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By the use of flotation tests it was confirmed that there are two functions of oxygen in sulphide mineral flotation. Sized samples of galena and chalcopyrite were sulphidized, washed free of excess sulphide ion, and then contacted with air-saturated water for certain lengths of time. The mineral was then transferred to a sealed laboratory flotation cell containing water with a known concentration of dissolved oxygen. Xanthate and frother were added and flotation continued for 1 min.Both the extent of mineral oxidation and the concentration of dissolved oxygen markedly affected the flotation of galena and chalcopyrite. The response to a change in either variable is dependent on the level of the other, but generally best flotation occurs with the maximum degree of air saturation of the pulp. Galena flotation is hindered by oxidation of the mineral beyond a small threshold amount but a similar effect for chalcopyrite was not observed...

Jan 1, 1967

By Kenneth Wardell

Criteria have been fully developed for determining the optimum size of oil and gas well blocks. The criteria lead to the formation of well barrier pillars which are, of themselves, inherently stable and take account of variable mine roof and floor conditions. The criteria ensure, through considerations of ground movement, that strains transmitted to well casings, are within tolerable limits of casing specifications. The criteria cater for well barrier pillars in multi-seam mining situations and where previous old mining has taken place. The criteria maintain flexibility in being adaptable to local mine design situations. The criteria are applicable to proposed extraction thicknesses up to 15 feet at depths up to 2,400 feet. The criteria are related to producing wells and to abandoned wells. In the latter connection, various states of well abandonment are recognised.

Jan 1, 1980

By William H. Hamilton

INTRODUCTION It was not very many years ago that tunneling machine manufacturers spent considerable time trying to convince contractors and mine operators of the advantages of mechanical tunnel boring over conventional drill and blast methods. Today there are few doubters left. There is universal agreement that, not only are tunneling machines here to stay, but the ratio of bored rock tunnels to blasted rock tunnels is increasing at an accelerated pace, and within the next twenty years I predict almost all tunnels will be bored by machine. I believe we are today at a very important mile-post in the development of tunnel boring systems. Felix Gaye stated in his recent article (1) "It is important to disseminate between the efficiency of cutting tools and the overall efficiency of the boring operation". Mechanized tunnel boring in the past placed almost total emphasis on the rock cutting and boring ability of the tunneling machine. With advancements in technology and better solutions to the problems of rock fracture, steering control, and structural design, the emphasis today can be placed on the total-system concept. Tunneling machine design, as one of the key elements in the overall system, presents many problems that are not totally solved today. These design problems are, in the most part, not related with rock fracture, but rather with criteria associated with the over-all operation.

Jan 1, 1997

By Eric Konigsmann

"The Pogo project is located on the Goodpaster River, 38 miles north of Delta Junction in east central Alaska. Sumitomo Metal Mining and Teck Corporation are planning to develop a 2,500 ton per day underground mine and mill at Pogo. A preliminary resource of 5.5 million ounces of gold has been identified in two flat lying lenses. An underground adit has been developed to facilitate underground drilling of the deposit and to provide samples for bench and pilot scale metallurgical testwork.Flowsheet development included the evaluation of several processing options. The final flowsheet selected includes SAGhall mill grinding, gravity concentration with intensive cyanidation and direct electrowinning, sulfide flotation with ultrafine regrinding, and cyanide leaching and CIP gold recovery from the flotation concentrates. Flotation tailings will be filtered for placement in a dry stack storage facility or disposed of as paste backfill underground. All of the CIP tailings will be disposed of underground as paste backfill. A pilot plant was carried out to evaluate the proposed flowsheet described above and to confirm the gravity recovery predictions.Great care was taken in the development of the flowsheet and site layout concepts to mitigate the environmental impact of the proposed operation. An overview of the site water management concepts is presented and the impact of water issues on the process flowsheet is discussed."

Jan 1, 2002

By D. X. Tang, G. Wilson, S. S. Peng

Design and implementation of a roof bolting plan requires reliable geotechnical information of strata, such as rock strength, and locations of interfaces and voids/fractures. The drilling parameters obtained during normal roof bolt installation cycle provide a fast and economic way to gather information on the geological structure within the bolted horizon. The purpose of this research project is to develop a method for identifying the geological features in the mine roof strata based on drilling parameters of roof bolter. The criterion for void/fracture prediction has been developed and proven valid. This paper focuses on the estimation of the strength of roof strata by using drilling parameters. Based on the results of a series of underground and laboratory tests, feed pressure is found to be the most sensitive parameter when the strength of roof strata changes. Moreover, it was also found that both penetration rate and rotation rate have obvious impact on the magnitude of feed pressure. Based on these findings, the criterion for the estimation of roof strata strength has been developed using the relationship among feed pressure, penetration rate and rotation rate and implemented in MRGIS.

