in a state that enables it to undergo this particular form of combustion, it must be assumed, sometimes, to play a definite part in the spontaneous combustion of coal in the goaf (waste). Tables 1 and 2 contain the analyses of samples of dust collected from a mine and from a dust collector. Some idea of the degree of fineness of the particles of fusain may be obtained from a study of the analyses of the dust from the dust collector; 80 per cent. of the dust would pass through a 200-mesh screen while the fusain was concentrated in the finest dust. The material that passed through a 90-mesh screen contained 54 per cent. of fusain while that between a 30- and a 90-mesh only con-

Jan 1, 1925

By M. I. Sherman, J. D. H. Strickland

PRELIMINARY experiments in these laboratories showed that whereas pyrite1 produced only sul-fate the action of aqueous chlorine solutions on most other sulfide ores resulted in the formation of a mixture of sulfate and elemental sulfur, the production of the latter being favored by a very dilute solution of oxidant. The reactions taking place were obviously complex and only a detailed kinetic study could be expected to clarify the position and enable a prediction to be made of conditions leading to the rapid formation of metal salt and the economically desirable elemental form of sulfur. Galena was chosen for the first investigation as it is of widespread occurrence and is representative of a simple cubic lattice sulfide containing the monosulfide unit, S2-. Experimental Procedure The apparatus and general technique used in this work have already been described.' Analyses for chlorine and sulfate were carried out by the same methods as those used for pyrite. The lead in 1 ml aliquots of solution was determined polarographi-cally, after destroying chlorine with hydrazine hy-drochloride and making solutions 0.5 molar with hydrochloric acid. A large sample of Kansas galena, assaying at better than 98 pet PbS, was crushed and wet sieved to give fractions of —10 + 14, —20 + 28, —28 + 35, and —48 + 65 Tyler screen. The particles were almost perfect cubes and the apparent surface Per gram was calculated assuming each particle a cube Of side equal to the mean mesh opening. A volume shape factor, calculated as for pyrite, was exactly unity. The main apparatus was unsuitable for direct visual examination of the ore particles during the reaction. For this purpose a small cell from a Spekker Absorptiometer optical flats 1 cm apart) was l by a greased microscope slide after filling with oxidant solution. One or two ore particles were placed in the cell and the solution was stirred by a glass covered speck of iron wire activated by an external rotating magnet. The surface of an ore particle was examined under a binocular microscope at between 10 and 40 magnifications. Results Experiments were made under a wide variety of conditions, the form of presentation of the data being illustrated by Fig. 1, where the concentrations of chlorine, sulfate, and sulfur are plotted against time. The fictitious concentration of solid sulfur is used for convenience and is the molarity of sulfur which would be recorded if the elementary sulfur formed during the reaction were dissolved in the liquid iii the reaction vessel. As some lead sulfate is occluded with the sulfur on the ore particles the amounts of sulfur and sulfate formed during a reaction cannot be calculated

Jan 1, 1958

By R. H. Jacoby, V. J. Berry

Future depletion performance and ultimate oil recovery from reservoirs producing under volumetric control are often predicted with the aid of a material balance equation. When the reservoir fluid is very volatile, however, certain assumptions implicit in the use of the conventional methods are no longer valid. This is became laboratory differential vaporization test procedures do not adequately represent the reservoir depletion process and the performance of surface separation facilities. In such cases recovery of stock tank oil per unit of pressure decline can be predicted only from a detailed knowledge of the separator conditions and the over-all composition of the fluid entering the wellbore at each stage of depletion. Surface recovery is not simply related to the total quantity of liquid flowing into the well under reservoir conditions. In order to improve predictions for reservoirs which produce volatile oils, a step wise method of calculation has been developed. This method uses relative permeability data and multicomponent flash calculations to predict oil and gas production as a function of reservoir pressure. Calculations are presented for a reservoir containing a volatile crude oil, and predicted tank oil recovery by primary depletion is more than twice that predicted by conventional methods which are known to be adequate for ordinary black crude oils. Calculated maximum produced gas-oil ratio is less than one-fourth of the conventional prediction. Wellstream compositions have also been used to determine variation in stock tank oil composition and liquid content of the separator gas. This information is of particular importance for crude stabilization calculations and for design of gasoline plant facilities to recover LPG and natural gasoline. INTRODUCTION The estimation of oil reserves and the prediction of future recovery performance of petroleum reservoirs is a frequent task of the petroleum engineer. If the reservoir produces under volumetric control, performance calculations for primary depletion are made by combining oil and gas material balances with the gas-oil flow characteristics of the reservoir rock. For black oil reservoirs, the Schilthuis1 type material balance is commonly employed. For gas or gas-condensate reservoirs, where only one phase is flowing under bottom-hole conditions, a more simplified material balance is used. In the period in which these material balance methods were conceived and put into practice, it was common to classify reservoirs according to the type of fluid produced as (1) black oil reservoirs, or (2) gas or gas-condensate reservoirs. Recently, however, deeper drilling and more extensive studies of reservoir fluid properties have led to the recognition of reservoir fluids with phase characteristics between those of ordinary black oils, and gases or gas-condensate fluids. These intermediate fluids contain relatively large amounts of the hydrocarbons ethane through decane and are found in deep, high temperature (250°F) reservoirs. Such fluids are often referred to as high shrinkage crudes or "volatile oils." They are usually characterized by tank oil gravities above 45° API. high solution gas/oil ratios,

