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By D. Hong

The leaching behavior of rhenium in ammonium iodide solutions with iodine as oxidant has been studied. Experiments were carried out in an autoclave. The effect of stirring speed, temperature, pH of the solution, iodine and iodide concentrations on the dissolution of rhenium was investigated. It was found that high temperature and high pH of the solutions were essential for the efficient leaching of rhenium. The dissolution rate was found to be dependent upon the concentration of iodine and iodide. It was concluded that the dissolution of rhenium under the conditions studied was controlled by mass transfer of iodine with an apparent activation energy of 15.77 kJ/mole.

Jan 1, 1997

By Richard Campbell, MEHMET KIZIL, Ismet Canbulat, Serkan Saydam

The design and effectiveness of ground consolidation to regain stability of longwall faces vary widely and are often based predominantly on-site precedence or what were considered successful applications at other sites in similar situations. Little is known regarding product migration characteristics or change in rockmass conditions as a result of the application of consolidation chemicals. This paper presents the in-situ testing rationale designed and implemented recently across several longwall operations in the Bowen Basin, Queensland, Australia to provide quantitative measurement of the actual zone of influence of various resin injection products. Product migra- tion was physically measured by monitoring the change in rockmass temperature as a result of the exothermic chemical reaction of the various strata consolidation chemicals used. In conjunction with strata coring and Lugeon transmissivity testing pre- and post-injection to characterise the improvement in rockmass conditions due to consolidation product injection. The results of the testing programme, migration measurements, and rockmass assessment are presented, along with a discussion on how site- based Rock Mechanics Engineers can incorporate the data into the design of strata consolidation plans.

Jun 25, 2024

By V. Steinbach

Non-renewable mineral raw materials are grouped into three categories to investigate ways leading to sustainable use of natural resources: 1.) metallic resources, 2.) non-metallic resources with the exception of the fertilizer minerals, and 3) the fertilizer minerals for the nutrients nitrogen (N), potassium (K), and phosphorous (P). With the exception of minerals in Group 3 which are essential for plant growth, mankind does not need raw materials as such, only the intrinsic property of a material that fulfils a useful function. This is especially true for non-metallic materials. Metallic resources have the best chance to become renewable if one makes optimal use of the resources of the man-made technosphere. For the fertilizer elements K and N there does not exist a problem, because sea water or air respectively provide an inexhaustible source for them. This does not apply to P however. So P is serving as one of our apposite case studies for solving sustainability challenges. For all the challenges along the road from a non-sustainable to a sustainable resource economy technology can be envisioned to come to the rescue provided conditions that are considered to be essential for sustainable use for all natural resources-- affordable renewable energy and human ingenuity to find new solutions for functions, to optimize processes and to minimize losses-- are satisfied.

Jan 1, 2011

"INTRODUCTION Twin Metals Minnesota (TMM) (operating as a joint venture between Duluth Metals and Antofagasta PLC) assumed control of the property in 2010. Amec became involved with the project in 2011 and in 2012 incorporated additional drilling in order to update historic resource estimates. The Maturi geological model and resource estimate was updated in 2014 to incorporate additional information obtained during 2013 and 2014 drill campaigns. In 2017, Amec was purchased by the Wood Group and is now known as Wood. Geology The Twin Metals Minnesota (TMM) Maturi, Maturi Southwest, Birch Lake, and Spruce Road properties are located in northeastern Minnesota (Figure 1). This talk discussed the Maturi deposit only, although all four deposits share similarities. The following geology is summarized from Peterson and Severson (2002).Maturi lies within the Superior Province of the Canadian Shield which is exposed in central and northeastern Minnesota and extends northward into Ontario. In eastern Minnesota, the Midcontinent Rift System developed during crustal scale extension in the Mesoproterozoic Era. The rift system is traceable, as exposures of mantle-derived tholeiitic to subalkaline mafic lava flows, intrusives, and rift-filling fluvial sedimentary rocks, and in the subsurface as a gravity anomaly (high), from the eastern end of Lake Superior, arcing west across the lake basin, and extending south-southwest to northeastern Kansas. Intrusion of the Duluth Complex, circa 1,108 - 1,099 Ma, was related to rifting and is co-genetic with the North Shore Volcanic Group mafic volcanic rocks that form the hanging wall of the Duluth Complex to the east. Cu-Ni-precious metals (PM) mineralization including Pt, Pd, Au and Ag within the Duluth Complex is hosted by mafic to ultramafic intrusive rocks that are part of the overall intrusive complex. The Duluth Complex is defined as a more or less continuous mass of mafic to felsic plutonic rocks that extends northeastward for more than 170 miles (275 km) in an arcuate fashion from Duluth nearly to Grand Portage in Minnesota. It is bounded by a footwall of Paleoproterozoic sedimentary rocks and Archean granite-greenstone terranes (Peterson and Severson, 2002), and a hanging wall largely of comagmatic anorthosite, rift related flood basalts, and hypabyssal intrusions of the Beaver Bay Complex. Mineralization is hosted in the basal mineralized zone (BMZ) of the South Kawishiwi Intrusion (SKI). The SKI magmas intruded sub-horizontally between hangingwall Anorthositic Series (AN) rocks and footwall granitic rocks of the Neoarchean Giants Range batholith (GRB). The Maturi local geology and the deposit footprint (shaded orange) is shown in Figure 2."