Jan 1, 2006

By G. R. Corbett

Between 1977 and 1984, No. 26 Colliery, at Glace Bay in the Sydney Coalfield, suffered from a series of 37 rock/gas outbursts. These events were characterized by the complete pulverization of a sandstone which was propelled into the mine roadway and an associated release of methane gas. The events began to appear at a depth of 700 m and increased in intensity and damage to the excavation as the mining depth increased. At the time of the closure of No. 26 Colliery (as a result of an unrelated fire), these outbursts were the subject of intensive investigation. Although No. 26 is now closed, there is concern that similar events could appear at Phalen Colliery where current development work is proceeding at a depth close to the 700 m threshold. Past investigations into rock/gas outbursts included studies of in situ stresses, the simulation of outburst events in the laboratory, investigations into the potential for destressing an& degassing of problem sandstone and the development of numerical models to assist in the design of openings in outburst prone ground. However, despite this work, methods of predicting outburst conditions are presently limited to examination of probe hole cores for core discing, and methods of working under such conditions are limited to boring and firing and using volley firing techniques to initiate any outbursts while workers are safely out of the heading. During this investigation of worldwide occurrences of this phenomena, literature obtained suggested that outbursts might generate microseismic precursors. An intrinsically safe (IS) microseismic monitoring system was designed and developed based on CANMET's rockburst monitoring system currently in use in hardrock mines, and installed in a development roadway at the deepest extent of the Phalen Colliery. The system will record microseismic activity associated with development work to try to identify characteristic precursors of outburst-prone conditions. This paper describes the steps taken to identify a microseismic system suitable for use at Phalen colliery, of which part of the requirement was that it be IS and approved for use in the Sydney Coalfield. The modifications to the selected system are described, along with its capabilities and the preliminary results of its performance over the first few months of use.

Jan 1, 1994

By R. L. Dunsmore

Introduction If one had been called upon to describe petroleum oil refining seventy-five years ago, he could have acceded to the request quite satisfactorily in about fifteen minutes. Fifteen years ago, an hour and a half would have been sufficient to give a general idea of oil refining, and of the equipment used for this purpose. Today, so extensive has been the research into all phases of the refining and manufacturing of petroleum products, and so rapid the strides in improvement in technique and equipment, that I doubt if a week would suffice to give an adequate outline of ail the ramifications of present-day oil refining. I propose to only 'hit the high spots', dealing particularly with the equipment and methods employed at the Imperoyal refinery, which you are to visit. Crude oil, the refiner's raw material, contains essentially only two elements, hydrogen and carbon. These are not present in the free state but are combined in various proportions as 'hydrocarbons'. A given crude oil is not made up of just one hydrocarbon, but of myriads; some solid, others liquid, and still others gaseous at atmospheric temperature and pressure, ail dissolved one in the other. Moreover, the nature and the relative amounts of the several hydrocarbons vary very considerably in crude oils from different sources. That is, a 'crude' from Oklahoma will contain hydrocarbons not present in crude from Mexico, and is different again from the Venezuela crude. Not only this but oil in a certain well in, say, Peru may be differently constituted from that in a well half a mile distant from it.

Jan 1, 1931

By H. H. Dreissen, F. J. Fontein

The operating principle of the classifying cyclone has been described often but some special aspects of the cyclone receive further clarification here. In addition, several uses of the classifiers are summarized and made clear by means of practical examples. In coal and ore washeries, the washing cyclone is widely used for the separation by specific gravity of sizes up to about 12 mm. This application has lately been extended to the separation by specific gravity of particles up to about 50 mm. This use makes special demands on the construction and wear resistance of the cyclone. The sieve bend, a development of the Dutch State Mines which is less well known than the hydrocy-clone, is dealt with at some length. The sieve bend is an apparatus designed for wet screening. Attention is given to the variables influencing the performance of the sieve bend. Hydrocyclones are now so widely applied that it would be difficult to find an industry not, directly or indirectly, using them or knowing how to use them since publications on this subject abound.1-3,5,9-11,13-15 However, because of the large number of variables influencing the operation of classifying cyclones, it is not entirely possible to calculate the results of this type of cyclone. Therefore, a number of lesser known variables will be discussed here along with some special applications of the classifying cyclone. FACTORS INFLUENCING CYCLONE CLASSIFICATION Shape of Particles: The shape of particles may cause a much coarser classification than the one expected, considering the sieve analysis and the cyclone dimensions chosen. This was clearly shown by feeding a mixture of spheres and disks in water into a cyclone. The spheres were 0.36 mm diam and the disks, 3 mm diam and 0.03 mm thick. These dimensions were chosen in order that the disks and spheres might have the same rates of fall under gravity. Both spheres and disks had a specific gravity of 1.05. The results obtained with these particles in a cyclone are summarized in Table I. Test No. 2 shows that the catch of spheres was