Jan 1, 1958

The early history of coal in West Virginia is all included with that of Virginia in the few records available but for present-day readers it is much more convenient that the account of this area prior to the Civil War be grouped with that since then. West Virginia shares with Maryland in the first record of coal noted in the Appalachian fields. This was along the upper Potomac River, in the fall of 1736, and the data about it are given under Maryland, as most' of the development of the area was in that state. The next record of coal was left by John Peter Salley in his account of the expedition he made with Howard and others in 1742. (See p. 17.) The next reference found is that of Dr. Thomas Walker, in 1750, when he passed through the Pocahontas coal field. This has been described on page 18. Six years later, in March 1756, Capt. William Preston, who was with Major Lewis in his expedition down Big Sandy River, wrote in his journal: "Tuesday 2.... Moved down the branch and- came to the main creek where we camped. Put on half rations. Came into the Cole land; crossed the river 8 times."1 The party crossed from the head of Clinch River to Horse Pen Creek, then to Jacob's Fork and down it to Dry Fork of Tug River; the coal was seen in what is now McDowell County. The early settlers must have known of the presence of the great Pittsburgh bed in the northern part of the state, both along the Monongahela River and elsewhere, because the outcrops could easily be seen along streams in many. places. The report of the Commissioners for Adjusting Claims to Unpatented Lands, made in 1789, contains several references to coal in the names of streams, made years earlier. The earliest is one for 1,000 acres to James Walker, in Monongalia County, "adjoining his settlement on a branch of the right hand fork of Pappaw known by the name of the Stone Cole Lick made in the year 1773."2 Another of 400 acres in the same locality was settled upon in 1777.2 A third spoke of a tract "on the left hand fork of Stone Cole about three miles from the mouth," in 1783.1 Monongalia County then covered all of the northern

Jan 1, 1942

By L. C. Graton

Although marked by numerous well-known attributes of its own, gold does not possess a kind and range of physical, chemical and geological characteristics wholly different and apart from those of other metals. Instead, it is merely one of the family of metals, with its individual and distinctive traits subordinate to the underlying family relationships and resemblances. The geologist concerned with pure science will pursue, therefore, the same general course and will examine the same broad kinds of facts and interrelations when studying the occurrence of gold as when studying that of copper or cadmium, or any other metal. But when we come to consider the use and economics of the metals, we discover that gold differs strikingly from all the others. Gold, in short, is unique, not by virtue of its inherent characteristics, but because of a peculiar and concerted psychological regard in which it is held. It will be evident, therefore, that the geologist who would deal with gold supply must give far greater weight to economic considerations than is required in his contacts with any other metal. If the geologist be called the scientist of occurrence, and the economist the scientist of use, the economic geologist stands as the necessary link between them. Perhaps it is in part because the economic geologist has made himself more familiar with the science of occurrence than with the science of use and has thus in some degree failed to bridge effectively the gap between the two fields, especially with regard to gold, that the usen1 of gold now appear to be in a state of general concern and even of alarm for the security and adequacy of future supplies. In the case of no other mineral commodity do the users, as a rule, trouble themselves greatly about the adequacy of supply except in so far as that may affect the price which they shall have to pay for the commodity. Oversupply, with resulting low price, they regard as a gift of good fortune. As to long-term undersupply, they are generally content to go ahead on faith, leaving the producer to discover as best he may the means for meeting their requirements or the inventor to find a substitute. But history has shown that for gold a different situation exists. While

