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By Stefan Larsson, Jan Ekström, Jennie Kock-Larsen, Håkan Garin

"This paper describes the testing procedure (or protocols) for quality control of dry deep mixing columns in a major ground improvement project carried out in Sweden. Quality control was mainly based on column penetration tests performed at different stages in the project and on two occasions after installation. In the paper, the results from the tests are compared with tests on the unimproved clay. As expected, the results show that the correlation between undrained shear strength in the columns and in the unimproved soft soil depends mainly on the in-situ stress. However, the correlation probably depends on when the tests were performed after mixing. When the influence of the in-situ stress was excluded from the analysis, no significant correlation could be identified. This means that the undrained shear strength in the columns and in the unimproved soft can be considered to be uncorrelated when the strengths and the corresponding variability are evaluated with depth from groups of tests.INTRODUCTIONQuality control and quality assessment of deep mixing (QC/QA) constitute a key component in verification of the limit state design. Due to the complex mixing process and varying geological conditions, it is normally not possible to sufficiently assess the strength and deformation properties in advance. In Sweden, the most commonly used QC/QA method for verification of the limit state is the column penetration test (Axelsson and Larsson 2003; Bergman et al. 2013). The method works well but is time-consuming and requires many tests since property variability is normally high. The column penetration test can be used to assess the undrained shear strength Cu,col. However, it is not clear how the strength correlates to the undrained shear strength of the unimproved soil Cu,soil. There are common factors such as the in-situ stress state and the natural water content, which makes a positive correlation probable, i.e. as Cu,soil decreases, Cu,col also decreases and vice versa. The unimproved soil has a natural spatial variability, but it is not known if the improved soil follows the same variation. The mixing process has a substantial influence on the strength variability and may supersede the influence of other factors. However, if a sufficiently good correlation exists between Cu,col and Cu,soil, information from the geotechnical ground investigations can be used in the design and planning of QC/QA of deep mixing in a more stringent manner. Information about the correlation is also essential in reliability based design, where a strong positive correlation may have a negative influence on reliability. However, as discussed by Al-Naqshabandy and Larsson (2013), this correlation may be weak or insignificant for a representative failure domain where the mixing process may have a dominant influence on the strength variability. It is thus of interest to assess the correlation."

Jan 1, 2015

By J. García, B. Arango, F. Calderón, O. J. Restrepo-Baena, A. Carreno, L. Rojas-Mendoza, J. Pérez, E. Bedoya

"Tungsten extraction is a subject of global interest due to is properties. These properties, such as its high melting point, have contributed to the development of metallurgical extraction processes that can be adapted to the particular chemical composition and mineralogy of the ore. In Colombia there is a research deficit in tungsten related areas, and especially with regard to its extractive metallurgy. In this study the physical, chemical and mineralogical characterization of a sample were performed. Subsequently, crushing and grinding were employed to reduce the material to a more convenient size, making it suitable for further concentration and metallurgical processes. Through physical concentration techniques it was obtained a concentrated ranging between 60 -70 % of WO3 content.INTRODUCTION Tungsten is a metal of great economic importance due to its excellent properties such as high density and extraordinary melting point 3422°C), which is indeed the highest of all the elements. Tungsten is primarily used in metal alloys, manufacture of special steels, coatings and catalysts; products of interest to both international and national industry. However; given that the use and economic value is determined by the percentage of tungsten in the mineral, particle size and chemical associations, it becomes essential to properly characterize the mineral to further define possible metallurgical extraction routes. The metallurgical processes for minerals enriched in tungsten may vary depending on location and the genesis of the ore body, which means that for each ore a particular set of operating conditions must be determined. This is important since process standardization can lead to misuse of the mineral resource. However, in Colombia there is a research deficit as it relates to minerals enriched in tungsten and to its extractive metallurgy. Then, there is a need to conduct studies that can lead to a better understanding of the ore, and to develop extraction processes for the metal of interest. EXPERIMENTAL A state of the art review was made in order to gain insights of the tungsten metallurgical process. Comminution was necessary with the aim to reduce the sample size; therefore the sample was taken into crushing and grinding stages. Concentration techniques such as magnetic separation, gravity and / or electrostatic were also applied. Physical, chemical and mineralogical characterization were performed by using polished sections, grain size determination, X-Ray Fluorescence (XRF) and X-ray diffraction (XRD) techniques."

