Search Documents

By M. J. Gula

In the solvent extraction -electrowinning recovery of copper from oxide or sulfide ores there is a continuous transfer of iron and other impurities from the primary leach solution to the copper electrowinning electrolyte via chemical transfer or mechanical entrainment. Iron is the principal impurity that has to be controlled in the electrolyte by a "bleeding" of the electrowinning solution. This bleeding transfers copper and sulfuric acid back to the primary leach circuit along with the iron. Copper is recovered via the solvent extraction process and generally the sulfuric acid is used as a reagent in leaching. Unfortunately, cobalt, which is added to the electrowinning solution to modify the anodic process, is irreversibly lost through the bleeding operation. This cobalt loss represents a significant operating cost to SX-EW copper producers. DiphonixTM ion exchange resin contains diphosphonic acid and sulfonic acid functional groups on a polystyrene-divinyl benzene matrix. This resin has been found to strongly and selectively extract ferric ion from copper sulfate -sulfuric acid solutions containing cobalt. Thus, an ion exchange process using DiphonixTM resin for the control of iron has been developed to replace the conventional bleed stream process. The new process minimizes the loss of cobalt from the electrowinning circuit and strips the iron into a sulfate based solution suitable for leach solution makeup. In addition, this process can effect a lowering of the total iron concentration in the electrolyte circuit with an associated increase in current efficiency. In this paper, data on the loading and elution of iron are presented. Laboratory and pilot scale data will be discussed along with information on process design and comparative economics.

Jan 1, 1996

By Richard J. Fantel

The U.S. Bureau of Mines performed engineering and economic analyses on 130 domestic phosphate mines and deposits, all containing demonstrated resources, of which 73 are in the Southeastern states of Florida and North Carolina, to determine the domestic availability of phosphate rock. Of the total domestic resources studied (6.4 billion tons of recoverable rock) over 60 percent is found in these two Southeastern states. At an estimated cost of $30 per ton, in January 1981 dollars, approximately 1 billion tons of rock is potentially recoverable from Southeastern deposits, increasing to 3 billion tons at $45. In addition, there is nearly 6 billion tons of recoverable rock at the inferred level (some presently unmineable) in Florida and Georgia.

Jan 1, 1983

By D. L. Madge

The text of this chapter was not received in time for printing.

Jan 1, 1979

By C. Duke

The water treatment industry has historically been involved with reducing or inhibiting the inherant scale forming or fouling tendencies of natural waters associated with large industrial cooling water systems. Fouling is an extremely complex phenomenon. From a fundamental point of view, it may be characterized as a combined momentum, heat, and mass transfer problem. Chemical reaction kinetics is involved, as well as the solubility characteristics of salts in water and corrosion technology. It is a routine practice to over size pumps, piping and heat exchangers to compensate for fouling.

Jan 1, 1983

By P. C. van Aswegen

The Bacterial Oxidation (BIOX®) process for the pre-treatment of refractory ores for gold recovery developed by Genmin, the mining division of Gencor, has been operating successfully at the Fairview mine since October 1986. The continuous operation of a pilot plant at Genmin Process Research has resulted in further process developments to improve plant operating efficiencies. These new developments which include a higher solids content of the pulp feed to BIOX®, lower retention times, higher operating temperatures, lower power utilization for oxygen dispersion .and reduced nutrient addition have all been successfully implemented on the Fairview plant.lt has furthermore been confirmed that the arsenic precipitate formed in the neutralization of effluent solutions complies to the United States of America EPA standards. Continuous cyanidation pilot plant work conducted on BIOX® product has indicated that cyanide consumption can be drastically decreased if a continuous flowsheet is implemented in preference to a batch leaching system.

Jan 1, 1991

By Y. Luo

Surface subsidence monitoring is the most effective means for investigating the nature of, and developing the techniques for predicting, the surface movement and deformation process. However, because of imperfection in survey equipment and field practices, the surface movement data collected from field survey are not error-free. Also due to lack of proper numerical techniques for computing surface deformation from the measured surface movement data, a relatively large portion of the subsidence data collected could not provide more information other than surface movement. In this paper, the sources and magnitude of errors in the measured surface movements and calculated surface deformation are discussed. Techniques for improving the accuracy of the calculated deformation indices (i.e., slope, strain, and curvature) are developed. The proposed techniques include: (1) proper selection of monument spacing for subsidence monitoring; (2) a data smoothing technique for data pre-processing; and (3) a number of numerical methods and/or procedures for calculating surface deformation indices from the measured surface movement data.