Jan 1, 1931

By Howard A. Meyerhoff

Nonmetallic rock and mineral products are so diversified that any generalizations regarding the industries based upon them are of doubtful value and can be misleading. They are geared to every phase of the national economy and respond sensitively and immediately to any economic change, but the responses vary with the individual products. They are also affected by political and competitive factors to a degree that is disconcerting and, at times, ruinous to operators, owners, and stockholders of mineral properties. It is not unusual to find these special factors functioning in reverse of general trends insofar as individual products are concerned. As this summary is being written in the final weeks of 1949 production statistics for the year are not complete, but it is obvious that few, if any, new production records will be set, and that 1949 level, will, in general, be lower than those of 1948. The decline in output is not alarming and reflects in large part the tendency of users, who have been finding sources of supply more dependable to rely on prompt deliveries rather than on inventories to meet immediate needs. Except for the government's program of stock piling which, insofar as it has worked at all, is of more direct interest and benefit to foreign than to domestic producers, industrial inventories have been further reduced, and the neater balance between production and consumption has freed capital for the manufacturer and has cut down the serious hazard of substantial inventory losses. There are no quantity products and only a few special products that cannot be supplied in quick response to current demands. Normal development of a few nonmetallic industries has been retarded by the government's unpredictable application and irrational interpretation of antitrust laws, and by extension of preferential tariffs to new countries and new products. Synthesis is likewise a potent threat. in certain fields, but otherwise it is difficult to make a review of 1949 read much differently from a review of 1948. Changes have been qualitative rather than quantitative, except for a few operations that have been pinched out by the relentless competition that characterizes many of the industrial mineral industries.

Jan 1, 1950

By G. Derge, R. E. Grace

A S detailed studies of mass transport in hetero- geneous systems are made, a knowledge of the chemical diffusion coefficients in various liquid and solid phases is necessary to understand the kinetics of any total reaction. For example, in zone refining some information must be available about the diffusion coefficients of various species in the liquid and solid regions near the moving interface. In liquid-liquid reactions, of which slag-metal reactions are of particular interest to metallurgists, the diffusion coefficient of a transferring species must be known accurately in both phases in order to predict a transfer coefficient for the over-all process. Diffusion data for various elements in liquid iron and iron-carbon alloys have been roughly deter-

Jan 1, 1959

By J. H. Frye, S. G. Holder, E. E. Stansbury

Internal friction studies on annealed and cold-worked pure silver and alloys of silver with 4.5 atomic pct each of Cd, Sn, and Sb are reported. Small amounts of cold work, introduced by stretching pure silver, decrease the internal friction; large amounts of cold work, by wire drawing, cause this decreased internal friction to rise. Results of severol anneoling histories on the room-temperature in-ternal friction indicate a rather complex recovery and recrystallization behavior. A rather system-atic alloy effect is observed for the elements of Period V-B in silver in both the annealed and cold-worked states. DURING recent years internal friction measurements at very small stress levels have been interpreted in terms of structural models and mechanisms occurring within the metal or alloy.These measurements have been made over wide ranges of frequency of vibration and of temperature. While the effects of impurities, alloying, and plastic deformation have been studied by numerous investigators, no investigations of the effect of a series of solutes related by their position in the Periodic Table on a given solvent seem to have been reported. The present paper reports internal friction measurements on silver and on certain silver-base solid solutions to determine the values of room-temperature internal friction associated with varying amounts of plastic deformation and after different annealing