Jan 1, 1963

By Robert Burgess, Dale Gill, Jaco Steyn, Bill Kyslinger

"With mining, especially coal extraction, comes the necessity of supporting the roof. Since the 1950s, the primary method for roof support has been the use of roof bolts. Roof bolting is considered one of the most hazardous jobs in underground coal mining. In 2004, there were 3,405 injuries reported to the U.S. Mine Safety and Health Administration (MSHA). Of those injuries, 17 percent were associated with bolting machines (593 injuries). The majority of the injuries resulted from rock falling from supported roof. However, injuries involving a part of the body being struck by, or caught between, during bolting and drilling occurred with relatively high frequency (Burgess and Steiner, 2007).Roof drilling and bolt installation is labor-intensive and repetitive. These labor-intensive and repetitive requirements can lead to cumulative trauma. Operators are expected to perform a considerable amount of lifting, carrying, bending, reaching and stretching. Back and shoulders become sore from bending and twisting to install bolts or lift and position drill steels, wrenches and bolts. Confined operator spaces also contribute to difficult and awkward working positions for the operators (Cornelius and Turin, 1998).In South Africa, the majority of the roof bolting machines used are “man-in-position” style machines (Fig. 1). This puts the operator in close proximity to where the drilling and bolting process is performed. When proper operation procedures are followed, it has been proven to be a very effective, productive and safe system. The MSHA-certified automatic temporary roof support (ATRS), canopies and dust collection system of Fletcher bolters all provide the operator with unparalleled protection. However, there are some occupational hazards inherent to the zone located next to the drilling and bolting zone. This has led some customers to request relocating the operator away from this zone. The idea being that the operators will no longer be located in the face area, greatly reducing their exposure to dust, noise, machine and geological hazards."

Mar 1, 2017

By John Latilla

Exxaro Mining?s Matla Coal situated in Mpumalanga, South Africa operates two shortwall faces on the No 4 and No 2 seam while the No 5 seam has also been longwalled in the past. Severe strata loading events have lead to a number of serious roof falls on the wall face (facebreaks) resulting in safety threats as well as considerable production losses. In 2002 the No 4 seam shortwall suffered a facebreak restricted mainly to the tailgate side of the mining panel due to a thick, near surface dolerite sill not breaking properly. This was partly due to the premature suspension of longwalling in the overlying No 5 seam. The resultant overloading lead to severe pillar damage and subsequent bord collapse. Surface pre-split blasting was successfully used to relieve the pressure as well as to pre-condition the dolerite above the following two panels. The shortwall on the No 2 seam has experienced mid-face loading due to No 4 seam chain pillars lying over this area and creating a secondary cantilever effect. Pre-split blasting of the solid rock above the No 4 seam pillars has resulted in a significant reduction in the number of facebreaks. The panel layout of the No 2 seam was subsequently changed so that the chain pillars on both the No 4 and No 2 seam are superimposed whereas previously they were offset.

