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By E. W. GOODWIN, V. F. Parry, J. B. Goodman, L. D. Schmidt, J. D. Davis, A. C. Fieldner, W. S. Landers, J. L. ELDER

The Heliopore process is essentially an arrangement that uses the waste heat in the exhaust gas of an internal - combustion engine to carbonize coal (noncaking ) or lignite . The gases distilled from the coal furnish fuel for the internal - combustion engine , which drives an electric generator . Thus the main products of the plant are electricity and char . A flow diagram illustrating the principles of operation of the Heliopore process is given in figure 1. The primary equipment consists of a carbonizing retort , gas cooling and scrubbing equipment, a gas storage holder, and an engine to burn the gaseous carbonization products . Coal is charged into the top of the retort while the hot gases from the engine travel upward through special ducts in the retort countercurrent to the coal flow . The hot gases never come into direct contact with the coal . Char is discharged at the bottom of the retort and hot gases at the top . The gaseous products resulting from carbonization of the coal are drawn off by an exhauster through the condensing and scrubbing equipment to take out tar and liquor , then to a gas holder , and finally are burned in a gas engine . The gas engine drives an electric generator and the engine exhaust gases are returned to the retort to carbonize coal . The entire process was intended to be continuous and self - sustaining, and to use coal as the only fuel . The plant may be said to be a large - scale pilot plant in that , although it is of full commercial size , its main purpose is to provide data for the design of others of its type . The installation tested had a daily throughput of about 4 tons of coal . Figures 2 , 3 , and 4 picture some details of the plant and equipment used in the experimental testing . Further details of the equipment and engineering drawings of the castings are shown in figures 8 to 22 in the Appendix .

Dec 1, 1943

By Thomas R. Bur

The patterns of variation of the 21 anisotropic elastic constants with direction arc presented for all of the symmetry systems that are normally expected to occur in rocks and in the constituent minerals. The exception, which is not discussed, is the triclinic system for which no elastic constants are available. Variations are shown for rotations about the principal axes by means of polar graphs. These include graphs for all of the n-fold symmetry axes possible for elastic symmetry and thus make it possible to visualize variational patterns for rotations about any n-fold axis. Variations throughout space are shown by means of equal area projections for the only constants (those relating axial stress to axial strain) that are uniquely defined by a single closed surface. For those unfamiliar with the compliance (Sij) and stiffness (cij) coefficients, the variations that can be shown by Young's modulus (E), Poisson's ratio (v), and shear modulus (G) are also given.

Jan 1, 2012

By Kenneth J. Miller

The Federal Bureau of Mines coal-pyrite flotation process has been modi¬fied to produce a concentrated final clean coal slurry underflow that could be dewatered more effectively by filtration or centrifugation. This change was accomplished by redesigning the Bureau's two-stage flotation pilot plant facility and running the second-stage flotation step with undiluted or only partially diluted first stage coal froth concentrate. Results of the pilot plant flotation tests showed that substantial sulfur reduction could be achieved by flotation with undiluted pulp but some dilution is recommended for maximum selectivity. For example, coal-pyrite flotation in slurry of 25 percent solids yielded clean coal products analyzing as low as 0.7 percent pyritic sulfur and froth reject products containing slightly over 3.0 percent pyritic sulfur. In comparison, coal-pyrite flotation with pulp diluted to about 12.5 percent solids yielded clean coal containing as low as 0.4 percent pyritic sulfur and froth reject of 5.6 to 6.7 percent pyritic sulfur. Despite the need for some dilution, it was concluded that excellent coal-¬pyrite flotation selectivity could be achieved without diluting to 6 or 7 per¬cent solids as done in the earlier work. Thus the economics of coal-pyrite flotation would be improved by easing clean coal dewatering problems and by reducing second-stage flotation cell volume requirements.

Jan 1, 1977

By O. C. Blade

Sales of diesel fuel in the United States exceeded 150,000,000 barrels during 1953 and 140,000,000 barrels during 1952. Following are some figures on the distribution of this fuel computed from data issued by the Bureau of Mines. 2/ [ ] Deliveries of diesel type fuel from refineries totaled 91,170,000 barrels during the first six months of 1954, 3/ a corresponding figure for 1953 was 86,284,000 barrels.