Jan 1, 1957

By S. Y. Ogawa

The effects of sulfur (up to 0.1 pet) on the deformation and fracture characteristics of iron, in cast form, were studied at strain rates up to 100 pct pcr sec and at temperatures of 1600o to -3300 oF. The effects of oxygen and manganese additions on the behavior of Fe-S alloys were studied under comparable test conditions. Brittle fracture characteristics, evident at all strain rates, resulted from the presence of the liquid iron sulfide phase at grain boundaries. Ductility could be restored in three ways: solution of the sulfide in solid y iron at higher temperatures, spheroid-zzation of the liquid sulfide, and increase. in the melting point ot the sulfide. THE literature shows that most previous studies of deformation and fracture at hot working temperatures have been based on measurements of energy absorption, reduction of height in forging upset tests, torsion tests of bar or wire samples, and so forth,' but that relatively few tension tests have been used at high temperatures and strain rates. The present work was initiated to study the ef- fects of temperature, strain rate, composition, and structure on the deformation and fracture characteristics of iron, utilizing cast specimens tested in tension. As in a previous study,' strain rates up to 100 pct per sec were chosen for the temperature range 1600° to 2400° to provide data which might be useful in the interpretation of the deformation and fracture behavior of steels under hot working conditions. The previous work was with Fe-P solid solution al10ys;2 this work is concerned with Fe-S alloys, and with the effects of oxygen and manganese additions. MATERIALS AND PROCEDURE Cast tes! specimens were employed throughout, since most of the difficulty during hot working occurs in the initial breakdown of the ingot. Alloy Systems. Ten 25 lb. heats containing sulphur were prepared. Of these, three had manganese additions, and two had oxygen additions. The sulfur content varied from 0.023 to 0.10 pct. Manganese contents were intended to be ten to twenty times the sulfur content of the particular alloy. Oxygen, being more difficult to control in small melts, was varied by the amount of solid deoxidizer added, but poor control of the oxygen content was experienced in most instances. Table I shows the chemical analyses of the heats. Melting and Casting. Electrolytic-iron chips were melted by high frequency induction in a prefired, clay-graphite crucible lined with rammed magnesite.

Jan 1, 1962

INTRODUCTION Porphyry copper deposits have been reported from the Caribbean area by Pease (1966), Cox, et al. (1973), Guild (1974), Kesler, et al. (1975), and others. This chapter summarizes the most widely known characteristics of those deposits. Only one deposit that conceivably can be classed as a porphyry copper occurrence is in production (Pueblo Viejo, Dominican Republic), but others are known whose tonnage and grade are of economic interest. Deposits in this province may be classified as copper-gold or copper-molybdenum types (Kesler, 1972), but deposits associated with quartz-rich plutons that have high Na2O:K2O and high gold:copper but low molybdenum: copper ratios dominate. Porphyry copper occurrences are reported in the literature from Puerto Rico, Haiti, the Dominican Republic, Jamaica, and Cuba. Only the porphyry copper deposits from Puerto Rico are extensively described in the literature; consequently the Caribbean porphyry copper province in general is not as well documented as the southern Cordilleran orogen. Because past published technical descriptions are incomplete, some data presented here are new to the literature. The Caribbean includes the island arcs between North and South America. Porphyry copper occurrences are known from the Greater Antilles, the generally east-west trending group of islands that lies south of North America. Fig. 48, therefore, only covers the Greater Antilles portion of the Caribbean. Porphyry copper deposits in this area are not described by the Lowell and Guilbert (1970) model in details of metallization (general paucity of molybdenum), alteration (scarcity of orthoclase), or petrography (preponderance of quartz diorite). Therefore, this model should be modified to include deposits associated with quartz-bearing plutons such as those found in the Caribbean. In the Meme deposit on Haiti ore occurs in skarn adjacent to the quartz diorite phase of a composite quartz monzonite-granodio-rite-quartz diorite pluton (Kesler, 1968). This deposit, with a K-Ar 66 m.y. date, is not included in Fig. 48 as a porphyry copper deposit because metallization is restricted largely to the intruded rocks. Although the intrusive rocks at the Meme deposit may contain sulfide near skarn contacts they are otherwise essentially unaltered. Porphyry molybdenum deposits as defined by Clarke (1972) have not been reported in the Caribbean area.