Jan 1, 2018

By T. H. Ueng

Solving ventilation networks of natural air splitting is a classical problem in mine ventilation. A common approach to this problem is to formulate it based on Kirchhoff's voltage and current laws and obtain the solution by an iterative technique known as the Hardy Cross method. In this paper, it is shown that the problem can be formulated and analyzed as an unconstrained optimization (minimization) problem. The computational experience with the method of conjugate gradients is also discussed.

Jan 1, 1984

By M. Misra

The dielectric properties and flotability of different ranks of Argonne Premium Coal samples are presented. The flotability of different ranks of coal are correlated with the dielectric properties and intrinsic moisture (or bound water) content. Measured dielectric properties of as-received coals and other constituents are incorporated into a mixture equation to calculate the dielectric properties of bound water present in the different ranks of coal. The nature of bound water present in low-rank hydrophilic coals is significantly different from that present in high-rank hydrophobic coals. The water molecules present in low-rank lignite have an oriented dipole-dipole interaction and are tightly bound to the surface. For high-rank coals, the water molecules are not bound to the surface and have a randomly distributed clathrate ice-like structure. Controlled thermal treatment can modify the structural nature of bound water present in low-rank hydrophilic coals and increase their flotability.

Jan 1, 1990

By A. J. Kwitowski

Remote control for mining machines ordinarily means the operator is not seated on the machine, but is located within direct view of the machine and work area Thus, remote control operators are exposed to the hazards of roof/rib falls and dust/methane explosions. The U.S. Bureau of Mines has developed a method to disassociate remote operators from these hazards. Off-board, computer-based "tele-operational" systems are utilized that station the operators one-hundred meters or more distant from the working faces. Details are provided for tele-operated systems for thin-seam extraction and haulage equipment in highwall and deep, room-and-pillar coal mines.

Jan 1, 1992

By J. R. J. Edwards

Jaspilite, a mineral consisting of silica and iron oxide in varying proportions, is one of the host rocks of the high grade ore deposits situated in the Middleback Range of South Australia. As a result of laboratory investigations, a flowsheet was postulated for the beneficiation of jaspilite to produce an acceptable grade product for feeding to blast furnaces, The flowsheet involved the reduction of the hematite in the haspilite to magnetite, the grinding of the reduced product to 95 pct minus 325 mesh Tyler followed by wet magnetic separation, hydroseparation and filtration to yield a magnetite concentrate. Agglomeration of the fine concentrate would then be necessary to meet the physical requirements of blast furnace feed. To prove the postulated flowsheet, to obtain a more accurate estimate of costs and to obtain design data for a commercial installation, a pilot plant was constructed at Whyalla, South Australia.

Jan 1, 1960

By N. W. Stump

New developments in on-stream analysis using immersed radioisotope gauges including results from plant installations are described. The control of grinding and flotation using a small digital computer has been complemented by this development. A control scheme for grinding which is based on maximum throughput at constant product size and preliminary work in flotation control are also outlined.