Jan 1, 1954

By D. A. Reynolds, J. D. Davis

During early development of the blast furnace, Connellsville coke made entirely from Pittsburgh-bed coal proved to be an excellent fuel. The need for blending coking coals arose as the industry grew and it became necessary to carbonize coals having voking properties inferior to those of Pittsburgh coal Most coals carbonized today in continental Europe and this country are blonded: This practise has improved the quality of coke and permitted the utilization of coals that would yield inferior coke, if carbonized sepa- rately, The depletion of the world's better coking coals, which has been noted by leading coal technologists,2/4/wes accelerated during the recent war and. It is important, therefore, that reserves be evaluated and conserved. In the principal, steel-producing sections of this country, Pocahontas coals have been blended so extensively that the terms "low-volatile coking coal": and. "Pocahontas" have become virtually synonymous. Other low-volatile coals. have been used to manufacture metallurgical coke and will be used more extensively as, the supply of the better known and more accessible Pocahontas coals decreases. Recognizing the need for augmenting the supply of high-rank coking coals, the Bureau of Mines has included both low- and medium-volatile coals in its Survey of the Carbonizing Properties of American Coals, which was started with the cooperation of the American Gas Association in 1929. Twenty coals, 12 of low-volatile and 8 of medium-volatile rank, have been blended with high-volatile A Pittsburgh-bed coal, and five standard low- volatile coals have been blended with various high-volatile coals. Most of the results of carbonization tests of these coals and their blends have been

May 1, 1946

By Robert S. Schechter

A minitest of the new potassium chloride-potassium carbonate two-stage in-situ uranium leach process has been carried out at the Intercontinental Energy Corporation (IEC) Zamzow project site in South Texas. Substantial quantities of high concentration uranium were produced indicating the viability of the leach solution. The test results yield information regarding the reservoir dispersivity, the average cation-exchange capacity of the formation, and the distribution coefficients describing cation-exchange reactions. The test also indicates permeability anisotropy and the existence of disturbed flow fields.

Jan 1, 1985

By D. Bienstock

A high-B.t.u, gas can be synthesized by the catalytic methanation of a mixture of 2.5 to 3 parts of hydrogen to 1 part of carbon monoxide, obtained in the gasification of coal, using a steel catalyst followed by Raney nickel in a hot-gas-recycle system. Conversion of 99 percent of the H2+CO yields a fuel gas with a heating value of 983 to 1130 B.t.u. per cubic foot containing 78 to 96 percent methane, no carbon monoxide, and very small amounts of unsaturated hydrocarbons. With the steel catalyst alone, conversions were 85 to 90 percent, giving a fuel gas of 810 to 868 B.t.u, per cubic foot, or 847 to 975 B.t.u. on a C02-free basis. INTRODUCTION In 1948 the U.S, marketed production of natural gas was 5.15 trillion cubic feet; by 1958 it had reached 11.0 trillion cubic feet, a rate of growth of 8 percent annually. 4 5 Although demand is expected to increase less rapidly, by 1966 it may reach 16 trillion cubic feet, based on an estimated 4.7 percent annual increase.6

Jan 1, 1961

By A. W. Fahrenwald

The purpose of screening is to separate a crushed or natural product into one or more products in which size of grain is constant, or within certain size limits. The ore dresser finds need for this operation in the laboratory, in the study of ore-dressing processes, and for various purposes in the plants. In the plant, for example, screens are employed in closed circuit with crushing devices such as rolls, and sometimes are used in closed circuit with ball mills. Screens are generally used to prepare jig feed where a sized feed is wanted. For any given sieve opening there is in any feed a certain percentage of grains that will pass through the sieve meshes only with difficulty and under favorable conditions. For example, cylindrical grains of length greater than the maximum dimension of the sieve mesh and of diameter less than the sieve opening pass the sieve only when the long axis of the grain is normal or nearly normal to the sieve. Whether such grains should actually be in the through's or the oversize of a screening operation--considered from the point of view of the subsequent treatment of the grains--can not be said. The grains that pass the sieve opening in a screening process only under-favorable conditions have been named "difficult" grains by R. K. Warner.4 In many ore-dressing flow-sheets it probably matters little whether these difficult grains show up in the screen through's or oversize. The main objection to them is that they are sieve-blinding.