Jan 1, 2015

By Félix Lewandowsky

El presente texto describe las actividades para corregir los pasivos ambientales heredados y asumidos bajo responsabilidad de la Compañía Minera Colquirrumi S.A. Para ello, se elaboró un plan de cierre de los cuatro depósitos de los relaves de Hualgayoc donde se busca mostrar los criterios utilizados, los estudios de ingeniería y la forma cómo se ejecutaron las obras de cierre definitivas de los depósitos de relaves.

Jan 1, 2015

By F. J. Macias, A. Bruland, F. E. Dahl

"Tunnelling by use of Tunnel Boring Machine (TBM) is gaining a greater presence as a suitable excavation method. Disc cutter consumption has a strong influence on performance and cost when using TBMs and the influence becomes even more relevant in hard rock. Furthermore, good predictions of TBM performance and cost facilitate the control of risk as well as avoiding delays and budget overruns. Since abrasive wear is the most common process affecting cutter consumption, good laboratory assessments are needed. A new abrasivity test method called Rolling Indentation Abrasion Test was developed. The goal of the new test design and procedure is to reproduce wear behaviour on hard rock tunnel boring in a more realistic way than traditionally used methods by introducing wear by rolling contact on intact rock samples. INTRODUCTIONHigh investments are involved in the tunnelling industry, especially in Tunnel Boring Machines (TBMs) projects. Performance predictions and cost estimations are crucial for planning and risk management of TBM projects. Cutter consumption has a large influence in terms of time and cost, and an even greater effect in case of hard rock projects. Many factors are influencing the amount of cutters consumed in hard rock TBMs. Normal TBM operation results mainly in abrasive wear on the cutters and appropriate methods for abrasivity assessment are needed. Rock abrasiveness cannot be considered as an intrinsic property and the complete tribological system should be considered in addition to the geological properties of the rock.In the present paper, a new test method for abrasivity assessment in tunnel boring called Rolling Indentation Abrasion Test (RIAT) is presented. The traditionally used test methods for determination of rock abrasiveness uses sliding or impact contact in order to cause wear while the RIAT introduces rolling contact on intact rock samples. The ambition of the new test device is to have a reliable method to evaluate the cutter wear in hard rock tunnel boring by reproducing wear behaviour on rolling disc cutters in a more realistic way. It has been established by many authors that the abrasion of a cutter ring is proportional to its rolling distance (Rostami, 1997; Bruland, 1998). In the present work, the weight loss of a mini-cutter ring is measured subsequent to testing in order to evaluate wear in the rolling process and could hence be related to cutter ring wear. Indentation of the tools in the intact rock sample is considered as an indication of the surface hardness of the rock or the resistance to indentation by rolling."

Jan 1, 2015

By Yi Yang, Mark Zoback

"We report laboratory studies of the time-dependent deformation of core samples from four different formations in the Williston Basin - the Lodgepole formation, the Middle and Lower Bakken formations and Three Forks formation. The laboratory tests reveal varying amounts of viscoplastic deformation in response to applied differential stress. The time-dependent deformation is generally greater in rocks with higher clay and organic content, and can be described by a power-law function. Because the magnitude of the creep strain is linearly proportional to the applied differential stress, we can utilize viscoelastic theory and geophysical logs to estimate the degree to which tectonic stress is affected by viscoplastic stress relaxation. We suggest that viscoplastic stress relaxation results in the Upper and Lower Bakken Formations act as frac barriers during hydraulic fracture stimulation in the Middle Bakken, but the Lodgepole and the Three Forks Formations are not frac barriers.INTRODUCTIONHorizontal drilling and multi-stage hydraulic fracturing in shale reservoirs are critical for successful exploitation of ultra-low permeability shale gas, tight gas and shale oil reservoirs. Characterization of the mechanical properties of the reservoir rocks is essential to understanding the behavior of rocks during drilling and completion. Previous laboratory studies have shown that the timedependent deformation in clay-rich shales can be characterized as linear/viscoelastic deformation (Chang et al., 1997; Hagin and Zoback, 2004a, b; Sone and Zoback, 2013b, 2013c). Sone and Zoback (2013c) showed that laboratory measurements of time-dependent deformation in various gas shale reservoir rocks, and demonstrated that the viscoplastic deformation of these rocks can be characterized by a power-law function. They interpreted the results in the framework of linear viscoelastic theory to quantitatively assess the geomechanical effect of viscous time-dependent deformation over engineering and geological time scales. (Sone and Zoback, 2014) further extended the theory and proposed a viscous relaxation model that can be applied to predict the continuous differential stress magnitude using the geophysical logs. They tested the validity of their model by comparing the stress prediction with the occurrence of drilling induced tensile fractures (DITFs) and the vertical hydraulic fracture penetration observed from microseismicity."