Jan 1, 1992

By S. A. Lolon, J. F. Brune

"INTRODUCTION In underground longwall coal mining, the mined-out areas or gobs frequently contain methane which can form explosive methane-air mixtures. Historically, there have been many events of mine fires and explosions recorded in the United States and other countries that have demonstrated the existence of such explosive mixtures, herein referred to as Explosive Gas Zones (EGZs), inside and around the perimeter of bleeder-ventilated longwall gobs (Loane et al., 1975; Lynn et al., 1986; Elkins, et al., 2001; McKinney et al., 2001; Dziurzynski and Wasilewski, 2012; Brune, 2013). The risk of mine explosions can increase if the EGZs migrate out from the gob into the surrounding mine entries. Several factors can induce EGZs outflowing from the gob, but the most common cause is the fluctuating barometric pressure. Atmospheric pressures change regularly every day but can fluctuate abruptly and become increasingly hazardous in adverse weather conditions. Other sudden pressure changes can result from roof falls, failing ventilation controls and fan outages. Any such fluctuation of mine ventilation pressure will disturb the pressure differential between the gob and the surrounding mine workings and may cause EGZs to outgas from the gob. The correlation between major mine explosions and abrupt barometric pressure changes has been studied and confirmed for explosions in coal mining countries including the United States, South Africa, Australia, and Poland (Hosler, 1948; Boyer, 1964; Kissell et al., 1973; Fauconnier, 1992; Hemp, 1994; Wasilewski, 2014; Belle, 2014; and Lolon, 2017). Disastrous mine explosions appear to happen more frequently during stormy weather, which, in the United States, typically occurs during the late fall and winter seasons. ROOT CAUSE AND EFFECT OF GOB BREATHING Gob breathing is the result of the pressure differential between gob internal and external pressures caused by external atmospheric pressure fluctuations that occur naturally as a result of gravitational and thermal forces in the atmosphere (Lindzen and Chapman, 1969). Other major and sudden pressure changes may be caused by fan failures, failures of ventilation controls or roof falls can also cause an unexpected gob breathing. Normal barometric fluctuations occur every day but usually do not pose an explosion risk as they occur gradually so gob pressures have sufficient time to equilibrate. More extreme fluctuations associated with cyclonic weather systems and storms often result in more rapid and larger drops or rises in barometric pressure (Hosler, 1948; Fauconnier, 1992). A study by Lolon (2017) found that the timing of historical mine explosions showed consistency with the occurrence of abrupt and intense barometric variations."

Jan 1, 2018

By Yuting Xue, Khaled Mohamed

The failure of coal ribs is a major hazard in underground coal mines. Researchers from the National Institute for Occupational Safety and Health (NIOSH) have been working on the development of an engineering-based rib control method. A user-friendly standalone application, called Design of Rib Support (DORS), is being developed to ease the calculations of rib support. DORS can estimate the Primary Rib Support Density (PRSD, ton/ft2) for development loading. However, it still needs to take account of another key factor, bolt length, in rib support design. The bolt length can be estimated from the rib fracture depth, and this study focuses on the coal rib fracture depth analysis with numerical modeling and artificial neural network. A total of 331 FLAC3D simulations with different mining scenarios and rib conditions were conducted for this study. Machine learning was then used to predict coal rib fracture depth under different conditions. Based on the numerical simulations, the parameters for mining scenarios and rib conditions were collected as features for machine learning, and coal rib fracture depths were collected as the target to predict. Good data correlation (r-square) was obtained with the use of an artificial neural network. The

By Rolph Linder

It is generally known and accepted that the efficiency of the blast furnace process, expressed by the symbols specific production and coke consumption, is influenced by a large number of variables connected to the type of burden, the alloy contents of the produced iron and the conditions of production as composition and preheating of the blast, the furnace heat losses and the possible use of fuels added on the tuyere level. It is furthermore obvious, that the coke consumption of the process will be influenced by specific production which could be said to be the result of two counter-acting influences. With high production, realized through intensive blowing, the passage time of the ore through the furnace is shortened leading to a decrease of the indirect reduction taking place in the upper part of the shaft within the temperature range of 300 to 1000°C. Simultaneously the external heat losses (constant in time) will be smaller calculated on each ton of iron and the resulting change in coke consumption will be the effect of both those influences. It is certainly of interest to be able to predetermine the effect of those variables before a change in the production practice is carried out.