Jan 1, 1929

By A. W. Deurbrouck

This report describes the preparation characteristics of the significant coalbeds from which samples could be obtained in Webster County, W. Va. In 1964, approximately 825,000 tons of coal was produced in the county, of which 732,000 tons was mechanically cleaned in three preparation plants. The Sewell coal bed accounted for 94 percent of the coal produced. Twelve samples were collected from five coalbeds. Four of the samples would require upgrading to meet metallurgical requirements; two others of just over 8.0 percent ash would require some upgrading. In general the coalbed samples collected in the county were of medium-sulfur and medium-to low-ash content as received or after removal of the sink 1.58-specific-gravity material.

Jan 1, 1966

By J. E. Hamak

This publication contains analyses and related source data for 266 natural gas samples from 20 States and 2 foreign countries. None of the analyses have been previously published in annual reports. All samples were obtained and analyzed as part of the U.S. Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted since 1917. The analyses published herein were made by mass spectrometer and chromatograph.

Jan 1, 1992

By Benjamin W. Haynes

This Bureau of Mines publication comprises a compilation of the state of the science in Pacific Ocean manganese nodule mineralogy and elermental composition. The report is divided into three sections: morphology, mineralogy and elemental composition. The nodule morphology section defines what is considered a nodule for the study, and details the external characteristics and internal structure. Nodule mineralogy is discussed in three sections: manganese minerals, iron oxide minerals, and accessory minerals. The major manganese minerals discussed are todorokite, birnessite, and vernadite. The iron oxide minerals are less well known and include feroxyhyte, goethite, and lepidocrocite. Accessory minerals present include quartz, clays, and other silicates and nonsilicates. A discussion on moisture content is also included. The elemental composition section presents data on 74 elements occurring as cations or anions. Summary data, histograms, and interelement correlation coefficients are presented. The elements are grouped as follows: major and minor elements of potential economic interest (8), other major and minor elements (9), elements of environmental interest (8), rare-earth elements (15), precious-metal-group elements (6), radioactive elements (3), other trace elements (17), and anion-forming elements (8). Cross sectional determinations of Ni, Cu, Zn, Co, Pb, Fe, Ce, and Ba are given for a single nodule to show the general tendency of different growth patterns within a nodule because of different element associations and composition.

Jan 1, 1982

By H. Dolezal

A laboratory study of acid-ferrous sulfate treatment of low-grade manganese ores from the Cuyuna range, Minnesota resulted in 93-percent extraction of manganese as manganese sulfate with consumption of 3.8 pounds of H2S04 per pound of extracted manganese. Two types of ore were treated in consecutive stages. The first are contained carbonate minerals of manganese and iron, both soluble in H2S04 solution. The second ore contained manganese oxide minerals, insoluble in straight acid solution but soluble in the ferrous sulfate solution obtained from treating the first ore. Leaching data were obtained by countercurrent percolation of coarse (minus-1/2-inch) ore particles at room temperature and by agitating minus-65-mesh ore particles in heated solution. Extraction of manganese and acid consumption were the same, but the percolation leach required 6 days compared with 1 hour for hot agitation. Variations in the size of ore particles treated, leaching time, acid concentration, solution temperatures, and method of applying ferrous sulfate solution to the oxide ore were studied. The effects of several reagents for removing iron from solution and improving filtration were also studied.