Jan 1, 2015

By A. Hartikainen, M. Rinne, F. Johansson, R. Yorke, L K. T. Uotinen, E. Korpi, J. Antikainen

"In order to determine the in-situ shear strength of rock joints, large scale testing is required. However, this is both expensive and difficult to execute. One possible method to overcome this may be to use photogrammetry to capture large joint surface roughness in-situ and downscale it to replica samples, which could be sheared in laboratory. In this paper, as a first part in such a method, a technique to digitize surface roughness and to produce replica samples for laboratory shear testing from a larger joint sample are presented. First, a thin granitic rock slice with dimensions of 1.75 m x 0.95 m of granitic intact rock was chosen for the study. The joint surface is fresh and created through tensile induced splitting. The large joint sample is digitized using photogrammetry. Then, one fullscale 1.7 m x 0.6 m geometry is cropped from the digitized joint geometry and then subsamples at 10x, 7.5x, 5x, 2.5x and 1x scales. All sub-geometries are scaled down digitally to produce 0.17 m by 0.06 m geometries. The geometries are used to make casting molds both positive and negative to produce samples with perfect matedness. The casting molds are 3D printed in polylactic acid plastic and C60/75 concrete is cast to produce a replica series. In addition to the creation of this replica series, two pilot replicas are also tested using a portable shear box with a 0.5 MPa normal pressure. The results from the pilot rounds are presented and discussed. Finally, suggestions for future research are given.INTRODUCTIONThe rock mass strength is in many cases controlled by the shear strength of rock joints, especially in hard rock masses. The shear strength is generally found to be influenced by several parameters, including normal stress, the basic friction angle of the intact rock, the joint surface roughness, the joint wall compressive strength, the matedness of the joint surfaces, weathering and infilling. The effect of these parameters for the joint shear strength can be evaluated in laboratory scale. However, the shear strength is known to be scale dependent. How the scale effect influences the strength is not fully understood. The general consensus is that the shear strength decreases when sample size increases, i.e. a negative scale effect (Bandis et al. 1981). However, some studies have presented contradictory results, see for example Hencher et al. (1993) and Kutter & Otto (1990). The extent and nature of the scale effect is still a question of debate (Tatone & Grasselli 2013)."