Jan 1, 1964

By R. J. Morlock

Prior to 1912, coal research for Republic Steel, Corporation was limited to a periodic box test conducted in a commercial coke oven. Then in 1912, a Koppers movable-wall test oven was -built to research wall pressures for selected blends and to conduct other varied research work. In the 1950's economic pressures caused a reassessment of position resulting in the establishment of a Coal and Coal Chemical research group in 1956. In 1958 this group, along with other groups of research endeavor were incorporated into the new Republic Steel Corporation Research Center at Independence¬ Ohio. Currently this section is divided into four groups. 1) Coal Preparation, 2) Coal-Chemicals, 3) Coal Characterization, and 4) Coal Carbonization. The objective of each group is described, and a brief listing of the work done under the first three groups is indicated. A more detailed description of the studies by the Coal Carbonization group of the coking characteristics of Republic Steel Corporation's coals as blended among themselves or in conjunction with selected purchased coals follows. The wall pressure, contraction, and stability index criteria are specified, and the method of assessing these criteria as a function of blend composition is indicated.

Jan 1, 1963

By M. A. Klugman

[This paper represents a portion of a lager study, concerning dispersion patterns of major, minor and trace elements in wall-rock about ore-bodies in part of the Colorado Mineral Belt. This phase of the work pertains to the Mg/Ca ratio variations in wall-rock adjacent to ore-bodies in two mines of the Alma-Horseshoe Mining District of Central Colorado. The mining district is located 80 miles southwest of Denver (Figure 1) on the east flank of the Mosquito Range. The area is typified by rugged relief with altitudes from 10,500 to 14,000 feet.]

Jan 1, 1962

By Kan Aketa

The Japanese iron and steel industry has been developed remarkably, supported by the increase of steel demand. In particular, progress in various technical aspects of the ironmaking process, including burden materials, equipment, and operation has greatly contributed to the increase in productivity and the reduction of the fuel rate in blast furnaces. With the recent rise in the price of petroleum, the conversion of the energy source from oil to coke has resulted in a temporary increase in the fuel rate of blast furnaces.

Jan 1, 1982

By D. R. Kelland

A program has been carried out over the last two years to apply the technology of High Gradient Magnetic Separation (HGMS) to the problem of mineral beneficiation and specifically oxidized taconite iron ores. This program, supported by the RANN division of the National Science Foundation, has consisted of a laboratory program at the Francis Bitter National Magnet Lab- oratory at MIT and a pilot investigation at the Hanna Mining Company Research Laboratory. 1 The laboratory tests were conducted using several batch type high gradient separators and a continuous separator with a rotating matrix which was constructed at the beginning of the program. The high field magnets available at F.B.N.M.L. were used for investigations above 10 kG but most of the test work was performed in the range of this field value. Ore samples were contributed by several iron ore companies and consisted of oxidized taconites having goethite and hematite as their principal components.

Jan 1, 1975

By Ernest B. Snyder

The word "line" has been used loosely for many forms of the common steel plant flux. For example, many people use the word "lime" for nigh calcium and dolomitic limestone, for high calcium and dolomitic quicklime (also called caustic lime, calcined lime; burnt lime, pulverized and pebble lime) and ;van for clinkered dolomite. Calcium hydroxide, also called slaked lime and hydrated lime, is called "lime" but is seldom used as a flux except when the quicklime air slakes in open boxes or bins. All of the above forms of "lime" are used in the steel plant. Calcium hydroxide is used for water treatment, acid neutralizing, and as a lubricant for wire drawing. All the other limes are used as fluxes in the sintering plant, blast furnace or steel producing furnaces. In the production of self-flux or super-flux sinter, high calcium and dolomitic limestone fines are used. Where quicklime fines are available, they may be added to the sinter mix also. The blast furnace uses both high calcium and/or dolomitic limestone. A few trials have been made using iron oxide stabilized dolomitic lime in an attempt to reduce coke consumption and to increase the production rate. The trials were very successful but would' not be economical, except in periods of coke shortages, with resulting extremely high coke cost and exceptionally high hot metal demand.