Jan 1, 1959

By Albert W. Deurbrouck

The performance of four sand cones was evaluated by the Bureau of Mines in three preparation plants that utilized cones in various flow schemes. The cone at plant A was a simple two-product one that provided clean coal and refuse. Plant B had two cones; one cone made a primary separation and the other a secondary separation. The primary cone separated salable coal from heavy rejects. The secondary cone separated a low-ash metallurgical coal and an intermediate-ash product suitable for plant fuel or steam markets. In plant C the sand cone was equipped with a middlings draw Which continually removed an intermediate specific-gravity product below the surface of the cone. The three primary separations of raw coal effected between floats and sinks were excellent. The recovery efficiencies for the plus 1/4-inch material ranged from 99.8 to 97.6 percent, the error areas ranged from 19 to 23 square centimeters, and the probable errors in specific gravity ranged from 0.033 to 0.024. The performance data of the two secondary separations varied from excellent in plant B, where the separation was on a par with the primary separations, to somewhat inferior in plant C, where the secondary separation was effected at the middlings draw.

Jan 1, 1965

This section of Minerals and Materials analyzes the following three factors affecting the recent performance of the U.S. and world mineral industries: 1) the health of the U.S. and world economies, 2) the level of interest rates and 3) the performance of productivity in both the U.S. mineral industry and the general economy. While these indicators do not exhaust the possible critical factors, they represent an initial attempt to probe some of the considerations underlying the performance of the U.S. minerals and materials industry. The U.S. and World Economies It is essential to analyze the state of the U.S. and world economy because the demand for minerals and materials is a derived demand; that is, since minerals and materials are used in the productive process, the demand for them is a direct function of the demand for the finished products of which they are a basic input. Thus, the demand for minerals and materials is directly affected by changes in present and planned consumption and investment expenditures. The past two issues of this publication have highlighted the generally discouraging performance of the national and inter-national economies. Briefly, the world economy is in the third year of the first long recession in recent history where inflation rates have remained above 5 percent. With many countries either unable or unwilling to support domestic spending while inflation continues, there has been a growing tendency to institute trade-restrictive policies to support domestic demand. The resulting weakened demand conditions in exporting nations have had a direct effect on the mineral industry.

Jan 1, 1982

According to industry representatives, U.S. producers were listing unalloyed 95.5 percent aluminum ingot in October at 53-57.5 cents per pound, but reportedly much is being priced at 53 cents. New York dealers raised their October positions by about 3 cents to 56-56.5 cents, mainly to cover spot supply shortages. London Metal Exchange 3-month forward contracts traded up in October from 52.3 to 57.3 cents per pound and closed at 56.4 cents. ASBESTOS The Jaquays Asbestos Corp. has announced the imminent closure of its mine and mill in Globe, Arizona. This is the last asbestos producer in the State having operated continuously, except during the early thirties, since 1914. Cost of compliance with environmental regulations was given as the reason for closure.

Jan 1, 1978

By R. S. Fowkes

The Bureau of Mines constructed a fully automated pilot plant facility to study the hydraulic transportation of solids through a lock hopper feeder system. An equation for the energy requirements to transport coarse solids hydraulically proved applicable to this system. Optimum velocities were obtained for limestone, mine refuse, and bituminous coal. The experimental data, calculations, and graphs show the effect of velocity, specific gravity, and solids concentration on head loss and power requirements. Other data were obtained and evaluated to determine the effect of particle size on head loss. Results also are given for (a) tests using friction reducing polymers; (b) tests using seven test sections of steel alloy pipe to determine their wear characteristics; (c) tests to determine spatial segregation of moving particles; and (d) tests to determine the effect of shape, size, and specific gravity on particle velocity in a horizontal pipeline. The lock hopper feeder system was found practical for continuous hydraulic transportation of the material types and size ranges tested.