Jan 1, 2015

By P. R. La Pointe, J. Clark

"Studies have shown that the roof in coal mines is nearly twice as likely to fail at intersections as at entries due to enlarged roof spans, stress redistribution and other factors. However, the relative stability of intersections in a mine varies, and an improved understanding of what factors impact roof instability can lead to efficient, proactive mining practices that both enhance stability and mining efficiency.A study was undertaken at an underground longwall coal mine to develop a model to predict the stability at the intersections of entries and cross-cuts. The statistical analyses relied upon observational and measured data regarding the development of tension cracks, seepage, intersection geometry, mining practices, geological attributes and geomechanical factors at 783 intersections. Each intersection was given a NIOSH roof. Common data mining techniques, such as multivariate linear regression, multinomial logistic regression, decision trees and probabilistic neural nets, were considered and evaluated to establish correlations and associations between stability and the other variables. Two of the more successful techniques were Decision Trees and Multinomial Logistic Regression. The analyses showed that a number of factors impacted stability:• Overburden thickness (impact on stress concentration magnitudes)• Initial opening area (impact on stress concentration magnitudes)• Sulfur content (depositional environment & impact of mechanical properties, leaching effects)• Intersection type (impact on stress concentrations)• Gob distance (impact on stress concentrations)• Presence or proximity of a particular sandstone (impact on mechanical properties)• Roof bolt type and diameter (impact on reinforcement)Some factors showed no statistically significant relation to stability. These included:• Total area• Supported areaSeepage was a more problematic variable in assess. Seepage is associated with instability, but it is not clear whether seepage occurs as a consequence of instability, for example, through the creation of tension cracks, or whether the intersection has been excavated where water already exists and has degraded the rock prior to excavation, leading to greater instability.Seepage appears related to the geology of the roof rock mudstones, not the sandstones. Tension cracks in the intersections occur preferentially where the Sulfur content is below 0.9%. The Sulfur may relate to mechanical differences in the roof rock, and where the Sulfur is low, the roof is less stable, there are more tension cracks, and seepage is greater. This suggests that the weaker mudstones may be more prone the development of tension cracks, not because these rocks are more brittle, but possibly weaker.2-way and 3-way intersections appear to have less seepage than 4-way, although very few intersections overall have any seepage. This is similar to the roof stability, in which the 2-way and 3-way are more stable. 2-way and 3-way intersections have fewer-than-expected tension cracks, while 4-way have more than expected. These results suggest that four-way intersections are weaker and more prone to tension crack development, also suggesting that increased seepage results from weaker roof conditions, rather than the converse. Thus seepage appears to be mostly a consequence of instability rather than a cause and is higher where there are 4-way intersections, mudstone geology and external loading factors like depth of cover and proximity to gob that promotes crack development. The study also indicated that a better understanding of the mudrock facies could reduce uncertainty."

Jan 1, 2015

By K. Soucek, J. Ptácek, A. Hastíková, R. Kukutsch, P. Konícek, P. Waclawik

"Cable bolts are used frequently as a secondary support system (with steel arch support) in difficult stress-strain conditions of deep coal mines. The load transfer mechanism of cable bolts depends on several factors, such as the strength, deformation and geometric properties of the bolts, resin and the surrounding rock mass so-called cable-resin-rock system (CRR system). The bonding length and bolt/borehole diameter ratio strongly influence the final bearing capacity of the CRR system.The study presents the behaviour of CRR system during a pull-out test which is usually used in the carboniferous rock mass in the Czech part of the Upper Silesian Coal Basin. A series of 28 pull out tests were performed on 3-m-long cable bolts, with various combinations of borehole diameters and bonding lengths, to understand this behaviour. Boreholes were drilled into a solid rock mass consisting of fine-grained sandstone to guarantee similar conditions during the pull-out tests. Video inspection and measurement of borehole diameters were performed to determine their quality and real diameters. Three characteristics were observed from pull-out test results: ultimate pull-out load; displacement of the end of bolt and system stiffness. Numerical modelling by FEM (Finite Element Method) was used to determine the stiffness of the CRR system for variable bolt/borehole ratios and bonding lengths each under constant load. A linear elasto-plastic model and a mohr-coulomb model were used for cable and resin-rock respectively. The results of the experiment may contribute significantly to improving of the methodology of cable bolts installation as well as the design of used cable bolts."

Jan 1, 2015

By J. Mizera, J. Zdunek, K. J. Kurzydlowski, A. Dobkowska

This work concerns comparison of corrosion resistance of the aircraft aluminum alloy composed of Al - 2.3%Li - 0.1% Zr. The alloy was hot rolled (HR) from 13 mm to a thickness of 4 mm (e = 2.4) and 1 mm (e = 5.2). Corrosion resistance was investigated by Potentiodynamic Polarization Test. The investigation relied on exposure samples in two different corroding medium: 0.5 M NaCl solution and 0.01 M Na2SO4 solution with added 0.01% of Cl- at room temperature. Furthermore, the microstructure was analyzed using the optical microscope with polarized beam. The hardness was measured on lengthwise profile. It was stated that alloy after the largest deformation (equivalent total strain e = 5.2) is characterized by the best mechanical properties and the best corrosion resistance. The alloys in initial state and after deformation to 4 mm (e = 2.4) are characterized by worse corrosion resistance. It is associated with microstructure and density of dislocation in analyzing material.