Jan 1, 2007

By L. Lui, A. Cauchon, A. R. Laplante

"The gravity circuit at Les Mines Camchib Inc. consists of two pinched sluices to bleed a feed to one of two 76 cm (30"") Knelson concentrator. The Knelson concentrate is upgraded to smeltable grade with a smaller Knelson (18/30 cm) and a riffleless table. Their tails are column cyanided and washed prior to recycle to the grinding circuit. This paper details size-by-size circuit performance. The Knelsons recover around 90% of free gold (as determined by Mozley Laboratory Separator), even below 37 µm. The sluices are ineffective, with upgrading ratios around 2, but approaching unity in the fine sizes. Much of the effectiveness of the circuit lies in the high gold circulating loads in the grinding circuit, which partly atone for the poor sluice performance, and the ability of the Knelsons to recover free gold. Secondary upgrading recovers slightly above 99% of the primary concentrate gold, 90% of it in a 65% Au concentrate and the balance in a heavily loaded (10 to 20 oz/st) pregnant solution. INTRODUCTIONBackgroundThe operating performance of the mill of Les Mines Camchib Inc. has been described earlier (Laplante et al., 1989). The presence of significant chalcopyrite (1 % and up) makes flotation necessary prior to cyanidation, to limit cyanide consumption and minimize environmental impact. In 1982, the presence of very high gold circulating loads in the grinding circuit lead to the commissioning of a gravity circuit, schematically shown in Figure 1. Gravity recovery of gold has been found beneficial because it increases metallurgical recovery by 1-3% (Laplante et al, 1987), as only part of the flotation tail is cyanided, and economic recovery, because of the lower net smelter return of gold in the flotation concentrate (as compared with the gravity concentrate). The latter increase is estimated, with a net smelter return of 95%, at 1.5% when gold recovery by gravity is equal to 30%. In early 1988, a sampling program was initiated to characterize the behaviour of gold in the grinding/gravity circuit. This paper reports on the results of this study."

Jan 1, 1990

By V. I. Lakshmanan

Process Research ORTECH Inc. (PRO), with its in-depth knowledge on cobalt behaviour in nickel matte smelters and its novel mixed chloride hydrometallurgical processing, is developing a hybrid process to enhance cobalt recovery. PRO’s experimental data is compared with plant information on cobalt behaviour in smelters. In final stages of iron rejection in the converters, the thermodynamics of the matte-slag system dictates the undesirable transfer of the cobalt to the final converter slags. This results in much lower cobalt recovery in the product Copper/Nickel matte (<60%) in present copper and nickel smelters. This information is used to transfer cobalt into desired quantity of converter slag. The enriched cobalt slag is subjected to PRO mixed chloride process to recover nickel, and cobalt as high value salts of importance in lithium ion batteries. From a typical converter slag containing 3.5% Ni, 1.5% Co, and 1.0% Cu, PRO leach process extracts 98 % Ni, and 98 % Co, and 99% Cu. Application of this process to enhance cobalt recovery in typical Copper/Nickel smelters is presented. In addition, this will also enhance the Copper and Nickel recovery. Both these aspects are of interest to the Copper, Nickel, and cobalt producers. INTRODUCTION In pyrometallurgical extraction of copper and nickel from sulphide ores cobalt often occurs with copper and nickel. The requirement of cobalt is increasing due to its need in lithium ion cells used in electric vehicles. Therefore its efficient and economical extraction in a form suitable for use in lithium batteries is of great interest at present. In the pyrometallurgical processing of copper and nickel sulphide concentrates the concentrate is smelted to produce a furnace matte, which is then sent for converting to remove the iron to produce iron free (~1% Fe) matte for further processing to copper or nickel matte. The copper/nickel matte is processed for metals recovery by hydrometallurgical or vapo-metallurgical or oxidation – reduction routes to make market products. As shown in Figures 1 and 2 the slags are produced in the smelting step and in the converting steps. The metal losses in smelting are controlled by the oxygen pressure in that step and slag production which is controlled by concentrate grade. The slag produced in the converting step which is carried out at a higher oxygen pressure contains higher level of metals is often returned to the smelting step to increase value metals recovery.

Jan 1, 2019

Who Macraes Mining Company Limited is can be summed up by the following statements: +&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; We have been New Zealand&apos;s largest gold producer for seven years +&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; We have one of the lowest market capitalisation per reserve ounce of the gold producers in the &nbsp;Australian Gold Index +&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; We have a resource finding cost of less than NZ$l0 per ounce +&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; We have a large land bank with proven reserves +&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; We have an Operating Cash Margin of approximately NZ$200 per ounce +&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; We have reduced our Dry Milled Tonne Cost by 34% since 1992 &nbsp; Our Mission is to continually grow our gold business, through maximising cashflow and focusing on our value drivers being: +&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; Increasing reserves +&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; Increasing cash operating margins +&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; Increasing production &nbsp; The real challenge is the reduction of operating costs and the optimisation of revenue, particularly in the current gold price environment. &nbsp; The Company has as at 31 December 1996 total mineral resources of 6.1 million ounces and reserves of 3.4 million ounces. This together with our current cash position of approximately NZ$15 million and strong hedging book of approximately 800,000 ounces places the Company on a sound financial footing whilst positioning itself to aggressively pursue its growth strategy when gold price and market conditions improve.