Jan 1, 1978

By G. F. Huff, G. R. Bailey, J. H. Richards

An improved bomb-sampling technique for obtaining samples for oxygen analysis from liquid steel is described. Analyses of samples taken from open-hearth furnaces by the improved method show sufficient agreement with laboratory data to indicate the accuracy of the method is better than that of other existing sampling methods. THE bomb-sampling method of determining the oxygen content of a liquid-steel bath was studied by obtaining and analyzing more than 200 samples from normal open-hearth heats. Of these samples, about 60 were obtained with a bomb of conventional design;' the remainder were taken with a somewhat modified bomb designed to give greater protection against slag contamination. In the new device, the contacting faces of the cast-iron mold halves are machined so that they fit closely; the opening at the top of the bomb is covered with a thin steel cap; and the top of the bomb is further covered with a wood block held in place by heavy steel wire. After the bomb has passed through the slag layer and has entered the steel bath, the wire melts and the wood block floats to the surface. Thereafter, the steel melts through the thin cap and flows into the bomb cavity where it is deoxidized with aluminum wire. An assembled bomb, ready for sampling, is shown in Fig. 1. To standardize sampling procedure, the samples were usually taken through the center door and at the bottom of the furnace; that is, the bomb was on the bottom when the metal cap melted. After each addition to the furnace, at least 20 min elapsed before a sample was taken. The oxygen contents of all the samples were determined by using the vacuum-fusion method, two or more specimens from each sample being analyzed. The specimens were cubes of metal cut from a region in the interior of the bomb sample, as shown in Fig. 2. Drillings for carbon analysis were obtained immediately above the oxygen-analysis region. Reproducibility of Results In determining the reproducibility of the results obtained with the modified bomb, the following four factors were studied: 1—variation in the oxygen concentration of duplicate specimens taken from a single sample; 2—variation in the oxygen concentration of duplicate samples taken in quick succession: 3—effect of the amount of aluminum wire

Jan 1, 1953

By Y. C. Liu, R. H. Richman

Deformation and recrystallization textures of the a solid solutions of Cu-P, Cu-As, and Cu-Sb alloys are examined as a function of composition. It is found that the deformation texture of copper is unckanged up to a composition of 0.43, 0.41, and 0.24 at. pct of phosphorus, arsenic, and antimony, respectzvely, and then the transition to the 70 : 30 brass type of deformation texture proceeds linearly as the logarithm of the solute content. Recrystallization textures consist of strong, new components that do not all bear the usual<111> rotational relation to the deformation components. The dependence of the deformation texture transitions and the recrystallization orientations upon composition and solute-element type is discussed. A systematic evolution of individual recrystallization components in the annealing texture of copper was portrayed as a function of germanium or tin content in a previous study.&apos; Similar patterns of tex-tural change have been observed with copper-zinc alloys,2 and in less detailed studies of other systems.3,4 In fact, most of the literature dealing with preferred orientations in copper alloys indicates that the influence of solute elements upon textures in copper is of one general type. As the alloy content of copper is increased, the deformation texture changes from the copper type to the 70:30 brass type, and the annealing texture undergoes a comparable change from the (001) [ loo] orientation of unalloyed copper to the {113} <211> type of 70:30 brass, with the notable exception of copper alloyed with Periodic Subgroup V-B elements.4-8 In almost every case it is possible to describe the reorientations after annealing as 30 to 40 deg rotations about <1ll> poles of the deformation components. Since there is apparently not much difference in the final textures of the copper binary systems already investigated, only a limited variety of preferred orientations has served as the basis for current theories of the origin of annealing textures. In order to test the validity of the proposed theories, and the possibility that the <111> rotations are not unique, it would be most desirable to study the reorientation relationships of additional, and heretofore unanalyzed, recrystallization components if such components exist. Examination of the literature reveals a good deal of uncertainty concerning preferred orientations in copper alloyed with elements in Subgroup V-B of the Periodic Table. Phosphorus is known to inhibit the cube texture in copper when present in amounts as low as 0.01 wt pct,8 but the recrystallized matrix that occurs instead of the cube orientation was reported as either random or weakly textured, with orientations not observed in Cu-Zn, Cu-Ge, or Cu-Sn alloys.4-9 A Cu-0.75 at. pct As alloy apparently contained, along with the (001)[100] and (113) <211> type of recrystallization components, {110} <112> and (110) <001> components, whereas an almost random distribution of orientations was found in alloys of higher arsenic content.4 A {110} <001> component also appeared in rolledand annealed Cu-Sb alloys, but otherwise the recrystallization textures of Cu-Sb alloys seem to con-