Jan 1, 2015

By A. S. Ibrado, D. W. Fuerstenau

"Gold, silver and copper form various complexes with cyanide, of which only the singly charged dicyano form adsorbs appreciably on activated carbon. The adsorption of the dicyano complexes appears to be controlled predominantly by chemical reaction at the surface of a shrinking unreacted core. Metal uptake over time is non-linear, which eliminates control by boundary layer diffusion. The rate of adsorption is not enhanced by a reaction interruption, which suggests the absence of concentration gradients in the pores. Finally, the rate of adsorption increases with decreasing activated carbon size in a manner consistent with the shrinking core model. The results of this investigation accentuate the importance of efficient acid washing of carbon and removing carbon fines from the barren carbon stream. INTRODUCTION With the dwindling reserves of high-grade ores, most of the world’s gold is produced from low-grade ores by cyanide leaching. In the past, leaching was followed by the Merrill-Crowe process, in which gold is precipitated from clarified pregnant solutions by zinc cementation. This process is still being used for high-silver ores, where the cost of carbon stripping becomes prohibitive. For deposits with silver-to-gold ratios of about 4 or less, adsorption on activated carbon would be the usual solution purification step taken. The process simplifies solid-liquid separation and offers a viable solution to preg-robbing organic carbon in some ores. The modern industrial application of carbon adsorption started with the carbon-in-pulp (CIP) process, where carbon adsorption was used mainly as a solution purification step. In 1973, Homestake Mining Company commissioned the first large-scale CIP plant in the U.S.A.1 Later, carbon was added earlier in the circuit to control preg-robbing by adsorbing gold cyanide onto activated carbon as soon as it is dissolved. The scheme is successful because activated carbon is a stronger adsorber than the organic carbon found in preg-robbing ores. This process came to be known as the carbon-in-leach (CIL) process. Numerous research investigations have been performed on the chemistry involved in the CIP process, which at the time of its introduction was not clearly understood. Of these, research on the kinetics of adsorption probably bears the most immediate impact on industrial practice,2,3 where adsorption systems rarely reach equilibrium, if at all, and slight slowdowns in the adsorption rate can translate into significant decreases in revenue. To illustrate this, organic compounds, like flotation reagents, have been known to impair CIP circuits. However, laboratory tests showed that the organic compounds do not significantly affect the adsorption capacity of activated carbon. Rather, the harmful effect may be attributed to a lowered adsorption rate.4,5 Also well known is the faster rate at which fine activated carbon powders reach equilibrium compared to coarse activated carbon, even though the final (equilibrium) amount of material adsorbed per unit weight is the same."

Jan 1, 2015

By K. Bommer

"In today’s fast paced, globally competitive world, reliability and machine uptime are of the utmost importance to a successful operation. Along with these targets more emphasis is being put on cost reduction and decreasing the environmental impact of the overall system. To achieve these goals, automatic lubricators and lubrication systems have been used in many industries for years and are now becoming a common tool in the mining industry as well. These systems are able to provide proper lubrication amounts at the proper times autonomously, helping to keep the machines running smoothly while minimizing the physical support required. Copper mines in the southwest have begun utilizing auto lubrication to avoid mistakes and unplanned shut downs on critical equipment. This paper will describe the engineering behind these products and review case histories where these tools have been successfully utilized in the mining industry. INTRODUCTION In a dirty, dusty, wet environment, where machine uptime is imperative, proper lubrication of bearings is the only way to survive. With the push for cost reduction and mines striving to lower their environmental impact and increase worker safety according to MSHA guidelines, the old lubrication practices have come under scrutiny. It is no longer encouraged or cost effective to have maintenance personal walk from point to point throughout the entire mine pumping a shot of grease into each bearing once per shift. Automatic lubricators and lubrication systems have been on the market for years but recently, as the market focus has changed and technology has developed, the use of these systems has begun to rise in the mining industry. Automatic lubrication systems can be as simple as a single point lubricator lubricating one (1) bearing or a more complex system lubricating numerous bearings. With system design, the automatic lubricator provides a preset amount of grease to a bearing at regular, predetermined intervals. The systems designed to lubricate more than one bearing contain grease pumps of some design and possibly PLC controllers which can be used to remotely adjust and monitor the system. As can be seen in Figure 1, the right amount of lubrication can be achieved much more reliably with automatic lubricators. Depending on application needs, the market now has products to fit almost every wish list. This paper is going to focus on the single point systems that are lower in cost but are still being effective."