Jan 1, 1997

By Greenwood J. N

This work was commenced at a time when information on the manufacture of cemented tungsten carbide was urgently needed in Australia. Much information of a general type has been published, but many of the details of the processes used are still undisclosed. The aim of this research was to determine a satisfactory way in which cemented tungsten carbide could, be made, and to investigate the problems which are associated with the process. As the work proceeded, its ramifications grew continually, and it was necessary to limit the possible lines of investigation. After much experimental work, a 9% cobalt-tungsten carbide alloy was developed which had satisfactory properties when used as a cutting tip. The effect of certain variables on the properties of this particular alloy was investigated.The tungsten carbide was prepared in stages from King Island scheelite concentrates under strict laboratory control, whilst the cobalt (1) used was made from cobalt oxide prepared from crude cobalt oxide obtained from Eisdon.In order to clarify the detailed experimental work, a brief summary of the method used for the preparation of cemented tungsten carbide follows.Tungsten carbide and cobalt are prepared in a very finely powdered state, and are then thor,oughly mixed by a ball milling operation. The resultant mixture is pressed in a suitably shaped die into small compacts which are subsequently &apos;&apos;&apos;presintered,&apos;&apos; i.e., heated&apos; in hydrogen between 800&#176;C. and 1000&#176;C. The final sintering is carried out in hydrogen between 1,400&#176;C.and 1,600&#176;C. for about half an hour. These &quot;alloys&quot; may contain from 3 to 13% cobalt, depending on the particular properties required of them.PREPARATION OF MATERIALSThe tungsten oxide prepared as described by Smithells (2) was extremely finely divided, and after a few hours&apos; grinding in a ball mill, the powder consisted of material below 10 microns iJ;l size. The oxide was reduced to tungsten metal with hydrogen in a tube furnace. The reduction was carried out at 800-900&#176; C., a rapid flow of hydrogen being maintained in order to remove the water vapour&apos; formed as a result of the reactions:

Jan 1, 1942

By Boden A

A procedure was developed for recovering metal values from copper-smelter fume. The fume is first leached to neutrality with dilute sulphuric acid to obtain a solution of zinc sulphate containing a low level of impurities. The tailings from this leach are treated with hydrochloric acid in two stages, in which tin and zinc are quantitatively leached and recovered as a tin concentrate and a zinc sulphatelzinc chloride solution.About 80 per cent of the lead sulphate is converted into lead chloride, which can be recovered as a pure product.Data on the effect of temperature, acid concentration, aeration, and solid/liquid ratios on the hydrochloric acid leach are presented, and the fate of the most important metals during the recovery process is described. Alternative treatments of the tailings from the neutral sulphuric acid leach were briefly investigated.

Jan 1, 1977

By Panshi Xie, Xicai Gao, Yi Luo, Youfu Zeng, Yongping Wu, Shenghu Luo

This research investigates roof deformation and failure characteristics, as well as mechanical interaction between the panels of the roof strata above two adjacent working faces in a steeply inclined coal seam. Physical modeling with photogrammetry measurement method has been employed in this investigation. The movement of roof strata and section pillar, as well as the stratum morphological characteristics, was quantitatively analyzed. Results show that the roof movement direction above the two panels has zoning characteristics, especially in the lower panel. Roof migration in the lower panel of the working face is larger than that in the upper panel. The roof to floor closure perpendicular to the seam direction is larger than the sliding along the seam. The maximum roof concave and convex bending occurred at the middle and upper parts of both panels; the roof bending in the upper panel mining area indicates a larger mining disturbance induced by lower panel mining. The void ratio contour of the lower panel is an asymmetrically arched shape, which is different from that of the upper panel area. The higher roof strata above the upper panel exhibit separation and breaking, whereas the lower roof exhibits compression due to mining in lower panel. The section pillar is compressed and slides slightly, which aggravates the mechanical interaction between the panels and increases the caving height of the roof over the lower panel and the periodic weighting intensity