Jan 1, 1974

By D. R. Nagaraj

Adsorption of sulfide collectors such as xanthate on pyrite has been studied extensively over several decades using a wide variety of techniques. In spite of this, there are unanswered questions as to the identity of adsorbed species on pyrite surfaces -dixanthogen vs. iron xanthate complexes. Far less is known in non-xanthate collector systems. We have used Secondary Ion Mass Spectroscopy (SIMS) successfully in the past to obtain direct evidence for the identity of the adsorbed collector species on copper sulfides, galena and Cu-activated quartz. The present study is an extension of the SIMS analysis to investigate the adsorption of xanthate, dithiovhosphate, dithiocarbamate, and modified thionocarbamates and thioureas on pyrite. Adsorption of these collectors on chalcocite was also studied for comparison. An attempt was also made to obtain SIMS spectra for pure dixanthogens at room temperature. Only in the case of dithiocarbamate (DTC) was there direct evidence for the presence of not only the collector dimer, but also iron-DTC complexes. On chalcocite, only the copper-DTC complexes were detected (no dimer). In the case of xanthate, the collector molecular ion and its S adduct -which are possible fragments from dixanthogen -were detected on pyrite, along with a fragment peak: suggesting Fe2X. For dithiophosphate, the collector molecular ion and Fe(DTP)(OH) complex were detected (no dimer). For modified thionocarbamate and thiourea, adsorption on pyrite was negligible.

Jan 1, 1997

By P. Crouse, J. Obermeyer

"INTRODUCTION Site location and history The Holden Mine is a former underground copper mine that was developed and operated by the Howe Sound Mining Company (Howe Sound) from 1938 to 1957. The mine is located in north-central Washington State, U.S., near Lake Chelan in the area shown as Holden Village in Figure 1. Although Rio Tinto never owned or operated the mine, they are managing and funding a several hundred million dollar clean-up to prevent future water and soil contamination and to reclaim the former mine site under the United States Environmental Protection Agency (USEPA) Superfund process. The former mine included an onsite mill and a nearby housing complex for the miners. Howe Sound developed the mine as a series of near-horizontal drifts and tunnels, interspersed with stopes and shafts that connect different mine levels underground. The tunnels that were excavated to develop the mine total nearly 100 km in length.During development of the underground workings, Howe Sound removed more than 230,000 cubic meters (m3) of waste rock from the tunnels and deposited this material in two waste rock piles. Ore was processed from the mine in the onsite mill to produce a copper concentrate that was shipped off site for smelting. Roughly 10 million tonnes of tailings were produced as a by-product of the milling operation, most of which were deposited in three large impoundments (Tailings Piles 1, 2 and 3) directly south of and adjacent to Railroad Creek. Howe Sound closed the mine in 1957. In 1961, the property was transferred to Holden Village, Inc. (Holden Village), a not-for-profit corporation that maintains a year-round community and operates an interdenominational religious retreat in the former miners’ town. With the exception of the patented private land, the remainder of the Site is on National Forest lands and is administered by the U.S. Forest Service. The mine is remote. It is only accessible by boat or float plane from Chelan, Washington, up Lake Chelan to Lucerne, nearly 40 km. Vehicle access from Lucerne to the mine is provided through a 17.5-km-long winding gravel road that climbs 640 meters in elevation. The general site features are shown in Figure 2. Physical setting The Holden Mine is located on the eastern slopes of the Cascade Mountain Range at an elevation between 975 and 1,050 m above mean sea level. Holden Mine was developed adjacent to Railroad Creek, which lies in a glacial U-shaped valley carved into the igneous and metamorphic bedrock with steep-sided slopes (Figure 2)."