Jan 1, 2015

By H. Huang, Y. Takasaki, R. N. Gow

"The presence of enargite (Cu3AsS4) is problematic in gold processing not only because it is environmentally hazardous due to its arsenic content but also because it is refractory, causing both cyanide and oxygen consumption to increase. Selective leaching and treatment of the arsenic would prove advantageous prior to applying conventional gold leaching methods. The reactivity of enargite samples from Butte in Montana and Quiruvilca in Peru were spectroelectrochemically studied under alkaline conditions – pH range of 8-13 – using Raman spectroscopy and cyclic voltammetry. Raman spectra of the surface were collected during and after potentially cycled voltammograms in order to determine and compare surface species against theoretical EH-pH diagrams constructed from mass-balanced thermodynamic calculations using STABCAL software. Under slightly oxidizing conditions, covellite (CuS) peaks were found in a short matter of time, above ~100mV vs. SHE for pH 9-13, suggesting arsenic leaching specifically occurred. At longer conditioning times, elemental sulfur was observed and tended to passivate the surface. The presence of elemental sulfur suggests that copper was eventually leached from the surface. By operating above pH 12, under slightly reducing conditions near -300mV vs. SHE, arsenic can be selectively leached as thioarsenate (AsS4 3-) or thiosulfate (AsO4 3-) without sulfur formation.IntroductionEnvironmental limitations on the pyrometallurgical processing of ores and concentrates bearing arsenic and other hazardous elements often outweigh those in hydrometallurgical processing, particularly when minerals like enargite (Cu3AsS4) are present. The hydrometallurgical processing of enargite-bearing materials can be broken down into two categories: the co-dissolution of arsenic and copper under acidic conditions, and the selective leaching of arsenic under alkaline conditions. The selective leaching of arsenic would preferably leave behind copperrich sulfide phases, typically chalcocite (Cu2S) and covellite (CuS), which then become more amenable to conventional copper (and gold) processing. Furthermore, selective leaching often employs sulfide (S2-), bisulfide (HS-) or polysulfides (Sx 2-) to first extract the arsenic as AsS4 3- and AsS3 3- (Delfini et al., 2003; Anderson and Twidwell, 2008; Tongamp et al., 2010a,b). However, hypochlorite leaching (Viñals et al., 2003; Curreli et al., 2005; Mihajlovic et al., 2007), ammoniacal leaching (Gajam and Raghavan, 1983), and finegrinding to mechanically activate the enargite surface (Balaz and Achimovicova, 2006) have been investigated to increase the normally slow reaction kinetics. Because gold ores are becoming more refractory due to increasing arsenic contents as a result of enargite, these methods are being examined more closely by the gold-mining industry."

Jan 1, 2015

By Justin Cardwell, Alyson Cartwright

"Grade estimation is the cornerstone of longrange mine planning. Pit designs, metal recovery, mining costs, reserves calculations and reporting are all dependent upon a reliable grade model. If the geology is poorly understood or the interpolation methods and parameters have been haphazardly constructed, then massive financial losses will be the inevitable outcome. Therefore, a properly trained geologist must use all of the appropriate tools available including deposit knowledge and advances in modeling technology to construct the most geostatistically and practically sound long-range block model.Certain deposits, such as the sedimenthosted deposits at Tenke-Fungurume, require an interpolation method that best suits the style of mineralization. In 2014, Hexagon Mining developed a tool in MineSight called dynamic unfolding (MSDU) that has the potential to improve upon previous Euclidean-based interpolation methods. MSDU utilizes the nonstationarity of a folded grade trend to more accurately construct variograms and improve interpolation results based upon a modeled three-dimensional surface.Geology overview. The sediment-hosted Tenke-Fungurume mining district is located in the southeastern part of the Democratic Republic of the Congo (Fig. 1). The rocks within the district are primarily dolomites and shales from the lower half of the Roan Supergroup that were mineralized by ascending pregnant copper and cobalt rich brines within a massive sedimentary basin (Cailteux et al., 2005) (Fig. 2). These oxidized brines likely found a fluid channel in the porous RSC unit. The surrounding rock units provided a redox boundary for copper and cobalt precipitation along organic rich beds, forming a massive stratabound deposit that was later broken up by several subsequent tectonic events (Dewaele et al., 2006)."