By Panshi Xie, Xicai Gao, Yi Luo, Youfu Zeng, Yongping Wu, Shenghu Luo

This research investigates roof deformation and failure characteristics, as well as mechanical interaction between the panels of the roof strata above two adjacent working faces in a steeply inclined coal seam. Physical modeling with photogrammetry measurement method has been employed in this investigation. The movement of roof strata and section pillar, as well as the stratum morphological characteristics, was quantitatively analyzed. Results show that the roof movement direction above the two panels has zoning characteristics, especially in the lower panel. Roof migration in the lower panel of the working face is larger than that in the upper panel. The roof to floor closure perpendicular to the seam direction is larger than the sliding along the seam. The maximum roof concave and convex bending occurred at the middle and upper parts of both panels; the roof bending in the upper panel mining area indicates a larger mining disturbance induced by lower panel mining. The void ratio contour of the lower panel is an asymmetrically arched shape, which is different from that of the upper panel area. The higher roof strata above the upper panel exhibit separation and breaking, whereas the lower roof exhibits compression due to mining in lower panel. The section pillar is compressed and slides slightly, which aggravates the mechanical interaction between the panels and increases the caving height of the roof over the lower panel and the periodic weighting intensity

By Shail J. Butani

In 1986 the Bureau of Mines conducted a probability sample survey, Mining Industry Population Survey, to measure such employee characteristics as occupation; principal equipment operated; work location at the mine; present job, present company, and total mining experience; job-related training during the last 2 years; age; sex; race; and education. The population estimates are necessary to properly analyze the Mine Safety and Health Administration (MSHA) injury (includes illness and fatality data) statistics; that is, to compare and contrast injury rates for various subpopulations in order to identify those groups that are exhibiting higher than average injury rates. This report uses the survey&apos;s results to characterize the U.S. nonmetallic mining workforce from March through September 1986. Similar reports have been prepared for the metallic, stone, and sand and gravel mining industries, as well as for the entire metal and nonmetal mining (includes metallic, stone, sand and gravel, and nonmetallic industries) sector and the cool mining sector.

Jan 1, 1988

By Woodcock J. T

When an aqueous suspension of pyrite and manganese ore reacts with oxygen, manganese is dissolved by the ferrous sulphate and sulphuric acid produced by the oxidation of pyrite. The kinetics of certain steps in the overall reaction were studied. A rate equation for the oxidation of ferrous sulphate by gaseous oxygen was derived for the temperature range from 1000 to 200&#176; C. An exact rate equation for the production of ferrous ion from pyrite could not be established but it was shown that the temperature, oxygen pressure, pyrite surface area, and the reduction of ferric ion by pyrite are important. A rate equation was derived for the reaction of manganese dioxide with ferrous sulphate. A major facfor controlling the rate was whether or not ferric oxide was formed by hydrolysis at the manganese dioxide surface.It was shown that if hydrolysis was prevented the factor cpntrolling the rate of the overall reaction ,was the rate of production of ferrous ion, and little ferrous ion was oxidised by oxygen. When hydrolysis of iron did occur, the overall rate was not a simplefunction of anyone factor and much ferrous ion was wasted by oxidation with oxygen.INTRODUCTIONIn another paper (Cornelius and Woodcock, 1958) the results of the reaction of an aqueous suspension of a manganese ore and pyrite with oxygen are reported. It is shown that the ferrous ion and sulphuric acid generated in situ by the oxidation of pyrite, dissolves manganese as manganous sulphate. To obtain a better understanding of the process as a whole, the kinetics of certain steps in the overall reaction were studied.When an aqueous suspension of a manganese ore and pyrite reacts with oxygen, the overall reaction may be conventionally represented by equation (1) (Cornelius and Woodcock, 1958).2Mn02 + 2FeSz + 6i02 + 2HzO= 2MnS04 + 2H2S04+ F&apos;ez03 ... , .. (1)

Jan 1, 1958

By D. Michael Holloway

The California Department of Transportation (CALTRANS) evaluated several pile foundation schemes for supporting the structures along the realignment of Interstate 880. The project replaces the double-decked (Cypress) viaduct collapsed in Oakland, California during the 1989 Loma Prieta Earthquake. Structural support demands led to the selection of steel pipe piles (16-, 24-, and 42-inch-(406-, 610- and 1067-mm-)diameter), filled with concrete and steel reinforcement. Deep penetrations required through layers of very dense/cemented sands in some locations, caused serious drivability and pile integrity concerns. The need for large pile driving hammers and large diameter steel pipe piles pushed the engineers well beyond local experience. Such questions as the feasibility of driving the pipes closed-ended through dense upper strata and quantifying the effects of installation on the long-term capacities of the piles led Caltrans to develop a comprehensive pile test program to address the design and construction issues effectively. The results were furnished to prospective bidders on the production stages of the ensuing contracts.

Jan 1, 1995