Jan 1, 1962

By J. L. Gregg, C. W. Kuttner

ReceNtly there has been considerable interest in the production and use of extra hard alloys composed primarily of tungsten and carbon. Dr. Hoyt&apos;s recent paper1 gives a good description of these alloys and describes their performance when used as tools. There are a number of these alloys on the market sold under various trade names, and it is the purpose of this paper to describe the results of an investigation of the structure of five of these alloys by means of microscopic and X-ray methods. The samples studied were in the form of small tools or wiredrawing dies, which were either purchased or supplied as samples. They were in some cases not supplied by the original makers but were furnished by the agents in this country, and we wish to call attention to the fact that they may not be truly representative of the materials supplied under the various trade names No performance data are given and no inference as to the inferiority of one alloy as against any other is made. K. Schröter2 recently described methods for polishing alloys of this type for microscopic examination and has presented photomicrographs of several alloys. However, he did not identify their constituents or describe methods for their identification. Constituents and Their Identification As far back as 1915 attempts were made to utilize tungsten carbides commercially, but the great brittleness of these carbides made these first attempts unsuccessful. Later, successful dies were made by sintering the powdered carbides with small amounts of iron, nickel, or cobalt. Due to the high melting points of the tungsten carbides (2600" to 2800" C.), it is difficult to melt the carbides without volatilizing almost quantitatively the added element of the iron group. Inasmuch as the added metal does not exceed 20 per cent. and is usually present in much smaller amounts, some understanding of the tungsten-carbon equilibrium dia-

Jan 1, 1929

By C. W. Kuttner, J. L. Gregg

ReceNtly there has been considerable interest in the production and use of extra hard alloys composed primarily of tungsten and carbon. Dr. Hoyt&apos;s recent paper1 gives a good description of these alloys and describes their performance when used as tools. There are a number of these alloys on the market sold under various trade names, and it is the purpose of this paper to describe the results of an investigation of the structure of five of these alloys by means of microscopic and X-ray methods. The samples studied were in the form of small tools or wiredrawing dies, which were either purchased or supplied as samples. They were in some cases not supplied by the original makers but were furnished by the agents in this country, and we wish to call attention to the fact that they may not be truly representative of the materials supplied under the various trade names No performance data are given and no inference as to the inferiority of one alloy as against any other is made. K. Schröter2 recently described methods for polishing alloys of this type for microscopic examination and has presented photomicrographs of several alloys. However, he did not identify their constituents or describe methods for their identification. Constituents and Their Identification As far back as 1915 attempts were made to utilize tungsten carbides commercially, but the great brittleness of these carbides made these first attempts unsuccessful. Later, successful dies were made by sintering the powdered carbides with small amounts of iron, nickel, or cobalt. Due to the high melting points of the tungsten carbides (2600" to 2800" C.), it is difficult to melt the carbides without volatilizing almost quantitatively the added element of the iron group. Inasmuch as the added metal does not exceed 20 per cent. and is usually present in much smaller amounts, some understanding of the tungsten-carbon equilibrium dia-

Jan 1, 1929

By W. R. Shimer

IN his valuable report on Finishing Temperatures and Properties of Rails, I Dr. G. K. Burgess, Chief of the Division of Metallurgy, U. S. Bureau of Standards, has begun a line of investigation which should be continued by those interested in the subject, and who have proper facilities for carrying put the work. For the past year or more the Bethlehem Steel Co. has been conducting experiments to learn the effect of rail finishing temperatures on their physical properties and microstructure and the results are here given for the consideration of those interested in the rail situation. . Considerable differences of opinion have been expressed by various authorities, in the past, as to the effect of large or small grain size and high or low finishing temperatures of steel rails on their physical properties and wearing qualities. Low finishing temperatures and, therefore, low shrinkage, have been advocated on the theory that the wearing qualities would be improved. Others have recommended high finishing temperatures. The generally accepted cause for rail failures, due to the development ,of transverse fissures, is excessive wheel pressure on hard rails. One of the causes advanced for hard rails has been that they contain too high per centages of carbon and manganese; another that the rails were finished at too low a temperature, i.e., at or near the critical point. In the experiments herein described the rails were rolled from reheated blooms. All the rail blooms were charged hot in a reheating furnace and brought up to about the original ingot-rolling temperature before rolling into rails. These rails gave better results in deflection, withstood a greater number of drops before breaking, and showed greater ductility, than. rails of identically the same composition and section which were rolled, direct from the ingot. Rails rolled from reheated blooms, finished at somewhat higher temperatures than when rolled direct from the ingot, have a different microstructure, which the writer does not believe is due so much to the difference in finishing temperatures, as to the difference in

Jan 3, 1915