Jan 1, 2015

By Manjeet Chowdhry, Qingxia Liu, Phillip Choi, Zhenghe Xu

Computational chemistry methods, such as density functional theory (DFT), are powerful tools to quantify reagent-mineral interactions encountered in sulphide mineral flotation. A quantitative relationship between theoretically calculated parameters based on chemical structure of collectors and their reactivity with different metals/minerals can provide valuable insights for design and development of more powerful and tailor-made reagents offering enhanced metal/mineral selectivity. DFT calculations at B3LYP/6-311++G(3df,3pd) level were employed to elucidate the reactivity of neutral sulphide collector reagents, including thionocarbamates (TC), thioureas (TU), xanthogen-formates (XF), dialkyldithiocarbamates (DTC) and dialkyltrithiocarbonates (TTC) with different heavy metal ions (Cu2+, Zn2+ and Pb2+) in solution. The extent of delocalization of lone pair electrons of heteroatoms (attached directly to C in C=S) over C=S group was found to be the dominant factor in determining the collector’s reactivity. Order of reactivity was established as: TU > TC > XF > DTC > TTC. All the collectors showed superior affinity towards copper followed by lead. Unidentate binding was observed through sulphur atom except for xanthogen-formate for which bidentate binding mode was observed. Effect of nature of substituent groups at N and/or O atom on reactivity of thionocarbamate and thiourea was also investigated. The results obtained through DFT calculations are consistent with the experimental data reported in literature.

Jan 1, 2015

By Dworzak, Andrzej Biessikirski, Jozef Pyra

During the detonation process 20-30% of the energy is being consumed only on the quarrying pro-cess. The remaining amount of the energy generates harmful effects such as: shock wave, acoustic wave, fly rocks and ground vibrations. The ground vibrations effect is the most dangerous especially to structures which are situated nearby an open pit mine.

Jan 1, 2015

By N. Behnood

"This paper describes how material selection, quality assurance, and failure investigation play important roles in the efficiency and safety of mining and metallurgical operations.INTRODUCTION Material selection, quality assurance, and failure investigation are all complementary elements of materials engineering in the application of materials technology for failure prevention. Based on commodity price increase of 300% between 2002 to 2013 [1] and increased cost ofcapital projects and operation, equipment failure, which in some cases causes complete shutdown of the operation, becomes a vital importance in mining and metallurgical plants. The following sections present a number of examples from many failure cases experienced by the author during his three decades of work as a materials engineer in the mining industry."