Jan 1, 2017

By Saul J. Escalera

Mechanisms involved in the depression of the sulfides: pyrite, chalcopyrite, galena and sphalerite with potassium permanganate have been investigated. Flotation tests were conducted using potassium amyl xanthate, Z-6, and pine oil in the absence and presence of potassium permanganate at around pH = 6. 5 naturally yielded by the sulfides in the pulp. On the basis of crystal chemistry considerations, the amount of xanthate adsorbed by the sulfides depends on the amount of sulfur and metal ions present on the surface; thus, the avidity of the sulfides for xanthate should increase in the order: sphalerite C chalcopyrite 4 galena 4 pyrite, and the ease of depression response to the permanganate action should be in the same order. Depression of the sulfides in the system occurs primarily due to the removal of the collector ions by the permanganate ions to form manganese dioxide and dixanthogen according to the reaction: 3 M(RX)2 + 2 Mn04 + 4 H20 2 ? MnO2 + 3(RX-XR) + 3 M+2 8OH where M represents the metal ion, RX the xanthate ion and (RX-XR) the dixanthogen molecule. Results seem to indicate that the permanganate ions play a triple role in the system: (1) they convert xanthate ions into dixanthogen, (2) they further oxidize the mineral surface and (3) if present in excess, they may oxidize the xanthate beyond the dixanthogen stage with the formation of CO2, H20 and SO4. All sulfides, except for chalcopyrite, showed a depression response in the order predicted regardless of the order of addition of xanthate and permanganate reagents. Chalcopyrite did not depress as easily; this behavior may be due to the avidity of the colloidal MnO2 to adsorb Cu+2 ions on its surface, this would destabilize the colloid making it coalesce with the formation of a layer of precipitated MnO2 on the surface of the mineral. The presence of this layer would prevent further action of the permanganate ions on chalcopyrite.

Jan 1, 1970

By Robert J. M. Miller

Thank you Mr. Chairman. For more than 15 years a debate has been taking place among students of massive sulphide deposits as to the origin of these deposits. Prior that time it was widely accepted that the deposits were of hydrothermal, epigenetic and even replacement origin (Wilson, 14). Kinkel, Knight, Stanton and others advanced hypotheses which would explain the, formation of the deposits by different, largely syngenetic, volcanogeric processes. I was fortunate in having become involved in exploration for these deposits at about the time the debate was beginning and thus had an opportunity to apply with some success, some of the new and old ideas for formation of massive sulphide deposits. The deposits which I will discuss today are all located n northwestern Quebec, in the Abitibi orogenic belt. Mattagami Lake Mines is about 100 miles due south and Noranda's Horne Mine about 200 miles south of James Bay. In 1959 I prepared a talk which was presented to the 1960 CIM Convention calling attention to the spatial and possible genetic relationship between the ore sulphides of the Mattagami Area, Quebec and the tuffite, as well as the structures which controlled the ore. In this present paper I would like to cover the following points: (1) The general criteria used by the epigeneticists to support their contention that the deposits were formed after the enclosing rocks.

Jan 1, 1973

By J. J. Moore

Combustion synthesis or self propagating high temperature synthesis (SHS) reaction systems are discussed with respect to thermodynamics and kinetics. In particular, tile effect of the process parameters, ego particle size, AHf, ignition and combustion temperatures on these self sustaining reactions is discussed. Combustion theory is used to investigate the effect of the overall activation energy of the SHS reaction on the combustion front propagation rate and in obtaining a clearer understanding of the transition from stable to unstable propagation. Finally, examples of the application of combustion synthesis to advanced materials processes are made, in particular the synthesis of Ni-Ti -X intermetallic shape memory alloys, TiC-Al2O3 and ZrB2 ?Al2O3 ceramic composite materials.

Jan 1, 1991

Good morning ladies and gentlemen of the AIME. I was doubly pleased when Toby Yu asked me to present to you my thoughts on the past, the present, and the future of bulk transportation by barge. My first pleasure comes from sharing with you the subject that has been my career for many years. I love this industry in the same way Mark Twain loved our rivers. Somehow, I can find in all of the activities that make up this crazy barge business the same sort of excitement that he found in "steam boating." The second reason for my enthusiasm is that Toby carefully pointed out that the presentation had to be kept to a maximum of 15 minutes. I can promise you that I will hold to his maximum time limit.

Jan 1, 1982

By E. Fregeau-Wu

To recycle steelmaking slags for their iron, manganese, and lime contents, removal of the phosphorus-bearing dicalcium silicate and calcium phosphate is essential. Slow-cooling of slags was necessary to promote the sufficient grain growth to achieve liberation. In-situ grain size distribution determination showed that a high soaking temperature, a long soaking time, a very slow cooling rate, and the addition of fluorspar were shown to promote grain growth. High gradient magnetic separation on slow-cooled slags removed much of the dicalcium silicate. Liberation modelling was used to discuss the breakage and beneficiation characteristics of the slow-cooled slags.