Jan 1, 1979

By R. J. Hickson

The giant El Abra copper mine project under development in Northern Chile will come on stream in early 1997 at a production rate of 500 million pounds of cathode copper annually. Ownership is 51 % Cyprus Amax and 49% Codelco. Cyprus Amax has construction responsibility. Total project cost is $1050 million. El Abra will incorporate latest operational technology with labor efficient practices to achieve world class productivity levels and low initial cash costs of about US $0.35/lb copper. Development procedures for the almost 800 million ton oxide deposit, as well as the hydrometallurgical processes selected for recovery of the copper values are discussed. Construction costs and pertinent technical data are shown.

Jan 1, 1996

By J. Fuchs

This paper describes the mechanized narrow vein cut-and-fill approach used for the Deep Copper orebody at Falconbridge Limited's Strathcona Mine. Strategies for achieving high productivity while maintaining ground stability at depth and controlling dilution are discussed, including the use of mini-electrohydraulic drilling equipment, containerized truck haulage, consolidated rockfill placement techniques, and a miners' incentive system.

Jan 1, 1992

By Hamid Maleki

Mine seismicity is influenced by the mechanical properties of both near-seam strata and overburden/underburden and the prudent selection of mining methods and mine layout designs, utilizing sitespecific structural setting of the mines. The importance of adequate data collection, monitoring, and prudent structural designs has long been recognized and utilized in many U.S. operations with adequate engineering resources. In this paper, two case studies of historic seismic events and contributing factors, in deep coal and trona mines with overburden thickness exceeding 1,500 ft, are reviewed using observations and analysis. By back analyzing the overburden response in a historic room-and-pillar coal mine, the overburden collapse mechanism associated with a 3.3 magnitude seismic event is reviewed as well as the need for improvements in designs including panel and barrier pillar widths. Similar high-order seismic events were also experienced in trona mines of the Green River Basin during 1990s, interrupting room-and-pillar mining and creating ground control concerns. Efforts to improve structural mine designs are described in this paper leading to stable and productive operations for decades following the high-order seismic events in both coal and trona case studies. These efforts included improving room-and-pillar extraction layouts and utilizing properly designed longwall mining techniques that were verified using long-term geotechnical instrumentation. The study mines are located on the Wasatch Plateau (WP), Utah and in the Green River Basin (GRB), Wyoming. More recently, in Utah’s East Mountain alone, Energy West Mining Company (EWMC) has extracted some 165 million tons of coal without any significant incidents. Overall, favorable geologic conditions and prudent mine layout designs are key elements to this successful experience in both single- and two-seam layouts. Utilization of conservatively designed longwall mining technique in the GRB has been geotechnically stable, using reported experience in 15 panels and monitoring results in the Northwest (NW) District with measurable longwallinduced seismicity being rare. These studies demonstrate a considerable amount of progress that has been made within the last four decades in the application of longwall mining technique, integrated monitoring, and analyses for the verification of structural designs in mines in the United States.

Jul 1, 2023

By B. T. Field

Pyroprocessing systems range from low temperature dryers to high temperature reactors. The materials and process requirements cover a broad spectrum. It is not the intent of this paper to do a detailed examination of individual processes and equipment, since that can be found in a multitude of other sources; rather it is the intent of this paper to examine the key process variables and offer empirical guidelines to assist in a user?s overall evaluation.

Jan 1, 1998

By D. A. Poulter

The stability of a liner system is influenced by many factors which can be compiled into four basic groups. They are: 1. the liner system components and physical characteristics; 2. the geometry and slope of the liner system; 3. the loading conditions on the liner system; and 4. the foundation conditions under the liner system. Failures in the liner system that are due to one or more factors from the first three groups usually result in movement relative to the plans of the liner system. Failures associated with factors in the fourth group result in deformation(s) across the liner system section beyond its design limits. For purposes of these discussions a failure in the liner system refers to displacements or movements resulting in physical damage to the liner system such that it can no longer function.

Jan 1, 1995

By G. L. Simmons

Aqueous pressure oxidation at low temperature, although desirable from a process engineering and operations point of view, presents unique problems when temperatures approach 160°C (320°F). In developing the pressure oxidation process for the Lone Tree Mine, elemental sulfur formation and agglomeration with pyrite proved to be a problem. This paper discusses some of the unique features of the Lone Tree sulfide deposit and its amenability to low temperature oxidation. Problems encountered during pilot plant operation and their solutions are discussed.

Jan 1, 1993