Jan 1, 2015

By Brian Danyliw

"Dust control is an increasingly important consideration for all mining operations from a health, safety, environmental and maintenance perspective. Modern mining operations incorporate a variety of mechanical dust control techniques into design however in many cases these engineered systems are unable to meet desired fugitive dust level targets. In these cases a variety of chemical dust suppression options are available to operators to assist in meeting their targets. This paper provides an overview of available chemistries, discussion of application techniques and equipment requirements and available performance monitoring technologies. This paper will also include a number of case histories discussing the treatment approach chosen, challenges encountered, chemical feed, storage and application equipment, monitoring techniques employed and results achieved.INTRODUCTIONDust FundamentalsFugitive dust by definition is an aerosol consisting of particulate matter suspended in a gaseous medium. Aerosols can include suspensions of particulate (solids) or sprays (liquids) or a mixture of both. Of particular concern from an occupational health and safety perspective are aerosols of particulate matter due to their involvement in classical occupations lung diseases such as silicosis, poisoning through chronic exposure to compounds such as lead and beryllium and expected involvement in more modern identified conditions such as cancer, asthma, and a host of other respiratory and non-respiratory conditions which may be caused or influenced through exposure to dust.According to the ""Glossary of Atmospheric Chemistry Terms"" (IUPAC, 1990), ""Dust: Small, dry, solid particles projected into the air by natural forces, such as wind, volcanic eruption, and by mechanical or man-made processes such as crushing, grinding, milling, drilling, demolition, shoveling, conveying, screening, bagging, and sweeping. Dust particles are usually in the size range from about 1 to 100 µm in diameter, and they settle slowly under the influence of gravity."" It should be noted that the behavior of particulates with respect to settling rate in air is a function of particle mass and shape and therefore the geometric size of the particle can be misleading. Occupational hygienists utilize the concept of particle aerodynamic diameter as a more representative reflection of particle size. Particle aerodynamic diameter, is defined as ""the diameter of a hypothetical sphere of density 1 g/cm3 having the same terminal settling velocity in calm air as the particle in question, regardless of its geometric size, shape and true density."" The expression of particle size as aerodynamic diameter allows for a more consistent understanding of particle behavior both from a settling perspective as well as from the perspective of how dust particles will behave in the respiratory tract. Figure 1 illustrates settling rates for particles of various aerodynamic diameters. The relationship between particle size and settling rate is important for understanding what size of particles must be addressed by dust control strategies as well as what particle sizes represent the most danger from an exposure and occupational health perspective."

Jan 1, 2015

By Lifeng Yang, Xiang Zhang, Liang Yuan, Yonghui Wang, Bing Hou, Mian Chen, Rixing Zhang

Large-scale hydraulic fracturing technique has been widely applied to the development of shale gas reservoirs, where the interaction between natural fractures and critical fracture zones has substantial impact on the propagation of hydraulic fractures. Therefore, it is of significant importance to understand and experimentally verify such mechanism. To reach this end, tri-axial fracturing tests were implemented on 400mm×400mm×400mm block samples collected from Longmaxi shale outcrops. The interplay between hydraulic and natural fractures was investigated during the tests, factoring in the role of pump rate in affecting the created fracture network. Based on the experimental results, the critical fracture zone, defined as the weak formation zone nearby the wellbore created by staged pressure implementation that is observed rapid fracture propagation upon next stage of pressure increase, was thoroughly investigated. The analysis illustrates that given the high brittleness of the shale formation, abundant critical fracture zones are generated around natural fractures with pressure building up at a relatively low pump rate. As the pump rate increases, hydraulic fractures initiate and come into play with critical fracture zones, implying emergence of a large number of micro-cracks. A changing pump rate modifies the way of interaction between hydraulic and natural fractures and the subsequent formation of fracture network. Long term fracturing fluid injection with relatively low pump rate below the activation of critical zones is suggested. Also proposed is appropriate timing when applying a specific pump rate that will contribute to the improvement of hydraulic fracture propagation.

Jan 1, 2015

By Shazad Hosein, William Birch, Douglas A. Anderson

This paper will present the results of tests of a new method for assessing explosive performance using wavelet transform analysis of standard blast seismograms. The theoretical background of the method was presented at an earlier ISEE conference.

Jan 1, 2015

By W. Beres

Many non-commercial operators are currently faced with the need to operate fleets of legacy gas turbine engines. How long such engines can be kept in service safely, without replacing a significant portion of their aging structural components, has become a growing concern to engine life-cycle managers, due to uncertainties in the remaining lives of critical components of these engines. This paper describes the application of the damage tolerance methodology to predict safe inspection intervals (SII) for critical components of gas turbine engines, using components of a turboprop engine for a transport aircraft as examples. High temperature components of this engine are made of advanced aerospace alloys. The methods of predicting three-dimensional fatigue crack growth at the critical location of turbine discs and spacers using both commercial and in-house developed algorithms are presented. Sensitivity analyses are performed to determine the effect of variations in material parameters on the predicted safe inspection intervals. In addition, spin rig tests performed for both turbine discs and spacers are described. Finally, crack growth rates predicted by numerical analyses are compared to those obtained from spin rig testing and the damage tolerance of the turbine components is assessed.

Jan 1, 2015