Jan 1, 1992

By H. W. Hintze

Coal handling facilities, such as utility plants, coal terminals, ports, manufacturing, processing, etc. Protect themselves against interruptions in coal receipts by maintaining a 60 to 90 day supply in storage. Not too long ago, these storage piles were referred in terms of hundreds or thousands of tons. Today, it is not unusual to have hundreds of thousands or millions of tons in storage. Burn, or shipping and receiving, rates have increased dramatically and storage piles have grown in horizontal as well as vertical dimensions. Fixed systems for delivering and retrieving coal from storage have increased in length and operating capacity and have become highly sophisticated in their operation. With few exceptions, mobile material handling equipment is used to handle all coal beyond the reach of these systems. These machines take excess loose coal from the fixed system to the storage area, place it on the storage pile, compact it, maintain the pile, protect against spontaneous combustion, the spread of fires if they occur, and return the coal to the reclaim system as required, plus many of the small chores around the facility.

Jan 1, 1981

By Pawan Bharadwaj, Wim Mulder, Thomas Tscharner, Guy Drijkoningen, Rob Jenneskens

"The Earth’s properties, composition and structure ahead of a tunnel boring machine (TBM) should be mapped for hazard assessment during excavation. We study the use of seismic-exploration techniques for this purpose. We focus on a seismic system for soft soils, where shear waves are better and easier to interpret than compressional waves, as has been shown over the last decade. The system is intended to be deployed on the machine’s cutter head, with a few seismic sources and sufficiently many seismic sensors to tackle spatial variability and noise characteristics. An important property of the newly developed system is its ability to process data with very little human interaction. Images need to be available in near real time, without human interactions slowing down the imaging process. This can be achieved by employing Full Waveform Inversion, which minimizes the difference between modeled and observed data. Because this method may suffer from local minima in the cost function if the data lack low-frequency information, we employ a dedicated seismic source that can generate sufficiently low frequencies for the relevant length scales. With data acquired in a number of field settings that mimic realistic TBM configurations, we show that the designed seismic system can successfully look ahead of the TBM and offers a valuable capability to support decision-making during tunnel excavation. INTRODUCTION While excavating a tunnel with a Tunnel Boring Machine (TBM), the geology and the ground conditions along the planned tunnel trajectory need to be investigated in order to safely and efficiently carry out the underground operations. This entails detecting the occurrence of boulders, foundations, pipes and faults, necessary to prevent hazards and time-consuming delays in the tunnel boring operations. In order to facilitate ground prediction ahead of a TBM, techniques as used in seismic exploration can be deployed. Two components common to seismic-exploration techniques are data acquisition and processing, the latter including inversion. We will discuss each of these for the application to tunnel excavation with TBM, in particular for soft soils."

Jan 1, 2016

By V. Srivastava, T. Ghosh

The modeling and simulation of semiautogenous (SAG) mills have been widely used in the design and optimization of mill performance in terms of its power draw, processing capacity and product size distribution. However, these models are solved under steady approximation and do not provide any information on mill charge distribution in real time. 7KLVSDSHUDWWHPSWVWRFKDUDFWHUL]HPLOOFRQWHQWVE\VROYLQJ:KLWHQ¶V¿UVW RUGHUFRQWHQW EDVHGPRGHOLQWKH0$7/$% Simulink environment. The parameters in the model, such as breakage rate constant, discharge rate and appearance function, were estimated using process and design data collected from a gold mine operating in Alaska coupled with a nonlinear parameter estimation scheme. This model was then used to predict the dynamic responses of other key operational variables, such as mill power, bearing pressure, charge level and product size distribution. The transient response of mill behavior with respect to changes in feed size distribution, tonnage and mill feed water is also presented. This dynamic simulation approach can be used for practicing different control strategy and training purposes. The observed response of mentioned variables was validated using dynamic response data from the plant to encompass operational characteristics of SAG mill behavior.

By H. M. Breza

Recovery of phosphate concentrate has received increased attention as the existing mine and plant production capacity limitations of the Texasgulf Inc. Aurora, North Carolina Mine are reached. Improved mining techniques and mineral processing of waste streams offer a potential to increase overall phosphate production without major expansion of the Mining facility. Innovative processes have been or are being identified to maximize pit mining recovery and to minimize losses in waste streams, resulting in more effective use of the valuable phosphate natural resource. This paper will describe the various continuous recovery improvement programs being implemented to achieve this goal.

Jan 1, 1994