Jan 1, 1969

By Stanton L. Tainter

"INTRODUCTION Molybdenite, the only common mineral and ore of molybdenum, occurs wide¬-spread but is concentrated as the main ore mineral in commercial quantities in only a few known deposits. Consequently, the Government sought additional sources of the minerals as a precaution against the possible shortage of moylbdenm for war uses. Upon request by the War Production Board, the New Year’s Eve and Esperanza properties of the Amargosa Molybdenum & Copper Corp. were investigated by the Geological Survey 3/ and the bureau of Mines 4/. The Survey appraised the mineral potentialities of the deposit and prepared topographic and geologic maps, and the Bureau made a preliminary engineering examination. The deposits were previously examined by W. J. Vanderwilt, consulting engineer. It was largely due to his recommendations that interest was stimulated in the deposits.Development on the New Year’s Eve deposit indicated a small tonnage of sub marginal ore. There was little development at the Esperanza, but surface examination revealed a large volume of rock containing a little molybdenite and a trace of copper in the oxidized outcrops. Some molybdic oxide was noted suggesting that some molybdenite might have been leached from the oxidized outcrops and that the molybdenite content in the sulfide zone might be higher."

Feb 1, 1947

By Raymond W. Hiteshue, Sam Friedman, Robert Madden

Experiments were made in a semicontinuous unit to provide engineering data for designing experimental continuous systems . These systems would be used to study the hydrogasification of hvab coal and char (from lowtemperature carbonization ) to high - Btu gas . In experiments at 800 ° C and with a coal residence time of several seconds , yields of hydrocarbon gases increased from about 2,000 scf / ton of maf coal at 250 psig to 7,000 scf at 1,000 psig . With 15 minutes residence time , yields increased from 8,000 scf/ton of maf coal at 250 psig to 17,500 cubic feet at 1,000 psig . In all cases , small quantities of heavy oils were produced along with the gaseous hydrocarbons . Production of oils could be minimized with a corresponding increase in gaseous hydrocarbons by increasing the retention time of the volatiles within the hot zone . Yields of gaseous hydrocarbons from char were slightly greater than from coal under similar conditions . Although the hydrogasification reaction is very pressure dependent , substantial quantities of coal (40 to 60 percent ) could be reacted to gaseous hydrocarbons at pressures as low as 50 psig provided reaction temperatures were increased to 1,200 ° C. It was also demonstrated that a hvab coal could be hydrogasified continuously without incurring agglomeration . This was achieved by dispersing coal in a relatively large reactor with concurrent flow of hydrogen . At 1,000 psig and 800 ° C , it was possible to react about 35 percent of the coal and to produce a gas containing up to 52 percent methane .

Jan 1, 1964

A study was conducted by the Bureau of Mines to evaluate natural gas as an automotive fuel and to provide guidelines for optimum engine adjustments for low exhaust emissions. The study was conducted using a single-cylinder engine, a multicylinder engine, and a total of eight vehicles. Results from single-cylinder engine tests showed that the light-load, lean-limit misfire region for natural gas begins at an air-fuel ratio between 150 and 160 pct of stoichiometric. Changes in ignition timing significantly influenced emissions of nitrogen oxides and hydrocarbons, but had little effect on carbon monoxide emission. Low emissions can be achieved with current-design engines by adjustment of engine parameters, but only with heavy penalty to engine performance. Emissions from vehicles fueled with natural gas are virtually unaffected by ambient temperature change within the range 20° to 100° F. The organic emissions from engines fueled with natural gas were estimated to be 22 to 25 pct as reactive as the emissions produced using gasoline. Levels of exhaust emissions from vehicles fueled with natural gas were unchanged over 10,000 miles of normal driving.

Jan 1, 1973

By Jr. Karr

The Bureau of Mines studied the influence of carbonization method, temperature, and carrier gas on the composition of eight different low-temperature tars produced from a Colorado subbituminous coal. A fluidized bed was compared with an entrained bed, temperature was varied from 500° C to 650° C, and external heating using recycle gas as the carrier gas was compared with internal heating using oxygen-containing gas. The entrained bed yielded significantly more m-cresol and m-ethylphenol, indicating that thermodynamic equilibrium was more nearly approached in the system. Increasing the temperature greatly increased the yield of benzenes and naphthalenes, while paraffins, olefins, and total tar acids were reduced. Using oxygen in the carrier gas decreased the yield of low-boiling phenols and increased that of paraffins and olefins at 650° C.

Jan 1, 1966